WO2019064851A1 - 毛髪処理用組成物及び毛髪処理用ミスト化粧料 - Google Patents
毛髪処理用組成物及び毛髪処理用ミスト化粧料 Download PDFInfo
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- WO2019064851A1 WO2019064851A1 PCT/JP2018/027366 JP2018027366W WO2019064851A1 WO 2019064851 A1 WO2019064851 A1 WO 2019064851A1 JP 2018027366 W JP2018027366 W JP 2018027366W WO 2019064851 A1 WO2019064851 A1 WO 2019064851A1
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- hair
- composition
- hair treatment
- polyoxyethylene
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
Definitions
- the present invention relates to a hair treatment composition which is filled in a container and discharged in a mist form by a pump dispenser or a trigger dispenser. Further, the present invention relates to a mist cosmetic for hair treatment using the composition for hair treatment.
- Hair treatment compositions are known which are filled in a container and discharged in the form of a mist by means of a pump dispenser or trigger dispenser.
- a pump dispenser or trigger dispenser When the composition is discharged in the form of a mist, the composition can be uniformly applied to the hair in a wide range, and since dripping from the hair after application can be suppressed, the feeling of use is excellent.
- composition for hair treatment discharged in the form of mist hair styling performance is imparted or conditioning performance is imparted depending on the composition design.
- composition for hair treatment which can be discharged in the form of mist is disclosed in the following Patent Documents 1 to 3.
- Patent Document 1 listed below contains 0.01 to 10.0% by weight of a vinylpyrrolidone polymer having a weight average molecular weight of 1,000 or more and less than 160,000, and a vinylpyrrolidone polymer having a weight average molecular weight of 160,000 to 30,000 or less.
- a composition comprising 0.01 to 5.0% by weight of water is disclosed. This composition may be discharged in the form of a mist.
- Patent Document 2 discloses a composition containing a hydroxyalkyl urea, an alkylene oxide derivative, and a hydrophilic polyether-modified silicone. This composition may be discharged in the form of a mist.
- Patent Document 3 discloses a composition containing two types of copolymers having specific structural units, ethanol, and water. This composition is a composition discharged in the form of a mist.
- a film-forming component film-forming polymer capable of forming a strong film on hair is exhibited in order to exhibit excellent hair setting properties. It is often done.
- the film-forming component film-forming polymer
- excellent hair-setting performance can be imparted.
- a film-forming component film-forming polymer
- the film formed between the hair becomes too hard, and the hair style is shaped by external impact such as hand comb or wind. Is easy to break down.
- the film formed between the hairs collapses, it is not possible to hold the hair styling hairstyle for a long time.
- the hair style which has been trimmed due to an external impact is likely to be broken, and it may not be possible to hold the styled hair style for a long time.
- the object of the present invention is to fill in a container and discharge in a mist form by a pump type dispenser or a trigger type dispenser, so that the styled haircut is less likely to be broken even if it receives an external impact, and the hair is shaped It is providing the composition for hair treatment which can hold
- Another object of the present invention is to provide a hair treatment mist cosmetic using the above-mentioned composition for treating hair.
- the present invention is a composition for treating hair which is filled in a container and discharged in the form of a mist by a pump dispenser or a trigger dispenser, which comprises the following component (A), the following component (B), and There is provided a hair treatment composition comprising component (C).
- Component (A) Film-forming polymer
- Component (B) Alkylene oxide addition polymer of sugar alcohol
- Component (C) Ethanol
- the component (A) preferably contains the following component (A1).
- Component (A1) Anionic film-forming polymer obtained by using alkyl (meth) acrylate as an essential monomer component
- the component (A) preferably contains the following component (A11).
- Anionic film-forming polymer selected from the group consisting of Component (A11): (Acrylate / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer, and (alkyl acrylate / diacetone acrylamide) copolymer
- the component (B) preferably contains the following component (B1).
- Component (B1) Polyoxypropylene Sorbit
- composition for treating hair of the present invention preferably contains the following component (D).
- the component (D) preferably contains the following component (D1).
- Component (D1) nonionic surfactant selected from the group consisting of polyoxyethylene glyceryl monoisostearate, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene butylene glycol monoisostearate, and polyoxyethylene hydrogenated castor oil Agent
- the hair treatment composition of the present invention is preferably a hair setting composition.
- the present invention comprises a container having a container body and a pump dispenser or trigger dispenser, and the composition for treating hair described above, wherein the composition for treating hair is filled in the container. To provide mist cosmetics.
- the composition for treating hair according to the present invention is a composition for treating hair which is filled in a container and discharged in a mist form by a pump dispenser or a trigger dispenser.
- the hair treatment composition of the present invention contains the specific component (A), component (B) and component (C), so it is filled in a container and made into a mist by a pump dispenser or trigger dispenser. When discharged, it is difficult for the hair styling to be broken even if it receives an external impact, and it is possible to hold the hair styling for a long time.
- the composition for treating hair of the present invention is filled in a container, and is discharged in the form of a mist by a pump dispenser or a trigger dispenser.
- the hair treatment composition of the present invention is discharged in the form of a mist, so it is generally a liquid composition that is liquid at 25 ° C.
- the mist shape includes a mist shape.
- the hair treatment composition of the present invention contains a film-forming polymer, an alkylene oxide addition polymer of a sugar alcohol, and ethanol.
- component (A) the above-mentioned “film-forming polymer” may be referred to as “component (A)".
- component (B) alkylene oxide addition polymerization product of sugar alcohol
- the hair treatment composition of the present invention contains component (A), component (B), and component (C).
- the present inventors adopt a composition containing the component (A), the component (B), and the component (C) in the composition for treating hair, and a film in which the adhesion between hairs is maintained for a long time I found that I could form it.
- the hair style which has been hair-dressed is less likely to be broken even under external impact, and the hair-styled hair style can be held for a long time.
- the hair treatment composition of the present invention preferably contains a nonionic surfactant.
- nonionic surfactant may be referred to as “component (D)".
- composition for treating hair of the present invention may contain other components other than the components (A) to (D).
- component (A), component (B), component (C), component (D) and other components may be used alone or in combination of two or more. It is also good.
- Component (A) is a film-forming polymer. Component (A) functions as a main hair styling component. In addition, by using the component (A) together with the component (B) and the component (C), the hair styling that has been hair-dressed is unlikely to be broken even when receiving an external impact, and the hair styling can be held for a long time. As the component (A), only one type may be used, or two or more types may be used in combination.
- an anionic film formation polymer As said component (A), an anionic film formation polymer, a cationic film formation polymer, an amphoteric film formation polymer, a nonionic film formation polymer, etc. are mentioned.
- anionic film-forming polymer examples include alkyl (meth) acrylate copolymers, (meth) acrylic acid / alkyl (meth) acrylate copolymers, (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) Acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer, methyl vinyl ether / maleic ester copolymer, vinyl acetate / crotonic acid copolymer, vinyl acetate / crotonic acid / vinyl neodecanoate copolymer Combined, vinyl acetate / crotonic acid / vinyl propionate copolymer, vinyl acetate / monobutyl monobutyl ester / isoborolyl acrylate copolymer, polyvinyl pyrrolidone / acrylate / (meth) acrylic acid copolymer, (styrene / (
- Examples of the above-mentioned cationic film-forming polymer include vinyl pyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose chloride, Vinylimidazolium trichloride / vinylpyrrolidone copolymer, hydroxyethyl cellulose / dimethyldiallyl ammonium chloride, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, methylvinylimidazolium chloride / vinylpyrrolidone copolymer, and (vinylpyrrolidone / (vinylpyrrolidone / Examples include dimethylaminopropyl methacrylamide / lauryl dimethylaminopropyl methacrylamide) copolymer and the like.
- nonionic film-forming polymer examples include polyvinyl alcohol, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, vinyl methyl ether / ethyl maleate copolymer, polyvinyl caprolactam and the like.
- A) preferably comprises an anionic film-forming polymer obtained using alkyl (meth) acrylate as the essential monomer component.
- anionic film-forming polymer obtained by using alkyl (meth) acrylate as an essential monomer component may be referred to as "component (A1)".
- the component (A) contains the component (A1).
- Component (A) is an anionic film-forming polymer selected from the group consisting of (alkyl acrylate / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer, and (alkyl acrylate / diacetone acrylamide) copolymer It is more preferred to include (at least one anionic film-forming polymer).
- an anionic film formation selected from the group consisting of the above-mentioned "(acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer, and (alkyl acrylate / diacetone acrylamide) copolymer"
- the polymer may be referred to as "component (A11)".
- the component (A) contains the component (A11).
- composition for treating hair according to the present invention comprises (Acrylatez / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer and (alkyl acrylate / diacetone acrylamide) copolymer as the component (A11).
- Acrylatez / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer and (alkyl acrylate / diacetone acrylamide) copolymer as the component (A11).
- the component (A11) is a sodium salt, an ammonium salt, a triethanolamine salt, a 2-amino-2-methyl-1-propanol salt (AMP), and a 2-amino-2-methyl-1,3-propanediol salt It may be neutralized using (AMPD) or the like.
- the content of the component (A) is preferably 2% by mass or more, more preferably 3% by mass or more, preferably 10% by mass or less, and more preferably 8% by mass in 100% by mass of the composition for hair treatment of the present invention It is below.
- the content of the component (A) is equal to or more than the above lower limit, the hair styling becomes more difficult to break, and the hair styling can be held for a long time.
- the content of the component (A) is less than or equal to the above upper limit, the occurrence of clogging due to the hair treatment composition remaining in the discharge port of the dispenser can be suppressed.
- the content of component (A) is the sum of the content of all components (A) in the hair treatment composition of the present invention.
- the content of the component (A1) is preferably 2% by mass or more, more preferably 3% by mass or more, preferably 10% by mass or less, more preferably 8% by mass in 100% by mass of the composition for hair treatment of the present invention It is below.
- the content of the component (A1) is equal to or more than the above lower limit, the hair styling becomes more difficult to break, and the hair styling can be held for a long time.
- the content of the component (A1) is less than or equal to the above upper limit, the occurrence of clogging due to the hair treatment composition remaining in the discharge port of the dispenser can be suppressed.
- the content of the component (A1) is the sum of the content of all the components (A1) in the hair treatment composition of the present invention.
- the content of the component (A11) is preferably 2% by mass or more, more preferably 3% by mass or more, preferably 10% by mass or less, more preferably 8% by mass in 100% by mass of the composition for hair treatment of the present invention It is below.
- the content of the component (A11) is equal to or more than the above lower limit, the hair styling becomes more difficult to break, and the hair styling can be held for a long time.
- the content of the component (A11) is less than or equal to the above upper limit, the occurrence of clogging due to the hair treatment composition remaining in the discharge port of the dispenser can be suppressed.
- the content of component (A11) is the sum of all components (A11) in the hair treatment composition of the present invention.
- Component (B) is an alkylene oxide addition polymer of sugar alcohol. By using the component (B), adhesion can be imparted between the hairs. In addition, by using the component (B) together with the component (A) and the component (C), the hair styling that has been hair-dressed is less likely to be broken even under external impact, and the hair styling can be held for a long time. As the component (B), only one type may be used, or two or more types may be used in combination.
- Component (B) can be obtained, for example, by adding alkylene oxide to a sugar alcohol.
- sugar alcohol include sorbitol and maltitol.
- alkylene oxide (oxyalkylene group) include ethylene oxide (oxyethylene group) and propylene oxide (oxypropylene group).
- Component (B) is a polyoxypropylene from the viewpoint of making it more difficult for the hair styling to be broken even if it receives an external impact by enhancing the adhesion between the hairs, and for holding the hair styling for a longer time. It is preferred to include a sorbite. Polyoxypropylene sorbite is a propylene oxide addition polymer of sorbitol.
- polyoxypropylene sorbite may be referred to as “component (B1)”.
- the component (B) contains the component (B1).
- Component (B1) is a component different from component (D).
- the number average molecular weight of the component (B1) is not particularly limited.
- the number average molecular weight of the component (B1) is preferably 200 or more, more preferably 300 or more, preferably 1000 or less, more preferably 900 or less, from the viewpoint of imparting good cohesion between hairs having a hair set.
- the content of the component (B) is preferably 2% by mass or more, more preferably 2.5% by mass or more, preferably 10% by mass or less, more preferably 7% by mass in 100% by mass of the composition for hair treatment of the present invention It is less than mass%.
- the content of component (B) is the sum of the content of all components (B) in the hair treatment composition of the present invention.
- the content of the component (B1) is preferably 2% by mass or more, more preferably 2.5% by mass or more, preferably 10% by mass or less, more preferably 7% by mass in 100% by mass of the composition for hair treatment of the present invention It is less than mass%.
- the content of the component (B1) is the sum of the content of all the components (B1) in the hair treatment composition of the present invention.
- Component (C) is ethanol.
- the hair treatment composition can be favorably discharged in the form of a mist, and the discharge stability of the hair treatment composition can be enhanced. Furthermore, by using the component (C), it is possible to improve quick drying during application and reduce stickiness.
- the content of the component (C) is preferably 30% by mass or more, more preferably 35% by mass or more, still more preferably 40% by mass or more, preferably 95% by mass in 100% by mass of the composition for hair treatment of the present invention
- the content is more preferably 90% by mass or less, still more preferably 80% by mass or less.
- Component (D) is a nonionic surfactant. By using the component (D), it is easy to stir the hair and make a thick hair bundle. Moreover, the hair setting performance by a component (A) can be improved effectively by using a component (D). Moreover, the composition for hair treatment can be favorably discharged by using the component (D). As the component (D), only one type may be used, or two or more types may be used in combination.
- linear type polyoxyalkylene fatty acid ester such as polyethylene glycol fatty acid ester, polyoxyethylene alkyl ether fatty acid ester; polyoxyethylene butylene glycol ether fatty acid ester, polyoxyethylene glycerin ether fatty acid ester, poly Multi-chain type polyoxyalkylene fatty acid esters such as oxyethylene sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil ether, polyoxyethylene hydrogenated castor oil ether fatty acid ester, polyoxyethylene trimethylol propane ether fatty acid ester; polyoxyethylene alkyl ether, Polyoxyalkylene alkyl ether such as polyoxyethylene / polyoxypropylene alkyl ether; Glycerin fat Esters, polyglycerol fatty acid esters, sorbitan fatty acid esters, fatty acid esters such as alkylene glycol fatty acid esters, and the like.
- polyoxyethylene butylene glycol ether fatty acid ester examples include polyoxyethylene butylene glycol isostearate and polyoxyethylene butylene glycol diisostearate.
- the average addition mole number of ethylene oxide (polyoxyethylene group) of the polyoxyethylene butylene glycol ether fatty acid ester is not particularly limited, but is preferably 5 or more, and more preferably 70 or less.
- polyoxyethylene glycerin ether fatty acid ester examples include polyoxyethylene glyceryl monolaurate, polyoxyethylene glyceryl monostearate, polyoxyethylene glyceryl distearate, polyoxyethylene glyceryl tristearate, and polyoxyethylene glyceryl monooleate.
- polyoxyethylene glyceryl trioleate polyoxyethylene glyceryl monoisostearate, polyoxyethylene glyceryl diisostearate, and polyoxyethylene glyceryl triisostearate.
- the average addition mole number of ethylene oxide (polyoxyethylene group) of the polyoxyethylene glycerin ether fatty acid ester is not particularly limited, but is preferably 3 or more, and preferably 70 or less.
- polyoxyethylene sorbitan fatty acid ester examples include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monooleate, and polyoxyethylene sorbitan monoisostearate. And monocobalt oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, and polyoxyethylene sorbitan trioleate.
- the average addition mole number of ethylene oxide (polyoxyethylene group) of the polyoxyethylene sorbitan fatty acid ester is not particularly limited, but is preferably 10 or more, and more preferably 200 or less.
- polyoxyethylene hydrogenated castor oil ether polyoxyethylene hydrogenated castor oil etc. are mentioned, for example.
- the average addition mole number of ethylene oxide (polyoxyethylene group) of the polyoxyethylene hydrogenated castor oil ether is not particularly limited, but is preferably 10 or more, and preferably 120 or less.
- polyoxyethylene hydrogenated castor oil ether fatty acid ester examples include polyoxyethylene hydrogenated castor oil with monolaurate, polyoxyethylene hydrogenated castor oil with monoisostearate, and polyoxyethylene hydrogenated castor oil with triisostearate.
- the average addition mole number of ethylene oxide (polyoxyethylene group) of the polyoxyethylene hydrogenated castor oil ether fatty acid ester is not particularly limited, but is preferably 3 or more, and preferably 70 or less.
- polyoxyethylene trimethylolpropane ether fatty acid ester examples include polyoxyethylene trimethylolpropane trimyristate, polyoxyethylene trimethylolpropane distearate, polyoxyethylene trimethylolpropane tristearate and polyoxytriisostearate. Ethylene trimethylol propane and the like can be mentioned.
- the average addition mole number of ethylene oxide (polyoxyethylene group) of the polyoxyethylene trimethylolpropane ether fatty acid ester is not particularly limited, but is preferably 3 or more, and more preferably 50 or less.
- (D) preferably contains a multi-chain type polyoxyalkylene fatty acid ester.
- the component (D) contains a multi-chain type polyoxyalkylene fatty acid ester.
- Component (D) is a nonionic selected from the group consisting of polyoxyethylene glyceryl monoisostearate, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene butylene glycol monoisostearate, and polyoxyethylene hydrogenated castor oil It is more preferred to include a surfactant (at least one non-ionic surfactant).
- the surfactant may be referred to as "component (D1)”.
- the component (D) contains the component (D1).
- the content of the component (D) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, preferably 5% by mass or less, in 100% by mass of the composition for hair treatment of the present invention Is 4% by mass or less.
- the content of the component (D) is at least the above lower limit and the above upper limit, the hair styling performance by the component (A) is more effectively enhanced, and the hair styling hairstyle becomes even more difficult to break, and hair styling is performed The hairstyle can be held longer.
- the content of the component (D) is not less than the lower limit and not more than the upper limit, the hair treatment composition can be discharged more favorably.
- the content of component (D) is the sum of the content of all components (D) in the composition for hair treatment of the present invention.
- the content of the component (D1) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, preferably 5% by mass or less, in 100% by mass of the composition for hair treatment of the present invention Is 4% by mass or less.
- the content of the component (D1) is not less than the above lower limit and not more than the above upper limit, hair styling performance by the component (A) is more effectively enhanced, and the hair styling hairstyle becomes more difficult to break, and hair styling is performed The hairstyle can be held longer.
- the content of the component (D1) is not less than the lower limit and not more than the upper limit, the composition for treating hair can be more favorably discharged.
- the content of component (D1) is the sum of the content of all components (D1) in the hair treatment composition of the present invention.
- the hair treatment composition of the present invention may contain water, as long as the effects of the present invention are not impaired.
- the content of water is preferably 60% by mass or less, more preferably 50% by mass or less in 100% by mass of the composition for treating hair of the present invention is there.
- the water content is equal to or less than the above upper limit, the composition for treating hair can be favorably discharged in the form of mist, and the fast drying property at the time of application can be favorably improved and the stickiness can be favorably reduced.
- composition for treating hair according to the present invention comprises, as components different from the components (A) to (D) mentioned above, polyhydric alcohols, higher alcohols having 12 to 18 carbon atoms, ester oils, hydrocarbon oils, oils and fats, silicone oils And sequestering agents, antioxidants, plant extracts, pigments, pH adjusters, flavors, preservatives and the like.
- polyhydric alcohol examples include glycerin, diglycerin, 1,3-butylene glycol, propylene glycol, dipropylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1 And 2-octanediol, 1,2-decanediol, and polyoxypropylene methyl glucoside.
- Examples of the higher alcohol having 12 to 18 carbon atoms include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol and the like.
- ester oil examples include isopropyl palmitate, glyceryl tri-2-ethylhexanoate, isopropyl myristate, propylene glycol monostearate, propylene glycol monolaurate, and polyglyceryl isostearate.
- hydrocarbon oil examples include liquid paraffin, petrolatum, squalene, squalane and the like.
- fats and oils olive oil, camellia oil, macadamia nut oil, and avocado oil etc. are mentioned, for example.
- silicone oil examples include methyl polysiloxane, methyl phenyl polysiloxane, and methyl hydrogen polysiloxane.
- composition for hair treatment of this invention does not contain a solid wax at 25 degreeC.
- the composition for treating hair according to the present invention preferably contains no hydrocarbon oil which is solid at 25 ° C.
- the hair treatment composition of the present invention can be produced by a known method for producing a hair treatment composition.
- the composition for hair treatment of the present invention is not particularly limited, it can be produced, for example, by mixing the component (A), the component (B), the component (C) and the other components.
- a paddle mixer etc. can be used for mixing.
- the composition for treating hair according to the present invention is characterized in that it is filled in a container and discharged in the form of a mist by a pump dispenser or a trigger dispenser.
- the hair treatment composition of the present invention is used for a hair treatment mist cosmetic.
- the hair treatment composition of the present invention can be applied uniformly over a wide range without dripping to the hair, and hair styling can be performed without sticky feeling.
- a film capable of maintaining the adhesion between hair for a long time can be formed well, and hair styling can be performed even if it receives an external impact.
- the hairstyle is less likely to break down, and it is possible to hold the styled hairstyle for a longer time.
- the mist cosmetic for hair treatment of the present invention comprises a container and the composition for hair treatment described above.
- the container has a container body and a pump dispenser or trigger dispenser.
- the composition for hair treatment is filled in the container.
- the container body preferably has an opening. It is preferable that the pump dispenser or the trigger dispenser is attached to the opening of the container body.
- the amount by which the hair treatment composition of the present invention is discharged by one discharge operation of the pump dispenser or the trigger dispenser is not particularly limited as long as the effect of the present invention is exhibited.
- the amount of the hair treatment composition of the present invention to be discharged is preferably 0.05 mL / once or more, from the viewpoint of being able to uniformly apply over a wide range without dripping to the hair and achieving hair setting without feeling of stickiness. More preferably, it is 0.15 mL / 1 or more, preferably 1.0 mL / 1 or less, more preferably 0.5 mL / 1 or less.
- the container having the container body and the pump dispenser or the trigger dispenser is not particularly limited as long as it can discharge the hair treatment composition of the present invention in the form of a mist.
- a pump type dispenser for example, Y-150 (discharge amount: about 0.15 mL / once) made by Yoshino Kogyosho, and Z-155 (discharge amount: about 0 made by Mitani Valve Co., Ltd.) 15 mL / once) and the like.
- M3-M discharge volume: about 0.5 mL / once
- Z-305, T-305 by Mitani Valve Co., Ltd.
- a container body is filled with a composition for hair treatment, a pump dispenser or a trigger dispenser, and a container body filled with the composition for hair treatment And so on.
- the hair treatment composition of the present invention is suitably used as a hair styling agent composition since the hair styling that has been trimmed is unlikely to be broken even if it receives an external impact, and the hair styling that has been hair styling can be held for a long time.
- the hair treatment composition of the present invention may also be used to hold a hair styling hair using a hair styling composition comprising a solid wax at 25 ° C. or a hydrocarbon oil solid at 25 ° C., such as a hair wax. Can.
- the composition for treating hair according to the present invention can be used by applying to a hair set using a hair setting composition containing a solid wax at 25 ° C. such as a hair wax or a hydrocarbon oil solid at 25 ° C. .
- the hair treatment composition of the present invention is a post-treatment agent composition
- the hair treatment mist cosmetic of the present invention is a post-treatment agent.
- the hairdressing agent composition containing wax solid at 25 ° C. or hydrocarbon oil solid at 25 ° C. may contain wax solid at 25 ° C., and may contain hydrocarbon oil solid at 25 ° C. It may well contain waxes that are solid at 25 ° C and hydrocarbon oils that are solid at 25 ° C.
- the hair treatment composition of the present invention is preferably a post-treatment composition used for hair that has been hairdressed by the hairdressing composition.
- the mist cosmetic for hair treatment of the present invention is preferably a post-treatment agent used for hair that has been hairdressed by the hairdressing composition.
- Hair that has been trimmed using a hair styling composition that contains a solid wax at 25 ° C. or a hydrocarbon oil that is solid at 25 ° C., such as hair wax has the advantage of being able to freely restyle hair, but has inferior hair retention.
- a hairdressing style for a long time.
- the hair treatment composition of the present invention is applied to a hair set using a hair setting composition containing a solid wax at 25 ° C. or a hydrocarbon oil solid at 25 ° C., such as a hair wax, external treatment Even if it receives an impact, the styled haircut is unlikely to collapse, and it becomes possible to hold the styled haircut for a long time.
- composition for treating hair of the present invention is a solid wax at 25 ° C. such as hair wax or a solid at 25 ° C.
- a hair styling composition containing a hydrocarbon oil By localizing on the surface of hair styled using a hair styling composition containing a hydrocarbon oil, adhesion between hair styled hair is more effectively imparted, and it receives external impact. It is considered that a film is formed which is hard to break the hairdressing hairstyle, and that the hairdressing hairstyle can be held for a long time.
- Component (A) (Acrylate / alkyl acrylate (C1-18) / alkyl (C1-8) acryl amide) copolymer: trade name “Plasize L-9909 U”, manufactured by Hikaru Kagaku Kogyo Co., Ltd. (alkyl acrylate / diacetone acrylamide) copolymer: trade name "Plastic size L-9540U", made by Kayaku Chemical Industry Co., Ltd.
- Component (B) Polyoxypropylene Sorbit (number average molecular weight 700): trade name "Sannicks SP-750", manufactured by Sanyo Chemical Industries, Ltd.
- Component (D) Polyoxyethylene glyceryl monoisostearate 1 (average added mole number of oxyethylene group: 20): trade name "braunone RGL-20 MISE” manufactured by Aoki Yushi Kogyo Co., Ltd. polyoxyethylene glyceryl monoisostearate 2 (average added mole of oxyethylene group) Number 25): trade name "EMALEX GWIS-125", manufactured by Nippon Emulsion Co., Ltd., polyoxyethylene glyceryl monoisostearate 3 (average added mole number of oxyethylene group: 30): trade name "EMALEX GWIS-130", manufactured by Nippon Emulsion Co., Ltd.
- Polyoxyethylene glyceryl monoisostearate 4 (average added mole number of oxyethylene group: 60): trade name "EMALEX GWIS-160EX” manufactured by Nippon Emulsion Co., Ltd.
- polyoxyethylene hydrogenated castor oil 1 (average added mole number of oxyethylene group 20): trade name "EMALEX HC-20 , Nippon Emulsion Co., Ltd.
- polyoxyethylene hydrogenated castor oil 2 (average added mole number of oxyethylene group: 40): trade name "Buranon RCW-40", Aoki Yushi Kogyo Co., Ltd. polyoxyethylene cured castor oil 3 (oxyethylene group) Average added mole number of 50): trade name "Buranon RCW-50", Aoki Yushi Kogyo Co., Ltd. polyoxyethylene hydrogenated castor oil 4 (average added mole number of oxyethylene group 100): trade name "Brownon RCW-100", Aoki Yushi Kogyo Co., Ltd. Monoisostearate polyoxyethylene butylene glycol (Average addition mole number 10 oxyethylene groups): trade name "EMALEX BGIS-110", manufactured by Nippon Emulsion Co.
- Examples 1 to 10 and Comparative Examples 1 to 6 The composition shown in the following Tables 1 and 2 was blended (blending unit is% by mass) to prepare a hair treatment composition.
- the compounding amount in the table (the compounding amount in 100% by mass of the composition for hair treatment) is indicated by the compounding amount (unit: mass%) of the pure part.
- the obtained composition for treating hair was filled in a container body, and the container body and a pump-type dispenser ("Y-150" manufactured by Yoshino Kogyosho Co., Ltd.) were closed together to obtain a mist cosmetic for hair treatment.
- evaluation The following evaluation was performed using the obtained mist cosmetic for hair treatment. The evaluation was conducted by five expert panelists and discussed to determine the evaluation results.
- the composition for treating hair is uniformly applied to the hair of the hair wig (Lesson Mannequin: manufactured by Eucalyptus Japan) using the obtained mist cosmetic for treating hair, and after being conformed to the hair, the fingertip and palm of the hand The hair was brushed so that the entire hair flowed backward using. The hair bundle after 5 minutes of hair setting was observed, and the degree of hair cohesion was visually evaluated based on the following criteria.
- the hair treatment compositions of Comparative Examples 5 to 6 were not tested because they could not be discharged in a mist form from a pump dispenser.
- Test Example 3 Hardness of Hair
- Test Example 2 After the evaluation of Test Example 2, the hair that had been hairdressed was touched, and the hardness of the hair was sensory-evaluated based on the following criteria.
- the hair treatment compositions of Comparative Examples 5 to 6 were not tested because they could not be discharged in a mist form from a pump dispenser.
- Test Example 4 Hair setting retention after hair setting
- the composition for treating hair is uniformly applied to the hair of the hair wig (Lesson Mannequin: manufactured by Eucalyptus Japan) using the obtained mist cosmetic for treating hair, and after being conformed to the hair, the fingertip and palm of the hand The hair was brushed so that the entire hair flowed backward using. Then, the hair wig after hair setting was allowed to stand in a constant temperature and humidity chamber (25 ° C., 60% RH) for 1 hour.
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Abstract
Description
成分(B):糖アルコールの酸化アルキレン付加重合物
成分(C):エタノール
成分(A)は、皮膜形成ポリマーである。成分(A)は、主たる整髪成分として機能する。また、成分(A)を、成分(B)及び成分(C)とともに用いることにより、外的な衝撃を受けても整髪された髪型が崩れにくく、整髪された髪型を長時間保持できる。成分(A)は、1種のみが用いられてもよく、2種以上が併用されてもよい。
成分(B)は、糖アルコールの酸化アルキレン付加重合物である。成分(B)を用いることにより、毛髪間に粘着力を付与することができる。また、成分(B)を、成分(A)及び成分(C)とともに用いることにより、外的な衝撃を受けても整髪された髪型が崩れにくく、整髪された髪型を長時間保持できる。成分(B)は、1種のみが用いられてもよく、2種以上が併用されてもよい。
成分(C)は、エタノールである。成分(C)を用いることにより、毛髪処理用組成物をミスト状に良好に吐出でき、毛髪処理用組成物の吐出安定性を高めることができる。さらに、成分(C)を用いることにより、塗布時の速乾性を高めるとともに、べたつきを低減することができる。
成分(D)は、非イオン性界面活性剤である。成分(D)を用いることにより、髪を纏め、太い毛束を作りやすくなる。また、成分(D)を用いることにより、成分(A)による整髪性能を効果的に高めることができる。また、成分(D)を用いることにより、毛髪処理用組成物を良好に吐出することができる。成分(D)は、1種のみが用いられてもよく、2種以上が併用されてもよい。
本発明の毛髪処理用組成物は、本発明の効果を阻害しない範囲で、水を含有していてもよい。
本発明の毛髪処理用組成物は、容器内に充填されて、ポンプ式ディスペンサー又はトリガー式ディスペンサーにより、ミスト状に吐出されることを特徴とする。本発明の毛髪処理用組成物は、毛髪処理用ミスト化粧料に用いられる。本発明の毛髪処理用組成物を、毛髪用ミスト化粧料に用いることにより、毛髪に対して垂れ落ちずに広範囲に均一に塗布でき、べたつき感なく整髪できる。また、本発明の毛髪処理用組成物を、毛髪用ミスト化粧料に用いることにより、毛髪間の粘着力が長時間保持される皮膜が良好に形成され、外的な衝撃を受けても整髪された髪型がより一層崩れにくく、整髪された髪型をより長時間保持することができる。
以下、本発明について、実施例及び比較例を挙げて具体的に説明する。本発明は、以下の実施例のみに限定されない。
(アクリレーツ/アクリル酸アルキル(C1-18)/アルキル(C1-8)アクリルアミド)コポリマー:商品名「プラサイズ L-9909U」、互応化学工業社製
(アクリル酸アルキル/ジアセトンアクリルアミド)コポリマー:商品名「プラサイズ L-9540U」、互応化学工業社製
ポリオキシプロピレンソルビット(数平均分子量700):商品名「サンニックス SP-750」、三洋化成工業社製
エタノール
モノイソステアリン酸ポリオキシエチレングリセリル1(オキシエチレン基の平均付加モル数20):商品名「ブラウノン RGL-20MISE」、青木油脂工業社製
モノイソステアリン酸ポリオキシエチレングリセリル2(オキシエチレン基の平均付加モル数25):商品名「EMALEX GWIS-125」、日本エマルジョン社製
モノイソステアリン酸ポリオキシエチレングリセリル3(オキシエチレン基の平均付加モル数30):商品名「EMALEX GWIS-130」、日本エマルジョン社製
モノイソステアリン酸ポリオキシエチレングリセリル4(オキシエチレン基の平均付加モル数60):商品名「EMALEX GWIS-160EX」、日本エマルジョン社製 モノイソステアリン酸ポリオキシエチレン硬化ヒマシ油(オキシエチレン基の平均付加モル数50):商品名「EMALEX RWIS-150」、日本エマルジョン社製
ポリオキシエチレン硬化ヒマシ油1(オキシエチレン基の平均付加モル数20):商品名「EMALEX HC-20」、日本エマルジョン社製
ポリオキシエチレン硬化ヒマシ油2(オキシエチレン基の平均付加モル数40):商品名「ブラウノン RCW-40」、青木油脂工業社製
ポリオキシエチレン硬化ヒマシ油3(オキシエチレン基の平均付加モル数50):商品名「ブラウノン RCW-50」、青木油脂工業社製
ポリオキシエチレン硬化ヒマシ油4(オキシエチレン基の平均付加モル数100):商品名「ブラウノン RCW-100」、青木油脂工業社製
モノイソステアリン酸ポリオキシエチレンブチレングリコール(オキシエチレン基の平均付加モル数10):商品名「EMALEX BGIS-110」、日本エマルジョン社製
精製水
下記の表1~2に示す配合成分を配合(配合単位は質量%)し、毛髪処理用組成物を調製した。表中の配合量(毛髪処理用組成物100質量%中の配合量)は、純分の配合量(単位:質量%)で示した。
得られた毛髪処理用ミスト化粧料を用いて、以下の評価を行った。なお、評価は専門パネル5名で行い、協議して評価結果を決定した。
得られた毛髪処理用ミスト化粧料において、毛髪処理用組成物を繰り返し5回吐出し、吐出された液滴の状態を目視で観察し、下記の基準で評価した。
○(良好):ミスト状に吐出される
×(不良):ミスト状に吐出されない
得られた毛髪処理用ミスト化粧料を用いて、毛髪処理用組成物を、ヘアウィッグ(レッスンマネキン:ユーカリジャパン社製)の毛髪に均一に塗布し、髪に馴染ませた後、指先と手の平とを使って髪全体が後方に流れるように撫でつけて整髪を施した。整髪5分後の毛束を観察し、毛髪のまとまり度合いを下記の基準で目視評価した。なお、比較例5~6の毛髪処理用組成物については、ポンプ式ディスペンサーからミスト状に吐出することができなかったため、試験を行わなかった。
○○(かなり良好):毛髪同士の強いまとまりがある毛束が形成されている
○(良好):毛髪同士のまとまりがある毛束が形成されている
△(やや良好):細い毛束が形成される程度であり、毛髪にまとまりがほとんどない
×(不良):毛束ができず、毛髪同士のまとまりが全くない
試験例2の評価後、整髪した毛髪に触れ、毛髪の硬さを下記の基準で官能評価した。なお、比較例5~6の毛髪処理用組成物については、ポンプ式ディスペンサーからミスト状に吐出することができなかったため、試験を行わなかった。
○○(かなり良好):毛髪同士の粘着力が強く、毛髪がまとまることによる強固な皮膜感がある
○(良好):毛髪同士の粘着力があり、毛髪がまとまることによる皮膜感がある
△(やや良好):毛髪同士の粘着力が弱く、毛髪がまとまることによる皮膜感がほとんどない
×(不良):毛髪同士の粘着力がなく、毛髪がまとまることによる皮膜感が全くない
得られた毛髪処理用ミスト化粧料を用いて、毛髪処理用組成物を、ヘアウィッグ(レッスンマネキン:ユーカリジャパン社製)の毛髪に均一に塗布し、髪に馴染ませた後、指先と手の平とを使って髪全体が後方に流れるように撫でつけて整髪を施した。次いで、整髪後のヘアウィッグを恒温恒湿機(25℃、60%RH)に1時間静置した。
○○(かなり良好):整髪した髪の形状が保持され続けている
○(良好):若干の乱れがあるものの、整髪した髪の形状が保持され続けている
△(やや良好):明らかな乱れがあり、整髪した髪の形状が崩壊し始めている
×(不良):整髪した髪の形状が全く保持されておらず乱れている
Claims (8)
- 容器内に充填されて、ポンプ式ディスペンサー又はトリガー式ディスペンサーにより、ミスト状に吐出される毛髪処理用組成物であって、
下記成分Aと、下記成分Bと、下記成分Cとを含有する、毛髪処理用組成物。
成分A:皮膜形成ポリマー
成分B:糖アルコールの酸化アルキレン付加重合物
成分C:エタノール - 前記成分Aが、下記成分A1を含む、請求項1に記載の毛髪処理用組成物。
成分A1:必須のモノマー成分として(メタ)アクリル酸アルキルを用いて得られるアニオン性皮膜形成ポリマー - 前記成分Aが、下記成分A11を含む、請求項1又は2に記載の毛髪処理用組成物。
成分A11:(アクリレーツ/アクリル酸アルキル(C1-18)/アルキル(C1-8)アクリルアミド)コポリマー、及び(アクリル酸アルキル/ジアセトンアクリルアミド)コポリマーからなる群より選ばれるアニオン性皮膜形成ポリマー - 前記成分Bが、下記成分B1を含む、請求項1~3のいずれか1項に記載の毛髪処理用組成物。
成分B1:ポリオキシプロピレンソルビット - 下記成分Dを含有する、請求項1~4のいずれか1項に記載の毛髪処理用組成物。
成分D:非イオン性界面活性剤 - 前記成分Dが、下記成分D1を含む、請求項5に記載の毛髪処理用組成物。
成分D1:モノイソステアリン酸ポリオキシエチレングリセリル、モノイソステアリン酸ポリオキシエチレン硬化ヒマシ油、モノイソステアリン酸ポリオキシエチレンブチレングリコール、及びポリオキシエチレン硬化ヒマシ油からなる群より選ばれる非イオン性界面活性剤 - 整髪剤組成物である、請求項1~6のいずれか1項に記載の毛髪処理用組成物。
- 容器本体とポンプ式ディスペンサー又はトリガー式ディスペンサーとを有する容器と、
請求項1~7のいずれか1項に記載の毛髪処理用組成物とを備え、
前記容器内に、前記毛髪処理用組成物が充填されている、毛髪処理用ミスト化粧料。
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JP2012025744A (ja) * | 2010-06-25 | 2012-02-09 | Shiseido Co Ltd | 整髪用化粧料 |
JP2012126680A (ja) * | 2010-12-15 | 2012-07-05 | Mandom Corp | 整髪剤用ミスト化粧料 |
JP2013063918A (ja) * | 2011-09-15 | 2013-04-11 | Mandom Corp | 整髪用ミスト化粧料 |
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KR20200013038A (ko) | 2020-02-05 |
CN110831572A (zh) | 2020-02-21 |
JP6938105B2 (ja) | 2021-09-22 |
JPWO2019064851A1 (ja) | 2020-05-28 |
KR102339025B1 (ko) | 2021-12-14 |
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