WO2017190417A1 - Procédé de préparation d'une électrode épaisse et dense à base de graphène - Google Patents
Procédé de préparation d'une électrode épaisse et dense à base de graphène Download PDFInfo
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- WO2017190417A1 WO2017190417A1 PCT/CN2016/088763 CN2016088763W WO2017190417A1 WO 2017190417 A1 WO2017190417 A1 WO 2017190417A1 CN 2016088763 W CN2016088763 W CN 2016088763W WO 2017190417 A1 WO2017190417 A1 WO 2017190417A1
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- WIPO (PCT)
- Prior art keywords
- graphene
- electrode
- density
- salt
- preparing
- Prior art date
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 242
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 227
- 238000000034 method Methods 0.000 title claims abstract description 41
- 150000003839 salts Chemical class 0.000 claims abstract description 53
- 239000007772 electrode material Substances 0.000 claims abstract description 38
- 239000000017 hydrogel Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 29
- 238000002360 preparation method Methods 0.000 claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 5
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 58
- 239000011592 zinc chloride Substances 0.000 claims description 29
- 235000005074 zinc chloride Nutrition 0.000 claims description 29
- 239000007789 gas Substances 0.000 claims description 26
- 238000006722 reduction reaction Methods 0.000 claims description 20
- 230000009467 reduction Effects 0.000 claims description 15
- 239000012298 atmosphere Substances 0.000 claims description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 13
- 239000012266 salt solution Substances 0.000 claims description 13
- 150000002500 ions Chemical class 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 11
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 239000003638 chemical reducing agent Substances 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 4
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 4
- 229940071870 hydroiodic acid Drugs 0.000 claims description 4
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 4
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims description 4
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 4
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 230000002950 deficient Effects 0.000 claims description 3
- 239000001307 helium Substances 0.000 claims description 3
- 229910052734 helium Inorganic materials 0.000 claims description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 3
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
- 229960001790 sodium citrate Drugs 0.000 claims description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 claims description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 claims description 2
- 229910001626 barium chloride Inorganic materials 0.000 claims description 2
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 2
- 230000005540 biological transmission Effects 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 229940116318 copper carbonate Drugs 0.000 claims description 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 claims description 2
- 239000011790 ferrous sulphate Substances 0.000 claims description 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 229910001958 silver carbonate Inorganic materials 0.000 claims description 2
- LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 claims description 2
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
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- 239000010949 copper Substances 0.000 claims 1
- 229960002089 ferrous chloride Drugs 0.000 claims 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims 1
- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- 235000015497 potassium bicarbonate Nutrition 0.000 claims 1
- 239000011736 potassium bicarbonate Substances 0.000 claims 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims 1
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- 238000000696 nitrogen adsorption--desorption isotherm Methods 0.000 description 2
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- 238000011160 research Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
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- 230000001276 controlling effect Effects 0.000 description 1
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- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
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- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
Definitions
- the invention relates to a preparation method and application of a "high-thickness" and “high-density” electrode based on graphene, and belongs to the technical field of graphene.
- Graphene is a sp 2 hybrid single-layer carbon atom crystal having a two-dimensional honeycomb lattice structure, which is an uneven, wrinkled two-dimensional crystal and is considered as a unit unit for constructing other sp 2 carbonaceous materials.
- the excellent electrical, thermal, mechanical and optical properties of graphene have caused people's research boom in recent years.
- Graphene materials have great advantages in the field of electrochemical energy storage due to their microscopic nanometer scale, high activity specific surface area, high reactivity and high electrochemical capacity. Although the graphene material itself has a high energy density, the performance of the graphene-based energy storage device is not satisfactory, and the energy density of the entire device is still at a low level. This is because the energy storage device not only includes the electrode active material, but also includes the current collector, the electrolyte, the separator, the binder, and the package casing. The lower the active layer quality of the graphene electrode material, so that the electrode active material accounts for the device. The proportion is very low, making the device's energy density difficult to exceed current levels. Therefore, designing a thick electrode based on graphene and increasing the specific gravity of the active material in the energy storage device is the key to improving the energy density of the energy storage device.
- the graphene electrode should not only be “thick” but also "tight”: design graphite
- the alkenyl thick electrode which has the advantage of high electrochemical activity of the graphene material in a limited device volume, is an important way to increase the energy density of the energy storage device.
- excessively thick and too dense electrodes can cause agglomeration of the graphene material itself and hinder ion transport during charge and discharge. That is to say, electrolyte ions are difficult to enter the inside of the thick electrode during charging and discharging, resulting in low utilization of the electrode material, low capacity and large polarization, which affects the energy output of the entire device. Therefore, the pore structure of the graphene-based thick-density electrode is optimized, and studying the electrochemical behavior of the electrolyte ions is of great significance for improving the volumetric energy density of the energy storage device.
- the pore structure of the electrode is optimized, and the thickness and density of the electrode are taken into consideration, and the mode of transport of the electrolyte ions in the thick electrode during charging and discharging is optimized to solve the energy density in the device application.
- the problem has important theoretical research value and practical application significance.
- the problem to be solved by the present invention is the technical problem that the graphene electrode material is easy to agglomerate, the electrolyte ions are blocked in the thick electrode, and the volume energy density of the electrochemical energy storage device is low.
- the present invention provides a method for preparing a once-formed graphene-based thick-dense electrode, which optimizes the electrochemical transport of electrolyte ions in a thick electrode by adjusting the pore, thickness and density of the electrode, and improves the energy of the energy storage device. density.
- a method for preparing a graphene-based thick-density electrode comprises the following steps:
- Step 1 Preparation of graphene hydrogel: reducing the graphene derivative solution to obtain a graphene hydrogel having a three-dimensional structure;
- Graphene hydrogel has a three-dimensional structure of porous channels, which is beneficial to the transfer of electrons and the storage and transport of electrolyte ions.
- Step 2 Composite of graphene and salt component: the graphene hydrogel prepared in the first step is immersed in a salt solution having a concentration of c, and statically adsorbed for t hours, and then the graphene hydrogel is taken out and dried to obtain graphite. a complex of an alkene and a salt component;
- the graphene hydrogel has a strong liquid phase adsorption capacity, which is favorable for the loading of the salt component on the graphene sheet. Static adsorption also reduces energy consumption during the compounding of salt components with graphene.
- Step 3 Gas production of salt component: The composite of graphene and salt component is placed in an oxygen-deficient atmosphere or a reducing atmosphere, heat-treated at a temperature T 1 , taken out and repeatedly washed and purified with a washing solvent to obtain a three-dimensional graphite. Alkene block material;
- Step 4 Preparation of a graphene-based thick-density electrode: directly cutting the three-dimensional graphene block obtained in the third step into an electrode material having a diameter d, a thickness h, and a density ⁇ ;
- the salt described in the second step is a salt which generates a gas at a temperature T 0 and T 1 ⁇ T 0 .
- the method can realize the precise regulation of the pore structure of the graphene bulk material on the three-dimensional scale by using the hydrogel and utilizing the impact on the three-dimensional pore structure during the gas production process of the salt. Therefore, as an electrode, the graphene material can realize efficient storage and rapid transport of ions, and has higher capacity and excellent rate characteristics.
- the invention utilizes the pore-forming effect of gas-producing salts on graphene during heating to prepare a three-dimensional porous graphene bulk material. Different from other pore-forming methods, the method starts from graphene hydrogel, and the gas-producing salt does not etch with graphene during heating, and the impact of gas on graphene sheets is utilized.
- the obtained graphene has high yield and uniform pores, and is suitable for mass production of porous graphene materials; gas generated after heating is released, and the obtained graphene has less impurities and high purity; Impurities occupy the pores of graphene, and after cleaning, the effect of secondary pore formation on graphene is achieved.
- the graphene is a three-dimensional shaped bulk structure, which can be directly applied to an electrode material, the electrode has a large thickness and density, and the processing steps of preparing the electrode from the powder graphene are avoided, and Due to its high surface area, it has a high capacity, and because of its three-dimensional controllable structure, it also has good fast charge and discharge characteristics.
- the present invention provides a method for preparing a graphene-based thick-density electrode, and innovatively proposes a gas-generating salt-generating gas to control the microstructure of the graphene material.
- the graphene material prepared by the method has high yield and large density, and is a formed bulk material, which is free from preparation and processing of the electrode material, and the material can be directly applied to the electrode.
- the method can achieve precise regulation of the thickness, density, porosity and specific surface area of the formed graphene block electrode in a large range.
- the graphene-based thick-density electrode provided by the invention realizes densification of the electrode material, and greatly increases the thickness of the electrode by adjusting the pore structure of the electrode, thereby effectively solving the low density and thickness of the graphene electrode material. problem.
- the electrode material can be directly applied to an electrochemical energy storage device, effectively increasing the volume energy density of the device.
- the graphene derivative described in the first step is at least one selected from the group consisting of graphene oxide, modified graphene, and porous graphene.
- the reduction treatment according to the first step comprises: hydrothermal reduction or chemical reduction, and the reducing agent used for chemical reduction is used. At least one of hydrazine hydrate, urea, thiourea, hydroiodic acid, sodium citrate, and sodium hydrogen sulfite is included.
- the salt which can be sublimed at the temperature T 0 includes: potassium chloride, potassium bromide, sodium chloride, sodium bromide, calcium chloride, chlorination.
- Ferrous, ferrous nitrate, ferrous sulfate, ferric chloride, ferric nitrate, ferric sulfate, zinc chloride, zinc nitrate, zinc sulfate, barium chloride, barium nitrate, silver nitrate, copper chloride, copper nitrate, copper sulfate At least one of magnesium chloride and magnesium nitrate.
- the salt which can be decomposed to generate gas at temperature T 0 includes: calcium carbonate, iron carbonate, barium carbonate, silver carbonate, copper carbonate, sodium hydrogencarbonate, carbonic acid. At least one of potassium hydrogen, ammonium nitrate, ammonium chloride, and ammonium sulfate.
- the solvent used in the salt solution described in the second step is water, ethanol, benzene, toluene, acetone, diethyl ether, dioxane, tetrahydrofuran, N-methyl.
- the concentration c of the salt solution described in the second step is 0.01M-10M, and the adsorption time t is 0.01h-48h.
- the anoxic atmosphere described in the third step includes at least one of nitrogen, argon and helium, and the reducing atmosphere includes ammonia, hydrogen and carbon monoxide. At least one of them.
- the electrode material described in the fourth step has a diameter of 0.2 cm ⁇ d ⁇ 10 cm, a thickness of 10 ⁇ m ⁇ h ⁇ 6 mm, and a density of 0.2 g ⁇ cm -3 ⁇ ⁇ . ⁇ 1.6g ⁇ cm -3 .
- Example 1 is a scanning electron microscope picture of a three-dimensional graphene bulk material prepared in Example 1;
- Example 2 is a nitrogen adsorption desorption isotherm (77K) of the graphene electrode prepared in Example 1;
- Example 3 is a graph showing the charge and discharge curves of the graphene electrode prepared in Example 1 under an ionic liquid system.
- the invention provides a preparation method of a graphene-based thick-density electrode, which comprises the following steps:
- the selected graphene derivative is selected from at least one of graphene oxide, modified graphene, and porous graphene.
- graphene oxide is preferred.
- the reduction method includes hydrothermal reduction, chemical reduction, and the chemical reducing agent used includes at least one of hydrazine hydrate, urea, thiourea, hydroiodic acid, sodium citrate, and sodium hydrogen sulfite.
- hydrothermal reduction is preferred in the reduction process.
- Salt component should be selected to produce a salt in the gas temperature T 0, temperature T 0 is divided into at sublimable salts and salts of the decomposed gas generated at the temperature T 0.
- the salt component is preferably one of zinc chloride, magnesium chloride, and zinc nitrate.
- the solvent in the salt solution is water, ethanol, benzene, toluene, acetone, diethyl ether, dioxoperane, tetrahydrofuran, N-methylpyrrolidone, liquid ammonia, carbon disulfide, carbon tetrachloride, chloroform, inorganic acid, liquid ammonia. At least one of them.
- the solvent of the salt solution is preferably water.
- the salt solution concentration c is 0.01M-10M, and the soaking time t is 0.01h-48h. It can be understood that the concentration of the salt solution is too large or the immersion time is too long, and the gas generated by the salt component enhances the pore-forming effect of the three-dimensional graphene block, thereby causing a decrease in electrode density, which is disadvantageous for high-volume energy density energy storage. . Similarly, the concentration of the salt solution is too small or the soaking time is too short, and the gas generated by the salt component has a weak pore-forming effect on the three-dimensional graphene block, and the specific capacity of the electrode is low.
- the salt solution has a concentration of 0.5 M and a soaking time of 12 h.
- the heated anoxic atmosphere includes at least one of nitrogen, argon, and helium.
- the reducing atmosphere includes at least one of ammonia gas, hydrogen gas, and carbon monoxide.
- one of argon gas, nitrogen gas, and ammonia gas is preferred.
- the pore structure of the graphene block is regulated, and the heating temperature T 1 ⁇ T 0 .
- the electrode material has a diameter of 0.2 cm ⁇ d ⁇ 10 cm, a thickness of 10 ⁇ m ⁇ h ⁇ 6 mm, and a density of 0.2 g ⁇ cm -3 ⁇ ⁇ ⁇ 1.6 g ⁇ cm -3 . It can be understood that the thickness of the electrode material is too large or the density is too large, which hinders the transmission of electrolyte ions during charging and discharging of the device, and reduces the specific capacity of the material; and if the thickness of the electrode material is too small or the density is too small, the active material is lowered in the device.
- the volumetric specific gravity reduces the volumetric energy density of the device.
- the electrode material has a diameter of 0.4 cm, a thickness of 400 ⁇ m, and a density of 0.87 g ⁇ cm -3 .
- the above graphene hydrogel was immersed in 20 mL of 0.5 M zinc chloride aqueous solution for 12 h, and then the graphene hydrogel was taken out. At this time, zinc chloride was adsorbed on the graphene sheet layer of the hydrogel, and the graphene was hydrogelated. The gel was dried under vacuum at 70 ° C for 24 h to obtain a zinc chloride and graphene composite.
- the salt component generates a gas to regulate the pore structure of the graphene block
- the zinc chloride and the graphene composite were placed in a heating furnace, heated at 600 ° C for 1 h in an argon atmosphere, taken out, and repeatedly washed and purified with dilute hydrochloric acid to obtain a three-dimensional graphene bulk material.
- the graphene bulk material was cut, and the thickness of the control electrode was 400 ⁇ m, at which time the electrode material diameter was 0.4 cm.
- FIG. 1 Scanning electron micrograph of the three-dimensional graphene bulk material prepared in Example 1 is shown in FIG. 1.
- the nitrogen adsorption desorption isotherm (77K) of the graphene electrode prepared in Example 1 is as shown in FIG. 2, and the preparation of Example 1 is as shown in FIG.
- the charge and discharge curves of the graphene electrode in the ionic liquid system are shown in Fig. 3.
- Example 2 The concentration of the zinc chloride aqueous solution in Example 1 was adjusted to 0.1 M, and the rest was the same as in Example 1.
- Example 3 The concentration of the zinc chloride aqueous solution in Example 1 was adjusted to 1 M, and the rest was the same as in Example 1.
- Example 4 The concentration of the zinc chloride aqueous solution in Example 1 was adjusted to 2 M, and the rest was the same as in Example 1.
- Example 5 The concentration of the zinc chloride aqueous solution in Example 1 was adjusted to 4 M, and the rest was the same as in Example 1.
- Comparative Example 1 The concentration of the zinc chloride aqueous solution in Example 1 was adjusted to 0 M, and the rest was the same as in Example 1.
- the graphene-based thick-density electrodes prepared in Examples 1-5 and the comparative examples were pressed on a current collector stainless steel mesh, and two were carried out under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. Electrode test. The concentration of the zinc chloride aqueous solution, the density of the electrode, and the mass specific capacity and volume specific capacitance of the electrode are shown in Table 1.
- the concentration of zinc chloride solution has a great influence on the density of the electrode.
- the volume ratio of the final graphene electrode has a great influence.
- concentration of the solution is too low, the pore structure of the electrode is not rich, which is not conducive to the transport of electrolyte ions.
- the volumetric specific capacitance is low; when the concentration of the solution is too high, the pore-forming effect of zinc chloride on the graphene electrode is too strong, resulting in a low electrode density, resulting in a lower volume specific capacitance. From the above investigation, we found that the concentration of the salt component has a great influence on the capacity of the graphene-based thick-density electrode.
- Example 6 The graphene hydrogel soaking time in Example 1 was adjusted to 1 h, and the rest was the same as in Example 1.
- Example 7 The graphene hydrogel soaking time in Example 1 was adjusted to 5 h, and the rest was the same as in Example 1.
- Example 8 The graphene hydrogel soaking time in Example 1 was adjusted to 18 h, and the rest was the same as in Example 1.
- Example 9 The graphene hydrogel soaking time in Example 1 was adjusted to 24 h, and the rest was the same as in Example 1.
- the graphene-based thick-density electrodes prepared in Examples 1, 6-9 and the comparative examples were pressed on a collector stainless steel mesh under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. Perform a two-electrode test. The soaking time of the graphene hydrogel, the density of the electrode, and the mass specific capacity and volume specific capacitance of the electrode are shown in Table 2.
- the soaking time of the graphene hydrogel has a great influence on the density of the electrode and the volumetric capacitance of the final graphene electrode.
- the salt component is negative. Insufficient load, the subsequent pore-forming effect is not obvious, and the void structure inside the electrode is not conducive to the transport of electrolyte ions, resulting in a lower volume specific capacitance;
- the soaking time is too long, the zinc chloride on the graphene electrode during heating
- the pore-forming effect is too strong, resulting in a lower electrode density, resulting in a lower volumetric capacitance.
- Example 10 The heating temperature of the graphene and zinc chloride composite in Example 1 was adjusted to 400 ° C, and the rest was the same as in Example 1.
- Example 11 The heating temperature of the graphene and zinc chloride complex in Example 1 was adjusted to 500 ° C, and the rest was the same as in Example 1.
- Example 12 The heating temperature of the graphene and zinc chloride composite in Example 1 was adjusted to 700 ° C, and the rest was the same as in Example 1.
- Example 13 The heating temperature of the graphene and zinc chloride composite in Example 1 was adjusted to 800 ° C, and the rest was the same as in Example 1.
- the graphene-based thick-density electrode prepared in Examples 1, 10-13 was pressed on a current collector stainless steel mesh, and two electrodes were carried out under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. test.
- the heating temperature of the graphene and zinc chloride complex, the density of the electrode, and the mass specific capacity and volume specific capacitance of the electrode are shown in Table 3.
- the heating temperature of the graphene and zinc chloride complex has a great influence on the density of the electrode and the volume specific capacitance of the final graphene electrode.
- zinc chloride does not volatilize and remains in the form of a solid in the pores of the three-dimensional graphene, and has almost no pore-forming effect, resulting in a lower mass-to-capacity ratio and volume specific capacity of the final electrode;
- the temperature is too high, the evaporation rate of zinc chloride is too fast, and the pore-forming effect on graphene is too strong, resulting in a decrease in electrode density, resulting in a lower volume ratio capacitance. From the above investigation, we found that the heating temperature of the graphene and salt component complex also has a great influence on the capacity of the graphene-based thick-density electrode.
- Example 14 The zinc chloride aqueous solution of Example 1 was adjusted to a zinc nitrate aqueous solution, and the heating temperature was lowered to 200 ° C, and the rest was the same as in Example 1.
- Example 15 The zinc chloride aqueous solution of Example 1 was adjusted to a magnesium chloride aqueous solution, and the heating temperature was lowered to 500 ° C, and the rest was the same as in Example 1.
- Example 16 The aqueous zinc chloride solution of Example 1 was adjusted to an aqueous solution of copper chloride, and the heating temperature was raised to 800 ° C, and the rest was the same as in Example 1.
- the graphene-based thick-density electrodes prepared in Examples 1, 14-16 and the comparative examples were pressed on a collector stainless steel mesh under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. Perform a two-electrode test.
- the composition of the solute in the salt solution, the density of the electrode, and the mass specific capacity and volume specific capacitance of the electrode are shown in Table 4.
- the pore structure of the three-dimensional graphene block can also be regulated by adjusting the heat treatment temperature of the heated gas.
- the heat treatment temperature of the heated gas For example, zinc nitrate and magnesium chloride are easily decomposed by heat. From the viewpoint of reducing energy consumption, we should lower the heat treatment temperature to achieve the effect of adjusting the microstructure of the graphene material. Copper chloride is relatively stable in heat and has a high boiling point. Therefore, we need to increase the heat treatment temperature to achieve the purpose of regulating the structure of graphene materials.
- the above investigations show that the effect of regulating the pore structure of the graphene electrode is achieved by the heated gas produced by the salt, which has great universality.
- Example 17 The cut thickness of the graphene electrode in Example 1 was adjusted to 100 ⁇ m, and the rest was the same as in Example 1.
- Example 18 The cut thickness of the graphene electrode in Example 1 was adjusted to 200 ⁇ m, and the rest was the same as in Example 1.
- Example 19 The cut thickness of the graphene electrode in Example 1 was adjusted to 300 ⁇ m, and the rest was the same as in Example 1.
- Example 20 The cut thickness of the graphene electrode in Example 1 was adjusted to 600 ⁇ m, and the rest was the same as in Example 1.
- Example 21 The cut thickness of the graphene electrode in Example 1 was adjusted to 800 ⁇ m, and the rest was the same as in Example 1.
- the graphene-based thick-density electrode prepared in Examples 1, 14-18 was pressed on a current collector stainless steel mesh, and two electrodes were carried out under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. test.
- the thickness of the graphene electrode, the mass specific capacity and the volume specific capacitance of the electrode, and the volumetric energy density of the device are shown in Table 5.
- the thickness of the graphene electrode has a great influence on the mass specific capacity, the volume specific capacity, and the volume energy density of the device.
- the electrode When the electrode is too thin, the electrode has a higher mass specific capacity and volume specific capacity due to the smoother ion transport and storage, but the too thin electrode causes the electrode active material to have a low occupancy rate in the entire device, and the folded device
- the volumetric energy density is low; when the electrode is too thick, the electrolyte ions are difficult to pass through.
- the specific capacity of the electrodes is very low, which also leads to a lower volumetric energy density of the device.
- Example 22 The zinc chloride aqueous solution in Example 1 was adjusted to an aqueous potassium hydroxide solution, and the obtained graphene and the conductive carbon black and the binder were made into an electrode at a mass ratio of 8:1:1, and the rest were the same as in Example 1. .
- Example 23 The zinc chloride aqueous solution of Example 1 was adjusted to an aqueous sodium carbonate solution, and the obtained graphene and the conductive carbon black and the binder were formed into an electrode at a mass ratio of 8:1:1, and the rest were the same as in Example 1.
- the graphene-based thick-density electrode prepared in Examples 1, 22, and 23 was pressed on a current collector stainless steel mesh to carry out two electrodes under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. test.
- the yield of the porous graphene, the specific surface area of the graphene, the volume specific capacitance of the electrode, and the capacity retention ratio of the electrode material at a large current are shown in Table 6.
- the etched bases and salts (potassium hydroxide and sodium carbonate in Examples 22 and 23) reacted significantly with graphene during heating, as compared to the gassable salt.
- this method is not suitable for a large number of graphene materials Volume production.
- the graphene block can not maintain its bulk structure, the density is greatly reduced, but the specific surface area is not significantly improved, so its volumetric specific capacitance is small.
- the graphene material prepared by the etchant requires an electrode preparation process and cannot maintain its three-dimensional structure, so that poor rate performance is exhibited. From the above analysis, we can conclude that compared with the etchant, the gas-forming salt can make the pore-forming effect of graphene more obvious, and the obtained product has higher yield, larger density and superior rate characteristics.
- Example 24 The three-dimensional hydrogel precursor in Example 1 was adjusted to a two-dimensional graphene sheet, and a two-dimensional graphene material was prepared by compounding a gas salt with graphene, and the obtained graphene and conductive carbon black were adhered. The junction was made into an electrode at a mass ratio of 8:1:1, and the rest was the same as in Example 1. Capacitance performance test:
- the graphene-based thick-density electrodes prepared in Examples 1 and 24 were pressed against a current collector stainless steel mesh, and subjected to a two-electrode test under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system.
- the density of the porous graphene, the specific surface area of the graphene, the volume specific capacitance of the electrode, and the capacity retention ratio of the electrode material at a large current are shown in Table 7.
- the graphene precursor was adjusted to a sheet of two-dimensional graphene, and the obtained porous graphene was a lamellar graphene, which was a powder graphene, which was light in density and small in volumetric capacity.
- the density of the electrode is significantly improved, and High volume capacity and capacity retention at high rates. From the above analysis, we can get: Compared with the two-dimensional graphene sheet, the three-dimensional graphene hydrogel is used as the precursor, and the obtained product can maintain the bulk morphology, the density is high, the volume specific capacity is high, and the high ratio is high. The capacity retention rate is high.
- Example 25 The cleaning solvent in Example 1 was adjusted to deionized water, and the rest was the same as in Example 1.
- Example 26 The mixture after the heat treatment in Example 1 was washed without using a washing solvent, and was directly applied to the electrode material, and the rest was the same as in Example 1.
- the graphene-based thick-density electrode prepared in Examples 1, 25, and 26 was pressed on a current collector stainless steel mesh, and subjected to two-electrode test under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. .
- the density of the obtained graphene material, the specific surface area of graphene, the volume specific capacitance of the electrode, and the capacity retention ratio of the electrode material at a large current are shown in Table 8.
- the heat-treated mixture was washed with dilute hydrochloric acid and deionized water, respectively, in comparison with the unwashed material, and it can be seen that the step of washing has a secondary pore-forming effect on the graphene material.
- the cleaning process can increase the specific surface of the electrode material, increase the pore structure of the material, and further improve the electrochemical performance of the electrode.
- Example 27 The graphite oxide powder in Example 1 was adjusted to nitrogen-doped graphene, and the rest was the same as in Example 1.
- Example 28 The graphite oxide powder in Example 1 was adjusted to porous graphene, and the rest was the same as in Example 1.
- the graphene-based thick-density electrode prepared in Examples 1, 27, and 28 was pressed on a current collector stainless steel mesh to perform two-electrode test under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. .
- the density of the obtained graphene material, the specific surface area of graphene, the volume specific capacitance of the electrode, and the capacity retention ratio of the electrode material at a large current are shown in Table IX.
- the graphene raw material before hydrothermal reduction is adjusted to modified graphene (nitrogen-doped graphene) and porous graphene, and the obtained electrode material also has a high capacitance value under high current charge and discharge. Has a high capacity retention rate.
- the method can also be applied to the regulation of three-dimensional pore structure based on precursors of different graphene derivatives, and has certain universality.
- Example 29 The hydrothermal reduction in the process of preparing the graphene hydrogel in Example 1 was adjusted to be reduced by urea, and the rest was the same as in Example 1.
- Example 30 The hydrothermal reduction in the process of preparing the graphene hydrogel in Example 1 was adjusted to be reduced with sodium hydrogen sulfite, and the rest was the same as in Example 1.
- Example 31 The hydrothermal reduction in the process of preparing the graphene hydrogel in Example 1 was adjusted to be reduced with hydroiodic acid, and the rest was the same as in Example 1.
- the graphene-based thick-density electrode prepared in Example 1, 29-31 was pressed on a current collector stainless steel mesh and subjected to two-electrode test under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. .
- the density of the obtained graphene material, the specific surface area of graphene, the volume specific capacitance of the electrode, and the capacity retention ratio of the electrode material are shown in Table 10.
- the graphene oxide dispersion liquid prepared by the above method has a high capacitance value and excellent rate characteristics in a different reduction form (hydrothermal reduction, reduction of a reducing agent). Therefore, our proposed method of pore regulation is also feasible for three-dimensional graphene hydrogels prepared by different reduction methods.
- Example 32 The heating atmosphere in Example 1 was adjusted to nitrogen gas, and the rest was the same as in Example 1.
- Example 33 The heating atmosphere in Example 1 was adjusted to ammonia gas, and the rest was the same as in Example 1.
- the graphene-based thick-density electrode prepared in Example 1, 30, 31 was pressed on a current collector stainless steel mesh, and subjected to two-electrode test under an ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) system. .
- the density of the obtained graphene material, the specific surface area of graphene, the volume specific capacitance of the electrode, and the capacity retention ratio of the electrode material at a large current are shown in Table 11.
- the inert atmosphere and the reducing atmosphere in the heat treatment process have little effect on the obtained graphene material, and the electrode materials all exhibit high capacitance values and excellent rate characteristics. Therefore, the method for controlling the pore size of the graphene material has certain universality for different heat treatment atmospheres.
- Table 8 lists the mass ratio capacitance, volume ratio capacitance, electrolyte system, electrode thickness, and volume energy density of the device, as shown in Table 12.
- Table 8 shows a comparison of specific capacitance values, electrode thicknesses, and device volume energy densities of the graphene-based thick-density electrode prepared in Example 1 of the present invention and a portion of the reported electrode material. It can be seen from the above table that the graphene-based thick-density electrode prepared by the method proposed in the present invention can achieve a very high electrode thickness of 400 ⁇ m and has a high volumetric energy density, which is much higher than the above. Electrode material.
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Abstract
L'invention concerne un procédé de préparation d'une électrode épaisse et dense à base de graphène. Le procédé comprend les étapes suivantes pour la préparation d'un hydrogel de graphène, le mélange du graphène et d'un composant de sel, la formation et l'élimination de gaz du composant de sel, et la préparation de l'électrode épaisse et dense à base de graphène. Le procédé selon l'invention permet de préparer un bloc de graphène poreux tridimensionnel en utilisant l'action porogène d'un sel gazogène sur un réseau de graphène pendant le chauffage. Par rapport aux autres procédés formant des pores, le sel gazogène n'attaque pas le graphène pendant le chauffage, le rendement du graphène obtenu est élevé, et le procédé est approprié pour la production en masse de matériaux de graphène poreux ; le gaz généré après chauffage étant éliminé, le graphène obtenu comporte donc peu d'impuretés et démontre une grande pureté ; une petite quantité des impuretés restantes occupe les pores du graphène, et un effet porogène secondaire est obtenu sur le réseau de graphène après lavage. Le graphène a une structure en bloc tridimensionnelle et peut être appliqué directement sur un matériau d'électrode, l'électrode étant plus épaisse et plus dense, et l'étape consistant à préparer une électrode à partir de graphène pulvérulent est également évitée.
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