WO2018139390A1 - Composition de détergeant liquide - Google Patents

Composition de détergeant liquide Download PDF

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Publication number
WO2018139390A1
WO2018139390A1 PCT/JP2018/001712 JP2018001712W WO2018139390A1 WO 2018139390 A1 WO2018139390 A1 WO 2018139390A1 JP 2018001712 W JP2018001712 W JP 2018001712W WO 2018139390 A1 WO2018139390 A1 WO 2018139390A1
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Prior art keywords
component
content
mass
less
detergent composition
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PCT/JP2018/001712
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English (en)
Japanese (ja)
Inventor
誠二 矢野
侃 季
裕一 窪田
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花王株式会社
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Publication of WO2018139390A1 publication Critical patent/WO2018139390A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the present invention relates to a liquid detergent composition, particularly a liquid detergent composition for textiles such as clothing.
  • Patent Document 1 JP 2012-12436A
  • Patent Document 2 US 8071521 B1
  • the nonionic surfactant (c) is contained as an essential component, the content of the component (c) is 0.3% by mass or more, the content of the component (c), and the content of the component (a)
  • the mass ratio (c) / (a) to the amount is 7 or less, and the mass ratio (c) / (b) between the content of the component (c) and the content of the component (b) is 10 or less.
  • the liquid detergent composition it was found that the cleaning ability against oil stains and foaming properties and rinsing properties were excellent, and in particular, excellent cleaning ability was obtained against cooking oil stains, and the present invention was completed. .
  • the present invention contains the following components (a) to (c), the content of the component (c) is 0.3% by mass or more, the content of the component (c), and the content of the component (a)
  • the mass ratio (c) / (a) to the amount is 7 or less, and the mass ratio (c) / (b) between the content of the component (c) and the content of the component (b) is 10 or less.
  • a liquid detergent composition is provided.
  • R 1 represents a straight-chain or branched saturated or unsaturated hydrocarbon group having 6 to 8 carbon atoms
  • R 2 represents an alkylene group having 1 to 3 carbon atoms
  • R 3 and R 4 are independent of each other.
  • An alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, or R 3 and R 4 are bonded to each other by a hetero atom, and each independently represents an alkylene group having 1 to 3 carbon atoms or a hydroxyalkylene group.
  • X represents a group selected from —COO—, —CONH—, and —O—, and m is a number of 0 or 1.
  • C Nonionic surfactant
  • a liquid detergent that has a high application cleaning ability against dirt, especially cooking oil dirt, is rich in foam when washing, quickly disappears when rinsing, and can be quickly and easily completed.
  • a composition can be provided. Further, the effect of the present invention can be obtained even when washing and rinsing with high hardness washing water.
  • the component (a) is an anionic surfactant having 12 to 18 carbon atoms excluding fatty acids.
  • component (a) examples include alkyl sulfate salts or alkenyl group sulfate salts (hereinafter referred to as (a-1)), ⁇ -olefin sulfonate salts (hereinafter referred to as (a-2)), alkane sulfones. Acid salt (hereinafter referred to as (a-3)), polyoxyethylene alkyl sulfate ester salt (hereinafter referred to as (a-4)), and alkylbenzene sulfonate (hereinafter referred to as (a-5)).
  • the component (a-1) is an alkyl sulfate having an alkyl group or an alkenyl group having 12 to 18 carbon atoms.
  • an ester salt or an alkenyl sulfate ester salt is an ⁇ -olefin sulfonate having an alkenyl group of 14 to 16 carbon atoms
  • the (a-3) component is an alkyl group having a carbon number of 12
  • the alkanesulfonic acid salt having 18 or less and the component (a-4) includes a polyoxyethylene alkylsulfuric acid ester salt having an alkyl group or an alkenyl group having 12 to 18 carbon atoms and an average added mole number of ethylene oxide of 1 to 3
  • (A-5) component includes alkylbennes having an alkyl group or an alkenyl group having 12 to 14 carbon atoms. Nsuruhon acid salts are preferred.
  • the component (a) includes, as the component (a-1), an alkyl sulfate salt or an alkenyl sulfate salt having an alkyl group or alkenyl group having 16 to 18 carbon atoms (hereinafter referred to as (a-1-3)). It is preferable to contain. Further, the component (a) preferably contains an alkyl sulfate ester salt having an alkyl group having 16 carbon atoms as the component (a-1).
  • the (a-1-3) of the present invention has both the ease of rinsing such that bubbles disappear quickly during rinsing and the ability to apply and clean oil stains.
  • the mass ratio of the content of the component to the content of the component (a) ((a-1-3) / (a)) is preferably 0.03 or more, more preferably 0.07 or more, and still more preferably 0.8. From the point which is 13 or more, More preferably 0.2 or more and is excellent in foaming property, Preferably it is 1 or less, More preferably, it is 0.43 or less, More preferably, it is 0.33 or less.
  • the (a-1) component (a) component is included because it is excellent in ease of rinsing such that the foam disappears quickly during rinsing, excellent in application cleaning ability against oil stains, and excellent in foaming properties.
  • the mass ratio to the amount ((a-1-3) / (a)) is preferably 0.03-1, more preferably 0.03-0.43, and still more preferably 0.03-0.33. More preferably, it is 0.07 to 0.33, more preferably 0.13 to 0.33, and still more preferably 0.2 to 0.33.
  • the component (a) may be one or more selected from the components (a-1) to (a-5). From the viewpoints of ease of rinsing such that bubbles disappear quickly during rinsing and improvement of coating and washing ability against oil stains, it is preferable to use the component (a-1), the component (a-3) or the component (a-4). However, from the standpoints of foaming properties, ease of rinsing such that the foam disappears quickly during rinsing, and application cleaning ability, the use of the component (a-1), the component (a-1), and (a-2) It is more preferable to use an appropriate combination of one or more selected from the component, the component (a-3), the component (a-4), and the component (a-5).
  • the components (a-1-3) and (a-1-3) are excluded. It is more preferable to use one or two or more types selected from the component (a). It is particularly preferable to use a combination of one or more selected from the component (a-1-3) and the component (a-1) excluding the component (a-1-3).
  • the content of the component (a-1) is the content of the component (a) from the viewpoint of ease of rinsing such that bubbles disappear quickly during rinsing.
  • the mass ratio ((a-1) / (a)) to 0.2 is 0.2 or more, more preferably 0.35 or more, still more preferably 0.45 or more, and still more preferably 0.55 or more.
  • anionic surfactant one or two or more kinds selected from alkali metal ions, alkaline earth metal ions, ammonium ions and alkanol ammonium ions from the point that foamability and coating washing ability are more excellent.
  • An ion more preferably one or more ions selected from alkali metal ions.
  • Alkali metal ions are preferably one or two ions selected from sodium ions and potassium ions, and more preferably sodium ions, from the viewpoint of more excellent foamability and coating cleaning ability.
  • Specific examples of the component (a-1) include sodium dodecyl sulfate, sodium tetradecyl sulfate, sodium hexadecyl sulfate, sodium octadecyl sulfate, and the component (a-1-3) includes sodium hexadecyl sulfate, sodium octadecyl sulfate, and the like. Is mentioned.
  • Specific examples of the component (a-2) include sodium ⁇ -olefin sulfonate having 14 to 16 carbon atoms.
  • Specific examples of the component (a-3) include sodium secondary alkyl sulfonate having 13 to 17 carbon atoms.
  • Specific examples of the component (a-5) include sodium dodecylbenzenesulfonate.
  • the content of the component (a) in the liquid detergent composition of the present invention is preferably 0.75% by mass or more from the viewpoint of foaming properties, ease of rinsing such that bubbles quickly disappear during rinsing, and application cleaning ability. More preferably 1% by mass or more, further preferably 2% by mass or more, further preferably 3% by mass or more, further preferably 5% by mass or more, preferably 25% by mass or less, more preferably 20% by mass or less. is there.
  • the content of the component (a) in the liquid detergent composition of the present invention is preferably 0.75 to 25% by mass, more preferably 1 to 20% by mass, and still more preferably 2 to 2%. It is 20% by mass, more preferably 5 to 20% by mass.
  • Component (b) is an amine oxide type surfactant having a hydrocarbon group having 6 to 8 carbon atoms.
  • the hydrocarbon group having 6 to 8 carbon atoms include an alkyl group or alkenyl group having 6 to 8 carbon atoms, and these may be linear or branched.
  • the component (b) is preferably an amine oxide type surfactant having a hydrocarbon group having 8 carbon atoms from the viewpoint that the ease of rinsing such that bubbles disappear quickly upon rinsing and the ability to apply and clean oil stains are better.
  • Examples of the amine oxide type surfactant of the present invention include compounds represented by the following general formula (1).
  • R 1 represents a straight-chain or branched saturated or unsaturated hydrocarbon group having 6 to 8 carbon atoms
  • R 2 represents an alkylene group having 1 to 3 carbon atoms
  • R 3 and R 4 are independent of each other.
  • An alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, or R 3 and R 4 are bonded to each other by a hetero atom, and each independently represents an alkylene group having 1 to 3 carbon atoms or a hydroxyalkylene group.
  • X represents a group selected from —COO—, —CONH—, and —O—, and m is a number of 0 or 1.
  • R 1 is preferably a linear or branched alkyl group or alkenyl group from the viewpoint that the ease of rinsing such that bubbles disappear quickly during rinsing and the ability to apply and clean oil stains are better. More preferably, it is a linear alkyl group or alkenyl group, more preferably a linear alkyl group, still more preferably a primary alkyl group.
  • the carbon number of R 1 is preferably 8 from the viewpoint that the ease of rinsing such that bubbles disappear quickly during rinsing and the ability to apply and clean oil stains are more excellent.
  • Preferred examples of the component (b) compound include those in the general formula (1) wherein R 1 is a straight-chain alkyl group having 6 to 8 carbon atoms, and R 3 and R 4 are all methyl groups or R 3 and R 4. Are bonded to each other by an oxygen atom and are all ethylene groups, and m is 0. Among them, hexyldimethylamine is more excellent in ease of rinsing such that bubbles disappear quickly during rinsing and coating washing ability.
  • One or two kinds selected from oxide and octyldimethylamine oxide are preferable, and octyldimethylamine oxide is more preferable.
  • a component may be used individually by 1 type, and may be used in combination of 2 or more types as appropriate. From the standpoint of ease of rinsing such that the foam quickly disappears during rinsing and coating and washing ability, those using an amine oxide type surfactant having an alkyl group having 6 to 8 carbon atoms alone, or those having 6 to 8 carbon atoms It is more preferable to use a combination of two or more amine oxide surfactants having an alkyl group.
  • the content of the component (b) in the liquid detergent composition of the present invention is preferably 0.3% by mass or more, more preferably from the viewpoint that the ease of rinsing such that bubbles disappear quickly during rinsing and the coating cleaning ability are more excellent.
  • it is more preferably 3% by mass or less.
  • the content of the component (b) in the liquid detergent composition of the present invention is preferably 0.3 to 6% by mass, more preferably 0.3 to 5% by mass, and still more preferably It is 0.5 to 5% by mass, more preferably 0.5 to 3% by mass, still more preferably 1 to 3% by mass, still more preferably 1.5 to 3% by mass, and still more preferably 2 to 3% by mass.
  • (a) + (b) is preferably 2% by mass or more, and more preferably from the viewpoint of the ability to apply and clean the cooking oil stains and foam. Is 3% by mass or more, more preferably 5% by mass or more, further preferably 7% by mass or more, preferably 30% by mass or less, more preferably 25% by mass or less, and further preferably 20% by mass or less.
  • (a) + (b) is preferably 2 to 30% by mass, more preferably 2 to 25% by mass, and still more preferably 3 to 25% by mass. %, More preferably 5 to 20% by mass, still more preferably 7 to 20% by mass.
  • the liquid detergent composition of the present invention contains (c) a nonionic surfactant.
  • a nonionic surfactant examples include polyoxyalkylene alkyl ether, polyoxyalkylene alkenyl ether, alkyl polyglucoside, alkyl glycoside, sucrose fatty acid ester, polyglycerin fatty acid ester, fatty acid monoethanolamide, fatty acid
  • diethanolamide polyoxyethylene hydrogenated castor oil
  • polyoxyethylene sorbitan fatty acid ester polyoxyethylene sorbite fatty acid ester
  • alkyl saccharide surfactant alkyl saccharide surfactant
  • polyoxyalkylene alkyl ether fatty acid monoethanolamide and fatty acid diethanolamide
  • polyoxyalkylene one or more selected from alkyl ethers and fatty acid monoethanolamides are more preferred.
  • Polyoxyethylene alkyl ether is more preferable in terms of excellent ease of rinsing.
  • the alkyl group of the polyoxyalkylene alkyl ether is preferably a straight chain from the viewpoint of cleaning ability against dirt such as cooking oil stains and product stability.
  • the alkylene group of the polyoxyalkylene alkyl ether is preferably one or two selected from an ethylene group and a propylene group, more preferably from the viewpoint of the cleaning ability against dirt such as cooking oil dirt and the stability of the product. Is an ethylene group.
  • the number of carbon atoms of the alkyl group of the polyoxyalkylene alkyl ether is preferably 8 or more, more preferably 10 or more, and still more preferably 12 or more, from the viewpoint of cleaning ability against dirt such as cooking oil stains and product stability. From the same viewpoint, it is preferably 18 or less, more preferably 16 or less, and still more preferably 14 or less.
  • the number of moles of oxyalkylene added to the polyoxyalkylene alkyl ether is preferably 1 or more, more preferably 5 or more, and even more preferably 10 or more, from the viewpoints of cleaning ability against dirt such as cooking oil stains and product stability. And from the same viewpoint, it is preferably 30 or less, more preferably 25 or less, and still more preferably 21 or less.
  • the fatty acid monoethanolamide is preferably one selected from fatty acids having a hydrocarbon group of 7 to 21 carbon atoms and amides of monoethanol, from the viewpoint of cleaning ability against dirt such as cooking oil stains and product stability. Or 2 or more types, More preferably, it is 1 type or 2 types chosen from coconut oil fatty acid monoethanolamide and palm kernel oil fatty acid monoethanolamide, More preferably, it is coconut oil fatty acid monoethanolamide.
  • the content of the nonionic surfactant as the component (c) of the present invention is preferably 16% by mass or less from the viewpoint that the ease of rinsing such that bubbles disappear quickly during rinsing and the ability to apply and clean cooking oil stains are better. More preferably, it is 15 mass% or less, More preferably, it is 10 mass% or less, More preferably, it is 9 mass% or less, More preferably, it is 6 mass% or less, More preferably, it is 4 mass% or less, More preferably, it is 1 mass% or less. .
  • the content of the nonionic surfactant as the component (c) of the present invention is preferably 0.3% by mass or more, more preferably 0.6% by mass, from the viewpoint of foaming properties during washing in the washing machine. % Or more.
  • the mass ratio (c) / (a) is preferably 7 or less, more preferably 4.4 or less, and still more preferably 2.3 or less.
  • the mass ratio (c) / (a) of the content of the nonionic surfactant as the component (c) of the present invention and the content of the component (a) ) Is preferably 0.02 or more, more preferably 0.04 or more.
  • the mass ratio (c) / (b) is preferably 10 or less, more preferably 6 or less, and still more preferably 2.7 or less.
  • the mass ratio (c) / (b) of the content of the nonionic surfactant as the component (c) of the present invention and the content of the component (b) ) Is preferably 0.1 or more, more preferably 0.2 or more.
  • the liquid detergent composition of the present invention may contain (d) a water-miscible organic solvent.
  • the component (d) may be a water-miscible solvent often used in any detergent composition, and a water-miscible organic solvent having one or two groups selected from a hydroxy group and an ether group. preferable.
  • the water-miscible organic solvent referred to in the present invention refers to an organic solvent that dissolves 50 g or more in 1 L of deionized water at 25 ° C., that is, an organic solvent that dissolves 50 g / L or more in water.
  • water-miscible organic solvent (d) examples include (1) alkanols, (2) alkylene glycols having 2 to 6 carbon atoms, such as ethylene glycol, propylene glycol, butylene glycol, and hexylene glycol, and glycerin (hereinafter referred to as glycerin).
  • Polyalkylene glycols composed of alkylene glycol units having 2 to 4 carbon atoms
  • poly ) Alkylene glycol (mono or di) alkyl ether hereinafter sometimes referred to as alkyl ethers
  • alkyl glyceryl ethers having alkyl having 1 to 8 carbon atoms
  • Aromatic ethers Aromatic
  • the component (d) from the viewpoint of achieving excellent solubility and product stability, preferably one or more substances selected from the groups (1) to (6) are used, and more preferably A solvent selected from the above (1) alkanols, (2) glycols, (4) alkyl ethers, and (6) aromatic ethers is used.
  • a solvent selected from the above (1) alkanols, (2) glycols, (4) alkyl ethers, and (6) aromatic ethers is used.
  • specific examples include one or two selected from propylene glycol and diethylene glycol monobutyl ether.
  • the liquid detergent composition of the present invention preferably has as little (d) water-miscible organic solvent content as possible.
  • the content of the component (d) is preferably 10% by mass or less, more preferably 9% by mass or less, still more preferably 7% by mass or less, and still more preferably. 5% by mass or less, more preferably 1% by mass or less, still more preferably 0.1% by mass or less, still more preferably 0.01% by mass or less, still more preferably 0% by mass, that is, it is more preferable.
  • the ratio of the content of the component (d) to the total content of the component (a) and the content of the component (b) is (d) / (( a) + (b)) is 0.5 or less, preferably 0.4 or less, more preferably 0.3 or less, still more preferably 0.1 or less, still more preferably 0.01 or less, still more preferably 0. is there.
  • the liquid detergent composition of the present invention can contain other components within a range that does not impair the purpose and effect of the present invention.
  • Other components include, for example, anionic surfactants other than the component (a) of the present invention, amphoteric surfactants other than the component (b) of the present invention, and chelating agents and foam increasing agents generally used for liquid detergent compositions. , Builders, rust inhibitors, viscosity modifiers, pH adjusters, antioxidants, antibacterial / antifungal agents, preservatives, and optional components such as colorants and fragrances.
  • anionic surfactant other than the component (a) of the present invention examples include alkyl sulfate esters having less than 12 carbon atoms such as sodium 2-ethylhexyl sulfate and sodium decyl sulfate.
  • amphoteric surfactant other than the component (b) of the present invention examples include alkylamine oxides having 9 or more carbon atoms such as dodecyldimethylamine oxide, tetradecyldimethylamine oxide, hexadecyldimethylamine oxide, and laurylimidazolinium.
  • Alkylimidazolinium-type betaines such as betaine, cocoylimidazolinium betaine, lauramide propyl betaine, amidopropyl betaines such as palm kernel fatty acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine, lauryl ethoxysulfobetaine, stearyl ethoxysulfobetaine Hydroxy such as alkyl sulfobetaine, coconut oil fatty acid hydroxy sulfobetaine, lauryl hydroxysulfobetaine, tetradecyl hydroxysulfobetaine Ruhobetain, bis lauryl dimethyl carboxyl betaine, alkyl carboxyl betaine such as stearyl hexyl methyl carboxyl betaine.
  • chelating agents include ethylenediaminetetraacetic acid and phosphonates.
  • foam increasing agent examples include fatty acid alkanolamides.
  • Examples of the builder include sodium tripolyphosphate, sodium silicate, sodium carbonate, sodium sulfate, sodium citrate, and sodium polyacrylate.
  • rust inhibitor examples include pentaerythritol ester and phytic acid ester.
  • viscosity modifier examples include hydroxyethyl cellulose, methyl cellulose, carboxyvinyl polymer, and the like.
  • pH adjuster examples include sodium hydroxide, potassium hydroxide, alkanolamine, sulfuric acid, hydrochloric acid, citric acid, lactic acid, tartaric acid, oxalic acid, malic acid and the like.
  • antioxidants examples include butylhydroxytoluene, biphenylethylenated cresol, sodium sulfite and sodium bisulfite.
  • antibacterial and antifungal agents examples include silver ion antibacterial agents, zinc oxide, copper oxide, dihydroammonium phosphate, lithium carbonate, vanillin, and ethylene vanillin compounds.
  • preservative examples include methyl paraoxybenzoate, butyl paraben, and 1,2-benzothiazolin-3-one.
  • the remaining amount other than the above components (a) to (d) and optional components can be water.
  • the water is preferably water that does not affect the composition, such as deionized water.
  • the pH at 25 ° C. of the liquid detergent composition of the present invention is preferably 7 or less, more preferably 6 or less, from the viewpoint of the ability to apply and clean cooking oil stains and the ease of rinsing such that bubbles disappear quickly during rinsing. More preferably, it is 5 or less.
  • the pH of the liquid detergent composition of the present invention at 25 ° C. is preferably 1 or more, more preferably 3 or more, and further preferably 3.5 or more. The pH value can be adjusted by the above pH adjuster.
  • the content of the component (b) and the amphoteric interface other than the components (b) and (b) is preferably 0.2 or more, more preferably 0.4 or more, still more preferably 0.6 or more, and still more preferably 0, from the viewpoint of improving rinsing properties during rinsing. .8 or more, preferably less than 1.
  • the total content of surfactants other than fatty acids is 2 to 40% by mass, preferably 5 to 32.5% by mass, and more preferably 7 to 25% by mass.
  • surfactant other than fatty acid refers to all surfactants other than fatty acid contained in the liquid detergent composition of the present invention.
  • the liquid detergent composition of this invention is manufactured by mixing each component suitably.
  • the liquid detergent composition for clothing of the present invention is suitable for household laundry, more preferably suitable for hand-washing laundry, and can be applied to textiles such as clothing, bedding, and fabrics, and preferably clothing cleaning. Used as an agent.
  • composition [1] The following components (a) to (c) are contained, the content of the component (c) is 0.3% by mass or more, the content of the component (c) and the content of the component (a) The mass ratio (c) / (a) of the liquid detergent is 7 or less, and the mass ratio (c) / (b) of the content of the component (c) and the content of the component (b) is 10 or less.
  • Composition (A) an anionic surfactant having 12 to 18 carbon atoms excluding fatty acid
  • R 1 represents a straight-chain or branched saturated or unsaturated hydrocarbon group having 6 to 8 carbon atoms
  • R 2 represents an alkylene group having 1 to 3 carbon atoms
  • R 3 and R 4 are independent of each other.
  • An alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, or R 3 and R 4 are bonded to each other by a hetero atom, and each independently represents an alkylene group having 1 to 3 carbon atoms or a hydroxyalkylene group.
  • X represents a group selected from —COO—, —CONH—, and —O—, and m is a number of 0 or 1.
  • C Nonionic surfactant
  • component (a) is component (a-1), ⁇ -olefin sulfonate salt in component (a-2), alkane sulfonate salt in component (a-3), (a -4)
  • the component (a) preferably contains an alkyl sulfate or alkenyl sulfate salt having 16 to 18 carbon atoms in the alkyl group or alkenyl group as the component (a-1-3).
  • the mass ratio of the content of the component (a-1-3) to the content of the component (a) is preferably 0.03 or more, more preferably 0.07 or more, and further preferably 0.13 or more. More preferably, it is 0.2 or more, preferably 1 or less, more preferably 0.43 or less, still more preferably 0.33 or less, preferably 0.03 to 1, more preferably 0. 0.03 to 0.43, more preferably 0.03 to 0.33, more preferably 0.07 to 0.33, still more preferably 0.13 to 0.33, and still more preferably 0.2 to 0.33.
  • the liquid detergent composition according to the above [3].
  • the component (a) may be one or more selected from the components (a-1) to (a-5), the component (a-1), (a-3) It is preferable to use the component or the component (a-4), the use of the component (a-1), the component (a-1), the component (a-2), the component (a-3), ( It is more preferable to use one or more selected from the components a-4) and (a-5) in appropriate combinations, and the components (a-1-3) and (a-1-3) It is more preferable to use one or a combination of two or more selected from component (a) excluding component (a-1) and component (a-1) excluding component (a-1-3)
  • the liquid detergent composition according to any one of [1] to [4], wherein it is particularly preferable to use one or more selected from the above.
  • the mass ratio ((a-1) / (a)) of the content of the component (a-1) to the content of the component (a) is 0.2 or more, more preferably 0.35 or more.
  • the counter ion of the anionic surfactant is one or more ions selected from alkali metal ions, alkaline earth metal ions, ammonium ions and alkanol ammonium ions, more preferably alkali metal ions.
  • R 1 is preferably a linear or branched alkyl group or alkenyl group, more preferably a linear alkyl group or alkenyl group, still more preferably a linear alkyl group,
  • component (b) is preferably one or two selected from hexylmethylamine oxide and octyldimethylamine oxide, more preferably octyldimethylamine oxide.
  • a liquid detergent composition as described in 1. above.
  • the total content (a) + (b) of the component (a) and the component (b) is preferably 2% by mass or more, more preferably 3% by mass or more, still more preferably 5% by mass or more, and further preferably Is 7% by mass or more, preferably 30% by mass or less, more preferably 25% by mass or less, still more preferably 20% by mass or less, preferably 2 to 30% by mass, more preferably 2 to 25% by mass.
  • the liquid detergent composition according to any one of [1] to [11], more preferably 3 to 25% by mass, still more preferably 5 to 20% by mass, and still more preferably 7 to 20% by mass.
  • the nonionic surfactant (c) is preferably a polyoxyalkylene alkyl ether, a polyoxyalkylene alkenyl ether, an alkyl polyglucoside, an alkyl glycoside, a sucrose fatty acid ester, a polyglycerin fatty acid ester, a fatty acid monoethanolamide, One or more selected from fatty acid diethanolamide, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, and alkyl saccharide surfactant, more preferably polyoxyalkylene alkyl ether, fatty acid One or more selected from monoethanolamide and fatty acid diethanolamide, more preferably polyoxyalkylene alkyl ether, and fatty acid monoethanol It is one or more selected from Ruamido, the [1] Liquid detergent composition according to any one of to [12].
  • the mass ratio (c) / (a) of the content of the component (c) to the content of the component (a) is preferably 4.4 or less, more preferably 2.3 or less,
  • the mass ratio (c) / (b) of the content of the component (c) to the content of the component (b) is preferably 6 or less, more preferably 2.7 or less, preferably 0
  • liquid detergent composition according to any one of [1] to [15], further comprising an amphoteric surfactant other than the component (b).
  • the mass ratio of the content of the component (b) and the total content of the amphoteric surfactants other than the components (b) and (b) is preferably 0.2 or more, more preferably 0.8. 4 or more, More preferably, it is 0.6 or more, More preferably, it is 0.8 or more, Preferably it is less than 1,
  • liquid detergent composition according to any one of [1] to [17], further comprising (d) a water-miscible organic solvent.
  • the mass ratio (d) / ((a) + (b)) of the content of the component (d) and the total content of the components (a) and (b) is 0.5 or less, preferably Is 0.4 or less, more preferably 0.3 or less, still more preferably 0.1 or less, still more preferably 0.01 or less, still more preferably 0, the liquid detergent according to any one of the above [18] Composition.
  • the content of the component (a) is preferably 0.75% by mass or more, more preferably 1% by mass or more, further preferably 2% by mass or more, further preferably 3% by mass or more, and further preferably 5% by mass. % Or more, preferably 25% by mass or less, more preferably 20% by mass or less, preferably 0.75 to 25% by mass, more preferably 1 to 20% by mass, still more preferably 2 to 20% by mass.
  • the liquid detergent composition according to any one of [1] to [19], more preferably 5 to 20% by mass.
  • the content of the component (b) is preferably 0.3% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, still more preferably 1.5% by mass or more,
  • the amount is preferably 2% by mass or more, preferably 6% by mass or less, more preferably 5% by mass or less, still more preferably 3% by mass or less, preferably 0.3 to 6% by mass, more preferably 0.00%.
  • liquid detergent composition according to any one of [1] to [20], wherein is 2 to 3% by mass.
  • the content of the component (c) is preferably 0.3% by mass or more, more preferably 0.6% by mass or more, preferably 16% by mass or less, more preferably 15% by mass or less, more [1] to [21], preferably 10% by mass or less, more preferably 9% by mass or less, further preferably 6% by mass or less, further preferably 4% by mass or less, and still more preferably 1% by mass or less.
  • a liquid detergent composition according to any one of the above.
  • the content of the component (d) is preferably 10% by mass or less, more preferably 9% by mass or less, still more preferably 7% by mass or less, still more preferably 5% by mass or less, and further preferably 1% by mass or less.
  • a “cotton short sleeve shirt for evaluation” was prepared by the following method. Specifically, a washing machine (Qingdao Haier Washing Machine Co., Ltd., Standard: XQS60-ZY1128) and 2.5 kg of a commercially available cotton short-sleeved shirt (Shanghai Three Gun (group) Co., Ltd. Manufacture, round neck, size: L, 100% cotton), add detergent, hard water (CaCl 2 and MgCl 2 .6H 2 O 6: 4 at a temperature of 20 ° C.
  • the mixture was mixed at a molar ratio of 5), and the conditions described below were set, and washing was repeated 5 times.
  • the conditions for washing each time were a water amount of 54 L and a cleaning agent dose of 27 g (that is, the cleaning agent dose with respect to the water amount (the cleaning agent (g) / water (L)) was 0.5 g / L) and the washing time was 12 minutes. Rinse the water twice and dehydrate for 5 minutes.
  • the detergent is a nonionic surfactant (polyoxyethylene alkyl ether obtained by adding an average of 6 moles of oxyethylene groups to a primary alcohol having 12 alkyl groups, trade name: EMULGEN 108) And a mixture of amorphous sodium silicate and sodium carbonate at a mass ratio of 1: 1: 3.
  • a nonionic surfactant polyoxyethylene alkyl ether obtained by adding an average of 6 moles of oxyethylene groups to a primary alcohol having 12 alkyl groups, trade name: EMULGEN 108
  • EMULGEN 108 EMULGEN 108
  • This solution is titrated with 10 mmol / L sulfuric acid while gently stirring until the color of the solution changes from blue to reddish purple.
  • a pH meter is used instead of the indicator, and the amount of 10 mmol / L sulfuric acid (ml) required until the pH value is 4.8 is defined as a.
  • a washing machine washing time 10 minutes, storage water rinsing 2 times, removal
  • the ratio of the “area of the water surface covered with bubbles” to the “area of the entire water surface” is expressed in “%”. If no bubbles can be confirmed, write “No”. The larger the numerical value in this case, the better.
  • the cotton short-sleeve shirt for evaluation is taken out, and the washing liquid immediately after squeezing three sheets is squeezed 30 cm above the basin so that the water content is 100 to 140% by mass with respect to the shirt with the cotton short-sleeve for evaluation.
  • Check the condition of the surface Insert a straight ruler slightly into the foam to break the foam on the surface, measure the height from the surface of the water to the top of the foam, and express it in centimeters (cm). In this evaluation, the case of 2 cm or more is acceptable, and the larger the numerical value, the better.
  • the ratio of the “area of the water surface covered with bubbles” to the “area of the entire water surface” is expressed in “%”. If no bubbles can be confirmed, write “No”. The smaller the numerical value in this case, the better.
  • the artificial soiling cloth used was a cotton cloth cut to 6cm x 6cm (100% cotton, 40S whole cotton, purchased from Shanghai Rakuyoku Co., Ltd.). Then, it was left standing in a dark place where it was not exposed to light for 2 hours.
  • Lar oil Toka Kato (Sichuan Yuka Foods Co., Ltd.) 50g is added to soy oil (refined first grade, ARAWANA) 200g, stirred at 80 ° C for 2 hours, then Whatman filter paper (grade 1, particle retention capacity) : 11 ⁇ m)) and filtered.
  • each liquid detergent composition As an evaluation of each liquid detergent composition, a set of four artificially contaminated cloths was used. 0.5 g of each artificially contaminated cloth was coated with a liquid detergent composition and allowed to stand for 15 minutes, and then 4 artificially contaminated cloths coated with the detergent composition were 179 mg / L (calculated in terms of calcium carbonate) at a water temperature of 20 ° C.
  • the total amount of the cleaning composition brought in is 2.0 g), and is rotated at a rotational speed of 200 rpm, a washing time of 10 minutes, a temperature of 20 with a targotometer (RIDCi RHLQIII type vertical decontamination device, manufactured by China Chemical Industry Research Institute).
  • washing was performed at a temperature of ° C.
  • the washed artificially contaminated cloth (hereinafter referred to as treated cloth) is dehydrated in a two-tank washing machine (manufactured by Matsushita, XPB52-500S) for 1 minute and then dried at 40 ° C. for 1 hour.
  • the reflectivity was measured with a meter (Nippon Denshoku Industries Co., Ltd., Color meter ZE 6000) (C light source 2 degree visual field), and the Z value was recorded. In this evaluation, the case of 76 or more is acceptable, and the larger the numerical value, the better.
  • ⁇ PH measurement method> The pH was measured using a pH meter (D-52) and a pH electrode (6367-10D) manufactured by Horiba, Ltd. according to the following procedure.
  • As the standard solution pH4 standard solution (part number: K9084KF), pH7 standard solution (part number: K9084KG) and pH9 standard solution (part number: K9084KH) manufactured by Yokogawa Electric Corporation were transferred to a 50 ml beaker and used.
  • the pH electrode was washed thoroughly with ion exchange water and wiped off with tissue paper.
  • the internal electrode replenishment port of the pH electrode was opened, and the pH electrode was immersed in a beaker containing a pH 7 standard solution.
  • the “CAL” button was pressed after one minute.
  • the pH electrode was washed thoroughly with ion-exchanged water and wiped off with tissue paper.
  • the same operation was repeated using a pH 4 standard solution and a pH 9 standard solution, and a three-point calibration was performed.
  • the electrode was immersed in a pH 7 standard solution in the calibration mode, the “ENTER” button was pressed, pH reproducibility was checked, and if within 0.05 pH, the calibration was completed.
  • the pH electrode was thoroughly washed with ion-exchanged water and wiped off with tissue paper. After confirming that the internal electrode replenishment port of the pH electrode was open, the measurement was performed by pressing the “MEAS” button two minutes later with the pH electrode immersed in the sample by 3 cm.
  • each compounding component used for the Example and the comparative example is shown together as follows.
  • (A-1) (A-1-1): Sodium dodecyl sulfate (Manufacturer: Tokyo Chemical Industry Co., Ltd.)
  • A-1-2 Sodium tetradecyl sulfate (manufacturer: Wako Chemical Co., Ltd.)
  • A-1-3 Sodium hexadecyl sulfate (Manufacturer: Wako Chemical Co., Ltd.)
  • A-2) C14 / C16 ⁇ -olefin sulfonic acid sodium salt (trade name: Hostapur OS Liquid, content of active ingredient 42 mass%, manufacturer: Clariant Product (Deutschland) GmbH)
  • A-3) Secondary alkyl sulfonate sodium (trade name: Hostapur SAS 60, content of active ingredient 60 mass%, manufacturer: Clariant Product (Deutschland) GmbH)
  • A-4): polyoxyethylene (EO average addition mole number 3) sodium lauryl ether sulfate (trade name: EMAL 20C, content of active ingredient 25% by mass, content of sodium dodecyl sulfate 5.5% by mass, (Manufacturer: Kao Corporation
  • C-1 Mixture of lauryl polyoxyethylene ether and myristyl polyoxyethylene ether with polyoxyethylene addition (average number of moles of EO added 10) (trade name: KAO EMULGEN 110L, manufacturer: Kao (Shanghai) Chemical Co., Ltd. Company)
  • C-2 Lauryl polyoxyethylene ether with addition of polyoxyethylene (average number of moles of EO added: 21) (trade name: EMULGEN 121, manufacturer: Kao Corporation)
  • C-3) Palm oil fatty acid monoethanolamide (cocamide MEA) (trade name: AMINON C-01S, manufacturer: Shanghai Kao Chemical Co., Ltd.)
  • D-1 Propylene glycol (trade name: PROPYLENE GLYCOL USP / EP (US) (BR) (TH), manufacturer: Dow Chemical Company)
  • the alkyl sulfate or alkenyl group having 16 or more and 18 or less carbon atoms in the alkyl group or alkenyl group as the component (a-1-3) is used as the component (a).
  • a sulfate ester salt and can further selectively contain (d) component, an anionic surfactant other than (a) component, and / or amphoteric surfactant other than (b) component, Also, the effects of the present invention can be realized.
  • the total content of the components (a) and (b) (a) + (b) and / or the content of the component (a-1-3) Mass ratio to content (a-1-3) / (a) and / or mass ratio of content of component (a-1) to content of component (a) (a-1) / (a) And / or the mass ratio (d) / ((a) + (b)) of the content of the component (d) and the total content of the component (a) and the component (b) satisfies a predetermined range. It is preferable that a more excellent effect can be obtained.
  • the liquid detergent composition of the present invention has a strong application cleaning ability against cooking oil stains, the foams are fast when washing in hand-washing and washing machine washing, and rinsing is easy when rinsing. Applicable as a cleaning agent for clothing.

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Abstract

L'invention fournit une composition de détergeant liquide qui comprend les composants (a) à (c), et dans laquelle la teneur en composant (c) est supérieure ou égale à 0,3% en masse, le rapport massique （ｃ）／（ａ） de la teneur en composant (c) et de la teneur en composant (a) est inférieur ou égal à 7, et le rapport massique （ｃ）／（b） de la teneur en composant (c) et de la teneur en composant (b) est inférieur ou égal à 10. L'invention concerne également un détergeant liquide qui présente une forte capacité de nettoyage par application sur les tâches de graisse de cuisine, un moussage rapide lors du nettoyage lors d'un lavage à la main et d'un lavage en machine, et un rinçage facile lors du rinçage. (a) est un tensioactif anionique de 12 à 18 atomes de carbone, acide gras exclu ; (b) est un tensioactif de type oxyde d'amine ; et (c) est un tensioactif non ionique.
PCT/JP2018/001712 2017-01-25 2018-01-22 Composition de détergeant liquide WO2018139390A1 (fr)

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CN111394200B (zh) * 2019-12-31 2021-06-25 纳爱斯浙江科技有限公司 一种无二噁烷的液体餐具洗涤剂组合物及其制备方法

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WO2004067690A1 (fr) * 2003-01-28 2004-08-12 Kao Corporation Composition de detergent liquide
JP2010013579A (ja) * 2008-07-04 2010-01-21 Kao Corp 液体洗浄剤組成物
JP2011046926A (ja) * 2009-07-31 2011-03-10 Lion Corp 衣料用液体洗浄剤組成物
JP2011153231A (ja) * 2010-01-27 2011-08-11 Lion Corp 液体洗浄剤組成物
WO2012070308A1 (fr) * 2010-11-24 2012-05-31 花王株式会社 Composition de nettoyant liquide de surface dure
JP2016008276A (ja) * 2014-06-25 2016-01-18 ライオン株式会社 食器洗い用液体洗浄剤

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WO2015176221A1 (fr) * 2014-05-20 2015-11-26 The Procter & Gamble Company Compositions de détergent à lessive liquide à faible teneur en tensioactif, à forte teneur en carbonate et présentant un profil amélioré de lessive de savon
CN104987960A (zh) * 2015-07-13 2015-10-21 于文 织物纤维护理型生物酶洗衣液及其制备方法

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Publication number Priority date Publication date Assignee Title
WO2004067690A1 (fr) * 2003-01-28 2004-08-12 Kao Corporation Composition de detergent liquide
JP2010013579A (ja) * 2008-07-04 2010-01-21 Kao Corp 液体洗浄剤組成物
JP2011046926A (ja) * 2009-07-31 2011-03-10 Lion Corp 衣料用液体洗浄剤組成物
JP2011153231A (ja) * 2010-01-27 2011-08-11 Lion Corp 液体洗浄剤組成物
WO2012070308A1 (fr) * 2010-11-24 2012-05-31 花王株式会社 Composition de nettoyant liquide de surface dure
JP2016008276A (ja) * 2014-06-25 2016-01-18 ライオン株式会社 食器洗い用液体洗浄剤

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