WO2020195367A1 - 表示体 - Google Patents

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Publication number
WO2020195367A1
WO2020195367A1 PCT/JP2020/006493 JP2020006493W WO2020195367A1 WO 2020195367 A1 WO2020195367 A1 WO 2020195367A1 JP 2020006493 W JP2020006493 W JP 2020006493W WO 2020195367 A1 WO2020195367 A1 WO 2020195367A1
Authority
WO
WIPO (PCT)
Prior art keywords
display body
multilayer film
light
blank medium
diffraction grating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2020/006493
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
正志 久保田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP2021508269A priority Critical patent/JPWO2020195367A1/ja
Priority to CN202080025680.6A priority patent/CN113646671B/zh
Priority to EP20777415.9A priority patent/EP3951448B1/en
Publication of WO2020195367A1 publication Critical patent/WO2020195367A1/ja
Priority to US17/484,232 priority patent/US12158598B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30—Identification or security features, e.g. for preventing forgery
    • B42D25/328—Diffraction gratings; Holograms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/023—Optical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/405—Marking
    • B42D25/43—Marking by removal of material
    • B42D25/435—Marking by removal of material using electromagnetic radiation, e.g. laser
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/45—Associating two or more layers
    • B42D25/455—Associating two or more layers using heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/45—Associating two or more layers
    • B42D25/46—Associating two or more layers using pressure
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/18—Diffraction gratings
    • G02B5/1814—Diffraction gratings structurally combined with one or more further optical elements, e.g. lenses, mirrors, prisms or other diffraction gratings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/18—Diffraction gratings
    • G02B5/1861—Reflection gratings characterised by their structure, e.g. step profile, contours of substrate or grooves, pitch variations, materials
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/28—Interference filters
    • G02B5/285—Interference filters comprising deposited thin solid films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/416—Reflective
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/418—Refractive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays

Definitions

  • the present invention relates to a display body.
  • holograms that are difficult to forge or duplicate have been used for the purpose of proving that the article is genuine. For example, if a transparent film containing a hologram is attached to a card on which personal information such as a face image is recorded, the personal information can be protected from falsification. In addition, the use of holograms in banknotes and securities can prevent unauthorized duplication of them. Further, in recent years, it has been proposed to record a face image on an ID (identification) card or the like by using a hologram (Patent Documents 1 and 2).
  • holograms are difficult to forge or duplicate themselves, so they are used for various articles for which unauthorized duplication is desired to be suppressed.
  • an object of the present invention is to provide a technique capable of manufacturing a display body for displaying a structural color image in a short time.
  • a multilayer film including a laminate composed of two or more dielectric layers having different refractive indexes and having one or more recesses on one main surface, and the other of the laminates.
  • the visible region means a wavelength region of 350 to 750 nm.
  • an article with a display body including the display body according to the first aspect surface and the article supporting the display body is provided.
  • the third aspect of the present invention is a blank medium on which an image is recorded by laser beam irradiation, and is composed of two or more dielectric layers having different refractive indexes, and one or more recesses are mainly one of them by the laser beam irradiation.
  • the laminated body formed on the surface and the other main surface of the laminated body face each other, and the light in the visible region emitted from the other main surface is emitted from the other main surface at an incident angle different from the emission angle.
  • a blank medium is provided with one or more reflective surfaces incident on the surface.
  • an article with a blank medium including the blank medium according to the third aspect and the article supporting the blank medium is provided.
  • a method for manufacturing a display body including forming the one or more recesses by irradiating the blank medium according to the third aspect with the laser beam.
  • a method for manufacturing an article with a display body which includes manufacturing the display body by the method according to the fifth aspect and supporting the display body on the article.
  • a method for manufacturing an article with a display body which comprises forming one or more recesses by irradiating the blank medium with the blank medium according to the fourth aspect with the laser beam. Will be done.
  • FIG. 5 is a cross-sectional view schematically showing a blank medium that can be used for manufacturing the display shown in FIG.
  • FIG. 2 is a cross-sectional view illustrating a method of manufacturing the display body shown in FIG. The cross-sectional view which shows typically the optical behavior which occurs when the display body which concerns on a comparative example is illuminated with white light.
  • FIG. 5 is a cross-sectional view schematically showing an optical behavior that occurs when the display body shown in FIG. 1 is illuminated with white light.
  • FIG. 5 is a cross-sectional view schematically showing a display body according to a second embodiment of the present invention.
  • FIG. 6 is a cross-sectional view schematically showing a blank medium that can be used for manufacturing the display body shown in FIG.
  • FIG. 5 is a cross-sectional view schematically showing an article with a display body according to an embodiment of the present invention.
  • FIG. 5 is a cross-sectional view schematically showing an article with a blank medium according to an embodiment of the present invention.
  • the graph which shows an example of the transmission spectrum obtained by the computer simulation about the part corresponding to the recess of a multilayer film.
  • FIG. 1 is a cross-sectional view schematically showing a display body according to the first embodiment of the present invention.
  • the display body 1A includes a multilayer film 13, front layers 11R, 11G and 11B, reflective layers 12R, 12G and 12B, and back layers 14R, 14G and 14B.
  • the surface of the display body 1A on the multilayer film 13 side is the front surface, and the back surface thereof is the back surface.
  • the surface closer to the front surface of the display body 1A is referred to as a front surface
  • the surface closer to the back surface of the display body 1A is referred to as a back surface.
  • the multilayer film 13 is a dielectric multilayer film including a laminate composed of two or more dielectric layers having different refractive indexes.
  • the multilayer film 13 is composed of a laminated body in which dielectric layers 13a and 13b having different refractive indexes are alternately laminated.
  • the multilayer film 13 can further include a protective layer that covers the front surface of the laminate. This protective layer may have a single layer structure or a multi-layer structure.
  • each layer constituting the multilayer film 13 is, for example, in the range of 5 nm to 500 ⁇ m.
  • each layer constituting the multilayer film 13 for example, a transparent dielectric such as zinc sulfide and titanium dioxide can be used.
  • the multilayer film 13 is composed of two types of dielectric layers 13a and 13b having different refractive indexes (materials), but the multilayer film 13 has three or more types of dielectric layers having different refractive indexes (materials). It may be composed of.
  • the front surface of the laminated body is provided with a first recess RR, a second recess RG, and a third recess RB as one or more recesses.
  • the first recess RR, the second recess RG, and the third recess RB are provided here on the dielectric layer 13a located on the outermost surface of the laminate.
  • the third recess RB can be omitted. Further, the second recess RG can also be further omitted.
  • the depths of the first recess RR, the second recess RG, and the third recess RB are different from each other.
  • the depth is shallower in the order of the first recess RR, the second recess RG, and the third recess RB, but any of them may be the shallowest, and any of them may be the deepest.
  • the dielectric layer 13a on the foremost front side is drawn thicker than the other dielectric layers 13a and 13b in order to make it easier to understand the difference in the depths of the recesses.
  • the dielectric layer 13a on the frontmost side may have the same thickness as any of the other dielectric layers 13a and 13b, or may be thinner than any of them.
  • the multilayer film 13 When white light is incident at the first incident angle, the multilayer film 13 exhibits high transmittance over the entire visible region at a position where these recesses are not provided, or in the visible region. It shows low transmittance throughout.
  • the multilayer film 13 when white light is incident at the first incident angle, the multilayer film 13 exhibits low transmittance over the entire visible region at a position where these recesses are not provided. .. Note that "white light” is light having substantially the same intensity over the entire visible region.
  • the first portion corresponding to the first concave portion RR, the second portion corresponding to the second concave portion RG, the third portion corresponding to the third concave portion RB, and the portion not provided with the concave portion Shows different transmission spectra when white light is incident at the first incident angle.
  • the first to third portions have different wavelengths that show the maximum or minimum transmittance in the visible region when white light is incident at the first incident angle.
  • the transmission spectrum when white light is incident on the multilayer film 13 at the first incident angle has a first wavelength in the first portion corresponding to the first concave portion RR as compared with a portion in which the concave portion is not provided.
  • the ratio of the transmittance in the region to the transmittance in other wavelength regions is larger, and the maximum transmittance is shown at the first wavelength in this first wavelength region.
  • the transmission spectrum when white light is incident on the multilayer film 13 at the first incident angle is, for example, in the second portion corresponding to the second concave portion RG, as compared with the portion in which the concave portion is not provided, for example.
  • the ratio of the transmittance in the second wavelength region to the transmittance in other wavelength regions is larger, and the maximum transmittance is shown in the second wavelength in this second wavelength region.
  • the transmission spectrum when white light is incident on the multilayer film 13 at the first incident angle is higher in the third portion corresponding to the third concave portion RB than in the portion where the concave portion is not provided.
  • the ratio of the transmittance in the third wavelength region to the transmittance in other wavelength regions is larger, and the maximum transmittance is shown at the third wavelength in this third wavelength region.
  • the transmission spectrum when white light is incident on the multilayer film 13 at the first incident angle has a first wavelength in the first portion corresponding to the first concave portion RR, as compared with a portion in which the concave portion is not provided.
  • the ratio of the transmittance in the region to the transmittance in other wavelength regions is smaller, and shows the minimum transmittance at the first wavelength in this first wavelength region.
  • the transmission spectrum when white light is incident on the multilayer film 13 at the first incident angle is, for example, in the second portion corresponding to the second concave portion RG, as compared with the portion in which the concave portion is not provided, for example.
  • the ratio of the transmittance in the second wavelength region to the transmittance in other wavelength regions is smaller, and shows the minimum transmittance in the second wavelength in this second wavelength region.
  • the transmission spectrum when white light is incident on the multilayer film 13 at the first incident angle is higher in the third portion corresponding to the third concave portion RB than in the portion where the concave portion is not provided.
  • the ratio of the transmittance in the third wavelength region to the transmittance in other wavelength regions is smaller, and the minimum transmittance is shown at the third wavelength in this third wavelength region.
  • the multilayer film 13 adopts the former configuration.
  • the first to third wavelength regions are different wavelength regions within the visible region.
  • the longest wavelength in the second wavelength region is shorter than the shortest wavelength in the first wavelength region
  • the longest wavelength in the third wavelength region is shorter than the shortest wavelength in the second wavelength region.
  • the first, second, and third wavelength regions are red, green, and blue wavelength regions, respectively.
  • the front layer 11R, the reflection layer 12R, and the back layer 14R are laminated in this order on the back surface of the multilayer film 13.
  • the front layer 11G, the reflection layer 12G, and the back layer 14G are laminated on the back layer 14R in this order.
  • the front surface layer 11B, the reflection layer 12B, and the back surface layer 14B are laminated on the back surface layer 14G in this order.
  • Each of the front layers 11R, 11G and 11B is made of, for example, a transparent resin.
  • This transparent resin may be a cured product of a thermosetting resin or a photocurable resin, may be a thermoplastic resin, or may be an adhesive or an adhesive.
  • Each of these layers may have a single layer structure or a multi-layer structure.
  • the back surfaces of the front layers 11R, 11G and 11B are provided with first, second and third relief structures, respectively.
  • the first, second and third relief structures are the first reflective surface which is the interface between the front layer 11R and the reflective layer 12R, the second reflective surface which is the interface between the front layer 11G and the reflective layer 12G, and the front surface, respectively.
  • the third reflective surface which is the interface between the layer 11B and the reflective layer 12B, causes white light to enter the multilayer film 13 at the first incident angle
  • the light emitted from the back surface of the multilayer film 13 is the light of this light. It is possible to make the light incident on the back surface of the multilayer film 13 at a second incident angle different from the ejection angle.
  • the first relief structure causes a first blazed diffraction grating on the first reflection surface
  • the second relief structure causes a second blazed diffraction grating on the second reflection surface
  • the third relief structure is a third relief structure.
  • a first blazed diffraction grating is formed on the three reflecting surfaces.
  • the arrangement directions of the grooves or ridges constituting them are parallel to each other.
  • the arrangement direction of these grooves or ridges is parallel to the Y direction.
  • the spatial frequencies of the grating lines are different from each other.
  • the first blazed diffraction grating has the lowest spatial frequency of the grid lines
  • the third blazed diffraction grating has the highest spatial frequency of the grid lines.
  • the magnitude relationship of the spatial frequency of the grating lines between the first to third blazed diffraction gratings may be different from this.
  • the first blazed diffraction grating is light (light of the first wavelength) transmitted through the first portion corresponding to the first concave portion RR of the multilayer film 13 when white light is incident on the multilayer film 13 at the first incident angle.
  • the blaze angle and the grating constant (line spacing) are determined so that the light is incident on the multilayer film 13 again at the second incident angle.
  • the spatial frequency of the grid lines constituting the first blazed diffraction grating is, for example, in the range of 950 to 2050 lines / mm.
  • the blaze angle of the first blazed diffraction grating is, for example, in the range of 1 ° to 89 °.
  • the second blazed diffraction grating is the light transmitted through the second portion corresponding to the second concave RG of the multilayer film 13 (light of the second wavelength) when the white light is incident on the multilayer film 13 at the first incident angle.
  • the blaze angle and the grating constant are determined so that the light is incident on the multilayer film 13 again at the second incident angle.
  • the spatial frequency of the grid lines constituting the second blazed diffraction grating is, for example, in the range of 950 to 2050 lines / mm.
  • the blaze angle of the second blazed diffraction grating is made equal to, for example, the blaze angle of the first blazed diffraction grating.
  • the third blazed diffraction grating is light (light of a third wavelength) transmitted through a third portion corresponding to the third recess RB of the multilayer film 13 when white light is incident on the multilayer film 13 at the first incident angle.
  • the blaze angle and the grating constant are determined so that the light is incident on the multilayer film 13 again at the second incident angle.
  • the spatial frequency of the grid lines constituting the third blazed diffraction grating is, for example, in the range of 950 to 2050 lines / mm.
  • the blaze angle of the third blazed diffraction grating is made equal to, for example, the blaze angle of the first blazed diffraction grating.
  • the structure generated by the first to third relief structures at the interface may be a diffraction grating other than the blazed diffraction grating.
  • the structure generated by the first to third relief structures at the interface is a diffraction grating other than the blazed diffraction grating, and the light of the first, second, and third wavelengths is red, green, and blue light, respectively.
  • the lattice constants of these diffraction gratings are, for example, within the above-mentioned range with respect to the blazed diffraction grating.
  • the structure in which the first to third relief structures are generated at the interface is such that when white light is incident on the multilayer film 13 at the first incident angle, the light transmitted through the multilayer film 13 is transmitted to the multilayer film 13. It does not have to have a function as a diffraction grating as long as it can be re-incident at two incident angles.
  • the reflective layers 12R, 12G and 12B cover the back surfaces of the front layers 11R, 11G and 11B, respectively.
  • the reflective layers 12R and 12G are made of a transparent material.
  • the reflective layers 12R and 12G have different refractive indexes from the front layers 11R and 11G, respectively.
  • the materials exemplified for the dielectric layers 13a and 13b can be used.
  • the reflective layer 12B is made of a transparent material or an opaque material.
  • the reflective layer 12B is made of a transparent material, its refractive index is different from that of the front layer 11B.
  • the transparent material for example, the materials exemplified for the dielectric layers 13a and 13b can be used.
  • the opaque material for example, a metal material such as aluminum, silver and an alloy containing one or more of them can be used.
  • Each of the reflective layers 12R, 12G and 12B may have a single-layer structure or a multi-layer structure.
  • the back surface layers 14R, 14G and 14B cover the back surfaces of the reflective layers 12R, 12G and 12B, respectively.
  • Each of the back layers 14R, 14G and 14B is made of, for example, a transparent resin.
  • the back layer 14B may be opaque.
  • the resin constituting each of the back layers 14R, 14G and 14B may be a cured product of a thermosetting resin or a photocurable resin, may be a thermoplastic resin, and may be an adhesive or an adhesive. May be good.
  • the front layer 11B, the reflective layer 12B and the back layer 14B can be omitted. Further, the front layer 11G, the reflection layer 12G and the back layer 14G can be further omitted.
  • the reflective layer 12R and the back layer 14R can be omitted.
  • materials having different refractive indexes are used for the front layer 11R and the back layer 14R.
  • 1 or 2 of the front layer 11G, the reflection layer 12G, and the back layer 14G can be omitted.
  • materials having different refractive indexes are used for the front layer 11G and the back layer 14G.
  • 1 or 2 of the front layer 11B, the reflection layer 12B, and the back layer 14B can be omitted.
  • materials having different refractive indexes are used for the front layer 11B and the back layer 14B.
  • FIG. 2 is a cross-sectional view schematically showing a blank medium that can be used for manufacturing the display shown in FIG.
  • FIG. 3 is a cross-sectional view illustrating a method of manufacturing the display body shown in FIG.
  • the reference reference numeral OL represents the objective lens of the laser device.
  • the blank medium 1A0 shown in FIG. 2 is prepared.
  • the blank medium 1A0 has the same structure as the display body 1A except that the laminated body is not provided with the first recess RR, the second recess RG, and the third recess RB.
  • the image is recorded by irradiating the laminate with a laser beam.
  • the laser beam LB is irradiated to the region of the front surface of the laminated body where the first recess RR, the second recess RG and the third recess RB should be formed.
  • the first recess RR, the second recess RG, and the third recess RB are formed on the front surface of the laminated body.
  • the diameter of the beam spot is usually several tens of ⁇ m. Therefore, by this laser beam irradiation, for example, a recess having an opening diameter of several tens of ⁇ m or more can be formed.
  • the laser device is a pulse laser
  • the depth of the recess formed by the irradiation of the laser beam LB can be adjusted, for example, by changing the number of times of irradiation of the pulsed light. As described above, the display body 1A is obtained.
  • FIG. 4 is a cross-sectional view schematically showing the optical behavior that occurs when the display body according to the comparative example is illuminated with white light.
  • a flat reflecting surface REF is laminated.
  • a display body installed parallel to the back surface of the film 13 and separated from the multilayer film 13 is drawn.
  • this display body is designed as follows. That is, when the front surface of the display body is illuminated with the white light L1 emitted by the light source LS, all the light components of the white light incident at the first incident angle ⁇ 1 are provided in the portion of the multilayer film 13 where the recess is not provided. Causes weakening interference and does not pass through the multilayer film 13 and is not reflected by the multilayer film 13. Further, in the first portion of the multilayer film 13 corresponding to the first concave portion RR, among the white light incident at the first incident angle ⁇ 1, the light L2 having the first wavelength in the red region is transmitted through the multilayer film 13.
  • Light having other wavelengths causes weakening interference and does not pass through the multilayer film 13 and is not reflected by the multilayer film 13.
  • the light having the second wavelength in the green region is transmitted through the multilayer film 13 and other.
  • Light having a wavelength of is not transmitted through the multilayer film 13 due to weakening interference, and is not reflected by the multilayer film 13.
  • the third portion of the multilayer film 13 corresponding to the third concave portion RB among the white light incident at the first incident angle ⁇ 1, the light having the third wavelength in the blue region is transmitted through the multilayer film 13 and other.
  • Light having a wavelength of is not transmitted through the multilayer film 13 due to weakening interference, and is not reflected by the multilayer film 13.
  • the first portion corresponding to the first concave portion RR transmits the light L2 having the first wavelength in the red region among the white light L1 incident on the multilayer film 13 at the first incident angle ⁇ 1 and other.
  • Light having a wavelength is neither transmitted nor reflected.
  • the light L2 as the transmitted light is reflected by the reflecting surface REF. Since the reflecting surface REF is installed parallel to the back surface of the multilayer film 13, the light L2 as the reflected light is specularly reflected by the reflecting surface REF. As a result, the light L2 re-enters the multilayer film 13 at an incident angle equal to its emission angle.
  • the first incident angle ⁇ 1 is larger than 0 °
  • the above-mentioned injection angle is also larger than 0 °. Therefore, the light L2 as the reflected light may re-enter the portion of the multilayer film 13 other than the first portion, for example, the third portion corresponding to the third recess RB.
  • the light having the third wavelength in the blue region passes through the multilayer film 13, but the light having other wavelengths weakens each other. It causes interference and does not penetrate the multilayer film 13. And here, the light L2 has the first wavelength in the red region.
  • this display body cannot display the original image to the observer OB.
  • FIG. 5 is a cross-sectional view schematically showing the optical behavior that occurs when the display body shown in FIG. 1 is illuminated with white light.
  • the first reflective surface DG is drawn as a structure installed on the back surface side of the multilayer film 13. Further, also here, in order to facilitate understanding, it is assumed that the multilayer film 13 is designed in the same manner as described with reference to FIG.
  • the first portion corresponding to the first concave portion RR transmits the white light L1 incident on the multilayer film 13 at the first incident angle ⁇ 1 and transmits the light L2 having the first wavelength in the red region, and the like.
  • Light having a wavelength of is neither transmitted nor reflected.
  • the light L2 as the transmitted light is incident on the first reflecting surface DG.
  • the first reflecting surface DG constitutes the first blazed diffraction grating.
  • the first blazed diffraction grating diffracts the light L2 of the first wavelength transmitted through the first portion corresponding to the first concave portion RR of the multilayer film 13, and forms the light L3 into the multilayer film 13 with a second incident angle ⁇ 2. Let it enter again with.
  • the transmission characteristics of the multilayer film 13 change according to the incident angle of the incident light.
  • the second portion corresponding to the second concave portion RG and the third portion corresponding to the third concave portion RB do not transmit the light L2 of the first wavelength incident at the first incident angle ⁇ 1.
  • these portions may transmit the light L3 of the first wavelength incident at the second incident angle ⁇ 2 different from the first incident angle ⁇ 1.
  • other parts of the multilayer film 13 may also transmit the light L3 of the first wavelength incident at the second incident angle ⁇ 2.
  • this display body can display the original image to the observer OB.
  • the display body 1A described with reference to FIG. 1 can be manufactured by performing laser drawing on the multilayer film 13 of the blank medium 1A0 described with reference to FIG. This laser drawing can be completed in a much shorter time than the process of transferring the hologram pixel by pixel onto a blank medium. Therefore, according to the above-mentioned technique, it is possible to manufacture a display body that displays a structural color image in a short time.
  • this display body 1A requires an advanced and complicated optical design, and high accuracy is required. Therefore, it is difficult to forge this display body 1A.
  • FIG. 6 is a cross-sectional view schematically showing a display body according to a second embodiment of the present invention.
  • FIG. 7 is a cross-sectional view schematically showing a blank medium that can be used for manufacturing the display shown in FIG.
  • the display body 1B shown in FIG. 6 and the blank medium 1B0 shown in FIG. 7 are the same as the display body 1A and the blank medium 1A0 according to the first embodiment, respectively, except for the points described below.
  • the front layer 11 is provided on the back surface of the multilayer film 13.
  • the front layer 11 is made of, for example, a transparent resin.
  • This transparent resin may be a cured product of a thermosetting resin or a photocurable resin, may be a thermoplastic resin, or may be an adhesive or an adhesive.
  • the front surface layer 11 may have a single layer structure or a multi-layer structure.
  • the back surface of the front layer 11 includes a plurality of regions each consisting of the first to third sub regions. These regions are regularly arranged on the back surface of the front layer 11. According to one example, each of these regions has a shape extending in the X direction and is arranged in the Y direction.
  • the first to third sub-regions are provided with the first to third relief structures described in the first embodiment, respectively.
  • each of these first to third subregions has a shape extending in the X direction and is arranged in the Y direction.
  • the first diffraction grating DGR, the second diffraction grating DGG and the third diffraction grating DGB are generated on the reflection surface which is the interface between the front layer 11 and the reflection layer 12, respectively.
  • the first recess RR, the second recess RG, and the third recess RB are provided at the positions of the first diffraction grating DGR, the second diffraction grating DGG, and the third diffraction grating DGB, respectively.
  • the reflective layer 12 covers the back surface of the front layer 11.
  • the material of the reflective layer 12 for example, the material exemplified for the reflective layer 12B can be used.
  • the back surface layer 14 covers the back surface of the reflection layer 12.
  • the back layer 14 is made of, for example, a transparent resin.
  • the back layer 14 may be opaque.
  • the resin constituting the back layer 14 may be a cured product of a thermosetting resin or a photocurable resin, may be a thermoplastic resin, or may be an adhesive or an adhesive.
  • the reflection layer 12, and the back layer 14 can be omitted.
  • materials having different refractive indexes are used for the front layer 11 and the back layer 14.
  • the display body 1B has the first recess RR, the second recess RG, and the third recess RB formed at the positions of the first diffraction grating DGR, the second diffraction grating DGG, and the third diffraction grating DGB, respectively.
  • the display body 1A can be manufactured by the same method as described above.
  • the same effect as that of the first embodiment can be obtained.
  • the display body 1B according to the second embodiment can display a brighter image as compared with the display body 1A according to the first embodiment. .. Further, the display body 1B according to the second embodiment can be easily formed thinner than the display body 1A according to the first embodiment.
  • FIG. 8 is a cross-sectional view schematically showing an article with a display according to an embodiment of the present invention.
  • the article 100AB with a display body is, for example, a printed matter.
  • the article 100AB with a display is, for example, a personal authentication medium such as a banknote, securities, certificates, a credit card, a passport and an ID (identification) card, or a package for packaging the contents.
  • the article 100AB with a display body includes the display body 1AB and the article 110 supporting the display body 1AB.
  • Article 110 includes a printing base material and a printing layer provided on the printing base material when it is a printed matter.
  • the material of the printing substrate is, for example, plastic, metal, paper, or a composite thereof.
  • the display body 1AB is the display body 1A or 1B described above.
  • the display body 1AB is supported by the article 110 so that the front surface thereof is adjacent to the outside of the article 100AB with the display body.
  • the display body 1AB can be supported by the article 110, for example, by being attached to the surface of the article 110 or embedded in the article 110.
  • the article 100AB with a display body can be manufactured, for example, by manufacturing the display body 1AB in advance and supporting the display body 1AB by the article 110.
  • the article 100AB with a display body can also be manufactured by the following method.
  • FIG. 8 is a cross-sectional view schematically showing an article with a blank medium according to an embodiment of the present invention.
  • the article 100AB0 with a blank medium shown in FIG. 8 has the same structure as the article 100AB with a display body, except that the multilayer film 13 is not provided with the first recess RR, the second recess RG, and the third recess RB. are doing. That is, the article 100AB0 with a blank medium includes the blank medium 1AB0 and the article 110 supporting the blank medium 1AB0.
  • the blank medium 1AB0 is the blank medium 1A0 or 1B0 described above.
  • An article 100AB0 with a blank medium may be prepared in advance, and the article 100AB with a display body may be manufactured by irradiating the blank medium 1AB0 with a laser beam.
  • the front surface of the laminate forming the first recess RR, the second recess RG, and the third recess RB is exposed, when the display body 1A, 1B or 1AB, or the article 100AB with the display body is used, they are used.
  • the recess may be deformed due to friction or the like. Therefore, it is preferable to provide a protective layer made of a transparent material on the front surface of the laminate.
  • the protective layer may cover only the front surface of the laminated body, or may cover the front surface of the display body 1AB and the front surface of the article 110.
  • the thick protective layer does not affect the interference in the multilayer film 13.
  • the thin protective layer can affect the interference in the multilayer film 13. That is, in the latter case, the protective film is used as a part of the multilayer film 13. Therefore, in this case, the multilayer film 13 is designed to exhibit the above-mentioned optical characteristics with the protective layer included.
  • a display body having a structure similar to that of the display body 1A described with reference to FIG. 1 was manufactured.
  • the multilayer film 13 is composed of one dielectric layer 13a and one dielectric layer 13b.
  • a material having a refractive index of 1.98 was used, and the thickness thereof was 700 nm.
  • a material having a refractive index of 1.28 was used, and the thickness thereof was set to 650 nm.
  • the first recess RR was formed so that the thickness of the first portion was 600 nm.
  • the second recess RG was formed so that the thickness of the second portion was 300 nm.
  • the third concave portion RB was formed so that the thickness of the third portion was 200 nm.
  • a protective layer was formed on the dielectric layer 13a.
  • a material having a refractive index of 2.5 was used, and the thickness thereof was sufficiently increased so as not to affect the interference in the multilayer film 13.
  • the first blazed diffraction grating was formed so that the spatial frequency of the grating lines was 1150 lines / mm.
  • the second blazed diffraction grating was formed so that the spatial frequency of the grating lines was 1320 lines / mm.
  • the third blazed diffraction grating was formed so that the spatial frequency of the grating lines was 1550 lines / mm.
  • FIG. 10 is a graph showing the transmission spectrum obtained by computer simulation for the third portion corresponding to the third concave portion RB of the multilayer film 13.
  • FIG. 11 is a graph showing the transmission spectrum obtained by computer simulation for the third portion corresponding to the second concave portion RG of the multilayer film 13.
  • FIG. 12 is a graph showing a transmission spectrum obtained by computer simulation for the third portion corresponding to the first concave portion RR of the multilayer film 13.
  • the transmittance of the portion of the multilayer film 13 in which the recess is not provided is substantially constant over the entire visible region.
  • the transmittance in the blue region is lower than the transmittance in other wavelength regions in the visible region. That is, the light transmitted through the third portion has low intensity in the blue region and high intensity in the green region and the red region. Therefore, the light transmitted through the third portion looks yellow.
  • the transmittance in the green region is lower than the transmittance in other wavelength regions in the visible region. That is, the light transmitted through the second portion has low intensity in the green region and high intensity in the blue region and the red region. Therefore, the light transmitted through the second portion looks magenta.
  • the transmittance in the red region is lower than the transmittance in other wavelength regions in the visible region. That is, the light transmitted through the first portion has low intensity in the red region and high intensity in the blue region and the green region. Therefore, the light transmitted through the first portion looks cyan.
  • the strong primary diffracted light of red, green and blue is inclined with respect to the normal direction, respectively. Eject in the direction. That is, the combination of the first, second, and third blazed diffraction gratings has a substantially uniform reflectance over almost the entire visible region, and a reflecting surface that reflects the incident light at a reflection angle different from the incident angle. Functions as.
  • this display body should be able to display a color image having a pattern corresponding to the arrangement of the first recess RR, the second recess RG, and the third recess RB as a diffraction image.
  • the present invention is not limited to the blazed diffraction grating, and a holographic diffraction grating, a laminar diffraction grating, or the like can also be used.

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Electromagnetism (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Ceramic Engineering (AREA)
  • Diffracting Gratings Or Hologram Optical Elements (AREA)
  • Credit Cards Or The Like (AREA)
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PCT/JP2020/006493 2019-03-28 2020-02-19 表示体 Ceased WO2020195367A1 (ja)

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JP2021508269A JPWO2020195367A1 (enExample) 2019-03-28 2020-02-19
CN202080025680.6A CN113646671B (zh) 2019-03-28 2020-02-19 显示体
EP20777415.9A EP3951448B1 (en) 2019-03-28 2020-02-19 Display body
US17/484,232 US12158598B2 (en) 2019-03-28 2021-09-24 Display

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JP2019-064029 2019-03-28

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US20220011481A1 (en) 2022-01-13
EP3951448A4 (en) 2022-06-08
JPWO2020195367A1 (enExample) 2020-10-01
EP3951448B1 (en) 2024-10-16
CN113646671A (zh) 2021-11-12
US12158598B2 (en) 2024-12-03
CN113646671B (zh) 2023-12-22

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