WO2020259383A1 - 准分子激光退火装置、多晶硅薄膜的制备方法、薄膜晶体管及制备方法 - Google Patents
准分子激光退火装置、多晶硅薄膜的制备方法、薄膜晶体管及制备方法 Download PDFInfo
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- WO2020259383A1 WO2020259383A1 PCT/CN2020/096768 CN2020096768W WO2020259383A1 WO 2020259383 A1 WO2020259383 A1 WO 2020259383A1 CN 2020096768 W CN2020096768 W CN 2020096768W WO 2020259383 A1 WO2020259383 A1 WO 2020259383A1
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- 238000005224 laser annealing Methods 0.000 title claims abstract description 68
- 229910021420 polycrystalline silicon Inorganic materials 0.000 title claims abstract description 58
- 239000010409 thin film Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 230000003287 optical effect Effects 0.000 claims abstract description 85
- 230000005540 biological transmission Effects 0.000 claims abstract description 58
- 239000010408 film Substances 0.000 claims description 65
- 229910021417 amorphous silicon Inorganic materials 0.000 claims description 47
- 229920005591 polysilicon Polymers 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 38
- 239000000758 substrate Substances 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000000059 patterning Methods 0.000 claims description 4
- 230000003595 spectral effect Effects 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 20
- 238000010586 diagram Methods 0.000 description 19
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 8
- 229920001621 AMOLED Polymers 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000004065 semiconductor Substances 0.000 description 6
- 229910052581 Si3N4 Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 238000000137 annealing Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 238000012876 topography Methods 0.000 description 2
- HGCGQDMQKGRJNO-UHFFFAOYSA-N xenon monochloride Chemical compound [Xe]Cl HGCGQDMQKGRJNO-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
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- 239000002210 silicon-based material Substances 0.000 description 1
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- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/067—Dividing the beam into multiple beams, e.g. multifocusing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02524—Group 14 semiconducting materials
- H01L21/02532—Silicon, silicon germanium, germanium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02587—Structure
- H01L21/0259—Microstructure
- H01L21/02592—Microstructure amorphous
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02656—Special treatments
- H01L21/02664—Aftertreatments
- H01L21/02667—Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth
- H01L21/02675—Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth using laser beams
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
- H01L21/268—Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/324—Thermal treatment for modifying the properties of semiconductor bodies, e.g. annealing, sintering
Definitions
- the present disclosure relates to the field of display technology, and in particular to an excimer laser annealing device, a preparation method of a polysilicon film, a thin film transistor and a preparation method thereof.
- the production methods of polysilicon films mainly include: Excimer Laser Annealing (ELA), Solid Phase Crystallization (SPC), Metal Induced Crystallization (MIC), etc.
- ELA Excimer Laser Annealing
- SPC Solid Phase Crystallization
- MIC Metal Induced Crystallization
- LTPS TFT low temperature poly-silicon thin film transistor
- an excimer laser annealing device including: a laser output module configured to emit a first laser beam; a pulse extension module including a first beam splitting component and a transmission component; wherein the first beam splitting component is configured In order to receive the first laser beam when moving to the optical path of the first laser beam, the received first laser beam is divided into a first reflected light and a first emergent light, the first reflected light
- the laser energy accounts for 20% to 40% of the laser energy of the first laser beam; the first outgoing light is directly emitted, the first reflected light is directed to the transmission component, and will be transmitted through the The first reflected light after the component is transmitted is emitted; the transmission component is configured to receive the first reflected light, and cause the first reflected light to be transmitted to the first splitter after being transmitted in the transmission component part.
- the pulse extension module further includes a second beam splitting component and a driving component;
- the second beam splitting component is configured to receive the first laser beam when moving to the optical path of the first laser beam , Dividing the received first laser beam into second outgoing light and second reflected light, the laser energy of the second reflected light accounts for 40% to 60% of the laser energy of the first laser beam;
- the second emitted light is directly emitted, the second reflected light is emitted to the transmission component, and the second reflected light transmitted by the transmission component is emitted;
- the transmission component is also configured to receive The second reflected light, and the second reflected light is transmitted in the transmission assembly and then directed toward the second spectroscopic part;
- the driving part and the first spectroscopic part and the second spectroscopic part Are connected to each other and configured to drive the first beam splitting part and the second beam splitting part to move;
- the excimer laser annealing device further includes a controller, and the controller is connected with the driving part; the The controller is configured to control the driving
- the light splitting coefficient of the first light splitting component is 30%, and the light splitting coefficient of the second light splitting component is 50%.
- the laser output module includes a laser configured to emit the first laser beam.
- the laser output module includes a laser and a dimming component; the laser is configured to emit a second laser beam; the dimming component is arranged between the laser and the pulse extension module and is located The optical path of the second laser beam; the dimming component is configured to receive the second laser beam, adjust the laser energy of the second laser beam to obtain the first laser beam, and emit the The first laser beam; the laser energy of the first laser beam is less than the laser energy of the second laser beam.
- the laser is an excimer laser.
- the transmission assembly includes a first reflecting part, a second reflecting part, a third reflecting part, and a fourth reflecting part; the first reflecting part and the third reflecting part are arranged on the first reflecting part.
- One side of the optical path of the laser beam, the second reflecting part and the fourth reflecting part are arranged on the other side of the optical path of the first laser beam, and the first reflecting part and the fourth reflecting part Are arranged in a direction perpendicular to the optical path of the first laser beam, and the second reflective member and the third reflective member are arranged in a direction perpendicular to the optical path of the first laser beam.
- the first spectroscopic component is located on the optical path of the first laser beam; the first reflective component is configured to receive the first reflected light and direct the first reflected light to all The second reflective member; the second reflective member is configured to direct the first reflected light reflected by the first reflective member toward the third reflective member; the third reflective member is configured to pass through the The first reflected light reflected by the second reflective member is directed toward the fourth reflective member; the fourth reflective member is configured to direct the first reflected light reflected by the third reflective member toward the The first beam splitting component; or, the second beam splitting component is located on the optical path of the first laser beam; the first reflective component is configured to receive the second reflected light and emit the second reflected light toward the second Reflective part; the second reflective part is configured to direct the second reflected light reflected by the first reflective part toward the third reflective part; the third reflective part is configured to pass through the second The second reflected light reflected by the reflective member is directed toward the fourth reflective member; the fourth reflective member is configured to direct the second reflected light reflected by the third
- the first beam splitter includes a first bracket and a first beam splitter fixed in the first bracket
- the second beam splitter includes a second bracket and is fixed in the second bracket
- the drive component includes a motor, the motor is connected to the first bracket and the second bracket respectively.
- a method for preparing a polysilicon thin film which includes: forming an amorphous silicon thin film on a substrate and heating the amorphous silicon thin film; using the above-mentioned excimer laser annealing device to treat the amorphous silicon thin film.
- the crystalline silicon film is subjected to laser annealing treatment to form a polycrystalline silicon film.
- using the excimer laser annealing device to perform laser annealing treatment on the amorphous silicon thin film to form a polysilicon thin film includes: controlling the first spectroscopic component and the second beam splitter in the excimer laser annealing device One of the two splitting components moves to the optical path of the first laser beam emitted by the laser output module, and controls the other of the first splitting component and the second splitting component to move to a position deviating from the laser output module. The position of the optical path of the first laser beam; laser annealing is performed on the amorphous silicon film to form the polysilicon film.
- performing laser annealing treatment on the amorphous silicon thin film includes: controlling the scanning frequency of laser pulses output by the laser in the excimer laser annealing device to be 300 Hz to 600 Hz, and performing laser annealing treatment on the amorphous silicon film.
- the film is subjected to laser annealing treatment; and/or, the overlap rate of the laser pulses output by the laser is controlled to be 92% to 98%, and the amorphous silicon film is subjected to laser annealing treatment; and/or, the output of the laser is controlled
- the scanning rate of the laser pulse is 4-16 mm/s, and the amorphous silicon film is laser-annealed; and/or, the laser energy density of the laser pulse output by the laser is controlled to be 300-500 mJ/cm 2 , And performing laser annealing treatment on the amorphous silicon thin film.
- the temperature for heating the amorphous silicon film is 400° C. to 500° C., and the heating time is 0.5 to 3 hours.
- forming an amorphous silicon film on a substrate includes: forming the amorphous silicon film on a substrate on which a buffer layer is formed.
- a method for manufacturing a thin film transistor including: forming a gate, a gate insulating layer, an active pattern, a source and a drain on a substrate; wherein, forming the active pattern includes: using the above-mentioned polysilicon film
- the preparation method forms a polysilicon film; and performs patterning processing on the polysilicon film to obtain the active pattern.
- a thin film transistor is provided, which is manufactured by the above-mentioned method for manufacturing a thin film transistor.
- FIG. 1 is a schematic structural diagram of an excimer laser annealing device provided by some embodiments of the disclosure
- FIG. 2 is a schematic structural diagram of another excimer laser annealing device provided by some embodiments of the disclosure.
- FIG. 3 is a schematic structural diagram of yet another excimer laser annealing device provided by some embodiments of the present disclosure.
- 4A is a diagram of a laser pulse waveform provided by some embodiments of the present disclosure.
- 4B is another laser pulse waveform diagram provided by some embodiments of the present disclosure.
- 4C is a topography diagram of a polysilicon provided by some embodiments of the present disclosure.
- FIG. 5 is a schematic structural diagram of yet another excimer laser annealing device provided by some embodiments of the present disclosure.
- FIG. 6 is a schematic structural diagram of yet another excimer laser annealing device provided by some embodiments of the disclosure.
- Fig. 7A is another laser pulse waveform diagram provided by some embodiments of the present disclosure.
- Fig. 7B is another laser pulse waveform diagram provided by some embodiments of the present disclosure.
- FIG. 7C is a topography diagram of another polysilicon provided by some embodiments of the present disclosure.
- FIG. 8 is a schematic diagram of the connection relationship between a pulse extension module and a controller provided by some embodiments of the present disclosure.
- FIG. 9 is a schematic structural diagram of a pulse extension module provided by some embodiments of the disclosure.
- FIG. 10 is a schematic structural diagram of another pulse extension module provided by some embodiments of the present disclosure.
- FIG. 11 is a schematic structural diagram of yet another pulse extension module provided by some embodiments of the present disclosure.
- FIG. 12A is a schematic diagram of a working state of a pulse extension module provided by some embodiments of the present disclosure.
- FIG. 12B is a schematic diagram of the working state of another pulse extension module provided by some embodiments of the present disclosure.
- FIG. 13 is a flowchart of a method for preparing a polysilicon film according to some embodiments of the disclosure.
- FIG. 14 is a flowchart of another method for preparing a polysilicon film according to some embodiments of the disclosure.
- FIG. 15 is a schematic diagram of a preparation process of a polysilicon film provided by some embodiments of the present disclosure.
- FIG. 16 is a schematic diagram of a manufacturing process of a TFT provided by some embodiments of the disclosure.
- Some embodiments of the present disclosure provide an excimer laser annealing device, as shown in FIG. 1, including a laser output module 1, a pulse extension module 2, an optical module 4 and a process chamber 5.
- the laser output module 1 is used to emit the first laser beam.
- the pulse extension module 2 is used to extend the pulse time of the laser beam it emits.
- the optical module 4 is used to adjust the laser beam output from the pulse extension module 2 so that the laser beam irradiated on the sample to be annealed in the process chamber 5 meets the laser annealing conditions of the sample to be annealed.
- the optical module 4 includes a first sub-optical module 401, a second sub-optical module 402 and a third sub-optical module 403.
- the laser beam output from the pulse extension module 2 sequentially passes through the first sub-optical module 401, the second sub-optical module 402, and the third sub-optical module 403, so that the laser beam changes from a spot with uneven energy distribution to a linear laser with uniform energy distribution bundle.
- the linear laser beam is incident on the process chamber 5 to anneal the sample to be annealed.
- the pulse extension module 2 includes a first light splitting component 22 and a transmission component 27.
- the first beam splitter 22 is used to receive the first laser beam when moving to the optical path of the first laser beam, and divide the received first laser beam into the first outgoing light 221 and the first reflected light 222.
- the first reflected light The laser energy of 222 accounts for 20%-40% of the laser energy of the first laser beam received by the first spectroscopic component 22, such as 20%, 30% or 40%; the first outgoing light 221 is directly emitted and the first reflected
- the light 222 is directed to the transmission component 27, and the first reflected light 222 transmitted by the transmission component 27 is emitted.
- the first beam splitter 22 is a beam splitter.
- the transmission component 27 is used to receive the first reflected light 222 and cause the first reflected light 222 to be transmitted to the first light splitting component 22 after being transmitted in the transmission component 27.
- the first laser beam is divided into the first outgoing light 221 and the first reflected light 222 by the first beam splitting part 22, the first outgoing light 221 is directly emitted, and the first reflected light 222 is directed to the transmission component 27, and then passes through the transmission component. After the transmission of 27, it exits through the first light splitting component 22.
- the first outgoing light 221 that is emitted first and the first reflected light 222 that is emitted later are combined into the same optical path, so that the pulse time of the laser beam emitted from the pulse extension module 2 is extended from the time when the first outgoing light 221 is emitted to the first The time for a reflected light 222 to emit, thereby extending the laser pulse time emitted from the pulse extension module 2.
- the pulse time of the first laser beam emitted from the laser output module 1 is 20-30 ns, and the second energy peak in the laser pulse waveform is lower than the first energy peak.
- the pulse time of the laser beam emitted from the pulse extension module 2 is 60-90 ns, and the second energy peak in the laser pulse waveform is lower than the first energy peak.
- the energy distribution in the laser pulse waveform can be approximately understood as the distribution of laser pulse energy within the pulse time.
- the first emitted light 221 corresponds to the first energy peak
- the first reflected light 222 corresponds to the second energy peak. That is, when the first emitted light 221 and the first reflected light 222 are emitted, the laser pulse There is a peak in energy.
- the first beam splitter 22 in the pulse extension module 2 divides the received first laser beam into a first emitted light 221 and a first reflected light 222, and The laser energy of the first reflected light 222 accounts for 20%-40% of the laser energy of the first laser beam received by the first spectroscopic component 22, the first outgoing light 221 is directly emitted, and the first reflected light 222 is transmitted through the transmission component 27 Then it exits through the first light splitting component 22.
- the second energy peak value in the waveform of the laser pulse transmitted from the pulse extension module 2 to the surface of the sample to be annealed in the process chamber 5 is lower than the first energy peak value.
- the tetragonal polycrystalline silicon shown in FIG. 4C can be obtained.
- the average size of the tetragonal polycrystalline silicon is 328 nm, and the 3 times the standard deviation is 147 nm, which improves the polycrystalline silicon.
- the uniformity of the product thereby improving the product yield.
- the process window of the excimer laser annealing process is 445 mJ/cm 2 to 455 mJ/cm 2 , so the available range of process parameters is wide, and the influence of the fluctuation of process parameters on polysilicon is relatively stable.
- SRU Short Range Uniformity
- TFT Thin Film Transistor
- the tetragonal polysilicon is suitable for any LTPS (Low Temperature Poly-silicon)-AMOLED (Active-matrix organic light-emitting diode) display device, for example, the resolution is greater than 400PPI (Pixels Per Inch, pixel density) LTPS-AMOLED display device.
- LTPS Low Temperature Poly-silicon
- AMOLED Active-matrix organic light-emitting diode
- the pulse extension module 2 further includes a second light splitting component 23.
- the second beam splitter 23 is used to receive the first laser beam when moving to the optical path of the first laser beam, and divide the received first laser beam into the second outgoing light 231 and the first laser beam.
- the second reflected light 232, the laser energy of the second reflected light 232 accounts for 40%-60% of the laser energy of the first laser beam received by the second beam splitter 23, such as 40%, 50%, or 60%; 231 emits, emits the second reflected light 232 toward the transmission component 27, and emits the second reflected light 232 transmitted by the transmission component 27.
- the second beam splitter 23 is a beam splitter.
- the transmission component 27 is also used to receive the second reflected light 232 and cause the second reflected light 232 to be transmitted to the second light splitting component 23 after being transmitted in the transmission component 27.
- the first laser beam is divided into the second emitted light 231 and the second reflected light 232 by the second beam splitting component 23.
- the second emitted light 231 is directly emitted, and the second reflected light 232 is emitted to the transmission component 27, and then passes through the transmission component. After the transmission of 27, it exits through the second light splitting component 23.
- the second emitted light 231 emitted first and the second reflected light 232 emitted later are combined into the same optical path, so that the pulse time of the laser beam emitted from the pulse extension module 2 is extended from the time when the second emitted light 231 is emitted to the first
- the emission time of the second reflected light 232 thereby prolongs the laser pulse time emitted from the pulse extension module 2.
- the pulse time of the first laser beam emitted from the laser output module 1 is about 24 ns, and the second energy peak in the laser pulse waveform is lower than the first energy peak, as shown in FIG. 7B
- the pulse time of the laser beam emitted from the pulse extension module 2 is about 84 ns, and the second energy peak in the laser pulse waveform is higher than the first energy peak.
- the second beam splitter 23 in the pulse extension module 2 divides the received first laser beam into a second exit light 231 and a second reflected light 232, and The laser energy of the second reflected light 232 accounts for 40% to 60% of the laser energy of the first laser beam received by the second beam splitter 23.
- the second outgoing light 231 is directly emitted, and the second reflected light 232 is transmitted through the transmission assembly 27 Then it exits through the second light splitting component 23.
- the second energy peak value in the waveform of the laser pulse transmitted from the pulse extension module 2 to the surface of the sample to be annealed in the process chamber 5 is higher than the first energy peak value.
- the original tetragonal crystal system can be changed to obtain the hexagonal polycrystalline silicon or polygonal polycrystalline silicon shown in FIG. 7C.
- the average of the hexagonal polycrystalline silicon or polygonal polycrystalline silicon The size is 376nm and the 3 times standard deviation is 376nm.
- the process window of the excimer laser annealing process is 440 mJ/cm 2 to 445 mJ/cm 2 .
- the polygonal polysilicon or hexagonal polysilicon is suitable for LTPS-LCD (Liquid Crystal Display, liquid crystal display) or LTPS-AMOLED display devices with a resolution of less than 200 PPI.
- LTPS-LCD Liquid Crystal Display, liquid crystal display
- LTPS-AMOLED display devices with a resolution of less than 200 PPI.
- the first spectroscopic component 22 can be moved to the optical path AA' of the first laser beam to obtain tetragonal polycrystalline silicon according to production needs, or the second spectroscopic component 23 can be moved to the first The laser beam is on the optical path AA' to obtain hexagonal polysilicon or polygonal polysilicon.
- the pulse extension module 2 further includes a driving part 24, which is connected to the first light splitting part 22 and the second light splitting part 23 and is configured to drive the first light splitting part 22 And the movement of the second spectroscopic component 23.
- the driving part 24 includes a motor connected to both the first light splitting part 22 and the second light splitting part 23 for driving the first light splitting part 22 and the second light splitting part 23 to move.
- the driving part 24 includes two motors, the two motors are respectively connected to the first splitting part 22 and the second splitting part 23, one motor is used to drive the first splitting part 22 to move, the other motor is used To drive the second beam splitter 23 to move.
- the first beam splitting component 22 includes a first bracket 223 and a first beam splitter 224 fixed in the first bracket 223, and the second beam splitting component 23 includes a second bracket 233 and fixed on the second bracket. 233 within the second beam splitter 234.
- the driving part 24 includes a motor which is connected to the first bracket 223 and the second bracket 233, respectively, so as to drive the movement of the first beam splitter 224 and the second beam splitter 234.
- the positions of the first spectroscopic component 22 and the second spectroscopic component 23 are not limited.
- the first beam splitting member 22 and the second beam splitting member 23 are both located at positions deviated from the optical path AA' of the first laser beam.
- the first beam splitting member 22 is located on the optical path AA' of the first laser beam
- the second beam splitting member 23 is located at a position deviated from the optical path AA' of the first laser beam.
- the second beam splitting member 23 is located on the optical path AA' of the first laser beam
- the first beam splitting member 22 is located at a position deviated from the optical path AA' of the first laser beam.
- the first laser beam emitted by the laser output module 1 reaches the first beam splitter 22 or the second beam splitter 23 in the pulse extension module 2.
- the optical path AA' of the first laser beam is the optical path of the laser beam emitted by the laser 11.
- the position deviated from the optical path AA' of the first laser beam may be any side deviated from the optical path AA' of the first laser beam.
- the first beam splitting component 22 and the second beam splitting component 23 can arrange at appropriate positions in the pulse extension module 2 deviating from the optical path AA' of the first laser beam according to actual conditions.
- the first beam splitting part 22 and the second beam splitting part 23 may be arranged at Deviating from the same side of the optical path AA' of the first laser beam
- the first beam splitting part 22 and the second beam splitting part 23 can also be arranged on opposite sides of the optical path AA' of the first laser beam, and placed in the excimer laser annealing device
- one of the first beam splitter 22 and the second beam splitter 23 is moved to the optical path AA′ of the first laser beam, and the other remains at the original position.
- the position of the first beam splitting component 22 should also be based on the fact that when the second beam splitting component 23 is located on the optical path AA' of the first laser beam, the light transmission between the second beam splitting component 23 and the transmission assembly 27 will not be affected.
- the position of the second light splitting component 23 should be based on the fact that when the first light splitting component 22 is located on the optical path AA' of the first laser beam, the light transmission between the first light splitting component 22 and the transmission assembly 27 will not be affected.
- the driving part 24 can move the first beam splitting part 22 to the optical path AA' of the first laser beam, and move the second beam splitting part 23 Move to a position deviated from the optical path AA' of the first laser beam, so that the first laser beam passes through the first beam splitter 22 to be divided into the first outgoing light 221 and the first reflected light 222, the first outgoing light 221 is directly emitted, and the first reflected light
- the light 222 is emitted after being transmitted in the transmission component 27.
- the driving part 24 can move the second beam splitting part 23 to the optical path AA' of the first laser beam, and move the first beam splitting part 22 Move to a position deviated from the optical path AA' of the first laser beam, so that the first laser beam passes through the second beam splitter 23 to be divided into the second outgoing light 231 and the second reflected light 232, the second outgoing light 231 is directly emitted, and the second reflected light
- the light 232 exits after being transmitted in the transmission assembly 27.
- the excimer laser annealing device further includes a controller 3 connected to the driving part 24, and the controller 3 is used to control the driving part 24 to drive the first spectroscopic part
- One of the 22 and the second beam splitter 23 moves to the optical path AA′ of the first laser beam, and the other moves to a position deviated from the optical path AA′ of the first laser beam.
- the controller 3 controls the driving part 24 to drive the first beam splitting part 22 to move to the optical path AA' of the first laser beam, so that the first beam splitting part 22 receives the first laser beam and drives the second laser beam.
- the spectroscopic member 23 moves to a position deviated from the optical path AA′ of the first laser beam.
- the controller 3 controls the driving part 24 to drive the second beam splitting part 23 to move to the optical path AA' of the first laser beam in response to the second control signal, so that the second beam splitting part 23 receives the first laser beam and drives the first laser beam.
- a beam splitter 22 moves to a position deviated from the optical path AA′ of the first laser beam.
- the excimer laser annealing device further includes a touch screen and a processor, and both the touch screen and the controller 3 are connected to the processor.
- the operator can input a control instruction on the interface of the touch screen, and the processor generates a first control signal or a second control signal according to the control instruction and sends it to the controller 3 so that the controller 3 responds to the first control signal
- a control signal or a second control signal controls the driving part 24 to drive the movement of the first light splitting part 22 and the second light splitting part 23.
- the excimer laser annealing device further includes a touch screen, and the controller 3 is connected to the touch screen, and the controller 3 also has a processing function.
- the operator can input a control instruction on the touch screen interface, and the controller 3 converts the control instruction into a first control signal or a second control signal, and responds to the first control signal or the second control signal
- the control driving part 24 drives the movement of the first spectroscopic part 22 and the second spectroscopic part 23.
- the first beam splitting component 22 and the second beam splitting component 23 are both beam splitters, the beam splitting coefficient of the first beam splitting component 22 is 30%, and the beam splitting coefficient of the second beam splitting component 23 is 50%. That is, the first spectroscopic member 22 is a spectroscope with a spectral coefficient of 30%, and the second spectroscopic member 23 is a spectroscope with a spectral coefficient of 50%.
- the spectroscopic coefficient of the first spectroscopic component 22 is 30%, that is, among the first emitted light 221 and the first reflected light 222 split by the first spectroscopic component 22, the laser energy of the first emitted light 221 accounts for the amount of laser energy received by the first spectroscopic component 22
- the laser energy of the first laser beam received is 70%
- the laser energy of the first reflected light 222 accounts for 30% of the laser energy of the first laser beam received by the first spectroscopic component 22. Therefore, as shown in FIG. 12A, the first outgoing light 221 that accounts for 70% of the laser energy in the first laser beam received by the first beam splitting part 22 is directly emitted, and the first laser beam received by the first beam splitting part 22 accounts for another part.
- the first reflected light 222 of 30% laser energy is transmitted by the transmission component 27 and then emitted through the first light splitting component 22, and the first reflected light 222 and the first emitted light 221 are combined into the same optical path.
- the spectroscopic coefficient of the second spectroscopic component 23 is 50%, that is, of the second emitted light 231 and the second reflected light 232 split by the second spectroscopic component 23, the laser energy of the second emitted light 231 accounts for the amount of laser energy received by the second spectroscopic component 23.
- the laser energy of the first laser beam received is 50%
- the laser energy of the second reflected light 232 accounts for 50% of the laser energy of the first laser beam received by the second beam splitter 23. Therefore, as shown in FIG. 12B, the second outgoing light 231 that accounts for 50% of the laser energy in the first laser beam received by the second beam splitting part 23 is directly emitted, and the first laser beam received by the second beam splitting part 23 accounts for another part.
- the second reflected light 232 of 50% laser energy is transmitted by the transmission component 27 and then emitted through the second beam splitting component 23, and the second reflected light 232 and the second emitted light 231 are combined into the same optical path.
- the laser output module 1 includes a laser 11.
- the laser 11 is used to emit a first laser beam.
- the laser 11 is an excimer laser, such as a xenon chloride (XeCl) excimer laser, and the wavelength of the first laser beam emitted by it is 308 nm.
- XeCl xenon chloride
- the laser output module 1 includes a laser 11 and a dimming component 12.
- the laser 11 is used to emit a second laser beam.
- the laser 11 is an excimer laser, such as a xenon chloride (XeCl) excimer laser.
- the dimming component 12 is arranged between the laser 11 and the pulse extension module 2 and is located on the optical path of the second laser beam. The dimming component 12 is used to receive the second laser beam, adjust the laser energy of the second laser beam to obtain the first laser beam, and emit the first laser beam.
- the laser energy of the first laser beam is less than the laser energy of the second laser beam, that is, the dimming component 12 is used to weaken the laser energy of the laser beam.
- the dimming component 12 is a beam splitter with a 2% splitting coefficient, so the laser energy of the first laser beam emitted from the dimming component 12 accounts for 98% of the laser energy of the second laser beam emitted by the laser 11.
- the first laser beam received by the first beam splitting component 22 can be a laser beam directly emitted from the laser 11, or a laser beam emitted by the laser 11 after being adjusted by the dimming component 12.
- the laser beam depends on the actual structure of the laser output module 1.
- the transmission assembly 27 includes a first reflective part 271, a second reflective part 272, a third reflective part 273, and a fourth reflective part 274; the first reflective part 271 and the second reflective part
- the three reflective parts 273 are located on one side of the optical path AA' of the first laser beam
- the second reflective part 272 and the fourth reflective part 274 are located on the other side of the optical path AA' of the first laser beam
- the four reflecting parts 274 are arranged in a direction perpendicular to the optical path AA′ of the first laser beam
- the second reflecting part 272 and the third reflecting part 273 are arranged in a direction perpendicular to the optical path AA′ of the first laser beam.
- the first reflecting component 271 is used to receive the first reflected light 222 split from the first beam splitting component 22, and The first reflected light 222 is directed to the second reflective member 272; the second reflective member 272 is used to direct the first reflected light 222 reflected by the first reflective member 271 to the third reflective member 273; the third reflective member 273 is used to The first reflected light 222 reflected by the second reflective member 272 is directed toward the fourth reflective member 274; the fourth reflective member 274 is used to direct the first reflected light 222 reflected by the third reflective member 273 toward the first spectroscopic member 22 .
- the first reflected light 222 separated from the first spectroscopic component 22 is reflected by the first reflecting component 271, the second reflecting component 272, the third reflecting component 273, and the fourth reflecting component 274 in this order, it is directed to the first spectroscopic component 22 , And exit along the exit direction of the first exit light 221, which automatically superimposes and merges with the first exit light 221 into the same optical path, thus prolonging the pulse time of the laser beam exiting from the pulse extension module 2.
- the first reflecting part 271 is used to receive the second reflected light 232 split from the second beam splitting part 23, and The second reflected light 232 is directed to the second reflective member 272; the second reflective member 272 is used to direct the second reflected light 232 reflected by the first reflective member 271 to the third reflective member 273; the third reflective member 273 is used to The second reflected light 232 reflected by the second reflective member 272 is directed to the fourth reflective member 274; the fourth reflective member 274 is used to direct the second reflected light 232 reflected by the third reflective member 273 to the second spectroscopic member 23 .
- the second reflected light 232 split from the second spectroscopic component 23 is reflected by the first reflecting component 271, the second reflecting component 272, the third reflecting component 273, and the fourth reflecting component 274 in turn, it is directed toward the second spectroscopic component 23. , And exit along the exit direction of the second exit light 231, which automatically superimposes and merges with the second exit light 231 into the same optical path, thus prolonging the pulse time of the laser beam exiting the pulse extension module 2.
- the distance of the first reflected light 222 or the second reflected light 232 along the optical path of the transmission component 27 is 9-11 m.
- Some embodiments of the present disclosure also provide a method for preparing a polysilicon film, as shown in FIG. 13, including S1 to S2.
- An amorphous silicon film 32 is formed on the substrate 30, and the amorphous silicon film 32 is heated.
- the preparation method includes S10 to S60.
- the substrate 30 is pre-cleaned.
- the substrate 30 may be a glass substrate or a flexible substrate, such as a PI (Polyimide) substrate.
- PI Polyimide
- an inorganic material is deposited on the substrate 30 to form a buffer layer 31.
- the buffer layer 31 may have a double-layer structure or a single-layer structure.
- the material of the buffer layer 31 may be an inorganic material including silicon nitride (SiN X ) and silicon dioxide (SiO 2 ).
- silicon nitride with a thickness of, for example, 50 to 150 nm may be deposited on the substrate 30 first, and after the silicon nitride layer is obtained, the silicon nitride layer may be deposited, for example, with a thickness of 100 nm. ⁇ 350nm silicon dioxide to obtain a silicon dioxide layer.
- an amorphous silicon material is deposited on the side of the buffer layer 31 away from the substrate 30 to form an amorphous silicon film 32, and the amorphous silicon film 32 is heated.
- a PECVD (Plasma Enhanced Chemical Vapor Deposition) method is used to form the amorphous silicon film 32, and the thickness of the amorphous silicon film 32 is 30-60 nm.
- the temperature at which the amorphous silicon film 32 is heated is 400°C to 500°C, such as 400°C, 450°C, or 500°C, and the time is 0.5 to 3 hours, such as 0.5 hour, 1 hour, 2 hours, or 3 hours. hour.
- the substrate 30 on which the amorphous silicon film 32 is formed is placed in the process chamber 5 of the excimer laser annealing device.
- the substrate 30 on which the amorphous silicon film 32 is formed is placed in the process chamber 5, and its position is such that the laser light incident on the process chamber 5 irradiates the surface of the amorphous silicon film 32.
- one of the first beam splitter 22 and the second beam splitter 23 is controlled to be placed on the optical path AA' of the first laser beam, and the other moves to Deviate from the position of the optical path AA' of the first laser beam.
- the first beam splitter 22 can be controlled to move to the optical path AA' of the first laser beam.
- the second beam splitter 23 can be controlled to move to the optical path AA' of the first laser beam.
- the scanning frequency of the laser pulse output by the laser 11 is 300 Hz to 600 Hz, for example, 300 Hz, 400 Hz, 500 Hz, or 600 Hz.
- the overlap rate of the laser pulses output by the laser 11 is 92%-98%, for example, 92%, 95%, or 98%.
- the scan rate of the laser pulse output by the laser 11 is 4-16 mm/s, for example, 4 mm/s, 10 mm/s or 16 mm/s.
- the laser energy density of the laser pulse output by the laser 11 is 300-500 mJ/cm 2 , for example, 300 mJ/cm 2 , 400 mJ/cm 2 or 500 mJ/cm 2 .
- the first beam splitting component 22 When the first beam splitting component 22 is placed on the optical path AA' of the first laser beam, the first beam splitting component 22 divides the received first laser beam into the first outgoing light 221 and the first reflected light 222, and the An outgoing light 221 is directly emitted, the first reflected light 222 is directed to the transmission component 27, and the first reflected light 222 transmitted by the transmission component 27 is emitted. Since the laser energy of the first reflected light 222 accounts for 20%-40% of the laser energy of the first laser beam received by the first beam splitter 22, as shown in FIG.
- the laser beam irradiating the surface of the amorphous silicon film 32
- the first energy peak of is greater than the second energy peak, so the amorphous silicon film 32 can form a tetragonal polycrystalline silicon film 33 as shown in FIG. 4C after annealing.
- the second beam splitter 23 When the second beam splitter 23 is placed on the optical path AA' of the first laser beam, the second beam splitter 23 divides the received first laser beam into second outgoing light 231 and second reflected light 232, The second outgoing light 231 is directly emitted, the second reflected light 232 is directed to the transmission assembly 27, and the second reflected light 232 transmitted by the transmission assembly 27 is emitted. Since the laser energy of the second reflected light 232 accounts for 40% to 60% of the laser energy of the first laser beam received by the second beam splitter 23, as shown in FIG.
- the laser beam irradiated to the surface of the amorphous silicon film 32 The first energy peak of is smaller than the second energy peak, so the amorphous silicon film 32 can form a hexagonal or polygonal polysilicon film 33 after annealing as shown in FIG. 7C.
- Some embodiments of the present disclosure also provide a thin film transistor (Thin Film Transistor, TFT) manufacturing method, including: forming a gate 36, a gate insulating layer 35, an active pattern 34, a source 38, and a drain on the substrate 30. ⁇ 39.
- the formation process of the active pattern 34 includes: forming the polysilicon film 33 by the above-mentioned preparation method of the polysilicon film, and performing a patterning process on the polysilicon film 33 to obtain the desired active pattern 34.
- the patterning process may include processes such as exposure, development, and etching.
- the formation process is as follows: based on the formation of the polysilicon film 33, the polysilicon film 33 is patterned to form the semiconductor pattern 34 of the TFT; A gate insulating layer 35, a gate 36 and an interlayer insulating layer 37 are sequentially formed on the 34.
- the orthographic projection of the gate 36 on the substrate 30 is within the range of the orthographic projection of the semiconductor pattern 34 on the substrate 30, and the gate 36
- the area is smaller than the area of the semiconductor pattern 34, the gate insulating layer 35 and the interlayer insulating layer 37 are formed with a first via hole and a second via hole; the source electrode 38 and the drain electrode 39 are simultaneously formed on the interlayer insulating layer 37, the source The electrode 38 and the drain electrode 39 contact the semiconductor pattern 34 through the first via hole and the second via hole penetrating the interlayer insulating layer 37 and the gate insulating layer 35, respectively, thereby forming a TFT.
- Some embodiments of the present disclosure also provide a thin film transistor, and the TFT is manufactured by the above-mentioned manufacturing method.
- the TFT is suitable for, for example, any LTPS-AMOLED.
- the TFT is suitable for, for example, LTPS-LCD and LTPS-AMOLED with a resolution of less than 200 PPI.
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Abstract
Description
Claims (16)
- 一种准分子激光退火装置,包括:激光输出模块,被配置为出射第一激光束;脉冲延长模块,包括第一分光部件和传输组件;其中,所述第一分光部件被配置为在移动至所述第一激光束的光路上时接收所述第一激光束,将接收到的所述第一激光束分为第一反射光和第一出射光,所述第一反射光的激光能量占所述第一激光束的激光能量的20%~40%;将所述第一出射光直接出射,将所述第一反射光射向所述传输组件,并将经所述传输组件传输后的所述第一反射光出射;所述传输组件被配置为接收所述第一反射光,并使所述第一反射光在所述传输组件中传输后射向所述第一分光部件。
- 根据权利要求1所述的准分子激光退火装置,其中,所述脉冲延长模块还包括第二分光部件和驱动部件;所述第二分光部件被配置为在移动至所述第一激光束的光路上时接收所述第一激光束,将接收到的所述第一激光束分为第二出射光和第二反射光,所述第二反射光的激光能量占所述第一激光束的激光能量的40%~60%;将所述第二出射光直接出射,将所述第二反射光射向所述传输组件,并将经所述传输组件传输后的所述第二反射光出射;所述传输组件还被配置为接收所述第二反射光,并使所述第二反射光在所述传输组件中传输后射向所述第二分光部件;所述驱动部件与所述第一分光部件和所述第二分光部件相连接,被配置为驱动所述第一分光部件和所述第二分光部件移动;其中,所述准分子激光退火装置还包括控制器,所述控制器与所述驱动部件相连接;所述控制器被配置为响应于第一控制信号控制所述驱动部件驱动所述第一分光部件移动至所述第一激光束的光路上,以使所述第一分光部件接收所述第一激光束,并驱动所述第二分光部件移动至偏离所述第一激光束的光路的位置;以及响应于第二控制信号控制所述驱动部件驱动所述第二分光部件移动至所述第一激光束的光路上,以使所述第二分光部件接收所述第一激光束,并驱动所述第一分光部件移动至偏离所述第一激光束的光路的位置。
- 根据权利要求2所述的准分子激光退火装置,其中,所述第一分光部件的分光系数为30%,所述第二分光部件的分光系数为50%。
- 根据权利要求2所述的准分子激光退火装置,其中,所述激光输 出模块包括激光器,所述激光器被配置为发射所述第一激光束。
- 根据权利要求2所述的准分子激光退火装置,其中,所述激光输出模块包括激光器和调光部件;所述激光器被配置为发射第二激光束;所述调光部件设置于所述激光器与所述脉冲延长模块之间且位于所述第二激光束的光路上;所述调光部件被配置为接收所述第二激光束,对所述第二激光束的激光能量进行调节以得到所述第一激光束,并出射所述第一激光束;所述第一激光束的激光能量小于所述第二激光束的激光能量。
- 根据权利要求4或5所述的准分子激光退火装置,其中,所述激光器为准分子激光器。
- 根据权利要求1~6任一项所述的准分子激光退火装置,其中,所述传输组件包括第一反射部件、第二反射部件、第三反射部件、第四反射部件;所述第一反射部件和所述第三反射部件设置在所述第一激光束的光路的一侧,所述第二反射部件和所述第四反射部件设置在所述第一激光束的光路的另一侧,且所述第一反射部件和所述第四反射部件沿垂直所述第一激光束的光路的方向排布,所述第二反射部件和所述第三反射部件沿垂直所述第一激光束的光路的方向排布。
- 根据权利要求7所述的准分子激光退火装置,其中,所述第一分光部件位于所述第一激光束的光路上;所述第一反射部件配置为接收所述第一反射光,并将所述第一反射光射向所述第二反射部件;所述第二反射部件配置为将经过所述第一反射部件反射的所述第一反射光射向所述第三反射部件;所述第三反射部件配置为将经过所述第二反射部件反射的所述第一反射光射向所述第四反射部件;所述第四反射部件配置为将经过所述第三反射部件反射的所述第一反射光射向所述第一分光部件;或者,第二分光部件位于所述第一激光束的光路上;所述第一反射部件配置为接收第二反射光,并将所述第二反射光射向所述第二反射部件;所述第二反射部件配置为将经过所述第一反射部件反射的所述第二反射光射向所述第三反射部件;所述第三反射部件配置为将经过所述第二反射部件反射的所述第二反射光射向所述第四反射部件;所述第四反射部件配置为将经过所述第三反射部件反射的所述第二反射光射向所述第二分光部件。
- 根据权利要求2所述的准分子激光退火装置,其中,所述第一分光部件包括第一支架以及固定在所述第一支架内的第一分光镜,所述第二分光部件包括第二支架以及固定在所述第二支架内的第二分光镜;所述驱动部件包括一个电机,所述电机分别与所述第一支架和所述第二支架连接。
- 一种多晶硅薄膜的制备方法,包括:在衬底上形成非晶硅薄膜,并对所述非晶硅薄膜进行加热处理;采用权利要求1~9任一项所述的准分子激光退火装置,对所述非晶硅薄膜进行激光退火处理,以形成多晶硅薄膜。
- 根据权利要求10所述的多晶硅薄膜的制备方法,其中,采用所述准分子激光退火装置,对所述非晶硅薄膜进行激光退火处理,以形成多晶硅薄膜,包括:控制所述准分子激光退火装置中的第一分光部件和第二分光部件中的一个移动至激光输出模块出射的第一激光束的光路上,并控制所述第一分光部件和所述第二分光部件中的另一个移动至偏离所述激光输出模块出射的所述第一激光束的光路的位置;对所述非晶硅薄膜进行激光退火处理,以形成所述多晶硅薄膜。
- 根据权利要求10所述的多晶硅薄膜的制备方法,其中,对所述非晶硅薄膜进行激光退火处理,包括:控制所述准分子激光退火装置中的激光器输出的激光脉冲的扫描频率为300Hz~600Hz,并对所述非晶硅薄膜进行激光退火处理;和/或,控制所述激光器输出的激光脉冲的重叠率为92%~98%,并对所述非晶硅薄膜进行激光退火处理;和/或,控制所述激光器输出的激光脉冲的扫描速率为4~16mm/s,并对所述非晶硅薄膜进行激光退火处理;和/或,控制所述激光器输出的激光脉冲的激光能量密度为300~500mJ/cm 2,并对所述非晶硅薄膜进行激光退火处理。
- 根据权利要求10所述的多晶硅薄膜的制备方法,其中,对所述非晶硅薄膜进行加热处理的温度为400℃~500℃,加热时间为0.5~3小时。
- 根据权利要求10~13任一项所述的多晶硅薄膜的制备方法,在衬底上形成非晶硅薄膜,包括:在形成有缓冲层的衬底上形成所述非晶硅薄膜。
- 一种薄膜晶体管的制备方法,包括:在衬底上形成栅极、栅绝缘层、有源图案、源极和漏极;其中,形成有源图案包括:采用权利要求10~14任一项所述的制备方法形成多晶硅薄膜;对所述多晶硅薄膜进行图案化处理,以得到所述有源图案。
- 一种薄膜晶体管,采用权利要求15所述的制备方法制得。
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CN1691275A (zh) * | 2004-03-31 | 2005-11-02 | 株式会社液晶先端技术开发中心 | 结晶设备、结晶方法、器件、光学调制元件和显示装置 |
JP2006071855A (ja) * | 2004-09-01 | 2006-03-16 | Sumitomo Heavy Ind Ltd | 光学装置 |
JP2007335654A (ja) * | 2006-06-15 | 2007-12-27 | Advanced Lcd Technologies Development Center Co Ltd | 結晶化装置および結晶化方法 |
CN104766813A (zh) * | 2015-03-31 | 2015-07-08 | 京东方科技集团股份有限公司 | 准分子激光退火装置 |
CN105511030A (zh) * | 2016-01-15 | 2016-04-20 | 京东方科技集团股份有限公司 | 一种激光脉冲延时系统和激光退火系统 |
CN109676244A (zh) * | 2017-10-17 | 2019-04-26 | 三星显示有限公司 | 激光晶化装置 |
CN110265289A (zh) * | 2019-06-25 | 2019-09-20 | 京东方科技集团股份有限公司 | 准分子激光退火装置、多晶硅薄膜的制备方法 |
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CN1691275A (zh) * | 2004-03-31 | 2005-11-02 | 株式会社液晶先端技术开发中心 | 结晶设备、结晶方法、器件、光学调制元件和显示装置 |
JP2006071855A (ja) * | 2004-09-01 | 2006-03-16 | Sumitomo Heavy Ind Ltd | 光学装置 |
JP2007335654A (ja) * | 2006-06-15 | 2007-12-27 | Advanced Lcd Technologies Development Center Co Ltd | 結晶化装置および結晶化方法 |
CN104766813A (zh) * | 2015-03-31 | 2015-07-08 | 京东方科技集团股份有限公司 | 准分子激光退火装置 |
CN105511030A (zh) * | 2016-01-15 | 2016-04-20 | 京东方科技集团股份有限公司 | 一种激光脉冲延时系统和激光退火系统 |
CN109676244A (zh) * | 2017-10-17 | 2019-04-26 | 三星显示有限公司 | 激光晶化装置 |
CN110265289A (zh) * | 2019-06-25 | 2019-09-20 | 京东方科技集团股份有限公司 | 准分子激光退火装置、多晶硅薄膜的制备方法 |
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