Classifications

• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
  • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
  • G02B1/11—Anti-reflection coatings
• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
  • C03C17/001—General methods for coating; Devices therefor
  • C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C3/00—Glass compositions
  • C03C3/04—Glass compositions containing silica
  • C03C3/06—Glass compositions containing silica with more than 90% silica by weight, e.g. quartz
• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C2201/00—Glass compositions
  • C03C2201/06—Doped silica-based glasses
  • C03C2201/30—Doped silica-based glasses containing metals
  • C03C2201/40—Doped silica-based glasses containing metals containing transition metals other than rare earth metals, e.g. Zr, Nb, Ta or Zn
  • C03C2201/42—Doped silica-based glasses containing metals containing transition metals other than rare earth metals, e.g. Zr, Nb, Ta or Zn containing titanium
• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C2217/00—Coatings on glass
  • C03C2217/70—Properties of coatings
  • C03C2217/73—Anti-reflective coatings with specific characteristics
• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C2217/00—Coatings on glass
  • C03C2217/70—Properties of coatings
  • C03C2217/73—Anti-reflective coatings with specific characteristics
  • C03C2217/732—Anti-reflective coatings with specific characteristics made of a single layer

Definitions

• the present specification generally relates to high aspect ratio glass wafers and, more specifically to high aspect ratio glass wafers having a large diameter, small edge exclusion, low bow, low warp, and low total thickness variation (TTV).
• TTV total thickness variation
• the number of reflections can be high, such as, for example, 10 reflections or more and, therefore, any inconsistencies in flatness are compounded tenfold. Further to the requirements that the glass substrates have high degrees of flatness, the substrates must be exceedingly thin to meet the production tolerances of the devices being produced.
• a glass wafer has a first major surface, a second major surface that is parallel to and opposite of the first major surface, a thickness between the first major surface and the second major surface.
• the glass wafer has a diameter from greater than or equal to 175 mm to less than or equal to 325 mm and a thickness of less than 0.350 mm.
• a width of the edge portion is less than 10 mm.
• the glass wafer further comprises an annular edge portion that extends from an outermost diameter of the glass wafer toward the geometrical center of the glass wafer.
• a width of the edge portion is less than 10 mm. In some embodiments width of the edge portion is 0 to 10 mm. In some embodiments width of the edge portion is 0.2 mm to 10 mm.
• an optical, electrical, or mechanical device in another embodiment, includes a glass wafer has a first major surface, a second major surface that is parallel to and opposite of the first major surface, a thickness between the first major surface and the second major surface, and an annular edge portion that extends from an outermost diameter of the glass wafer toward the geometrical center of the glass wafer.
• the glass wafer has a diameter from greater than or equal to 175 mm to less than or equal to 325 mm and a thickness of less than 0.350 mm.
• a width of the edge portion is less than 10 mm.
• a glass wafer in yet another embodiment, includes a first major surface, a second major surface that is parallel to and opposite of the first major surface, a thickness between the first major surface and the second major surface, and an annular edge portion that extends from an outermost diameter of the glass wafer toward a geometrical center of the glass wafer.
• a diameter of the glass wafer is from greater than or equal to 200 mm to less than or equal to 325 mm and a thickness of the glass wafer is from greater than or equal to 0.225 mm to less than or equal to 0.325 mm.
• a width of the edge portion is less than 5 mm.
• TTV total thickness variation
• FIGS. 1A and IB schematically depict side views of a glass wafer according to embodiments disclosed and described herein;
• FIG. 2 schematically depicts a plan view of a glass wafer according to embodiments disclosed and described herein;
• FIG. 3 schematically depicts a coated glass wafer according to embodiments disclosed an described herein.
• FIG. 4 schematically depicts a coated glass wafer having a layered coating structure according to embodiments disclosed and described herein.
• a glass wafer has a first major surface, a second major surface that is parallel to and opposite of the first major surface, a thickness between the first major surface and the second major surface, and an annular edge portion that extends from an outermost diameter of the glass wafer toward the geometrical center of the glass wafer.
• the glass wafer has a diameter from greater than or equal to 175 mm to less than or equal to 325 mm and a thickness of less than 0.350 mm.
• a width of the edge portion is less than 10 mm.
• glass wafers having a large diameter and small thickness from silica.
• limitations in forming and finishing glass wafers made from silica that have large diameters, small thickness, and good surface properties have heretofore prevented the formation of such glass wafers.
• glass wafers having a diameter of from about 100 mm to 150 mm and a thickness of about 0.5 mm or greater that also have good surface properties, such as low bow, low warp, and low TTV.
• the diameter of the glass wafers increases, and as the thickness of the glass wafer decreases, it becomes more and more difficult to achieve a glass wafer that has good surface properties without fracturing the glass wafer during finishing.
• a "glass wafer” refers to wafers that comprise from 40 wt% to 100 wt% S1O2 on an oxide basis.
• the term "silica glass wafers” refers to glass wafers that comprise from 90 wt% to 100 wt% S1O2 on an oxide basis. Accordingly, as used herein, the term “glass wafer” includes the subclass of "silica glass wafers.”
• the edge of the glass wafer can no longer be processed using conventional techniques, such as, for example computer numeric control (CNC) machining. Therefore, the edge of the glass wafer may be chamfered, which can lead to damage.
• CNC computer numeric control
• a carrier for the glass wafer during processing generally has an annular shape and is made from plastic so that it does not scratch or chip the glass wafer.
• the carrier also generally will only contact the glass wafer at an edge portion so that the majority of the surface of the glass wafer may be polished. Accordingly, when polishing a glass wafer having a large diameter under such conditions, a large amount of pressure is exerted on the both the glass wafer and the carrier, which can cause damage to the glass wafer or cause the plastic carrier to break— thereby causing damage to the glass wafer.
• the survivability of glass wafers having large diameters and small thickness is difficult.
• FIG. 1 An exemplary glass wafer 100, such as, for example, a silica glass wafer, according to embodiments described herein is depicted in FIG. 1.
• the glass wafer 100 is formed primarily from silica, such as comprising from greater than or equal to 40 wt% to less than or equal to 100 wt% Si0 2 on an oxide basis.
• the glass wafer 100 is a silica glass wafer comprising from greater than or equal to 90 wt% to less than or equal to 100 wt% Si0 2 .
• a silica glass wafer is a subclass of a glass wafer.
• the silica glass wafer comprises less than about 1000 parts per billion (ppb) by weight metal contaminants, such as less than 900 ppb metal contaminants, or even less than 800 ppb metal contaminants. In one or more embodiments, the silica glass wafer comprises less than about 100 parts per billion (ppb) by weight metal contaminants, such as less than 50 ppb metal contaminants, or even less than 20 ppb metal contaminants. In some embodiments, the silica glass wafer comprises less than 1000 parts per million (ppm) by weight OH groups, such as less than 900 ppm OH groups, or even less than 800 ppm OH groups.
• the silica glass wafer comprises less than 100 parts per million (ppm) by weight OH groups, such as less than 50 ppm OH groups, less than 20 ppm OH groups, less than 10 ppm OH groups, or less than 5 ppm OH groups. In embodiments, the silica glass wafer comprises less than 100 ppm by weight OD groups, such as less than 50 ppm OD groups, less than 20 ppm OD groups, less than 10 ppm OD groups, or less than 5 ppm OD groups.
• ppm parts per million
• the glass wafer such as, for example, a silica glass wafer, may comprise T1O2 to control the coefficient of thermal expansion (CTE) of the glass wafer and to increase the transmission of the glass wafer.
• T1O2 is not considered a metal contaminant as described in the preceding paragraph.
• a glass wafer may comprise from greater than or equal to 0 wt% to less than or equal to 20 wt% T1O2, such as from greater than or equal to 5 wt% to less than or equal to 15 wt% Ti0 2 , or from greater than or equal to 7 wt% to less than or equal to 7.5 wt% Ti0 2 .
• a silica glass wafer comprises from greater than or equal to 0 wt% T1O2 to less than or equal to 10 wt% T1O2, such as, for example, from greater than or equal to 7 wt% Ti0 2 to less than or equal to 7.5 wt% Ti0 2 .
• the above components may be characterized by ICP-MS and FTIR techniques, respectively as described in U.S. Patent No. 7,928,026 and U. S. Patent No. 8,062,986, both of which are incorporated herein by reference in their entirety.
• the glass wafer 100 such as, for example, a silica glass wafer, may have a refractive index of from greater than or equal to 1.45 to less than or equal to 1.90.
• the refractive index of a material describes the speed at which light propagates through the material. It is defined by the following equation (1):
• n - C Eq. (1)
• n the refractive index of a given material
• c the speed of light in a vacuum
• v the phase velocity of light in the given material.
• the "refractive index” is based on light with a wavelength of 589 nm.
• the glass wafer 100 has a refractive index from greater than or equal to 1.50 to less than or equal to 1.90, such as from greater than or equal to 1.55 to less than or equal to 1.90, from greater than or equal to 1.60 to less than or equal to 1.90, from greater than or equal to 1.65 to less than or equal to 1.90, from greater than or equal to 1.70 to less than or equal to 1.90, from greater than or equal to 1.65 to less than or equal to 1.80, from greater than or equal to 1.65 to less than or equal to 1.75, from greater than or equal to 1.75 to less than or equal to 1.90, from greater than or equal to 1.80 to less than or equal to 1.90, or from greater than or equal to 1.85 to less than or equal to 1.90.
• refractive index from greater than or equal to 1.50 to less than or equal to 1.90, such as from greater than or equal to 1.55 to less than or equal to 1.90, from greater than or equal to 1.60 to less than or equal to 1.90, from greater than or equal to 1.65 to less
• the glass wafer 100 has a refractive index from greater than or equal to 1.45 to less than or equal to 1.85, from greater than or equal to 1.45 to less than or equal to 1.80, from greater than or equal to 1.45 to less than or equal to 1.75, from greater than or equal to 1.45 to less than or equal to 1.70, from greater than or equal to 1.45 to less than or equal to 1.65, from greater than or equal to 1.45 to less than or equal to 1.60, from greater than or equal to 1.45 to less than or equal to 1.55, or from greater than or equal to 1.45 to less than or equal to 1.50.
• the glass wafer has a refractive index from greater than or equal to 1.50 to less than or equal to 1.85, such as from greater than or equal to 1.55 to less than or equal to 1.80, from greater than or equal to 1.60 to less than or equal to 1.75, or from greater than or equal to 1.65 to less than or equal to 1.70.
• the glass wafer 100 such as, for example, a silica glass wafer, has a first major surface 110 and a second major surface 120 that is substantially parallel to, and opposite of, the first major surface 110. Exposed at the outermost diameter (i.e., along the circumference) of the glass wafer 100 is a sidewall 140 positioned between, and in contact with, the first major surface 110 and the second major surface 120. Together, the first major surface 110 and the second major surface 120 define a thickness, t, of the glass wafer 100. As used herein, the thickness t of the glass wafer 100 refers to the average distance between the first major surface 110 and the second major surface 120 as measured generally perpendicular to the first major surface 110 and the second major surface 120.
• FIGS. 1A and IB are an exemplary schematic views that are used to describe various elements of glass wafers 100 according to embodiments and are not drawn to scale.
• the thickness t of the glass wafer 100 depicted in FIGS. 1 A and IB is not drawn to scale and is thinner than depicted in FIGS 1 A and IB.
• the glass wafer 100 such as, for example, a silica glass wafer, has a diameter d that extends in a straight line from a first position 131 on an edge portion 130 of the glass wafer through the geometrical center of the glass wafer 100 to a second position 132 on the edge portion 130 of the glass wafer.
• the diameter d of the glass wafer 100 is substantially constant regardless of the location of the first position 131 and the second position 132 along the circumference of the glass wafer 100.
• minor variances in the diameter d may occur as a result of inconsistencies in the manufacturing process.
• the diameter d refers to the average diameter d of the glass wafer 100.
• the diameter d of the glass wafer 100 includes an annular edge portion 130 that extends from an exposed edge surface of the glass wafer 100 toward the geometrical center of the glass wafer 100.
• the glass wafer 100 such as, for example, a silica glass wafer, has a diameter d that extends in a straight line from a first point 131 on the edge of the glass wafer through the geometrical center of the glass wafer 100 to a second point 132 on the edge of the glass wafer.
• the glass wafers 100 are formed to have a relatively large diameter when compared to glass wafers conventionally described in the art. These large diameters allow the silica glass wafers to be used in multiple applications that may require larger diameter wafers, as well as provide for efficient formation of silica in a large wafer that can be divided in the sizes that are desired.
• the diameter d of the glass wafer 100 is from greater than or equal to 175 mm to less than or equal to 325 mm, such as from greater than or equal to 185 mm to less than or equal to 325 mm, greater than or equal to 195 mm to less than or equal to 325 mm, greater than or equal to 205 mm to less than or equal to 325 mm, greater than or equal to 215 mm to less than or equal to 325 mm, greater than or equal to 225 mm to less than or equal to 325 mm, greater than or equal to 235 mm to less than or equal to 325 mm, greater than or equal to 245 mm to less than or equal to 325 mm, greater than or equal to 250 mm to less than or equal to 325 mm, greater than or equal to 260 mm to less than or equal to 325 mm, greater than or equal to 270 mm to less than or equal to 325 mm
• the diameter d of the glass wafer 100 is from greater than or equal to 175 mm to less than or equal to 315 mm, such as from greater than or equal to 175 mm to less than or equal to 300 mm, from greater than or equal to 175 mm to less than or equal to 290 mm, from greater than or equal to 175 mm to less than or equal to 280 mm, from greater than or equal to 175 mm to less than or equal to 270 mm, from greater than or equal to 175 mm to less than or equal to 260 mm, from greater than or equal to 175 mm to less than or equal to 250 mm, from greater than or equal to 175 mm to less than or equal to 240 mm, from greater than or equal to 175 mm to less than or equal to 230 mm, from greater than or equal to 175 mm to less than or equal to 220 mm, from greater than or equal to 175 mm to less than or equal to 210 mm, or from greater than or equal to 1
• the diameter d of the glass wafer 100 is from greater than or equal to 200 mm to less than or equal to 300 mm, such as from greater than or equal to 210 mm to less than or equal to 290 mm, from greater than or equal to 220 mm to less than or equal to 280 mm, from greater than or equal to 230 mm to less than or equal to 270 mm, from greater than or equal to 240 mm to less than or equal to 260 mm, or from greater than or equal to 245 mm to less than or equal to 255 mm. It should be understood that the above ranges include all ranges and subranges between the ranges explicitly recited.
• the diameter d of the glass wafers 100 is substantially constant when measured at any point along the circumference of the glass wafer
• the variance in diameter is provided as an absolute value in comparison to the average diameter of the glass wafer.
• the glass wafer may have diameters from 249.8 mm to 250.2 mm.
• the variance in diameter d across the circumference of the glass wafer is ⁇ 0.20 mm or less, such as ⁇ 0.15 mm or less, or ⁇ 0.10 mm or less.
• the glass wafer 100 such as, for example, a silica glass wafer
• the glass wafers 100 will have a large surface area— as defined by the diameter d of the glass wafer— and a relatively small thickness t defined by the distance between the first major surface 110 and the second major surface 120.
• the ratio of the diameter d of the glass wafer 100 compared to the thickness t of the glass wafer may be expressed by the aspect ratio of the glass wafer 100.
• the aspect ratio of the glass wafer 100 is defined as the ratio of the diameter d of the glass wafer to the thickness t of the glass wafer.
• the aspect ratio is expressed herein as two numbers separated by a colon (e.g. 150: 1).
• the numbers in the aspect ratio do not necessarily represent the actual value of the diameter d of the glass wafer 100 or the thickness of the glass wafer 100. Rather, they represent the relationship between the diameter d of the glass wafer 100 and the thickness of the glass wafer 100.
• a glass wafer 100 with a diameter d of 300 mm and a thickness t of 0.2 mm would have an aspect ratio expressed as 1500: 1.
• the aspect ratio may be from greater than or equal to 475:1 to less than or equal to 700:1, such as from greater than or equal to 500:1 to less than or equal to 700:1, from greater than or equal to 525:1 to less than or equal to 700:1, from greater than or equal to 550:1 to less than or equal to 700:1, from greater than or equal to 575:1 to less than or equal to 700:1, from greater than or equal to 600:1 to less than or equal to 700:1, from greater than or equal to 625:1 to less than or equal to 700:1, from greater than or equal to 650:1 to less than or equal to 700:1, or from greater than or equal to 675:1 to less than or equal to 700:1.
• the aspect ratio may be from greater than or equal to 475:1 to less than or equal to 675:1, from greater than or equal to 475:1 to less than or equal to 650:1, from greater than or equal to 475:1 to less than or equal to 625:1, from greater than or equal to 475:1 to less than or equal to 600:1, from greater than or equal to 475:1 to less than or equal to 575:1, from greater than or equal to 475:1 to less than or equal to 550:1, from greater than or equal to 475:1 to less than or equal to 525:1, or from greater than or equal to 475:1 to less than or equal to 500:1.
• the aspect ratio may be from greater than or equal to 500:1 to less than or equal to 675:1, from greater than or equal to 525:1 to less than or equal to 650:1, from greater than or equal to 550:1 to less than or equal to 625:1, or from greater than or equal to 575:1 to less than or equal to 600:1. It should be understood that the above ranges include all ranges and subranges between the ranges explicitly recited.
• the glass wafers 100 such as, for example, a silica glass wafers, according to embodiments have a relatively large diameter d and a relatively small thickness t, which may be expressed in the aspect ratio of the glass wafer 100 disclosed above.
• the thickness t of the glass wafer is, according to embodiments, less than 0.350 mm, such as less than 0.325 mm, less than 0.300 mm, less than 0.275 mm, less than 0.250 mm, or less than 0.225 mm.
• the thickness t of the glass wafer 100 may be from greater than or equal to 0.225 mm to less than or equal to 0.325 mm, such as from greater than or equal to 0.235 mm to less than or equal to 0.325 mm, from greater than or equal to 0.245 mm to less than or equal to 0.325 mm, from greater than or equal to 0.255 mm to less than or equal to 0.325 mm, from greater than or equal to 0.265 mm to less than or equal to 0.325 mm, from greater than or equal to 0.275 mm to less than or equal to 0.325 mm, from greater than or equal to 0.285 mm to less than or equal to 0.325 mm, from greater than or equal to 0.295 mm to less than or equal to 0.325 mm, from greater than or equal to 0.305 mm to less than or equal to 0.325 mm, or from greater than or equal to 0.315 mm to less than or equal to 0.325 mm.
• the thickness t of the glass wafer 100 may be from greater than or equal to 0.225 mm to less than or equal to 0.315 mm, from greater than or equal to 0.225 mm to less than or equal to 0.295 mm, from greater than or equal to 0.225 mm to less than or equal to 0.285 mm, from greater than or equal to 0.225 mm to less than or equal to 0.275 mm, from greater than or equal to 0.225 mm to less than or equal to 0.265 mm, from greater than or equal to 0.225 mm to less than or equal to 0.255 mm, from greater than or equal to 0.225 mm to less than or equal to 0.245 mm, or from greater than or equal to 0.225 mm to less than or equal to 0.235 mm.
• the thickness t of the glass wafer 100 may be from greater than or equal to 0.235 mm to less than or equal to 0.315 mm, from greater than or equal to 0.245 mm to less than or equal to 0.305 mm, from greater than or equal to 0.255 mm to less than or equal to 0.295 mm, or from greater than or equal to 0.265 mm to less than or equal to 0.285 mm. It should be understood that the above ranges include all ranges and subranges between the ranges explicitly recited.
• the quality of the first major surface 110 and the second major surface 120 is controlled for certain applications.
• the quality of the first major surface 110 and the second major surface 120 of the glass wafer can be quantified by measuring the TTV, bow, and warp of the glass wafer 100. It should be understood that each of these measurements are independent and various embodiments may have any combination of values of TTV, bow, and warp disclosed below.
• the TTV of the glass wafer 100 is measured as defined in ASTM F657. Namely, the TTV is the difference between the maximum and minimum values of thickness encountered during a scan pattern or series of point measurements of first major surface 110 and the second major surface 120 of the glass wafer 100.
• the glass wafer 100 has a TTV of less than 5 ⁇ .
• the glass wafer 100 has a TTV of less than or equal to 4 ⁇ , such as less than or equal to 3 ⁇ , less than or equal to 2 ⁇ , or less than or equal to 1 ⁇ . It should be understood that the above ranges include all ranges and subranges between the ranges explicitly recited. If the TTV of the glass wafer is too high, the amount of distortion in the glass wafer will increase, particularly in applications where the light is reflected off of multiple surfaces in the glass wafer.
• the glass wafer 100 such as, for example, a silica glass wafer, may have a relatively small bow and/or warp.
• bow refers to the deviation of the center point of the median surface to a reference plane.
• warp refers to the difference between the maximum and minimum distances of the median surface from the reference plane.
• the glass wafer 100 such as, for example, a silica glass wafer, may have a bow of less than ⁇ 40 ⁇ .
• the glass wafer 100 may have a bow of less than or equal to ⁇ 35 ⁇ , such as less than or equal to ⁇ 30 ⁇ , less than or equal to ⁇ 25 ⁇ , less than or equal to ⁇ 20 ⁇ , less than or equal to ⁇ 15 ⁇ , or less than or equal to ⁇ 10 ⁇ . It should be understood that the above ranges include all ranges and subranges between the ranges explicitly recited.
• the amount of distortion in the glass wafer will increase, particularly in applications where the light is reflected off of multiple surfaces in the glass wafer and/or adjacent layers and is transmitted through total internal reflection as it passes transversely across a portion of the glass wafer.
• the glass wafer 100 such as, for example, a silica glass wafer, may have a warp of less than or equal to 45 ⁇ .
• the glass wafer 100 may have a warp less than or equal to 40 ⁇ , less than or equal to 35 ⁇ , less than or equal to 30 ⁇ , less than or equal to 25 ⁇ , less than or equal to 20 ⁇ , less than or equal to 15 ⁇ , or less than or equal to 10 ⁇
• the above ranges include all ranges and subranges between the ranges explicitly recited.
• the quality of the glass wafer, and particularly the quality of the first major surface 1 10 and the second major surface 120 may be quantified by measuring the optical wedge of at least one of the first major surface 1 10 and the second major surface 120.
• the optical wedge refers to an angle between two plane surfaces.
• the optical wedge may range from a few millionths of a degree to as much as three degrees.
• the optical wedge is measured in seconds of arc (arc- sec).
• the glass wafer 100 has an optical wedge of less than 0.030 arc-sec.
• the glass wafer 100 has an optical wedge of less than or equal to 0.025 arc-sec, such as less than or equal to 0.020 arc-sec, less than or equal to 0.015 arc-sec, or less than or equal to 0.010 arc-sec. It should be understood that the above ranges include all ranges and subranges between the ranges explicitly recited.
• first major surface 1 10 and the second major surface may be relatively smooth so as to not disrupt the optical properties of the glass wafer 100, such as, for example, a silica glass wafer.
• Rough surfaces increase light scattering and reflectivity in the visible light range.
• rough surfaces can decrease intensity and contrast when the glass wafer 100 is utilized in imaging systems.
• at least one of the first major surface 1 10 and the second major surface 120 may have a surface roughness (R a ) of less than or equal to 2 nm. Surface roughness (R a ) may be characterized by the following equation (4):
• At least one of the first major surface 110 and the second major surface 120 may have a surface roughness (R a ) of less than or equal to about 1.5 nm, less than or equal to about 1.0 nm, or less than or equal to 0.5 nm.
• the glass wafer 100 such as, for example, a silica glass wafer, comprises an annular edge portion 130 present at the outer circumference of the glass wafer 100.
• the edge portion surrounds the clear aperture of the glass wafer.
• the term "clear aperture” refers to a finished portion of the glass wafer of that has properties, such as, for example, optical properties, that meet one or more specified values.
• the term clear aperture diameter refers to an outer edge of the clear aperture portion of the glass wafer.
• the edge portion 130 will not have properties that meet one or more of the specified values.
• the specified values will be determined by the desired end use of the glass wafer and may be different in various embodiments.
• the specified values are generally selected from one or more of the surface roughness, the bow, the warp, and the TTV values described above as well as the haze, the stain, the wedge, and the scratch-dig values described herein.
• the edge portion 130 extends from the outermost diameter of the glass wafer 100 toward the geometrical center of the glass wafer 100 for a distance referred to herein as the width w of the edge portion 130.
• the width w of the edge portion 130 is substantially constant around the circumference of the glass wafer 100.
• the edge portion is a product of the finishing of the glass wafer 100.
• a ring holder is used to hold the glass wafer 100 when it undergoes finishing processes such as, for example, coating the glass wafer. It should be understood that the ring holder need not be present for every step of the finishing process.
• the ring holder is named as such because of its annular shape. Accordingly, the ring holder contacts the glass wafer 100 at or near the edge portion 130 and holds the glass wafer 100 while the coating processes are conducted. In case of coated glass wafers, this leads to an annular edge portion 130 that does not have the coating of the remainder ("clear aperture" portion of ) of the coated glass wafer 100.
• the edge portion 130 does not have the finish of the clear aperture, and may also have superficial damage, such as, for example, scratches, indentations, cracks, microcracks, etc.
• the clear aperture is a relatively pristine surface that is usable in many applications. Accordingly, it is desirable to keep the width w of the edge portion 130 as small as possible.
• the width w of the edge portion 130 is less than 10 mm, such as less than or equal to 9 mm, less than or equal to 8 mm, less than or equal to 7 mm, or less than or equal to 6 mm. In other embodiments, the width w of the edge portion 130 is less than or equal to 5 mm, such as less than or equal to 4 mm, or less than or equal to 3 mm (for example 0mm to 5 mm, 0.2 mm to 5 mm, 0mm to 3 mm, or 0.2 mm to 3 mm).
• the quality of the clear aperture is provided, in part, by various finishing processes, such as polishing, grinding, and other surface treatments.
• a ring holder is placed around the circumference of the glass wafer, such as, for example, a silica glass wafer, thereby contacting the sidewall 140 of the glass wafer 100, such as, for example, a silica glass wafer.
• the ring holder secures the glass wafer during various finishing processes, such as, for example, polishing.
• the finishing processes are not conducted on the entire surface of the glass wafer. For instance, in one or more embodiments and with reference to FIG. 2, the finishing processes are not conducted on the edge portion 130 of the glass wafer 100.
• At least a part of the edge portion 130 may comprise a chamfer where the surface of the glass wafer is angled from one or more of the major surfaces 110, 120 to the sidewall 140.
• the angle of the chamfer is not particularly limited, and in some embodiments may be an angle of 15° to about 75° measured from the plane of the adjacent major surface.
• This chamfered part of the edge portion results in a sidewall 140 that does not span the entire thickness t of the glass wafer 100.
• the sidewall 140 comprises from 50% to 70% of the wafer thickness t, such as from 55% to 65% of the wafer thickness t.
• the sidewall may be from 0.1 mm to 0.14 mm.
• the chamfered portion of the edge portion 130 is not included in the measurement of the bow, warp, and TTV.
• the chamfered part of the glass wafer is not on the same plane as the first major surface 110 or the second major surface 120, the chamfered part of the glass wafer will not receive the same finishing treatment as the first major surface 110 and the second major surface.
• the glass wafer 100 such as, for example, a silica glass wafer, is divided into an edge portion 130 and a clear aperture, and the edge portion 130 may have superficial damage.
• the clear aperture is a relatively pristine surface that is usable in many applications. Various properties of the clear aperture are described below.
• the clear aperture generally transmits light from the first major surface 110 or the second major surface 120 of the glass wafer 100, such as, for example, a silica glass wafer, through the glass wafer 100 and to the other of the first major surface 110 or second major surface 120.
• Haze occurs when the light is reflected from the surface of the glass wafer 100 that is exposed to the light, when light is refracted within the glass wafer 100, when light is reflected from the surface of the glass wafer 100 that is not exposed to the light, and when light passes through the glass wafer at an angle determined by the refractive index of the glass wafer 100, which is described above.
• the haze of the glass wafer may be measured according to ASTM D1003. According to embodiments, inside the clear aperture the glass wafer 100 has a haze of less than 1%. In other embodiments, the glass wafer 100 has a haze of 0%.
• glass wafers such as, for example, silica glass wafers
• the glass wafer has a stain of about 0.
• Another measurable property of the glass wafer such as, for example, a silica glass wafer, surface is the scratch-dig as described in MIL-O-13830.
• the scratch-dig sets a limit on the amount of area surface defects occupy relative to the overall clear aperture of the glass wafer.
• a scratch is defined as any marking or tearing of the wafer surface, and a dig is defined as a small rough spot in the glass wafer surface and includes bubbles and stains.
• the scratch-dig is represented by two numbers separated by a slash, such as 60/40.
• the first number defines a scratch width (in microns) according to a visual standard
• the second number refers to digs and establishes a limit to the actual size of the digs (in xlO microns).
• the scratch-dig of the glass wafer may be 40/20 or less, such as 20/10 or less.
• the annular an annular edge portion 130 may have scratch-dig of greater than 40/20.
• the glass wafers such as, for example, silica glass wafers, described hereinabove may have coatings.
• the coating may be an antireflective coating.
• a coated glass wafer 300 such as, for example, a silica glass wafer, comprises a glass wafer 100 having an anti reflective coating 310 on one of its major surfaces.
• the anti reflective coating 310 may comprise an air-side surface and may be in contact with a major surface of the glass wafer 100.
• the term "contact" can mean either direct contact or indirect contact. Direct contact refers to contact in the absence of intervening material and indirect contact refers to contact through one or more intervening materials.
• Elements in direct contact touch each other.
• Elements in indirect contact do not touch each other, but do touch an intervening material or series of intervening materials, where the intervening material or at least one of the series of intervening materials touches the other.
• Elements in contact may be rigidly or non-rigidly joined. Contacting refers to placing two elements in direct or indirect contact. Elements in direct contact may be said to directly contact each other. Elements in indirect contact may be said to indirectly contact each other. It should be understood that when two elements are "in contact” with one another, in some embodiments, they are in direct contact with one another. It should be understood that FIG. 3 is illustrative only and is not drawn to scale.
• an anti reflective coating 310 refers to a coating that has relatively low reflectance (i.e., high transmission) at one or more wavelengths.
• the coated glass wafer 300 may have a reflectance of less than or equal to about 0.2% over all wavelengths from 450 nm to 700 nm when viewed on a surface comprising an AR coating 120 at an angle of incidence of less than or equal to about 10°.
• Reflectance is a property of a surface that describes the relative amount of light reflected by the surface. Reflectance is defined as the intensity of light reflected divided by the intensity of the incident light and may be expressed as a percentage. Reflectance may vary for a given material based on the wavelength of incident light and the angle of incidence.
• Reflectance may be measured over a range of wavelengths of visible light (i.e. 450 nm to 700 nm). Unless otherwise mentioned, reflectance as referenced herein is measured at an angle of incidence less than or equal to about 10° (relative to normal to the surface of the reflective coating).
• the anti reflective coating 310 may comprise materials such as, without limitation, Si0 2 , A1 2 0 3 , Ge0 2 , SiO, A10 x N y , A1N, SiN x , SiO x N y , Si u Al v O x N y , Ta 2 0 5 , Nb 2 0 5 , Ti0 2 , Zr0 2 , TiN, MgO, MgF 2 , BaF 2 , CaF 2 , Sn0 2 , Hf0 2 , Y 2 0 3 , Mo0 3 , DyF 3 , YbF 3 , YbF x O y , YF 3 , CeF 3 , polymers, fluoropolymers, plasma-polymerized polymers, siloxane polymers, silsesquioxanes, polyimides, fluorinated polyimides, polyetherimide, polyethersulfone, polyphenylsulfone,
• the anti reflective coating 310 of one or more embodiments may comprise multiple layers.
• One of such embodiments is depicted in FIG. 4.
• the layers 311 , 312, and 313 of the anti reflective coating 310 may be in contact with a first major surface of the glass wafer 100, such as, for example, a silica glass wafer, and/or in contact with another layer.
• a first major surface of the glass wafer 100 such as, for example, a silica glass wafer
• another layer In one or more embodiments, only one layer is in contact with the major surface of the glass wafer 100.
• each layer is applied in such a manner that no layer is in contact with more than two other layers. It should be understood that FIG. 4 is illustrative only and is not drawn to scale.
• a UV filtering coating, an infrared absorbing coating, and the like may be applied to the glass wafer, such as, for example, a silica glass wafer,. Any suitable coating known now or later developed may be applied to the glass wafer depending on the desired use of the wafer.
• the glass wafer 100 such as, for example, a silica glass wafer, may be used in various devices, such as, but not limited to, virtual reality displays, circuitry, or integrated circuits, MEMS, LED, CIS, c-PV, memory, Logic ICs, RF/Analog ICs, microfluidic devices, microdisplays, Laser/VCSEL, fuel cells, microbatteries, power devices, optical and physical sensors, antennas, filters, spectrometers, measurement devices, microwave devices, cover glasses, protective covers, gratings, connectors, optical couplings, and the like.
• glass wafers 100 according to embodiments may be used in optical devices, such as in waveguides, as lenses, etc. Further, glass wafers according to embodiments may be used insulating materials and interposers.
• a glass wafer comprises: a first major surface; a second major surface that is parallel to and opposite of the first major surface; a thickness between the first major surface and the second major surface; and an annular edge portion that extends from an outermost diameter of the glass wafer toward a geometrical center of the glass wafer, wherein a diameter of the glass wafer is from greater than or equal to 175 mm to less than or equal to 325 mm, the thickness is less than 0.350 mm, and a width of the edge portion is less than 10 mm.
• a second clause includes the glass wafer of the first clause, wherein the diameter of the glass wafer is from greater than or equal to 200 mm to less than or equal to 300 mm.
• a third clause includes the glass wafer of any one of the first and second clauses, wherein the thickness is from greater than or equal to 0.225 mm to less than or equal to 0.325 mm.
• a fourth clause includes the glass wafer of any one of the first through third clauses, wherein the width of the edge portion is less than 5 mm.
• a fifth clause includes the glass wafer of any one of the first through fourth clauses, wherein an aspect ratio of the glass wafer is from greater than or equal to 475: 1 to less than or equal to 700: 1.
• a sixth clause includes the glass wafer of any one of the first through fifth clauses, wherein a variance in diameter d across a circumference of the glass wafer is ⁇ 0.20 mm or less.
• a seventh clause includes the glass wafer of any one of the first through sixth clauses, wherein the glass wafer has a total thickness variation (TTV) of less than 5 ⁇ .
• TTV total thickness variation
• An eighth clause includes the glass wafer of any one of the first through seventh clauses, wherein the glass wafer has a bow of less than or equal to ⁇ 35 ⁇ .
• a ninth clause includes the glass wafer of any one of the first through eighth clauses, wherein the glass wafer has a warp of less than or equal to 45 ⁇ .
• a tenth clause includes the glass wafer of any one of the first through ninth clauses, wherein the glass wafer has an optical wedge of less than 0.030 arc-sec.
• An eleventh clause includes the glass wafer of any one of the first through tenth clauses, wherein the glass wafer has a scratch-dig of 40/20 or less.
• a twelfth clause includes the glass wafer of any one of the first through eleventh clauses, wherein the glass wafer further comprises an anti-reflective coating.
• a thirteenth clause includes an optical, electrical, or mechanical device comprising the glass wafer of any one of first through twelfth clauses.
• a fourteenth clause includes a glass wafer comprising: a first major surface; a second major surface that is parallel to and opposite of the first major surface; a thickness between the first major surface and the second major surface; and an annular edge portion that extends from an outermost diameter of the glass wafer toward a geometrical center of the glass wafer, wherein a diameter of the glass wafer is from greater than or equal to 200 mm to less than or equal to 325 mm, the thickness is from greater than or equal to 0.225 mm to less than or equal to 0.325 mm, a width of the edge portion is less than 5 mm, a total thickness variation (TTV) of the glass wafer is less than 1 ⁇ , a bow of the glass wafer is less than or equal to ⁇ 15 ⁇ , and a warp of the glass wafer is less than or equal to 30 ⁇
• TTV total thickness variation
• a fifteenth clause includes the glass wafer of the fourteenth clause, wherein the glass wafer has a refractive index from greater than or equal to 1.45 to less than or equal to 1.90.
• a sixteenth clause includes the glass wafer of any one of the fourteenth and fifteenth clauses, wherein the glass wafer has a surface roughness (Ra) of less than or equal to 2 nm.
• a seventeenth clause includes the glass wafer of any one of the fourteenth through fifteenth clauses, wherein the glass wafer has a scratch-dig of 20/10 or less.
• An eighteenth clause includes the glass wafer of any one of the fourteenth through seventeenth clauses, wherein the glass wafer has an optical wedge of less than 0.030 arc-sec.
• a nineteenth clause includes the glass wafer of any one of the fourteenth through eighteenth clauses, wherein a variance in diameter d across a circumference of the glass wafer is ⁇ 0.20 mm or less.
• a twentieth clause includes the glass wafer of any one of the fourteenth through nineteenth clauses, wherein the glass wafer further comprises an anti-reflective coating.

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• 2018
  • 2018-02-22 TW TW107105940A patent/TWI771375B/zh active
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