WO2018051983A1 - 繊維詰め物体およびそれを用いた繊維製品 - Google Patents
繊維詰め物体およびそれを用いた繊維製品 Download PDFInfo
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- WO2018051983A1 WO2018051983A1 PCT/JP2017/032898 JP2017032898W WO2018051983A1 WO 2018051983 A1 WO2018051983 A1 WO 2018051983A1 JP 2017032898 W JP2017032898 W JP 2017032898W WO 2018051983 A1 WO2018051983 A1 WO 2018051983A1
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- Prior art keywords
- yarn
- fiber
- bulky
- stuffed
- bulkiness
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/06—Thermally protective, e.g. insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B68—SADDLERY; UPHOLSTERY
- B68G—METHODS, EQUIPMENT, OR MACHINES FOR USE IN UPHOLSTERING; UPHOLSTERY NOT OTHERWISE PROVIDED FOR
- B68G1/00—Loose filling materials for upholstery
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B68—SADDLERY; UPHOLSTERY
- B68G—METHODS, EQUIPMENT, OR MACHINES FOR USE IN UPHOLSTERING; UPHOLSTERY NOT OTHERWISE PROVIDED FOR
- B68G11/00—Finished upholstery not provided for in other classes
- B68G11/02—Finished upholstery not provided for in other classes mainly composed of fibrous materials
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2500/00—Materials for garments
- A41D2500/30—Non-woven
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
Definitions
- the present invention relates to a fiber-stuffed object composed of stuffed cotton and side fabric made of synthetic fiber, and a fiber product using the same.
- Natural material feathers and stuffed cotton made of synthetic fibers are generally widely used as fillers for heat-resistant clothing.
- natural feathers are a mixture of downballs (grain-like) and feathers (feathers) that are generally collected in small quantities from the waterfowl's chest.
- Natural feathers are derived from a specific structural form of keratin fibers, rich in supple texture, easy to follow along with the body, and exhibit excellent lightness and heat retention. For this reason, products using natural feathers as stuffed cotton have been recognized by ordinary users for their functions, and are widely applied to clothing such as bedding and jackets.
- padded cotton using natural feathers has heat retention when dried, but not only rain or snow but also “wetting” that occurs during actions such as sweat and moisture can greatly reduce the heat retention, It has been known for a long time that the heat retention is very poor because feathers lack rapid drying. For this reason, it is possible to demonstrate a certain degree of heat retention even when wet, and because it has excellent quick-drying properties after being wet, it is possible to quickly recover from ⁇ wetting '' where heat retention is reduced.
- the stuffed cotton is required by the market.
- Patent Document 1 discloses a stuffed product in which long-fiber stuffed cotton and side fabrics in which flower yarns are integrated with a core yarn are sewn and integrated.
- Patent Document 2 discloses a technique in which an excessively supplied yarn is fixed with a yarn length difference by injecting compressed air from a direction perpendicular to a traveling yarn in an entanglement nozzle to open and entangle the yarn. It is disclosed.
- the stuffed cotton made of synthetic fibers of Patent Document 1 and Patent Document 2 cannot be compared with natural feathers in terms of supple texture and lightness (bulkyness), and may be sweaty when wet or sports.
- supple texture and lightness bulkyness
- the thermal insulation is reduced at a stretch because the feeling of swelling is lost like a feather.
- Patent Document 3 a sheet-like stuffed cotton in which short fibers are laminated has been proposed.
- JP 2012-67429 A (Claims) JP 2012-67430 A (Claims) JP 2013-136858 A (Claims)
- the stuffed cotton of Patent Document 3 lacks a supple texture, lightness (bulkyness), and is said to have a heat retaining function even when wet, but still expects high heat retention when wet. The current situation is not possible.
- the present inventors have found that the stuffed cotton of Patent Document 3 has little fine space (dead air) inside the stuffed cotton, and therefore lacks a supple texture and lightness (bulkyness). I was occupied by water and thought that high heat retention could not be expected.
- An object of the present invention is a synthetic fiber that has a lot of fine space, is excellent in bulkiness at the time of drying, has a supple texture, a lightweight feeling, and maintains heat retention even when wet. It is to provide a stuffed cotton and a fiber product using the same.
- the fiber-stuffed object of the present invention is a fiber-stuffed object composed of a stuffed cotton made of synthetic fiber and a side fabric, and the stuffed cotton made of synthetic fiber has (1) a fineness ratio (sheath) of core yarn to sheath yarn. / Core) is 0.5 to 2.0, (2) the entanglement point of the core yarn and the sheath yarn is 1 to 30 pieces / mm in the fiber axis direction, and (3) the sheath yarn forming a loop It is characterized by comprising a bulky yarn having a curvature radius of 2.0 to 30.0 mm.
- the textile product of the present invention is characterized in that the fiber-stuffed object of the present invention is used in at least a part.
- the fiber-filled object of the present invention has many fine spaces, is excellent in bulkiness when dried, has a supple texture and light weight, and retains heat retention even when wet. Therefore, it is possible to apply in a wide range of fields from clothing use to industrial use.
- the fiber stuffed object of the present invention is composed of stuffed cotton made of synthetic fiber and a side fabric.
- the bulky yarn used for the stuffed cotton made of the synthetic fiber of the present invention is made of synthetic fiber and has a bulky structure.
- This bulky structure is composed of a sheath yarn that forms a loop and a core yarn that substantially fixes the sheath yarn by being entangled with the sheath yarn, and the sheath yarn has a three-dimensional crimped structure. It is characterized by being.
- the synthetic fiber refers to a fiber made of a synthetic polymer, and refers to a synthetic fiber manufactured by melt spinning or solution spinning.
- a thermoplastic polymer that can be melt-molded can be made into a fiber by a melt spinning method, and the fiber can be produced with high productivity. Therefore, it is preferably used in the present invention.
- thermoplastic polymer here means, for example, polyethylene terephthalate or a copolymer thereof, polyethylene naphthalate, polybutylene terephthalate, polytrimethylene terephthalate, polypropylene, polyolefin, polycarbonate, polyacrylate, polyamide, polylactic acid, thermoplastic polyurethane, etc. And a melt moldable polymer.
- thermoplastic polymers polycondensation polymers represented by polyesters and polyamides are crystalline polymers, and since they have a high melting point, they were heated at a relatively high temperature during post-processing, molding and actual use. Even in the case, there is no deterioration or settling, which is preferable. From the viewpoint of heat resistance, it is preferable that the melting point of the polymer is 165 ° C. or higher.
- additives such as inorganic materials such as titanium oxide, silica and barium oxide, colorants such as carbon black, dyes and pigments, flame retardants, fluorescent brighteners, antioxidants, and ultraviolet absorbers are used in the polymer used in the present invention.
- An agent may be included in the polymer.
- the fineness ratio of the sheath yarn to the core yarn is 0.5 to 2.0.
- the fineness of the sheath yarn and the core yarn are close to each other, and it can be used without feeling a sense of foreign matter when compressed.
- the fineness ratio (sheath / core) of the core yarn and the sheath yarn can be 0.7 to 1.5, and the effect of the present invention is more remarkable. More preferable in terms.
- the core yarn and the sheath yarn are simple in that they do not feel the above-mentioned efficient fluid processing and the feeling of foreign matter when compressed. It is preferable that the fibers have the same yarn fineness and mechanical properties. Specifically, in the present invention, it is preferable to prepare two or more drums produced under the same yarn making conditions and use them for the core yarn and the sheath yarn.
- the core yarn and the sheath yarn are preferably single fibers made of one type (single) resin.
- the size of the above-mentioned three-dimensional crimp is in the micron order where latent shrinkage collected by a general production method such as conventional side-by-side composite fiber or hollow fiber is developed. It is preferable to be in the order of millimeters (10 ⁇ 3 m) rather than (10 ⁇ 6 m).
- the bulkiness and resilience of the processed yarn in the circumferential direction and the cross-sectional direction can be freely controlled by the size of the three-dimensional crimp. It is also possible to suppress entanglement of yarns, which is one of the objects of the invention.
- the size of the crimp to the millimeter order (10 ⁇ 3 m), it is excellent mainly from the viewpoint of balance between the bulkiness of the yarn and the compression recovery property, as well as the suppression of the entanglement of the yarn.
- the bulky yarn used in the stuffed cotton of the present invention is composed of a sheath yarn 1 that forms a loop and a core yarn 2 that substantially fixes the yarn by being intertwined with the yarn. .
- a point where the sheath yarn 1 and the core yarn 2 are entangled is called an entanglement point, and the entanglement point has a role of supporting the self-supporting of the loop made of the yarn, which is a feature of the present invention, and exists at a certain period. Is preferred.
- the entanglement points are preferably 3 to 30 / mm, more preferably 5 to 15 / mm.
- the nozzle is not particularly limited as long as the effect can be achieved.
- a suction nozzle which will be described later, running on a thread in the nozzle, and further rotating the thread sucked by the suction nozzle outside the nozzle, the sheath thread is entangled like wrapping around the core thread Form a form.
- a general interlace nozzle or Taslan nozzle it will give the effect of stirring, opening and entanglement of the yarn in the nozzle, and it is difficult to achieve the entanglement number of the present invention. Absent.
- the excessively supplied yarn forms a bulky yarn in which a large loop is formed in the outer layer.
- a photoelectric fluff detection device In order to determine the core yarn and sheath yarn and to continuously evaluate the number of loops per unit length in the fiber axis direction of the processed yarn, a photoelectric fluff detection device can be used. For example, using a photoelectric fluff measuring machine (TORAY FRAY COUNTER), 0.6 mm and 1.0 mm from the yarn surface may be evaluated under conditions of a yarn speed of 10 m / min and a running yarn tension of 0.1 cN / dtex.
- TORAY FRAY COUNTER photoelectric fluff measuring machine
- the bulky yarn used in the stuffed cotton of the present invention is characterized by a three-dimensional crimped structure, that is, a spiral structure, and the curvature radius of the yarn is 2.0 to 30.0 mm.
- the radius of curvature of the spiral structure referred to here is an image observed two-dimensionally by a digital microscope or the like in two or more places in the three-dimensional crimp 3 formed by the fiber having the spiral structure in FIG. It corresponds to the radius of the most inscribed circle.
- the radius of curvature is more preferably from 2.0 mm to 20.0 mm, and within such a range, it means that the large loop made of the sheath yarn has a spring-like crimp. For this reason, the sheath yarn comes into contact with a point while having an appropriate repulsion feeling against the compression in the cross-sectional direction of the bulky yarn, and a very comfortable bulkiness is achieved.
- the range in which the effect of the present invention is exhibited well is particularly preferably 3.0 mm to 15.0 mm. In such a range, there is no problem with long-term durability, and the effect of the present invention is effective when applied to garment applications where repeated compression recovery is applied, particularly sports garments used in harsh environments.
- the processed yarn By heat-treating the processed yarn in which this large loop is formed in the outer layer with reference to the crystallization temperature of the polymer using the processed yarn, the processed yarn expresses a three-dimensional shrinkage. Become. This three-dimensional crimp of the yarn expresses good bulkiness in both the circumferential direction and the cross-sectional direction of the processed yarn, and is suitably controlled according to the desired characteristics. . From the viewpoint of controlling the expression of crimp after the heat treatment, the fiber used in the present invention is preferably a latent crimp fiber.
- the latent crimped fiber is in a straight form before the heat treatment, and the crimp appears after the heat treatment.
- the speed of the cooling air at the time of spinning is 15 m / min or more, the radius of curvature of the sheath yarn forming the loop of the fluid processed yarn of the present invention is 30 mm or less. Therefore, the speed of the cooling air at the time of spinning is 15 m / min.
- the speed of the cooling air during spinning exceeds 100 m / min, yarn swaying will occur and this will contribute to deterioration of operability such as yarn breakage. Therefore, the speed of the cooling air during spinning will exceed 100 m / min. Is not preferred.
- the fiber-stuffed object of the present invention is a fiber-stuffed object composed of a stuffed cotton made of synthetic fiber and a side fabric, and the stuffed cotton made of synthetic fiber is (1)
- the fineness ratio of the core yarn to the sheath yarn (sheath / core) is 0.5 to 2.0
- the entanglement point between the core yarn and the sheath yarn is 1-30 pieces / mm in the fiber axis direction
- the radius of curvature of the sheath yarn forming the loop is 2.0 to 30.0 mm. It consists of bulky yarn.
- the fiber having a three-dimensional crimped structure used in the present invention is preferably a hollow section fiber.
- the density of the yarn (weight per unit volume) is lower from the viewpoint of light weight and heat retention. Therefore, fibers having a hollow cross section are preferably used. From the viewpoint of lightness of the yarn, a hollow cross-section fiber having a hollow ratio of 20% or more is more preferable.
- the hollow ratio refers to two-dimensional imaging at a magnification at which ten or more fibers can be observed with an electron microscope (SEM) after cutting a hollow cross-section fiber.
- SEM electron microscope
- Ten randomly selected fibers are extracted from the photographed image, and the areas of the fibers and the hollow portion are measured using image processing software to obtain the area ratio. All the above values were measured for 10 images, and the average value of the 10 images was defined as the hollow ratio of the hollow cross-section fiber of the present invention.
- the side surface of the fiber is observed with a microscope or the like, and the fiber diameter in terms of a round section is measured from the image. It is also possible to calculate the hollowness ratio by evaluating the ratio of the actually measured fineness (measured weight) to the fineness (converted weight) converted as a solid fiber from the fiber diameter.
- the hollow ratio is preferably that the bulky yarn has an air layer from the viewpoint of light weight and heat retention, which is the object of the present invention, and particularly preferably has a hollow ratio of 30% or more. If it is in such a range, it is possible to feel better lightness when holding the processed yarn in a bundle, and it means that it has an air layer with lower thermal conductivity, so it has excellent heat retention. It is.
- the bulky yarn used in the stuffed cotton of the present invention has an excellent bulkiness, and the yarn constituting it preferably has an appropriate resilience.
- the single yarn fineness of the synthetic fiber to be constituted is preferably 3.0 dtex or more.
- such a resilience provides a space between fibers, that is, it can create a lot of fine air layers, so that the resilience contributes to a lightweight feeling and, in turn, a heat retaining property.
- the constituting filaments preferably have appropriate rigidity, and the single yarn fineness is more preferably 6.0 dtex or more.
- the fineness mentioned here is a value calculated from the obtained fiber diameter, the number of filaments and the density, or a value calculated from the simple average value obtained by measuring the weight of the unit length of the fiber a plurality of times per 10,000 m. means.
- the bulky yarn of the present invention preferably has a breaking strength of 0.5 to 10.0 cN / dtex, an elongation of 5 to 700%, and a Young's modulus of 8 to 13 Gpa.
- the breaking strength is a value obtained by obtaining a load-elongation curve of a processed yarn under the conditions shown in JIS L1013 (1999) and dividing the load value at the time of breaking by the initial fineness.
- the elongation is a value obtained by dividing the elongation at break by the initial test length.
- the Young's modulus is a stress that causes 100% elastic strain, that is, a stress that causes 100% elastic recovery.
- the breaking strength of the bulky yarn of the present invention is preferably 0.5 cN / dtex or more in order to be able to withstand the process passability and actual use of the high-order processing step, and the upper limit that can be implemented. Is 10.0 cN / dtex.
- the elongation is preferably 5% or more in consideration of the processability of the post-processing process, and the upper limit that can be implemented is 700%. Since the Young's modulus represents the flexibility of the yarn, it represents the flexibility of the stuffed cotton made of the bulky yarn, that is, the compression elasticity. When the Young's modulus is 8 Gpa or less, the yarn is too soft to achieve a practical level of bulkiness. A Young's modulus of 13 Gpa or more is not preferable because the yarn is hard and the compression elasticity of cotton is high, so that the flexibility is insufficient. Further, the Young's modulus is preferably 8 to 12 Gpa.
- the breaking strength and elongation can be adjusted by controlling the conditions in the manufacturing process according to the intended application.
- the breaking strength is preferably 0.5 to 4.0 cN / dtex.
- the breaking strength is 1.0 to 6.0 cN / dtex.
- the stuffed cotton of the present invention by using the bulky yarn, air due to a lot of fine spaces can be contained between the single fibers of the yarn, and a three-dimensional crimped form can be maintained. It is possible to achieve stuffed cotton that has a supple texture, light weight, and excellent compression recovery.
- the bulkiness indicating the lightweight property, the compression height indicating the compression recovery rate, and the recovery height are all indices indicating the volume including the air layer under a constant load. That is, there is a feeling of lightness, so that the numerical value of bulkiness is large.
- the higher the compression height the softer the texture.
- the higher the recovery height the better the recovery after compression and the more the cotton becomes more elastic.
- the bulky yarn of the present invention is excellent in the initial bulkiness of the stuffed object when it is made into a stuffed object, and even if it is repeatedly compressed and recovered during use, it is restored to its original bulkiness without sagging. I found that I can do it. Because the sheath yarn, which is responsible for the initial bulkiness and recoverability at the time of compression, has resilience due to the crimped structure, it will be excellent in the above-mentioned compression recovery, and when used for a long time But it can maintain a good feeling of swelling.
- the bulky yarn of the present invention having three-dimensional crimps could create a lot of fine spaces inside the stuffed cotton.
- the bulky yarn of the present invention has (2) entanglement points of the core yarn and sheath yarn in the fiber axis direction of 1 to 30 pieces / mm, and (3) the radius of curvature of the sheath yarn forming the loop is 2 Since it has a characteristic of ⁇ 30 mm, the stuffed cotton made of the bulky yarn can maintain the state of opening in the radial direction in the cross-sectional direction of the processed yarn as well as the initial bulkiness (FIG. 1).
- the spring-like behavior of the radially opened sheath yarn of the present invention is difficult to achieve with conventional straight filaments.
- the spring-like behavior of the radially opened sheath yarn of the present invention is born when the sheath yarns repel each other, and the sheath yarns having three-dimensional crimps are mutually attached. By supporting each other, the settling of the sheath yarn can be greatly suppressed.
- the three-dimensional crimped structure also has the above-mentioned Young's modulus.
- One of the effects of the present invention is that the bulkiness is hardly lowered. That is, since the bulkiness of the stuffed cotton is maintained even when it gets wet, the heat retaining property is also maintained by including many fine spaces.
- the three-dimensional crimped structure is good for drainage because water droplets in the stuffed cotton easily flow. As described later, it was found to be very excellent in bulkiness and drying speed when wet, and to have excellent characteristics when used in various applications as a stuffed object.
- Such a bulky yarn can also be obtained by applying a processed yarn processed for the purpose of increasing the added value of the fiber.
- a processed yarn processed for the purpose of increasing the added value of the fiber is mixed by a fluid processing nozzle or the like.
- the bulky yarns can be inserted one by one into the side ground, but as a filling form, it is preferable to form a sheet bundle with a form of several to several tens of yarn bundles or side by side. .
- this sheet-like material is used, it is easy to fill the side, and it is easy to adjust the filling amount according to the application, so it becomes a thin, lightweight, heat-insulating material, and does not come out of the side. Unnecessary sewing is not necessary. For this reason, there is no restriction
- Wadding with bulky yarn of the present invention the bulkiness as measured by the measurement method described later, 7000 cm 3/30 g or more, and the compression ratio is 70% or more, and a recovery rate of 50% or more. Thereby, a more excellent light weight feeling and a more supple texture can be achieved.
- bulkiness particularly preferably 13120cm 3 / 30g or less.
- the form of stuffed cotton used in the present invention may be a spherical or radial grain cotton mainly composed of short fibers, a fiber web, a sheet-like cotton, or a bulky thread mainly composed of long fibers.
- a characteristic that was found effective for long-time use or wet use that is expected in actual use was discovered.
- Bulky yarns mainly composed of fibers are preferred.
- the dry state here refers to the state when the official moisture content of the fiber is reached, not the absolute dry state. In general, if 48 hr is left in an environment of a temperature of 20 ° C. and a humidity of 65%, the official moisture content of the fiber can be reached. In the case of polyester, the official moisture content is 0.3%.
- the washing method when evaluating the stuffed object of the present invention by the washing method, it is preferable to use a fine mesh net or a side fabric made of woven or knitted fabric. Although it is not particularly limited as long as it has a structure in which the cotton pad is not exposed to the outside during washing, especially dehydration, the use of the side fabric made of woven or knitted fabric is more preferable from the viewpoint that the cotton pad is difficult to expose. .
- the fiber-stuffed object of the present invention maintains a three-dimensional structure of bulky yarns even in a wet state compared to a dry state, and has a low rate of decrease in bulkiness. Even if it gets wet in harsh sports such as mountain climbing, bulkiness is unlikely to decrease.
- the bulkiness referred to here is directly proportional to the heat retention. That is, the high bulkiness means that there is a lot of dead air (immovable air) in the stuffed object, and the heat conductivity of the air is low, so that the heat retention is also high.
- the dry state refers to a state after the stuffed object of the present invention is left in an environment of a temperature of 20 degrees and a humidity of 65% for 48 hours.
- fiber filling objects wash repeated 5 times of the present invention, bulky in the dry state 6500 cm 3/30 g or more, the compression height showing a compression recovery rate is 60mm or more, and a recovery height is 40mm or more . More preferred is, even if the washing repeated 5 times, bulky dry state is 6700cm 3 / 30g or more. In consideration of charging efficiency of bulky yarn productivity and wadding, be laundered repeatedly 5 times, bulkiness 13120cm 3 / 30g or less, the compression height is 120mm or less, the recovery height is particularly preferably less than 100mm .
- the bulkiness reduction of 50% moisture content is less than 0.3. More preferred is less than 0.28.
- the lower limit of the bulkiness lowering property is not particularly set, but considering that the moisture does not reach all the three-dimensional structure of the sheath yarn that controls the bulkiness, the bulkiness lowering property is preferably 0.05 or more.
- the bulkiness reduction of 35% moisture content is less than 0.2.
- the lower limit of the bulkiness lowering property is not particularly set, but considering that the moisture does not reach all the three-dimensional structure of the sheath yarn that controls the bulkiness, the bulkiness lowering property is preferably 0.05 or more.
- the present invention reduces the decrease in bulkiness even when the stuffed cotton is wet. It was found that can be demonstrated.
- the sheath yarn that controls bulkiness has a three-dimensional crimped structure, and as described above, the size of the three-dimensional crimp is preferably in the order of millimeters (10 ⁇ 3 m). Therefore, moisture easily enters and exits, and even in a wet state, for example, in a state where the moisture content is 50% or 35%, a fine space that does not contain moisture remains, which can greatly contribute to maintaining heat retention.
- the evaluation index of heat retention mentioned here is an integral product of heat consumption (unit: W ⁇ min / ° C. ⁇ m 2 ).
- the calculation method is to calculate the amount of heat consumed when a specific moisture content is reached from a specific moisture content, and to calculate the area with respect to the horizontal axis (time). Integral product (unit: W ⁇ min / ° C ⁇ m 2 ).
- the wet state here refers to a state where sweat is sweated by intense exercise such as sports, and moisture is stuffed and contained in cotton.
- the integral product of the heat consumption when reaching the 5% moisture content from the 50% moisture content is 25 W ⁇ min / ° C. ⁇ m 2 or less.
- the integral product of the heat consumption when reaching the 35% moisture content from the 50% moisture content is 15 W ⁇ min / ° C. ⁇ m 2 or less.
- the sheath yarn that controls bulkiness preferably has a three-dimensional crimped structure, and preferably forms a continuous loop without partial breakage.
- the three-dimensional crimp structure in the present invention is a spiral structure of a single filament filament as illustrated in FIG. 2 and means having a three-dimensional crimp 3.
- this three-dimensional crimp evaluation ten or more single yarns are sampled at 10 points randomly selected from the processed yarns, and the crimped form of each single yarn can be confirmed with a digital microscope or the like. It can be evaluated by observing at a magnification. In this image, if the observed single yarn has a spirally swung form, it is determined that it has a three-dimensional crimped structure, and if it is a straight form, it is crimped. It is determined that there is no structure.
- the size of this three-dimensional crimp is of the micron order (explicit latent yarn collected by a general production method such as a conventional side-by-side composite fiber or hollow fiber). It is preferable to be in the order of millimeters (10 ⁇ 3 m) rather than 10 ⁇ 6 m).
- the bulkiness and resilience of the processed yarn in the circumferential direction and the cross-sectional direction can be freely controlled by the size of the three-dimensional crimp. It is also possible to suppress entanglement of yarns, which is one of the objects of the invention. In particular, by setting the size of the crimp to the millimeter order, it is excellent mainly from the viewpoint of balance between the bulkiness and compressibility of the yarn and the suppression of entanglement between the yarns.
- the bulky yarn of the present invention uniformly adheres a silicone-based oil before use as stuffed cotton.
- the silicone to be adhered here is preferably formed by forming a silicone film on the sheath yarn and the core yarn by appropriately crosslinking by heat treatment or the like.
- the silicone-based oil agent includes dimethylpolysiloxane, hydrogen methylpolysiloxane, aminopolysiloxane, epoxy polysiloxane, and the like, and these may be used alone or in combination.
- a dispersant, a viscosity modifier, a crosslinking accelerator, an antioxidant, a flame retardant, and an antistatic agent are contained within a range that does not impair the purpose of silicone adhesion. be able to.
- silicone oil Even if this silicone oil is straight, it can also be used as an aqueous emulsion, but it is preferable to use it as an aqueous emulsion from the viewpoint of uniform adhesion of the oil.
- the silicone-based oil is preferably treated so that it can be adhered to the bulky yarn in an amount of 0.1 to 5.0 wt% by using an oil guide, oiling roller or spraying. Thereafter, it is preferably dried at an arbitrary temperature and time for a crosslinking reaction.
- This silicone-based oil can be attached in a plurality of times, and it is also preferable to laminate a strong silicone film by attaching the same type of silicone or different types of silicone separately.
- the side fabric used for the fiber-stuffed object of the present invention is not particularly limited, but may be a woven fabric or a knitted fabric.
- One side of the side fabric may be a woven fabric, and one side may be a combination of knitting.
- the woven fabric density there is no particular limitation on the woven fabric density, but if the cover factor, which is the total of the weft yarn density and the warp yarn density, is 1500 or more, the effect of blocking air can be exhibited more preferably.
- attaining 25% moisture content from 50% moisture content of the fiber stuffing object comprised from the stuffing cotton and side fabric of this invention is 50 minutes or less. It has been found that the three-dimensional crimped size of the bulky yarn used in the stuffed cotton of the present invention is on the order of millimeters (10 ⁇ 3 m) and the moisture can easily enter and exit, so that the drying speed is very fast. It has been found that excellent quick-drying can be quickly recovered from intense wetting with reduced heat retention.
- the drying rate referred to here is the time when the fiber-filled object of the present invention reaches a 25% moisture content from a 50% moisture content.
- the bulky yarn used for the stuffed cotton of the present invention has a three-dimensional crimp size of a millimeter order (10 ⁇ 3 m) size, which is greatly improved in the drying speed, specifically 50% It takes 45 minutes or more to reach the 5% moisture content from the moisture content, that is, it is preferably 1.0% (moisture content) / min or more.
- the present invention is preferably a fiber-stuffed object characterized in that the side fabric and stuffed cotton are quilted.
- the quilt stitching method is not particularly limited, the longitudinal direction of the stuffed cotton may be arranged in parallel in the quilt, but may be arranged in perpendicular to the quilt. It is also preferable that both ends of the stuffed cotton and an arbitrary portion in the middle are sewn with a quilt. If it does in this way, the bias
- a preferred side fabric is a fabric having an air permeability of 1.0 cc / cm 2 ⁇ sec or more.
- the dust-packing property of the stuffed cotton of the present invention and the fiber stuffed object composed of the side fabric having an air permeability of 1.0 cc / cm 2 ⁇ sec or more is very small.
- the dust generation property is preferably 100 pieces / minute or less.
- the fiber-stuffed object of the present invention is preferably a fiber product used in at least one part.
- Textile products here are used for daily use such as general clothing, sports clothing, clothing materials, interior products such as carpets, sofas, curtains, vehicle interiors such as car seats, cosmetics, cosmetic masks, wiping cloths, health products, etc. It can be used for environmental and industrial materials such as filters and hazardous substance removal products.
- the fiber-stuffed object of the present invention is excellent in heat retention when wet, so that it is suitable for jackets, pants, and cold clothes for clothing. Furthermore, since quick-drying is excellent, it is suitable for sports applications.
- the core yarn and sheath yarn used in the present invention may be synthetic fibers obtained by fiberizing a thermoplastic polymer by a melt spinning method.
- the spinning temperature when spinning the synthetic fiber used in the present invention is a temperature at which the polymer used exhibits fluidity.
- the temperature indicating the fluidity varies depending on the molecular weight, but the melting point of the polymer is a guideline, and may be set at a melting point + 60 ° C. or lower. If it is less than this, the polymer is not thermally decomposed in the spinneret or the spin pack, and the molecular weight reduction is suppressed, which is preferable.
- the discharge amount may be 0.1 g / min / hole to 20.0 g / min / hole per discharge hole as a range in which the discharge can be stably performed.
- the molten polymer discharged in this manner is cooled and solidified, and is taken up by a roller to which an oil agent is applied and whose peripheral speed is defined, thereby forming a synthetic fiber.
- the take-up speed may be determined from the discharge amount and the target fiber diameter, but is preferably in the range of 100 to 7000 m / min for stable production.
- This synthetic fiber may be stretched after being wound once, or may be continuously stretched without being wound once, from the viewpoint of improving the highly oriented mechanical properties.
- the stretching conditions for example, in a stretching machine composed of a pair of rollers or more, if the fibers are made of a polymer that generally shows a synthetic fiber that can be melt-spun, the first roller that is set to a temperature not lower than the glass transition temperature and not higher than the melting point; By the peripheral speed ratio of the second roller corresponding to the crystallization temperature, the second roller is stretched in the fiber axis direction without difficulty, and is heat set and wound.
- dynamic viscoelasticity measurement (tan ⁇ ) of the composite fiber is performed, and a temperature equal to or higher than the peak temperature on the high temperature side of the obtained tan ⁇ may be selected as the preheating temperature.
- the cross-sectional shape of the synthetic fiber of the present invention is not particularly limited, and by changing the shape of the discharge hole in the spinneret, a general round cross section, a triangular cross section, a Y type, an eight leaf type, a flat type It is possible to make it irregular such as various types and hollow types. Moreover, it does not need to consist of a single polymer, and may be a composite fiber composed of two or more types of polymers. However, from the viewpoint of expressing the three-dimensional crimp of the sheath yarn, which is an important requirement of the present invention, among the above, a side-by-side type composite fiber in which a hollow cross section and two kinds of polymers are bonded is used. Is appropriate.
- the bulky yarn of the present invention is a suction nozzle (9 in FIG. 3) capable of supplying a predetermined amount of the above-mentioned synthetic fiber (8 in FIG. 3) by a supply roller (7 in FIG. 3) having a nip roller or the like and jetting compressed air. ) Is the first step of sucking the core yarn and the sheath yarn.
- the flow rate of compressed air ejected from the nozzle is such that the yarn inserted from the supply roller into the nozzle has the minimum necessary tension, and the yarn swings between the supply roller and the nozzle and within the nozzle. What is necessary is just to inject
- the optimum flow rate of the compressed air changes depending on the hole diameter of the suction nozzle to be used.
- the range in which the yarn tension can be applied and the formation of a large loop, which will be described later, can be made smoothly is that the air velocity in the nozzle is 100 m / s or more.
- a guideline for the upper limit value of the air flow speed is 700 m / s or less, and if it is within such a range, the traveling yarn does not cause yarn swaying due to excessively injected compressed air, and the nozzle can be stably formed. You will be traveling inside.
- the jetting angle of compressed air (16 in FIG. 4) is preferably a propulsion jet that is jetted at less than 60 ° with respect to the running yarn. It is preferable from the viewpoint of forming a large loop with yarn uniformly with high productivity.
- the vertical jet flow in which the fluid is injected at 90 ° to the traveling yarn, but the traveling yarn is opened by the jet flow injection from the vertical direction.
- processing by a propulsion jet is preferable. The processing by this propulsion jet can also suppress the formation of short arch-shaped loops that are easy to form in the case of a vertical jet.
- the jetting angle of compressed air is more preferably 45 ° or less with respect to the running yarn.
- the stability and propulsive force of the jet air flow immediately after the nozzle is high. It is particularly preferred that
- the step of turning the yarn sucked by the suction nozzle outside the nozzle to form a large loop of yarn is the second step of the present invention.
- the yarn guided to the suction nozzle may be performed with one feed or with two feeds, but it is preferable to perform the processing with two feeds in order to produce the bulky yarn of the present invention.
- the term “two feeds” as used herein means a method of supplying two or more yarns to a nozzle by supplying a difference in supply speed (amount) in advance with a supply roller or the like.
- the excessively supplied yarn (sheath yarn) forms a bulky yarn in which a large loop is formed in the outer layer.
- the nozzle is designed based on the concept that a large loop can be formed by swirling the two yarns supplied at a position away from the nozzle without giving any disturbance or opening process in the nozzle.
- the sheath yarn turns while opening when the ratio of the airflow velocity to the yarn velocity (airflow velocity / yarn velocity) is 100 to 3000. I found a phenomenon.
- the air velocity mentioned here refers to the velocity of the air flow ejected from the downstream of the suction nozzle along with the traveling yarn, and can be controlled by the discharge diameter of the nozzle and the flow rate of the compressed air. Further, the yarn speed can be controlled by the rotation speed of a roller for taking the processed yarn after the fluid processing nozzle. Since the turning force of the traveling yarn increases and decreases depending on the speed ratio between the airflow and the yarn, the speed ratio should be close to 3000 when strengthening the target tangling point of the bulky yarn. On the other hand, when it is desired to make the entanglement point slow, it may be close to 100.
- the speed ratio can be changed in the degree of the entanglement point by intermittently changing the flow rate of the compressed air or changing the speed of the take-up roller.
- the air velocity / yarn velocity is set to 200 to 2000.
- the air velocity / yarn velocity is set to 400 to 1500 from the viewpoint of imparting appropriate restraint and flexibility. Particularly preferred.
- the turning point (10 in FIG. 3) which is the base point at which this turning force is expressed, is started by causing the traveling yarn to detach from the accompanying airflow. Specifically, it is sufficient to change the yarn path with a bar guide or the like.
- the take-up roller (12 in FIG. 3) in the traveling direction of the running yarn pulls the running yarn at a specified speed, thereby A sheath thread swirls around to form a large loop.
- the swiveling point of the traveling yarn is preferably located at a position away from the nozzle discharge port. It is.
- the distance between the nozzle and the turning point suitable for producing the bulky yarn of the present invention varies depending on the jetting air velocity, and the jetting airflow is 1.0 ⁇ 10 ⁇ 5 to 1.0 ⁇ 10 ⁇ It is preferable that a turning point (10 in FIG. 3) exists while traveling for 3 seconds.
- the distance between the nozzle and the turning point is from 2.0 ⁇ 10 ⁇ 5 to 5.0 ⁇ 10 More preferably, it is present while driving for -4 seconds.
- the period of the entanglement point of the bulky yarn of the present invention can be controlled by adjusting this turning point.
- the entanglement point has a role of supporting the independence of the loop made of the sheath yarn that is a feature of the present invention, and it is preferable that the entanglement point exists at a certain period. From this viewpoint, it is preferable to adjust the turning point so that the entanglement point of the core yarn and the sheath yarn in the bulky yarn is 1 to 30 pieces / mm. Such a range is preferable because a loop exists with an appropriate interval even after the three-dimensional crimp of the sheath yarn is expressed. From this viewpoint, it is more preferable to adjust the turning point so that the entanglement point is 5 to 15 pieces / mm.
- the processed yarn (11 in FIG. 3) in which a large loop of sheath yarn is formed is subjected to heat treatment after being wound once or subsequent to bulky processing in order to develop shape fixation and three-dimensional crimp. Is preferred.
- FIG. 3 illustrates a processing step in which heat treatment is performed subsequent to the large loop formation step.
- This heat treatment (13 in FIG. 3) is performed by heating the processed yarn with a heater or the like, and the processing temperature is a crystallization temperature ⁇ 30 ° C. of the polymer used. If the treatment is performed within this temperature range, the treatment temperature is away from the melting point of the polymer, so there is no portion fused and cured between the yarns, there is no foreign matter feeling, and the good feel of the bulky yarn of the present invention is impaired. There is nothing.
- a heater used in this heat treatment step a general contact type or non-contact type heater can be adopted, but a non-contact type heater is suitably adopted from the viewpoint of bulkiness before heat treatment and suppression of yarn deterioration.
- the Non-contact heaters mentioned here include air heaters such as slit heaters and tube heaters, steam heaters heated by high-temperature steam, halogen heaters using radiant heating, carbon heaters, microwave heaters, etc. To do.
- the heating time for example, the time required for fixing the fiber structure of the fibers constituting the processed yarn, fixing the shape of the processed yarn, and completing the expression of the crimp of the yarn is a guideline. It is preferable to adjust according to the required characteristics.
- the processed yarn for which the heat treatment process has been completed may be wound with a winder or the like having a tension control function by regulating the speed via a roller (14 in FIG. 3) (15 in FIG. 3).
- the winding shape is not particularly limited, and can be a so-called cheese winding or bobbin winding. In consideration of processing into a final product, it is possible to combine a plurality of yarns in advance to form a tow or to make a sheet as it is.
- the bulky yarn of the present invention preferably has a silicone oil agent uniformly attached before and after the heat treatment step.
- the silicone to be adhered here is preferably formed by forming a silicone film on the sheath yarn and the core yarn by appropriately crosslinking by heat treatment or the like.
- the silicone-based oil referred to here includes dimethylpolysiloxane, hydrodienemethylpolysiloxane, aminopolysiloxane, epoxypolysiloxane, and the like, and these may be used alone or in combination.
- a dispersant for uniformly forming a film on the bulky yarn, a dispersant, a viscosity modifier, a crosslinking accelerator, an antioxidant, a flame retardant, and an antistatic agent are contained within a range that does not impair the purpose of silicone adhesion. be able to.
- silicone oil Even if this silicone oil is straight, it can also be used as an aqueous emulsion, but it is preferable to use it as an aqueous emulsion from the viewpoint of uniform adhesion of the oil.
- the silicone-based oil is preferably treated so that it can be adhered to the bulky yarn in an amount of 0.1 to 5.0 wt% by using an oil guide, oiling roller or spraying.
- This silicone-based oil can be attached in a plurality of times, and it is also preferable to laminate a strong silicone film by attaching the same type of silicone or different types of silicones separately.
- Fineness The 100-meter weight of the fiber was measured, and the fineness was calculated by multiplying by 100. This was repeated 10 times, and the value obtained by rounding off the second decimal place of the simple average value was defined as the fineness of the fiber.
- the single yarn fineness was calculated by dividing the fineness described above by the number of filaments constituting the fiber. Also in this case, the value obtained by rounding off the second decimal place was defined as the single yarn fineness.
- the number of entanglements referred to here counts the number of single yarns of the sheath yarn that have entered between the single yarns of the core yarn.
- Crimp form evaluation (three-dimensional crimp, radius of curvature) At 10 points randomly selected from the bulky yarns, 10 or more single yarns were collected, and each single yarn was observed at a magnification at which the crimped form could be confirmed with a microscope VHX-2000 manufactured by Keyence Corporation. did. In this image, when the observed single yarn has a spirally swung form, it is determined that there is a three-dimensional crimped structure (evaluation: yes). It was determined that there was no contracted structure (evaluation: none). Further, from the same image, the radius of a perfect circle that is most inscribed in two or more places in the three-dimensional crimp 3 as shown in FIG. 2 was evaluated using image processing software (WINROOF).
- WINROOF image processing software
- the evaluation method of bulkiness, compression rate, recovery rate / bulkness is generally expressed by the degree of swelling per unit weight (volume including the air layer). Bulkiness is also called fill power.
- Pretreatment 35 g of the stuffed cotton of the present invention is left to dry in an environment of a temperature of 20 degrees and a humidity of 65% for 48 hours.
- -Input Put 30 g of pre-treated cotton into a cylinder container with an inner diameter d of 28.8 cm and a height of 50 cm. At this time, it is preferable to slowly put the sample into the cylinder so as to keep the swollen cotton from becoming lumps.
- the volume V of stuffed cotton having a height of hcm in this cylinder container is expressed by the following equation.
- Tactile and cushion sample creation A plain woven fabric made of a woolen yarn of nylon 20D is used as the side fabric (vertical density 80 / 2.54 cm, horizontal density 113 / 2.54 cm).
- As a cushion sample 5 g of the stuffed cotton of the present invention was filled in a side of 21 cm ⁇ 21 cm.
- the tactile sensation of pressing the cushion sample was evaluated in the following four stages. S: An excellent texture that is excellent in bulkiness and flexibility and does not feel a foreign body feeling. A: Good texture with bulkiness and flexibility. B: A good texture that is bulky and does not feel a foreign body feeling. C: Poor texture that is not bulky and feels a foreign body.
- JISL1096 Insulating property It measures according to A method (constant temperature method).
- Drying speed A cushion sample similar to (5) above is used. After the sample is poured into pure water for 5 minutes, the measurement is started after dehydration with a dehydrator so that the water content becomes 50%. The measurement is performed every 5 minutes, and ends when the moisture content reaches 25%.
- Air permeability A cushion sample similar to (5) above is used. The air permeability of the side ground was measured according to JIS L1096 (Method A).
- PET Polyethylene terephthalate
- the wound undrawn yarn was drawn 3.0 times between rollers heated to 90 ° C. and 140 ° C. at a drawing speed of 800 m / min to obtain a drawn yarn having a fineness of 84 dtex and 12 filaments.
- the obtained drawn yarn (synthetic fiber) is supplied to each of two supply rollers, and one supply roller is supplied with a core yarn at a supply speed of fluid processing conditions.
- the speed was 30 m / min as the speed, and the other supply roller was sucked with a suction nozzle at a speed 600 m / min as the sheath yarn supply speed of the fluid processing conditions.
- the nozzle supply pressure of the suction nozzle was 0.25 Mpa, and the flow rate was 74 L / min.
- the film was taken up at 30 m / min with a take-up roller.
- the processed yarn was guided to a tube heater through a roller and heat-treated with heated air at 150 ° C. for 10 seconds to set a bulky yarn form and to develop a three-dimensional crimp on the yarn.
- the bulky yarn was wound around a drum at 30 m / min by a tension control type winder (winder) installed after the tube heater.
- a silicone oil containing polysiloxane at a concentration of 8 wt% was uniformly applied by a putting method so that the final polysiloxane adhesion amount was 1 wt% with respect to the bulky yarn, and the temperature was 170 ° C.
- the processed yarn was collected by heat treatment for 5 minutes.
- the bulky yarn collected in Example 1 has a three-dimensional crimped structure on the order of millimeters in which the entanglement point of the core yarn and the sheath yarn is 13 pieces / mm, and the curvature radius of the sheath yarn is 6.5 mm. Yes.
- Example 2 As the entanglement conditions of the fluid processing conditions, the nozzle supply pressure and flow rate of the suction nozzle are changed, the entanglement point of the core yarn and the sheath yarn is 10 pieces / mm, and the radius of curvature of the bulky yarn crimp is 7.5 mm. All the procedures were performed according to Example 1 except for the above. In Example 2, although the bulkiness, compression height, and recovery height were slightly inferior, in the tactile evaluation, a good texture (A) having bulkiness and flexibility was obtained. There were no problems with the bulkiness reduction when wet, the integral product of the heat consumption, the drying speed, and the dust generation. The results are shown in Table 1.
- Example 3 As the entanglement conditions of the fluid processing conditions, the nozzle supply pressure and flow rate of the suction nozzle are changed, the entanglement point of the core yarn and the sheath yarn is 20 pieces / mm, and the curvature radius of the crimp of the bulky yarn is 20 mm Were all carried out according to Example 1. In Example 3, although the bulkiness, the compression height, and the recovery height were slightly inferior, in the tactile evaluation, a good texture (A) having bulkiness and flexibility was obtained. There were no problems with the bulkiness reduction when wet, the integral product of the heat consumption, the drying speed, and the dust generation. The results are shown in Table 1.
- Comparative Example 1 The core yarn was 56T-12, the sheath yarn was 160T-24, and the others were carried out according to Example 1. In Comparative Example 1, the bulkiness, compression height, and recovery height were inferior, and there was no bulkiness even in the tactile sensation evaluation. The wet bulkiness reduction, integral product of heat consumption, drying speed, and dust generation have problems in practical use. The results are shown in Table 1.
- Comparative Example 2 As the entanglement conditions of the fluid processing conditions, changing the nozzle supply pressure and flow rate of the suction nozzle, the curvature radius of the bulky yarn crimp is 1.0 mm, the entanglement point is 20 pieces / mm, and the three-dimensional crimp is All the procedures were performed according to Example 1 except for the absence. In Comparative Example 2, the bulkiness, the compression height, and the recovery height were inferior, and there was no bulkiness even in the tactile sensation evaluation. Although the bulkiness reduction property when wet and the integral product of heat consumption reached a practical level, there was a problem in practicality in terms of drying speed and dust generation. The results are shown in Table 1.
- Example 4 160T-24 was used for both the core yarn and the sheath yarn.
- the supply pressure of the fluid processing nozzle is set to 0.3 Mpa
- the air flow rate of the nozzle is set to 84 L / min
- the entanglement point of the core yarn and the sheath yarn is 13 pieces / mm
- the radius of curvature of the bulky yarn crimp is 7. It carried out according to Example 1 except that it was 0 mm.
- the tactile sensation evaluation the bulkiness and flexibility are excellent, but the feeling of foreign matter is felt a little, so the texture evaluation is A.
- favorable results were obtained for the bulkiness reduction property when wet, the integral product of the heat consumption, the drying rate, and the dust generation property. The results are shown in Table 2.
- Example 5 The core yarn was 160T-24, and the sheath yarn was 84T-12.
- the supply pressure of the fluid processing nozzle is set to 0.3 Mpa, the air flow rate of the nozzle is set to 84 L / min, the entanglement point of the core yarn and the sheath yarn is 15 pieces / mm, and the radius of curvature of the bulky yarn crimp is 7. It carried out according to Example 1 except that it was 0 mm.
- the tactile sensation evaluation since there was a slight foreign body sensation, the texture evaluation was A.
- favorable results were obtained for the bulkiness reduction property when wet, the integral product of the heat consumption, the drying rate, and the dust generation property. The results are shown in Table 2.
- Example 6 The core yarn was 84T-12 and the sheath yarn was 160T-24.
- the supply pressure of the fluid processing nozzle is set to 0.3 Mpa
- the air flow rate of the nozzle is set to 84 L / min
- the entanglement point of the core yarn and the sheath yarn is 20 pieces / mm
- the radius of curvature of the bulky yarn crimp is 7. It carried out according to Example 1 except that it was 0 mm.
- the tactile sensation evaluation since there was a slight foreign body sensation, the texture evaluation was A.
- favorable results were obtained for the bulkiness reduction property when wet, the integral product of the heat consumption, the drying rate, and the dust generation property. The results are shown in Table 2.
Abstract
Description
(1)芯糸と鞘糸の繊度比(鞘/芯)が0.5~2.0であり、
(2)芯糸と鞘糸の絡合点が繊維軸方向に、1~30個/mm存在し、
(3)ループを形成する鞘糸の曲率半径が2.0~30.0mmである、
嵩高糸からなることを特徴とする。
(A-B)/A≦0.3 ・・・(1)
(A-C)/A≦0.2 ・・・(2)
A:繰り返し5回洗濯後の乾燥状態の嵩高性(cm3/30g)
B:湿潤状態(水分率50%)の嵩高性(cm3/30g)
C:湿潤状態(水分率35%)の嵩高性(cm3/30g)
ここで水分率(%)は以下の式で表される。
水分率(%)=(W1-W0)/W0×100%
W1:湿潤時の重さ(g)
W0:乾燥時の重さ(g)。
本発明の嵩高糸は、ニップローラなどを有した供給ローラ(図3の7)により前述した合成繊維(図3の8)を規定量供給し、圧空の噴射が可能なサクションノズル(図3の9)によって芯糸及び鞘糸を吸引することが第1の工程になる。このサクションノズル(図3の9)において、ノズルから噴射する圧空の流量は、供給ローラからノズルに挿入する糸条が必要最低限の張力を有して供給ローラ-ノズル間及びノズル内で糸揺れ等を起こさず安定的に走行する流量を噴射すればよい。この圧空の流量は、使用するサクションノズルの孔径により最適量が変化する。糸張力を付与でき、後述する大ループの形成が円滑にできる範囲としては、ノズル内での気流速度が100m/s以上であることが目安となる。この気流速度の上限値の目安は、700m/s以下とすることであり、係る範囲であれば、過剰に噴射された圧空により、走行糸条が糸揺れ等を起こすことなく、安定的にノズル内を走行することになる。
あるが、本発明の嵩高糸を製造するには、2フィードによる加工を行うことが好適である。ここで言う2フィードとは、2本以上の糸に予め供給ローラなどで供給速度(量)に差をつけて、ノズルに供給する手法を意味し、後述する気流による旋回力を利用することで過剰に供給された側の糸(鞘糸)が外層に大ループを形成した嵩高糸を形成することになる。この2フィードを活用する場合には、ノズル内で走行糸条に撹乱、開繊及び交絡の効果を付与するインターレス加工ノズルやタスラン加工ノズルでループを有した加工糸を製造することも不可能ではない。
繊維の100mの重量を測定し、100倍することで繊度を算出した。これを10回繰り返し、その単純平均値の小数点第2位を四捨五入した値をその繊維の繊度とした。単糸繊度とは、その繊維を構成するフィラメント数により前述した繊度を除することにより、算出した。この場合も、小数点第2位を四捨五入した値を単糸繊度とした。
ここで言う絡合数は、芯糸の単糸間に入り込んでいる鞘糸の単糸本数をカウントする。
・絡合数の数え方:
(a)サンプルを適当な長さで採取する
(b)黒用紙に、芯糸を張った状態で両端を貼り付ける
(c)観察倍率(×100)条件で、糸長さ方向に連続で撮影する
(d)1画像の芯糸長さを測る
(e)1画像の絡合数をカウントする
(f)サンプルの絡合数=1画像内の絡合数/芯糸長さを計算する。1mm当たりの絡合数で算出する。
嵩高糸から無作為に選出した10箇所において、各々10本以上の単糸を採取し、それぞれの単糸を(株)キーエンス社製マイクロスコープVHX-2000にて捲縮形態が確認できる倍率で観察した。この画像において、観察される単糸がらせん状に旋回した形態を有している場合には、3次元的な捲縮構造有り(評価:あり)と判定し、ストレートな形態の場合には捲縮構造無し(評価:なし)と判定した。また、同じ画像から、画像処理ソフト(WINROOF)を用いて、図2に示したような、3次元的な捲縮3に2箇所以上で最も多く内接する真円の半径を評価した。前述の通り無作為に抽出した計100本の単糸をミリメートル単位で小数点第2位までを測定し、この単純平均の小数点第2位を四捨五入した値を本発明の3次元的な捲縮構造の曲率半径とした。
・嵩高性の評価方法は、規定重量あたりの膨らみ度合い(空気層を含む体積)で表すのが、一般的である。嵩高性はフィルパワーとも呼ばれている。
・前処理:本発明の詰め綿35gを温度20度、湿度65%の環境に48hr放置して乾燥状態にする。
・投入:前処理後の詰め綿30gを内径d28.8cm×高さ50cmのシリンダー容器に入れる。その際に、詰め綿の膨らみを保って塊にならないように試料をゆっくりとシリンダーに入れるのが好ましい。このシリンダー容器における、高さhcmの詰め綿の体積Vは、以下の式のように表される。
詰め綿の体積V=π・d2・h/4=651×h(cm3)
・測定:下記荷重をそれぞれに詰め綿に載せた際の高さを読み取り、嵩高性、圧縮率、回復率を以下の式で求める。
嵩高性用の荷重:0.15g/cm2を載せた時の試料の高さ:h0(cm)
圧縮高さ用の荷重:6.00g/cm2を載せた時の試料の高さ:h1(cm)
回復高さ用の荷重:0.15g/cm2を載せた時の試料の高さ:h2(cm)
式A:嵩高性(cm3/30g)=651×h0
式B:圧縮率(%)=(h0-h1)/h0×100%
式C:回復率(%)=(h2-h1)/(h0-h1)×100%。
・座布団サンプル作成:
側地としてナイロン20Dのウーリ加工糸からなる平織物を使用する(タテ密度80本/2.54cm、ヨコ密度113本/2.54cm)。座布団サンプルとして21cm×21cmの側地に、本発明の詰め綿を5g充填した。
・評価
該座布団サンプルを押さえた触感を下記の4段階で評価した。S:嵩高性及び柔軟性に優れ、異物感を感じない優れた風合い。
A:嵩高性及び柔軟性を有した良好な風合い。
B:嵩高性を有し、かつ異物感を感じない程度の良好な風合い。
C:嵩高性がなく、異物感を感じる不良な風合い。
洗濯法は、JIS L0217 105法に準ずるものである。座布団サンプルは上記(5)と同様である。
・洗剤:中性洗剤(使用量:20g)
・水温:30℃
・洗濯浴比: 生地:水=1:60
・洗濯時間(分):25(5回)
・すすぎ浴比:生地:水=1:65
・すすぎ時間(分):20(5回)
・脱水時間(分):10(5回)。
JISL1096 保温性 A法(恒温法)に沿って、測定する。
A.測定器:KES-F7、精密迅速熱物性測定装置サーモラボ IIB)
B.保温率の熱板温度:36℃
C.試料作成:上記(5)と同様に座布団サンプルを作成。
D.乾燥状態:温度20度、湿度65%の環境に48hrを放置した状態という。
E.湿潤条件:純水に5分間どぼづけ後、サンプルの水分率を50%になるように、脱水機で脱水後、測定を開始する。測定は、水分率が5%に成る段階で終了する。50%水分率時の消費熱量、35%水分率時の消費熱量、5%水分率時の消費熱量、50%水分率時から35%水分率時の消費熱量の積分積、50%水分率時から5%水分率時の消費熱量の積分積を評価した。水分率は下式の通りである。
水分率(%)=(W1-W0)/W0×100%
W1:湿潤時の重さ(g)
W0:乾燥時の重さ(g)
ここでいう乾燥状態は、温度20℃、湿度65%の環境に48hr放置した後の状態を指す。
上記(5)と同様な座布団サンプルを使用する。サンプルを純水に5分間どぼづけ後、水分率を50%になるように、脱水機で脱水後、測定を開始する。測定は、5分毎にデータ取りを行い、水分率が25%に成る段階で終了する。
上記(5)と同様な座布団サンプルを使用する。側地の通気度は、JIS L1096(A法)に準じて測定した。
JISB9923タンブリング法に準じて測定する。上記(5)と同様な座布団サンプルを使用する。粒径0.3μm以上の粒子の数(個/分)を捕集し、カウントする。
ポリエチレンテレフタレート(PET:IV=0.65dl/g)を290℃で溶融後、計量し、紡糸パックに流入させ、図5に例示されるような3つのスリット17(スリット幅0.1mm)が同心円状に配置された中空断面用吐出孔から、中空率30%となるように吐出した。吐出された糸条に20℃の冷却風を40m/minの流れで片側から吹き付けて冷却固化後、非イオン系の紡糸油剤付与し、紡糸速度1500m/minで未延伸糸を巻き取った。引き続き、巻き取った未延伸糸を90℃と140℃に加熱したローラ間で延伸速度800m/minで3.0倍延伸し、繊度84dtex、フィラメント数12、の延伸糸とした。
流体加工条件の絡合条件として、サクションノズルのノズル供給圧、流量を変更して、芯糸と鞘糸の絡合点は10個/mm、かつ嵩高糸の捲縮の曲率半径を7.5mmにした以外は全て実施例1に従い、実施した。実施例2においては、嵩高性、圧縮高さ、回復高さが若干劣るものの、触感評価では嵩高性及び柔軟性を有した良好な風合い(A)が得られた。湿潤時の嵩高低下性や消費熱量の積分積、乾燥速度、発塵性は問題なかった。結果を表1に示す。
流体加工条件の絡合条件として、サクションノズルのノズル供給圧、流量を変更して、芯糸と鞘糸の絡合点は20個/mm、嵩高糸の捲縮の曲率半径を20mmにした以外は全て実施例1に従い、実施した。実施例3においては、嵩高性、圧縮高さ、回復高さが若干劣るものの、触感評価では嵩高性及び柔軟性を有した良好な風合い(A)が得られた。湿潤時の嵩高低下性や消費熱量の積分積、乾燥速度、発塵性は問題なかった。結果を表1に示す。
芯糸を56T-12に、鞘糸を160T-24を使用し、それ以外は実施例1に従い、実施した。比較例1においては、嵩高性、圧縮高さ、回復高さが劣り、触感評価でも嵩高性がなく、異物感を感じる不良な風合い(C)が得られた。湿潤時の嵩高低下性や消費熱量の積分積、乾燥速度、発塵性は実用性に問題があった。結果を表1に示す。
流体加工条件の絡合条件として、サクションノズルのノズル供給圧、流量を変更して、嵩高糸の捲縮の曲率半径を1.0mmに、交絡点を20個/mmに、3次元捲縮がないこと以外は全て実施例1に従い、実施した。比較例2においては、嵩高性、圧縮高さ、回復高さが劣り、触感評価でも嵩高性がなく、異物感を感じる不良な風合い(C)となった。湿潤時の嵩高低下性や消費熱量の積分積が辛うじて実用レベルには達したが、乾燥速度、発塵性においては実用性に問題があった。結果を表1に示す。
一般市販のダウンジャケットから、天然羽毛30gを採集し、詰め綿の特性を実施例1同様に評価した。触感評価では、嵩高性及び柔軟性に優れ、異物感を感じない優れた風合い(S)が得られた。しかし、湿潤時の嵩高性の低下が大きく、消費熱量、乾燥速度、発塵性いずれも実施例1~3に及ばない結果であった。結果を表1に示す。
芯糸、鞘糸ともに、160T-24を使用した。流体加工ノズルの供給圧は0.3Mpa,ノズルのエアー流量を84L/minに設定して、芯糸と鞘糸の絡合点は13個/mm、嵩高糸の捲縮の曲率半径を7.0mmにした以外は実施例1に従い、実施した。触感評価では、嵩高性及び柔軟性に優れているが、異物感は少し感じているため、風合い評価はAとした。なお、湿潤時の嵩高低下性、消費熱量の積分積、および乾燥速度、発塵性いずれも良好な結果が得られた。結果を表2に示す。
芯糸は160T-24、鞘糸は84T-12、それぞれを使用した。流体加工ノズルの供給圧は0.3Mpa,ノズルのエアー流量を84L/minに設定して、芯糸と鞘糸の絡合点は15個/mm、嵩高糸の捲縮の曲率半径を7.0mmにした以外は実施例1に従い、実施した。触感評価では、若干異物感があったため、風合い評価はAとした。なお、湿潤時の嵩高低下性、消費熱量の積分積、および乾燥速度、発塵性いずれも良好な結果が得られた。結果を表2に示す。
芯糸は84T-12、鞘糸は160T-24、それぞれを使用した。流体加工ノズルの供給圧は0.3Mpa,ノズルのエアー流量を84L/minに設定して、芯糸と鞘糸の絡合点は20個/mm、嵩高糸の捲縮の曲率半径を7.0mmにした以外は実施例1に従い、実施した。触感評価では、若干異物感があったため、風合い評価はAとした。なお、湿潤時の嵩高低下性、消費熱量の積分積、および乾燥速度、発塵性いずれも良好な結果が得られた。結果を表2に示す。
2 芯糸
3 3次元的な捲縮
7 供給ローラ
8 合成繊維
9 サクションノズル
10 旋回点
11 嵩高糸
12 引き取りローラ
13 チューブヒータ
14 デリバリローラ
15 ワインダー
16 圧空の噴射角度
17 スリット
Claims (8)
- 合成繊維からなる詰め綿及び側地から構成された繊維詰め物体であり、合成繊維からなる詰め綿は、
(1)芯糸と鞘糸の繊度比(鞘/芯)が0.5~2.0であり、
(2)芯糸と鞘糸の絡合点が繊維軸方向に、1~30個/mm存在し、
(3)ループを形成する鞘糸の曲率半径が2.0~30.0mmである、
嵩高糸からなることを特徴とする繊維詰め物体。 - 前記合成繊維からなる詰め綿が、乾燥状態の嵩高性が7000cm3/30g以上であり、かつ圧縮率は70%以上であり、回復率は50%以上であることを特徴とする繊維詰め物体。
- 前記合成繊維からなる詰め綿が、繰り返し5回洗濯後の乾燥状態の嵩高性が6500cm3/30g以上、かつ湿潤時の嵩高低下性として、下記(1)式および下記(2)式を満足することを特徴とする請求項1または請求項2に記載の繊維詰め物体。
(A-B)/A≦0.3 ・・・(1)
(A-C)/A≦0.2 ・・・(2)
A:繰り返し5回洗濯後の乾燥状態の嵩高性(cm3/30g)
B:湿潤状態(水分率50%)の嵩高性(cm3/30g)
C:湿潤状態(水分率35%)の嵩高性(cm3/30g) - 50%水分率から5%水分率に到達する際の消費熱量の積分積が25W・分/℃・m2以下であることを特徴とする請求項1~3のいずれか1項に記載の繊維詰め物体。
- 50%水分率から25%水分率に到達する際の乾燥時間が50分以下であることを特徴とする請求項1~4のいずれか1項に記載の繊維詰め物体。
- 側地と詰め綿がキルト縫いされていることを特徴とする請求項1~5のいずれか1項に記載の繊維詰め物体。
- 側地の通気度が1.0cc/cm2・秒以上である織編物からなり、発塵性が100個/分以下であることを特徴とする請求項1~6のいずれか1項に記載の繊維詰め物体。
- 請求項1~7のいずれか1項に記載の繊維詰め物体が少なくとも1部に使用されたことを特徴とする繊維製品。
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JP2020084377A (ja) * | 2018-11-27 | 2020-06-04 | 東レ株式会社 | 嵩高糸 |
JP2020143396A (ja) * | 2019-03-06 | 2020-09-10 | 倉敷紡績株式会社 | 詰め物用糸及びこれを用いた詰め物体 |
JP2020153039A (ja) * | 2019-03-22 | 2020-09-24 | 倉敷紡績株式会社 | 詰め物用糸及びこれを用いた詰め物体 |
JP2020165025A (ja) * | 2019-03-29 | 2020-10-08 | 倉敷紡績株式会社 | 詰め物用糸及びこれを用いた詰め物体 |
US20230193524A1 (en) * | 2020-06-29 | 2023-06-22 | Toray Industries, Inc. | Chenille yarn, textile product, clothing, and bedding |
JP7420624B2 (ja) | 2020-03-30 | 2024-01-23 | 倉敷紡績株式会社 | 制電性着用品及び制電性防寒衣服 |
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CN107849755A (zh) * | 2015-07-22 | 2018-03-27 | 东丽株式会社 | 膨松纱 |
JP6696288B2 (ja) * | 2016-04-26 | 2020-05-20 | 東レ株式会社 | 嵩高構造糸 |
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