WO2019190220A1 - Composition cosmétique de démaquillage comprenant un tensioactif hydrosoluble et un tensioactif liposoluble - Google Patents

Composition cosmétique de démaquillage comprenant un tensioactif hydrosoluble et un tensioactif liposoluble Download PDF

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Publication number
WO2019190220A1
WO2019190220A1 PCT/KR2019/003632 KR2019003632W WO2019190220A1 WO 2019190220 A1 WO2019190220 A1 WO 2019190220A1 KR 2019003632 W KR2019003632 W KR 2019003632W WO 2019190220 A1 WO2019190220 A1 WO 2019190220A1
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WO
WIPO (PCT)
Prior art keywords
makeup
soluble surfactant
polyglyceryl
water
oil
Prior art date
Application number
PCT/KR2019/003632
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English (en)
Korean (ko)
Inventor
박효영
유현주
Original Assignee
주식회사 아모레퍼시픽
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020190032725A external-priority patent/KR20190114797A/ko
Application filed by 주식회사 아모레퍼시픽 filed Critical 주식회사 아모레퍼시픽
Priority to US17/043,548 priority Critical patent/US11904039B2/en
Priority to CN201980023453.7A priority patent/CN111936113A/zh
Publication of WO2019190220A1 publication Critical patent/WO2019190220A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up

Definitions

  • the present invention relates to a composition for removing makeup makeup comprising a water-soluble surfactant and an oil-soluble surfactant, and more particularly, a mixture of a water-soluble surfactant having an HLB (Hydrophile Lipophile Balance) value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less.
  • the present invention relates to a cosmetic composition for removing makeup having excellent removal effect of a makeup residue according to the use of a makeup product, including a composition as an active ingredient, and having an improved transparency effect and a feeling on the skin.
  • Cleansing cosmetics that clean the skin there are various products.
  • cleansing products that remove color cosmetic ingredients are cream, emulsion, liquid, and transparent gel, and emulsion type, oil type, and aqueous type. It is widely used depending on its characteristics.
  • Typical emulsion types are cleansing lotions and creams, and they are characterized by providing a cleansing effect by blending a large amount of nonionic surfactant with oil.
  • Emulsion type has 20 ⁇ 70% by weight of oily ingredient, so it has excellent cleansing effect and softness and massage effect when using.However, if it is difficult to remove with water due to oil residue on the skin after use, wipe off with tissue-off product.
  • the skin irritation is concerned by the physical stimulation according to the tissue-off product, there is a feeling of oil remains even after wiping with a tissue, there is an inconvenience that you have to wash the water using a foam cleansing soap.
  • Korean Unexamined Patent Publication No. 2003-0051972 has a surfactant-free additives cleansing composition comprising a small amount of oil
  • Korean Patent Publication No. 2002-0037206 has a oil-free oil-in-water makeup component It is proposed a cleansing composition to remove the.
  • it is difficult to remove makeup sufficiently with only a small amount of oil and in the latter case, there is a limitation in removing other makeup components in addition to silicone.
  • the present inventors improve the transparency of the composition while exhibiting an excellent removal (cleansing) effect on the makeup make-up compared to the conventional makeup makeup removal cosmetic composition containing only a water-soluble surfactant (hydrophilic surfactant) as a main component.
  • a cosmetic composition comprising a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less in a specific mixing ratio as an active ingredient is a makeup
  • the make-up (cleansing) effect on the makeup ingredients remaining on the skin due to the makeup is very excellent, and while improving the transparency of the composition does not contain an oil to provide a fresh feel and to improve the feeling and to complete the present invention.
  • An object of the present invention is to provide a cosmetic composition for removing makeup makeup excellent in makeup removal efficacy.
  • the present invention provides a cosmetic composition for removing makeup makeup comprising a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less as an active ingredient, preferably a water-soluble solution having an HLB value of 13 or more.
  • the surfactant and the oil-soluble surfactant having an HLB value of 12 or less are preferably mixed in a weight ratio of 3 to 20: 0.1 to 3.3, more preferably 4 to 17: 0.1 to 1.5, and most preferably 4.5 to 8: 0.2 to 1.3. It provides a cosmetic composition for removing makeup makeup comprising a mixture as an active ingredient.
  • the present invention also provides the use of a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less, more precisely, as a makeup make-up remover, in the manufacture of a cosmetic composition or cosmetic for removing makeup makeup. do.
  • the cosmetic composition for removing makeup makeup according to the present invention is excellent in the removal power (cleansing power) for the makeup product by containing a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less in a specific mixing ratio.
  • the turbidity of the composition is maintained at 15 NTU or less, so the transparency improvement effect of the cosmetic formulation is very excellent, and it does not contain oil, and it is neat and does not need double removal (washing / washing), and irritates the skin by using a small amount of surfactant. This feeling is very good.
  • Example 1 is a photograph showing an excellent makeup removal force, that is, a cleansing effect of the cosmetic composition for removing makeup makeup of Example 1 according to the present invention.
  • the term "about” as used to express length, area, volume, time (period), concentration, capacity (content, etc.), temperature, humidity, pressure, etc., is a tolerance of up to 10% in the value or range of values. Means that it exists.
  • the present invention relates to a cosmetic composition for removing makeup makeup comprising, as an active ingredient, a mixture of a water-soluble surfactant having an HLB (Hydrophile Lipophile Balance) value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less.
  • HLB Hydrophile Balance
  • the HLB value best represents the nature of the surfactant and essentially determines the nature of the system.
  • surfactants having an HLB value of 1.5 to 3 are antifoaming agents.
  • Surfactants having an HLB value of 4 to 6 are water-in-oil type ( Water in Oil (W / O emulsion) emulsifier, surfactants with HLB values of 7-9 are used as wetting agents, and surfactants with HLB values of 8-18 are used as oil in water (O / W emulsion) emulsifiers. It is common to be.
  • the HLB value of the water-soluble surfactant is 13 or more, most preferably 14 to 18, when the HLB value is less than 13, the removal effect (cleansing force) for the makeup and the effect of improving the transparency of the composition is not only slight. A water soluble composition cannot be made.
  • the water-soluble surfactant is polyglyceryl-6 caprylate (polyglyceryl-6 caprylate), polyglyceryl-10 laurate (polyglyceryl-10 laurate), Fiji-6 caprylic / capric glycerol Group consisting of PED-6 caprylic / capric glycerides, PEG-7 glyceryl cocoate, polysorbate 20, and disodium cocoamphodiacetate It may be characterized in that one or more selected from, preferably a mixture of polyglyceryl-6 caprylate (polyglyceryl-6 caprylate) and polyglyceryl-10 laurate (polyglyceryl-10 laurate).
  • the HLB value of the oil-soluble surfactant is 12 or less, more preferably 9 to 12, most preferably 10 to 12, the removal force for the makeup (cleansing force) when the HLB value exceeds 12 This can be reduced, and the effect of improving the transparency of the composition can be lowered.
  • the oil-soluble surfactant is polyglyceryl-10 diisostearate, polyglyceryl-2 laurate, polyglyceryl-2 sesquicaprylate ( polyglyceryl-2 sesquicaprylate, polyglyceryl-5 trioleate, polyglyceryl-10 dioleate, Fiji-20 glyceryl triisostearate (PEG-20 glyceryl) triisostearate, PEG-8 isostearate, PEG-8 glyceryl isostearate, PIG-20 glyceryl isostearate , Fiji-15 glyceryl isostearate (PEG-15 glyceryl isostearate), polysorbate 60 (polysorbate 60) and polysorbate 80 (polysorbate 80) may be characterized in that at least one member selected from the group consisting of , Preferably A poly glyceryl -10 di isostearate.
  • the composition may be prepared in an oil-in-water type (Oil in Water.O / W emulsion) or water-in-oil type (Water in Oil.W / O emulsion), and preferably prepared in an oil-in-water type emulsion method. .
  • Improving the transparency of the composition in the present invention means a transparent or translucent state of the formulation.
  • the turbidity nephelometric turbidity unit (NTU) of the composition is 15 or less, preferably 13 or less, most preferably 10 or less.
  • the mixture is a water-soluble surfactant and a water-soluble surfactant is preferably 3 to 20: 0.1 to 3.3, more preferably 4 to 17: 0.1 to 1.5, most preferably 4.5 to 8: 0.2 to 1.3 It is mixed by the weight ratio of. If the weight ratio is out of the removal force (cleansing force) for the makeup is reduced, the transparency improvement effect of the composition may be lowered.
  • the content of the water-soluble surfactant included in the composition while maintaining the weight ratio of the water-soluble surfactant and the oil-soluble surfactant is 1 to 40% by weight, preferably 3 to based on the total weight of the composition 20% by weight, more preferably 4 to 17% by weight, most preferably 4.5 to 8% by weight, and the content of the water-soluble surfactant is less than 1% by weight based on the total weight of the composition.
  • Cosmetics for removing makeup make-up as a removal effect (cleansing force) to the desired makeup and the effect of improving the transparency of the composition is insignificant, and when the content exceeds 40% by weight, the increase in effect is not large compared to the increase in content, and the formulation stability and feeling of use may be reduced. Can be.
  • the content of the oil-soluble surfactant included in the composition while maintaining the weight ratio of the water-soluble surfactant and the oil-soluble surfactant is 0.1 to 10% by weight, preferably 0.1 to 10 based on the total weight of the composition 3.3% by weight, more preferably 0.1 to 1.5% by weight, most preferably 0.2 to 1.3% by weight, and the content of the oil-soluble surfactant is less than 0.1% by weight based on the total weight of the composition
  • the removal power (cleansing power) to the desired makeup and the effect of improving the transparency of the composition are insignificant, and when the content exceeds 10% by weight, the increase in effect is not large compared to the increase in content, and the formulation stability and feeling of use may be reduced. Can be.
  • the composition is a moisturizer (polyol, etc.), oils, waxes, viscosity regulators, thickeners, pH regulators, fats, organic solvents, solubilizers, concentrations in consideration of the limit of use in accordance with the rules on cosmetic safety Agents, gelling agents, emollients, antioxidants, suspending agents, stabilizers, foaming agents, fragrances, water, ionic emulsifiers, nonionic emulsifiers, fillers, metal ion sequestrants, chelating agents, preservatives, vitamins, wetting It may further contain auxiliaries commonly used in the field of cosmetics or dermatology, such as agents, dyes, pigments, hydrophilic actives, lipophilic actives, lipid vesicles or any other ingredients commonly used in cosmetics. In addition, the composition of the present invention may further contain a skin absorption promoting substance to increase the skin condition improving effect.
  • the composition is not particularly limited in formulating, but softening longevity, astringent longevity, nourishing longevity, lotion, eye cream, nutrition cream, massage cream, cleansing cream, cleansing foam, cleansing water, powder, essence
  • It may be a cosmetic composition having a formulation, such as a pack.
  • the cosmetic composition of each of these formulations may contain various components formulated into conventional cosmetic compositions according to the various formulations described above or suitably for the end purpose, and the types and amounts of these components can be easily selected by those skilled in the art.
  • the makeup make-up is lipstick, lip gloss, lip balm, lip pencil, rouge, lip palette, pact, powder, blusher, twin cake, compact, powder pact, pressed powder, skin cover, foundation, concealer eye shadow, eyebrow , Eyeliner and mascara may be produced by applying one or more cosmetic formulations selected from the group consisting of skin, but is not limited thereto.
  • Example 1 Example 2
  • Example 3 Example 4
  • Example 5 Example 6
  • Example 7 Purified water to 100 to 100 to 100 to 100 to 100 to 100 to 100 Water soluble surfactant Polyglyceryl-6 caprylate 5 7 0 2 5 5 5
  • Oil-soluble surfactants Polyglyceryl-10 diisostearate One One One One - 0.5 One Polyglyceryl-10 dioleate - - - - One 0.5 -
  • Example 1 ⁇ 7 containing water-soluble surfactant and oil-soluble surfactant Cosmetics Composition
  • the water-soluble surfactant polyglyceryl-6 caprylate (HLB 15) and polyglyceryl-10 laurate (HLB 16) and the oil-soluble interface The active agents polyglyceryl-10 diisostearate (HLB 11) and polyglyceryl-10 dioleate (HLB 11.7) were used.
  • the preparation method of the cosmetic composition according to Comparative Example 1 of Table 2 was as follows.
  • the preparation method of the cosmetic composition according to Comparative Example 2 of Table 2 was as follows.
  • Polyglyceryl-6 caprylate using polyglyceryl-6 caprylate and polyglyceryl-10 laurate, which are water-soluble surfactants, were mixed in a weight ratio of polyglyceryl-10 laurate 5: 2. The mixture was prepared and then heated to a temperature of about 60 ° C. to dissolve.
  • the preparation method of the cosmetic composition according to Comparative Example 3 of Table 2 was as follows.
  • polyglyceryl-10 diisostearate 2: The mixture mixed in the weight ratio of 1 was prepared, and it melt
  • the preparation method of the cosmetic composition according to Comparative Example 4 of Table 2 was as follows.
  • the makeup cosmetics of mascara, lipstick and foundation which are commonly used for cosmetic purposes, were applied to white artificial leather by 0.02 g / 20 ⁇ L in 2 cm ⁇ 2 cm areas, and then dried for about 30 minutes.
  • the artificial leather coated with the makeup cosmetic was rubbed five times from top to bottom with a cotton ball (area: 3 cm x 4 cm) moistened with 2 g of the cosmetic composition of Examples 1 to 7 and Comparative Examples 1 to 4, and then to artificial leather.
  • Whether or not the applied makeup cosmetics were removed (cleansing power) was checked by visual and color difference meters.
  • the color difference meter measures the brightness level (L) with a value of 5.00 to 99.99 AU (arbitrary unit), and when the brightness level is 70 AU or more (the level of the cosmetic removal effect can be seen with the naked eye), Evaluated as high.
  • Example 1 The cosmetic composition of Example 1 was found to have an excellent cleansing effect on three makeup cosmetics applied to artificial leather, namely foundation, lipstick and mascara;
  • Comparative Example 1 had only a cleansing effect on mascara applied to artificial leather, and the cosmetic composition of Comparative Example 2 was confirmed to have little cleansing effect on foundation, lipstick and mascara applied to artificial leather.
  • the cosmetic composition of Examples 2 to 7 exhibits a similar cleansing effect to the cosmetic composition of Example 1, that is, a cleansing effect on foundation, lipstick, and mascara applied to artificial leather. (Not shown).
  • the cosmetic composition of Examples 1, 2, 5 and 6 has a brightening degree of 70 AU or more in artificial leather coated with three makeup cosmetics, namely, foundation, lipstick, and mascara, so the cleansing effect is very excellent. It was done;
  • Comparative Example 2 The cosmetic composition of Comparative Example 2 was found to have almost no cleansing effect as the brightness degree was less than 70 AU in artificial leather applied with foundation, lipstick and mascara.
  • Example 2 Example 3
  • Example 4 Example 5
  • Example 6 Example 7 foundation 87.3 83.8 72.8 75.4 86.8 81.6 71.7 lipstick 76.9 70.3 58.3 68.5 71.0 74.6 60.4 Mascara 84.2 83.0 78.8 80.9 84.8 83.3 71.3
  • the cleansing power is improved, and in particular, the water-soluble surfactant having an HLB value of 13 or more and the oil-soluble surfactant having an HLB value of 12 or less are identified in the present invention.
  • Cosmetic compositions (Examples 1 to 7) comprising a mixture mixed in a weight ratio of 7: 1 or 5: 1 within the defined content range was confirmed that the cosmetic removal effect is significantly increased.
  • Example 3 The cosmetic composition of Example 3 and Example 4 was very excellent in turbidity reduction effect
  • Example 1 The cosmetic composition of Example 1, Example 2, Example 5, Example 6, and Example 7 was excellent in turbidity reduction effect;
  • the transparency of the composition is improved as the turbidity decreases, and in particular, the water-soluble surfactant having an HLB value of 13 or more and the oil-soluble surfactant having an HLB value of 12 or less
  • the cosmetic composition comprising a mixture mixed in a weight ratio of 7: 1 or 5: 1 within the content range defined and defined in the present invention not only improves transparency due to turbidity reduction, but also as described in Test Example 1 for makeup cosmetics It was confirmed that the cleansing effect also increased significantly.
  • Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Turbidity (NTU) 8.6 7.83 6.36 6.21 7.71 7.64 8.45

Abstract

La présente invention concerne une composition cosmétique de démaquillage comprenant un tensioactif hydrosoluble et un tensioactif liposoluble et, plus spécifiquement, une composition cosmétique de démaquillage qui comprend, en tant que principe actif, un mélange d'un tensioactif hydrosoluble dont la valeur d'équilibre hydrophile-lipophile (HLB) est supérieure ou égale à 13 et d'un tensioactif liposoluble dont la valeur d'HLB est inférieure ou égale à 12 et qui peut éliminer remarquablement les résidus de maquillage résultant de l'utilisation d'un produit de maquillage, améliorer remarquablement la clarté de la composition et être très agréable à utiliser sur la peau.
PCT/KR2019/003632 2018-03-30 2019-03-28 Composition cosmétique de démaquillage comprenant un tensioactif hydrosoluble et un tensioactif liposoluble WO2019190220A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US17/043,548 US11904039B2 (en) 2018-03-30 2019-03-28 Cosmetic composition for makeup removal comprising water-soluble surfactant and oil-soluble surfactant
CN201980023453.7A CN111936113A (zh) 2018-03-30 2019-03-28 含有水溶性表面活性剂以及油溶性表面活性剂的彩妆妆容去除用化妆料组合物

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20180037438 2018-03-30
KR10-2018-0037438 2018-03-30
KR10-2019-0032725 2019-03-22
KR1020190032725A KR20190114797A (ko) 2018-03-30 2019-03-22 수용성 계면활성제 및 유용성 계면활성제를 포함하는 메이크업 화장 제거용 화장료 조성물

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WO2019190220A1 true WO2019190220A1 (fr) 2019-10-03

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006022061A (ja) * 2004-07-09 2006-01-26 Kanebo Ltd 透明状クレンジング化粧料
KR20100014247A (ko) * 2007-03-29 2010-02-10 가부시키가이샤 시세이도 수중유형 유화 조성물
JP2011126809A (ja) * 2009-12-17 2011-06-30 Kao Corp クレンジング化粧料
JP2012214404A (ja) * 2011-03-31 2012-11-08 Nof Corp クレンジング料
JP2014091734A (ja) * 2012-11-06 2014-05-19 Nof Corp クレンジングクリーム

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006022061A (ja) * 2004-07-09 2006-01-26 Kanebo Ltd 透明状クレンジング化粧料
KR20100014247A (ko) * 2007-03-29 2010-02-10 가부시키가이샤 시세이도 수중유형 유화 조성물
JP2011126809A (ja) * 2009-12-17 2011-06-30 Kao Corp クレンジング化粧料
JP2012214404A (ja) * 2011-03-31 2012-11-08 Nof Corp クレンジング料
JP2014091734A (ja) * 2012-11-06 2014-05-19 Nof Corp クレンジングクリーム

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