WO2019045251A1 - Composition aqueuse de vernis à ongles comprenant un copolymère à base d'acrylate - Google Patents

Composition aqueuse de vernis à ongles comprenant un copolymère à base d'acrylate Download PDF

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Publication number
WO2019045251A1
WO2019045251A1 PCT/KR2018/007624 KR2018007624W WO2019045251A1 WO 2019045251 A1 WO2019045251 A1 WO 2019045251A1 KR 2018007624 W KR2018007624 W KR 2018007624W WO 2019045251 A1 WO2019045251 A1 WO 2019045251A1
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Prior art keywords
copolymer
acrylate
nail polish
weight
composition
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PCT/KR2018/007624
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English (en)
Korean (ko)
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박유진
최석원
박명삼
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코스맥스 주식회사
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations

Definitions

  • Nail polish is a makeup cosmetic that uses various colors to make your nails beautiful.
  • nitrocellulose is used as a film-forming agent, and a plasticizer which softens the coating film is used.
  • organic solvents are mainly used.
  • the oil-based nail polish has an odor due to the use of an organic solvent, and may cause a headache when used in an airtight room, which has a space limitation in use.
  • acetone which is used to clean oil-based nail polish, is classified as dangerous and has a fire and explosion hazard. Due to these problems, there is a growing interest in aqueous nail polishes that have the same function and effect as the oil-based nail polishes, without the need for a remover.
  • Korean Patent Laid-Open Publication No. 2014-0086437 discloses a water-based enamel composition using a water-dispersible acrylic resin having a glass transition temperature of 30 to 50 ° C as a water-soluble resin and a method for producing the same. However, .
  • One aspect of the present invention provides an aqueous nail polish composition excellent in durability by containing an acrylate-based copolymer having a low glass transition temperature.
  • One aspect provides an aqueous nail polish composition
  • an aqueous nail polish composition comprising an acrylate-based copolymer having a low glass transition temperature.
  • nail polish refers to an enamel liquid that is applied to add a gloss or color to the nail or toenails, and can be divided into an aqueous nail polish and an oil-based nail polish.
  • Oil-based nail polish is a nail polish based on an organic solvent, which has relatively good durability, but it has a disadvantage that it requires a remover such as acetone because of its strong odor using an organic solvent.
  • the "aqueous nail polish” is a water based nail polish, which has no irritating odor peculiar to the oil nail polish.
  • Conventional aqueous nail polish has the problem that the sustainability is not good despite these merits. Accordingly, there is provided an aqueous nail polish having improved persistence by using an acrylate-based copolymer having a low glass transition temperature.
  • glass transition temperature (Tg) can be defined as the temperature at which a polymer material starts to move with its molecules active by temperature. Since the value is different for each polymer material, Is one of the important characteristics of.
  • the glass transition temperature can be measured by a conventional method, for example, by a differential scanning calorimeter (DSC) or a dynamic mechanical analysis (DMA).
  • DSC differential scanning calorimeter
  • DMA dynamic mechanical analysis
  • the glass transition temperature of the copolymer is between the glass transition temperature of the homopolymer and its position varies with the copolymer composition. That is, the glass transition temperature varies depending on the ratio of the different kinds of monomers to be copolymerized.
  • the above-mentioned "glass transition temperature of the homopolymer” means the glass transition temperature of the polymer composed of one type of monomer.
  • the acrylate-based copolymer may have a melting point of 0 ° C or lower, 0 ° C or lower to -100 ° C or higher, -90 ° C to 0 ° C, -90 ° C to -10 ° C, -90 ° C to -20 ° C, -80 to -40 ⁇ ⁇ , -80 to -50 ⁇ ⁇ , -80 to -50 ⁇ ⁇ , -80 to 0 ⁇ ⁇ , -80 to -10 ⁇ ⁇ , -80 to -20 ⁇ ⁇ , -70 to -50 ⁇ ⁇ , or about-60 ⁇ ⁇ , of -70 to 0 ⁇ ⁇ , -70 to -10 ⁇ ⁇ , -70 to -20 ⁇ ⁇ , -70 to -30 ⁇ ⁇ , -70 to -40 ⁇ ⁇ , And may have a transition temperature.
  • An aqueous nail polish composition comprises a polymer having a high glass transition temperature that is outside of the above range by including an acrylate-based copolymer having a low glass transition temperature, specifically a glass transition temperature of -80 to -20 ° C
  • the aqueous coating composition of the present invention is excellent in stability after application.
  • the aqueous nail polish composition according to one embodiment may have a contrast persistence of greater than about 68% immediately after application, even after 3 days of application.
  • the acrylate-based copolymer may be included in the composition and may function as a film forming agent and / or an increasing agent together with a main role of improving the sustainability.
  • the water-soluble film former or thickener described in the expression " further comprises water-soluble film former " or “ further comprises thickener " is used herein to refer to the lower glass transition temperature Is meant to mean other components except for the acrylate-based copolymer.
  • the acrylate-based copolymer may be a water-soluble resin.
  • acrylate-based copolymer may include all of copolymers formed by polymerization of two or more kinds of acrylate monomers.
  • the acrylate-based monomer may include both salts, esters, and conjugate bases of acrylic acid, methacrylic acid, and derivatives thereof.
  • acrylate monomer examples include acrylates, methacrylates, methyl acrylate, ethyl acrylate, 2-chloroethyl vinyl ether, Acrylate, 2-ethylhexyl acrylate, hydroxyethyl methacrylate, butyl acrylate, butyl methacrylate, trimethylolpropane triacrylate, triacrylate: TMPTA), but are not limited thereto.
  • the salt may include, but is not limited to, a sodium salt, an ammonium salt, a calcium salt, a magnesium salt, and the like.
  • the acrylate-based copolymer may include various types of copolymers composed of acrylic acid and other monomers as well as an acrylate copolymer formed by polymerizing two or more monomers composed of acrylic acid, methacrylic acid or a simple ester thereof .
  • the copolymer of acrylic acid and other monomers may be selected from the group consisting of Ammonium Acrylates Copolymer, Ammonium VA / Acrylates Copolymer, Sodium Acrylates Copolymer, Ethylene / acrylic acid copolymers, ethylene / calcium acrylate copolymers, ethylene / magnesium acrylate copolymers, ethylene / sodium acrylate copolymers, ethylene / acrylic acid copolymers, Ethylene / Zinc Acrylate Copolymer, Ethylene / Acrylic Acid / VA Copolymer, Acrylates / Vinyl Copolymer, Ethylene / Zinc Acrylate Copolymer, VP Copolymer), acrylate / Vie copolymer (Acrylates / VA Copolymer), stearates-10 allyl ether / acrylate Acrylate copolymers (Acrylates / Steareth-50 Acrylate Copolymer),
  • the acrylate-based copolymer may also include a polymer of acrylic acid and its salt.
  • the polymer of acrylic acid and its salt may be selected from the group consisting of Polyacrylic Acid, Ammonium Polyacrylate, Potassium Aluminum Polyacrylate, Potassium Polyacrylate, (Sodium Polyacrylate), and the like, but the present invention is not limited thereto.
  • the acrylate-based copolymer may be used alone or in combination of two or more.
  • the acrylate-based copolymer is used in an amount of 0.5 to 5.0% by weight, 0.5 to 4.5% by weight, 0.5 to 4.0% by weight, 0.5 to 3.5% by weight, 0.5 to 3.0% by weight, 0.5 to 2.5% 2.0 to 5 weight percent, 1.0 to 5.0 weight percent, 1.0 to 4.5 weight percent, 1.0 to 3.5 weight percent, 1.0 to 3.0 weight percent, 1.0 to 2.5 weight percent, 1.0 to 2.0 weight percent, or about 2.0 weight percent, But is not limited thereto. If the content of the acrylate-based copolymer is less than 0.5 wt%, the effect of improving the durability of the nail polish may be reduced. If the content exceeds 2.0 wt%, the gloss retention may be decreased. Therefore, the content of the acrylate-based copolymer can be appropriately selected in consideration of the durability and gloss persistence of the nail polish.
  • composition according to one embodiment may further comprise at least one (e.g., 1, 2, 3, or 4 components) selected from the group consisting of water-soluble film formers, dispersants, thickeners, and defoamers.
  • the compositions according to other embodiments may further comprise both water-soluble film formers, dispersants, thickeners, and defoamers.
  • the water-soluble film-forming agent may include a water-soluble component that forms a film on the nail or the nail.
  • the water-soluble film-forming agent include polyurethane (for example, polyurethane-10, polyurethane-11, polyurethane 15, polyurethane- Etc.), polyvinyl pyrrolidone, polyvinyl acetate, acrylamide copolymer, and the like.
  • the water-soluble film former may be polyurethane.
  • the water-soluble film-forming agent may be contained in an amount of 15 to 35% by weight, 20 to 30% by weight, 23 to 29% by weight, 25 to 27% by weight, or about 26% by weight based on the total weight of the composition.
  • the dispersant may serve to improve the dispersibility of the composition and increase the dispersion stability to prevent re-aggregation after dispersion, and any conventionally usable anionic, nonionic or amphoteric surfactant may be used .
  • the HLB (Hydrophile-Lipophile Balance) value of the dispersant is not particularly limited, but may be 8 or more, specifically 10 or more.
  • Examples thereof include polysorbate-60, polysorbate-80, polysorbate-85, PEG-7 olivate, PEG-8 oleate, polyglyceryl-3 methyl glucose distearate, Oleate-10 / polyoxyl 10 oleyl ester, PEG-8 laurate, isostearate-20, PEG-60 almond glyceride, PEG-20 methyl glucose sesquistearate, 20, Stearat's-20, Stearat's-21, Cere's-20, Isocetes-20, and the like.
  • the dispersant may be polysorbate-n.
  • the dispersant may be polysorbate-60.
  • the dispersing agent may be used in an amount of 0.5-5.0 wt%, 0.5-4.0 wt%, 0.5-3.0 wt%, 1.0-5.0 wt%, 1.0-4.0 wt%, 1.0-3.0 wt%, 1.5-2.5 wt% Or about 2.0% by weight.
  • the thickener may include an inorganic thickener, a polysaccharide thickener, an anionic thickener, and the like.
  • the thickener include Lithium Magnesium Sodium Silicate, Magnesium Aluminum Silicate, Aluminum Silicate, Aluminum silicate, calcium silicate, magnesium silicate, magnesium trisilicate, sodium magnesium silicate, zirconium silicate, and lithium magnesium silicate.
  • Silicate-based inorganic thickeners such as montmorillonite, attapulgite, bentonite, fuller's earth, hectorite, kaolin, pyrophyllite, ), Zeolite (Zeolite), hyaluronic acid, xanthan gum, carrageenan, ka But it may include such as bots, and the like.
  • the thickener may be an inorganic thickener.
  • the builder may be a silicate-based inorganic builder.
  • the thickener may be lithium magnesium sodium silicate.
  • the thickener may be included in an amount of 0.5 to 3.0 wt%, 0.5 to 2.5 wt%, 0.5 to 2.0 wt%, 0.5 to 1.5 wt%, 0.5 to 1.0 wt%, or about 0.7 wt% based on the total weight of the composition.
  • the content of the thickening agent is less than 0.5% by weight, the dye may be separated from the layer. If the content of the thickening agent exceeds 3.0% by weight, the viscosity may increase and the flowability may disappear.
  • the antifoaming agent serves to prevent or reduce the amount of foam formed on the surface of the liquid formulation.
  • the antifoaming agent include simethicone, dimethicone, polysiloxane, polydimethylsiloxane, and polymethylphenylsiloxane. But is not limited thereto.
  • the antifoam agent may be a silicone antifoam agent. In another embodiment, the antifoaming agent may be imethiconone.
  • the antifoaming agent may be used in an amount of 0.01 to 0.1 wt%, 0.01 to 0.05 wt%, 0.03 to 0.1 wt%, 0.03 to 0.07 wt%, 0.03 to 0.05 wt%, 0.04 to 0.1 wt%, 0.04 to 0.06 wt% Or about 0.05% by weight. If the content of the defoaming agent is less than 0.01% by weight, the defoaming time may become long, and the viscosity may increase to cause a change of the formulation. If the content of the defoaming agent exceeds 0.1% by weight, creaming or pinholes may occur.
  • the composition according to one embodiment may further comprise purified water.
  • the purified water may be a filter or water in which impurities have been removed through distillation, but is not limited thereto.
  • the purified water is a main solvent used in the production of an aqueous nail polish composition, and can control the viscosity and drying composition.
  • an aqueous solvent-based nail polish composition uses purified water as a main solvent, unlike an ester solvent, a ketone solvent, an alcohol solvent, or a hydrocarbon solvent. It is possible to produce a nail-polish composition which is harmless.
  • the composition according to one embodiment comprises, based on the total weight of the composition, from 0.5 to 5.0 wt% of an acrylate-based copolymer having a glass transition temperature (Tg) of from -80 DEG C to -20 DEG C, from 15 to 35 wt% 0.5 to 5.0% by weight of a dispersing agent, 0.1 to 3.0% by weight of an increasing agent, 0.01 to 0.1% by weight of an antifoaming agent and 40 to 80% by weight of purified water.
  • Tg glass transition temperature
  • the purified water is used in an amount of 40 to 80% by weight, 40 to 75% by weight, 45 to 80% by weight, 45 to 75% by weight, 45 to 70% by weight, 50 to 80% by weight, 50 to 75% by weight, 60 to 70% by weight, 65 to 80% by weight, or 65 to 70% by weight, based on 50 to 70% by weight, 55 to 80% by weight, 55 to 75% To 75% by weight.
  • the content of the purified water is less than 40% by weight, the viscosity of the aqueous nail polish composition is excessively lowered to an appropriate viscosity, and when it exceeds 80% by weight, the viscosity of the aqueous nail polish composition is too low, can do.
  • composition according to the present disclosure can be selected any additional components and / or amounts thereof so that the beneficial properties of the composition according to the present disclosure are not adversely affected or substantially not affected by the anticipated addition.
  • the aqueous nail polish composition can be made into an aqueous nail polish product, and the manufacture of the aqueous nail polish can be carried out according to a conventional method.
  • the term " about " or “ approximately” means that the value referred to may vary to some extent.
  • the value may be 10%, 5%, 2%
  • the aqueous nail polish composition according to one aspect has excellent persistence and gloss persistence of an aqueous nail polish by including an acrylate-based copolymer having a low glass transition temperature. Also, unlike oil-based nail polish, organic solvent is not used, so there is no strong smell.
  • FIG. 1 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 1.
  • FIG. 1 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 1.
  • FIG. 2 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Example 1.
  • FIG. 2 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Example 1.
  • Fig. 3 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 2.
  • FIG. 4 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 3.
  • FIG. 4 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 3.
  • Example 1 and Comparative Examples 1 to 3 Preparation of aqueous nail polish composition
  • An aqueous nail polish composition comprising an ammonium acrylate copolymer was prepared using an ammonium acrylate copolymer raw material having a different glass transition temperature (Tg).
  • each raw material was weighed in a beaker according to each component and content shown in Table 1, and then mixed uniformly at room temperature for 30 minutes at 600 rpm using a disper. Thereafter, air bubbles were removed at room temperature to prepare an aqueous nail polish composition. As a result, a milky white liquid composition was obtained.
  • Table 1 shows specific components and contents of the aqueous nail polish composition according to Example 1 and Comparative Examples 1 to 3. Unless otherwise stated herein, the component content is by weight.
  • polyurethane was used as a water-soluble film forming agent
  • polysorbate 60 was used as a dispersing agent
  • Lithium magnesium sodium silicate was used as a thickening agent
  • Simethicone was used.
  • each nail polish composition was provided to 10 consumers in their 20s and 30s.
  • the test site (nail) before application of the nail polish was photographed with VISIA-CR (Canfield Scientific, Inc., U. S. A.). After applying the nail polish, photographs were taken immediately after Day 1, Day 1, Day 2, Day 3, and Day 7.
  • VISIA-CR Canfield Scientific, Inc., U. S. A.
  • photographs were taken immediately after Day 1, Day 1, Day 2, Day 3, and Day 7.
  • To analyze the results we selected the cross-polarized image from which the reflected light was removed and measured the change of area using Image Pro Analyzer (Media Cybernetics, Inc., USA) Respectively.
  • the durability of the product was calculated by the following formula (1).
  • a work duration (%) (Z-X) / (Y-X) 100
  • FIG. 1 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 1.
  • FIG. 1 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 1.
  • FIG. 2 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Example 1.
  • FIG. 2 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Example 1.
  • Fig. 3 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 2.
  • FIG. 4 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 3.
  • FIG. 4 is a graph showing the contrast strength (%) immediately after application of the nail polish composition according to Comparative Example 3.
  • Comparative Example 1 which did not contain an ammonium acrylate copolymer
  • Comparative Example 2 or 3 which contained an ammonium acrylate copolymer having a glass transition temperature of 10 DEG C or 50 DEG C
  • the contrast persistence was 68.3% immediately after the application on the third day, I could.
  • Example 2 and Comparative Examples 4 to 6 Preparation of aqueous nail polish composition
  • An aqueous nail polish composition comprising an ammonium acrylate copolymer was prepared by varying the content of the ammonium acrylate copolymer.
  • each raw material was weighed in a beaker according to each component and content shown in Table 2 below, and then uniformly mixed at room temperature for 30 minutes at 600 rpm using a disper. Thereafter, air bubbles were removed at room temperature to prepare an aqueous nail polish composition. As a result, a milky white liquid composition was obtained.
  • Table 2 shows the specific components and contents of the aqueous nail polish composition according to Example 2 and Comparative Examples 4 to 6.
  • polyurethane was used as a water-soluble film forming agent
  • polysorbate 60 was used as a dispersing agent
  • Lithium magnesium sodium silicate was used as a thickening agent
  • Simethicone was used.
  • Example 2 and Comparative Examples 4 to 6 were provided to 20 consumers in their 20s and 30s. Then, we compared the shine power between Day 3 and Day 3 immediately after application (Day 0, Day 3), and scored each item to 0 ⁇ 5, and the scores were averaged. Table 3 below shows the evaluation results of the gloss persistence of the nail polish composition according to Example 2 and Comparative Examples 4 to 6.

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Abstract

La présente invention concerne une composition aqueuse de vernis à ongles comprenant un copolymère à base d'acrylate ayant une température de transition vitreuse basse. Selon un aspect, la composition aqueuse de vernis à ongles comprend un copolymère à base d'acrylate ayant une température de transition vitreuse basse, ayant ainsi une excellente durabilité et rétention de brillance dans un vernis à ongles aqueux. De plus, la présente invention n'utilise pas de solvants organiques, contrairement à un vernis à ongles huileux, et ainsi ne présente pas d'odeur forte.
PCT/KR2018/007624 2017-08-31 2018-07-05 Composition aqueuse de vernis à ongles comprenant un copolymère à base d'acrylate WO2019045251A1 (fr)

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WO2021076238A1 (fr) * 2019-10-17 2021-04-22 ILNP Cosmetics Inc. Compositions de film protecteur transparent de vernis à ongles et procédés de fabrication
US20210299022A1 (en) * 2020-03-26 2021-09-30 Oystershell Nv Composition for the treatment of nail fungus
US20230190621A1 (en) * 2021-12-17 2023-06-22 Ashley Ann Thomas Water-based nail polish

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KR102211895B1 (ko) * 2019-05-10 2021-02-04 코스맥스 주식회사 비누화 베이스를 포함하는 수성 네일 폴리쉬 조성물
KR102298139B1 (ko) * 2019-05-20 2021-09-06 코스맥스 주식회사 필 오프 타입 수성 네일 폴리쉬 조성물
KR102284167B1 (ko) * 2019-09-06 2021-07-30 코스맥스 주식회사 아크릴레이트계 공중합체를 포함하는 네일 프라이머 조성물
KR102523258B1 (ko) * 2020-10-21 2023-04-21 코스맥스 주식회사 글리터타입 필오프 수성 네일폴리쉬 화장료 조성물
KR20240060367A (ko) 2022-10-28 2024-05-08 코스맥스 주식회사 파우더를 밀착시키기 위한 수성 네일 폴리쉬 조성물

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