WO2019196040A1 - 电芯及锂离子电池 - Google Patents
电芯及锂离子电池 Download PDFInfo
- Publication number
- WO2019196040A1 WO2019196040A1 PCT/CN2018/082717 CN2018082717W WO2019196040A1 WO 2019196040 A1 WO2019196040 A1 WO 2019196040A1 CN 2018082717 W CN2018082717 W CN 2018082717W WO 2019196040 A1 WO2019196040 A1 WO 2019196040A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pole piece
- notch
- end portion
- battery cell
- cell according
- Prior art date
Links
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 11
- 238000004806 packaging method and process Methods 0.000 claims description 6
- 239000006182 cathode active material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000011149 active material Substances 0.000 description 2
- 238000007373 indentation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0431—Cells with wound or folded electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the battery field of the present application is particularly a battery core and a lithium ion battery.
- Lithium-ion batteries have been widely used in consumer electronics, but due to their own characteristics, lithium-ion batteries have certain safety risks. If the electronic product of the consumer product falls, the outer aluminum foil is prone to tear, which causes the internal short circuit of the battery to fail.
- a lithium ion battery coated with a double-sided pole piece can be used, and the separator is used to finish the tail. During the falling process, there is a large friction between the outer layer of the separator and the package to relieve the impact force, and the outer layer only has Double-sided pole pieces greatly reduce the risk of tearing and breakage short circuits. Since the pole piece is completely continuous coated, only the ear side has a difference, and it is difficult to distinguish the starting end of the battery core. If the feeding is wrong, the pole is misaligned and the package is affected.
- an object of the present application is to provide a battery cell and a lithium ion battery capable of discriminating the head and the tail of the pole piece.
- the present application provides a battery core including a first pole piece wound to form a portion of a battery core, wherein the first pole piece has a first end portion along a length direction of the unfolded first pole piece And the edge of the first end is formed with a first notch.
- the first pole piece further has a second end opposite to the first end portion in the length direction, wherein the edge of the second end portion is formed with a second notch.
- the first notch and the second notch are disposed opposite to each other along the length direction and the openings thereof are opposite in direction.
- one of the first end and the second end forms the head of the first pole piece and the other forms the tail of the first pole piece.
- the present application further comprising winding a second pole piece forming a part of the battery core, wherein the second pole piece has a third end portion and a third end portion along a length direction of the unfolded second pole piece The edge is formed with a third gap.
- the second pole piece further has a fourth end portion opposite to the third end portion along the length direction of the second pole piece, wherein the edge of the fourth end portion is formed with a fourth notch.
- the third notch and the fourth notch are disposed opposite to each other along the length direction of the second pole piece and the openings thereof are opposite in direction.
- one of the third end and the fourth end forms the head of the second pole piece and the other forms the tail of the second pole piece.
- one of the first pole piece and the second pole piece is a cathode pole piece, and the other is an anode pole piece.
- the first notch is formed at the beginning of the anode pole piece, and the third notch is formed at the finishing end of the cathode pole piece.
- the tabs are disposed on the top of the cell in the thickness direction of the cell.
- a tab is provided in the thickness direction at the bottom of the cell opposite the top.
- a lithium ion battery comprising the battery core according to any of the above embodiments, and a packaging pouch for packaging the battery core.
- the first pole piece along the length direction of the first pole piece, the first pole piece has a first end portion, and a first notch is formed at the edge of the first end portion, thereby helping to identify the head and the tail of the first pole piece, thereby It is avoided that the external force point directly acts on a single pole piece during the cell replacement process, thereby reducing the safety risk of the battery core in the replacement process.
- FIG. 1 is a top plan view of one embodiment of a first pole piece of a battery cell of the present application
- FIG. 2 is a top plan view of one embodiment of a first pole piece of the battery cell of the present application
- Figure 3 is a plan view of one embodiment of a first pole piece of the cell of the present application.
- FIG. 4 is a top plan view of one embodiment of a second pole piece of the battery cell of the present application.
- 5 to 8 are schematic views of respective embodiments of one of the pole pieces of the battery of the present application.
- Figure 9 is a plan view of an embodiment of the battery cell of the present application, wherein the tabs are located on the same side of the cell;
- Figure 10 is a top plan view of another embodiment of the battery cell of the present application, wherein the tabs are located on both sides of the cell;
- Figure 11 is a top plan view of one embodiment of a battery cell of the present application in which the tabs are not cut.
- the present application provides a battery cell 1 including a first pole piece 2 wound to form a part of a battery cell, wherein the first pole piece 2 has a length along the length direction of the unfolded first pole piece 2.
- the one end portion 4 and the edge of the first end portion 4 are formed with a first notch 6.
- the provision of a notch at one end of the continuously coated cathode pole piece helps to distinguish the head and the tail of the pole piece, the end of the pole piece at the inside of the cell is the head, and the end of the pole piece outside the cell is Tail.
- the battery core often needs to be replaced due to the life decay.
- By providing a notch on the pole piece it is possible to avoid the external force point directly acting on the single pole piece during the cell replacement process, thereby reducing the electricity. The safety risk of the core during the replacement process.
- the first pole piece 2 further has a second end portion 8 opposite to the first end portion 4 in the longitudinal direction, wherein the edge of the second end portion 8 is formed with a second notch 10 .
- a notch may be provided at the first end portion 4 or the second end portion 8 of the first pole piece 2 for positioning of the feed; and during the replacement of the battery core, the point of force can be avoided as a separate pole piece To reduce the risk of short circuit.
- the distance between the center of the first notch 6 or the second notch 10 from the edge of the first end portion 4 or the second end portion 8 of the first pole piece 2 is the width of the first end portion 4 or the second end portion 8.
- the width of the first notch 6 or the second notch 10 is 1/7 to 3/5 of the width of the first end portion 4 or the second end portion 8 of the first pole piece 2, first If the gap 6 or the second notch 10 is too large, the edge of the first notch 6 or the second notch 10 is too small from the edge of the first pole piece 2, and the powder is easily dropped to cause a short circuit; the first notch 6 or the second notch 10 Too small to effectively avoid the external force to open the point.
- the center of the first notch 6 described herein refers to the deepest portion where the first notch 6 is recessed toward the first pole piece 2, and the center of the second notch 10 refers to the deepest portion where the second notch 10 is recessed toward the first pole piece 2. .
- the width of the first end portion 4 or the second end portion 8 means the width along the width direction of the first pole piece 2.
- the first notch 6 and the second notch 10 are disposed opposite to each other in the longitudinal direction and the openings thereof are opposite in direction.
- the first notch 6 is an axisymmetric structure
- the second notch 10 is also an axisymmetric structure
- the axis of symmetry of the first notch 6 is the same as the axis of symmetry of the second notch 10, that is, two axes of symmetry. In a straight line.
- one of the first end portion 4 and the second end portion 8 forms the head of the first pole piece 2, and the other forms the tail of the first pole piece 2.
- a second pole piece 12 that is wound to form a portion of a battery cell is further included, wherein the second pole piece 12 has a third end along the lengthwise direction of the unfolded second pole piece 12.
- the portion 14 and the edge of the third end portion 14 are formed with a third notch 16.
- the second pole piece 12 further has a fourth end opposite to the third end portion 14 along the length direction of the second pole piece 12, wherein the edge of the fourth end portion is formed with a fourth notch.
- a notch may be provided at the third end portion 14 or the fourth end portion of the second pole piece 12 for positioning of the feeding; and during the replacement of the battery core, the point of the force can be avoided as a separate pole Tablet to reduce the risk of short circuit.
- the distance between the center of the third notch 16 or the fourth notch from the edge of the third end portion 14 or the fourth end portion of the second pole piece 12 is 1/3 of the width of the third end portion 14 or the fourth end portion.
- the width of the third notch 16 or the fourth notch is 1/7 to 3/5 of the width of the third end portion or the fourth end portion of the second pole piece 12, and the third notch 16 or the fourth notch If the distance between the edge of the third notch 16 or the fourth notch and the edge of the second pole piece 12 is too small, the powder may be easily dropped to cause a short circuit; the third notch 16 or the fourth notch may be too small to effectively avoid The external force opened the point.
- the third notch 16 and the fourth notch are disposed opposite to each other along the length direction of the second pole piece and the openings thereof are opposite in direction.
- one of the third end portion 14 and the fourth end portion forms the head of the second pole piece 12, and the other forms the tail portion of the second pole piece 12.
- one of the first pole piece 2 and the second pole piece 12 is a cathode pole piece, and the other is an anode pole piece.
- the first indentation 6 is formed in the beginning of the anode pole piece and the third indentation 16 is formed in the finishing section of the cathode pole piece.
- a diaphragm that is wound to form a portion of the battery core is further included, wherein the diaphragm is disposed between the first pole piece 2 and the second pole piece 12.
- FIG. 5 a schematic diagram of various embodiments of one of the pole pieces of the cell of the present application is shown.
- various structures of the pole piece are described by taking the first pole piece 2 as a cathode pole piece as an example, but it should be understood that the structure of the pole piece described below is also applicable to the anode pole piece (for example, the second pole)
- the sheet 12 is), that is, the following description does not constitute any limitation to the present application.
- both sides of the cathode pole piece 2 are coated with a cathode active material 3, and the cathode pole piece 2 includes a first notch 6.
- the cathode pole piece 2 has a plurality of tabs 5 thereon, the tabs 5 projecting from the edge of the cathode current collector 7, and the top of the cathode active material 3 protrudes from the edge of the cathode current collector 7 by about 0 to 2mm. That is, in this embodiment, the top of the cathode active material 3 is between the edge of the cathode pole piece 2 and the edge of the tab 5.
- both sides of the cathode pole piece 2 are coated with a cathode active material 3, and the cathode pole piece 2 includes a first notch 6.
- the cathode pole piece 2 has a plurality of tabs 5 thereon, the tabs 5 projecting from the edge of the cathode current collector 7, and the top of the cathode active material 3 protrudes from the edge of the cathode current collector 7 by about 0 to 2mm.
- the embodiment of Fig. 6 further comprises an insulating layer 9 which is applied at the location of the tabs 5 and which interfaces with the active material 3.
- both sides of the cathode pole piece 2 are coated with a cathode active material 3, and the cathode pole piece 2 includes a first notch 6.
- the cathode pole piece 2 has a plurality of tabs 5 thereon, and the tabs 5 protrude from the edges of the cathode current collector 7.
- the insulating layer 9 is further included in this embodiment. Different from the embodiment shown in Fig. 6, the insulating layer 9 in Fig. 7 extends along the edge of the coated region of the active material 3 to the lower middle portion of the tab 5.
- both sides of the cathode pole piece 2 are coated with a cathode active material 3, and the cathode pole piece 2 includes a first notch 6.
- the tab 5 of the same length as the current collector 7 is included in the embodiment shown in Fig. 8, and the tab 5 protrudes from the top of the cathode current collector 7.
- first pole piece 2 as the cathode pole piece, and all the structures and configurations as described above can be equally applied to the anode pole piece, and the above is only the embodiment of the present application. It does not constitute any limitation on this application.
- a tab 18 is disposed on the top of the cell along the thickness direction T of the cell.
- a tab 20 is provided at the bottom of the cell opposite the top.
- the tabs may be located on one side of the cell or on both sides of the cell.
- the tabs 18, 20 may be disposed at the top of the thickness direction T of the cell; and in the embodiment shown in FIG. 10, the tabs 18 may be placed in the electrical The top of the core, and the tab 20 can be placed at the bottom of the cell. It should of course be understood that the position and configuration of the tabs may depend on the particular application.
- Providing a notch in the head or tail of the pole piece helps to identify the head and tail of the pole piece, especially when the pole piece is provided on the top and bottom of the cell, it is not easy to distinguish the head and the tail of the pole piece. After the gap is set, the head and the tail can be easily distinguished, and the misalignment caused by the feeding error can be effectively avoided, thereby affecting the packaging of the battery core.
- Figure 11 shows a top view of one embodiment of a battery cell in accordance with the present application in which the tabs are not cut.
- the tabs 18, 20 may be disposed on the top and bottom of the cell, but in this embodiment the tabs 18, 20 are not cut such that the cell contains pole pieces of the same length as the current collector tab.
- the structure shown in FIG. 9 and FIG. 10 may be adopted, and the structure shown in FIG. 11 may also be adopted. It is also possible to cut the tab 18 without cutting the tab 20 and vice versa. Therefore, the various embodiments described above are not intended to limit the application.
- a lithium ion battery comprising the battery core according to any of the above embodiments, and a packaging pouch for packaging the battery core.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Secondary Cells (AREA)
Abstract
Description
Claims (18)
- 一种电芯,包括第一极片,其中,沿展开的所述第一极片的长度方向,所述第一极片具有第一端部,且所述第一端部的边缘设置有第一缺口。
- 根据权利要求1所述的电芯,其中,所述第一极片还具有沿所述长度方向与所述第一端部相对的第二端部,其中,所述第二端部的边缘形成有第二缺口。
- 根据权利要求2所述的电芯,其中,所述第一缺口和所述第二缺口沿所述长度方向彼此相对设置且二者开口方向相反。
- 根据权利要求2所述的电芯,其中,所述第一端部位于所述第一极片的头部,并且所述第二端部位于所述第一极片的尾部。
- 根据权利要求2所述的电芯,其中,所述第一缺口与所述第二缺口的对称轴在一条直线上。
- 根据权利要求2所述的电芯,其中,所述第一缺口的中心距所述第一端部边缘的距离为所述第一端部宽度的1/3~2/3;所述第二缺口的中心距所述第二端部边缘的距离为所述第二端部宽度的1/3~2/3。
- 根据权利要求2所述的电芯,其中,所述第一缺口的宽度为所述第一端部的宽度的1/7~3/5;所述第二缺口的宽度为所述第二端部的宽度的1/7~3/5。
- 根据权利要求1所述的电芯,其中,还包括第二极片,其中,沿展开的所述第二极片的长度方向,所述第二极片具有第三端部并且所述第三端部的边缘设置有第三缺口。
- 根据权利要求8所述的电芯,其中,所述第二极片还具有沿所述第二极片的长度方向与所述第三端部相对的第四端部,其中,所述第四端部的边缘形成有第四缺口。
- 根据权利要求9所述的电芯,其中,所述第三缺口和所述第四缺口沿所述第二极片的长度方向彼此相对设置且二者开口方向相反。
- 根据权利要求9所述的电芯,其中,所述第三端部为所述第二极片的头部,所述第四端部为所述第二极片的尾部。
- 根据权利要求9所述的电芯,其中,所述第三缺口的中心距所述第三端部的边缘的距离为所述第三端部的宽度的1/3~2/3;所述第四缺口的中心距所述第四端部的边缘的距离为所述第四端部的宽度的1/3~2/3。
- 根据权利要求9所述的电芯,其中,所述第三缺口的宽度为所述第三端部的宽度的1/7~3/5;所述第四缺口的宽度为所述第四端部的宽度的1/7~3/5。
- 根据权利要求8所述的电芯,其中,所述第一极片和所述第二极片中的一者为阴极极片,并且另一者为阳极极片。
- 根据权利要求14所述的电芯,其中,所述第一缺口形成在所述阳极极片的起始段,并且所述第三缺口形成在所述阴极极片的收尾段。
- 根据权利要求1中任一项所述的电芯,其中,所述电芯包含第一极耳,所述第一极耳从沿所述电芯的一侧突出。
- 根据权利要求16所述的电芯,其中,所述电芯还包含第二极耳,所述第二极耳从沿所述电芯的另一侧突出,所述第一极耳的突出方向与所述第二极耳的突出方向相反。
- 一种锂离子电池,其特征在于,包括权利要求1至17中任一项所述的电芯、以及封装所述电芯的包装袋。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA3095358A CA3095358C (en) | 2018-04-11 | 2018-04-11 | Battery cell having electrode plate with multiple tabs and lithium-ion battery |
CN201880088590.4A CN111699584A (zh) | 2018-04-11 | 2018-04-11 | 电芯及锂离子电池 |
JP2020554875A JP7163404B2 (ja) | 2018-04-11 | 2018-04-11 | 電池セル及びリチウムイオン電池 |
PCT/CN2018/082717 WO2019196040A1 (zh) | 2018-04-11 | 2018-04-11 | 电芯及锂离子电池 |
EP18914898.4A EP3780236A4 (en) | 2018-04-11 | 2018-04-11 | BATTERY ELEMENT AND LITHIUM-ION BATTERY |
US17/065,089 US20210028497A1 (en) | 2018-04-11 | 2020-10-07 | Battery cell and lithium ion battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2018/082717 WO2019196040A1 (zh) | 2018-04-11 | 2018-04-11 | 电芯及锂离子电池 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US17/065,089 Continuation US20210028497A1 (en) | 2018-04-11 | 2020-10-07 | Battery cell and lithium ion battery |
Publications (1)
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WO2019196040A1 true WO2019196040A1 (zh) | 2019-10-17 |
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Family Applications (1)
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PCT/CN2018/082717 WO2019196040A1 (zh) | 2018-04-11 | 2018-04-11 | 电芯及锂离子电池 |
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Country | Link |
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US (1) | US20210028497A1 (zh) |
EP (1) | EP3780236A4 (zh) |
JP (1) | JP7163404B2 (zh) |
CN (1) | CN111699584A (zh) |
CA (1) | CA3095358C (zh) |
WO (1) | WO2019196040A1 (zh) |
Cited By (1)
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CN112117499A (zh) * | 2020-09-30 | 2020-12-22 | 珠海冠宇电池股份有限公司 | 电池及电池的制造方法 |
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CN113097570B (zh) * | 2021-03-26 | 2022-08-30 | 宁德新能源科技有限公司 | 卷绕电芯及用于其的极耳错位测量方法 |
CN114614211B (zh) * | 2022-03-22 | 2024-01-23 | 东莞新能安科技有限公司 | 电化学装置、电池模组以及电子装置 |
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JP4538694B2 (ja) * | 1999-06-02 | 2010-09-08 | 株式会社豊田中央研究所 | 電極捲回型電池 |
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KR101154872B1 (ko) * | 2010-01-12 | 2012-06-18 | 주식회사 엘지화학 | 신규한 구조의 전극조립체 |
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- 2018-04-11 EP EP18914898.4A patent/EP3780236A4/en active Pending
- 2018-04-11 JP JP2020554875A patent/JP7163404B2/ja active Active
- 2018-04-11 CA CA3095358A patent/CA3095358C/en active Active
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2020
- 2020-10-07 US US17/065,089 patent/US20210028497A1/en active Pending
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CA3095358C (en) | 2024-01-09 |
CN111699584A (zh) | 2020-09-22 |
EP3780236A1 (en) | 2021-02-17 |
EP3780236A4 (en) | 2021-04-21 |
US20210028497A1 (en) | 2021-01-28 |
CA3095358A1 (en) | 2019-10-17 |
JP7163404B2 (ja) | 2022-10-31 |
JP2021517726A (ja) | 2021-07-26 |
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