WO2018188144A1 - 一种显示面板和显示装置 - Google Patents

一种显示面板和显示装置 Download PDF

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Publication number
WO2018188144A1
WO2018188144A1 PCT/CN2017/083792 CN2017083792W WO2018188144A1 WO 2018188144 A1 WO2018188144 A1 WO 2018188144A1 CN 2017083792 W CN2017083792 W CN 2017083792W WO 2018188144 A1 WO2018188144 A1 WO 2018188144A1
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WIPO (PCT)
Prior art keywords
substrate
alignment layer
plastic frame
display panel
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2017/083792
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English (en)
French (fr)
Inventor
简重光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HKC Co Ltd
Chongqing HKC Optoelectronics Technology Co Ltd
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HKC Co Ltd
Chongqing HKC Optoelectronics Technology Co Ltd
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Filing date
Publication date
Application filed by HKC Co Ltd, Chongqing HKC Optoelectronics Technology Co Ltd filed Critical HKC Co Ltd
Priority to US15/744,854 priority Critical patent/US20200026107A1/en
Publication of WO2018188144A1 publication Critical patent/WO2018188144A1/zh
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • C09D183/06Polysiloxanes containing silicon bound to oxygen-containing groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/18Homopolymers or copolymers of nitriles
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/14Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/05Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
    • C09K2323/057Ester polymer, e.g. polycarbonate, polyacrylate or polyester
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers

Definitions

  • the present application relates to the field of display technologies, and more particularly to a display panel and a display device.
  • the display has many advantages such as thin body, power saving, no radiation, and has been widely used.
  • Most of the displays on the market today are backlight-type displays, which include a display device and a backlight module.
  • the working principle of the display device is to place liquid crystal molecules in two parallel substrates, and apply driving voltages on the two substrates to control the rotation direction of the liquid crystal molecules to refract light of the backlight module to generate a picture.
  • the thin film transistor display includes a display device and a backlight module, and the display device includes a color filter substrate (CF Substrate, also referred to as a color filter substrate) and a thin film transistor array substrate (Thin Film Transistor Substrate, TFT Substrate).
  • CF Substrate also referred to as a color filter substrate
  • Thin Film Transistor Substrate TFT Substrate
  • a transparent electrode exists on the opposite inner side of the substrate.
  • a layer of liquid crystal molecules (LC) is sandwiched between the two substrates.
  • the display device controls the orientation of the liquid crystal molecules by an electric field, changes the polarization state of the light, and achieves the purpose of display by the penetration and blocking of the optical path by the polarizing plate.
  • OLED display uses an Organic Light-Emitting Diode (UIV OLED) for self-luminous display. It is a different type of illumination principle than liquid crystal display (LCD). OLED display technology has the advantages of self-illumination, wide viewing angle, almost infinite contrast, low power consumption, and extremely high reaction speed.
  • UUV OLED Organic Light-Emitting Diode
  • the technical problem to be solved by the present application is to provide a display panel that reduces the cost of production materials and improves production efficiency.
  • a display panel including
  • the frame is made of a self-evaporating or heat-curing adhesive.
  • an alignment layer is disposed on the first substrate; the plastic frame is simultaneously coated on the alignment layer and the first substrate.
  • the first substrate is generally made of glass material, the glass material does not absorb moisture, and the bonding is more stable; and the alignment layer is made of organic material, which is similar to the material of the alignment layer and has strong adhesion. Therefore, the plastic frame is simultaneously attached to the first substrate and the alignment layer. Can balance the strength and stability of the paste.
  • an alignment layer is disposed on the first substrate; the plastic frame is coated only on the first substrate; and the alignment layer is disposed at an inner position of the plastic frame.
  • the first substrate is generally made of glass. The glass material does not absorb moisture, and the paste is more stable. It is not easy to fall off during long-term use of the display panel, which is beneficial to improve the stability of the product.
  • the first substrate is provided with a first groove at a corresponding position of the plastic frame. Due to the presence of the first groove, the adhesive does not easily flow during coating, and can be stably attached to the vicinity of the first groove. When the bonding is cured, the adhesive is squeezed and does not easily diffuse to the display area of the display panel. Inside, contamination of liquid crystal molecules is conducive to improving display quality.
  • an alignment layer is disposed on the first substrate; the plastic frame is coated only on the alignment layer.
  • the alignment layer is made of organic material, which is similar to the material of the alignment layer and has strong adhesion, which is beneficial to improve the bonding strength.
  • the first substrate is provided with an alignment layer; the first substrate is provided with a second groove at a corresponding position of the plastic frame; and the alignment layer forms a third groove at a corresponding position of the second groove. Due to the presence of the third groove, the adhesive does not easily flow during coating, and can be stably attached to the vicinity of the third groove. When the bonding is cured, the adhesive is squeezed and does not easily diffuse to the display area of the display panel. Inside, contamination of liquid crystal molecules is conducive to improving display quality.
  • the adhesive includes an acrylate compound.
  • Acrylation has high polarity and full saturation. Thereby it has superior resistance to mineral oil and high temperature oxidation resistance. Its oil resistance is second only to fluorine rubber, and similar to the general high-acrylonitrile content of nitrile rubber.
  • the heat resistance is between general rubber and silicon and fluorine rubber. It is 30 ⁇ 60°C higher than the temperature of nitrile rubber. The maximum temperature is 180°C. It can be used up to 200°C in intermittent and short time. It is hot at 150°C. There was no significant change in air aging performance for several years. In addition, the most important thing is that it is very stable for extreme pressure type lubricating oils containing extreme pressure agents such as sulfur, chlorine and phosphorus.
  • the use temperature can reach 150 ° C, and the intermittent use temperature can be higher.
  • the nitrile rubber with a double bond is significantly hardened and brittle when the temperature exceeds 110 °C.
  • Acrylate rubber also has excellent ozone resistance, airtightness, flexing resistance and crack growth resistance, and UV discoloration resistance. Therefore, the use of acrylate as the adhesive of the present application can be cured by means of thermal curing, the heat curing device is simple, the cost is low, and the curing time is short, which is advantageous for improving production efficiency.
  • the adhesive comprises a compound of an aluminosiloxane, a two-terminal silanol type silicone oil, and a siloxane alkoxy oligomer.
  • a polycondensation reaction is produced between the aluminum siloxane, the two-terminal silanol type silicone oil, and the siloxane alkoxy oligomer to obtain transparency, multi-crosslinking number, high crosslinking density, and large bond energy.
  • the compound not only exhibits excellent light transmittance and heat resistance, but also exhibits an excellent tensile modulus of elasticity. Since there is no absorption in the ultraviolet region where the organic substance is decomposed, and it is hard to be deteriorated by light, it exhibits an excellent brightness retention ratio at the time of sealing. Therefore, the adhesive can be used as a good heat-curing adhesive material, the heat curing equipment is simple, the cost is low, and the curing time is short, which is favorable for improving production efficiency.
  • the adhesive comprises an ⁇ -cyanoacrylate compound.
  • Physicochemical properties colorless, transparent, low viscosity, non-flammable liquid, single component, no solvent, slightly irritating, volatile, volatile gas with weak tearing. In the case of moist moisture, it is catalyzed and quickly cures and sticks. Non-toxic after curing. Contact with traces of water vapor in the air, which is catalyzed by rapid polymerization and solidification, can be cured quickly. Therefore, the use of ⁇ -cyanoacrylate as the adhesive of the present application can be cured by means of self-evaporation, without additional investment in curing equipment, low cost, and short curing time, which is beneficial to improve production efficiency. rate.
  • the present application also discloses a display device including the display panel described herein.
  • the application adopts self-evaporating curing or heat curing adhesive as the plastic frame material, the temperature control equipment required for the heat curing adhesive is relatively low, and the curing speed is controllable, and has cost advantages and production compared with complicated ultraviolet curing equipment and coating equipment. higher efficiency.
  • the self-evaporating adhesive does not require curing equipment at all, and the cost is further reduced.
  • FIG. 1 is a schematic structural view of a display panel according to an embodiment of the present application.
  • FIG. 2 is another schematic structural view of a display panel according to an embodiment of the present application.
  • FIG. 3 is another schematic structural diagram of a display panel according to an embodiment of the present application.
  • FIG. 4 is another schematic structural diagram of a display panel according to an embodiment of the present application.
  • FIG. 5 is another schematic structural diagram of a display panel according to an embodiment of the present application.
  • FIG. 6 is another schematic structural diagram of a display panel according to an embodiment of the present application.
  • FIG. 7 is a schematic diagram of a method of manufacturing a display panel according to an embodiment of the present application.
  • first means two or more unless otherwise stated.
  • second means two or more unless otherwise stated.
  • connection In the description of the present application, it should be noted that the terms “installation”, “connected”, and “connected” are to be understood broadly, and may be fixed or detachable, for example, unless otherwise specifically defined and defined. Connected, or integrally connected; can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components.
  • Connected, or integrally connected can be mechanical or electrical; can be directly connected, or indirectly connected through an intermediate medium, can be the internal communication of the two components.
  • the specific meanings of the above terms in the present application can be understood on a case-by-case basis.
  • the embodiment shown in Figure 1 discloses a display panel.
  • the display panel includes:
  • the first substrate 10 is the first substrate 10,
  • the second substrate 20 is disposed opposite to the first substrate 10;
  • the plastic frame 30 is made of a self-evaporating curing or heat curing adhesive.
  • the temperature control equipment required for the heat curing adhesive is relatively low, and the curing speed is controllable. Compared with the complicated ultraviolet curing equipment and coating equipment, the cost advantage and the production efficiency are higher. The self-evaporating adhesive does not require curing equipment at all, and the cost is further reduced.
  • an acrylate compound is used as the heat curing adhesive.
  • Acrylation has high polarity and full saturation. Thereby it has superior resistance to mineral oil and high temperature oxidation resistance. Its oil resistance is only It is similar to fluorine rubber, and is similar to nitrile rubber which is generally high in acrylonitrile content.
  • the heat resistance is between general rubber and silicon and fluorine rubber. It is 30 ⁇ 60°C higher than the temperature of nitrile rubber. The maximum temperature is 180°C. It can be used up to 200°C in intermittent and short time. It is hot at 150°C. There was no significant change in air aging performance for several years.
  • the use temperature can reach 150 ° C, and the intermittent use temperature can be higher.
  • the nitrile rubber with a double bond is significantly hardened and brittle when the temperature exceeds 110 °C.
  • Acrylate rubber also has excellent ozone resistance, airtightness, flexing resistance and crack growth resistance, and UV discoloration resistance. Therefore, the use of acrylate as the adhesive of the present application can be cured by means of thermal curing, the heat curing device is simple, the cost is low, and the curing time is short, which is advantageous for improving production efficiency.
  • a compound of aluminum siloxane, a two-terminal silanol type silicone oil, and a siloxane alkoxy oligomer is used as the heat curing adhesive.
  • a polycondensation reaction is produced between the aluminum siloxane, the two-terminal silanol type silicone oil, and the siloxane alkoxy oligomer to obtain transparency, multi-crosslinking number, high crosslinking density, and large bond energy.
  • the compound not only exhibits excellent light transmittance and heat resistance, but also exhibits an excellent tensile modulus of elasticity. Since there is no absorption in the ultraviolet region where the organic substance is decomposed, and it is hard to be deteriorated by light, it exhibits an excellent brightness retention ratio at the time of sealing. Therefore, the adhesive can be used as a good heat-curing adhesive material, the heat curing equipment is simple, the cost is low, and the curing time is short, which is favorable for improving production efficiency.
  • an ⁇ -cyanoacrylate compound is used as the self-evaporating curing adhesive.
  • Ethyl ⁇ -cyanoacrylate is a colorless, transparent, low viscosity, nonflammable liquid, single component, solvent free, slightly irritating, volatile, and volatile. In the case of moist moisture, it is catalyzed and quickly cures and sticks. Non-toxic after curing. Contact with traces of water vapor in the air, which is catalyzed by rapid polymerization and solidification, can be cured quickly. Therefore, the use of ⁇ -cyanoacrylate as the adhesive of the present application can be cured by means of self-evaporation, without additional investment in curing equipment, low cost, and short curing time, which is advantageous for improving production efficiency.
  • the embodiment shown in Figure 2 discloses a display panel.
  • the display panel includes:
  • the first substrate 10 is the first substrate 10,
  • the second substrate 20 is disposed opposite to the first substrate 10;
  • the plastic frame 30 is made of a self-evaporating curing or heat curing adhesive.
  • the alignment layer 40 is disposed on the first substrate 10; the plastic frame 30 is simultaneously coated on the alignment layer 40 and the first substrate 10.
  • the first substrate 10 is generally made of glass, the glass material does not absorb moisture, and the bonding is more stable; and the alignment layer 40 is made of an organic material, which is similar to the material of the alignment layer 40, and has strong adhesion. Therefore, the plastic frame 30 is simultaneously attached to the first substrate. On the 10 and the alignment layer 40, the bonding strength and stability can be achieved.
  • an acrylate compound is used as the heat curing adhesive.
  • Acrylation has high polarity and full saturation. Thereby it has superior resistance to mineral oil and high temperature oxidation resistance. Its oil resistance is second only to fluorine rubber, and similar to the general high-acrylonitrile content of nitrile rubber.
  • the heat resistance is between general rubber and silicon and fluorine rubber. It is 30 ⁇ 60°C higher than the temperature of nitrile rubber. The maximum temperature is 180°C. It can be used up to 200°C in intermittent and short time. It is hot at 150°C. There was no significant change in air aging performance for several years.
  • the use temperature can reach 150 ° C, and the intermittent use temperature can be higher.
  • the nitrile rubber with a double bond is significantly hardened and brittle when the temperature exceeds 110 °C.
  • Acrylate rubber also has excellent ozone resistance, airtightness, flexing resistance and crack growth resistance, and UV discoloration resistance. Therefore, the use of acrylate as the adhesive of the present application can be cured by means of thermal curing, the heat curing device is simple, the cost is low, and the curing time is short, which is advantageous for improving production efficiency.
  • a compound of aluminum siloxane, a two-terminal silanol type silicone oil, and a siloxane alkoxy oligomer is used as the heat curing adhesive.
  • a polycondensation reaction is produced between the aluminum siloxane, the two-terminal silanol type silicone oil, and the siloxane alkoxy oligomer to obtain transparency, multi-crosslinking number, high crosslinking density, and large bond energy.
  • the compound not only exhibits excellent light transmittance and heat resistance, but also exhibits an excellent tensile modulus of elasticity. Since there is no absorption in the ultraviolet region where the organic substance is decomposed, and it is hard to be deteriorated by light, it exhibits an excellent brightness retention ratio at the time of sealing. Therefore, the adhesive can be used as a good heat-curing adhesive material, the heat curing equipment is simple, the cost is low, and the curing time is short, which is advantageous for lifting. High production efficiency.
  • an ⁇ -cyanoacrylate compound is used as the self-evaporating curing adhesive.
  • Ethyl ⁇ -cyanoacrylate is a colorless, transparent, low viscosity, nonflammable liquid, single component, solvent free, slightly irritating, volatile, and volatile. In the case of moist moisture, it is catalyzed and quickly cures and sticks. Non-toxic after curing. Contact with traces of water vapor in the air, which is catalyzed by rapid polymerization and solidification, can be cured quickly. Therefore, the use of ⁇ -cyanoacrylate as the adhesive of the present application can be cured by means of self-evaporation, without additional investment in curing equipment, low cost, and short curing time, which is advantageous for improving production efficiency.
  • the embodiment shown in Figure 3 discloses a display panel.
  • the display panel includes:
  • the first substrate 10 is the first substrate 10,
  • the second substrate 20 is disposed opposite to the first substrate 10;
  • the plastic frame 30 is made of a self-evaporating curing or heat curing adhesive.
  • the first substrate 10 is provided with an alignment layer 40; the plastic frame 30 is only coated on the first substrate 10; and the alignment layer 40 is disposed at an inner position of the plastic frame 30.
  • the first substrate 10 is generally made of glass. The glass material does not absorb moisture, and the paste is more stable. It is not easy to fall off during long-term use of the display panel, which is beneficial to improve the stability of the product.
  • an acrylate compound is used as the heat curing adhesive.
  • Acrylation has high polarity and full saturation. Thereby it has superior resistance to mineral oil and high temperature oxidation resistance. Its oil resistance is second only to fluorine rubber, and similar to the general high-acrylonitrile content of nitrile rubber.
  • the heat resistance is between general rubber and silicon and fluorine rubber. It is 30 ⁇ 60°C higher than the temperature of nitrile rubber. The maximum temperature is 180°C. It can be used up to 200°C in intermittent and short time. It is hot at 150°C. There was no significant change in air aging performance for several years.
  • the most important thing is that it is very stable for extreme pressure type lubricating oils containing extreme pressure agents such as sulfur, chlorine and phosphorus.
  • the use temperature can reach 150 ° C, and the intermittent use temperature can be higher.
  • the nitrile rubber with a double bond is significantly hardened and brittle when the temperature exceeds 110 °C.
  • Acrylate rubber also has excellent ozone resistance, airtightness, flexing resistance and crack growth resistance, and UV discoloration resistance. Therefore,
  • the use of acrylate as the adhesive of the present application can be cured by means of thermal curing, the heat curing device is simple, the cost is low, and the curing time is short, which is advantageous for improving production efficiency.
  • a compound of aluminum siloxane, a two-terminal silanol type silicone oil, and a siloxane alkoxy oligomer is used as the heat curing adhesive.
  • a polycondensation reaction is produced between the aluminum siloxane, the two-terminal silanol type silicone oil, and the siloxane alkoxy oligomer to obtain transparency, multi-crosslinking number, high crosslinking density, and large bond energy.
  • the compound not only exhibits excellent light transmittance and heat resistance, but also exhibits an excellent tensile modulus of elasticity. Since there is no absorption in the ultraviolet region where the organic substance is decomposed, and it is hard to be deteriorated by light, it exhibits an excellent brightness retention ratio at the time of sealing. Therefore, the adhesive can be used as a good heat-curing adhesive material, the heat curing equipment is simple, the cost is low, and the curing time is short, which is favorable for improving production efficiency.
  • an ⁇ -cyanoacrylate compound is used as the self-evaporating curing adhesive.
  • Ethyl ⁇ -cyanoacrylate is a colorless, transparent, low viscosity, nonflammable liquid, single component, solvent free, slightly irritating, volatile, and volatile. In the case of moist moisture, it is catalyzed and quickly cures and sticks. Non-toxic after curing. Contact with traces of water vapor in the air, which is catalyzed by rapid polymerization and solidification, can be cured quickly. Therefore, the use of ⁇ -cyanoacrylate as the adhesive of the present application can be cured by means of self-evaporation, without additional investment in curing equipment, low cost, and short curing time, which is advantageous for improving production efficiency.
  • the embodiment shown in Figure 4 discloses a display panel.
  • the display panel includes:
  • the first substrate 10 is the first substrate 10,
  • the second substrate 20 is disposed opposite to the first substrate 10;
  • the plastic frame 30 is made of a self-evaporating curing or heat curing adhesive.
  • the first substrate 10 is provided with an alignment layer 40; the plastic frame 30 is only coated on the first substrate 10; and the alignment layer 40 is disposed at an inner position of the plastic frame 30.
  • the first substrate 10 is provided with a first recess 51 at a corresponding position of the plastic frame 30.
  • the first substrate 10 is generally made of glass material, the glass material does not absorb moisture, and the paste is more stable, and the display panel is not easy to fall off during long-term use, which is advantageous for lifting. High product stability. Due to the presence of the first groove 51, the adhesive does not easily flow during coating, and can be stably attached to the vicinity of the first groove 51. When the adhesive is cured, the adhesive is squeezed and does not easily diffuse to the display panel. In the display area, liquid crystal molecules are contaminated, which is conducive to improving display quality.
  • an acrylate compound is used as the heat curing adhesive.
  • Acrylation has high polarity and full saturation. Thereby it has superior resistance to mineral oil and high temperature oxidation resistance. Its oil resistance is second only to fluorine rubber, and similar to the general high-acrylonitrile content of nitrile rubber.
  • the heat resistance is between general rubber and silicon and fluorine rubber. It is 30 ⁇ 60°C higher than the temperature of nitrile rubber. The maximum temperature is 180°C. It can be used up to 200°C in intermittent and short time. It is hot at 150°C. There was no significant change in air aging performance for several years.
  • the use temperature can reach 150 ° C, and the intermittent use temperature can be higher.
  • the nitrile rubber with a double bond is significantly hardened and brittle when the temperature exceeds 110 °C.
  • Acrylate rubber also has excellent ozone resistance, airtightness, flexing resistance and crack growth resistance, and UV discoloration resistance. Therefore, the use of acrylate as the adhesive of the present application can be cured by means of thermal curing, the heat curing device is simple, the cost is low, and the curing time is short, which is advantageous for improving production efficiency.
  • a compound of aluminum siloxane, a two-terminal silanol type silicone oil, and a siloxane alkoxy oligomer is used as the heat curing adhesive.
  • a polycondensation reaction is produced between the aluminum siloxane, the two-terminal silanol type silicone oil, and the siloxane alkoxy oligomer to obtain transparency, multi-crosslinking number, high crosslinking density, and large bond energy.
  • the compound not only exhibits excellent light transmittance and heat resistance, but also exhibits an excellent tensile modulus of elasticity. Since there is no absorption in the ultraviolet region where the organic substance is decomposed, and it is hard to be deteriorated by light, it exhibits an excellent brightness retention ratio at the time of sealing. Therefore, the adhesive can be used as a good heat-curing adhesive material, the heat curing equipment is simple, the cost is low, and the curing time is short, which is favorable for improving production efficiency.
  • an ⁇ -cyanoacrylate compound is used as the self-evaporating curing adhesive.
  • Ethyl ⁇ -cyanoacrylate is a colorless, transparent, low viscosity, nonflammable liquid, single component, solvent free, slightly irritating, volatile, and volatile. In the case of moist moisture, it is catalyzed and quickly cures and sticks. Non-toxic after curing. Contact with traces of water vapor in the air, which is catalyzed by rapid polymerization and solidification, so Can be cured quickly. Therefore, the use of ⁇ -cyanoacrylate as the adhesive of the present application can be cured by means of self-evaporation, without additional investment in curing equipment, low cost, and short curing time, which is advantageous for improving production efficiency.
  • the embodiment shown in Figure 5 discloses a display panel.
  • the display panel includes:
  • the first substrate 10 is the first substrate 10,
  • the second substrate 20 is disposed opposite to the first substrate 10;
  • the plastic frame 30 is made of a self-evaporating curing or heat curing adhesive.
  • the first substrate 10 is provided with an alignment layer 40; the plastic frame 30 is only coated on the alignment layer 40.
  • the alignment layer 40 is made of an organic material and has a similar adhesion to the alignment layer 40, and has strong adhesion, which is advantageous for improving the bonding strength.
  • an acrylate compound is used as the heat curing adhesive.
  • Acrylation has high polarity and full saturation. Thereby it has superior resistance to mineral oil and high temperature oxidation resistance. Its oil resistance is second only to fluorine rubber, and similar to the general high-acrylonitrile content of nitrile rubber.
  • the heat resistance is between general rubber and silicon and fluorine rubber. It is 30 ⁇ 60°C higher than the temperature of nitrile rubber. The maximum temperature is 180°C. It can be used up to 200°C in intermittent and short time. It is hot at 150°C. There was no significant change in air aging performance for several years.
  • the use temperature can reach 150 ° C, and the intermittent use temperature can be higher.
  • the nitrile rubber with a double bond is significantly hardened and brittle when the temperature exceeds 110 °C.
  • Acrylate rubber also has excellent ozone resistance, airtightness, flexing resistance and crack growth resistance, and UV discoloration resistance. Therefore, the use of acrylate as the adhesive of the present application can be cured by means of thermal curing, the heat curing device is simple, the cost is low, and the curing time is short, which is advantageous for improving production efficiency.
  • a compound of aluminum siloxane, a two-terminal silanol type silicone oil, and a siloxane alkoxy oligomer is used as the heat curing adhesive.
  • a polycondensation reaction is produced between the aluminum siloxane, the two-terminal silanol type silicone oil, and the siloxane alkoxy oligomer to obtain transparency, multi-crosslinking number, high crosslinking density, and large bond energy.
  • the compound not only exhibits excellent light transmittance and heat resistance, but also exhibits excellent properties. Tensile modulus of elasticity. Since there is no absorption in the ultraviolet region where the organic substance is decomposed, and it is hard to be deteriorated by light, it exhibits an excellent brightness retention ratio at the time of sealing. Therefore, the adhesive can be used as a good heat-curing adhesive material, the heat curing equipment is simple, the cost is low, and the curing time is short, which is favorable for improving production efficiency.
  • an ⁇ -cyanoacrylate compound is used as the self-evaporating curing adhesive.
  • Ethyl ⁇ -cyanoacrylate is a colorless, transparent, low viscosity, nonflammable liquid, single component, solvent free, slightly irritating, volatile, and volatile. In the case of moist moisture, it is catalyzed and quickly cures and sticks. Non-toxic after curing. Contact with traces of water vapor in the air, which is catalyzed by rapid polymerization and solidification, can be cured quickly. Therefore, the use of ⁇ -cyanoacrylate as the adhesive of the present application can be cured by means of self-evaporation, without additional investment in curing equipment, low cost, and short curing time, which is advantageous for improving production efficiency.
  • the embodiment shown in Figure 6 discloses a display panel.
  • the display panel includes:
  • the first substrate 10 is the first substrate 10,
  • the second substrate 20 is disposed opposite to the first substrate 10;
  • the plastic frame 30 is made of a self-evaporating curing or heat curing adhesive.
  • the first substrate 10 is provided with an alignment layer 40; the plastic frame 30 is only coated on the alignment layer 40.
  • the first substrate 10 is provided with a second recess 52 at a corresponding position of the plastic frame 30; the alignment layer 40 forms a third recess 53 at a corresponding position of the second recess 52.
  • the alignment layer 40 is made of an organic material and has a similar adhesion to the alignment layer 40, and has strong adhesion, which is advantageous for improving the bonding strength. Due to the presence of the third recess 53, the adhesive is less likely to flow during coating, and can be stably attached to the vicinity of the third recess 53. When the adhesive is cured, the adhesive is squeezed and does not easily diffuse to the display panel. In the display area, liquid crystal molecules are contaminated, which is conducive to improving display quality.
  • an acrylate compound is used as the heat curing adhesive.
  • Acrylation has high polarity and full saturation. Thereby it has superior resistance to mineral oil and high temperature oxidation resistance. Its oil resistance is second only to fluorine rubber, and similar to the general high-acrylonitrile content of nitrile rubber. Heat resistance is between general rubber Compared with silicon and fluororubber, it is 30 ⁇ 60°C higher than nitrile rubber, the highest temperature is 180°C, and it can be used up to 200°C in intermittent and short time. There is no obvious change in the performance of hot air aging at 150°C for several years. .
  • the use temperature can reach 150 ° C, and the intermittent use temperature can be higher.
  • the nitrile rubber with a double bond is significantly hardened and brittle when the temperature exceeds 110 °C.
  • Acrylate rubber also has excellent ozone resistance, airtightness, flexing resistance and crack growth resistance, and UV discoloration resistance. Therefore, the use of acrylate as the adhesive of the present application can be cured by means of thermal curing, the heat curing device is simple, the cost is low, and the curing time is short, which is advantageous for improving production efficiency.
  • a compound of aluminum siloxane, a two-terminal silanol type silicone oil, and a siloxane alkoxy oligomer is used as the heat curing adhesive.
  • a polycondensation reaction is produced between the aluminum siloxane, the two-terminal silanol type silicone oil, and the siloxane alkoxy oligomer to obtain transparency, multi-crosslinking number, high crosslinking density, and large bond energy.
  • the compound not only exhibits excellent light transmittance and heat resistance, but also exhibits an excellent tensile modulus of elasticity. Since there is no absorption in the ultraviolet region where the organic substance is decomposed, and it is hard to be deteriorated by light, it exhibits an excellent brightness retention ratio at the time of sealing. Therefore, the adhesive can be used as a good heat-curing adhesive material, the heat curing equipment is simple, the cost is low, and the curing time is short, which is favorable for improving production efficiency.
  • an ⁇ -cyanoacrylate compound is used as the self-evaporating curing adhesive.
  • Ethyl ⁇ -cyanoacrylate is a colorless, transparent, low viscosity, nonflammable liquid, single component, solvent free, slightly irritating, volatile, and volatile. In the case of moist moisture, it is catalyzed and quickly cures and sticks. Non-toxic after curing. Contact with traces of water vapor in the air, which is catalyzed by rapid polymerization and solidification, can be cured quickly. Therefore, the use of ⁇ -cyanoacrylate as the adhesive of the present application can be cured by means of self-evaporation, without additional investment in curing equipment, low cost, and short curing time, which is advantageous for improving production efficiency.
  • the embodiment discloses a method for manufacturing a display panel according to the present application.
  • the adhesive 70 is applied to the edge of the first substrate 10 by a gumming device 60, and then the adhesive is cured by self-evaporation curing or heat curing to form a plastic frame 30.
  • the first substrate is coated with an alignment layer and formed
  • the positional relationship between the rear plastic frame and the first substrate and the alignment layer can be referred to the above embodiment. Due to the curing by means of heat curing or self-evaporation, the coating equipment is relatively simple and inexpensive compared to the way of ultraviolet curing.
  • the embodiment further discloses a display device comprising the display panel of the present application and a backlight module located on the light incident surface of the display panel.
  • the display device may include a liquid crystal panel, a plasma panel, or the like.
  • the liquid crystal panel includes an array substrate and a color filter substrate (CF), and the array substrate is disposed opposite to the color filter substrate, and the array is A liquid crystal and a photo spacer (PS) are disposed between the substrate and the color filter substrate, and a thin film transistor (TFT) is disposed on the array substrate, and a color filter layer is disposed on the color filter substrate.
  • PS photo spacer
  • TFT thin film transistor
  • the display device of the present application may be a curved type panel.

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Abstract

一种显示面板和显示装置,显示面板包括第一基板(10),与第一基板(10)相向设置的第二基板(20);形成于第一基板(10)和第二基板(20)之间的胶框(30);胶框(30)采用自挥发固化或热固化的胶粘剂制成。

Description

一种显示面板和显示装置 【技术领域】
本申请涉及显示技术领域,更具体的说,涉及一种显示面板和显示装置。
【背景技术】
显示器具有机身薄、省电、无辐射等众多优点,得到了广泛的应用。现有市场上的显示器大部分为背光型显示器,其包括显示装置及背光模组(backlight module)。显示装置的工作原理是在两片平行的基板当中放置液晶分子,并在两片基板上施加驱动电压来控制液晶分子的旋转方向,以将背光模组的光线折射出来产生画面。
其中,薄膜晶体管显示器(Thin Film Transistor-Liquid Crystal Display,TFT-LCD)由于具有低的功耗、优异的画面品质以及较高的生产良率等性能,目前已经逐渐占据了显示领域的主导地位。同样,薄膜晶体管显示器包含显示装置和背光模组,显示装置包括彩膜基板(Color Filter Substrate,CF Substrate,也称彩色滤光片基板)和薄膜晶体管阵列基板(Thin Film Transistor Substrate,TFT Substrate),上述基板的相对内侧存在透明电极。两片基板之间夹一层液晶分子(Liquid Crystal,LC)。显示装置是通过电场对液晶分子取向的控制,改变光的偏振状态,并藉由偏光板实现光路的穿透与阻挡,实现显示的目的。
另有一种OLED显示器,采用有机发光二极管(Organic Light-Emitting Diode,UIV OLED)进行自发光显示。与液晶显示(Liquid Crystal Display,LCD)是不同类型的发光原理。OLED显示技术具有自发光、广视角、几乎无穷高的对比度、较低耗电、极高反应速度等优点。
现有的显示面板都需要采用胶水进行基板之间的固定,但现有的胶水涂布和固化需要昂贵的设备投入,且生产时间较长。
【发明内容】
本申请所要解决的技术问题是提供一种降低生产材料成本,提升生产效率的显示面板。
本申请的目的是通过以下技术方案来实现的:
一种显示面板,包括,
第一基板,
第二基板,与第一基板相向设置;
胶框,形成于第一基板和第二基板之间;
所述胶框采用自挥发固化或热固化胶粘剂制成。
进一步的,所述第一基板上设置有配向层;所述胶框同时涂布在配向层和第一基板上。第一基板一般是玻璃材质,玻璃材质不会吸收水汽,粘贴更稳定;而配向层为有机材质,与配向层材质相近,附着力强,因此,胶框同时粘贴在第一基板和配向层上,可以兼顾粘贴强度和稳定性。
进一步的,所述第一基板上设置有配向层;所述胶框仅涂布在第一基板上;所述配向层设置在所述胶框的内侧位置。第一基板一般是玻璃材质,玻璃材质不会吸收水汽,粘贴更稳定,在显示面板长期使用过程不易脱落,有利于提高产品的稳定性。
进一步的,所述第一基板在所述胶框对应位置设有第一凹槽。由于第一凹槽的存在,胶粘剂在涂布的时候不易流动,可以稳定附着在第一凹槽附近,在贴合固化的时候,胶粘剂会受到挤压,也不容易扩散到显示面板的显示区域内,污染液晶分子,有利于提高显示品质。
进一步的,所述第一基板上设置有配向层;所述胶框仅涂布在所述配向层上。配向层为有机材质,与配向层材质相近,附着力强,有利于提高粘贴强度。
进一步的,所述第一基板上设置有配向层;所述第一基板在所述胶框对应位置设有第二凹槽;所述配向层在第二凹槽对应位置形成第三凹槽。由于第三凹槽的存在,胶粘剂在涂布的时候不易流动,可以稳定附着在第三凹槽附近,在贴合固化的时候,胶粘剂会受到挤压,也不容易扩散到显示面板的显示区域 内,污染液晶分子,有利于提高显示品质。
进一步的,所述胶粘剂包括丙烯酸酯化合物。丙烯酸酯化具有高极性和完全饱和性。从而使其具有优越的耐矿物油和耐高温氧化性能。其耐油性仅次于氟胶,而与一般中高丙烯晴含量的丁腈橡胶相似。而耐热性介于通用橡胶和硅、氟橡胶之间,比丁腈橡胶使用温度高出30~60℃,最高使用温度180℃,断续和短时间使用可达200℃,在150℃热空气老化数年性能无明显变化。此外,最重要的是其对含有硫、氯、磷等极压剂的极压型润滑油十分稳定,使用温度可达150℃,间断使用温度可更高些。而带有双键的丁腈橡胶在含有极压剂的油中,当温度超过110℃时,即发生显著硬化与变脆。丙烯酸酯橡胶还具有优良的抗臭氧性、气密性、耐屈挠和耐裂口增长性,以及抗紫外线变色性等。因此,利用丙烯酸酯作为本申请的胶粘剂,可以利用热固化的方式进行固化,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
进一步的,所述胶粘剂包括铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物。通过铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物之间产生缩聚反应,得到具有透明性、多交联数、高的交联密度、和大的键能的化合物,不仅可以呈现出优异的透光率和耐热性,而且呈现出优异的抗拉弹性模量。在分解有机物质的紫外线区域不具有吸收,不易受到因光所导致的劣化,所以密封时呈现出优异的亮度保持率。因此,该胶粘剂可以作为良好的热固化黏合材料,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
进一步的,所述胶粘剂包括α-氰基丙烯酸乙酯化合物。物化性质:无色透明、低粘度、不可燃性液体,单一成分、无溶剂,稍有刺激味、易挥发、挥发气具弱摧泪性。遇潮湿水气即被催化,迅速合固化粘着。固化后无毒。接触空气中微量水汽,即被催化迅速聚合固化粘着之特性,因此可以快速固化。因此,利用α-氰基丙烯酸乙酯作为本申请的胶粘剂,可以利用自挥发的方式进行固化,无须额外的固化设备投资,成本低廉,且固化时间短,有利于提高生产效 率。
根据本申请的另一个方面,本申请还公开了一种显示装置,该显示装置包括本申请所述的显示面板。
本申请采用自挥发固化或热固化胶粘剂作为胶框材料,热固化胶粘剂需要的温控设备较为低廉,且固化速度可控,相比复杂的紫外线固化设备及涂布设备,具有成本优势,且生产效率更高。而自挥发的胶粘剂完全不需要固化设备,成本进一步降低。
【附图说明】
图1是本申请实施例的显示面板的结构示意图;
图2是本申请实施例的显示面板的另一结构示意图;
图3是本申请实施例的显示面板的另一结构示意图;
图4是本申请实施例的显示面板的另一结构示意图;
图5是本申请实施例的显示面板的另一结构示意图;
图6是本申请实施例的显示面板的另一结构示意图;
图7是本申请实施例的显示面板的制造方法示意图。
【具体实施方式】
这里所公开的具体结构和功能细节仅仅是代表性的,并且是用于描述本申请的示例性实施例的目的。但是本申请可以通过许多替换形式来具体实现,并且不应当被解释成仅仅受限于这里所阐述的实施例。
在本申请的描述中,需要理解的是,术语“中心”、“横向”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。此外,术语“第一”、“第二” 仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本申请的描述中,除非另有说明,“多个”的含义是两个或两个以上。另外,术语“包括”及其任何变形,意图在于覆盖不排他的包含。
在本申请的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。
这里所使用的术语仅仅是为了描述具体实施例而不意图限制示例性实施例。除非上下文明确地另有所指,否则这里所使用的单数形式“一个”、“一项”还意图包括复数。还应当理解的是,这里所使用的术语“包括”和/或“包含”规定所陈述的特征、整数、步骤、操作、单元和/或组件的存在,而不排除存在或添加一个或更多其他特征、整数、步骤、操作、单元、组件和/或其组合。
下面结合附图和较佳的实施例对本申请作进一步说明。
图1所示的实施方式公开了一种显示面板。该显示面板包括:
第一基板10,
第二基板20,与第一基板10相向设置;
胶框30,形成于第一基板10和第二基板20之间;
所述胶框30采用自挥发固化或热固化胶粘剂制成。
采用热固化胶粘剂需要的温控设备较为低廉,且固化速度可控,相比复杂的紫外线固化设备及涂布设备,具有成本优势,且生产效率更高。而自挥发的胶粘剂完全不需要固化设备,成本进一步降低。
可选的,采用丙烯酸酯化合物作为热固化胶粘剂。丙烯酸酯化具有高极性和完全饱和性。从而使其具有优越的耐矿物油和耐高温氧化性能。其耐油性仅 次于氟胶,而与一般中高丙烯晴含量的丁腈橡胶相似。而耐热性介于通用橡胶和硅、氟橡胶之间,比丁腈橡胶使用温度高出30~60℃,最高使用温度180℃,断续和短时间使用可达200℃,在150℃热空气老化数年性能无明显变化。此外,最重要的是其对含有硫、氯、磷等极压剂的极压型润滑油十分稳定,使用温度可达150℃,间断使用温度可更高些。而带有双键的丁腈橡胶在含有极压剂的油中,当温度超过110℃时,即发生显著硬化与变脆。丙烯酸酯橡胶还具有优良的抗臭氧性、气密性、耐屈挠和耐裂口增长性,以及抗紫外线变色性等。因此,利用丙烯酸酯作为本申请的胶粘剂,可以利用热固化的方式进行固化,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物作为热固化胶粘剂。通过铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物之间产生缩聚反应,得到具有透明性、多交联数、高的交联密度、和大的键能的化合物,不仅可以呈现出优异的透光率和耐热性,而且呈现出优异的抗拉弹性模量。在分解有机物质的紫外线区域不具有吸收,不易受到因光所导致的劣化,所以密封时呈现出优异的亮度保持率。因此,该胶粘剂可以作为良好的热固化黏合材料,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用α-氰基丙烯酸乙酯化合物作为自挥发固化的胶粘剂。α-氰基丙烯酸乙酯无色透明、低粘度、不可燃性液体,单一成分、无溶剂,稍有刺激味、易挥发、挥发气具弱摧泪性。遇潮湿水气即被催化,迅速合固化粘着。固化后无毒。接触空气中微量水汽,即被催化迅速聚合固化粘着之特性,因此可以快速固化。因此,利用α-氰基丙烯酸乙酯作为本申请的胶粘剂,可以利用自挥发的方式进行固化,无须额外的固化设备投资,成本低廉,且固化时间短,有利于提高生产效率。
图2所示的实施方式公开了一种显示面板。该显示面板包括:
第一基板10,
第二基板20,与第一基板10相向设置;
胶框30,形成于第一基板10和第二基板20之间;
所述胶框30采用自挥发固化或热固化胶粘剂制成。
其中,所述第一基板10上设置有配向层40;所述胶框30同时涂布在配向层40和第一基板10上。第一基板10一般是玻璃材质,玻璃材质不会吸收水汽,粘贴更稳定;而配向层40为有机材质,与配向层40材质相近,附着力强,因此,胶框30同时粘贴在第一基板10和配向层40上,可以兼顾粘贴强度和稳定性。
可选的,采用丙烯酸酯化合物作为热固化胶粘剂。丙烯酸酯化具有高极性和完全饱和性。从而使其具有优越的耐矿物油和耐高温氧化性能。其耐油性仅次于氟胶,而与一般中高丙烯晴含量的丁腈橡胶相似。而耐热性介于通用橡胶和硅、氟橡胶之间,比丁腈橡胶使用温度高出30~60℃,最高使用温度180℃,断续和短时间使用可达200℃,在150℃热空气老化数年性能无明显变化。此外,最重要的是其对含有硫、氯、磷等极压剂的极压型润滑油十分稳定,使用温度可达150℃,间断使用温度可更高些。而带有双键的丁腈橡胶在含有极压剂的油中,当温度超过110℃时,即发生显著硬化与变脆。丙烯酸酯橡胶还具有优良的抗臭氧性、气密性、耐屈挠和耐裂口增长性,以及抗紫外线变色性等。因此,利用丙烯酸酯作为本申请的胶粘剂,可以利用热固化的方式进行固化,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物作为热固化胶粘剂。通过铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物之间产生缩聚反应,得到具有透明性、多交联数、高的交联密度、和大的键能的化合物,不仅可以呈现出优异的透光率和耐热性,而且呈现出优异的抗拉弹性模量。在分解有机物质的紫外线区域不具有吸收,不易受到因光所导致的劣化,所以密封时呈现出优异的亮度保持率。因此,该胶粘剂可以作为良好的热固化黏合材料,热固化设备简单,成本低廉,且固化时间短,有利于提 高生产效率。
可选的,采用α-氰基丙烯酸乙酯化合物作为自挥发固化的胶粘剂。α-氰基丙烯酸乙酯无色透明、低粘度、不可燃性液体,单一成分、无溶剂,稍有刺激味、易挥发、挥发气具弱摧泪性。遇潮湿水气即被催化,迅速合固化粘着。固化后无毒。接触空气中微量水汽,即被催化迅速聚合固化粘着之特性,因此可以快速固化。因此,利用α-氰基丙烯酸乙酯作为本申请的胶粘剂,可以利用自挥发的方式进行固化,无须额外的固化设备投资,成本低廉,且固化时间短,有利于提高生产效率。
图3所示的实施方式公开了一种显示面板。该显示面板包括:
第一基板10,
第二基板20,与第一基板10相向设置;
胶框30,形成于第一基板10和第二基板20之间;
所述胶框30采用自挥发固化或热固化胶粘剂制成。
其中,所述第一基板10上设置有配向层40;所述胶框30仅涂布在第一基板10上;所述配向层40设置在所述胶框30的内侧位置。第一基板10一般是玻璃材质,玻璃材质不会吸收水汽,粘贴更稳定,在显示面板长期使用过程不易脱落,有利于提高产品的稳定性。
可选的,采用丙烯酸酯化合物作为热固化胶粘剂。丙烯酸酯化具有高极性和完全饱和性。从而使其具有优越的耐矿物油和耐高温氧化性能。其耐油性仅次于氟胶,而与一般中高丙烯晴含量的丁腈橡胶相似。而耐热性介于通用橡胶和硅、氟橡胶之间,比丁腈橡胶使用温度高出30~60℃,最高使用温度180℃,断续和短时间使用可达200℃,在150℃热空气老化数年性能无明显变化。此外,最重要的是其对含有硫、氯、磷等极压剂的极压型润滑油十分稳定,使用温度可达150℃,间断使用温度可更高些。而带有双键的丁腈橡胶在含有极压剂的油中,当温度超过110℃时,即发生显著硬化与变脆。丙烯酸酯橡胶还具有优良的抗臭氧性、气密性、耐屈挠和耐裂口增长性,以及抗紫外线变色性等。因此, 利用丙烯酸酯作为本申请的胶粘剂,可以利用热固化的方式进行固化,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物作为热固化胶粘剂。通过铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物之间产生缩聚反应,得到具有透明性、多交联数、高的交联密度、和大的键能的化合物,不仅可以呈现出优异的透光率和耐热性,而且呈现出优异的抗拉弹性模量。在分解有机物质的紫外线区域不具有吸收,不易受到因光所导致的劣化,所以密封时呈现出优异的亮度保持率。因此,该胶粘剂可以作为良好的热固化黏合材料,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用α-氰基丙烯酸乙酯化合物作为自挥发固化的胶粘剂。α-氰基丙烯酸乙酯无色透明、低粘度、不可燃性液体,单一成分、无溶剂,稍有刺激味、易挥发、挥发气具弱摧泪性。遇潮湿水气即被催化,迅速合固化粘着。固化后无毒。接触空气中微量水汽,即被催化迅速聚合固化粘着之特性,因此可以快速固化。因此,利用α-氰基丙烯酸乙酯作为本申请的胶粘剂,可以利用自挥发的方式进行固化,无须额外的固化设备投资,成本低廉,且固化时间短,有利于提高生产效率。
图4所示的实施方式公开了一种显示面板。该显示面板包括:
第一基板10,
第二基板20,与第一基板10相向设置;
胶框30,形成于第一基板10和第二基板20之间;
所述胶框30采用自挥发固化或热固化胶粘剂制成。
其中,所述第一基板10上设置有配向层40;所述胶框30仅涂布在第一基板10上;所述配向层40设置在所述胶框30的内侧位置。所述第一基板10在所述胶框30对应位置设有第一凹槽51。第一基板10一般是玻璃材质,玻璃材质不会吸收水汽,粘贴更稳定,在显示面板长期使用过程不易脱落,有利于提 高产品的稳定性。由于第一凹槽51的存在,胶粘剂在涂布的时候不易流动,可以稳定附着在第一凹槽51附近,在贴合固化的时候,胶粘剂会受到挤压,也不容易扩散到显示面板的显示区域内,污染液晶分子,有利于提高显示品质。
可选的,采用丙烯酸酯化合物作为热固化胶粘剂。丙烯酸酯化具有高极性和完全饱和性。从而使其具有优越的耐矿物油和耐高温氧化性能。其耐油性仅次于氟胶,而与一般中高丙烯晴含量的丁腈橡胶相似。而耐热性介于通用橡胶和硅、氟橡胶之间,比丁腈橡胶使用温度高出30~60℃,最高使用温度180℃,断续和短时间使用可达200℃,在150℃热空气老化数年性能无明显变化。此外,最重要的是其对含有硫、氯、磷等极压剂的极压型润滑油十分稳定,使用温度可达150℃,间断使用温度可更高些。而带有双键的丁腈橡胶在含有极压剂的油中,当温度超过110℃时,即发生显著硬化与变脆。丙烯酸酯橡胶还具有优良的抗臭氧性、气密性、耐屈挠和耐裂口增长性,以及抗紫外线变色性等。因此,利用丙烯酸酯作为本申请的胶粘剂,可以利用热固化的方式进行固化,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物作为热固化胶粘剂。通过铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物之间产生缩聚反应,得到具有透明性、多交联数、高的交联密度、和大的键能的化合物,不仅可以呈现出优异的透光率和耐热性,而且呈现出优异的抗拉弹性模量。在分解有机物质的紫外线区域不具有吸收,不易受到因光所导致的劣化,所以密封时呈现出优异的亮度保持率。因此,该胶粘剂可以作为良好的热固化黏合材料,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用α-氰基丙烯酸乙酯化合物作为自挥发固化的胶粘剂。α-氰基丙烯酸乙酯无色透明、低粘度、不可燃性液体,单一成分、无溶剂,稍有刺激味、易挥发、挥发气具弱摧泪性。遇潮湿水气即被催化,迅速合固化粘着。固化后无毒。接触空气中微量水汽,即被催化迅速聚合固化粘着之特性,因此 可以快速固化。因此,利用α-氰基丙烯酸乙酯作为本申请的胶粘剂,可以利用自挥发的方式进行固化,无须额外的固化设备投资,成本低廉,且固化时间短,有利于提高生产效率。
图5所示的实施方式公开了一种显示面板。该显示面板包括:
第一基板10,
第二基板20,与第一基板10相向设置;
胶框30,形成于第一基板10和第二基板20之间;
所述胶框30采用自挥发固化或热固化胶粘剂制成。
其中,所述第一基板10上设置有配向层40;所述胶框30仅涂布在所述配向层40上。配向层40为有机材质,与配向层40材质相近,附着力强,有利于提高粘贴强度。
可选的,采用丙烯酸酯化合物作为热固化胶粘剂。丙烯酸酯化具有高极性和完全饱和性。从而使其具有优越的耐矿物油和耐高温氧化性能。其耐油性仅次于氟胶,而与一般中高丙烯晴含量的丁腈橡胶相似。而耐热性介于通用橡胶和硅、氟橡胶之间,比丁腈橡胶使用温度高出30~60℃,最高使用温度180℃,断续和短时间使用可达200℃,在150℃热空气老化数年性能无明显变化。此外,最重要的是其对含有硫、氯、磷等极压剂的极压型润滑油十分稳定,使用温度可达150℃,间断使用温度可更高些。而带有双键的丁腈橡胶在含有极压剂的油中,当温度超过110℃时,即发生显著硬化与变脆。丙烯酸酯橡胶还具有优良的抗臭氧性、气密性、耐屈挠和耐裂口增长性,以及抗紫外线变色性等。因此,利用丙烯酸酯作为本申请的胶粘剂,可以利用热固化的方式进行固化,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物作为热固化胶粘剂。通过铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物之间产生缩聚反应,得到具有透明性、多交联数、高的交联密度、和大的键能的化合物,不仅可以呈现出优异的透光率和耐热性,而且呈现出优异的 抗拉弹性模量。在分解有机物质的紫外线区域不具有吸收,不易受到因光所导致的劣化,所以密封时呈现出优异的亮度保持率。因此,该胶粘剂可以作为良好的热固化黏合材料,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用α-氰基丙烯酸乙酯化合物作为自挥发固化的胶粘剂。α-氰基丙烯酸乙酯无色透明、低粘度、不可燃性液体,单一成分、无溶剂,稍有刺激味、易挥发、挥发气具弱摧泪性。遇潮湿水气即被催化,迅速合固化粘着。固化后无毒。接触空气中微量水汽,即被催化迅速聚合固化粘着之特性,因此可以快速固化。因此,利用α-氰基丙烯酸乙酯作为本申请的胶粘剂,可以利用自挥发的方式进行固化,无须额外的固化设备投资,成本低廉,且固化时间短,有利于提高生产效率。
图6所示的实施方式公开了一种显示面板。该显示面板包括:
第一基板10,
第二基板20,与第一基板10相向设置;
胶框30,形成于第一基板10和第二基板20之间;
所述胶框30采用自挥发固化或热固化胶粘剂制成。
其中,所述第一基板10上设置有配向层40;所述胶框30仅涂布在所述配向层40上。所述第一基板10在所述胶框30对应位置设有第二凹槽52;所述配向层40在第二凹槽52对应位置形成第三凹槽53。配向层40为有机材质,与配向层40材质相近,附着力强,有利于提高粘贴强度。由于第三凹槽53的存在,胶粘剂在涂布的时候不易流动,可以稳定附着在第三凹槽53附近,在贴合固化的时候,胶粘剂会受到挤压,也不容易扩散到显示面板的显示区域内,污染液晶分子,有利于提高显示品质。
可选的,采用丙烯酸酯化合物作为热固化胶粘剂。丙烯酸酯化具有高极性和完全饱和性。从而使其具有优越的耐矿物油和耐高温氧化性能。其耐油性仅次于氟胶,而与一般中高丙烯晴含量的丁腈橡胶相似。而耐热性介于通用橡胶 和硅、氟橡胶之间,比丁腈橡胶使用温度高出30~60℃,最高使用温度180℃,断续和短时间使用可达200℃,在150℃热空气老化数年性能无明显变化。此外,最重要的是其对含有硫、氯、磷等极压剂的极压型润滑油十分稳定,使用温度可达150℃,间断使用温度可更高些。而带有双键的丁腈橡胶在含有极压剂的油中,当温度超过110℃时,即发生显著硬化与变脆。丙烯酸酯橡胶还具有优良的抗臭氧性、气密性、耐屈挠和耐裂口增长性,以及抗紫外线变色性等。因此,利用丙烯酸酯作为本申请的胶粘剂,可以利用热固化的方式进行固化,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物作为热固化胶粘剂。通过铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物之间产生缩聚反应,得到具有透明性、多交联数、高的交联密度、和大的键能的化合物,不仅可以呈现出优异的透光率和耐热性,而且呈现出优异的抗拉弹性模量。在分解有机物质的紫外线区域不具有吸收,不易受到因光所导致的劣化,所以密封时呈现出优异的亮度保持率。因此,该胶粘剂可以作为良好的热固化黏合材料,热固化设备简单,成本低廉,且固化时间短,有利于提高生产效率。
可选的,采用α-氰基丙烯酸乙酯化合物作为自挥发固化的胶粘剂。α-氰基丙烯酸乙酯无色透明、低粘度、不可燃性液体,单一成分、无溶剂,稍有刺激味、易挥发、挥发气具弱摧泪性。遇潮湿水气即被催化,迅速合固化粘着。固化后无毒。接触空气中微量水汽,即被催化迅速聚合固化粘着之特性,因此可以快速固化。因此,利用α-氰基丙烯酸乙酯作为本申请的胶粘剂,可以利用自挥发的方式进行固化,无须额外的固化设备投资,成本低廉,且固化时间短,有利于提高生产效率。
参考图7,本实施方式公开一种本申请所述显示面板的制造方法。首先在第一基板10的边缘用涂胶设备60涂布胶粘剂70,然后采用自挥发固化或加热固化的方式使胶粘剂固化,形成胶框30。其中,第一基板上涂布由配向层,成型 后的胶框与第一基板、配向层的位置关系可以参考上述实施方式。由于采用热固化或自挥发的方式固化,相比紫外线固化的方式,其涂布设备相对简单,成本低廉。
本实施方式还公开一种显示装置,其包括本申请所述的显示面板,以及位于显示面板入光面的背光模组。
在上述实施例中,显示装置可包括液晶面板、等离子面板等,以液晶面板为例,液晶面板包括阵列基板和彩膜基板(CF),所述阵列基板与彩膜基板相对设置,所述阵列基板与彩膜基板之间设有液晶和间隔单元(photo spacer,PS),所述阵列基板上设有薄膜晶体管(TFT),彩膜基板上设有彩色滤光层。
在上述实施例中,本申请的显示装置可为曲面型面板。
以上内容是结合具体的优选实施方式对本申请所作的进一步详细说明,不能认定本申请的具体实施只局限于这些说明。对于本申请所属技术领域的普通技术人员来说,在不脱离本申请构思的前提下,还可以做出若干简单推演或替换,都应当视为属于本申请的保护范围。

Claims (19)

  1. 一种显示面板,包括,
    第一基板,
    第二基板,与第一基板相向设置;
    胶框,形成于第一基板和第二基板之间;
    所述胶框采用自挥发固化或热固化的胶粘剂制成;
    所述第一基板上设置有配向层;所述胶框同时涂布在配向层和第一基板上;所述第一基板在所述胶框对应位置设有第一凹槽;所述胶粘剂包括α-氰基丙烯酸乙酯化合物。
  2. 一种显示面板,包括,
    第一基板,
    第二基板,与第一基板相向设置;
    胶框,形成于第一基板和第二基板之间;
    所述胶框采用自挥发固化或热固化的胶粘剂制成。
  3. 根据权利要求2所述的显示面板,其中,所述第一基板上设置有配向层;所述胶框同时涂布在配向层和第一基板上。
  4. 根据权利要求3所述的显示面板,其中,所述第一基板上设置有配向层;所述胶框仅涂布在第一基板上;所述配向层设置在所述胶框的内侧位置。
  5. 根据权利要求4所述的显示面板,其中,所述第一基板在所述胶框对应位置设有第一凹槽。
  6. 根据权利要求2所述的显示面板,其中,所述第一基板上设置有配向层;所述胶框仅涂布在所述配向层上。
  7. 根据权利要求6所述的显示面板,其中,所述第一基板上设置有配向层;所述第一基板在所述胶框对应位置设有第二凹槽;所述配向层在第二凹槽对应位置形成第三凹槽。
  8. 根据权利要求2所述的显示面板,其中,所述胶粘剂包括丙烯酸酯化合物。
  9. 根据权利要求2所述的显示面板,其中,所述胶粘剂包括铝硅氧烷、两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物。
  10. 根据权利要求2所述的显示面板,其中,所述胶粘剂包括α-氰基丙烯酸乙酯化合物。
  11. 一种显示装置,其中,所述显示装置包括显示面板;所述显示面板包括:
    第一基板,
    第二基板,与第一基板相向设置;
    胶框,形成于第一基板和第二基板之间;
    所述胶框采用自挥发固化或热固化的胶粘剂制成。
  12. 根据权利要求11所述的显示装置,其中,所述第一基板上设置有配向层;所述胶框同时涂布在配向层和第一基板上。
  13. 根据权利要求12所述的显示装置,其中,所述第一基板上设置有配向层;所述胶框仅涂布在第一基板上;所述配向层设置在所述胶框的内侧位置。
  14. 根据权利要求13所述的显示装置,其中,所述第一基板在所述胶框对应位置设有第一凹槽。
  15. 根据权利要求11所述的显示装置,其中,所述第一基板上设置有配向层;所述胶框仅涂布在所述配向层上。
  16. 根据权利要求15所述的显示装置,其中,所述第一基板上设置有配向层;所述第一基板在所述胶框对应位置设有第二凹槽;所述配向层在第二凹槽对应位置形成第三凹槽。
  17. 根据权利要求11所述的显示装置,其中,所述胶粘剂包括丙烯酸酯化合物。
  18. 根据权利要求11所述的显示装置,其中,所述胶粘剂包括铝硅氧烷、 两末端硅烷醇型硅油和硅氧烷烷氧基低聚物的化合物。
  19. 根据权利要求11所述的显示装置,其中,所述胶粘剂包括α-氰基丙烯酸乙酯化合物。
PCT/CN2017/083792 2017-04-11 2017-05-10 一种显示面板和显示装置 Ceased WO2018188144A1 (zh)

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