WO2019190220A1 - Cosmetic composition for makeup removal comprising water-soluble surfactant and oil-soluble surfactant - Google Patents

Cosmetic composition for makeup removal comprising water-soluble surfactant and oil-soluble surfactant Download PDF

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Publication number
WO2019190220A1
WO2019190220A1 PCT/KR2019/003632 KR2019003632W WO2019190220A1 WO 2019190220 A1 WO2019190220 A1 WO 2019190220A1 KR 2019003632 W KR2019003632 W KR 2019003632W WO 2019190220 A1 WO2019190220 A1 WO 2019190220A1
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WO
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Prior art keywords
makeup
soluble surfactant
polyglyceryl
water
oil
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PCT/KR2019/003632
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French (fr)
Korean (ko)
Inventor
박효영
유현주
Original Assignee
주식회사 아모레퍼시픽
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Priority claimed from KR1020190032725A external-priority patent/KR20190114797A/en
Application filed by 주식회사 아모레퍼시픽 filed Critical 주식회사 아모레퍼시픽
Priority to US17/043,548 priority Critical patent/US11904039B2/en
Priority to CN201980023453.7A priority patent/CN111936113A/en
Publication of WO2019190220A1 publication Critical patent/WO2019190220A1/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up

Definitions

  • the present invention relates to a composition for removing makeup makeup comprising a water-soluble surfactant and an oil-soluble surfactant, and more particularly, a mixture of a water-soluble surfactant having an HLB (Hydrophile Lipophile Balance) value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less.
  • the present invention relates to a cosmetic composition for removing makeup having excellent removal effect of a makeup residue according to the use of a makeup product, including a composition as an active ingredient, and having an improved transparency effect and a feeling on the skin.
  • Cleansing cosmetics that clean the skin there are various products.
  • cleansing products that remove color cosmetic ingredients are cream, emulsion, liquid, and transparent gel, and emulsion type, oil type, and aqueous type. It is widely used depending on its characteristics.
  • Typical emulsion types are cleansing lotions and creams, and they are characterized by providing a cleansing effect by blending a large amount of nonionic surfactant with oil.
  • Emulsion type has 20 ⁇ 70% by weight of oily ingredient, so it has excellent cleansing effect and softness and massage effect when using.However, if it is difficult to remove with water due to oil residue on the skin after use, wipe off with tissue-off product.
  • the skin irritation is concerned by the physical stimulation according to the tissue-off product, there is a feeling of oil remains even after wiping with a tissue, there is an inconvenience that you have to wash the water using a foam cleansing soap.
  • Korean Unexamined Patent Publication No. 2003-0051972 has a surfactant-free additives cleansing composition comprising a small amount of oil
  • Korean Patent Publication No. 2002-0037206 has a oil-free oil-in-water makeup component It is proposed a cleansing composition to remove the.
  • it is difficult to remove makeup sufficiently with only a small amount of oil and in the latter case, there is a limitation in removing other makeup components in addition to silicone.
  • the present inventors improve the transparency of the composition while exhibiting an excellent removal (cleansing) effect on the makeup make-up compared to the conventional makeup makeup removal cosmetic composition containing only a water-soluble surfactant (hydrophilic surfactant) as a main component.
  • a cosmetic composition comprising a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less in a specific mixing ratio as an active ingredient is a makeup
  • the make-up (cleansing) effect on the makeup ingredients remaining on the skin due to the makeup is very excellent, and while improving the transparency of the composition does not contain an oil to provide a fresh feel and to improve the feeling and to complete the present invention.
  • An object of the present invention is to provide a cosmetic composition for removing makeup makeup excellent in makeup removal efficacy.
  • the present invention provides a cosmetic composition for removing makeup makeup comprising a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less as an active ingredient, preferably a water-soluble solution having an HLB value of 13 or more.
  • the surfactant and the oil-soluble surfactant having an HLB value of 12 or less are preferably mixed in a weight ratio of 3 to 20: 0.1 to 3.3, more preferably 4 to 17: 0.1 to 1.5, and most preferably 4.5 to 8: 0.2 to 1.3. It provides a cosmetic composition for removing makeup makeup comprising a mixture as an active ingredient.
  • the present invention also provides the use of a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less, more precisely, as a makeup make-up remover, in the manufacture of a cosmetic composition or cosmetic for removing makeup makeup. do.
  • the cosmetic composition for removing makeup makeup according to the present invention is excellent in the removal power (cleansing power) for the makeup product by containing a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less in a specific mixing ratio.
  • the turbidity of the composition is maintained at 15 NTU or less, so the transparency improvement effect of the cosmetic formulation is very excellent, and it does not contain oil, and it is neat and does not need double removal (washing / washing), and irritates the skin by using a small amount of surfactant. This feeling is very good.
  • Example 1 is a photograph showing an excellent makeup removal force, that is, a cleansing effect of the cosmetic composition for removing makeup makeup of Example 1 according to the present invention.
  • the term "about” as used to express length, area, volume, time (period), concentration, capacity (content, etc.), temperature, humidity, pressure, etc., is a tolerance of up to 10% in the value or range of values. Means that it exists.
  • the present invention relates to a cosmetic composition for removing makeup makeup comprising, as an active ingredient, a mixture of a water-soluble surfactant having an HLB (Hydrophile Lipophile Balance) value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less.
  • HLB Hydrophile Balance
  • the HLB value best represents the nature of the surfactant and essentially determines the nature of the system.
  • surfactants having an HLB value of 1.5 to 3 are antifoaming agents.
  • Surfactants having an HLB value of 4 to 6 are water-in-oil type ( Water in Oil (W / O emulsion) emulsifier, surfactants with HLB values of 7-9 are used as wetting agents, and surfactants with HLB values of 8-18 are used as oil in water (O / W emulsion) emulsifiers. It is common to be.
  • the HLB value of the water-soluble surfactant is 13 or more, most preferably 14 to 18, when the HLB value is less than 13, the removal effect (cleansing force) for the makeup and the effect of improving the transparency of the composition is not only slight. A water soluble composition cannot be made.
  • the water-soluble surfactant is polyglyceryl-6 caprylate (polyglyceryl-6 caprylate), polyglyceryl-10 laurate (polyglyceryl-10 laurate), Fiji-6 caprylic / capric glycerol Group consisting of PED-6 caprylic / capric glycerides, PEG-7 glyceryl cocoate, polysorbate 20, and disodium cocoamphodiacetate It may be characterized in that one or more selected from, preferably a mixture of polyglyceryl-6 caprylate (polyglyceryl-6 caprylate) and polyglyceryl-10 laurate (polyglyceryl-10 laurate).
  • the HLB value of the oil-soluble surfactant is 12 or less, more preferably 9 to 12, most preferably 10 to 12, the removal force for the makeup (cleansing force) when the HLB value exceeds 12 This can be reduced, and the effect of improving the transparency of the composition can be lowered.
  • the oil-soluble surfactant is polyglyceryl-10 diisostearate, polyglyceryl-2 laurate, polyglyceryl-2 sesquicaprylate ( polyglyceryl-2 sesquicaprylate, polyglyceryl-5 trioleate, polyglyceryl-10 dioleate, Fiji-20 glyceryl triisostearate (PEG-20 glyceryl) triisostearate, PEG-8 isostearate, PEG-8 glyceryl isostearate, PIG-20 glyceryl isostearate , Fiji-15 glyceryl isostearate (PEG-15 glyceryl isostearate), polysorbate 60 (polysorbate 60) and polysorbate 80 (polysorbate 80) may be characterized in that at least one member selected from the group consisting of , Preferably A poly glyceryl -10 di isostearate.
  • the composition may be prepared in an oil-in-water type (Oil in Water.O / W emulsion) or water-in-oil type (Water in Oil.W / O emulsion), and preferably prepared in an oil-in-water type emulsion method. .
  • Improving the transparency of the composition in the present invention means a transparent or translucent state of the formulation.
  • the turbidity nephelometric turbidity unit (NTU) of the composition is 15 or less, preferably 13 or less, most preferably 10 or less.
  • the mixture is a water-soluble surfactant and a water-soluble surfactant is preferably 3 to 20: 0.1 to 3.3, more preferably 4 to 17: 0.1 to 1.5, most preferably 4.5 to 8: 0.2 to 1.3 It is mixed by the weight ratio of. If the weight ratio is out of the removal force (cleansing force) for the makeup is reduced, the transparency improvement effect of the composition may be lowered.
  • the content of the water-soluble surfactant included in the composition while maintaining the weight ratio of the water-soluble surfactant and the oil-soluble surfactant is 1 to 40% by weight, preferably 3 to based on the total weight of the composition 20% by weight, more preferably 4 to 17% by weight, most preferably 4.5 to 8% by weight, and the content of the water-soluble surfactant is less than 1% by weight based on the total weight of the composition.
  • Cosmetics for removing makeup make-up as a removal effect (cleansing force) to the desired makeup and the effect of improving the transparency of the composition is insignificant, and when the content exceeds 40% by weight, the increase in effect is not large compared to the increase in content, and the formulation stability and feeling of use may be reduced. Can be.
  • the content of the oil-soluble surfactant included in the composition while maintaining the weight ratio of the water-soluble surfactant and the oil-soluble surfactant is 0.1 to 10% by weight, preferably 0.1 to 10 based on the total weight of the composition 3.3% by weight, more preferably 0.1 to 1.5% by weight, most preferably 0.2 to 1.3% by weight, and the content of the oil-soluble surfactant is less than 0.1% by weight based on the total weight of the composition
  • the removal power (cleansing power) to the desired makeup and the effect of improving the transparency of the composition are insignificant, and when the content exceeds 10% by weight, the increase in effect is not large compared to the increase in content, and the formulation stability and feeling of use may be reduced. Can be.
  • the composition is a moisturizer (polyol, etc.), oils, waxes, viscosity regulators, thickeners, pH regulators, fats, organic solvents, solubilizers, concentrations in consideration of the limit of use in accordance with the rules on cosmetic safety Agents, gelling agents, emollients, antioxidants, suspending agents, stabilizers, foaming agents, fragrances, water, ionic emulsifiers, nonionic emulsifiers, fillers, metal ion sequestrants, chelating agents, preservatives, vitamins, wetting It may further contain auxiliaries commonly used in the field of cosmetics or dermatology, such as agents, dyes, pigments, hydrophilic actives, lipophilic actives, lipid vesicles or any other ingredients commonly used in cosmetics. In addition, the composition of the present invention may further contain a skin absorption promoting substance to increase the skin condition improving effect.
  • the composition is not particularly limited in formulating, but softening longevity, astringent longevity, nourishing longevity, lotion, eye cream, nutrition cream, massage cream, cleansing cream, cleansing foam, cleansing water, powder, essence
  • It may be a cosmetic composition having a formulation, such as a pack.
  • the cosmetic composition of each of these formulations may contain various components formulated into conventional cosmetic compositions according to the various formulations described above or suitably for the end purpose, and the types and amounts of these components can be easily selected by those skilled in the art.
  • the makeup make-up is lipstick, lip gloss, lip balm, lip pencil, rouge, lip palette, pact, powder, blusher, twin cake, compact, powder pact, pressed powder, skin cover, foundation, concealer eye shadow, eyebrow , Eyeliner and mascara may be produced by applying one or more cosmetic formulations selected from the group consisting of skin, but is not limited thereto.
  • Example 1 Example 2
  • Example 3 Example 4
  • Example 5 Example 6
  • Example 7 Purified water to 100 to 100 to 100 to 100 to 100 to 100 to 100 Water soluble surfactant Polyglyceryl-6 caprylate 5 7 0 2 5 5 5
  • Oil-soluble surfactants Polyglyceryl-10 diisostearate One One One One - 0.5 One Polyglyceryl-10 dioleate - - - - One 0.5 -
  • Example 1 ⁇ 7 containing water-soluble surfactant and oil-soluble surfactant Cosmetics Composition
  • the water-soluble surfactant polyglyceryl-6 caprylate (HLB 15) and polyglyceryl-10 laurate (HLB 16) and the oil-soluble interface The active agents polyglyceryl-10 diisostearate (HLB 11) and polyglyceryl-10 dioleate (HLB 11.7) were used.
  • the preparation method of the cosmetic composition according to Comparative Example 1 of Table 2 was as follows.
  • the preparation method of the cosmetic composition according to Comparative Example 2 of Table 2 was as follows.
  • Polyglyceryl-6 caprylate using polyglyceryl-6 caprylate and polyglyceryl-10 laurate, which are water-soluble surfactants, were mixed in a weight ratio of polyglyceryl-10 laurate 5: 2. The mixture was prepared and then heated to a temperature of about 60 ° C. to dissolve.
  • the preparation method of the cosmetic composition according to Comparative Example 3 of Table 2 was as follows.
  • polyglyceryl-10 diisostearate 2: The mixture mixed in the weight ratio of 1 was prepared, and it melt
  • the preparation method of the cosmetic composition according to Comparative Example 4 of Table 2 was as follows.
  • the makeup cosmetics of mascara, lipstick and foundation which are commonly used for cosmetic purposes, were applied to white artificial leather by 0.02 g / 20 ⁇ L in 2 cm ⁇ 2 cm areas, and then dried for about 30 minutes.
  • the artificial leather coated with the makeup cosmetic was rubbed five times from top to bottom with a cotton ball (area: 3 cm x 4 cm) moistened with 2 g of the cosmetic composition of Examples 1 to 7 and Comparative Examples 1 to 4, and then to artificial leather.
  • Whether or not the applied makeup cosmetics were removed (cleansing power) was checked by visual and color difference meters.
  • the color difference meter measures the brightness level (L) with a value of 5.00 to 99.99 AU (arbitrary unit), and when the brightness level is 70 AU or more (the level of the cosmetic removal effect can be seen with the naked eye), Evaluated as high.
  • Example 1 The cosmetic composition of Example 1 was found to have an excellent cleansing effect on three makeup cosmetics applied to artificial leather, namely foundation, lipstick and mascara;
  • Comparative Example 1 had only a cleansing effect on mascara applied to artificial leather, and the cosmetic composition of Comparative Example 2 was confirmed to have little cleansing effect on foundation, lipstick and mascara applied to artificial leather.
  • the cosmetic composition of Examples 2 to 7 exhibits a similar cleansing effect to the cosmetic composition of Example 1, that is, a cleansing effect on foundation, lipstick, and mascara applied to artificial leather. (Not shown).
  • the cosmetic composition of Examples 1, 2, 5 and 6 has a brightening degree of 70 AU or more in artificial leather coated with three makeup cosmetics, namely, foundation, lipstick, and mascara, so the cleansing effect is very excellent. It was done;
  • Comparative Example 2 The cosmetic composition of Comparative Example 2 was found to have almost no cleansing effect as the brightness degree was less than 70 AU in artificial leather applied with foundation, lipstick and mascara.
  • Example 2 Example 3
  • Example 4 Example 5
  • Example 6 Example 7 foundation 87.3 83.8 72.8 75.4 86.8 81.6 71.7 lipstick 76.9 70.3 58.3 68.5 71.0 74.6 60.4 Mascara 84.2 83.0 78.8 80.9 84.8 83.3 71.3
  • the cleansing power is improved, and in particular, the water-soluble surfactant having an HLB value of 13 or more and the oil-soluble surfactant having an HLB value of 12 or less are identified in the present invention.
  • Cosmetic compositions (Examples 1 to 7) comprising a mixture mixed in a weight ratio of 7: 1 or 5: 1 within the defined content range was confirmed that the cosmetic removal effect is significantly increased.
  • Example 3 The cosmetic composition of Example 3 and Example 4 was very excellent in turbidity reduction effect
  • Example 1 The cosmetic composition of Example 1, Example 2, Example 5, Example 6, and Example 7 was excellent in turbidity reduction effect;
  • the transparency of the composition is improved as the turbidity decreases, and in particular, the water-soluble surfactant having an HLB value of 13 or more and the oil-soluble surfactant having an HLB value of 12 or less
  • the cosmetic composition comprising a mixture mixed in a weight ratio of 7: 1 or 5: 1 within the content range defined and defined in the present invention not only improves transparency due to turbidity reduction, but also as described in Test Example 1 for makeup cosmetics It was confirmed that the cleansing effect also increased significantly.
  • Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Turbidity (NTU) 8.6 7.83 6.36 6.21 7.71 7.64 8.45

Abstract

The present invention relates to a cosmetic composition for makeup removal comprising a water-soluble surfactant and an oil-soluble surfactant and, more specifically, to a cosmetic composition for makeup removal which comprises, as an active ingredient, a mixture of a water-soluble surfactant having a hydrophile-lipophile balance (HLB) value of at least 13 and an oil-soluble surfactant having an HLB value of at most 12, and which can excellently remove makeup residues resulting from using a makeup product, can excellently improve the clarity of the composition, and feels excellent to use on the skin.

Description

수용성 계면활성제 및 유용성 계면활성제를 포함하는 메이크업 화장 제거용 화장료 조성물Cosmetic composition for removing makeup makeup comprising a water-soluble surfactant and an oil-soluble surfactant
본 발명은 수용성 계면활성제 및 유용성 계면활성제를 포함하는 메이크업 화장 제거용 조성물에 관한 것으로, 더욱 상세하게는 HLB(Hydrophile Lipophile Balance) 값이 13 이상인 수용성 계면활성제와 HLB 값이 12 이하인 유용성 계면활성제의 혼합물을 유효성분으로 포함하는, 메이크업 제품 사용에 따른 메이크업 잔류물의 제거 효능이 우수하고, 조성물의 투명도 향상 효과 및 피부에 대한 사용감이 우수한 메이크업 화장 제거용 화장료 조성물에 관한 것이다. The present invention relates to a composition for removing makeup makeup comprising a water-soluble surfactant and an oil-soluble surfactant, and more particularly, a mixture of a water-soluble surfactant having an HLB (Hydrophile Lipophile Balance) value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less. The present invention relates to a cosmetic composition for removing makeup having excellent removal effect of a makeup residue according to the use of a makeup product, including a composition as an active ingredient, and having an improved transparency effect and a feeling on the skin.
피부를 청결히 하는 클렌징 화장료로 다양한 제품이 있으며, 일반적으로 색조 화장 성분을 지우는 클렌징 제품은, 성상별로는 크림상, 유액상, 액상, 투명 젤상이 있으며, 타입별로는 에멀젼 타입, 유성타입, 수성타입이 있어, 그 특성에 따라 다양하게 이용되고 있다.Cleansing cosmetics that clean the skin, there are various products. In general, cleansing products that remove color cosmetic ingredients are cream, emulsion, liquid, and transparent gel, and emulsion type, oil type, and aqueous type. It is widely used depending on its characteristics.
에멀젼 타입으로는 클렌징 로션과 크림이 대표적이며, 이들은 다량의 오일에 비이온 계면활성제를 배합함으로써 클렌징 효과를 부여함을 특징으로 하고 있다. 에멀젼 타입은 유성성분이 20~70중량%를 차지하고 있어, 클렌징 효과가 우수하고 사용 시 부드러움과 마사지 효과가 뛰어난 장점이 있지만, 사용 후 피부에 오일 잔류량이 많아 물로 제거하기 어려우면 티슈오프 제품으로 닦아내어야 하는 단점이 있다. 또한, 티슈오프 제품에 따른 물리적 자극에 의해 피부자극이 우려되며, 티슈로 닦아낸 후에도 유분감이 남아있어 폼클렌징인 비누를 사용하여 수성세안을 해야만 하는 불편함이 있다.Typical emulsion types are cleansing lotions and creams, and they are characterized by providing a cleansing effect by blending a large amount of nonionic surfactant with oil. Emulsion type has 20 ~ 70% by weight of oily ingredient, so it has excellent cleansing effect and softness and massage effect when using.However, if it is difficult to remove with water due to oil residue on the skin after use, wipe off with tissue-off product. There are disadvantages that should In addition, the skin irritation is concerned by the physical stimulation according to the tissue-off product, there is a feeling of oil remains even after wiping with a tissue, there is an inconvenience that you have to wash the water using a foam cleansing soap.
상기한 문제점들을 해결하기 위한 방안으로, 대한민국 공개특허 제2003-0051972호에서는 소량의 오일을 포함하는 계면활성제 무첨가성 클렌징 조성물을, 대한민국 공개특허 제2002-0037206호에서는 오일-프리형 수중유 메이크업 성분을 제거하는 클렌징 조성물을 제안하고 있다. 그러나, 전자의 발명에서 실제 소량의 오일만으로는 메이크업을 충분히 제거하기 어려우며, 후자의 경우 실리콘 이외에 다른 메이크업 성분을 제거하기에는 한계가 있는 실정이다.In order to solve the above problems, Korean Unexamined Patent Publication No. 2003-0051972 has a surfactant-free additives cleansing composition comprising a small amount of oil, Korean Patent Publication No. 2002-0037206 has a oil-free oil-in-water makeup component It is proposed a cleansing composition to remove the. However, in the former invention, it is difficult to remove makeup sufficiently with only a small amount of oil, and in the latter case, there is a limitation in removing other makeup components in addition to silicone.
이러한 메이크업 화장을 효과적으로 제거하기 위한 클렌징 화장료를 개발하려는 연구는 활발하게 진행되고 있지만, 이중 세안이 필요하지 않으면서 자극이 최소화되고 클렌징력 또한 우수한 클렌징 화장료의 개발의 진행 상황은 아직까지 미비한 상태이다.Research into developing cleansing cosmetics to effectively remove such makeup cosmetics is being actively conducted, but the progress of the development of cleansing cosmetics with minimal stimulation and excellent cleansing power without the need for facial cleansing is still incomplete.
아울러, 일반적으로 종래의 계면활성제를 이용한 안정한 수중유 에멀젼을 만들기 위해서는 계면활성제가 수상/유상 계면에 흡착하여 액정을 형성하는 것이 필요하며, 이를 위해 유상의 극성에 따라 사용될 계면활성제의 HLB(Hydrophile Lipophile Balance) 값을 주의 깊게 조정해야 한다. 더욱이, HLB 값을 조정하는 경우에도 오일 구조에 따라 적절한 유화제를 선택해야 하는 경우가 많아 그 선택에 많은 어려움이 있다.In addition, generally, in order to make a stable oil-in-water emulsion using a conventional surfactant, it is necessary to form a liquid crystal by adsorbing the surfactant to an aqueous / oil phase interface. Balance value should be carefully adjusted. Moreover, even when adjusting the HLB value, it is often necessary to select an appropriate emulsifier according to the oil structure, and there are many difficulties in the selection.
이러한 기술적 배경하에서, 본 발명자들은 수용성 계면활성제(친수성 계면활성제)만을 주성분으로서 포함하는 기존 메이크업 화장 제거용 화장료 조성물과 비교하여 메이크업 화장에 대한 우수한 제거(클렌징) 효과를 발휘하면서, 조성물의 투명도를 향상시킬 수 있는 화장료 조성물을 개발하고자 예의 노력한 결과, 본 발명에 따른 HLB 값이 13 이상인 수용성 계면활성제와 HLB 값이 12 이하인 유용성 계면활성제를 특정 혼합비로 혼합한 혼합물을 유효성분으로 포함하는 화장료 조성물은 메이크업 화장으로 인해 피부에 잔존하는 메이크업 성분에 대한 제거(클렌징) 효과가 매우 우수하고, 조성물의 투명도를 향상시키면서도 오일을 함유하지 않아 산뜻한 감촉감을 제공하여 사용감이 개선됨을 확인하고 본 발명을 완성하게 되었다.Under this technical background, the present inventors improve the transparency of the composition while exhibiting an excellent removal (cleansing) effect on the makeup make-up compared to the conventional makeup makeup removal cosmetic composition containing only a water-soluble surfactant (hydrophilic surfactant) as a main component. As a result of intensive efforts to develop a cosmetic composition that can be made, a cosmetic composition comprising a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less in a specific mixing ratio as an active ingredient is a makeup The make-up (cleansing) effect on the makeup ingredients remaining on the skin due to the makeup is very excellent, and while improving the transparency of the composition does not contain an oil to provide a fresh feel and to improve the feeling and to complete the present invention.
[선행기술문헌][Preceding technical literature]
[특허문헌][Patent Documents]
대한민국 공개특허 제2003-0051972호(2003년 6월 26일)Republic of Korea Patent Publication No. 2003-0051972 (June 26, 2003)
대한민국 공개특허 제2002-0037206호(2002년 5월 18일)Republic of Korea Patent Publication No. 2002-0037206 (May 18, 2002)
본 발명의 목적은 메이크업 제거 효능이 우수한 메이크업 화장 제거용 화장료 조성물을 제공하는 데 있다.An object of the present invention is to provide a cosmetic composition for removing makeup makeup excellent in makeup removal efficacy.
상기 목적을 달성하기 위해 본 발명은 HLB 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제의 혼합물을 유효성분으로 포함하는 메이크업 화장 제거용 화장료 조성물, 바람직하게는 HLB 값이 13 이상인 수용성 계면활성제와 HLB 값이 12 이하인 유용성 계면활성제를 바람직하게는 3~20 : 0.1~3.3, 더욱 바람직하게는 4~17 : 0.1~1.5, 가장 바람직하게는 4.5~8 : 0.2~1.3의 중량비로 혼합한 혼합물을 유효성분으로 포함하는 메이크업 화장 제거용 화장료 조성물을 제공한다.In order to achieve the above object, the present invention provides a cosmetic composition for removing makeup makeup comprising a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less as an active ingredient, preferably a water-soluble solution having an HLB value of 13 or more. The surfactant and the oil-soluble surfactant having an HLB value of 12 or less are preferably mixed in a weight ratio of 3 to 20: 0.1 to 3.3, more preferably 4 to 17: 0.1 to 1.5, and most preferably 4.5 to 8: 0.2 to 1.3. It provides a cosmetic composition for removing makeup makeup comprising a mixture as an active ingredient.
본 발명은 또한, 메이크업 화장 제거용 화장료 조성물 또는 화장품의 제조에 있어서, HLB 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제의 혼합물의 용도, 더 정확하게는 메이크업 화장 제거제로서의 용도를 제공한다.The present invention also provides the use of a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less, more precisely, as a makeup make-up remover, in the manufacture of a cosmetic composition or cosmetic for removing makeup makeup. do.
본 발명에 따른 메이크업 화장 제거용 화장료 조성물은 HLB 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제를 특정 혼합비로 혼합한 혼합물을 함유함으로써 메이크업 제품에 대한 제거력(클렌징력)이 우수하고, 조성물의 탁도가 15 NTU 이하로 유지시켜 화장료 제형의 투명도 향상 효과가 매우 우수하며, 오일을 함유하지 않아 산뜻하고 이중 제거(세정/세안)가 필요하지 않고, 소량의 계면활성제 사용으로 피부에 대한 자극이 적어 사용감이 매우 우수하다.The cosmetic composition for removing makeup makeup according to the present invention is excellent in the removal power (cleansing power) for the makeup product by containing a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less in a specific mixing ratio. , The turbidity of the composition is maintained at 15 NTU or less, so the transparency improvement effect of the cosmetic formulation is very excellent, and it does not contain oil, and it is neat and does not need double removal (washing / washing), and irritates the skin by using a small amount of surfactant. This feeling is very good.
도 1은 본 발명에 따른 실시예 1의 메이크업 화장 제거용 화장료 조성물의 우수한 화장 제거력, 즉 클렌징 효과를 나타낸 사진이다.1 is a photograph showing an excellent makeup removal force, that is, a cleansing effect of the cosmetic composition for removing makeup makeup of Example 1 according to the present invention.
다른 식으로 정의되지 않는 한, 본 명세서에서 사용된 모든 기술적 및 과학적 용어들은 본 발명이 속하는 기술분야에서 숙련된 전문가에 의해서 통상적으로 이해되는 것과 동일한 의미를 갖는다. 일반적으로 본 명세서에서 사용된 명명법은 본 기술분야에서 잘 알려져 있고 통상적으로 사용되는 것이다.Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In general, the nomenclature used herein is well known and commonly used in the art.
이하, 본 발명에 대하여 보다 구체적으로 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated more concretely.
본 명세서에서 길이, 면적, 부피, 시간(기간), 농도, 용량(함량 등), 온도, 습도, 압력 등을 표현하는데 사용된 용어 "약"은 해당 수치 또는 수치 범위에서 최대 10%의 허용오차가 존재한다는 것을 의미한다.As used herein, the term "about" as used to express length, area, volume, time (period), concentration, capacity (content, etc.), temperature, humidity, pressure, etc., is a tolerance of up to 10% in the value or range of values. Means that it exists.
본 발명은 일 관점에서, HLB(Hydrophile Lipophile Balance) 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제의 혼합물을 유효성분으로 포함하는 메이크업 화장 제거용 화장료 조성물에 관한 것이다.The present invention relates to a cosmetic composition for removing makeup makeup comprising, as an active ingredient, a mixture of a water-soluble surfactant having an HLB (Hydrophile Lipophile Balance) value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less.
HLB 값은 계면활성제의 성질을 가장 잘 나타내며, 본질적으로 그 계의 성질을 결정하는 것으로서 일반적으로 HLB 값이 1.5~3인 계면활성제는 소포제로, HLB 값이 4~6인 계면활성제는 유중수형(Water in Oil; W/O emulsion) 유화제로, HLB 값이 7~9인 계면활성제는 습윤제로, HLB 값이 8~18인 계면활성제는 수중유형(Oil in Water; O/W emulsion) 유화제로 사용되는 것이 일반적이다.The HLB value best represents the nature of the surfactant and essentially determines the nature of the system. In general, surfactants having an HLB value of 1.5 to 3 are antifoaming agents. Surfactants having an HLB value of 4 to 6 are water-in-oil type ( Water in Oil (W / O emulsion) emulsifier, surfactants with HLB values of 7-9 are used as wetting agents, and surfactants with HLB values of 8-18 are used as oil in water (O / W emulsion) emulsifiers. It is common to be.
본 발명에 있어서, 상기 수용성 계면활성제의 HLB 값은 13 이상, 가장 바람직하게는 14~18이며, 상기 HLB 값이 13 미만이면 화장에 대한 제거력(클렌징력) 및 조성물의 투명도 향상 효과가 미미할 뿐 아니라 수용성 조성물을 만들 수 없다.In the present invention, the HLB value of the water-soluble surfactant is 13 or more, most preferably 14 to 18, when the HLB value is less than 13, the removal effect (cleansing force) for the makeup and the effect of improving the transparency of the composition is not only slight. A water soluble composition cannot be made.
본 발명에 있어서, 상기 수용성 계면활성제는 폴리글리세릴-6 카프릴레이트(polyglyceryl-6 caprylate), 폴리글리세릴-10 라우레이트(polyglyceryl-10 laurate), 피이지-6 카프릴릭/카프릭 글리세라이드(PEG-6 caprylic/capric glycerides), 피이지-7 글리세릴 코코에이트(PEG-7 glyceryl cocoate), 폴리소르베이트 20(polysorbate 20), 및 디소디윰 코코암포디아세테이트(disodium cocoamphodiacetate)로 이루어진 군에서 선택되는 1종 이상인 것을 특징으로 할 수 있고, 바람직하게는 폴리글리세릴-6 카프릴레이트(polyglyceryl-6 caprylate) 및 폴리글리세릴-10 라우레이트(polyglyceryl-10 laurate)의 혼합물이다.In the present invention, the water-soluble surfactant is polyglyceryl-6 caprylate (polyglyceryl-6 caprylate), polyglyceryl-10 laurate (polyglyceryl-10 laurate), Fiji-6 caprylic / capric glycerol Group consisting of PED-6 caprylic / capric glycerides, PEG-7 glyceryl cocoate, polysorbate 20, and disodium cocoamphodiacetate It may be characterized in that one or more selected from, preferably a mixture of polyglyceryl-6 caprylate (polyglyceryl-6 caprylate) and polyglyceryl-10 laurate (polyglyceryl-10 laurate).
본 발명에 있어서, 상기 유용성 계면활성제의 HLB 값은 12 이하, 더욱 바람직하게는 9~12, 가장 바람직하게는 10~12이며, 상기 HLB 값이 12를 초과하는 경우 화장에 대한 제거력(클렌징력)이 저감되고, 조성물의 투명도 향상 효과가 낮아질 수 있다.In the present invention, the HLB value of the oil-soluble surfactant is 12 or less, more preferably 9 to 12, most preferably 10 to 12, the removal force for the makeup (cleansing force) when the HLB value exceeds 12 This can be reduced, and the effect of improving the transparency of the composition can be lowered.
본 발명에 있어서, 상기 유용성 계면활성제는 폴리글리세릴-10 디이소스테아레이트(polyglyceryl-10 diisostearate), 폴리글리세릴-2 라우레이트(polyglyceryl-2 laurate), 폴리글리세릴-2 세스키카프릴레이트(polyglyceryl-2 sesquicaprylate), 폴리글리세릴-5 트리올레이트(polyglyceryl-5 trioleate), 폴리글리세릴-10 디올레이트(polyglyceryl-10 dioleate), 피이지-20 글리세릴 트리이소스테아레이트(PEG-20 glyceryl triisostearate), 피이지-8 이소스테아레이트(PEG-8 isostearate), 피이지-8 글리세릴 이소스테아레이트(PEG-8 glyceryl isostearate), 피이지-20 글리세릴 이소스테아레이트(PEG-20 glyceryl isostearate), 피이지-15 글리세릴 이소스테아레이트(PEG-15 glyceryl isostearate), 폴리소르베이트 60(polysorbate 60) 및 폴리소르베이트 80(polysorbate 80)로 이루어진 군에서 선택되는 1종 이상인 것을 특징으로 할 수 있고, 바람직하게는 폴리글리세릴-10 디이소스테아레이트이다.In the present invention, the oil-soluble surfactant is polyglyceryl-10 diisostearate, polyglyceryl-2 laurate, polyglyceryl-2 sesquicaprylate ( polyglyceryl-2 sesquicaprylate, polyglyceryl-5 trioleate, polyglyceryl-10 dioleate, Fiji-20 glyceryl triisostearate (PEG-20 glyceryl) triisostearate, PEG-8 isostearate, PEG-8 glyceryl isostearate, PIG-20 glyceryl isostearate , Fiji-15 glyceryl isostearate (PEG-15 glyceryl isostearate), polysorbate 60 (polysorbate 60) and polysorbate 80 (polysorbate 80) may be characterized in that at least one member selected from the group consisting of , Preferably A poly glyceryl -10 di isostearate.
본 발명에 있어서, 상기 조성물은 수중유형(Oil in Water. O/W emulsion) 또는 유중수형(Water in Oil. W/O emulsion)으로 제조될 수 있으며, 바람직하게는 수중유형의 유화방법으로 제조된다.In the present invention, the composition may be prepared in an oil-in-water type (Oil in Water.O / W emulsion) or water-in-oil type (Water in Oil.W / O emulsion), and preferably prepared in an oil-in-water type emulsion method. .
본 발명에 있어서 상기 조성물의 투명도 향상은 제형의 투명 또는 반투명 상태를 의미한다.Improving the transparency of the composition in the present invention means a transparent or translucent state of the formulation.
본 발명에 있어서, 상기 조성물의 탁도 NTU(nephelometric turbidity unit)는 15 이하, 바람직하게는 13 이하, 가장 바람직하게는 10 이하이다.In the present invention, the turbidity nephelometric turbidity unit (NTU) of the composition is 15 or less, preferably 13 or less, most preferably 10 or less.
본 발명에 있어서, 상기 혼합물은 수용성 계면활성제 및 유용성 계면활성제를 바람직하게는 3~20 : 0.1~3.3, 더욱 바람직하게는 4~17 : 0.1~1.5, 가장 바람직하게는 4.5~8 : 0.2~1.3의 중량비로 혼합한 것이다. 상기 중량비를 벗어나는 경우 화장에 대한 제거력(클렌징력)이 저감되고, 조성물의 투명도 향상 효과가 낮아질 수 있다.In the present invention, the mixture is a water-soluble surfactant and a water-soluble surfactant is preferably 3 to 20: 0.1 to 3.3, more preferably 4 to 17: 0.1 to 1.5, most preferably 4.5 to 8: 0.2 to 1.3 It is mixed by the weight ratio of. If the weight ratio is out of the removal force (cleansing force) for the makeup is reduced, the transparency improvement effect of the composition may be lowered.
본 발명에 있어서, 상기 수용성 계면활성제 및 유용성 계면활성제의 중량비를 유지한 상태에서 상기 조성물에 포함되는 수용성 계면활성제의 함량은 조성물의 총 중량을 기준으로, 1~40중량%, 바람직하게는 3~20중량%, 더욱 바람직하게는 4~17중량%, 가장 바람직하게는 4.5~8중량%인 것을 특징으로 할 수 있으며, 상기 수용성 계면활성제의 함량이 조성물의 총 중량을 기준으로 1중량% 미만이면 메이크업 화장 제거용 화장료로서 목적하는 화장에 대한 제거력(클렌징력) 및 조성물의 투명도 향상 효과가 미미하고, 40중량%를 초과하면 함량 증가에 비해 그 효과의 증가가 크지 않으며 제형 안정도와 사용감을 저하시킬 수 있다.In the present invention, the content of the water-soluble surfactant included in the composition while maintaining the weight ratio of the water-soluble surfactant and the oil-soluble surfactant is 1 to 40% by weight, preferably 3 to based on the total weight of the composition 20% by weight, more preferably 4 to 17% by weight, most preferably 4.5 to 8% by weight, and the content of the water-soluble surfactant is less than 1% by weight based on the total weight of the composition. Cosmetics for removing makeup make-up as a removal effect (cleansing force) to the desired makeup and the effect of improving the transparency of the composition is insignificant, and when the content exceeds 40% by weight, the increase in effect is not large compared to the increase in content, and the formulation stability and feeling of use may be reduced. Can be.
본 발명에 있어서, 상기 수용성 계면활성제 및 유용성 계면활성제의 중량비를 유지한 상태에서 상기 조성물에 포함되는 유용성 계면활성제의 함량은 조성물의 총 중량을 기준으로, 0.1~10중량%, 바람직하게는 0.1~3.3중량%, 더욱 바람직하게는 0.1~1.5중량%, 가장 바람직하게는 0.2~1.3중량%인 것을 특징으로 할 수 있으며, 상기 유용성 계면활성제의 함량이 조성물의 총 중량을 기준으로 0.1중량% 미만이면 메이크업 화장 제거용 화장료로서 목적하는 화장에 대한 제거력(클렌징력) 및 조성물의 투명도 향상 효과가 미미하고, 10중량%를 초과하면 함량 증가에 비해 그 효과의 증가가 크지 않으며 제형 안정도와 사용감을 저하시킬 수 있다.In the present invention, the content of the oil-soluble surfactant included in the composition while maintaining the weight ratio of the water-soluble surfactant and the oil-soluble surfactant is 0.1 to 10% by weight, preferably 0.1 to 10 based on the total weight of the composition 3.3% by weight, more preferably 0.1 to 1.5% by weight, most preferably 0.2 to 1.3% by weight, and the content of the oil-soluble surfactant is less than 0.1% by weight based on the total weight of the composition As a cosmetic for removing makeup makeup, the removal power (cleansing power) to the desired makeup and the effect of improving the transparency of the composition are insignificant, and when the content exceeds 10% by weight, the increase in effect is not large compared to the increase in content, and the formulation stability and feeling of use may be reduced. Can be.
본 발명에 있어서, 상기 조성물은 화장품 안전에 관한 규칙에 의거한 사용 제한량을 고려하여, 보습제(폴리올 등), 오일, 왁스, 점도 조절제, 점증제, pH 조정제, 지방, 유기용매, 용해제, 농축제, 겔화제, 연화제, 항산화제, 현탁화제, 안정화제, 발포제(foaming agent), 방향제, 물, 이온형 유화제, 비이온형 유화제, 충전제, 금속이온봉쇄제, 킬레이트화제, 보존제, 비타민, 습윤화제, 염료, 안료, 친수성 활성제, 친유성 활성제, 지질 소낭 또는 화장품에 통상적으로 사용되는 임의의 다른 성분과 같은 화장품학 또는 피부 과학 분야에서 통상적으로 사용되는 보조제를 더 함유할 수 있다. 또한, 본 발명의 조성물은 피부 상태 개선 효과를 증가시키기 위하여 피부 흡수 촉진 물질을 더 함유할 수 있다.In the present invention, the composition is a moisturizer (polyol, etc.), oils, waxes, viscosity regulators, thickeners, pH regulators, fats, organic solvents, solubilizers, concentrations in consideration of the limit of use in accordance with the rules on cosmetic safety Agents, gelling agents, emollients, antioxidants, suspending agents, stabilizers, foaming agents, fragrances, water, ionic emulsifiers, nonionic emulsifiers, fillers, metal ion sequestrants, chelating agents, preservatives, vitamins, wetting It may further contain auxiliaries commonly used in the field of cosmetics or dermatology, such as agents, dyes, pigments, hydrophilic actives, lipophilic actives, lipid vesicles or any other ingredients commonly used in cosmetics. In addition, the composition of the present invention may further contain a skin absorption promoting substance to increase the skin condition improving effect.
본 발명에 있어서, 상기 조성물은 제형화하는데 있어서 특별히 한정되는 바가 없으나, 유연화장수, 수렴화장수, 영양화장수, 로션, 아이 크림, 영양 크림, 마사지 크림, 클렌징 크림, 클렌징 폼, 클렌징 워터, 파우더, 에센스, 팩 등의 제형을 갖는 화장료 조성물일 수 있다. 이들 각 제형의 화장료 조성물은 상기한 각종 제형에 따라 또는 최종 목적에 적합하게 통상의 화장료 조성물에 배합되는 각종 성분들을 함유할 수 있으며, 이들 성분의 종류와 양은 당업자에 의해 용이하게 선정될 수 있다.In the present invention, the composition is not particularly limited in formulating, but softening longevity, astringent longevity, nourishing longevity, lotion, eye cream, nutrition cream, massage cream, cleansing cream, cleansing foam, cleansing water, powder, essence It may be a cosmetic composition having a formulation, such as a pack. The cosmetic composition of each of these formulations may contain various components formulated into conventional cosmetic compositions according to the various formulations described above or suitably for the end purpose, and the types and amounts of these components can be easily selected by those skilled in the art.
본 발명에 있어서, 상기 메이크업 화장은 립스틱, 립글로스, 립밤, 립펜슬, 루즈, 립팔레트, 팩트, 파우더, 블러셔, 트윈케이크, 콤팩트, 파우더 팩트, 프레스트 파우더, 스킨커버, 파운데이션, 컨실러 아이섀도우, 아이브라우, 아이라이너 및 마스카라로 이루어진 군에서 선택되는 하나 이상의 화장료 제형을 피부에 적용하여 생성된 것임을 특징으로 할 수 있으나, 이에 한정되는 것은 아니다.In the present invention, the makeup make-up is lipstick, lip gloss, lip balm, lip pencil, rouge, lip palette, pact, powder, blusher, twin cake, compact, powder pact, pressed powder, skin cover, foundation, concealer eye shadow, eyebrow , Eyeliner and mascara may be produced by applying one or more cosmetic formulations selected from the group consisting of skin, but is not limited thereto.
이하, 실시예를 통하여 본 발명을 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 예시하기 위한 것으로서, 본 발명의 범위가 이들 실시예에 의해 제한되는 것으로 해석되지 않는 것은 당업계에서 통상의 지식을 가진 자에 있어서 자명할 것이다.Hereinafter, the present invention will be described in more detail with reference to Examples. These examples are only for illustrating the present invention, it will be apparent to those skilled in the art that the scope of the present invention is not to be construed as limited by these examples.
< 메이크업 화장 제거용 화장료 조성물의 제조 ><Preparation of Cosmetic Composition for Removing Makeup Cosmetics>
아래 표 1 및 표 2의 조성으로 실시예 1~7과 비교예 1~4의 메이크업 화장 제거용 화장료 조성물을 제조하였다(단위: 중량%). To the compositions of Tables 1 and 2 below to prepare a cosmetic composition for removing makeup makeup of Examples 1 to 7 and Comparative Examples 1 to 4 (unit: weight%).
구분division 원료명Raw material name 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 실시예 5Example 5 실시예 6Example 6 실시예 7Example 7
-- 정제수Purified water to 100to 100 to 100to 100 to 100to 100 to 100to 100 to 100to 100 to 100to 100 to 100to 100
수용성 계면활성제Water soluble surfactant 폴리글리세릴-6 카프릴레이트(polyglyceryl-6 caprylate)Polyglyceryl-6 caprylate 55 77 00 22 55 55 55
폴리글리세릴-10 라우레이트(polyglyceryl-10 laurate)Polyglyceryl-10 laurate 22 -- 77 55 22 22 --
유용성 계면활성제Oil-soluble surfactants 폴리글리세릴-10 디이소스테아레이트(polyglyceryl-10 diisostearate)Polyglyceryl-10 diisostearate 1One 1One 1One 1One -- 0.50.5 1One
폴리글리세릴-10 디올레이트(polyglyceryl-10 dioleate)Polyglyceryl-10 dioleate -- -- -- -- 1One 0.50.5 --
구분division 원료명Raw material name 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 비교예 4Comparative Example 4
-- 정제수Purified water to 100to 100 to 100to 100 to 100to 100 to 100to 100
수용성 계면활성제Water soluble surfactant 폴리글리세릴-6 카프릴레이트(polyglyceryl-6 caprylate)Polyglyceryl-6 caprylate 55 55 00 00
폴리글리세릴-10 라우레이트(polyglyceryl-10 laurate)Polyglyceryl-10 laurate 22 22 22 00
유용성 계면활성제Oil-soluble surfactants 폴리글리세릴-10 디이소스테아레이트(polyglyceryl-10 diisostearate)Polyglyceryl-10 diisostearate 0.050.05 00 1One 1One
폴리글리세릴-10 디올레이트(polyglyceryl-10 dioleate)Polyglyceryl-10 dioleate -- -- -- --
[[ 실시예Example 1~7]: 수용성 계면활성제 및 유용성 계면활성제 함유  1 ~ 7]: containing water-soluble surfactant and oil-soluble surfactant 화장료Cosmetics 조성물 Composition
상기 표 1의 실시예 1~7에 따른 화장료 조성물을 제조하기 위해, 수용성 계면활성제인 폴리글리세릴-6 카프릴레이트(HLB 15) 및 폴리글리세릴-10 라우레이트(HLB 16)와, 유용성 계면활성제인 폴리글리세릴-10 디이소스테아레이트(HLB 11) 및 폴리글리세릴-10 디올레이트(HLB 11.7)를 사용하였다.In order to manufacture the cosmetic composition according to Examples 1 to 7 of Table 1, the water-soluble surfactant polyglyceryl-6 caprylate (HLB 15) and polyglyceryl-10 laurate (HLB 16) and the oil-soluble interface The active agents polyglyceryl-10 diisostearate (HLB 11) and polyglyceryl-10 dioleate (HLB 11.7) were used.
구체적으로, Specifically,
1) 폴리글리세릴-6 카프릴레이트 : 폴리글리세릴-10 라우레이트 : 폴리글리세릴-10 디이소스테아레이트 = 5 : 2 : 1의 중량비(실시예 1 참조), 폴리글리세릴-6 카프릴레이트 : 폴리글리세릴-10 디이소스테아레이트 = 7 : 1의 중량비(실시예 2 참조), 폴리글리세릴-10 라우레이트 : 폴리글리세릴-10 디이소스테아레이트 = 7 : 1의 중량비(실시예 3 참조), 폴리글리세릴-6 카프릴레이트 : 폴리글리세릴-10 라우레이트 : 폴리글리세릴-10 디이소스테아레이트 = 2 : 5 : 1의 중량비(실시예 4 참조), 폴리글리세릴-6 카프릴레이트 : 폴리글리세릴-10 라우레이트 : 폴리글리세릴-10 디올레이트 = 5 : 2 : 1의 중량비(실시예 5 참조), 폴리글리세릴-6 카프릴레이트 : 폴리글리세릴-10 라우레이트 : 폴리글리세릴-10 디이소스테아레이트 : 폴리글리세릴-10 디올레이트 = 5 : 2 : 0.5 : 0.5의 중량비(실시예 6 참조) 및 폴리글리세릴-6 카프릴레이트 : 폴리글리세릴-10 디이소스테아레이트 = 5 : 1의 중량비(실시예 7 참조)로 혼합한 각각의 혼합물을 준비한 다음, 약 60℃의 온도로 가열하여 녹였다.1) polyglyceryl-6 caprylate: polyglyceryl-10 laurate: polyglyceryl-10 diisostearate = 5: 2: 1 weight ratio (see Example 1), polyglyceryl-6 capryl Rate: polyglyceryl-10 diisostearate = 7: 1 weight ratio (see Example 2), polyglyceryl-10 laurate: polyglyceryl-10 diisostearate = 7: 1 weight ratio (Example 3), polyglyceryl-6 caprylate: polyglyceryl-10 laurate: polyglyceryl-10 diisostearate = 2: 5: 1 weight ratio (see Example 4), polyglyceryl-6 Caprylate: Polyglyceryl-10 Laurate: Polyglyceryl-10 Dioleate = 5: 2: 1 Weight ratio (see Example 5), Polyglyceryl-6 Caprylate: Polyglyceryl-10 Laurate : Polyglyceryl-10 diisostearate: polyglyceryl-10 dioleate = 5: 2: 0.5: 0.5 weight ratio Example 6) and polyglyceryl-6 caprylate: polyglyceryl-10 diisostearate = 5: 1 each of the mixture was prepared in a mixture (see Example 7), and then the temperature of about 60 ℃ Heated to melt.
2) 상기 1)의 가열된 각각의 혼합물에 정제수를 첨가하고 분산기(disperser)로 교반하면서 약 80℃의 온도로 가온하였다.2) Purified water was added to each heated mixture of 1) and warmed to a temperature of about 80 ° C. with stirring with a disperser.
3) 상기 2)의 정제수가 첨가되고 가온된 각각의 혼합물을 상온(약 25℃)의 온도로 냉각하여 실시예 1~7의 화장료 조성물을 제조하였다.3) Purified water of 2) was added and the heated mixture was cooled to room temperature (about 25 ° C.) to prepare cosmetic compositions of Examples 1-7.
[비교예 1]: 수용성 계면활성제 및 유용성 계면활성제 함유 화장료 조성물COMPARATIVE EXAMPLE 1 Water-soluble surfactant and oil-soluble surfactant containing cosmetic composition
상기 표 2의 비교예 1에 따른 화장료 조성물의 제조방법은 다음과 같았다.The preparation method of the cosmetic composition according to Comparative Example 1 of Table 2 was as follows.
1) 수용성 계면활성제인 폴리글리세릴-6 카프릴레이트 및 폴리글리세릴-10 라우레이트와 유용성 계면활성제인 폴리글리세릴-10 디이소스테아레이트를 사용하여 폴리글리세릴-6 카프릴레이트 : 폴리글리세릴-10 라우레이트 : 폴리글리세릴-10 디이소스테아레이트 = 5 : 2 : 0.05의 중량비로 혼합한 혼합물을 준비한 다음, 약 60℃의 온도로 가열하여 녹였다.1) Polyglyceryl-6 caprylate using polyglyceryl-6 caprylate and polyglyceryl-10 laurate as water-soluble surfactant and polyglyceryl-10 diisostearate as oil-soluble surfactant: polyglycerol A mixture was prepared in a weight ratio of reel-10 laurate: polyglyceryl-10 diisostearate = 5: 2: 0.05, and then dissolved by heating to a temperature of about 60 ° C.
2) 상기 1)의 가열된 혼합물에 정제수를 첨가하고 분산기로 교반하면서 약 80℃의 온도로 가온하였다.2) Purified water was added to the heated mixture of 1) and warmed to a temperature of about 80 ° C. while stirring with a disperser.
3) 상기 2)의 정제수가 첨가되고 가온된 혼합물을 상온(약 25℃)의 온도로 냉각하여 화장료 조성물을 제조하였다.3) Purified water of 2) was added and the heated mixture was cooled to a temperature of about 25 ° C to prepare a cosmetic composition.
[비교예 2]: 수용성 계면활성제 함유 화장료 조성물Comparative Example 2: Water-soluble Surfactant-Containing Cosmetic Composition
상기 표 2의 비교예 2에 따른 화장료 조성물의 제조방법은 다음과 같았다.The preparation method of the cosmetic composition according to Comparative Example 2 of Table 2 was as follows.
1) 수용성 계면활성제인 폴리글리세릴-6 카프릴레이트 및 폴리글리세릴-10 라우레이트를 사용하여 폴리글리세릴-6 카프릴레이트 : 폴리글리세릴-10 라우레이트 = 5 : 2의 중량비로 혼합한 혼합물을 준비한 다음, 약 60℃의 온도로 가열하여 녹였다.1) Polyglyceryl-6 caprylate using polyglyceryl-6 caprylate and polyglyceryl-10 laurate, which are water-soluble surfactants, were mixed in a weight ratio of polyglyceryl-10 laurate = 5: 2. The mixture was prepared and then heated to a temperature of about 60 ° C. to dissolve.
2) 상기 1)의 가열된 혼합물에 정제수를 첨가하고 분산기로 교반하면서 약 80℃의 온도로 가온하였다.2) Purified water was added to the heated mixture of 1) and warmed to a temperature of about 80 ° C. while stirring with a disperser.
3) 상기 2)의 정제수가 첨가되고 가온된 혼합물을 상온(약 25℃)의 온도로 냉각하여 화장료 조성물을 제조하였다.3) Purified water of 2) was added and the heated mixture was cooled to a temperature of about 25 ° C to prepare a cosmetic composition.
[비교예 3]: 수용성 계면활성제 및 유용성 계면활성제 함유 화장료 조성물[Comparative Example 3]: Water-soluble surfactant and oil-soluble surfactant-containing cosmetic composition
상기 표 2의 비교예 3에 따른 화장료 조성물의 제조방법은 다음과 같았다.The preparation method of the cosmetic composition according to Comparative Example 3 of Table 2 was as follows.
1) 수용성 계면활성제인 폴리글리세릴-10 라우레이트와 유용성 계면활성제인 폴리글리세릴-10 디이소스테아레이트를 사용하여 폴리글리세릴-10 라우레이트 : 폴리글리세릴-10 디이소스테아레이트 = 2 : 1의 중량비로 혼합한 혼합물을 준비한 다음, 약 60℃의 온도로 가열하여 녹였다.1) Polyglyceryl-10 laurate using polyglyceryl-10 laurate as the water-soluble surfactant and polyglyceryl-10 diisostearate as the oil-soluble surfactant: polyglyceryl-10 diisostearate = 2: The mixture mixed in the weight ratio of 1 was prepared, and it melt | dissolved by heating to the temperature of about 60 degreeC.
2) 상기 1)의 가열된 혼합물에 정제수를 첨가하고 분산기로 교반하면서 약 80℃의 온도로 가온하였다.2) Purified water was added to the heated mixture of 1) and warmed to a temperature of about 80 ° C. while stirring with a disperser.
3) 상기 2)의 정제수가 첨가되고 가온된 혼합물을 상온(약 25℃)의 온도로 냉각하여 화장료 조성물을 제조하였다.3) Purified water of 2) was added and the heated mixture was cooled to a temperature of about 25 ° C to prepare a cosmetic composition.
[비교예 4] 유용성 계면활성제 함유 화장료 조성물[Comparative Example 4] Oil-soluble surfactant-containing cosmetic composition
상기 표 2의 비교예 4에 따른 화장료 조성물의 제조방법은 다음과 같았다.The preparation method of the cosmetic composition according to Comparative Example 4 of Table 2 was as follows.
1) 유용성 계면활성제인 폴리글리세릴-10 디이소스테아레이트를 약 60℃의 온도로 가열하여 녹였다.1) Polyglyceryl-10 diisostearate as an oil-soluble surfactant was dissolved by heating to a temperature of about 60 ℃.
2) 상기 1)의 가열된 폴리글리세릴-10 디이소스테아레이트에 정제수를 첨가하고 분산기로 교반하면서 약 80℃의 온도로 가온하였다.2) Purified water was added to the heated polyglyceryl-10 diisostearate of 1) and warmed to a temperature of about 80 ° C. while stirring with a disperser.
3) 상기 2)의 정제수가 첨가되고 가온된 폴리글리세릴-10 디이소스테아레이트를 상온(약 25℃)의 온도로 냉각하여 화장료 조성물을 제조하였다.3) Purified water of 2) was added and the heated polyglyceryl-10 diisostearate was cooled to a temperature of about 25 ° C. to prepare a cosmetic composition.
[시험예 1] 메이크업 화장 제거용 화장료 조성물의 클렌징력 평가[Test Example 1] Cleansing power evaluation of the cosmetic composition for removing makeup makeup
수용성 계면활성제 및 유용성 계면활성제의 조성 및 함량을 달리하여 제조한 실시예 1~7 및 비교예 1~4에 따른 화장료 조성물의 클렌징력을 평가하였다. The cleansing power of the cosmetic compositions according to Examples 1 to 7 and Comparative Examples 1 to 4 prepared by varying the composition and content of the water-soluble surfactant and the oil-soluble surfactant was evaluated.
< 클렌징력의 평가방법 >< Evaluation method of cleansing force >
먼저, 통상적으로 화장학적 용도로 사용되는 마스카라, 립스틱 및 파운데이션 각각의 메이크업 화장료를 흰색 인공피혁에 2cm x 2cm 면적으로 0.02g/20μL씩 도포 후 약 30분간 건조시켰다. 그다음, 상기 메이크업 화장료를 도포한 인공피혁을 실시예 1~7, 비교예 1~4의 화장료 조성물로 2g 씩 적신 화장솜(면적: 3cm x 4cm)으로 위에서 아래로 5회 문지른 다음, 인공피혁에 도포된 메이크업 화장료의 제거 여부(클렌징력)를 육안 및 색차계로 확인하였다. 여기서, 색차계는 밝기 정도(L)를 5.00~99.99 AU(arbitrary unit) 값으로 측정하며, 밝기 정도가 70 AU 이상일 때(육안으로도 화장료 제거 효과가 확인 가능한 수준) 메이크업 화장료에 대한 클렌징 효과가 높은 것으로 평가하였다.First, the makeup cosmetics of mascara, lipstick and foundation, which are commonly used for cosmetic purposes, were applied to white artificial leather by 0.02 g / 20 μL in 2 cm × 2 cm areas, and then dried for about 30 minutes. Next, the artificial leather coated with the makeup cosmetic was rubbed five times from top to bottom with a cotton ball (area: 3 cm x 4 cm) moistened with 2 g of the cosmetic composition of Examples 1 to 7 and Comparative Examples 1 to 4, and then to artificial leather. Whether or not the applied makeup cosmetics were removed (cleansing power) was checked by visual and color difference meters. Here, the color difference meter measures the brightness level (L) with a value of 5.00 to 99.99 AU (arbitrary unit), and when the brightness level is 70 AU or more (the level of the cosmetic removal effect can be seen with the naked eye), Evaluated as high.
그 결과, As a result,
1) 육안으로 클렌징 효과 확인 시 아래 도 1에 나타낸 바와 같이, 1) When checking the cleansing effect with the naked eye, as shown in Figure 1 below,
① 실시예 1의 화장료 조성물은 인공피혁에 도포된 3가지 메이크업 화장료, 즉 파운데이션, 립스틱 및 마스카라에 대한 클렌징 효과가 우수한 것으로 확인된 반면;① The cosmetic composition of Example 1 was found to have an excellent cleansing effect on three makeup cosmetics applied to artificial leather, namely foundation, lipstick and mascara;
② 비교예 1의 화장료 조성물은 인공피혁에 도포된 마스카라에 대한 클렌징 효과만이 있었고, 비교예 2의 화장료 조성물은 인공피혁에 도포된 파운데이션, 립스틱 및 마스카라에 대한 클렌징 효과가 거의 없는 것으로 확인되었다.② The cosmetic composition of Comparative Example 1 had only a cleansing effect on mascara applied to artificial leather, and the cosmetic composition of Comparative Example 2 was confirmed to have little cleansing effect on foundation, lipstick and mascara applied to artificial leather.
아울러, 육안으로 클렌징 효과 확인 시, 실시예 2~7의 화장료 조성물은 실시예 1의 화장료 조성물와 비슷한 정도의 클렌징 효과, 즉 인공피혁에 도포된 파운데이션, 립스틱 및 마스카라에 대한 클렌징 효과를 나타내는 것으로 확인되었다(데이터 미제시). In addition, when visually confirming the cleansing effect, it was confirmed that the cosmetic composition of Examples 2 to 7 exhibits a similar cleansing effect to the cosmetic composition of Example 1, that is, a cleansing effect on foundation, lipstick, and mascara applied to artificial leather. (Not shown).
2) 한편, 색차계로 클렌징 효과 확인 시 아래 표 3 및 표 4에 나타낸 바와 같이, 2) On the other hand, as shown in Table 3 and Table 4 below when checking the cleansing effect with a color difference meter,
① 실시예 1, 실시예 2, 실시예 5 및 실시예 6의 화장료 조성물은 3가지 메이크업 화장료, 즉 파운데이션, 립스틱 및 마스카라로 도포된 인공피혁에서 밝기 정도가 70 AU 이상으로 나타나 클렌징 효과가 매우 우수하였고; ① The cosmetic composition of Examples 1, 2, 5 and 6 has a brightening degree of 70 AU or more in artificial leather coated with three makeup cosmetics, namely, foundation, lipstick, and mascara, so the cleansing effect is very excellent. It was done;
② 실시예 3, 실시예 4 및 실시예 7의 화장료 조성물은 2가지 메이크업 화장료, 즉 파운데이션 및 마스카라로 도포된 인공피혁에서 밝기 정도가 70 AU 이상으로 나타나 클렌징 효과가 비교적 우수하였고; (2) The cosmetic compositions of Examples 3, 4 and 7 exhibited a brightening degree of 70 AU or more in artificial leather coated with two makeup cosmetics, namely, foundation and mascara, so that the cleansing effect was relatively excellent;
③ 비교예 1 및 비교예 3의 화장료 조성물은 마스카라로 도포된 인공피혁에서만 밝기 정도가 70 AU 이상으로 나타나 마스카라에 대한 클렌징 효과만이 있었고, 비교예 4의 화장료 조성물은 파운데이션으로 도포된 인공피혁에서만 밝기 정도가 70 AU 이상으로 나타나 파운데이션에 대한 클렌징 효과만이 있는 것으로 확인되었으며;③ The cosmetic compositions of Comparative Examples 1 and 3 had only a cleansing effect on mascara due to the brightness degree of 70 AU or more only in artificial leather applied with mascara, and the cosmetic composition of Comparative Example 4 was only applied to artificial leather applied with foundation. The degree of brightness was above 70 AU, confirming that there was only a cleansing effect on the foundation;
④ 비교예 2의 화장료 조성물은 파운데이션, 립스틱 및 마스카라로 도포된 인공피혁에서 밝기 정도가 70 AU 미만으로 나타나 클렌징 효과가 거의 없는 것으로 확인되었다.④ The cosmetic composition of Comparative Example 2 was found to have almost no cleansing effect as the brightness degree was less than 70 AU in artificial leather applied with foundation, lipstick and mascara.
 제형Formulation 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 실시예 5Example 5 실시예 6Example 6 실시예 7Example 7
파운데이션foundation 87.387.3 83.883.8 72.872.8 75.475.4 86.886.8 81.681.6 71.771.7
립스틱lipstick 76.976.9 70.370.3 58.358.3 68.568.5 71.071.0 74.674.6 60.460.4
마스카라Mascara 84.284.2 83.083.0 78.878.8 80.980.9 84.884.8 83.383.3 71.371.3
 제형Formulation 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 비교예 4Comparative Example 4
파운데이션foundation 64.264.2 65.365.3 62.862.8 71.171.1
립스틱lipstick 47.447.4 53.053.0 46.846.8 44.244.2
마스카라Mascara 71.471.4 66.266.2 74.774.7 65.865.8
결국, 수용성 계면활성제를 포함하는 화장료 조성물 중에 수용성 계면활성제의 함량을 증가시킬수록 클렌징력이 향상되고, 특히 HLB 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제를 본 발명에서 규명하여 정의한 함량범위 내에서 7 : 1 또는 5 : 1의 중량비로 혼합한 혼합물을 포함하는 화장료 조성물(실시예 1~7)은 화장 제거 효과가 현저하게 증가하는 것을 확인하였다.As a result, as the content of the water-soluble surfactant is increased in the cosmetic composition including the water-soluble surfactant, the cleansing power is improved, and in particular, the water-soluble surfactant having an HLB value of 13 or more and the oil-soluble surfactant having an HLB value of 12 or less are identified in the present invention. Cosmetic compositions (Examples 1 to 7) comprising a mixture mixed in a weight ratio of 7: 1 or 5: 1 within the defined content range was confirmed that the cosmetic removal effect is significantly increased.
[[ 시험예Test Example 2] 메이크업 화장 제거용  2] Makeup makeup removal 화장료Cosmetics 조성물의 투명도 평가 Evaluation of transparency of the composition
수용성 계면활성제 및 유용성 계면활성제의 조성 및 함량을 달리하여 제조한 실시예 1~7 및 비교예 1~4에 따른 화장료 조성물의 투명도 향상의 정도를 탁도계(Turbidimeter)를 이용하여 탁도(turbidity)로 평가하였다.The degree of transparency improvement of the cosmetic compositions according to Examples 1 to 7 and Comparative Examples 1 to 4 prepared by varying the composition and content of the water-soluble surfactant and the oil-soluble surfactant was evaluated by turbidity using a turbidimeter. It was.
< 투명도의 평가방법 >< Evaluation method of transparency >
표 1 및 표 2에 기재된 화장료 조성물의 투명도는 HF 사이언티픽-마이크로 1000IR 탁도계(HF Scientific-Micro 1000IR Turbidimeter)를 이용하여 22℃±1℃의 온도에서 측정하였다. 투명도는 NTU(nephelometric turbidity unit)로 측정된 탁도를 기준으로, 탁도 값이 낮을수록 더 투명한 제형으로 평가하였다.The transparency of the cosmetic compositions described in Table 1 and Table 2 was measured at a temperature of 22 ° C. ± 1 ° C. using an HF Scientific-Micro 1000IR Turbidimeter. Transparency was assessed as a more transparent formulation with lower turbidity values, based on turbidity measured in NTU (nephelometric turbidity unit).
그 결과, 아래 표 5 및 표 6에 나타낸 바와 같이, As a result, as shown in Tables 5 and 6 below,
① 실시예 3 및 실시예 4의 화장료 조성물은 탁도 감소 효과가 매우 우수하였고;① The cosmetic composition of Example 3 and Example 4 was very excellent in turbidity reduction effect;
② 실시예 1, 실시예 2, 실시예 5, 실시예 6 및 실시예 7의 화장료 조성물은 탁도 감소 효과가 우수하였으며;② The cosmetic composition of Example 1, Example 2, Example 5, Example 6, and Example 7 was excellent in turbidity reduction effect;
③ 비교예 3 및 비교예 4의 화장료 조성물은 탁도 감소 효과가 매우 낮게 나타나는 것으로 확인되었다.(3) The cosmetic compositions of Comparative Example 3 and Comparative Example 4 were found to exhibit a very low haze reduction effect.
한편, 유용성 계면활성제가 포함되어 있지 않은 비교예 2의 화장료 조성물, 및 유용성 계면활성제가 낮은 함량(즉, 0.05중량%)으로 포함되어 있는 비교예 1의 화장료 조성물은 탁도 감소 효과가 높게 나타난 반면, 비교예 1 및 비교예 2 각각의 화장료 조성물은 시험예 1에서 살펴본 바와 같이 메이크업 화장료에 대한 클렌징 효과는 높지 않은 것으로 평가되었다.On the other hand, the cosmetic composition of Comparative Example 2, which does not contain an oil-soluble surfactant, and the cosmetic composition of Comparative Example 1, which is contained in a low content (ie, 0.05% by weight) of the oil-soluble surfactant, showed a high turbidity reduction effect, Each cosmetic composition of Comparative Example 1 and Comparative Example 2 was evaluated as not having a high cleansing effect on the makeup cosmetic as described in Test Example 1.
결국, 유용성 계면활성제를 포함하는 화장료 조성물 중에 수용성 계면활성제의 함량을 증가시킬수록 탁도 감소에 따라 조성물의 투명도가 향상되고, 특히 HLB 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제를 본 발명에서 규명하여 정의한 함량범위 내에서 7 : 1 또는 5 : 1의 중량비로 혼합한 혼합물을 포함하는 화장료 조성물은 탁도 감소에 따른 투명도 개선 효과뿐만 아니라, 시험예 1에서 살펴본 바와 같이 메이크업 화장료에 대한 클렌징 효과도 현저하게 증가시키는 것을 확인하였다.As a result, as the content of the water-soluble surfactant is increased in the cosmetic composition including the oil-soluble surfactant, the transparency of the composition is improved as the turbidity decreases, and in particular, the water-soluble surfactant having an HLB value of 13 or more and the oil-soluble surfactant having an HLB value of 12 or less The cosmetic composition comprising a mixture mixed in a weight ratio of 7: 1 or 5: 1 within the content range defined and defined in the present invention not only improves transparency due to turbidity reduction, but also as described in Test Example 1 for makeup cosmetics It was confirmed that the cleansing effect also increased significantly.
실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 실시예 5Example 5 실시예 6Example 6 실시예 7Example 7
탁도(NTU)Turbidity (NTU) 8.68.6 7.837.83 6.366.36 6.216.21 7.717.71 7.647.64 8.458.45
비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 비교예 4Comparative Example 4
탁도(NTU)Turbidity (NTU) 10.510.5 6.916.91 207207 357357
이상으로 본 발명 내용의 특정한 부분을 상세히 기술하였는바, 당업계의 통상의 지식을 가진 자에게 있어서, 이러한 구체적 기술은 단지 바람직한 실시양태일 뿐이며, 이에 의해 본 발명의 범위가 제한되는 것이 아닌 점은 명백할 것이다. 따라서 본 발명의 실질적인 범위는 첨부된 청구항들과 그것들의 등가물에 의하여 정의된다고 할 것이다.The specific parts of the present invention have been described in detail above, and it is apparent to those skilled in the art that such specific descriptions are merely preferred embodiments, and thus the scope of the present invention is not limited thereto. something to do. Thus, the substantial scope of the present invention will be defined by the appended claims and their equivalents.

Claims (8)

  1. HLB(Hydrophile Lipophile Balance) 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제의 혼합물을 유효성분으로 포함하는 메이크업 화장 제거용 화장료 조성물.A cosmetic composition for removing makeup makeup comprising a mixture of a water-soluble surfactant having a HLB (Hydrophile Lipophile Balance) value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less as an active ingredient.
  2. 제1항에 있어서, 상기 수용성 계면활성제는 폴리글리세릴-6 카프릴레이트(polyglyceryl-6 caprylate), 폴리글리세릴-10 라우레이트(polyglyceryl-10 laurate), 피이지-6 카프릴릭/카프릭 글리세라이드(PEG-6 caprylic/capric glycerides), 피이지-7 글리세릴 코코에이트(PEG-7 glyceryl cocoate), 폴리소르베이트 20(polysorbate 20), 및 디소디윰 코코암포디아세테이트(disodium cocoamphodiacetate)로 이루어진 군에서 선택되는 1종 이상인 것을 특징으로 하는, 메이크업 화장 제거용 화장료 조성물.The method of claim 1, wherein the water-soluble surfactant is polyglyceryl-6 caprylate, polyglyceryl-10 laurate, Fiji-6 caprylic / capric Glyceride (PEG-6 caprylic / capric glycerides), PIG-7 glyceryl cocoate, polysorbate 20, and disodium cocoamphodiacetate Cosmetic composition for removing makeup makeup, characterized in that at least one selected from the group.
  3. 제1항에 있어서, 상기 유용성 계면활성제는 폴리글리세릴-10 디이소스테아레이트(polyglyceryl-10 diisostearate), 폴리글리세릴-2 라우레이트(polyglyceryl-2 laurate), 폴리글리세릴-2 세스키카프릴레이트(polyglyceryl-2 sesquicaprylate), 폴리글리세릴-5 트리올레이트(polyglyceryl-5 trioleate), 폴리글리세릴-10 디올레이트(polyglyceryl-10 dioleate), 피이지-20 글리세릴 트리이소스테아레이트(PEG-20 glyceryl triisostearate), 피이지-8 이소스테아레이트(PEG-8 isostearate), 피이지-8 글리세릴 이소스테아레이트(PEG-8 glyceryl isostearate), 피이지-20 글리세릴 이소스테아레이트(PEG-20 glyceryl isostearate), 피이지-15 글리세릴 이소스테아레이트(PEG-15 glyceryl isostearate), 폴리소르베이트 60(polysorbate 60) 및 폴리소르베이트 80(polysorbate 80)로 이루어진 군에서 선택되는 1종 이상인 것을 특징으로 하는, 메이크업 화장 제거용 화장료 조성물.The method of claim 1, wherein the oil-soluble surfactant is polyglyceryl-10 diisostearate, polyglyceryl-2 laurate, polyglyceryl-2 sesquicaprylate (polyglyceryl-2 sesquicaprylate), polyglyceryl-5 trioleate, polyglyceryl-10 dioleate, Fiji-20 glyceryl triisostearate (PEG-20 glyceryl triisostearate, PEG-8 isostearate, PIG-8 glyceryl isostearate, PIG-20 glyceryl isostearate ), PIG-15 glyceryl isostearate, characterized in that at least one member selected from the group consisting of polysorbate 60 (polysorbate 60) and polysorbate 80 (polysorbate 80), Makeup makeup removal A cosmetic composition.
  4. 제1항에 있어서, 상기 조성물의 탁도 NTU(nephelometric turbidity unit)는 15 이하인 것을 특징으로 하는, 메이크업 화장 제거용 화장료 조성물.The cosmetic composition for removing makeup makeup of claim 1, wherein the turbidity NTU (nephelometric turbidity unit) of the composition is 15 or less.
  5. 제1항에 있어서, 상기 혼합물은 HLB 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제를 중량 기준으로 3~20 : 0.1~3.3로 혼합한 것임을 특징으로 하는, 메이크업 화장 제거용 화장료 조성물.According to claim 1, wherein the mixture is a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less by weight of 3 to 20: 0.1 to 3.3, characterized in that the cosmetic for removing makeup makeup Composition.
  6. 제1항에 있어서, 상기 조성물은 유연화장수, 수렴화장수, 영양화장수, 로션, 아이 크림, 영양 크림, 마사지 크림, 클렌징 크림, 클렌징 폼, 클렌징 워터, 파우더, 에센스 또는 팩으로 제형화되는 것임을 특징으로 하는, 메이크업 화장 제거용 화장료 조성물.The composition of claim 1, wherein the composition is formulated as a softening cream, astringent makeup, nutrition cream, lotion, eye cream, nutrition cream, massage cream, cleansing cream, cleansing foam, cleansing water, powder, essence or pack Cosmetic composition for removing makeup makeup.
  7. 제1항에 있어서, 상기 메이크업 화장은 립스틱, 립글로스, 립밤, 립펜슬, 루즈, 립팔레트, 팩트, 파우더, 블러셔, 트윈케이크, 콤팩트, 파우더 팩트, 프레스트 파우더, 스킨커버, 파운데이션, 컨실러 아이섀도우, 아이브라우, 아이라이너 및 마스카라로 이루어진 군에서 선택되는 하나 이상의 화장료 제형을 피부에 적용하여 생성된 것임을 특징으로 하는, 메이크업 화장 제거용 화장료 조성물.The method of claim 1, wherein the makeup make-up is lipstick, lip gloss, lip balm, lip pencil, rouge, lip palette, pact, powder, blusher, twin cake, compact, powder pact, pressed powder, skin cover, foundation, concealer eye shadow, eye A cosmetic composition for removing makeup makeup, characterized in that it is produced by applying to the skin one or more cosmetic formulations selected from the group consisting of a brown, eyeliner and mascara.
  8. 메이크업 화장 제거용 화장료 조성물 또는 화장품의 제조에 있어서, HLB 값이 13 이상인 수용성 계면활성제 및 HLB 값이 12 이하인 유용성 계면활성제의 혼합물의 용도.Use of a mixture of a water-soluble surfactant having an HLB value of 13 or more and an oil-soluble surfactant having an HLB value of 12 or less in the manufacture of a cosmetic composition or cosmetic for removing makeup.
PCT/KR2019/003632 2018-03-30 2019-03-28 Cosmetic composition for makeup removal comprising water-soluble surfactant and oil-soluble surfactant WO2019190220A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US17/043,548 US11904039B2 (en) 2018-03-30 2019-03-28 Cosmetic composition for makeup removal comprising water-soluble surfactant and oil-soluble surfactant
CN201980023453.7A CN111936113A (en) 2018-03-30 2019-03-28 Cosmetic composition for removing makeup containing water-soluble surfactant and oil-soluble surfactant

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2018-0037438 2018-03-30
KR20180037438 2018-03-30
KR1020190032725A KR20190114797A (en) 2018-03-30 2019-03-22 Cosmetic Composition Containing Water-Soluble Surfactant and Oil-Soluble Surfactant for Removing Make-Up Cosmetics
KR10-2019-0032725 2019-03-22

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006022061A (en) * 2004-07-09 2006-01-26 Kanebo Ltd Transparent cleansing cosmetic
KR20100014247A (en) * 2007-03-29 2010-02-10 가부시키가이샤 시세이도 Oil-in-water type emulsion composition
JP2011126809A (en) * 2009-12-17 2011-06-30 Kao Corp Cleansing cosmetic
JP2012214404A (en) * 2011-03-31 2012-11-08 Nof Corp Cleansing preparation
JP2014091734A (en) * 2012-11-06 2014-05-19 Nof Corp Cleansing cream

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006022061A (en) * 2004-07-09 2006-01-26 Kanebo Ltd Transparent cleansing cosmetic
KR20100014247A (en) * 2007-03-29 2010-02-10 가부시키가이샤 시세이도 Oil-in-water type emulsion composition
JP2011126809A (en) * 2009-12-17 2011-06-30 Kao Corp Cleansing cosmetic
JP2012214404A (en) * 2011-03-31 2012-11-08 Nof Corp Cleansing preparation
JP2014091734A (en) * 2012-11-06 2014-05-19 Nof Corp Cleansing cream

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