WO2018181451A1 - 鋼板およびその製造方法と王冠およびdrd缶 - Google Patents
鋼板およびその製造方法と王冠およびdrd缶 Download PDFInfo
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- WO2018181451A1 WO2018181451A1 PCT/JP2018/012699 JP2018012699W WO2018181451A1 WO 2018181451 A1 WO2018181451 A1 WO 2018181451A1 JP 2018012699 W JP2018012699 W JP 2018012699W WO 2018181451 A1 WO2018181451 A1 WO 2018181451A1
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- crown
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
Definitions
- the present invention relates to a steel sheet, particularly a high-strength thin steel sheet having excellent formability and a method for producing the same.
- Typical examples of such steel plates include DRD (Drawing and Redrawing) cans formed by combining drawing and redrawing, as well as thin steel plates that serve as crown materials used as stoppers for glass bottles and the like.
- the present invention relates to a crown and a DRD can obtained by forming the steel plate.
- crowns are widely used for narrow-mouthed glass bottles.
- a crown is manufactured by press-molding a thin steel plate, and consists of a disk-shaped part that closes the mouth of the bottle and a bowl-shaped part around it. Seal the jar by caulking.
- Bottles that use crowns are often filled with high internal pressure contents such as beer and carbonated drinks. For this reason, even when the internal pressure increases due to a change in temperature or the like, the crown needs to have high pressure strength so that the crown is not deformed and the sealing of the bottle is not broken. Moreover, even if the strength of the material is sufficient, if the material uniformity of the steel plate used for the crown is low, the shape of the crown is not uniform, and those that are out of product specifications are included. Even if such a poorly shaped crown is caulked to the mouth of the bottle, sufficient sealing performance may not be obtained. Therefore, the steel plate used as the crown material must also be excellent in material uniformity.
- SR (Single Reduced) steel sheet is mainly used for the thin steel sheet used for the crown material.
- annealing is performed and temper rolling is performed.
- the sheet thickness of conventional steel plates for crowns is generally 0.22 mm or more, and sufficient compressive strength and formability are ensured by applying SR material made of mild steel used for food and beverage cans and the like. It was possible.
- the center of the crown is squeezed to some extent in the initial stage of molding, and then the outer edge is molded into a bowl shape.
- the material of the crown is a steel plate with low material uniformity
- the crown manufactured from the steel plate may have irregular outer diameters and heights, which may be out of product specifications. If the outer diameter and height of the crown become uneven, and there are things that deviate from the product specification, there is a problem that the yield when a large number of crowns are manufactured decreases.
- a crown whose outer diameter and height are out of specification is liable to cause leakage of contents during transportation after being plugged into a bottle, and has a problem that it does not serve as a lid.
- the crown Even if the outer diameter and height of the crown are within the product specification, if the steel plate strength is low, the crown may be removed due to insufficient pressure strength. In particular, when the plate thickness is as thin as 0.17 mm or less, for example, the crown is often disengaged according to the conventional pressure strength standard, and higher pressure strength is required as compared with the conventional case.
- the steel sheet described in Patent Document 1 uses steel containing 0.0060% or less of C, and has a predetermined relationship between the tension between the stands and the annealing temperature in secondary cold rolling. Value (direction / size) is obtained. Since this method does not control the hot rolling process that affects the formation of the metal structure, the obtained steel sheet has a large variation in material, and is difficult to put into practical use.
- the present invention has been made in view of the above problems, and an object of the present invention is to provide a steel plate having sufficient strength and excellent formability even when it is thinned, and a method for manufacturing the steel plate. Furthermore, the objective of this invention is providing the crown and DRD can excellent in shape stability adjusted to a predetermined dimension and shape.
- the inventors diligently studied how to solve the above-mentioned problems, and found that high strength and excellent formability can be imparted by specifying mechanical properties under a predetermined component composition.
- the present invention is derived from this finding, and the gist of the present invention is as follows.
- a DRD can comprising the steel plate according to (1) or (2).
- the present invention it is possible to provide a steel sheet having sufficient strength and excellent formability even with a thin wall, together with its advantageous manufacturing method. Furthermore, when the steel plate of the present invention is used for, for example, a crown or a DRD can, a crown having a high pressure strength and a DRD can excellent in shape stability can be formed.
- the steel sheet according to the present invention is in mass%, C: more than 0.0060% and 0.0100% or less, Si: 0.05% or less, Mn: 0.05% or more and 0.60% or less, P: 0.050. %: S: 0.050% or less, Al: 0.020% or more and 0.050% or less, N: 0.0140% or more and 0.0180% or less and Cr: 0.040% or less, the balance being It has a component composition of Fe and inevitable impurities, and an aging index in the rolling direction is 25 to 55 MPa.
- the "%" display regarding a component shows "mass%".
- C more than 0.0060% 0.0100% or less
- the aging index in the rolling direction of the steel sheet after the secondary cold rolling described later becomes less than 25 MPa, for example for crown use
- the pressure resistance decreases.
- wrinkles are generated in the flange portion when the DRD can is formed, resulting in a poorly shaped can.
- the C content exceeds 0.0100%, the ferrite of the steel sheet after the secondary cold rolling becomes too fine, the steel sheet strength is excessively increased, and the formability deteriorates, for example, when used for a crown In addition, the pressure strength is reduced due to the deterioration of the shape of the molded crown.
- the C content is more than 0.0060% and 0.0100% or less.
- the C content is 0.0065% or more and 0.0090% or less.
- the Si content is 0.05% or less.
- the Si content is preferably 0.004% or more. More preferably, it is 0.01% or more and 0.03% or less.
- Mn 0.05% or more and 0.60% or less
- the Mn content is 0.05% or more.
- the Mn content is set to 0.60% or less.
- the Mn content is 0.10% or more and 0.50% or less.
- the upper limit of the P content is 0.050%.
- the content of P is preferably made 0.001% or more.
- S 0.050% or less S combines with Mn in a steel plate to form MnS, and precipitates in a large amount to lower the hot ductility of the steel plate. This effect becomes significant when the S content exceeds 0.050%. Therefore, the upper limit of the S content is 0.050%. Further, in order to make S less than 0.005%, the removal S cost becomes excessive, so the S content is preferably made 0.004% or more.
- Al 0.020% or more and 0.050% or less
- Al is an element to be contained as a deoxidizing agent, and forms N and AlN in the steel to reduce the solid solution N in the steel. If the Al content is less than 0.020%, the effect as a deoxidizer becomes insufficient, causing solidification defects and increasing the steelmaking cost. Further, the aging index in the rolling direction of the steel sheet after the secondary cold rolling becomes less than 25 MPa, and for example, when it is used for a crown, the pressure strength decreases. Similarly, for example, when it is used for a DRD can, it causes a shape defect in which wrinkles are generated in the flange portion when the DRD can is formed.
- the Al content exceeds 0.050%, the formation of AlN increases, the amount of N contributing to the steel sheet strength as solute N described later decreases, and the steel sheet strength decreases. Is 0.050% or less.
- the Al content is 0.030% or less and 0.045% or less.
- N More than 0.0140% and 0.0180% or less
- the aging index in the rolling direction of the steel sheet after the secondary cold rolling becomes less than 25 MPa, which is used for, for example, a crown.
- the pressure strength decreases, and the amount of N that contributes to the strength of the steel sheet as solute N described later decreases, and the strength of the steel sheet decreases.
- a wrinkle will occur in a flange part at the time of DRD can fabrication, and it will become a poor shape can.
- the N content exceeds 0.0180%, the above aging index exceeds 55 MPa, and the steel sheet after the secondary cold rolling becomes excessively hardened, for example, when used for a crown, The shape deteriorates and the pressure strength decreases. Or when it uses for DRD cans, for example, the shape defect which a wrinkle generate
- the N content is more than 0.0150% and not more than 0.0170%.
- the Cr content exceeds 0.040%, the aging index in the rolling direction of the steel sheet after the secondary cold rolling becomes less than 25 MPa.
- the pressure strength is high. While decreasing, the amount of C which contributes to steel plate strength as solute C decreases, and steel plate strength decreases. Or when it uses for DRD cans, for example, the shape defect which a wrinkle generate
- the aging index in the rolling direction is 25 to 55 MPa. That is, when the aging index in the rolling direction of the steel sheet is less than 25 MPa, when the steel sheet is used for a crown, for example, a large number of crowns are formed and subjected to a pressure test, a crown having a low pressure strength is occasionally found. Thus, the yield when manufacturing the crown is reduced. Or when it uses for DRD cans, for example, the shape defect which a wrinkle generate
- the shape of the crown becomes non-uniform, and a large number of crowns are molded and subjected to a pressure test. As a result, there are some crowns with low pressure strength, and the yield in manufacturing the crown is lowered. Or when it uses for DRD cans, for example, the shape defect which a wrinkle generate
- the aging index satisfying the above is adjusted by adjusting the component composition, adjusting the heating temperature in the hot rolling process, the finishing rolling temperature, the rolling reduction of the final stand, and the winding temperature, and adjusting the rolling reduction of the primary cold rolling rate. And it can obtain by adjusting the cooling rate in a continuous annealing process, and adjusting the rolling reduction in a secondary cold rolling process. Details of the manufacturing conditions will be described later.
- the steel plate of the present invention is required to have a pressure strength that prevents the crown crimped on the mouth of the bottle from being removed by the internal pressure when the steel plate is used, for example.
- the steel plate for crowns that has been used conventionally has a thickness of 0.22 mm or more, but in order to reduce the thickness to 0.20 mm or less, particularly 0.18 mm or less, higher strength is required than before. .
- the yield strength of the steel sheet is less than 620 MPa, it is impossible to give sufficient pressure resistance to the thin crown as described above. For that purpose, the yield strength needs to be 620 MPa or more. If the yield strength is too high, the crown height becomes low during crown molding and the crown shape becomes non-uniform, so the yield strength in the rolling direction needs to be 700 MPa or less.
- yield strength can be measured by a metal material tensile test method shown in “JIS Z 2241”.
- a steel material (steel slab) having the above composition is heated at 1200 ° C. or higher, the finish rolling temperature is 870 ° C. or higher, and the rolling reduction of the final stand is 10% or higher.
- the holding time in the temperature range of 660 to 760 ° C. is 60 seconds or less, and the temperature is cooled to 450 ° C. or less at an average cooling rate of 10 ° C./s or more.
- the temperature specification is based on the surface temperature of the steel sheet.
- the average cooling rate is a value obtained by calculation based on the surface temperature. For example, the average cooling rate from the soaking temperature to a temperature range of 450 ° C. or less is ((soaking temperature ⁇ (temperature range of 450 ° C. or less)) / cooling time from the soaking temperature to (temperature range of 450 ° C. or less) ).
- the “temperature range of 450 ° C. or lower” in the above equation means a cooling stop temperature in the temperature range.
- the molten steel is adjusted to the above chemical components by a known method using a converter or the like, and then, for example, a slab by a continuous casting method is used as a steel material.
- Step material heating temperature 1200 ° C or higher
- the heating temperature of the steel material in the hot rolling process is set to 1200 ° C. or higher.
- the heating temperature is less than 1200 ° C.
- the amount of solute N necessary for securing strength in the present invention is reduced and the strength is lowered, so that the heating temperature is 1200 ° C. or higher.
- N in the steel is mainly present as AlN. Therefore, the total amount of N (Ntotal) minus the amount of N present as AlN (NasAlN) is subtracted (Ntotal ⁇ (NasAlN)). The amount of dissolved N was considered.
- the solute N amount is preferably 0.0141% or more, and can be ensured by setting the steel material heating temperature to 1200 ° C. or more.
- a more preferable amount of solute N is 0.0150% or more.
- the heating temperature of the steel material is preferably 1220 ° C. or more.
- the steel material heating temperature is preferably 1300 ° C. or lower because the effect is saturated even when the temperature exceeds 1300 ° C.
- the finishing temperature in the hot rolling process is less than 870 ° C.
- the aging index in the rolling direction of the steel sheet is less than 25 MPa, and for example, when it is used for a crown, the pressure resistance is lowered.
- a steel plate is used for, for example, a DRD can
- a shape defect that causes wrinkles in the flange portion at the time of forming the DRD can results.
- the finishing temperature is applied to, for example, a DRD can, a defective shape is generated in which wrinkles are generated in the flange portion when the DRD can is formed.
- the finishing temperature is 870 ° C. or higher.
- raising the finish rolling temperature more than necessary may make it difficult to produce a thin steel sheet.
- the finish rolling temperature is preferably in the temperature range of 870 ° C. or more and 950 ° C. or less.
- the rolling reduction of the final stand in the hot rolling process is 10% or more.
- the rolling reduction of the final stand is less than 10%, the aging index in the rolling direction of the steel sheet is less than 25 MPa, and for example, when it is used for a crown, the pressure resistance decreases.
- the rolling reduction of the final stand is 10% or more.
- the rolling reduction of the final stand is preferably 12% or more.
- the upper limit of the rolling reduction of the final stand is preferably 15% or less from the viewpoint of rolling load.
- Winding temperature 550-750 ° C
- the aging index in the rolling direction of the steel sheet is less than 25 MPa.
- the pressure resistance decreases when used for a crown, or for a DRD can, for example.
- the winding temperature is set to 550 ° C. or higher.
- the coiling temperature is higher than 750 ° C., a part of the ferrite of the steel sheet is coarsened, and the strength of the steel sheet is lowered.
- the winding temperature is preferably 750 ° C. or lower. Preferably they are 600 degreeC or more and 700 degrees C or less.
- pickling is preferably performed.
- the pickling is not particularly limited as long as the surface scale can be removed.
- the cold rolling is performed in two steps with the annealing interposed therebetween.
- Primary cold rolling reduction 88% or more
- the rolling reduction in the primary cold rolling process is 88% or more.
- the strain applied to the steel sheet by cold rolling decreases, so recrystallization in the continuous annealing process becomes non-uniform, and the size of the ferrite grain size after recrystallization
- the variation increases, the aging index in the rolling direction of the steel sheet after the secondary cold rolling becomes less than 25 MPa, and the pressure strength decreases.
- the rolling reduction in the primary cold rolling process is set to 88% or more. More preferably, the content is 89 to 94%.
- the soaking temperature in the continuous annealing step is 660 to 760 ° C.
- the soaking temperature is higher than 760 ° C., it is easy to cause troubles such as a heat buckle during continuous annealing, which is not preferable.
- the ferrite grain size of the steel sheet is partially increased to reduce the strength of the steel sheet, and the aging index in the rolling direction of the steel sheet is less than 25 MPa.
- the pressure strength decreases.
- a steel plate is used for, for example, a DRD can, a shape defect that causes wrinkles in the flange portion at the time of forming the DRD can results.
- the annealing temperature is less than 660 ° C., recrystallization becomes incomplete, the ferrite grain size of the steel sheet becomes partially fine, and the aging index in the rolling direction of the steel sheet after secondary cold rolling becomes less than 25 MPa. The pressure strength decreases.
- the soaking temperature is 660 to 760 ° C.
- the temperature is 680 to 730 ° C.
- the holding time when the soaking temperature is in the temperature range of 660 to 760 ° C is 60 seconds or less.
- C contained in the steel sheet segregates to the ferrite grain boundary, precipitates as carbides in the cooling process in the continuous annealing process, reduces the amount of solute C contributing to the steel sheet strength, and yield.
- the strength decreases the aging index in the rolling direction of the steel sheet after the secondary cold rolling becomes less than 25 MPa, and the pressure strength decreases.
- a shape defect that causes wrinkles in the flange portion at the time of forming the DRD can results.
- the holding time when the soaking temperature is in the temperature range of 660 to 760 ° C. is set to 60 seconds or less.
- the holding time is less than 5 seconds, the stability when the steel plate passes through the soaking roll is impaired, and therefore the holding time is preferably 5 seconds or more.
- Pre-cooling Cooling to 450 ° C or less at an average cooling rate of 10 ° C / s or more
- the average cooling rate is less than 10 ° C./s, carbide precipitation is promoted during cooling, the amount of solute C contributing to the steel plate strength is reduced, the yield strength is reduced, and the steel plate after the secondary cold rolling.
- the aging index in the rolling direction becomes less than 25 MPa, and the pressure strength decreases.
- an average cooling rate shall be 50 degrees C / s or less.
- carbide precipitation is promoted after the former stage cooling, the amount of solute C contributing to the steel sheet strength is reduced, the yield strength is lowered, and The aging index in the rolling direction of the steel sheet after the next cold rolling becomes less than 25 MPa, and the pressure strength decreases.
- a shape defect in which wrinkles are generated in the flange portion when the DRD can is formed is caused.
- the cooling stop temperature in the pre-cooling after soaking is less than 300 ° C., not only the carbide precipitation suppression effect is saturated, but also the aging index in the rolling direction of the steel sheet after secondary cold rolling becomes more than 55 MPa, and the steel sheet strength
- the shape of the crown becomes uneven, and if a large number of crowns are molded and subjected to a pressure test, there will be some crowns with low pressure strength. Yield in manufacturing decreases.
- the cooling stop temperature after soaking is preferably 300 ° C. or higher.
- the average cooling rate in the subsequent cooling is preferably 30 ° C./s or less. More preferably, it is 25 ° C./s or less. In the latter stage cooling, it is cooled to 140 ° C. or lower.
- the amount of solute C contributing to the strength of the steel sheet is reduced, the yield strength is reduced, and the aging index in the rolling direction of the steel sheet after the secondary cold rolling is less than 25 MPa, so that the pressure strength is reduced.
- a steel plate is used for, for example, a DRD can, a shape defect in which wrinkles are generated in the flange portion when the DRD can is formed is caused.
- the cooling stop temperature is less than 100 ° C., the effect is saturated, and an excessive cost is generated in the cooling facility. More preferably, it is 120 ° C. or higher.
- the steel sheet of the present invention can obtain high yield strength by the second cold rolling after annealing. That is, when the rolling reduction of secondary cold rolling is less than 10%, sufficient yield strength cannot be obtained, and for example, the pressure resistance when used for a crown is lowered. Moreover, if the rolling reduction of secondary cold rolling exceeds 40%, anisotropy will become excessive, for example, the pressure-resistant intensity
- the cold-rolled steel sheet obtained as described above is then subjected to plating treatment such as tin plating, chromium plating, nickel plating, etc., for example, by electroplating on the surface of the steel sheet, if necessary, to form a plating layer.
- plating treatment such as tin plating, chromium plating, nickel plating, etc.
- electroplating on the surface of the steel sheet, if necessary, to form a plating layer.
- the steel sheet of the present invention can have sufficient strength and excellent material uniformity even if it is thinned. Therefore, the steel sheet of the present invention is particularly suitable as a material for crowns or DRD cans.
- the crown of the present invention is formed using the steel plate described above.
- the crown is mainly composed of a disk-shaped part that closes the mouth of the bottle and a bowl-shaped part provided around the disk-shaped part.
- the crown of the present invention can be formed by press molding after punching the steel plate of the present invention into a circular blank. Since the crown of the present invention is manufactured from a steel sheet having sufficient yield strength and excellent material uniformity, it has excellent pressure resistance as a crown even when it is thinned, and has an outer diameter and high crown. Since the uniformity of the thickness is excellent, the yield in the crown manufacturing process is improved, and the amount of waste generated by the crown manufacturing is reduced.
- the DRD can of the present invention is formed using the steel plate described above.
- the DRD can be formed by punching the steel sheet of the present invention into a circular blank and then performing drawing and redrawing. Since the DRD can made of the steel plate of the present invention has a uniform shape and does not deviate from the product standard, the yield in the DRD can manufacturing process is improved, and the amount of waste generated in the DRD can manufacturing is reduced. Have.
- Steel slabs were obtained by containing the component composition shown in Table 1, with the balance being made of Fe and unavoidable impurities in a converter and continuously cast.
- the steel slab obtained here was subjected to hot rolling at the slab heating temperature, finish rolling temperature, and winding temperature shown in Table 2. After this hot rolling, pickling was performed. Next, primary cold rolling was performed at the rolling reduction shown in Table 2, and continuous annealing was performed under the continuous annealing conditions shown in Table 2, followed by secondary cold rolling at the rolling reduction shown in Table 2.
- the obtained steel sheet was continuously subjected to electrolytic chromic acid treatment to obtain tin-free steel.
- the steel plate obtained in accordance with the above was subjected to a heat treatment equivalent to 210 ° C. and 15 minutes of paint baking, and then subjected to a tensile test.
- the tensile test was performed according to “JIS Z 2241” using a JIS No. 5 size tensile test piece, and the yield strength in the rolling direction was measured. Further, the aging index in the rolling direction of the steel sheet was determined according to the measurement method described above.
- the heat treatment equivalent to this paint baking does not affect the steel plate material before the heat treatment.
- the obtained crown was also subjected to a pressure resistance test.
- the pressure resistance test was performed by molding a vinyl chloride liner inside the crown, plugging it into a commercial beer bottle, measuring the internal pressure at which the crown was released using the Secure Pal Secure Security Tester, and measuring the internal pressure at which the crown was released. The pressure strength was taken.
- the pressure resistance test is performed on 50 crowns, the number of crowns with a pressure strength of 165 psi or more is 47 or more, and the number of crowns with a pressure strength of 165 psi or more is 45 or 46 , And the case where the number of crowns having a pressure strength of 165 psi or more and less than 45 was evaluated as x.
- Table 2 The obtained results are shown in Table 2.
- the obtained steel sheet was subjected to a heat treatment equivalent to coating baking at 210 ° C. for 15 minutes, then formed into a DRD can, and the DRD can formability was evaluated. That is, using a circular blank having a diameter of 158 mm, drawing and redrawing were performed, a DRD can having an inner diameter of 82.8 mm and a flange diameter of 102 mm was formed, and DRD can moldability was evaluated.
- the steel sheets 1 to 22 had a stable pressure resistance, with a yield strength in the rolling direction of 600 MPa or more and a number of crowns having a pressure strength of 165 psi or more and 45 or more crowns. Further, the yield strength in the rolling direction was 560 MPa or more, and the standard deviation of the crown height was 0.09 mm or less, the crown moldability was good, and the DRD can moldability was good.
- the steel plate No. 29 has too much Mn content, so that the steel plate is excessively hardened and the shape of the crown deteriorates, so that the number of crowns having a pressure strength of 165 psi or more is less than 45 and has a high pressure resistance. The strength was not stably obtained. Moreover, it turned out that DRD can moldability also deteriorates.
- the steel plate No. 31 has too little Al content, the effect as a deoxidizing agent is insufficient, causing the occurrence of solidification defects and increasing the steelmaking cost.
- No. Steel plates 32 to 34 have an N content that is too high, so the aging index is over 55 MPa, the steel plate after secondary cold rolling is excessively hardened, and the shape of the formed crown is uneven. As a result, the number of crowns having a pressure strength of 165 psi or more was less than 45, and a high pressure strength could not be stably obtained. Moreover, it turned out that DRD can moldability also deteriorates.
- No. Steel sheets 35 to 37 have a low N content, so the aging index in the rolling direction of the steel sheet after secondary cold rolling is less than 25 MPa, and the number of crowns with a pressure strength of 165 psi or more is less than 45 and stable. It was found that the amount of N contributing to the steel plate strength as a solid solution N is reduced and the steel plate strength is lowered. Moreover, it turned out that DRD can moldability also deteriorates.
- the aging index in the rolling direction of the steel plate after the secondary cold rolling is less than 25 MPa, and the shape of the formed crown is non-uniform.
- the number of crowns having a strength of 165 psi or more was less than 45, and high pressure strength could not be stably obtained.
- DRD can moldability also deteriorates.
- the steel plate No. 39 has too much Cr, the aging index in the rolling direction of the steel plate after secondary cold rolling is less than 25 MPa, the number of crowns with a pressure strength of 165 psi or more is less than 45, and stable pressure resistance. It has been found that the amount of C that does not have strength and contributes to steel plate strength as solute C is reduced, and the steel plate strength is reduced. Moreover, it turned out that DRD can moldability also deteriorates.
- No. The number of crowns having a pressure strength of 165 psi or more is less than 45 due to the fact that the steel plate of 40 has too much Si content and the steel plate becomes excessively hard and the shape of the molded crown becomes non-uniform. Thus, a high pressure strength could not be stably obtained. Moreover, it turned out that DRD can moldability also deteriorates.
- Steel slabs were obtained by melting the steel having the component compositions of 4, 10 and 17 with the balance being Fe and inevitable impurities in a converter and continuously casting the steel.
- the steel slab obtained here was hot-rolled at the slab heating temperature, finish rolling temperature, and coiling temperature shown in Table 3. After hot rolling, pickling was performed. Next, primary cold rolling is performed at the rolling reduction shown in Table 3, and the soaking temperature, soaking time, precooling average speed, precooling cooling stop temperature, precooling average cooling speed, and postcooling cooling stop temperature shown in Table 3 are used. Continuous annealing was performed, followed by secondary cold rolling at the rolling reduction shown in Table 3.
- the obtained steel sheet was continuously subjected to electrolytic chromic acid treatment to obtain tin-free steel.
- the steel plate obtained as described above was subjected to a tensile test by the same method as described above, and similarly the aging index in the rolling direction of the steel plate was obtained. Furthermore, the crown moldability, the pressure strength of the crown and the DRD can moldability were evaluated in the same manner as described above. The obtained results are shown in Table 3.
- steel plate No. which is an example of the present invention.
- Steel plates of 41, 44, 46, 48, 49, 53 to 56, 59, 60, 64 have 45 or more crowns with a yield strength in the rolling direction of 600 MPa or more and a pressure strength of 165 psi or more, It had a stable pressure strength. Further, the yield strength in the rolling direction was 560 MPa or more, and the standard deviation of the crown height was 0.09 mm or less, the crown moldability was good, and the DRD can moldability was also good.
- steel plate No. which is a comparative example.
- Steel plates 42, 43, 45, 47, 50, 51, 52, 57, 58, 61, 62, 65, and 67 have slab heating temperature, finish rolling temperature, rolling reduction at the final stand in the hot rolling process, and winding.
- any of temperature, primary cold rolling reduction, soaking temperature, soaking holding time, pre-cooling average speed, secondary cold rolling reduction, and post-cooling average speed are out of the scope of the present invention, so secondary cold rolling It was found that the aging index in the rolling direction of the later steel sheet was less than 25 MPa, the number of crowns having a compressive strength of 165 psi or more was less than 45, and there was no stable compressive strength and / or the yield strength in the rolling direction was reduced. . Alternatively and / or DRD can moldability was found to deteriorate.
- Steel plate No. is a comparative example.
- the steel plate No. 63 has a secondary cold reduction ratio that is too high, so that the anisotropy becomes excessive, and the number of crowns having a pressure strength of 165 psi or more is less than 45 due to impairing the uniformity of the crown shape. It was found that it does not have a stable pressure strength. Moreover, it turned out that DRD can moldability deteriorates.
- Steel plate No. is a comparative example. Since the steel plate No. 66 has a too low pre-cooling stop temperature, the aging index in the rolling direction of the steel plate after the secondary cold rolling is over 55 MPa, the steel plate strength is excessively increased, and the pressure strength is 165 psi or higher. The number was less than 45, and it was found that the pressure resistance was not stable. Moreover, it turned out that DRD can moldability deteriorates.
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Abstract
Description
C:0.0060%超0.0100%以下、
Si:0.05%以下、
Mn:0.05%以上0.60%以下、
P:0.050%以下、
S:0.050%以下、
Al:0.020%以上0.050%以下、
N:0.0140%超0.0180%以下および
Cr:0.040%以下
を含有し、残部はFeおよび不可避的不純物の成分組成を有し、
圧延方向の時効指数が25~55MPaであり、
降伏強度が620~700MPaである鋼板。
鋼素材を1200℃以上で加熱し、仕上げ圧延温度:870℃以上および最終スタンドの圧下率:10%以上の条件にて圧延を施して550~750℃の温度範囲内で巻取る熱間圧延工程と、
前記熱間圧延後の熱延板に酸洗を行う酸洗工程と、
前記酸洗後の熱延板に、圧下率:88%以上の冷間圧延を行う一次冷間圧延工程と、
前記一次冷間圧延後の冷延板を、660~760℃の温度域に60秒以下で保持したのち、10℃/s以上の平均冷却速度で450℃以下の温度域まで冷却し、次いで5℃/s以上の平均冷却速度で140℃以下の温度域まで冷却する焼鈍工程と、
前記焼鈍板に、10%以上40%以下の圧下率で冷間圧延を行う二次冷間圧延工程と、を有する鋼板の製造方法。
まず、鋼板の成分組成における各成分量の限定理由から順に説明する。なお、成分に関する「%」表示は、特に断らない限り「質量%」を示す。
Cの含有量を0.0060%以下とすると、後述の二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に、耐圧強度が低下する。同様に、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生し形状不良の缶となる。一方、C含有量が0.0100%超となると、二次冷間圧延後の鋼板のフェライトが微細となりすぎて鋼板強度が過剰に上昇して成形性が劣化し、例えば王冠用に供した場合に、成形した王冠の形状が劣化することに起因して、耐圧強度が低下する。同様に、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生し形状不良の缶となる。よって、Cの含有量は0.0060%超0.0100%以下とする。好ましくは、Cの含有量は0.0065%以上0.0090%以下とする。
Siを多く含むと鋼板強度が過剰に上昇して成形性が劣化し、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。よって、Siの含有量は0.05%以下とする。また、過剰にSiを低下させることは製鋼コストの増大を招くため、Siの含有量は0.004%以上とすることが好ましい。より好ましくは、0.01%以上0.03%以下である。
Mnの含有量が0.05%を下回ると、Sの含有量を低下させても熱間脆化を回避することが困難になり、連続鋳造時に表面割れなどの問題が生じる。よって、Mnの含有量は0.05%以上とする。一方、Mnを多く含むと、Cと同様の理由により、例えば王冠用に供した場合に、成形した王冠の形状が劣化して耐圧強度が低下する。同様に、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。よって、Mnの含有量は0.60%以下とする。好ましくは、Mnの含有量は0.10%以上0.50%以下である。
Pの含有量が0.050%を超えると、鋼板が過剰に硬質化し、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に、成形した王冠の形状が劣化するとともに、耐圧強度が低下する。同様に、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。よって、Pの含有量の上限値は0.050%とする。また、Pを0.001%未満とするには脱Pコストが過大となるため、Pの含有量は0.001%以上とすることが好ましい。
Sは、鋼板中でMnと結合してMnSを形成し、多量に析出することで鋼板の熱間延性を低下させる。Sの含有量が0.050%を超えるとこの影響が顕著となる。よって、Sの含有量の上限値は0.050%とする。また、Sを0.005%未満とするには脱Sコストが過大となるため、Sの含有量は0.004%以上とすることが好ましい。
Alは、脱酸剤として含有させる元素であり、また鋼中のNとAlNを形成し、鋼中の固溶Nを減少させる。Al含有量が0.020%未満であると脱酸剤としての効果が不十分になり、凝固欠陥の発生を招くとともに製鋼コストが増大する。さらに、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に耐圧強度が低下する。同様に、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。一方、Alの含有量が0.050%超となると、AlNの形成が増加して、後述する固溶Nとして鋼板強度に寄与するN量が低減し、鋼板強度が低下するため、Al含有量は0.050%以下とする。好ましくは、Al含有量は0.030%以下0.045%以下である。
Nの含有量を0.0140%以下とすると、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に耐圧強度が低下するとともに、後述する固溶Nとして鋼板強度に寄与するN量が低減し、鋼板強度が低下する。あるいは、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生し形状不良の缶となる。一方、N含有量が0.0180%超となると、上記の時効指数が55MPa超となり、二次冷間圧延後の鋼板が過剰に硬質化し、例えば王冠用に供した場合に、成形した王冠の形状が劣化して耐圧強度が低下する。あるいは、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。好ましくは、Nの含有量は0.0150%超0.0170%以下とする。
Crの含有量が0.040%を超えると、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に耐圧強度が低下するとともに、固溶Cとして鋼板強度に寄与するC量が低減し、鋼板強度が低下する。あるいは、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。よって、Crの含有量の上限値は0.040%とする。また、Crを0.001%未満とするためには製鋼コストが過大となるため、Crの含有量は0.001%以上とすることが好ましい。
以上の成分以外の残部は、Feおよび不可避的不純物とする。
すなわち、鋼板の圧延方向の時効指数が25MPa未満となると、該鋼板を例えば王冠用に供して多数の王冠を成形して耐圧試験に供した場合に、耐圧強度の低い王冠が散見されることになり、王冠を製造する際の歩留りが低下する。あるいは、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。一方、時効指数が55MPaを超えると、鋼板強度が過剰に上昇するために、例えば王冠用に供した際に王冠の形状が不均一となり、多数の王冠を成形して耐圧試験に供した場合に、耐圧強度の低い王冠が散見されることになり、王冠を製造する際の歩留りが低下する。あるいは、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。
時効指数=(P2-P1)/A (A;予ひずみ前の試験片平行部断面積)
すなわち、本発明の鋼板には、例えば王冠に供する場合に、瓶の口にかしめた王冠が内圧によって外れないための、耐圧強度が求められる。従来用いられてきた王冠用鋼板の板厚は0.22mm以上であったが、板厚を0.20mm以下、特に0.18mm以下とする薄肉化にあたっては、従来よりも高い強度が必要となる。鋼板の降伏強度が620MPa未満であると、上記のような薄肉化した王冠に十分な耐圧強度を付与することが不可能である。そのためには、降伏強度は620MPa以上である必要がある。降伏強度が高すぎると王冠成形時に王冠高さが低くなり王冠形状が不均一となるため、圧延方向の降伏強度は700MPa以下である必要がある。
本発明の鋼板は、上記成分組成からなる鋼素材(鋼スラブ)を、1200℃以上で加熱し、仕上げ圧延温度が870℃以上で、最終スタンドの圧下率が10%以上とし、550~750℃の温度範囲内で巻取る熱間圧延工程と、前記熱間圧延後に酸洗する酸洗工程と、前記酸洗工程後に、圧下率が88%以上で冷間圧延する一次冷間圧延工程と、前記一次冷間圧延後に、均熱温度が660~760℃の温度域にある保持時間が60秒以下とし、10℃/s以上の平均冷却速度で450℃以下の温度域まで冷却し、5℃/s以上の平均冷却速度で140℃以下の温度域まで冷却する連続焼鈍工程と、10%以上40%以下の圧下率で二次冷間圧延を行うことで製造される。
熱間圧延工程の鋼素材の加熱温度は1200℃以上とする。該加熱温度が1200℃未満であると、本発明において強度を確保するために必要な固溶N量が低減し、強度が低下するため、1200℃以上とする。なお、本発明の鋼組成では鋼中Nは主にAlNとして存在すると考えられるため、Nの総量(Ntotal)からAlNとして存在するN量(NasAlN)を差し引いた(Ntotal-(NasAlN))を固溶N量とみなした。鋼板の圧延方向の降伏強度を600MPa以上とするためには、固溶N量は0.0141%以上であることが好ましく、鋼素材加熱温度を1200℃以上とすることで確保することができる。より好ましい固溶N量は、0.0150%以上であり、そのためには鋼素材加熱温度を1220℃以上とするとよい。鋼素材加熱温度は1300℃超としても効果が飽和するため1300℃以下が好ましい。
熱間圧延工程の仕上げ温度が870℃未満となると、鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。従って、仕上げ温度は、例えばDRD缶用に供した場合、DRD缶成形時にフランジ部にしわが発生する形状不良を生じる。従って、仕上げ温度は、870℃以上とする。一方、必要以上に仕上げ圧延温度を高くすることは薄鋼板の製造を困難にする場合がある。具体的には、仕上げ圧延温度は870℃以上950℃以下の温度範囲内とすることが好ましい。
熱間圧延工程の最終スタンドの圧下率は10%以上とする。最終スタンドの圧下率が10%未満となると、鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。従って、最終スタンドの圧下率は10%以上とする。フェライト粒径の標準偏差を小さくするには最終スタンドの圧下率は12%以上とすることが好ましい。最終スタンドの圧下率の上限は、圧延荷重の観点で15%以下とすることが好ましい。
熱間圧延工程の巻取温度が550℃未満となると、鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に耐圧強度が低下するため、あるいは、例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。従って、巻取温度は550℃以上とする。一方、巻取温度が750℃より高くなると、鋼板のフェライトの一部が粗大化し、鋼板の強度が低下し、例えば王冠用に供した場合に耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。従って、巻取温度は750℃以下が好ましい。好ましくは600℃以上700℃以下である。
その後、酸洗を行うことが好ましい。酸洗は、表層スケールが除去できればよく、特に条件を限定する必要はない。
(一次冷間圧延圧下率:88%以上)
まず、一次冷間圧延工程の圧下率は88%以上とする。一次冷間圧延工程の圧下率は88%未満となると冷間圧延で鋼板に付与されるひずみが低下するため、連続焼鈍工程における再結晶が不均一となり、再結晶後のフェライト粒径のサイズのばらつきが大きくなり、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となって耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。従って、一次冷間圧延工程の圧下率は88%以上とする。より好ましくは89~94%とする。
(均熱温度:660~760℃)
すなわち、連続焼鈍工程における均熱温度は、660~760℃の温度で行う。均熱温度を760℃超とすると、連続焼鈍においてヒートバックルなどの通板トラブルが発生しやすくなり、好ましくない。また、鋼板のフェライト粒径が一部粗大化し、鋼板の強度が低下するとともに、鋼板の圧延方向の時効指数が25MPa未満となり、例えば王冠用に供した場合に耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。一方、焼鈍温度が660℃未満であると、再結晶が不完全となり、鋼板のフェライト粒径が一部細かくなり、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となって耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。従って、均熱温度は、660~760℃の温度で行うこととする。好ましくは、680~730℃の温度で行う。
前記均熱後、10℃/s以上の平均冷却速度で450℃以下の温度域まで冷却する。平均冷却速度が10℃/s未満となると、冷却中に炭化物析出が促進されて、鋼板強度に寄与する固溶C量が低減し、降伏強度が低下するとともに、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となって耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合に、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。なお、平均冷却速度が50℃/s超となると上記の効果が飽和するため、平均冷却速度は50℃/s以下とすることが好ましい。
また、均熱後の前段冷却における冷却停止温度が450℃超となると、前段冷却後に炭化物析出が促進されて、鋼板強度に寄与する固溶C量が低減し、降伏強度が低下するとともに、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となって耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。なお、均熱後の前段冷却における冷却停止温度が300℃未満となると、炭化物析出抑制効果が飽和するばかりか、二次冷間圧延後の鋼板の圧延方向の時効指数が55MPa超となり、鋼板強度が過剰に上昇するため、例えば王冠用に供した場合に王冠の形状が不均一となり、多数の王冠を成形して耐圧試験に供すると耐圧強度の低い王冠が散見されることになり、王冠を製造する際の歩留りが低下する。さらに、鋼板を例えばDRD缶用に供した場合、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。さらにまた、通板する際の鋼板形状が劣化してトラブルが発生する、虞れがあるため、均熱後の冷却停止温度は300℃以上とすることが好ましい。
前段冷却後の後段冷却では、5℃/s以上の平均冷却速度で前段冷却時の冷却停止温度から140℃以下の温度域まで冷却する。平均冷却速度が5℃/s未満となると、鋼板強度に寄与する固溶C量が低減し降伏強度が低下するとともに、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となって耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。なお、平均冷却速度が30℃/s超となると、効果が飽和するばかりか、冷却設備に過剰なコストが発生するため後段冷却での平均冷却速度は30℃/s以下が好ましい。より好ましくは25℃/s以下である。
後段冷却では140℃以下まで冷却する。140℃超となると、鋼板強度に寄与する固溶C量が低減し、降伏強度が低下するとともに、二次冷間圧延後の鋼板の圧延方向の時効指数が25MPa未満となって耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。なお、冷却停止温度が100℃未満となると効果が飽和するばかりか、冷却設備に過剰なコストが発生するため100℃以上が好ましい。より好ましくは120℃以上である。
本発明の鋼板は、焼鈍後の二回目の冷間圧延により高い降伏強度を得ることができる。すなわち、二次冷間圧延の圧下率が10%未満であると、十分な降伏強度が得られず、例えば王冠用に供した場合の耐圧強度が低下する。また、二次冷間圧延の圧下率が40%を超えると、異方性が過大となり、例えば王冠用に供した場合の耐圧強度が低下する。さらに、鋼板を例えばDRD缶用に供した場合、DRD缶成形時にフランジ部にしわが発生する形状不良をまねく。よって、二次冷間圧延の圧下率は10%以上40%以下とすることが好ましい。より好ましくは、二次冷間圧延の圧下率は15%超35%以下である。
また、本発明の王冠は、上述した鋼板を用いて成形されるものである。王冠は、主に瓶の口を塞ぐ円盤状の部分と、その周囲に設けられた襞状の部分とから構成される。本発明の王冠は、本発明の鋼板を円形のブランクに打ち抜いた後、プレス成形により成形することができる。本発明の王冠は、十分な降伏強度を有し、かつ、材質均一性に優れた鋼板から製造されるので、薄肉化しても王冠としての耐圧強度に優れており、かつ王冠の外径および高さの均一が優れているため、王冠製造工程での歩留りが向上し、王冠製造に伴う廃棄物の排出量を減らす効果を有する。
なお、この塗装焼付け相当の熱処理は、該熱処理前の鋼板材質に何ら影響を与えるものではない。
ここで、耐圧試験は、王冠の内側に塩化ビニル製ライナーを成形し、市販ビール瓶に打栓してSecure Pak社製Secure Seal Testerを用いて王冠が外れる内圧を測定し、王冠が外れた内圧を耐圧強度とした。各50個の王冠に耐圧試験を実施して、耐圧強度が165psi以上である王冠の数が47個以上の場合を◎、耐圧強度が165psi以上である王冠の数が45個または46個の場合を○、耐圧強度が165psi以上である王冠の数が45未満の場合を×と評価した。得られた結果を表2に示す。
Claims (5)
- 質量%で、
C:0.0060%超0.0100%以下、
Si:0.05%以下、
Mn:0.05%以上0.60%以下、
P:0.050%以下、
S:0.050%以下、
Al:0.020%以上0.050%以下、
N:0.0140%超0.0180%以下および
Cr:0.040%以下
を含有し、残部はFeおよび不可避的不純物の成分組成を有し、
圧延方向の時効指数が25~55MPaであり、
降伏強度が620~700MPaである鋼板。 - 板厚が0.20mm以下である請求項1に記載の鋼板。
- 請求項1または2に記載の鋼板からなる王冠。
- 請求項1または2に記載の鋼板からなるDRD缶。
- 請求項1または2に記載の鋼板の製造方法であり、
鋼素材を1200℃以上で加熱し、仕上げ圧延温度:870℃以上および最終スタンドの圧下率:10%以上の条件にて圧延を施して550~750℃の温度範囲内で巻取る熱間圧延工程と、
前記熱間圧延後の熱延板に酸洗を行う酸洗工程と、
前記酸洗後の熱延板に、圧下率:88%以上の冷間圧延を行う一次冷間圧延工程と、
前記前記一次冷間圧延後の冷延板を、660~760℃の温度域に60秒以下で保持したのち、10℃/s以上の平均冷却速度で450℃以下300℃以上の温度域まで冷却し、次いで5℃/s以上30℃/s以下の平均冷却速度で140℃以下の温度域まで冷却する焼鈍工程と、
前記焼鈍板に、10%以上40%以下の圧下率で冷間圧延を行う二次冷間圧延工程と、を有する鋼板の製造方法。
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