Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
  • C09J175/04—Polyurethanes
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
  • C08G18/72—Polyisocyanates or polyisothiocyanates
  • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
  • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
  • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
  • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
  • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
  • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
  • C08G18/72—Polyisocyanates or polyisothiocyanates
  • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
  • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
  • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
  • C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/02—Elements
  • C08K3/08—Metals
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/40—Glass
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K9/00—Use of pretreated ingredients
  • C08K9/02—Ingredients treated with inorganic substances
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J7/00—Adhesives in the form of films or foils
  • C09J7/10—Adhesives in the form of films or foils without carriers
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J7/00—Adhesives in the form of films or foils
  • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
  • C09J7/35—Heat-activated
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
  • C09J9/02—Electrically-conducting adhesives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/02—Elements
  • C08K3/08—Metals
  • C08K2003/0812—Aluminium
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/02—Elements
  • C08K3/08—Metals
  • C08K2003/085—Copper
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K2201/00—Specific properties of additives
  • C08K2201/001—Conductive additives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K2201/00—Specific properties of additives
  • C08K2201/01—Magnetic additives
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
  • C09J2203/314—Applications of adhesives in processes or use of adhesives in the form of films or foils for carpets
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
  • C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2301/00—Additional features of adhesives in the form of films or foils
  • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
  • C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2301/00—Additional features of adhesives in the form of films or foils
  • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
  • C09J2301/314—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive layer and/or the carrier being conductive
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2301/00—Additional features of adhesives in the form of films or foils
  • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
  • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2475/00—Presence of polyurethane

Definitions

• the present invention relates to a latent reactive conductive adhesive film based on polyurethane.
• Adhesive tapes can absorb more and more often are no longer sufficient. That too
• Remedial measures include heat-activated, reactive adhesive films based on polyurethane.
• polyurethane adhesives Due to the high polarity of the polymer molecules and the partially crystalline structure within the polymer chains, polyurethane adhesives are characterized by very good adhesion properties even on surfaces that are difficult to bond. In addition own
• Polyurethane adhesives have a high resistance to plasticizers, oils, greases,
• One-component systems that can be used directly can be provided by means of polyurethane adhesives, i. H. Mixing the components immediately before use as well as a pot life until final curing is not necessary.
• the adhesive strength of the one-component, latently reactive systems corresponds entirely to that of two-component systems. Accordingly, quasi-static shear strengths on polycarbonate (PC) of> 12 MPa can be achieved with the one-component, latently reactive adhesive systems.
• PC polycarbonate
• latent reactive means that an aqueous, for example only 100 ⁇ m thin, polyurethane dispersion layer can be applied to a part to be bonded and dried some time before the actual bonding. At room temperature, this layer remains stable and non-blocking and the adhesive is only activated and subsequently glued when the two parts to be glued are heated. This allows for Users of the adhesive application and the final production of the adhesive connection are not only separated in time, but also in space.
• the shear strength is determined and measured in MPa (megapascal).
• the shear strength is the resistance that a solid body offers against tangential shear forces.
• Latent reactive, heat-activated adhesive systems are, for example, from the
• the adhesive shown in DE 10 2010 013 145 A1 fulfills a combination of different requirement profiles that have not previously been combined in a single adhesive system, namely, on the one hand, that of a latently reactive adhesive that is already slightly tacky at room temperature and cures under the influence of heat and enables structural bonding of the two joining partners.
• Structuretural bonding means that the two joining partners are joined by the adhesive to form a single structure, which is characterized in that in the event of an attempted later separation of the two joining partners, the bonded seam does not constitute the weak point in the bond forms, but rather one of the two joining partners.
• one-component polyurethane film which has no adhesive strength at room temperature and is no longer sticky even after it has been activated due to the addition of heat and subsequent cooling, but rather is part of a structural connection between two joining partners, as above
• a major advantage of the system described in both of the applications mentioned is the possibility of providing substrate surfaces with a reactive adhesive layer in a storage-stable manner, ie. H. the adhesive application can be outsourced from the actual manufacturing process of the desired end product. Processes are simplified and thus also cheaper.
• Adhesives are known which, in addition to having an adhesive force, also have conductive properties.
• Conductive adhesives are known from the prior art, including adhesive compositions containing urethane or based on urethane.
• WO 2014/122866 A1 describes a heat-conductive light-curable adhesive comprising polyurethane and a photopolymerizable one Monomer with a (meth) acryloyl group and an inorganic filler and one
• WO 2009/090997 A1 shows a curable, electromagnetically shielding, adhesive construction consisting of an electrically conductive filler-containing layer based on polyurethane-polyurea and epoxy resin and a curable insulating layer based on a second polyurethane-polyurea compound and epoxy resin without fillers.
• WO 2016/002780 A1 relates to a conductive adhesive comprising a polyurethane-polyurea, an epoxy resin and a filler, the polyurethane-polyurea being a
• Reaction product of a polyamino compound and a urethane prepolymer is a reaction product of a polyol component, a diisocyanate and a diol compound.
• the finished film is liquefied by heat and then flows between the parts to be connected.
• the adhesive film according to WO 2006/088127 A1 has an electromagnetic shielding effect due to the electrically conductive fillers contained in its hardenable adhesive layer based on polyurethane polyurea and epoxy resin.
• WO 2018/003704 A1 shows an electrically conductive adhesive which crosslinks under the action of heat, comprising a specific urethane-modified polyfunctional (meth) acrylate oligomer, a monfunctional (meth) acrylate oligomer, organic peroxide and electrically conductive particles.
• none of the conductive adhesives described above is able to provide high quasi-static shear strengths on the order of, for example,> 6 MPa and thus to enable a structural connection. Accordingly, the above conductive adhesive systems are only suitable for a comparatively limited range of applications. For application areas that have a comparatively high, i.e. structural adhesives such as high quasi-static shear strength, these adhesives are out of the question.
• a latent reactive adhesive film based on polyurethane, which according to the invention contains up to 98% by weight of a crystalline and / or a crystalline and amorphous polyurethane component, and 2 to 80% by weight, preferably 2 to 65% by weight of a conductive filler.
• the crystalline polyurethane component forms a dry film that has a semicrystalline structure, which means that the film has no tack at room temperature and is therefore easy to reposition.
• the polyurethane-based films have a melting temperature of 50 ° C plus / minus 10 ° C. If the films are melted to a temperature in the region of the melting temperature, they develop sticky properties, which results in pre-lamination, i.e. a first alignment of the joining partners to each other can be made possible.
• the actual activation of the films takes place at temperatures in the range of 70-120 ° C. After completion of the reaction triggered by the heat activation, there is a final structural connection that can withstand comparatively high loads in the long term.
• the fillers can be of an electrically conductive, thermally conductive or magnetically conductive type.
• Polyurethane component enables an adhesive system with a comparatively high quasi-static shear strength on polycarbonate of> 6 MPa and more. This enables flat, conductive, structural bonds to be realized.
• Examples are carpet bonds that are usually exposed to high loads. Here adhesives with high bond strengths are required.
• the adhesive system described above can be used to bond carpets that is both high-strength and dissipative.
• Adhesive bonds are widely used in the textile industry. The trend is towards integrating electronic components in textiles, such as clothing. For example, conductor tracks in the form of stripes or stamped parts can be provided for light integration in the fashion sector. Because the clothes are usually high when worn
• the conductive adhesive systems When exposed to loads, the conductive adhesive systems must have a correspondingly high bond strength.
• the adhesive system described above can meet these requirements.
• the conductive substance can be provided in different particle shapes. Spherical, dendritic, rod-shaped, spattery (misshapen) or even platelet-shaped particles can be used.
• Dispersing additives added which in turn also leads to poor conductivity.
• the layers of adhesive are thin, conductivity in the x-y direction of the adhesive film is more desirable.
• conductivity in the x-y direction of the adhesive film is more desirable.
• the polyurethane component can be reacted with isocyanate.
• the crystalline polyurethane component can, for example, be based on an anionic high molecular weight polyurethane dispersion. This forms a dry film, which has a semi-crystalline structure, which means that the film has no tack at room temperature and is therefore easy to reposition.
• the crystalline polyurethane component comprises semicrystalline polyester polyurethane. This enables the crystalline domains to melt, so that sticky properties develop, which enables pre-lamination.
• the adhesive film comprises a crosslinking agent, such as, for example, an isocyanate-containing component which is dispersed in particulate form in the polyurethane component.
• a crosslinking agent such as, for example, an isocyanate-containing component which is dispersed in particulate form in the polyurethane component.
• the crystalline polyurethane component with dispersed isocyanate particles forms a dry film, which has a semi-crystalline structure, which means that the film has no tack at room temperature and is therefore easy to reposition.
• the actual activation of the adhesive film takes place at temperatures in the range of 50-120 ° C.
• a crosslinking agent such as isocyanate, additionally results in a crosslinking reaction as a result of activation by heat treatment.
• the adhesive film has the comparatively high strengths of up to 10 MPa even at higher temperatures. After the reaction triggered by the heat activation has been completed, there is a permanent connection that can withstand comparatively high loads over the long term.
• the activation temperature depends on the
• the latently reactive adhesive film comprises up to 40% by weight of a crosslinking agent, up to 5% by weight of a thickener, and / or up to 5% by weight of one
• the crosslinker causes the adhesive to harden after activation by appropriate temperatures.
• the thickener gives the adhesive dispersion a viscosity necessary for coating during its manufacture.
• the dispersing additive helps to ensure that the various components are homogeneously distributed.
• the amorphous polyurethane component comprises polyurethanes and / or polyacrylates. In the latter case, this happens because the adhesive properties of acrylates promote their adhesion to substrates on which polyurethanes adhere less well.
• the latently reactive conductive adhesive film has a quasi-static shear strength of at least 6 MPa on a PC. This makes conductive adhesive films with unprecedented strength properties possible. Depending on the choice of fillers, the shear strength can also exceed 8 MPa on PC.
• the conductive filler comprises metals, silver-plated metals, metal oxides, metal hydroxides, metal nitrides, carbon-containing materials, conductive polymers, soft magnetic materials, and / or hard magnetic materials.
• the electrically conductive fillers include metals such as silver; silver-plated metals and metal oxides such as silver-plated copper, silver-plated aluminum, silver-plated glass or silver-plated zinc oxide; carbonaceous materials such as graphite, graphene, carbon nanotubes (CNT) and conductive polymers such as poly-3-hexylthiophene (P3HT).
• metals such as silver
• silver-plated metals and metal oxides such as silver-plated copper, silver-plated aluminum, silver-plated glass or silver-plated zinc oxide
• carbonaceous materials such as graphite, graphene, carbon nanotubes (CNT) and conductive polymers such as poly-3-hexylthiophene (P3HT).
• the thermally conductive fillers include metal oxides such as aluminum oxide, metal hydroxides such as aluminum hydroxides and metal nitrides such as boron nitride.
• the magnetically conductive fillers include soft magnetic materials such as alloys based on cobalt, nickel or iron; and hard magnetic materials such as neodymium iron boron (NdFeB) or cobalt samarium.
• soft magnetic materials such as alloys based on cobalt, nickel or iron
• hard magnetic materials such as neodymium iron boron (NdFeB) or cobalt samarium.
• the particle size of fillers based on metal is between 2 nm and 30 pm.
• the particle size of fillers in the form of silver-plated materials is preferably between 2 pm and 100 pm between 18 mih to 75 mih.
• Materials are usually between 3 nm to 70 miti.
• the filler contained in the present adhesive film can also be based on particle mixtures of the fillers described above. Mixtures of silver-plated materials and carbon-containing materials are preferably used. The above combination of fillers can be used to provide adhesive films with high quasi-static shear strength values and high electrical conductivity.
• the adhesive film has little to no tack at room temperature and can therefore be easily positioned or repositioned at the place of use or on the corresponding joining partners.
• the latent reactive adhesive film based on polyurethane has a layer thickness of 7 pm to 1000 mm.
• the above object is further achieved by using a latent reactive adhesive film based on polyurethane with the features of claim 6. Accordingly, the adhesive film is applied to the place of use or the joining partner, where the adhesive film is attached by means of a
• a method for producing a latent reactive adhesive film based on polyurethane with the features of claim 7. Accordingly, up to 98% by weight of a crystalline and / or a crystalline and amorphous polyurethane dispersion are first mixed with up to 80% by weight, preferably 2 to 65% by weight, of a conductive filler. The polyurethane dispersion together with the dispersed, conductive filler is then applied to a carrier, in particular a conductive one, or a release liner, so that a composite is formed. Finally the composite is dried.
• Polyurethane base with dispersed, conductive fillers can the above
• a conductive latent reactive adhesive film can be applied
• Polyurethane base can be provided with the following starting materials.
• a polyurethane dispersion can contain an aromatic crosslinking agent such as tolylene diisocyanate.
• TDI compounds Compounds (TDI compounds) and / or an aliphatic crosslinker such as isophorone diisocyanate (IPDI).
• IPDI isophorone diisocyanate
• the following particles can be used as electrically conductive fillers: eConduct Aluminum 202000®, eConduct Aluminum 451500®, VP70308®, eConduct Glass 352000®, eConduct Soft 205002® and eConduct Copper 341000® all from ECKART GmbH.
• the average common particle size in the experiments carried out has a diameter of 50 pm.
• a general formulation of a conductive latent reactive adhesive film based on polyurethane can be formed as follows:
• Table 1 shows that the crystalline polyurethane component and the conductive
• Fillers form the essential components of the conductive, latently reactive adhesive film.
• a crystalline polyurethane component with dispersed conductive filler particles points to the Cooling down to room temperature already shows high strength. This is solely due to the recrystallization of the polyurethane component.
• a crosslinking agent such as isocyanate
• a crosslinking agent such as isocyanate
• the isocyanate groups react with the functional groups of the thermoplastic polyurethane and crosslink the system.
• the adhesive film also shows at higher ambient temperatures
• Stabilizers pigments for coloring, catalysts, anti-aging agents, light stabilizers and other polymers for setting other adhesive properties.
• System 1 has a comparatively high conductivity of 0.2-0.4 mOhm.
• System 2 :
• Liquid crystalline polyurethane is optionally homogenized with a crosslinker and the corresponding conductive particles in a speed mixer.
• the dispersion obtained is applied to a substrate using a doctor knife.
• the resulting film is dried for 5 minutes at 50 ° C.
• the coating process can be repeated on the second side of the substrate, whereby a double-sided latent reactive adhesive tape is obtained.
• Aluminum and silver-plated copper achieve shear strength values between 8 and 11 MPa on PC even at comparatively high fill levels (i.e. even at more than 50% depending on the filler used).

Landscapes

• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Adhesives Or Adhesive Processes (AREA)
• Adhesive Tapes (AREA)

Priority Applications (7)

Applications Claiming Priority (1)

Publications (1)

Family

ID=64661314

Family Applications (1)

Country Status (7)

Cited By (1)

Families Citing this family (3)

Citations (10)

Family Cites Families (14)

• 2018
  • 2018-11-29 WO PCT/EP2018/083069 patent/WO2020108765A1/de not_active Ceased
  • 2018-11-29 KR KR1020217020270A patent/KR102625694B1/ko active Active
  • 2018-11-29 CA CA3121223A patent/CA3121223A1/en active Pending
  • 2018-11-29 EP EP18815576.6A patent/EP3887468B1/de active Active
  • 2018-11-29 JP JP2021531257A patent/JP2022515327A/ja active Pending
  • 2018-11-29 US US17/298,296 patent/US12139648B2/en active Active
  • 2018-11-29 CN CN201880099792.9A patent/CN113166602A/zh active Pending

Patent Citations (10)

Also Published As

Similar Documents

Legal Events