WO2018062327A1 - 光学レンズ - Google Patents
光学レンズ Download PDFInfo
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- WO2018062327A1 WO2018062327A1 PCT/JP2017/035074 JP2017035074W WO2018062327A1 WO 2018062327 A1 WO2018062327 A1 WO 2018062327A1 JP 2017035074 W JP2017035074 W JP 2017035074W WO 2018062327 A1 WO2018062327 A1 WO 2018062327A1
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- polyester resin
- optical lens
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- acid
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- 0 *C(*)([C@@]1CC2CC1)C2(*)*(*)=O Chemical compound *C(*)([C@@]1CC2CC1)C2(*)*(*)=O 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/123—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/137—Acids or hydroxy compounds containing cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B3/00—Simple or compound lenses
- G02B3/02—Simple or compound lenses with non-spherical faces
- G02B3/04—Simple or compound lenses with non-spherical faces with continuous faces that are rotationally symmetrical but deviate from a true sphere, e.g. so called "aspheric" lenses
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
- H04N23/00—Cameras or camera modules comprising electronic image sensors; Control thereof
- H04N23/50—Constructional details
- H04N23/55—Optical parts specially adapted for electronic image sensors; Mounting thereof
Definitions
- the present invention relates to an optical lens. Specifically, the present invention relates to an optical lens having low water absorption and excellent heat resistance, transparency, and optical properties (refractive index, Abbe number, photoelastic coefficient).
- Optical glass or optical transparent resin is used as an optical element material for optical systems of liquid crystal display devices, optical disk devices, projection screen optical systems, and various cameras such as cameras, film-integrated cameras, and video cameras. ing.
- Optical glass is excellent in heat resistance, transparency, dimensional stability, chemical resistance, etc., and there are many kinds of materials having various refractive indexes (nd) and Abbe numbers ( ⁇ d). In addition to being expensive, it has problems of poor molding processability and low productivity. In particular, processing to an aspheric lens used for aberration correction is a serious obstacle to practical use because it requires extremely high technology and high cost.
- optical lenses made of transparent resins for optics especially thermoplastic transparent resins
- the optical transparent resin include, for example, polyester resins (Prior Documents 1 and 2), polycarbonate resin made of bisphenol A, polymethyl methacrylate, and the like.
- Birefringence is one of the important optical characteristics that must be taken into account when an optical member is composed of a transparent resin for optics. That is, it is not preferable in many cases that the optical transparent resin has a large birefringence. In particular, in the above exemplified applications (liquid crystal display device, optical disk device, projection screen, etc.), if a film having a birefringence, a lens, etc. are present in the optical path, the image quality and signal reading performance are adversely affected. It is desired to use an optical member made of an optical transparent resin having a birefringence as low as possible. Needless to say, it is desirable that the birefringence of a camera lens, a spectacle lens, or the like is small.
- the birefringence exhibited by the optical polymer is mainly due to the orientation birefringence in the main chain orientation of the polymer and the photoelastic birefringence due to stress. There is.
- the signs of orientation birefringence and photoelastic birefringence are derived from the chemical structure of the polymer and are unique to each polymer.
- Oriented birefringence is birefringence that is generally manifested by the orientation of the main chain (polymer chain) of a chain polymer, and the orientation of the main chain is, for example, a process of extrusion or stretching during the production of a polymer film, or This occurs in a process involving material flow, such as an injection molding process frequently used in manufacturing optical members of various shapes, and remains fixed to the optical member.
- the refractive index increases in the direction parallel to the orientation direction of the polymer chain, it is expressed as "Orientation birefringence is positive", and when the refractive index increases in the orthogonal direction, it is expressed as "Orientation birefringence is negative".
- photoelastic birefringence is birefringence caused by elastic deformation (strain) of a polymer.
- elastic deformation strain
- the material is elastically deformed by an external force received in a state where the optical member is fixed to a device used at a normal temperature (below the glass transition temperature), which causes photoelastic birefringence.
- the photoelastic coefficient of the polymer is small, the occurrence of photoelastic birefringence is small.
- the photoelastic coefficient is defined as a coefficient ⁇ of ⁇ when a birefringence difference ⁇ n is caused by a stress difference ⁇ as shown in the following equation.
- the resin for optical lenses has low water absorption.
- the refractive index changes due to the influence of water molecules present inside the resin. If the moisture distribution is non-uniform, the refractive index of the lens will also be non-uniform and may not be applicable to precise optical design.
- the resin absorbs water, it expands and changes its dimensions. For example, in an optical system in which a plurality of lenses are combined, if water absorption and expansion occur, stress is generated between the lenses, causing damage to the lenses and occurrence of photoelastic birefringence. If the moisture distribution is non-uniform, non-uniform surface deformation can also occur.
- aberration correction is performed using a plurality of concave and convex lenses having different optical characteristics in order to improve the quality of a color image.
- chromatic aberration correction in which a concave lens having a high refractive index and a low Abbe number is combined with a convex lens having a low refractive index and a high Abbe number.
- the concave lens produces a chromatic aberration opposite in sign to that of the convex lens, thereby synthetically canceling out the chromatic aberration.
- the chromatic aberration is increased, the color blur is increased, and the image quality as a color image is extremely lowered.
- high Abbe number optical lens materials examples include calcium fluoride for inorganic materials and polymethyl methacrylate for organic materials.
- calcium fluoride is a crystal of an inorganic compound, it must be cut from a single crystal and polished for use as an optical lens. Furthermore, since it is soft and easily scratched and is easy to cleave, there are problems that it is expensive to manufacture and is not suitable for mass production.
- Polyester resin containing an aromatic ring has a large birefringence and a photoelastic coefficient and is inferior in optical properties.
- the total aliphatic polyester resin has a problem that it is inferior in heat resistance.
- the conventional optical lens made of polyester resin is not sufficient in terms of heat resistance and optical characteristics.
- the polycarbonate resin made of bisphenol A has weak points such as large birefringence, so that it can be used only for limited applications to be used as a lens material.
- polymethylmethacrylate is excellent in optical properties, it has poor performance such as heat resistance and mechanical properties, and further has a problem of high water absorption. Therefore, it cannot be used in fields where these performances are required.
- the present invention has been made in view of the above-described problems of the prior art, has a low water absorption, and is an optical lens excellent in heat resistance, transparency, and optical characteristics (refractive index, Abbe number, photoelastic coefficient). For the purpose of provision.
- an optical lens made of a polyester resin containing a specific alicyclic structure as a structural unit can solve the above problems, and completed the present invention. I let you.
- the present invention is as follows.
- R 1 is a hydrogen atom, CH 3 or C 2 H 5 , R 2 and R 3 are each independently a hydrogen atom or CH 3 , and n is 0 or 1. .
- the glass transition temperature of the polyester resin is 120 ° C. or higher.
- the amount of crystallization heat generated when the polyester resin cools is 5 J / g or less.
- the water absorption after 24 hours of the polyester resin is 0.25% or less.
- the absolute value of the photoelastic coefficient of the polyester resin is 40 ⁇ 10 ⁇ 12 Pa ⁇ 1 or less.
- the refractive index (nd) of the polyester resin is 1.60 or less.
- the Abbe number ( ⁇ d) of the polyester resin is 28 or more.
- optical lens according to any one of [1] to [4], wherein the optical lens is an aspheric lens.
- An optical system formed by combining the optical lens according to any one of [1] to [6] and another optical lens.
- an optical lens that has low water absorption and is excellent in heat resistance, transparency, and optical characteristics (refractive index, Abbe number, photoelastic coefficient).
- the result of 1 H-NMR measurement of the main reaction product obtained in the monomer synthesis example is shown.
- the result of 13 C-NMR measurement of the main reaction product obtained in the monomer synthesis example is shown.
- the result of the COSY-NMR measurement of the main reaction product obtained in the monomer synthesis example is shown.
- the present embodiment a mode for carrying out the present invention (hereinafter simply referred to as “the present embodiment”) will be described in detail.
- the following embodiments are examples for explaining the present invention, and are not intended to limit the present invention to the following contents.
- the present invention can be implemented with appropriate modifications within the scope of the gist thereof.
- the optical lens of the present embodiment is made of a polyester resin containing a unit (A) represented by the following general formula (1) (hereinafter also referred to as “unit (A)” or “structural unit (A)”).
- the resin contains a diol unit (B) (hereinafter also referred to as “unit (B)” or “structural unit (B)”) and a dicarboxylic acid or an ester-forming derivative unit (C) as necessary. (Hereinafter also referred to as “unit (C)” and “structural unit (C)”).
- R 1 is a hydrogen atom, CH 3 or C 2 H 5 , R 2 and R 3 are each independently a hydrogen atom or CH 3 , and n is 0 or 1. .
- an optical lens having low water absorption and excellent heat resistance, transparency, and optical properties can be suitably obtained.
- “excellent in heat resistance” means that the glass transition temperature (Tg) measured by the method described in Examples described later is sufficiently high, and “excellent in transparency” , Refers to the fact that the amount of heat generated by crystallization measured by the method described in the examples described later is sufficiently low, and “excellent optical properties (refractive index, Abbe number, photoelastic coefficient)”
- the refractive index (nd) and Abbe number ( ⁇ d) measured by the method described in the examples described later can be arbitrarily adjusted while keeping the absolute value of the photoelastic coefficient measured by the method described in the example sufficiently low. Point to.
- R 1 is preferably a hydrogen atom or CH 3
- R 2 and R 3 are preferably a hydrogen atom.
- R 1 , R 2 , and R 3 in the general formula (1) are hydrogen atoms.
- n is preferably 1 from the viewpoint of further improving the heat resistance.
- the content of the structural unit (A) with respect to all the structural units of the polyester resin is preferably 10 to 95 mol%.
- the content is 10 mol% or more, sufficiently good heat resistance and optical characteristics tend to be obtained.
- the said content is 95 mol% or less, since moldability can be improved, ensuring favorable heat resistance and an optical characteristic, it is preferable.
- the content of the unit (A) is more preferably 15 to 95 mol%, and still more preferably 20 to 95 mol%.
- the optical lens of the present invention is composed of a homopolyester resin composed of the structural unit (A).
- the optical lens of the present invention is made of a copolyester resin containing the structural unit (A), the structural unit (B), and the structural unit (C).
- the structural unit (B) is not particularly limited as long as it is a unit derived from diol, and specific examples thereof include ethylene glycol, trimethylene glycol, 1,4-butanediol, 1,5-pentanediol, 1, 6-hexanediol, diethylene glycol, propylene glycol, neopentyl glycol, 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, 1,2-decahydronaphthalenediethanol, 1,3-decahydronaphthalenediethanol, 1,4-decahydronaphthalene diethanol, 1,5-decahydronaphthalene diethanol, 1,6-decahydronaphthalene diethanol, 2,7-decahydronaphthalene diethanol, tetralin dimethanol, norbornane dimethanol, tricyclode Dimethanol, pentacyclopentadecane dimethanol, decahydro-1,4: 5,8-dimethanonaphthalenedi
- the structural unit (B) is preferably a unit derived from an aliphatic diol or a diol having a fluorene structure because good optical properties can be obtained. Moreover, it is more preferable that the unit derived from the diol having the fluorene structure has a cardo structure together with the fluorene structure.
- units derived from such aliphatic diols include 1,4-cyclohexanedimethanol, ethylene glycol, 3,9-bis (1,1-dimethyl-2-hydroxyethyl) -2,4,8,10- More preferred are units derived from tetraoxaspiro [5.5] undecane, 1,4: 3,6-dianhydro-D-sorbitol, decahydro-1,4: 5,8-dimethananaphthalenediethanol.
- the units derived from the diol having a fluorene structure include 9,9-bis [4- (2-hydroxyethoxy) phenyl] fluorene, 9,9-bis [4- (2-hydroxyethoxy) -3-methyl.
- optical isomers may be any of a cis isomer, a trans isomer, and a mixture thereof, and are not particularly limited.
- the above-mentioned units may be included alone or in combination of two or more.
- the structural unit (C) is not particularly limited as long as it is a unit derived from dicarboxylic acid or an ester-forming derivative thereof. Specific examples thereof include terephthalic acid, isophthalic acid, phthalic acid, and 1,3-naphthalenedicarboxylic acid.
- 1,4-naphthalenedicarboxylic acid 1,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, 2-methylterephthalic acid, biphenyldicarboxylic acid, tetralindicarboxylic acid and other aromatics Structural units derived from dicarboxylic acids and / or derivatives thereof; succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, decanedicarboxylic acid, dodecanedicarboxylic acid, cyclohexanedicarboxylic acid, decalin dicarboxylic acid, Norbornane dicarboxylic acid, tricyclo Candicarboxylic acid, pentacyclopentadecanedicarboxylic acid, 3,9-bis (1,1-dimethyl-2-carboxyethyl) -2
- the structural unit (C) is preferably a unit derived from an aliphatic dicarboxylic acid or an ester-forming derivative thereof, or a dicarboxylic acid having a fluorene structure or an ester-forming derivative thereof because good optical properties are obtained. . Moreover, about the unit derived from the dicarboxylic acid which has the said fluorene structure, or its ester-forming derivative, it is more preferable to have a cardo structure with a fluorene structure.
- a unit derived from an aliphatic dicarboxylic acid or an ester-forming derivative thereof a unit derived from dimethyl 1,4-cyclohexanedicarboxylate is more preferable from the viewpoint of physical properties balance between transparency, heat resistance and optical properties.
- the unit derived from a dicarboxylic acid having a fluorene structure or an ester-forming derivative thereof is 9,9-bis (methoxycarbonylmethyl) fluorene, from the viewpoint of balance of physical properties between transparency, heat resistance and optical properties, More preferred are units derived from 9,9-bis (2-methoxycarbonylethyl) fluorene and 9,9-bis (methoxycarbonylpropyl) fluorene.
- These optical isomers may be any of a cis isomer, a trans isomer, and a mixture thereof, and are not particularly limited. The above-mentioned units may be included alone or in combination of two or more.
- the polyester resin may contain other units such as a hydroxyl group and a carboxylic acid or its ester-forming derivative unit (A1) in addition to the units (A) to (C).
- the unit (A1) is not particularly limited, but examples thereof include oxyacids such as glycolic acid, lactic acid, hydroxybutyric acid, 2-hydroxyisobutyric acid, hydroxybenzoic acid, 6-hydroxycaproic acid, 4-hydroxycyclohexanecarboxylic acid, and the like. And / or a unit derived from a derivative thereof.
- the polyester resin is not particularly limited as long as it has the effects of the present invention, but preferably satisfies at least one of the following (1) to (6), and the following (1) to (4): It is more preferable to satisfy this, and it is even more preferable to satisfy all of the following (1) to (6).
- the glass transition temperature (Tg) of the polyester resin is not particularly limited as long as it has the effects of the present invention, but is preferably 120 ° C. or higher. Preferably it is 130 degreeC or more, More preferably, it is 140 degreeC or more. In addition, although an upper limit is not specifically limited, For example, it is 240 degreeC.
- the Tg can be measured by the method described in Examples described later. The Tg can be adjusted to the above range by appropriately adjusting the copolymerization ratio of the raw material monomer of the polyester resin, for example.
- the crystallization heat generation amount when the polyester resin cools is not particularly limited as long as it has the effects of the present invention, but is preferably 5 J / g or less, More preferably, it is 1 J / g or less, More preferably, it is 0.3 J / g or less.
- a lower limit is not specifically limited, For example, it is 0 J / g.
- the amount of crystallization heat generated when the temperature is lowered can be measured by the method described in Examples described later.
- the crystallization heat generation amount at the time of cooling can be adjusted to the above range by appropriately adjusting the copolymerization ratio of the raw material monomer of the polyester resin, for example.
- the water absorption rate after 24 hours of the polyester resin is not particularly limited as long as the polyester resin has the effect of the present invention, from the viewpoint of suppressing deformation due to moisture absorption and the change in refractive index, but is preferably 0.00. It is 25% or less, more preferably 0.23% or less, still more preferably 0.21% or less, and still more preferably 0.20% or less. In addition, although a lower limit is not specifically limited, For example, it is 0.01%.
- the water absorption rate can be measured by the method described in Examples described later.
- the said water absorption can be adjusted to the said range, for example by adjusting suitably the copolymerization ratio of the raw material monomer of a polyester resin.
- the polyester resin in the present invention is excellent in optical properties (refractive index, Abbe number, photoelastic coefficient). Specifically, by having a specific structure, it is possible to arbitrarily adjust the refractive index and the Abbe number while keeping the absolute value of the photoelastic coefficient sufficiently low. For example, the refractive index, Abbe number, and photoelastic coefficient can be adjusted to the following ranges by appropriately adjusting the copolymerization ratio of the raw material monomer of the polyester resin.
- the absolute value of the photoelastic coefficient is not particularly limited as long as it has the effect of the present invention, but is preferably 40 ⁇ 10 ⁇ 12 Pa ⁇ 1 or less, more preferably 35 ⁇ 10 ⁇ 12 Pa ⁇ 1 or less. More preferably, it is 30 ⁇ 10 ⁇ 12 Pa ⁇ 1 or less. In addition, although a lower limit is not specifically limited, For example, it is 0.01 * 10 ⁇ -12> Pa ⁇ -1 > .
- the absolute value of the photoelastic coefficient can be measured by the method described in Examples described later.
- the refractive index (nd) for d-line wavelength light is not particularly limited as long as it has the effect of the present invention, but is preferably 1.60 or less, more preferably 1.59 or less. It is more preferably 58 or less, even more preferably 1.57 or less, and particularly preferably 1.56 or less. In consideration of practical use as the optical lens of the present invention, the lower limit of the refractive index is not particularly limited, but is about 1.40.
- the refractive index with respect to the d-line wavelength light can be measured by the method described in Examples described later.
- the Abbe number ( ⁇ d) is not particularly limited as long as it has the effect of the present invention, but is preferably 28 or more, more preferably 30 or more, still more preferably 31 or more, and even more preferably 35. Above, especially preferably 40 or more. In consideration of practical use as the optical lens of the present invention, the upper limit of the Abbe number is not particularly limited, but is about 70. The Abbe number can be measured by the method described in Examples described later.
- the Abbe number ( ⁇ d) is a numerical value represented by the formula (1) described in the examples, and indicates the wavelength dependency of the refractive index. Therefore, a substance having a high Abbe number has a small change in the refractive index depending on the wavelength, and represents a small chromatic aberration.
- polyester resin in the present invention is excellent in optical characteristics (refractive index, Abbe number, photoelastic coefficient), for example, optical lenses for imaging and projection such as cameras, video cameras, projection televisions, laser printers, microlens arrays; It can be suitably used for optical component materials such as information transmission components such as optical fibers, optical fiber connectors, and optical waveguides.
- polyester resin of the present embodiment known antioxidants, mold release agents, ultraviolet absorbers, fluidity modifiers, crystal nucleating agents, reinforcing agents, dyes, antistatic agents, antibacterial agents, etc. It is preferable to add these additives.
- the polyester resin can be obtained by homopolymerizing the unit (A) and by copolymerizing each monomer corresponding to the units (A) to (C).
- a method for producing a monomer corresponding to the unit (A) will be described.
- Such a monomer is represented, for example, by the following general formula (2).
- R 1 is a hydrogen atom
- R 2 and R 3 are each independently a hydrogen atom or CH 3
- X is a hydrogen atom or carbon It is a hydrocarbon group which may contain a hydroxyl group of several 4 or less.
- R 1 is preferably a hydrogen atom or CH 3
- R 2 and R 3 are preferably a hydrogen atom.
- the hydrocarbon group include, but are not limited to, a methyl group, an ethyl group, a propyl group, a butyl group, a vinyl group, a 2-hydroxyethyl group, and a 4-hydroxybutyl group.
- the compound represented by the general formula (2) in this embodiment can be synthesized by using, for example, the route represented by the following formula (I) using dicyclopentadiene or cyclopentadiene and an olefin having a functional group as a raw material. .
- R 1 is a hydrogen atom, CH 3 or C 2 H 5 , R 2 and R 3 are each independently a hydrogen atom or CH 3 , and X is a hydrogen atom or a carbon number of 4 or less. Which may contain a hydroxyl group of
- the monoolefin having 13 to 21 carbon atoms represented by the general formula (4) can be produced, for example, by performing a Diels-Alder reaction between an olefin having a functional group and dicyclopentadiene.
- olefin having a functional group used in the Diels-Alder reaction include, but are not limited to, methacrylic acid, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, vinyl methacrylate, methacrylic acid-2 -Hydroxyethyl, 4-hydroxybutyl methacrylate, acrylic acid, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, vinyl acrylate, 2-hydroxyethyl acrylate, 4-hydroxybutyl acrylate Crotonic acid, methyl crotonic acid, ethyl crotonic acid, 3-methylcrotonic acid, methyl 3-methylcrotonate, ethyl 3-methylcrotonate and the like.
- Preferred olefins include methacrylic acid, methyl methacrylate, methacrylate.
- Acid-2-hydroxyethyl, acrylic acid, methyl acrylate, include 2-hydroxyethyl acrylate, methyl methacrylate, methyl acrylate may be mentioned as preferred olefin.
- examples of the olefin having a functional group used in the Diels-Alder reaction include acrylonitrile, methacrylonitrile, acrolein, and methacrolein.
- monoolefins represented by the general formula (4 ′) can be produced via the routes shown in the following formulas (II) and (III).
- R 1 is a hydrogen atom or CH 3 )
- R 1 is a hydrogen atom or CH 3 )
- the dicyclopentadiene used for the Diels-Alder reaction preferably has a high purity, and it is preferable to reduce the content of butadiene, isoprene and the like.
- the purity of dicyclopentadiene is preferably 90% or more, and more preferably 95% or more. Further, since dicyclopentadiene tends to depolymerize under heating conditions to form cyclopentadiene (so-called monocyclopentadiene), it is also possible to use cyclopentadiene instead of dicyclopentadiene.
- the monoolefin having 13 to 21 carbon atoms represented by the general formula (4) is substantially a monoolefin having 8 to 16 carbon atoms represented by the following general formula (7) (the first stage Diels-Alder reaction product).
- Dienophile Dienophile
- the second stage Diels-Alder reaction is considered to produce a monoolefin having 13 to 21 carbon atoms represented by the general formula (4).
- the monoolefin having 13 to 21 carbon atoms represented by the formula (4) is appropriately controlled by appropriately controlling the reaction conditions of the first stage Diels-Alder reaction.
- a monoolefin having 8 to 16 carbon atoms represented by the formula (7) can be selectively obtained.
- R 1 represents a hydrogen atom, CH 3 or C 2 H 5
- R 2 and R 3 each independently represent a hydrogen atom or CH 3
- X represents a hydrogen atom or a carbon number of 4 or less.
- the reaction temperature is preferably 100 ° C. or higher, more preferably 120 ° C. or higher, and further preferably 130 ° C. or higher.
- the reaction temperature is preferably less than 180 ° C. In any case, it is preferable to perform the reaction at a temperature of 250 ° C. or lower in order to suppress the by-product of the high boiling substance.
- reaction solvents such as aliphatic hydrocarbons having 6 or more carbon atoms, cyclohexane, toluene, xylene, ethylbenzene, mesitylene, propanol, butanol, etc. preferable. If necessary, it may be added to AlCl 3 or the like known catalysts.
- R 1 is a hydrogen atom
- R 2 and R 3 are each independently a hydrogen atom or CH 3
- X is a hydrogen atom or carbon (It is a hydrocarbon group which may contain a hydroxyl group of several 4 or less.)
- the reaction method of the Diels-Alder reaction is a batch system using a tank reactor, a semi-batch system in which a substrate or a substrate solution is supplied to a tank reactor under reaction conditions, and a substrate type under a reaction condition in a tube reactor. It is possible to adopt various reaction methods such as a continuous flow method for distributing the gas.
- the reaction product obtained by the Diels-Alder reaction can be used as a raw material for the next hydroformylation reaction as it is, but may be used for the next step after being purified by a method such as distillation, extraction or crystallization.
- bifunctional compound having 14 to 22 carbon atoms represented by (3) in formula (I) is, for example, a monoolefin having 13 to 21 carbon atoms represented by the general formula (4) and carbon monoxide.
- hydrogen gas can be produced by a hydroformylation reaction in the presence of a rhodium compound or an organophosphorus compound.
- the rhodium compound used in the hydroformylation reaction may be a compound that forms a complex with an organic phosphorus compound and exhibits hydroformylation activity in the presence of carbon monoxide and hydrogen, and the form of the precursor is not particularly limited. .
- rhodium acetylacetonate dicarbonyl hereinafter referred to as Rh (acac) (CO) 2
- Rh 2 O 3 Rh 4 (CO) 12
- Rh 6 (CO) 16 Rh (NO 3 ) 3, etc.
- the catalyst precursor may be introduced into the reaction mixture together with the organophosphorus compound to form a rhodium metal hydridocarbonyl phosphorus complex having catalytic activity in the reaction vessel.
- a rhodium metal hydridocarbonyl phosphorus complex may be prepared in advance. It may be introduced into the reactor.
- Rh (acac) (CO) 2 is reacted with an organophosphorus compound in the presence of a solvent, and then introduced into a reactor together with an excess of organophosphorus compound, and a rhodium-organophosphorus complex having catalytic activity and The method of doing is mentioned.
- a two-stage Diels-Alder reaction product having an internal olefin having a relatively large molecular weight represented by the general formula (4) is hydroformylated with a very small amount of rhodium catalyst.
- the amount of rhodium compound used in the hydroformylation reaction is preferably 0.1 to 60 micromoles per 1 mol of a monoolefin having 13 to 21 carbon atoms represented by the general formula (4) which is a substrate for the hydroformylation reaction. 0.1 to 30 ⁇ mol is more preferable, 0.2 to 20 ⁇ mol is further preferable, and 0.5 to 10 ⁇ mol is particularly preferable.
- the amount of the rhodium compound used is less than 60 micromoles per 1 mol of the monoolefin having 13 to 21 carbon atoms, it can be evaluated that it is practically not necessary to provide a collection and recycling facility for the rhodium complex. Thus, according to this embodiment, it is possible to reduce the economic burden related to the recovery and recycling equipment, and to reduce the cost for the rhodium catalyst.
- the organophosphorus compound that forms a catalyst for the hydroformylation reaction with the rhodium compound is not particularly limited.
- R a , R b , and R c include, but are not limited to, an aryl group that can be substituted with an alkyl group having 1 to 4 carbon atoms or an alkoxy group, an alkyl group having 1 to 4 carbon atoms, or an alkoxy group.
- alicyclic alkyl groups that can be substituted with triphenylphosphine and triphenylphosphite are preferably used.
- the amount of the organophosphorus compound used is preferably 300-fold to 10,000-fold mol, more preferably 500-fold to 10,000-fold mol, still more preferably 700-fold to 5000-fold mol, particularly preferably relative to the rhodium atom in the rhodium compound. Is 900 times to 2000 times mol.
- the amount of the organic phosphorus compound used is 300 times mol or more of the rhodium atom, the stability of the rhodium metal hydridocarbonyl phosphorus complex as the catalyst active material tends to be sufficiently secured, and as a result, good reactivity is ensured. Tend to. Moreover, when the usage-amount of an organic phosphorus compound is 10000 times mole or less of a rhodium atom, it is preferable from a viewpoint of fully reducing the cost concerning an organic phosphorus compound.
- the hydroformylation reaction can be carried out without using a solvent, but can be carried out more suitably by using a solvent inert to the reaction.
- Solvents that can be used in the hydroformylation reaction include those that dissolve the monoolefin having 13 to 21 carbon atoms, dicyclopentadiene or cyclopentadiene represented by the general formula (4), the rhodium compound, and the organophosphorus compound. If it does not specifically limit.
- hydrocarbons such as aliphatic hydrocarbons, alicyclic hydrocarbons, and aromatic hydrocarbons
- esters such as aliphatic esters, alicyclic esters, and aromatic esters
- Alcohols such as aromatic alcohols and alicyclic alcohols
- solvents such as aromatic halides.
- hydrocarbons are preferably used, and alicyclic hydrocarbons and aromatic hydrocarbons are more preferably used.
- the temperature for the hydroformylation reaction is preferably 40 ° C. to 160 ° C., more preferably 80 ° C. to 140 ° C.
- the reaction temperature is 40 ° C. or higher, a sufficient reaction rate tends to be obtained, and the residual monoolefin as a raw material tends to be further suppressed.
- the reaction is performed under pressure with carbon monoxide (hereinafter also referred to as “CO”) and hydrogen (hereinafter also referred to as “H 2 ”) gas.
- CO carbon monoxide
- H 2 hydrogen
- the CO and H 2 gases can be independently introduced into the reaction system, or can be introduced into the reaction system as a mixed gas prepared in advance.
- the molar ratio of CO and H 2 gas introduced into the reaction system is preferably 0.2 to 5, more preferably 0.5 to 2, and still more preferably 0.8 to 1.2. .
- the reaction activity of the hydroformylation reaction and the selectivity of the target aldehyde tend to be good. Since CO and H 2 gas introduced into the reaction system decrease with the progress of the reaction, the reaction control may be simple when a previously prepared mixed gas of CO and H 2 is used.
- the reaction pressure of the hydroformylation reaction is preferably 1 to 12 MPa, more preferably 1.2 to 9 MPa, and further preferably 1.5 to 5 MPa.
- the reaction pressure is 1 MPa or more, a sufficient reaction rate tends to be obtained, and the residual monoolefin as a raw material tends to be sufficiently suppressed.
- the reaction pressure is set to 12 MPa or less, it is economically advantageous because expensive equipment excellent in pressure resistance is not required.
- a batch reaction or a semi-batch reaction is suitable as a reaction system in the case of performing the hydroformylation reaction.
- the semi-batch reaction is performed by adding a rhodium compound, an organophosphorus compound and the solvent to the reactor, pressurizing or warming with CO / H 2 gas, etc. This can be done by feeding the solution to the reactor.
- the reaction product obtained by the hydroformylation reaction can be used as a raw material for the next reduction reaction as it is, but may be subjected to the next step after purification by distillation, extraction, crystallization, or the like.
- the compound having 14 to 22 carbon atoms represented by the general formula (2) in the formula (I) is obtained by converting a compound having 14 to 22 carbon atoms represented by the general formula (3) into a catalyst having hydrogenation ability and It can be produced by reduction in the presence of hydrogen.
- a catalyst containing at least one element selected from the group consisting of copper, chromium, iron, zinc, aluminum, nickel, cobalt, and palladium as a catalyst having hydrogenation ability. More preferable catalysts include a Cu—Cr catalyst, a Cu—Zn catalyst, a Cu—Zn—Al catalyst and the like, as well as a Raney-Ni catalyst, a Raney-Co catalyst, and the like, and more preferable catalysts include a Cu—Cr catalyst and a Raney catalyst. -Co catalyst.
- the amount of the hydrogenation catalyst used is 1 to 100% by mass, preferably 2 to 50% by mass, more preferably 5 to 5% by mass with respect to the compound having 14 to 22 carbon atoms represented by the general formula (3) as a substrate. 30% by mass.
- the amount of catalyst used is 1% by mass or more, the reaction proceeds sufficiently, and as a result, the yield of the target product tends to be sufficiently secured. Further, when the amount of catalyst used is 100% by mass or less, the balance between the amount of catalyst used for the reaction and the effect of improving the reaction rate tends to be good.
- the reaction temperature for the reduction reaction is preferably 60 to 200 ° C, more preferably 80 to 150 ° C.
- the reaction temperature for the reduction reaction is preferably 60 to 200 ° C, more preferably 80 to 150 ° C.
- the reaction temperature By setting the reaction temperature to 200 ° C. or lower, the occurrence of side reactions and decomposition reactions is suppressed, and the target product tends to be obtained with a high yield.
- the reaction temperature by setting the reaction temperature to 60 ° C. or higher, the reaction can be completed in an appropriate time, and there is a tendency that a decrease in productivity and a decrease in the yield of the target product can be avoided.
- the reaction pressure of the reduction reaction is preferably 0.5 to 10 MPa, more preferably 1 to 5 MPa as a hydrogen partial pressure.
- the hydrogen partial pressure is preferably 0.5 to 10 MPa or less, the occurrence of side reactions and decomposition reactions is suppressed, and the target product tends to be obtained in a high yield.
- the hydrogen partial pressure is set to 0.5 MPa or more, the reaction can be completed in an appropriate time, and a decrease in productivity and a decrease in the yield of the target product tend to be avoided.
- a gas inert to the reduction reaction for example, nitrogen or argon
- a solvent can be used.
- the solvent used for the reduction reaction include aliphatic hydrocarbons, alicyclic hydrocarbons, aromatic hydrocarbons, alcohols, and the like. Among them, alicyclic hydrocarbons, aromatic hydrocarbons, alcohols, etc. Are preferred. Specific examples thereof include cyclohexane, toluene, xylene, methanol, ethanol, 1-propanol and the like.
- the reaction method of the reduction reaction is a batch type using a tank reactor, a semi-batch type for supplying a substrate or a substrate solution to a tank reactor under the reaction conditions, a reaction condition in a tube type reactor filled with a molded catalyst. It is possible to adopt various reaction methods such as a continuous flow method in which a substrate and a substrate solution are circulated.
- the reaction product obtained by the reduction reaction can be purified by, for example, distillation, extraction, crystallization, or the like.
- the compound represented by the general formula (2) or the compound represented by the formula (8) is a monomer corresponding to the unit (A), and each unit corresponding to the units (B) to (C) is used.
- the method of copolymerizing with the monomer is not particularly limited, and a conventionally known polyester production method can be applied. Examples thereof include a melt polymerization method such as a transesterification method and a direct esterification method, or a solution polymerization method.
- a transesterification catalyst, an esterification catalyst, a polycondensation catalyst, or the like used in the production of a normal polyester resin can be used.
- These catalysts are not particularly limited.
- metals such as zinc, lead, cerium, cadmium, manganese, cobalt, lithium, sodium, potassium, calcium, nickel, magnesium, vanadium, aluminum, titanium, antimony, germanium, tin, etc.
- fatty acid salts, carbonates, phosphates, hydroxides, chlorides, oxides, alkoxides can be used alone or in combination of two or more.
- the catalyst compounds of manganese, cobalt, zinc, titanium, calcium, antimony, germanium, and tin are preferable, and compounds of manganese, titanium, antimony, germanium, and tin are more preferable.
- the amount of these catalysts to be used is not particularly limited, but the amount as a metal component with respect to the raw material of the polyester resin is preferably 1 to 1000 ppm, more preferably 3 to 750 ppm, and still more preferably 5 to 500 ppm.
- the reaction temperature in the polymerization reaction depends on the type of catalyst and the amount of the catalyst used, but is usually selected within the range of 150 ° C. to 300 ° C., preferably 180 ° C. to 280 ° C. in consideration of the reaction rate and resin coloring.
- the pressure in the reaction layer is preferably adjusted to 1 kPa or less finally from the atmospheric atmosphere, and more preferably 0.5 kPa or less.
- a phosphorus compound When performing the polymerization reaction, a phosphorus compound may be added if desired.
- the phosphorus compound include, but are not limited to, phosphoric acid, phosphorous acid, phosphoric acid ester, phosphorous acid ester, and the like.
- phosphate esters include, but are not limited to, methyl phosphate, ethyl phosphate, butyl phosphate, phenyl phosphate, dimethyl phosphate, diethyl phosphate, dibutyl phosphate, diphenyl phosphate, trimethyl phosphate, Examples thereof include triethyl phosphate, tributyl phosphate, and triphenyl phosphate.
- phosphites include, but are not limited to, methyl phosphite, ethyl phosphite, butyl phosphite, phenyl phosphite, dimethyl phosphite, diethyl phosphite, dibutyl phosphite, Examples thereof include diphenyl phosphite, trimethyl phosphite, triethyl phosphite, tributyl phosphite, and triphenyl phosphite. These can be used alone or in combination of two or more.
- the concentration of phosphorus atoms in the polyester resin of the present embodiment is preferably 1 to 500 ppm, more preferably 5 to 400 ppm, still more preferably 10 to 200 ppm.
- polyester resin of the present embodiment when the polyester resin of the present embodiment is produced, various stabilizers such as an etherification inhibitor, a heat stabilizer and a light stabilizer, a polymerization regulator and the like can be used.
- various stabilizers such as an etherification inhibitor, a heat stabilizer and a light stabilizer, a polymerization regulator and the like can be used.
- the polyester resin of the present embodiment includes an antioxidant, a light stabilizer, an ultraviolet absorber, a plasticizer, an extender, a matting agent, a drying regulator, an antistatic agent, as long as the purpose of the present embodiment is not impaired.
- Various additives such as anti-settling agent, surfactant, flow improver, drying oil, wax, filler, colorant, reinforcing agent, surface smoothing agent, leveling agent, curing reaction accelerator, thickener, molding aid Can be added.
- the polyester resin of the present embodiment can be a resin composition in which a resin other than the polyester resin of the present embodiment is used in a range that does not impair the desired effect of the present embodiment.
- a resin is not particularly limited.
- polyester resin other than the polyester resin in the present embodiment polycarbonate resin, (meth) acrylic resin, polyamide resin, polystyrene resin, cycloolefin resin, acrylonitrile-butadiene-styrene copolymer.
- Examples thereof include at least one resin selected from the group consisting of a polymer resin, a vinyl chloride resin, a polyphenylene ether resin, a polysulfone resin, a polyacetal resin, and a methyl methacrylate-styrene copolymer resin. These can use various well-known things and can add it to a resin composition individually by 1 type or in combination of 2 or more types.
- the optical lens of the present invention includes, for example, an imaging lens used for a camera, a video camera, etc .; a projection lens used for a projection television, a projection screen, etc .; an f ⁇ lens or a microlens array used for a laser printer, a liquid crystal display device, an optical disk It is a lens used for an apparatus, a vehicle-mounted camera, and the like.
- the method for molding the optical lens is not particularly limited, and examples thereof include injection molding, press molding, compression molding, injection compression molding, and extrusion molding.
- known additives such as an ultraviolet absorber, an antioxidant, a flame retardant, an antistatic agent, and a colorant can be added as long as the effects of the present invention are exhibited.
- the optical lens of the present invention is particularly preferably obtained by injection molding the polyester resin of the present embodiment into a lens shape with an injection molding machine or an injection compression molding machine.
- the molding environment must naturally be a low dust environment, preferably class 1000 or less, more preferably class 100 or less.
- the optical lens of the present invention is particularly preferably implemented by using it in the form of an aspheric lens as necessary. Since an aspherical lens can substantially eliminate spherical aberration with a single lens, it is not necessary to remove spherical aberration with a combination of a plurality of spherical lenses, thus reducing weight and reducing production costs. It becomes possible. Therefore, the aspherical lens is particularly useful as a camera lens among optical lenses.
- the astigmatism of the aspheric lens is preferably 0 to 15 m ⁇ , more preferably 0 to 10 m ⁇ .
- the thickness of the optical lens of the present invention can be set in a wide range according to the application and is not particularly limited, but is preferably 0.01 to 30 mm, more preferably 0.1 to 15 mm.
- the surface of the optical lens of the present invention may be provided with a coating layer such as an antireflection layer or a hard coating layer as necessary.
- the antireflection layer may be a single layer or a multilayer, and may be organic or inorganic, but is preferably inorganic. Specific examples include oxides or fluorides such as silicon oxide, aluminum oxide, zirconium oxide, titanium oxide, cerium oxide, magnesium oxide, and magnesium fluoride.
- the optical lens of the present invention can be used for various lenses such as a pickup lens, f- ⁇ lens, and eyeglass lens.
- SLR cameras digital still cameras, video cameras, mobile phones with cameras, film with lenses, telescopes, binoculars, microscopes, liquid crystal display devices, optical disk devices, projectors, in-vehicle cameras, etc. Is done.
- the optical lens of the present invention is a convex lens, it can be used in combination with other concave lenses, and when it is a concave lens, it can be used in combination with other convex lenses, and each can be used as an optical system with little chromatic aberration. it can.
- the glass transition temperature of the polyester resin was measured using a differential scanning calorimeter (trade name: DSC-60 / TA-60WS, manufactured by Shimadzu Corporation).
- a polyester resin (5 to 10 mg) was placed in an aluminum non-sealed container, heated to 280 ° C. at a temperature rising rate of 20 ° C./min in a nitrogen gas (50 mL / min) stream, and then rapidly cooled to prepare a measurement sample. The sample was heated again under the same conditions, and the temperature (midpoint glass transition temperature) at which the DSC curve changed by half the difference in baseline before and after the transition was defined as the glass transition temperature.
- the water absorption rate of the polyester resin was measured using a disk-shaped press-molded body having a diameter of 40 mm ⁇ and a thickness of 3 mm produced by the method described later as a measurement sample.
- the sample was dried for 48 hours in a vacuum dryer set at a temperature 30 ° C. lower than the glass transition temperature, and then immersed in water at 23 ° C. for 24 hours. A sample was taken out after the lapse of 24 hours, and the water absorption rate was calculated from the weight of the sample before and after water absorption using the following formula (2).
- ⁇ W (W ⁇ W 0 ) / W 0 ⁇ 100 (In the formula (2), ⁇ W represents a water absorption rate [%], W represents a weight [g] after water absorption, and W 0 represents a weight [g] before water absorption).
- Refractive index (nd) and Abbe number ( ⁇ d) The refractive index and Abbe number of the polyester resin were determined by cutting a disk-shaped press-molded body having a diameter of 40 mm ⁇ and a thickness of 3 mm produced by the method described later at a right angle from the center to obtain a glass transition with a dryer. After annealing for 10 hours at a temperature 20 ° C. lower than the temperature, measurement was performed using a precision refractometer (KPR-200, manufactured by Kalnew Optical Industry Co., Ltd.).
- the refractive index was measured at a wavelength of 587.6 nm (d-line), and the Abbe number was as follows from the refractive index measured at wavelengths of 486.1 nm (F-line), 587.6 nm (d-line), and 656.3 nm (C-line). It calculated using Formula (1).
- ⁇ d (nd ⁇ 1) / (nF ⁇ nC) (In the formula (1), ⁇ d is an Abbe number, nF is a refractive index at a wavelength of 486.1 nm, nd is a refractive index at a wavelength of 587.6 nm, and nC is a refractive index at a wavelength of 656.3 nm).
- Photoelastic coefficient A test piece of 1 cm ⁇ 5 cm was cut out from a film produced by the method described later, and used as a measurement sample.
- An ellipsometer (trade name: M220, manufactured by JASCO Corporation) was used to calculate from birefringence measurement with respect to load change at a wavelength of 632.8 nm.
- a film having a thickness of about 100 ⁇ m was prepared by a solution casting method. Specifically, the resin was dissolved in dichloromethane so as to have a concentration of 5 wt%, the resin solution was poured into a mold whose level was confirmed, and dichloromethane was gradually volatilized to produce a film on the mold. The obtained optical film was peeled off from the mold, and then sufficiently dried at a temperature 20 ° C. lower than the glass transition temperature in a dryer.
- a film having a thickness of 150 to 250 ⁇ m was produced by hot press molding. Specifically, 3 g of the resin is placed on the mold, and the press molding machine is set to a temperature 120 to 140 ° C. higher than the glass transition temperature of the resin (only Comparative Example 2 is a temperature 100 ° C. higher than the melting point of the resin). Pressing was performed for 2 minutes under a pressure of ⁇ 100 kgf / cm 2 . After a predetermined time, the mold was quickly moved to a cooling press molding machine through which cooling water was passed, and pressed for 2 minutes under a pressure of 100 kgf / cm 2 . After a predetermined time, the mold was taken out from the cooling press molding machine to obtain a film. In addition, the obtained film was annealed for 10 hours at a temperature 20 ° C. lower than the glass transition temperature in a dryer.
- films that could not be produced by the solution cast method due to the progress of the whitening phenomenon during film formation, poor release from the mold, or insufficient solubility in the solvent, films were produced by hot press molding. .
- reaction solution After performing replacement with nitrogen and a CO / H 2 mixed gas three times, the system was pressurized with a CO / H 2 mixed gas and reacted at 100 ° C. and 2 MPa for 5 hours. After completion of the reaction, the reaction solution was subjected to gas chromatography analysis, and a reaction solution containing 76 g of the compound represented by the formula (3a) and 1.4 g of the monoolefin represented by the formula (4a) (conversion rate 98%, selectivity) 97%), and after purification by distillation, a part was subjected to the following reaction.
- ⁇ Analysis method> 1 Gas chromatography measurement conditions-Analytical apparatus: Capillary gas chromatograph GC-2010 Plus manufactured by Shimadzu Corporation Analytical column: manufactured by GL Science Co., Ltd., InertCap1 (30 m, 0.32 mm ID, film thickness 0.25 ⁇ m -Oven temperature: 60 ° C (0.5 minutes)-15 ° C / min-280 ° C (4 minutes)-Detector: FID, temperature 280 ° C
- Comparative Examples 2 to 5 In Comparative Examples 2 to 5, the following commercially available products were purchased and evaluated. Comparative Example 2: Unipet (registered trademark) RT-553C (manufactured by Nippon Unipet Co., Ltd.) Comparative Example 3: Eastar (registered trademark) 5011 (manufactured by Eastman Chemical) Comparative Example 4: Acripet (registered trademark) VH000 (manufactured by Mitsubishi Chemical Corporation) Comparative Example 5: Iupilon (registered trademark) S-2000 (manufactured by Mitsubishi Engineering Plastics)
- the optical lens of the present invention has low water absorption and is excellent in heat resistance, transparency, and optical characteristics (refractive index, Abbe number, photoelastic coefficient). Therefore, the optical lens of the present invention can be suitably used in fields where glass lenses such as cameras, telescopes, binoculars, and television projectors have been used, and is extremely useful.
- the optical lens of the present invention can also be used as an aspheric lens. Furthermore, various optical systems can be formed by combining with other optical lenses.
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Abstract
Description
ここで、引張応力がかかっている方向(ポリマー鎖の配向方向)に対して、平行方向に屈折率が大きくなる場合は「光弾性複屈折は正」、直行する方向に屈折率が大きくなる場合は「光弾性複屈折は負」と表現する。
下記一般式(1)で表される単位(A)を含むポリエステル樹脂からなる光学レンズ。
前記一般式(1)におけるnが1である、[1]に記載の光学レンズ。
前記一般式(1)におけるR1、R2、及びR3が水素原子である、[1]又は[2]に記載の光学レンズ。
前記ポリエステル樹脂が下記(1)~(6)のいずれか一つ以上を満たす、[1]~[3]のいずれか一項に記載の光学レンズ。
(1)前記ポリエステル樹脂のガラス転移温度が120℃以上である。
(2)前記ポリエステル樹脂の降温時結晶化発熱量が5J/g以下である。
(3)前記ポリエステル樹脂の24時間後の吸水率が0.25%以下である。
(4)前記ポリエステル樹脂の光弾性係数の絶対値が40×10-12Pa-1以下である。
(5)前記ポリエステル樹脂の屈折率(nd)が1.60以下である。
(6)前記ポリエステル樹脂のアッベ数(νd)が28以上である。
前記光学レンズが非球面レンズである、[1]~[4]のいずれか一項に記載の光学レンズ。
前記光学レンズがカメラ用である、[1]~[4]のいずれか一項に記載の光学レンズ。
本実施形態の光学レンズは、下記一般式(1)で表される単位(A)(以下、「単位(A)」、「構成単位(A)」ともいう。)を含むポリエステル樹脂からなる。また、該樹脂は、必要に応じて、ジオール単位(B)(以下、「単位(B)」、「構成単位(B)」ともいう。)、及びジカルボン酸又はそのエステル形成性誘導体単位(C)(以下、「単位(C)」、「構成単位(C)」ともいう。)を含む。
上記した単位は、1種を単独で含まれていてもよく、2種以上を組み合わせて含まれていてもよい。
上記した単位は、1種を単独で含まれていてもよく、2種以上を組み合わせて含まれていてもよい。
ポリエステル樹脂は、単位(A)を単独重合することにより、また、単位(A)~(C)に対応する各単量体を共重合することにより、得ることができる。以下、単位(A)に対応する単量体の製造方法について説明する。かかる単量体は、例えば、下記一般式(2)で表される。
式(2)において、R1は、好ましくは水素原子又はCH3である。R2及びR3は、好ましくは水素原子である。上記炭化水素基としては、以下に限定されないが、例えば、メチル基、エチル基、プロピル基、ブチル基、ビニル基、2-ヒドロキシエチル基、4-ヒドロキシブチル基等が挙げられる。
前記一般式(4)で表される炭素数13~21のモノオレフィンは、例えば、官能基を有するオレフィンとジシクロペンタジエンのディールスアルダー反応を行うこと等で製造することが可能である。
以上の観点から、例えば、上記式(I)に示す反応ルートにおいて、1段目ディールスアルダー反応の反応条件を適宜制御することにより、式(4)で表される炭素数13~21のモノオレフィンあるいは式(7)で表される炭素数8~16のモノオレフィンを選択的に得ることができる。
なお、反応溶媒として炭化水素類やアルコール類、エステル類等を使用することも可能であり、炭素数6以上の脂肪族炭化水素類、シクロヘキサン、トルエン、キシレン、エチルベンゼン、メシチレン、プロパノール、ブタノール等が好ましい。また、必要に応じて、AlCl3等公知の触媒を添加してもよい。
前記式(I)中の一般式(3)で表される炭素数14~22の二官能性化合物は、例えば、一般式(4)で表される炭素数13~21モノオレフィンと一酸化炭素及び水素ガスをロジウム化合物、有機リン化合物の存在下でヒドロホルミル化反応させること等で製造することができる。
前記式(I)中の一般式(2)で表される炭素数14~22の化合物は、一般式(3)で表される炭素数14~22の化合物を、水素化能を有する触媒及び水素の存在下で還元することにより製造することが出来る。
本発明の光学レンズは、例えば、カメラ、ビデオカメラ等に使用する撮像レンズ;プロジェクションテレビ、プロジェクションスクリーン等に使用する投影用レンズ;レーザープリンターに使用するfθレンズやマイクロレンズアレイ、液晶表示装置、光ディスク装置、車載用カメラ等に使用されるレンズである。
(1)共重合組成
ポリエステル樹脂の共重合組成は、1H-NMR及び13C-NMRを測定し、各構成単位由来のピーク面積比から算出した。測定装置は核磁気共鳴装置(ブルカー・バイオスピン(株)製、商品名:AVANCE III 500/Ascend 500)を使用し、500MHzで測定した。溶媒には重クロロホルムを用いた。
ポリエステル樹脂のガラス転移温度は、示差走査熱量計((株)島津製作所製、商品名:DSC-60/TA-60WS)を使用して測定した。ポリエステル樹脂5~10mgをアルミニウム製非密封容器に入れ、窒素ガス(50mL/分)気流中、昇温速度20℃/分で280℃まで昇温後、急冷して測定用試料とした。該試料を同条件で再度昇温し、DSC曲線が転移前後における基線の差の1/2だけ変化した際の温度(中間点ガラス転移温度)をガラス転移温度とした。
ポリエステル樹脂の降温時結晶化発熱量は、上記Tgを測定後280℃で1分間保持した後、5℃/分の速度で降温した際に現れる発熱ピークの面積から算出した。
ポリエステル樹脂の吸水率は、後述の方法にて作製した直径40mmφ、厚さ3mmの円盤形プレス成形体を測定用試料として測定した。試料をガラス転移温度より30℃低い温度に設定した真空乾燥機で48時間乾燥した後、23℃の水中に24時間浸漬した。24時間経過後に試料を取り出し、吸水前後の試料の重量から、下記式(2)を用いて吸水率を算出した。
(式(2)中、ΔWは吸水率[%]、Wは吸水後の重量[g]、W0は吸水前の重量[g]を示す)。
ポリエステル樹脂の屈折率及びアッベ数は、後述の方法にて作製した直径40mmφ、厚さ3mmの円盤形プレス成形体を中央から直角に切出して測定用試料とし、該試料を乾燥機にてガラス転移温度より20℃低い温度で10時間アニール処理した後、精密屈折計(カルニュー光学工業(株)製、KPR-200)を用いて測定した。屈折率は波長587.6nm(d線)で測定し、アッベ数は波長486.1nm(F線)、587.6nm(d線)、及び656.3nm(C線)で測定した屈折率から下記式(1)を用いて算出した。
(式(1)中、νdはアッベ数、nFは波長486.1nmにおける屈折率、ndは波長587.6nmにおける屈折率、nCは波長656.3nmにおける屈折率を示す)。
金型に樹脂を6.0~6.5g乗せ、樹脂のガラス転移温度より40~50℃高い温度(比較例2のみ、樹脂の融点より100℃高い温度)に設定したプレス成形機にて、100kgf/cm2の圧力下、2分間プレスを行った。所定時間経過後、冷却水を通水した冷却用プレス成形機に速やかに金型を移動し、100kgf/cm2の圧力下、2分間プレスを行った。所定時間経過後、冷却用プレス成形機から金型を取り出し、プレス成形体を得た。
後述の方法にて作製したフィルムから1cm×5cmの試験片を切出し、測定用試料とした。エリプソメーター(日本分光(株)製、商品名:M220)を使用し、波長632.8nmにおける荷重変化に対する複屈折測定から算出した。
<実施例1~5及び比較例4>
溶液キャスト法にて厚さ約100μmのフィルムを作製した。具体的には、樹脂をジクロロメタンに5wt%濃度となるように溶解させ、水平を確認した金型に樹脂溶液を流し込み、徐々にジクロロメタンを揮発させて、金型上にフィルムを作製した。得られた光学フィルムは、金型から剥離した後、乾燥機にてガラス転移温度より20℃低い温度で十分に乾燥を実施した。
熱プレス成形にて厚さ150~250μmのフィルムを作製した。具体的には、金型に樹脂を3g乗せ、樹脂のガラス転移温度より120~140℃高い温度(比較例2のみ、樹脂の融点より100℃高い温度)に設定したプレス成形機にて、50~100kgf/cm2の圧力下、2分間プレスを行った。所定時間経過後、冷却水を通水した冷却用プレス成形機に速やかに金型を移動し、100kgf/cm2の圧力下、2分間プレスを行った。所定時間経過後、冷却用プレス成形機から金型を取り出し、フィルムを得た。
なお、得られたフィルムは、乾燥機にてガラス転移温度より20℃低い温度で10時間アニール処理を実施した。
500mLステンレス製反応器にアクリル酸メチル173g(2.01mol)、ジシクロペンタジエン167g(1.26mol)を仕込み195℃で2時間反応を行った。上記反応により、下記式(4a)で表されるモノオレフィン96gを含有する反応液を取得し、これを蒸留精製した後、一部を以下の反応に供した。
モノマー合成例で取得した成分のNMR分析を行った。NMRスペクトルを図1~3に示す。以下に示すGC-MS分析、及び図1~3のNMR分析の結果から、モノマー合成例で得られた主生成物は、前記式(2a)で表される化合物であることが確認された。
1)ガスクロマトグラフィー測定条件
・分析装置 :株式会社島津製作所製 キャピラリガスクロマトグラフGC-2010 Plus
・分析カラム :ジーエルサイエンス株式会社製、InertCap1(30m、0.32mmI.D.、膜厚0.25μm
・オーブン温度:60℃(0.5分間)-15℃/分-280℃(4分間)・検出器 :FID、温度280℃
・分析装置 :株式会社島津製作所製、GCMS-QP2010 Plus
・イオン化電圧:70eV
・分析カラム :Agilent Technologies製、DB-1(30m、0.32mmI.D.、膜厚1.00μm)
・オーブン温度:60℃(0.5分間)-15℃/分-280℃(4分間)
・装置 :日本電子株式会社製,JNM-ECA500(500MHz)
・測定モード :1H-NMR、13C-NMR、COSY-NMR
・溶媒 :CDCl3(重クロロホルム)
・内部標準物質:テトラメチルシラン
<実施例1~5>
撹拌機、加熱装置、窒素導入管、及びコールドトラップを備えた小型ポリエステル製造装置に、表1に記載の量の原料モノマー及びチタン(IV)テトラブトキシドを仕込み、窒素雰囲気下、240~250℃まで昇温し、撹拌した。該温度にて5時間以上保持した後、昇温と減圧を徐々に行い、最終的に260~270℃、0.1kPa以下で保持した。適度な溶融粘度となった時点で装置内に窒素を吹き込んで常圧とし、生成したポリエステル樹脂を回収した。
ポリエステル樹脂の評価結果を表1に示す。
撹拌機、加熱装置、窒素導入管、分縮器、全縮器、及びコールドトラップを備えたポリエステル製造装置に、表1に記載の量の原料モノマー及びオクチル酸スズ(II)を仕込み、窒素雰囲気下、240~250℃まで昇温し、撹拌した。該温度にて5時間以上保持した後、昇温と減圧を徐々に行い、最終的に260~270℃、0.1kPa以下で保持した。適度な溶融粘度となった時点で装置内に窒素を吹き込んで常圧とし、生成したポリエステル樹脂を回収した。
ポリエステル樹脂の評価結果を表1に示す。
比較例2~比較例5は、下記の市販品を購入し、評価を行った。
・比較例2:ユニペット(登録商標) RT-553C(日本ユニペット(株)製)
・比較例3:Eastar(登録商標) 5011(Eastman Chemical社製)
・比較例4:アクリペット(登録商標) VH000(三菱ケミカル(株)製)
・比較例5:ユーピロン(登録商標) S-2000(三菱エンジニアリングプラスチックス(株)製)
D-NHEs:デカヒドロ-1,4:5,8-ジメタノナフタレン-2-メトキシカルボニル-6(7)-メタノール
DMCD:1,4-シクロヘキサンジカルボン酸ジメチル(シス体/トランス体=7/3)
DMT:テレフタル酸ジメチル
CHDM:1,4-シクロヘキサンジメタノール(シス体/トランス体=3/7)
EG:エチレングリコール
BPEF:9,9-ビス(4-(2-ヒドロキシエトキシ)フェニル)フルオレン(「ビスフェノキシエタノールフルオレン」ともいう)
PMMA:ポリメチルメタクリレート
BPA-PC:ビスフェノールAからなるポリカーボネート樹脂
Claims (7)
- 前記一般式(1)におけるnが1である、請求項1に記載の光学レンズ。
- 前記一般式(1)におけるR1、R2、及びR3が水素原子である、請求項1又は2に記載の光学レンズ。
- 前記ポリエステル樹脂が下記(1)~(6)のいずれか一つ以上を満たす、請求項1~3のいずれか一項に記載の光学レンズ。
(1)前記ポリエステル樹脂のガラス転移温度が120℃以上である。
(2)前記ポリエステル樹脂の降温時結晶化発熱量が5J/g以下である。
(3)前記ポリエステル樹脂の24時間後の吸水率が0.25%以下である。
(4)前記ポリエステル樹脂の光弾性係数の絶対値が40×10-12Pa-1以下である。
(5)前記ポリエステル樹脂のd線波長光に対する屈折率(nd)が1.60以下である。
(6)前記ポリエステル樹脂のアッベ数(νd)が28以上である。 - 前記光学レンズが非球面レンズである、請求項1~4のいずれか一項に記載の光学レンズ。
- 前記光学レンズがカメラ用である、請求項1~4のいずれか一項に記載の光学レンズ。
- 請求項1~6のいずれか一項に記載の光学レンズと、他の光学レンズを組み合わせてなる、光学系。
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EP3521867A1 (en) | 2019-08-07 |
EP3521867A4 (en) | 2019-08-07 |
CN109642962B (zh) | 2022-07-08 |
TWI749070B (zh) | 2021-12-11 |
JP6961175B2 (ja) | 2021-11-05 |
US20200031990A1 (en) | 2020-01-30 |
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