WO2019185975A1 - Diffractive grating - Google Patents
Diffractive grating Download PDFInfo
- Publication number
- WO2019185975A1 WO2019185975A1 PCT/FI2019/050149 FI2019050149W WO2019185975A1 WO 2019185975 A1 WO2019185975 A1 WO 2019185975A1 FI 2019050149 W FI2019050149 W FI 2019050149W WO 2019185975 A1 WO2019185975 A1 WO 2019185975A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- waveguide
- grating
- different
- stack
- wavelengths
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/10—Beam splitting or combining systems
- G02B27/1006—Beam splitting or combining systems for splitting or combining different wavelengths
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/01—Head-up displays
- G02B27/0101—Head-up displays characterised by optical features
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/01—Head-up displays
- G02B27/017—Head mounted
- G02B27/0172—Head mounted characterised by optical features
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/10—Beam splitting or combining systems
- G02B27/1086—Beam splitting or combining systems operating by diffraction only
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/42—Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect
- G02B27/4272—Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect having plural diffractive elements positioned sequentially along the optical path
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/42—Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect
- G02B27/4294—Diffraction optics, i.e. systems including a diffractive element being designed for providing a diffractive effect in multispectral systems, e.g. UV and visible
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1814—Diffraction gratings structurally combined with one or more further optical elements, e.g. lenses, mirrors, prisms or other diffraction gratings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1814—Diffraction gratings structurally combined with one or more further optical elements, e.g. lenses, mirrors, prisms or other diffraction gratings
- G02B5/1819—Plural gratings positioned on the same surface, e.g. array of gratings
- G02B5/1823—Plural gratings positioned on the same surface, e.g. array of gratings in an overlapping or superposed manner
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1847—Manufacturing methods
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1861—Reflection gratings characterised by their structure, e.g. step profile, contours of substrate or grooves, pitch variations, materials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1866—Transmission gratings characterised by their structure, e.g. step profile, contours of substrate or grooves, pitch variations, materials
- G02B5/1871—Transmissive phase gratings
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/203—Filters having holographic or diffractive elements
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/24—Coupling light guides
- G02B6/26—Optical coupling means
- G02B6/34—Optical coupling means utilising prism or grating
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/01—Head-up displays
- G02B27/0101—Head-up displays characterised by optical features
- G02B2027/0112—Head-up displays characterised by optical features comprising device for genereting colour display
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/01—Head-up displays
- G02B27/0101—Head-up displays characterised by optical features
- G02B2027/0112—Head-up displays characterised by optical features comprising device for genereting colour display
- G02B2027/0114—Head-up displays characterised by optical features comprising device for genereting colour display comprising dichroic elements
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/01—Head-up displays
- G02B27/017—Head mounted
- G02B27/0172—Head mounted characterised by optical features
- G02B2027/0174—Head mounted characterised by optical features holographic
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/0035—Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
- G02B6/004—Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles
- G02B6/0043—Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles provided on the surface of the light guide
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0075—Arrangements of multiple light guides
- G02B6/0076—Stacked arrangements of multiple light guides of the same or different cross-sectional area
Definitions
- the invention relates to diffractive optics.
- the invention relates to gratings that can be used to couple light into waveguides used in diffractive display elements and devices.
- the invention can be used in personal display devices, such as head-mounted displays (HMDs) and head-up displays (HUDs).
- Such displays typically comprise a waveguide and at least one grating arranged onto or into the waveguide.
- Waveguides are key image-forming elements in many modern personal display devices.
- the image to be displayed can be coupled into and out of the waveguide, as well as modified within the waveguide, using diffractive gratings arranged in the main plane of the waveguide, typically on its surface.
- diffractive gratings arranged in the main plane of the waveguide, typically on its surface.
- an in-coupling grating for coupling an image from a projector into the waveguide
- an exit pupil expander grating for expanding the light field in one or more in-plane dimensions of the waveguide
- an out-coupling grating which couples the light field out of the waveguide to the user's eye.
- Waveguides can be arranged as stacks whose layers carry different wavelengths, in order to provide multicolor displays.
- One aim in in- and out-coupling arrangements of such stacks is to make complete wavelength separation between the layers.
- at least part of rays intended to one layer is coupled to another layer.
- a particular aim is to provide novel solution for improving color separation in in- and/or out-coupling arrangements of multicolor waveguides, waveguide stacks and display devices.
- the invention provides a selective diffractive grating comprising a periodic alternating pattern of first material having a first dispersion curve, and second material having a second dispersion curve different from the first dispersion curve.
- the first and second dispersion curves intersect each other at two or more different wavelengths, thus making the grating fully transparent at these wavelengths. These wavelengths can be called intersection wavelengths.
- the invention provides a waveguide comprising a grating of the
- the grating can be an in-coupling or out-coupling grating, for example.
- a stack of gratings each adapted to be transparent for two of the wavelengths and‘visible’ for one of the wavelengths, respectively, using the principle herein disclosed.
- the invention provides a waveguide stack having multiple layers, at least one of which is a waveguide of the above kind.
- each of the layers comprises an in-coupling and/or out-coupling grating which as aligned with each other. Placing the inventive grating on the topmost waveguide layer, for example, allows for two wavelengths corresponding to the intersection wavelengths to pass the topmost layer without interacting therewith and to couple a third wavelength in the topmost layer.
- the present method of manufacturing a selectively transparent diffractive grating comprising
- the invention offers significant benefits.
- the two intersection wavelengths give full control of colors in three-color display waveguide elements implemented with a single waveguide or using stack of waveguides in which each layer is intended to carry one color only.
- the two other wavelengths continue through the grating and the waveguide without interaction.
- the present completely wavelength-independent control it is possible to use only one waveguide and still achieve the same wavelength-separation for three colors as with three separate monochromatic waveguides.
- the invention suits particularly well to be used with RGB laser image projector having narrow wavelength bands.
- Fig. 1 shows a cross-sectional view of a grating according to one embodiment.
- Fig. 2 shows an exemplary graph of suitable dispersion curves of two different materials.
- Fig. 3 shows a waveguide stack taking advantage of the invention according to one embodiment.
- Fig. 4 shows a single-layer waveguide taking advantage of the invention according to one embodiment.
- Fig. 1 shows a grating made of two layers of different materials.
- the first layer 1 1 has a first wavelength-dependent index of refraction ni and the second layer 12 has a second wavelength-dependent index of refraction n 2 .
- the materials are interleaved so as to form a periodic diffractive structure, i.e. a grating.
- the indices of refraction ni and n 2 define dispersion curves, which are adapted to intersect at two or more distinct wavelengths, for which the grating is non-diffractive, i.e. fully transparent.
- the grating is diffractive (i.e. diffracts into non zero transmission or reflection order, such as the +/-1 st order).
- a diffractive grating having two passbands is achieved.
- Fig. 2 An exemplary dispersion curve graph is shown in Fig. 2, showing curves ni and n 2 of the different materials.
- wavelengths li and l 2 correspond to the intersection
- Fig. 2 illustrates a beneficial situation where the dispersion curves have suitably different "curvatures" so that they intersect twice at the visible wavelength range.
- At least one of the materials is silicon nitride, in particular amorphous hydrogenated silicon nitride (SiN x ). Its stoichiometry x can be tuned so as to make it suitable for the present use. Similar effect can be achieved with other materials, too, some of which are discussed below.
- at least one of the materials is titanium dioxide (Ti0 2 ), hafnium dioxide (Hf0 2 ) or zirkonium dioxide (Zr0 2 ) as such or as mixed oxides in various stoichiometric forms. These can be used with one another in suitable stoichiometry and, in particular, as co-materials with SiN x to achieve the present grating.
- the grating is formed of one of the following material pairs: SiNx- Ti02, SiNx-Hf02 or SiNx-Zr02.
- the different materials have the same elementary components but have stoichiometries adjusted so as to give the materials the different dispersion curves.
- Tuning of Ti0 2 and Hf0 2 mixed oxide dispersion curves is discussed e.g. by Mazur M., et al, Influence of Material Composition on Structural and Optical Properties of Hf02-Ti02 Mixed Oxide Coatings, Coatings 2016, 6, 13. Tuning of Ti0 2 dispersion curves is discussed in Huang Y., et al, Characterization of low temperature deposited atomic layer deposition Ti0 2 for MEMS applications, J. Vac. Sci. Technol. A, Vol. 31 , No. 1 , Jan/Feb 2013.
- the different wavelengths are in the visible wavelength range, preferably separated by at least 50 nm.
- the present grating is arranged on one or both of the main surfaces of a waveguide or within a waveguide.
- the present diffractive waveguide stack comprises at least two superimposed waveguide layers, at least one of which comprises a waveguide as discussed herein.
- the grating is optically connected to the waveguide so that at least at some other wavelengths than the wavelengths at which the dispersion curves intersect, the grating is capable of coupling light into the waveguide and/or interacting with the light field of the waveguide some other way.
- Fig. 3 shows an exemplary stack comprising three waveguide layers 30A-C, each of which has an in-coupling grating 33A-C, respectively, arranged thereon.
- the grating 33A of the topmost layer 30A is of the kind discussed here. Thus, it allows rays at wavelengths li and l 2 to pass through the layer 30A unobstructed, but couples rays at wavelength li into the layer 30A.
- the next layer 30B and grating 33B are configured to pass wavelength li to layer 30C and to couple wavelength l 2 to the layer 30B.
- the last grating 33C couples wavelengths li into the last layer 30C.
- the second and/or third gratings are also gratings according to the present invention, however having differently tuned transmission wavelengths, for preventing coupling of rays having adversely passed the upper layers to couple into the lower layers.
- filters can be used between the layers to prevent incompletely coupled rays to couple to the next layers.
- filters can be used between the layers to prevent incompletely coupled rays to couple to the next layers.
- a similar arrangement can be used in an out-coupler or exit pupil expander of the waveguide element.
- color separation can be achieved using a single waveguide layer and "virtual monochromatization", as described below with the aid of an example.
- Fig. 4 shows an exemplary single waveguide 40 comprising an in-coupler 45 having three in-coupling gratings 43A-C, respectively, arranged thereon as a grating stack.
- the gratings 43A-C are configured suitably in accordance with the invention so that each grating is transparent to two of the three wavelengths l ⁇ 5 l 2 , l 3 used and is therefore only visible to, i.e. diffracts, the third wavelength.
- the gratings 43A-C are all different with respect to each other so that all wavelengths will be coupled to the waveguide 40.
- a single physical waveguide 40 may guide all wavelengths necessary to produce a multicolor image but appears virtually as three monochromatic waveguides, where the different wavelengths can be controlled separately.
- This embodiment gives better control of light rays inside a single waveguide than is possible with gratings designed to work for all wavelengths simultaneously.
- the periods of the gratings can be chosen relatively freely, for example such that for each wavelength used, the diffraction angle is the same.
- the stack of gratings can be effectively achromatic.
- a similar grating stack can be used as an exit pupil expander (EPE) 46 and/or as an out-coupler 47. This way, the control of colors remains throughout the waveguide.
- EPE exit pupil expander
- intersection wavelengths of the stack of gratings is adapted so that each grating has one intersection wavelength common with one intersection wavelength other grating of the stack.
- the three wavelengths used are typically selected in the blue, green and red visible wavelength ranges.
- the present personal display device comprises a waveguide or waveguide stack of the above kind, serving as the display element of the device.
- a projector for projecting an image into the waveguide or waveguide stack at least partly through and with the aid of the grating.
- the projector is a multicolor projector adapted to emit light rays at least at three different wavelengths, two of which correspond to said different wavelengths to which the grating is transparent.
- the intersection wavelengths of the gratings can be suitably permuted with the three wavelengths of the projector.
- the projector is a three-color laser projector.
- the intersection wavelengths are set to correspond to two of the three colors, whereas at the wavelength of the third color, the indices of refraction of the two different materials differ sufficiently so as to cause significant diffraction. At that wavelength, the indices may differ for example by 0.05 units or more, in particular by 0.1 units or more, for achieving a decent diffraction efficiency.
- the grating finds uses also in out- coupling arrangements and exit pupil expander arrangements.
- the grating may be a linear grating with periodicity in one direction only or a two- dimensional grating with periodicity in two dimensions.
- the grating may form a separate entity on or within the waveguide or one of the grating materials may be unitary with the waveguide.
- the grating features may take any desired profile, such as a blazed profile. Gratings of the present kind may be used as parts of larger diffractive optical elements.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Diffracting Gratings Or Hologram Optical Elements (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP19774459.2A EP3732530B1 (en) | 2018-03-28 | 2019-02-25 | Diffractive grating |
| CN201980010969.8A CN111670403B (zh) | 2018-03-28 | 2019-02-25 | 衍射光栅 |
| JP2020545653A JP7587821B2 (ja) | 2018-03-28 | 2019-02-25 | 回折格子 |
| CA3095242A CA3095242A1 (en) | 2018-03-28 | 2019-02-25 | Diffractive grating |
| KR1020207023667A KR102733556B1 (ko) | 2018-03-28 | 2019-02-25 | 회절 격자 |
| SG11202008106PA SG11202008106PA (en) | 2018-03-28 | 2019-02-25 | Diffractive grating |
| US17/041,308 US12032182B2 (en) | 2018-03-28 | 2019-02-25 | Diffractive grating |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20185294 | 2018-03-28 | ||
| FI20185294A FI129359B (en) | 2018-03-28 | 2018-03-28 | Diffractive grating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2019185975A1 true WO2019185975A1 (en) | 2019-10-03 |
Family
ID=68060972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/FI2019/050149 Ceased WO2019185975A1 (en) | 2018-03-28 | 2019-02-25 | Diffractive grating |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US12032182B2 (https=) |
| EP (1) | EP3732530B1 (https=) |
| JP (1) | JP7587821B2 (https=) |
| KR (1) | KR102733556B1 (https=) |
| CN (1) | CN111670403B (https=) |
| CA (1) | CA3095242A1 (https=) |
| FI (1) | FI129359B (https=) |
| SG (1) | SG11202008106PA (https=) |
| WO (1) | WO2019185975A1 (https=) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11106048B2 (en) | 2014-08-08 | 2021-08-31 | Digilens Inc. | Waveguide laser illuminator incorporating a despeckler |
| US11194098B2 (en) | 2015-02-12 | 2021-12-07 | Digilens Inc. | Waveguide grating device |
| US11194162B2 (en) | 2017-01-05 | 2021-12-07 | Digilens Inc. | Wearable heads up displays |
| US11281013B2 (en) | 2015-10-05 | 2022-03-22 | Digilens Inc. | Apparatus for providing waveguide displays with two-dimensional pupil expansion |
| US11378732B2 (en) | 2019-03-12 | 2022-07-05 | DigLens Inc. | Holographic waveguide backlight and related methods of manufacturing |
| WO2022150841A1 (en) * | 2021-01-07 | 2022-07-14 | Digilens Inc. | Grating structures for color waveguides |
| US11442222B2 (en) | 2019-08-29 | 2022-09-13 | Digilens Inc. | Evacuated gratings and methods of manufacturing |
| US11448937B2 (en) | 2012-11-16 | 2022-09-20 | Digilens Inc. | Transparent waveguide display for tiling a display having plural optical powers using overlapping and offset FOV tiles |
| US11487131B2 (en) | 2011-04-07 | 2022-11-01 | Digilens Inc. | Laser despeckler based on angular diversity |
| US11543594B2 (en) | 2019-02-15 | 2023-01-03 | Digilens Inc. | Methods and apparatuses for providing a holographic waveguide display using integrated gratings |
| US11561409B2 (en) | 2007-07-26 | 2023-01-24 | Digilens Inc. | Laser illumination device |
| US11604314B2 (en) | 2016-03-24 | 2023-03-14 | Digilens Inc. | Method and apparatus for providing a polarization selective holographic waveguide device |
| US11703799B2 (en) | 2018-01-08 | 2023-07-18 | Digilens Inc. | Systems and methods for high-throughput recording of holographic gratings in waveguide cells |
| US11726332B2 (en) | 2009-04-27 | 2023-08-15 | Digilens Inc. | Diffractive projection apparatus |
| US11726329B2 (en) | 2015-01-12 | 2023-08-15 | Digilens Inc. | Environmentally isolated waveguide display |
| US11726323B2 (en) | 2014-09-19 | 2023-08-15 | Digilens Inc. | Method and apparatus for generating input images for holographic waveguide displays |
| US11747568B2 (en) | 2019-06-07 | 2023-09-05 | Digilens Inc. | Waveguides incorporating transmissive and reflective gratings and related methods of manufacturing |
| US12092914B2 (en) | 2018-01-08 | 2024-09-17 | Digilens Inc. | Systems and methods for manufacturing waveguide cells |
| US12140764B2 (en) | 2019-02-15 | 2024-11-12 | Digilens Inc. | Wide angle waveguide display |
| US12158612B2 (en) | 2021-03-05 | 2024-12-03 | Digilens Inc. | Evacuated periodic structures and methods of manufacturing |
| US12210153B2 (en) | 2019-01-14 | 2025-01-28 | Digilens Inc. | Holographic waveguide display with light control layer |
| US12298513B2 (en) | 2016-12-02 | 2025-05-13 | Digilens Inc. | Waveguide device with uniform output illumination |
| US12306585B2 (en) | 2018-01-08 | 2025-05-20 | Digilens Inc. | Methods for fabricating optical waveguides |
| US12397477B2 (en) | 2019-02-05 | 2025-08-26 | Digilens Inc. | Methods for compensating for optical surface nonuniformity |
| US12596218B2 (en) | 2012-04-25 | 2026-04-07 | Digilens Inc. | Holographic wide angle display |
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| FI128573B (en) * | 2018-03-28 | 2020-08-14 | Dispelix Oy | Waveguide display element |
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| US12118951B2 (en) * | 2022-08-17 | 2024-10-15 | Ii-Vi Delaware, Inc. | Display system with optical device |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP3732530A1 (en) | 2020-11-04 |
| JP2021516779A (ja) | 2021-07-08 |
| FI129359B (en) | 2021-12-31 |
| FI20185294A1 (en) | 2019-09-29 |
| CN111670403B (zh) | 2022-04-08 |
| SG11202008106PA (en) | 2020-09-29 |
| EP3732530C0 (en) | 2023-07-26 |
| EP3732530B1 (en) | 2023-07-26 |
| KR102733556B1 (ko) | 2024-11-26 |
| US12032182B2 (en) | 2024-07-09 |
| US20210080628A1 (en) | 2021-03-18 |
| CA3095242A1 (en) | 2019-10-03 |
| CN111670403A (zh) | 2020-09-15 |
| JP7587821B2 (ja) | 2024-11-21 |
| EP3732530A4 (en) | 2021-09-15 |
| KR20200136887A (ko) | 2020-12-08 |
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