WO2018188968A1 - Abgassystem - Google Patents

Abgassystem Download PDF

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Publication number
WO2018188968A1
WO2018188968A1 PCT/EP2018/058157 EP2018058157W WO2018188968A1 WO 2018188968 A1 WO2018188968 A1 WO 2018188968A1 EP 2018058157 W EP2018058157 W EP 2018058157W WO 2018188968 A1 WO2018188968 A1 WO 2018188968A1
Authority
WO
WIPO (PCT)
Prior art keywords
flow direction
scr
catalyst
scr catalyst
exhaust system
Prior art date
Application number
PCT/EP2018/058157
Other languages
German (de)
English (en)
French (fr)
Inventor
Rolf BRÜCK
Original Assignee
Continental Automotive Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Continental Automotive Gmbh filed Critical Continental Automotive Gmbh
Priority to KR1020197029780A priority Critical patent/KR20190122259A/ko
Priority to CN201880020697.5A priority patent/CN110537008A/zh
Priority to EP18715624.5A priority patent/EP3610141A1/de
Priority to JP2020504766A priority patent/JP2020516815A/ja
Publication of WO2018188968A1 publication Critical patent/WO2018188968A1/de
Priority to US16/600,122 priority patent/US20200040783A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/105General auxiliary catalysts, e.g. upstream or downstream of the main catalyst
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0097Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/103Oxidation catalysts for HC and CO only
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/105General auxiliary catalysts, e.g. upstream or downstream of the main catalyst
    • F01N3/106Auxiliary oxidation catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2006Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2006Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
    • F01N3/2013Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means
    • F01N3/2026Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means directly electrifying the catalyst substrate, i.e. heating the electrically conductive catalyst substrate by joule effect
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/16Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being an electric heater, i.e. a resistance heater
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/40Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a hydrolysis catalyst
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/60Discontinuous, uneven properties of filter material, e.g. different material thickness along the longitudinal direction; Higher filter capacity upstream than downstream in same housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2550/00Monitoring or diagnosing the deterioration of exhaust systems
    • F01N2550/04Filtering activity of particulate filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2550/00Monitoring or diagnosing the deterioration of exhaust systems
    • F01N2550/22Monitoring or diagnosing the deterioration of exhaust systems of electric heaters for exhaust systems or their power supply
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/02Adding substances to exhaust gases the substance being ammonia or urea
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the invention relates to an exhaust system for the aftertreatment of exhaust gases of an internal combustion engine with successively arranged viewed in the flow direction of the exhaust gas, a catalyst for the oxidation of the exhaust gas and / or a catalyst for
  • catalysts are used, for example, which absorb and bind nitrogen oxides (NO x ).
  • NO x nitrogen oxides
  • catalysts are also known which stimulate a conversion of nitrogen oxides to less harmful reaction products.
  • filters are known which filter out particles of a certain size from the exhaust gas.
  • a disadvantage of the known in the prior art devices for cleaning exhaust gases of an internal combustion engine is that the arrangement of the individual catalysts in the exhaust system is not optimal and thus the individual catalysts do not achieve their individual optimum effect.
  • the so-called SCR catalysts for the selective catalytic reduction of nitrogen oxides are often arranged downstream of the particle filter. This has As a result, the SCR catalyst can not operate at its optimum operating point.
  • the object relating to the exhaust system is achieved by a ⁇ From gas system having the features of claim. 1
  • An embodiment of the invention relates to an exhaust system for the aftertreatment of exhaust gases of an internal combustion engine with viewed in the flow direction of the exhaust gas arranged sequentially, a catalyst for the oxidation of the exhaust gas and / or a catalyst for storing nitrogen oxides, with an introduction point for supplying a reducing agent, with an SCR Catalyst for the selective catalytic reduction of nitrogen oxides and with a particulate filter, wherein the particulate filter in the flow direction after the SCR catalyst is arranged and arranged in the flow direction downstream of the particulate filter, a second SCR catalyst and / or an ammonia slip catalyst.
  • SCR catalyst in a particulate filter for example, by a partial coating of the particulate filter is not optimal, since the commonly used cell densities and cell geometries of the honeycomb body of the particulate filter is not optimal for the selective catalytic reduction of the exhaust gas in the
  • SCR catalysts are.
  • a first aftertreatment of the exhaust gas can be carried out, in particular a conversion of the nitrogen oxides to water and nitrogen can take place with the aid of the already introduced and vaporized reducing agent, which is typically formed by an aqueous urea solution.
  • the subsequent particle filter a purification of the exhaust gas flow is achieved.
  • An SCR catalytic converter downstream of the particulate filter can then convert nitrogen oxides still contained in the exhaust gas.
  • the second SCR catalyst can particularly advantageously have a cell geometry and / or cell density deviating from the first SCR catalyst and also have a different chemically active coating.
  • a conversion of the nitrogen oxides can be achieved even at lower temperatures and flow rates.
  • the first SCR catalytic converter arranged in the flow direction upstream of the particle filter is electrically heatable.
  • the electrical heating of the SCR catalyst is advantageous in order as quickly as possible, the exhaust gas to the required To heat operating temperature in order to perform the selective catalytic reduction can.
  • the first SCR catalytic converter in the flow direction has an extension of not more than 80 mm along the flow direction, wherein it preferably has an extension of less than 50 mm, with particular preference having an extension of less than 40 mm.
  • a particulate filter or to the second SCR catalyst relatively short ER- stretching of the first SCR catalyst is advantageous in order to influence the flow for the subsequent particulate filter only slightly and thus maintain a good filtering result in the Parti ⁇ particulate filters.
  • a preferred embodiment is characterized in that the first SCR catalyst in the flow direction is arranged at a distance along the flow direction of not more than 20 mm, preferably less than 10 mm and more preferably less than 5 mm to the particle filter.
  • the smallest possible distance is advantageous in order to be able to summarize the pressure loss arising from the first SCR catalytic converter and the particle filter. This facilitates the design of the exhaust system. It is also preferable if the first SCR catalyst in the flow direction and the second in the flow direction
  • SCR catalyst are formed with the particulate filter as a modular unit. This is advantageous to facilitate the assembly.
  • the SCR catalysts and the particle filter are formed by a common honeycomb body. This is advantageous to keep the number of installed elements as low as possible, whereby the assembly is simplified.
  • the honeycomb body of the particle filter one of the honeycomb body of the flow direction first SCR catalyst and the honeycomb body of the second SCR catalyst in Strö ⁇ tion deviating Zellgeo ⁇ metry and / or cell density. This is especially before ⁇ geous to adjust the individual components perfectly to their JE pier purpose and overall to achieve the lowest possible pressure drop over the individual components of time.
  • the filter characteristics and the VELOCITY ⁇ speed distribution can be influenced by the cell geometries, for example.
  • the cell geometry and / or the cell density and / or the chemically active coating of the honeycomb body and / or the coating amount of the honeycomb body of the first SCR catalyst in the direction of flow is determined by the cell geometry and / or the cell density and / or the cell density chemically active coating of the honeycomb body deviates in the flow direction second SCR catalyst.
  • the coating can also be advantageously adapted to the regularly lower concentration of ammonia and nitrogen oxides, in order nevertheless to produce as complete a conversion of the nitrogen oxides as possible.
  • the coating amount of the first SCR catalyst in the flow direction is higher than the coating amount of the second SCR catalyst in the flow direction.
  • Fig. 1 is a sectional view through an exemplary exhaust system with a plurality of catalysts.
  • the exhaust system 1 shows a sectional view through an exhaust system of an exhaust system 1.
  • the exhaust system 1 has a plurality of catalysts, which are arranged in housings and connected to each other by pipelines such that exhaust gas can flow through the catalysts.
  • a catalyst 3 for the oxidation of the exhaust gas is first arranged in the flow direction 2 of the exhaust gas.
  • a reducing agent such as an aqueous urea solution
  • an evaporation element 5 is arranged, on which the reducing agent can be evaporated, in order subsequently to react as ammonia with the nitrogen oxides in the exhaust gas.
  • a first SCR catalyst 6 Downstream follows then a first SCR catalyst 6, in which the nitrogen oxides in the exhaust gas react with the ammonia and the chemically active coating of the SCR catalyst 6 and thus form nitrogen and water.
  • the first SCR catalytic converter 6 is followed by a particle filter 7, which serves to filter the exhaust gas and in particular filters out soot particles from the exhaust gas.
  • a second SCR catalyst follows 8. In this chemical reaction takes place the same reaction as in the first SCR catalyst 6.
  • the advantage of such a structure is that already takes place a reduction of nitrogen oxides in the exhaust gas before Exhaust gas flows into the particle filter.
  • the exhaust gas flowing into the first SCR catalytic converter therefore still has a particularly high temperature and the exhaust gas distribution over the cross section of the flow path is not adversely affected by the particulate filter. This can be done a particularly we ⁇ kung full conversion of the nitrogen oxides in the exhaust gas.
  • the temperature of the exhaust gas drops significantly, as a result of which the chemical reaction in the downstream SCR catalyst usually does not proceed optimally.
  • the second SCR catalyst essentially serves to reduce the not yet reduced in the first SCR catalyst nitrogen oxide content.
  • an ammonia slip catalyst which can bind excess ammonia (NH 3 ) which was not reacted in the reduction of the nitrogen oxides in the exhaust gas. In this way, for example, a breakthrough of ammonia can be avoided in the exhaust, which ammonia could escape into the environment and could lead to an odor nuisance or pollution of the environment.
  • Figure 1 has in particular no limiting character and serves to illustrate the inventive concept.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
PCT/EP2018/058157 2017-04-13 2018-03-29 Abgassystem WO2018188968A1 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR1020197029780A KR20190122259A (ko) 2017-04-13 2018-03-29 배기가스 시스템
CN201880020697.5A CN110537008A (zh) 2017-04-13 2018-03-29 排气系统
EP18715624.5A EP3610141A1 (de) 2017-04-13 2018-03-29 Abgassystem
JP2020504766A JP2020516815A (ja) 2017-04-13 2018-03-29 排ガスシステム
US16/600,122 US20200040783A1 (en) 2017-04-13 2019-10-11 Exhaust gas system

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102017206425.0A DE102017206425A1 (de) 2017-04-13 2017-04-13 Abgassystem
DE102017206425.0 2017-04-13

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US16/600,122 Continuation US20200040783A1 (en) 2017-04-13 2019-10-11 Exhaust gas system

Publications (1)

Publication Number Publication Date
WO2018188968A1 true WO2018188968A1 (de) 2018-10-18

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2018/058157 WO2018188968A1 (de) 2017-04-13 2018-03-29 Abgassystem

Country Status (7)

Country Link
US (1) US20200040783A1 (ko)
EP (1) EP3610141A1 (ko)
JP (1) JP2020516815A (ko)
KR (1) KR20190122259A (ko)
CN (1) CN110537008A (ko)
DE (1) DE102017206425A1 (ko)
WO (1) WO2018188968A1 (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019131829B3 (de) * 2019-11-25 2021-01-14 Volkswagen Aktiengesellschaft Verfahren zur Abgasnachbehandlung eines Verbrennungsmotors

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006009934A1 (de) * 2006-03-03 2007-09-06 Daimlerchrysler Ag Abgasnachbehandlungssystem und Verfahren zur Abgasreinigung
US20110138776A1 (en) * 2010-09-02 2011-06-16 Ford Global Technologies, Llc Diesel engine exhaust treatment system
DE102014008056A1 (de) * 2014-05-28 2015-12-03 Daimler Ag Verfahren zum Betreiben einer Abgasanlage einer Verbrennungskraftmaschine, insbesondere für einen Kraftwagen
DE102015214734A1 (de) * 2015-08-03 2017-02-09 Ford Global Technologies, Llc Abgasnachbehandlungssystem für einen Dieselmotor

Family Cites Families (10)

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US20200040783A1 (en) 2020-02-06
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KR20190122259A (ko) 2019-10-29
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