WO2017183664A1 - Composition agricole/horticole - Google Patents

Composition agricole/horticole Download PDF

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Publication number
WO2017183664A1
WO2017183664A1 PCT/JP2017/015765 JP2017015765W WO2017183664A1 WO 2017183664 A1 WO2017183664 A1 WO 2017183664A1 JP 2017015765 W JP2017015765 W JP 2017015765W WO 2017183664 A1 WO2017183664 A1 WO 2017183664A1
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Prior art keywords
compound
agricultural
group
atom
horticultural
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PCT/JP2017/015765
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English (en)
Japanese (ja)
Inventor
寛之 萩原
誠也 櫻井
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三井化学アグロ株式会社
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Priority to JP2018513200A priority Critical patent/JP6683804B2/ja
Publication of WO2017183664A1 publication Critical patent/WO2017183664A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

Definitions

  • the present invention relates to a novel combination agricultural and horticultural composition and a method for controlling plant diseases or plant pests using the composition.
  • Torprocarb according to the present invention is a diamine derivative that exhibits a plant disease control action, and has been found to exhibit a high control effect especially against rice blast (Pyricularia oryzae) (WO2005 / 042474 (Patent Document 1)). ). Moreover, in WO2006 / 106811 (patent document 2), a pesticidal composition containing one or more compounds selected from the group consisting of a diamine derivative containing tolprocarb and other fungicides, insecticides and acaricides, and A method for controlling pests using them is disclosed.
  • Boscalid related to the present invention is CAS No. 188425-85-6, which is described as an SDHI agent in FRAC Code List 2015 (Non-Patent Document 1) and is known as a bactericidal agent. Further, a mixture (trade name: Signum) with pyraclostrobin, which is a strobilurin-based compound, is marketed, and its effect as a bactericidal agent is known.
  • Pyraziflumid is a known compound described as compound 3-21 in WO2007 / 072999 (patent document 3), and it is apple black scab, cucumber gray mold, barley powdery mildew (Blumeria graminis), wheat red rust. Disinfecting activity against diseases (Puccinia recondita) is disclosed.
  • Patent Document 4 an azole fungicide, a strobilurin fungicide, an amide fungicide, a heterocyclic fungicide, a carbamate fungicide, a copper agent with pyraziflumide as a main agent.
  • Guanidine fungicides, antibiotics, isoprothiolane, cyflufenamide, simoxanyl, fluorimido and tolfenpyrad as co-agents are disclosed, pyraziflumid and azoxystrobin, chlorothalonil, basic copper sulfate, fluorimide, and thiophanate methyl And the bactericidal action of the admixture.
  • Fluopyram is a CAS No. 658066-35-4, a compound known as an SDHI agent in FRAC Code List 2015 (Non-patent Document 1), and known as a bactericidal agent.
  • a mixed agent trade name: Luna® Sensation
  • trifloxystrobin ⁇ which is a strobilurin-based compound, is sold, and its effect as a bactericide is known.
  • Patent Document 5 discloses the bactericidal action of a mixed agent with isophetamide (Isofetamid) as a main ingredient, for example, difenoconazole, which is an azole compound, and pyraclostrobin, which is a strobilurin compound. Has been.
  • Bixafen is a CAS No. No. 581809-46-3, which is described as an SDHI agent in FRAC Code List 2015 (Non-Patent Document 1) and is known as a bactericidal agent.
  • Benzovindiflupyr is a known compound described in compound 13.01 in WO 2007/048556 (Patent Document 6), and has disclosed, for example, bactericidal activity against wheat red rust (Puccinia recondita), WO 2008/131901 (Patent Document 7) discloses a mixture containing benzovindiflupyr as a main agent and various antibacterial agents such as strobilurin and azole, for example.
  • Benzovindiflupyr (compound) A-1.1) and azoxystrobin, picoxystrobin, fludioxonil, cyprodinil Fungicidal action of admixture with is disclosed.
  • Fluxapyroxad is a CAS No. This compound is known as 907204-31-3, and is described as an SDHI agent in FRAC Code List 2015 (Non-patent Document 1) and is known as a bactericidal agent. Penflufen is a CAS No. This compound is known as 494793-67-8, and is described as an SDHI agent in FRAC Code List 2015 (Non-patent Document 1), and is known as a bactericidal agent.
  • Sedaxane is a CAS No. Is a compound known as 87497-67-6, and is described as an SDHI agent in FRAC Code List 2015 (Non-patent Document 1).
  • Sedaxane is a known compound disclosed as a compound Ia (trans), Ib (cis) or Ic (racemic) in WO2006 / 015865 (Patent Document 8).
  • a mixture with a pyrrole fungicide, fludioxonil, is disclosed and a bactericidal action is disclosed.
  • Isopyrazam is a CAS No. Is a compound known as 881685-58-1 and is described as an SDHI agent in FRAC Code List 2015 (Non-Patent Document 1). Isopyrazam is a known compound disclosed as Compound Ic in WO2006 / 037632 (Patent Document 9), and is composed of, for example, azoxystrobin, which is a strobilurin-based fungicide, using isopyrazam as a main ingredient. And a bactericidal action are disclosed.
  • Compound B1-11 is a known compound described as Compound 1 in Claim 1, Examples 1 to 13 of WO1992 / 012970 (Patent Document 10), or in WO2012 / 084812 (Patent Document 11).
  • WO1992 / 012970 discloses a bactericidal action against apple black scab (Apple Scab; Venturia inaequalis), and WO2012 / 084812 (Patent Document 11) discloses a bactericidal action against wheat powdery mildew.
  • Patent Document 12 discloses the bactericidal action of a mixture of compound B1-11-1 included in compound B1-11 as a main ingredient and mandestrobin, which is a strobilurin-based compound. Has been.
  • Compound B1-12 is a known compound disclosed in Synthesis Example P3 of WO2010 / 063700 (Patent Document 13). For example, antibacterial activity against gray mold fungus (Botrytis cinerea) is disclosed. Further, in WO2014 / 016279 (Patent Document 14), the bactericidal action of a mixed agent with compound B1-12 as a main ingredient and azoxystrobin, which is a strobilurin-based compound, or isopyrazam, which is an SDHI agent, is disclosed. Has been.
  • Compound B1-13 is a known compound disclosed as compound 29 in WO2010 / 130767 (Patent Document 15), and discloses, for example, bactericidal activity against apple black spot disease (Venturia inaequalis). Further, in WO2012 / 143127 (Patent Document 16), a bactericidal action of a mixture of compound B1-13 as a main ingredient with prothioconazole, which is a strobilurin-based compound, and fluxapyroxad, which is an SDHI agent. Is disclosed.
  • Compound B2-1 was prepared as compound No. 1 in compound A-7, Synthesis Example 1 or Examples 1 and 3 in Table A in WO2009 / 077443 (Patent Document 17).
  • Patent Document 17 1, a known compound disclosed as bactericidal activity against, for example, wheat red rust (Puccinia itrecondita).
  • WO2012 / 022729 discloses compound B2-1 as compound I, and discloses the bactericidal action of a mixture with epoxiconazole, which is an azole compound, with compound I as the main ingredient. Has been.
  • Compound B2-2 is a known compound included in the compounds claimed in WO2010 / 149414 (Patent Document 19).
  • compound B2-2 is disclosed as compound I-22, and sterilization of an admixture with compound I-22 as a main ingredient, for example, Boscalid (SDHI agent) The effect is disclosed.
  • SBHI agent Boscalid
  • Compound B2-3 is a known compound that is included in the compounds claimed in WO2010 / 149414 (Patent Document 19).
  • Compound B2-4 is a known compound disclosed in WO2012 / 165499 (Patent Document 21), for example, as compound (1-1a), and discloses bactericidal activity against wheat red rust (Puccinia recondita), for example.
  • Compound B2-4 is a known compound disclosed as Compound I-1 or I-2 in WO2014 / 061197 (Patent Document 22).
  • Compound B-1 and I-2 are combined with Fluxa, an SDHI agent. The bactericidal action of admixtures with pyroxad is disclosed.
  • Etaconazole is available from CAS No. This compound is known as 60207-93-4, is described as a DMI agent in FRAC Code List 2015 (Non-patent Document 1), and is known as a disinfectant. Benalaxyl-M is available from CAS No. This compound is known as 98243-83-5, and is described as a phenylamide-based fungicide in FRAC Code List 2015 (Non-patent Document 1), and is known as a fungicide.
  • Furalaxyl is available from CAS No. It is a compound known as 57646-30-7, described in FRAC Code List 2015 (Non-Patent Document 1) as a phenylamide fungicide, and is known as a fungicide.
  • Amethoctradin is a CAS no. It is a compound known as 865318-97-4, and is described as a QOSI (Quinone outside Inhibitor, stigmatellin binding type) fungicide in FRAC Code List 2015 (Non-Patent Document 1), and is known as a fungicide.
  • Metrafenone is a CAS No. This compound is known as 220899-03-6, and is described as an allyl phenyl ketone fungicide in FRAC Code List 2015 (Non-patent Document 1) and is known as a fungicide. Pyriophenone is a CAS no. This compound is known as 688046-61-9, and is described as an allyl phenyl ketone fungicide in FRAC Code List 2015 (Non-patent Document 1), and is known as a fungicide.
  • Proquinazid is a CAS No. It is a known compound as 189278-12-4, and is described as an azanaphthalene fungicide in FRAC Code List 2015 (Non-patent Document 1), and is known as a fungicide.
  • Flutianil is a CAS No. This compound is known as 958647-10-4 and is described as a thiazolidine-based fungicide in FRAC Code List 2015 (Non-patent Document 1), and is known as a fungicide.
  • Cyflufenamide is a CAS No. This compound is known as 180409-60-3 and is described as a phenylacetamide fungicide in FRAC Code List 2015 (Non-patent Document 1) and is known as a fungicide.
  • Oxathiapiprolin is a known compound disclosed in Table 2 of WO2008 / 013925 (Patent Document 23). Further, in WO2009 / 055514 (Patent Document 24), a mixture of oxathiapiproline as a main ingredient, for example, an SDHI agent, boscalid, or a strobilurin fungicide, azoxystrobin. Disclosed and disinfecting activity is disclosed.
  • Varifenate is a CAS No. It is a compound known as 283159-90-0, and is described as a CAA (Carboxylic Acid Amides) fungicide in FRAC Code List 2015 (Non-Patent Document 1) and is known as a fungicide.
  • Picarbutrazox is a known compound disclosed as compound (3) -8 in WO2003 / 016303 (Patent Document 25), and for example, a bactericidal action against grape downy mildew (Plasmopara viticola) is disclosed. ing.
  • WO2009 / 119072 discloses a mixture of Picarbutrazox as a main ingredient with, for example, chlorothalonil, and discloses bactericidal activity.
  • Compound B4-10 is a known compound disclosed as Compound 3 in WO2013 / 037717 (Patent Document 27).
  • bactericidal activity against Phytophthora infestans is disclosed.
  • Compound B4-11 is a known compound disclosed as Compound A in WO2010 / 094728 (Patent Document 28).
  • Compound B4-11 is used as a main agent, for example, a stroxylin-based fungicide, azoxystrobin.
  • Admixtures are disclosed, for example, bactericidal activity against tomato blight (Phytophthora infestans).
  • Compound B4-12 is a known compound disclosed in Table 1 of WO2005 / 121104 (Patent Document 29). Further, WO2014 / 013841 (Patent Document 30) discloses compound B4-12 as a main ingredient and a mixture with mandestrobin, which is a strobilurin-based compound, and is, for example, sterilized against wheat red snow rot (Microdocium nivale). Activity is disclosed.
  • Compound B4-13 is a known compound disclosed in Table 4 of WO2007 / 066601 (Patent Document 31).
  • Patent Document 32 discloses a compound B4-13 as a main agent, for example, a mixture with SDHI agent, fluxapyroxad, for example against wheat leaf blight (Mycosphaerella graminicola) Disinfecting activity is disclosed.
  • Compound B4-14 is a known compound disclosed as Compound 280 in Synthesis Example 13 of WO2009 / 137538 (Patent Document 33). For example, a bactericidal action against grape downy mildew (Plasmoparamviticola) is disclosed. Further, in WO2011 / 056463 (patent document 34), compound B4-14 is disclosed as compound 181, and a compound with compound 4-14 as a main agent, for example, bixafen (Bixafen), which is an SDHI agent, is disclosed. Disinfecting activity is disclosed.
  • Compound B4-15 is a known compound disclosed in WO2012 / 031061 (Patent Document 35) as Compound 81, Compound 129, Compound 136, Compound 239, or Compound 240 that can be produced in Synthesis Example 7.
  • a bactericidal action against gray mold (Botrytis cinerea) is disclosed.
  • a compound B4-15 as a main ingredient and a mixture with, for example, a resistance inducer, probenazole, are disclosed, and bactericidal activity is disclosed.
  • Compound B4-16 is a known compound disclosed as Compound 1 or Compound 179 in WO2009 / 099442 (Patent Document 36), and for example, a bactericidal action against wheat leaf blight (Septoria tritici) is disclosed.
  • Patent Document 37 discloses a mixture of, for example, epoxiconazole, which is an azole compound, with Compound B4-16 as a main ingredient, and disinfecting activity.
  • Compound B4-17 is a known compound disclosed as Compound 23 in WO2003 / 035617 (Patent Document 38).
  • bactericidal activity against wheat leaf blight (Seotoria tritici) is disclosed.
  • WO2011 / 044423 (Patent Document 39) discloses a compound B4-17 as a main ingredient and, for example, an admixture with epoxiconazole, which is an azole compound, and discloses bactericidal activity.
  • Dipymetitrone is a known compound disclosed as Compound 1 in WO2010 / 043319 (Patent Document 40), and discloses, for example, bactericidal activity against tomato blight (Phytophthora infestans).
  • Patent Document 41 discloses a mixture of dipimethitron as a main ingredient and, for example, an azoxystrobin, which is a strobilurin-based compound, and discloses a bactericidal action.
  • Compound B4-19 is a known compound disclosed in Synthetic Example 10 or Synthetic Example 25 in WO2011 / 081174 (Patent Document 42), and discloses, for example, bactericidal activity against apple black spot disease (Venturia inaequalis). Also, WO2013 / 047441 (Patent Document 43) discloses a compound B4-19 as a main ingredient, for example, a mixture of cyflufenamide (Cyflufenamid) and an azole fungicide, triflumizole (Triflumizole), and discloses a bactericidal action. ing.
  • Compound B4-20 or B4-21 is a known compound disclosed in Synthesis Example 1 or Synthesis Example 2 of WO2012 / 069652 (Patent Document 44).
  • An admixture with azoxystrobin which is a strobilurin-based compound, is disclosed, for example, a bactericidal action against tomato ring rot (Alternaria solani) is disclosed.
  • Compound B4-22 is a known compound disclosed as Compound 1 in WO2009 / 156098 (Patent Document 45), and for example, bactericidal activity against tomato alternaria (Alternaria / Tomato) is disclosed.
  • WO2011 / 080044 Patent Document 46
  • a compound B4-22 as a main ingredient and a mixture with, for example, prothioconazole, which is an azole compound, are disclosed, and a bactericidal action is disclosed.
  • Phosphorous acid is a CAS No. It is a compound known as 10294-56-1.
  • Phosphorous acid and its salt are described in FRAC Code List 2015 (Non-patent Document 1) as phosphite-based fungicides and are known as fungicides.
  • Non-patent Document 3 describes, for example, antibacterial activity against Aspergillus flavus.
  • Example 4 of WO2015 / 034359 discloses a bactericidal action against Pythium aphanidermatum, which is known as a bactericidal agent.
  • Imicyafos is a CAS No. 140163-89-9 is a known compound.
  • the journal of Nematology 2011 Mar; 43 (1): 1-6 (Non-Patent Document 4) describes insecticidal activity against Nematode nematode (Pratylenchus penetrans). Known as an insecticide.
  • Spinetoram is a CAS No. It is a compound known as 187166-40-1 or 187166-15-0, and is described as a spinosyn insecticide in IRAC Mode of Action Classification SchemeVersion 8.1 (Non-patent Document 2). is there.
  • Cyflumetofen is a CAS No. This compound is known as 400082-07-7, and is described as a beta-ketonitrile insecticide in IRAC Mode of Action Classification Scheme Version 8.1 (Non-patent Document 2), and is known as an insecticide. Cyenopyrafen is a CAS no. This compound is known as 560121-52-0, and is described as a beta-ketonitrile insecticide in IRAC Mode of Action Classification Scheme Version 8.1 (Non-patent Document 2), and is known as an insecticide.
  • Spirotetramat is a CAS no. This compound is known as 203313-25-1, and is described as a tetronic acid / tetramic acid insecticide in IRAC Mode of Action Classification Scheme Version 8.1 (Non-patent Document 2), and is known as an insecticide. Sulfoxaflor is a known compound disclosed in Synthesis Example II of WO2007 / 095229 (Patent Document 48), and has disclosed insecticidal activity.
  • Pirafluprole is a CAS No. This compound is known as 315208-17-4, and is described as a phenylpyrazole insecticide in SHIBUYA INDEX (2014) Index of Pesticides ISBN code: 9784881371787 (Non-patent Document 5), and is known as an insecticide.
  • Pyriprole is a CAS No. It is a compound known as 394730-71-3, and is described as a phenylpyrazole insecticide in SHIBUYA INDEX (2014) Index of Plasticides ISBN code: 978488137371787 (Non-patent Document 5), and is known as an insecticide.
  • Thiosultap is a CAS No. This compound is known as 98968-92-4, and is described as a nereistoxin family insecticide in IRAC Mode of Action Classification Scheme Scheme 8.1 (Non-patent Document 2) and is known as an insecticide.
  • Monfluorothrin is a CAS No. 609346-29-4 is a known compound.
  • Fluenesulfone is a CAS No. 318290-98-1 is a compound known as Pesticide Biochemistry and Physiology 2014 Feb; 109: 44-57 (Non-patent Document 7), which describes the insecticidal activity against Caenorhabditis elegans. It is known.
  • Thioxazafen is a CAS No. 330459-31-9, which is a compound known as SHIBUYA INDEX (2014) Index of Pesticides ISBN code: 97884881371787 (Non-patent Document 5) and is known as an insecticide.
  • Afidopyropene is a CAS No. 915972-17-7, a compound known as Pesticide Biochemistry and PhysiologyVolume 107, Issue 2, Octover 2013, Pages 169-176 (Non-patent Document 8), which describes the activity of pea aphid against the pea aphid And is known as an insecticide.
  • Full hexafon is CAS No. 1097630-26-6, a compound known as Pesticide Biochemistry and Physiology Volume 121, June 2015, Pages 122-128 (Non-patent Document 6), which is known as an insecticide. is there.
  • Fullfiprole is CAS No. This compound is known as 704886-18-0.
  • Mepafluthrin is available from CAS No. It is a compound known as 915288-13-0.
  • Tetramethylfluthrin is available from CAS No. It is a compound known as 84937-88-2. Pyrifluquinazone is a CAS No. This compound is known as 337458-27-2, and is described in Pesticide Biochemistry and Physiology Volume 121, June 2015, Pages 122-128 (Non-patent Document 6), and is known as an insecticide.
  • Dichloromezotiz is a CAS No. It is a compound known as 1263629-39-5.
  • Compound B4-48 is a known compound disclosed as Compound No. 3 in Table 1 of JP-A-5-78323 (Patent Document 50), and discloses the insecticidal activity of analogs.
  • Compound B4-49 is a known compound disclosed as Compound No. 6-004 and Synthesis Example 32 in WO2007 / 026965 (Patent Document 51), and discloses insecticidal activity.
  • the object of the present invention is to provide a new control combination that exhibits a high control effect on plant pests, exhibits high activity even when the amount of active ingredients administered to the pest habitat is low, and further suppresses phytotoxicity to plants. It is to provide an agricultural and horticultural composition and a method for controlling plant diseases or plant pests using the composition.
  • the combination of the present invention is a novel invention that is not disclosed in any of Patent Documents 1 to 51 and Non-Patent Documents 1 to 8.
  • the present invention is a new combination agricultural and horticultural composition that exhibits a high control effect against plant pests, exhibits high activity even when the amount of active ingredient administered to the pest habitat is low, and further suppresses phytotoxicity to plants.
  • the present invention relates to a method for controlling plant diseases or plant pests using the product and its composition.
  • the present invention 1) A farm characterized by containing (a) tolprocarb and (b) at least one compound selected from the compounds included in the following compound groups B1 to B4 or a salt thereof as active ingredients.
  • Horticultural compositions (B1-1) Boscalid; (B1-2) Pyraziflumid; (B1-3) fluopyram; (B1-4) Isofetamide (Isobetamid); (B1-5) Bixafen; (B1-6) Benzovindiflupyr; (B1-7) Fluxapyroxad; (B1-8) Penflufen; (B1-9) Sedaxan; (B1-10) Isopyrazam; (B1-11) (Wherein Rb2 represents a hydrogen atom or a fluorine atom); (B1-12) ; And (B1-13) ; Compound group B1 consisting of (B2-1) (Wherein Rb3 represents a hydrogen atom or a fluorine atom); (B2-2
  • a method for controlling plant diseases or plant pests which comprises applying the agricultural or horticultural composition according to any one of 1) to 7) to plants, seeds or soil, 9) Apply the following agricultural and horticultural compositions (i) and (ii) simultaneously to plants, seeds or soil, or apply one of the following agricultural and horticultural compositions (i) and (ii) to plants, seeds or soil.
  • Agricultural and horticultural composition a composition comprising tolprocarb (a) as an active ingredient
  • Agricultural and horticultural composition ii): the compound (b) described in any one of 1) to 3) as an active ingredient Containing composition, About.
  • the agricultural and horticultural composition of the present invention is a compound selected from tolprocarb or a specific compound included in compound B1 group to compound B4 group (including compound B11 group to compound B41 group and compound B12 group to compound B42 group). Alternatively, it exhibits an excellent control effect (synergistic control effect) that cannot be predicted from each individual component of the salt. Furthermore, the agricultural and horticultural composition suppresses phytotoxicity to plants.
  • agro-horticultural composition as the first invention and “a plant disease or plant pest control method” as the second invention.
  • composition for agriculture and horticulture which is the first invention, is characterized by combining tolprocarb and at least one compound selected from the compounds included in compound groups B1 to B4 or a salt thereof (partner agent in the present invention). To do.
  • tolprocarb and the partner in the present invention are known compounds, and commercially available products are used.
  • the agricultural and horticultural composition of the present invention can be produced according to a conventional method. That is, the plant disease control composition can be prepared by mixing a composition containing tolprocarb and the active ingredient of the partner in the present invention to produce a composition containing both active ingredients. A composition containing both active ingredients may be produced by adding other active ingredients to the composition containing. Usually, the said composition for agriculture and horticulture is manufactured using the mixture which mixed both active ingredients.
  • the agricultural and horticultural composition of the present invention can be used by further mixing a carrier with the obtained agricultural and horticultural composition, and if necessary, a surfactant, a wetting agent, a fixing agent, a thickener.
  • the pack agent means a preparation in which granules, wettable powder and the like are packaged with a water-soluble film.
  • the content of tolprocarb as an active ingredient in these preparations is usually in the range of 0.005 to 99% by weight, preferably in the range of 0.1 to 90%, and more preferably, It is in the range of 0.3 to 80%.
  • the content of the partner in the present invention as an active ingredient in these preparations is usually in the range of 0.005 to 99% by weight, preferably in the range of 0.1 to 90%. Yes, and more preferably 0.3 to 80%.
  • the total content of tolprocarb and the partner in the present invention is usually in the range of 0.01 to 99%, preferably in the range of 0.1 to 90%, and more preferably in the range of 0.1 to 90%. It is in the range of 3 to 80%.
  • the mixing ratio of tolprocarb and the partner in the present invention is usually in a weight ratio of 0.01 to 1,000, preferably 0.02 to 100, in the ratio of the partner in the present invention to tolprocarb. More preferably, the ratio is 0.05 to 10.
  • the total content of tolprocarb and the partner in the present invention varies depending on the preparation form, and is appropriately selected. 1 to 80% by weight for flowables, 0.1 to 80% by weight for wettable powders, 0.01 to 30% by weight for powders, and 0. 0% for granules. 5 to 20% by weight, 1 to 50% by weight for emulsions, and 1 to 80% by weight for packs.
  • the preferred total content of tolprocarb and the partner in the present invention is usually 5 to 80% by weight for wettable powders, 1 to 60% by weight for flowables, and 1 to 80% for granular wettable powders.
  • % By weight, 0.05 to 10% by weight for powders, 2 to 15% by weight for granules, 5 to 50% by weight for emulsions, 5 to 80% by weight for packs It is.
  • Further preferred total contents are usually 10 to 80% by weight for wettable powders, 5 to 50% by weight for flowables, 5 to 80% by weight for wettable powders, and for powders. 0.1 to 10% by weight, 2 to 10% by weight for granules, 5 to 20% by weight for emulsions, and 10 to 80% by weight for packs.
  • the content of the auxiliary agent is 0 to 80% by weight, and the content of the carrier is an amount obtained by subtracting the content of the active ingredient compound and the auxiliary agent from 100% by weight.
  • the carrier used in the above composition is a synthetic or natural inorganic or organic compounded to help the active ingredient reach the site to be treated and to facilitate the storage, transportation and handling of the active ingredient compound. It means a substance and can be used as a solid or liquid as long as it is usually used in agricultural and horticultural medicines, and is not limited to a specific one.
  • solid carrier examples include, for example, bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, amorphous silica, and ammonium sulfate; soy flour, wood flour, sawdust Plant organic substances such as wheat flour, lactose, sucrose, and glucose; or urea.
  • liquid carrier examples include aromatic hydrocarbons and naphthenes such as toluene, xylene and cumene; paraffinic hydrocarbons such as n-paraffin, iso-paraffin, liquid paraffin, kerosene, mineral oil and polybutene; Ketones such as acetone and methyl ethyl ketone; Ethers such as dioxane and diethylene glycol dimethyl ether; Alcohols such as ethanol, propanol and ethylene glycol; Carbonates such as ethylene carbonate, propylene carbonate and butylene carbonate; Non-protons such as dimethylformamide and dimethyl sulfoxide An organic solvent; or water.
  • aromatic hydrocarbons and naphthenes such as toluene, xylene and cumene
  • paraffinic hydrocarbons such as n-paraffin, iso-paraffin, liquid paraffin, kerosene, mineral oil and polybutene
  • Ketones such as acetone and methyl ethy
  • an adjuvant is used either alone or in combination depending on the purpose, taking into consideration the dosage form, processing method, etc. of the preparation. You can also.
  • the auxiliary agent include surfactants, binders, disintegrants, stabilizers, pH adjusters, antibacterial / antifungal agents, thickeners, antifoaming agents, and antifreeze agents.
  • surfactants used for the purpose of emulsifying, dispersing, spreading and / or wetting agricultural chemical formulations are, for example, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene fatty acid Formalin condensation of ester, polyoxyethylene resin acid ester, polyoxyethylene fatty acid diester, polyoxyethylene castor oil, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, polyoxyethylene alkyl phenyl ether , Polyoxyethylene polyoxypropylene block polymer, alkyl polyoxyethylene polyoxypropylene block polymer ether, alkylphenyl polyoxy Tylene polyoxypropylene block polymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene bisphenyl ether, polyoxyalkylene benzyl phenyl ether, polyoxyalkylene s
  • binder examples include sodium alginate, polyvinyl alcohol, gum arabic, CMC sodium or bentonite.
  • examples of the disintegrant include CMC sodium or croscarmellose sodium, and examples of the stabilizer include hindered phenol-based antioxidants, benzotriazole-based and hindered amine-based ultraviolet absorbers, and the like. .
  • Examples of the pH adjuster include phosphoric acid, acetic acid, and sodium hydroxide.
  • Examples of the antibacterial and antifungal agent include industrial bactericides such as 1,2-benzisothiazolin-3-one. It is done.
  • Examples of the thickener include xanthan gum, guar gum, CMC sodium, gum arabic, polyvinyl alcohol, or montmorillonite.
  • Examples of the antifoaming agent include silicone compounds.
  • Examples of the antifreezing agent include , Propylene glycol, ethylene glycol and the like. However, these adjuvants are not limited to the above.
  • Plant disease or plant pest control method Next, a plant disease or plant pest control method (sometimes simply referred to as “plant disease / pest control method” in this specification), which is a second invention, will be described.
  • the plant pest control method of the present invention can be carried out by applying the above-mentioned agricultural and horticultural composition to plants, seeds or soil.
  • compositions for agriculture and horticulture for example, foliage spraying treatment to plant individuals, seedling box treatment, spraying treatment on the soil surface, soil mixing after spraying treatment on the soil surface, injection treatment into the soil, Soil admixture after infusion treatment in soil, soil irrigation treatment, soil admixture after soil irrigation treatment, spraying treatment on plant seeds, smearing treatment on plant seeds, immersion treatment in plant seeds or powder on plant seeds For example, clothing processing.
  • foliage spraying treatment to plant individuals for example, seedling box treatment, spraying treatment on the soil surface, soil mixing after spraying treatment on the soil surface, injection treatment into the soil, Soil admixture after infusion treatment in soil, soil irrigation treatment, soil admixture after soil irrigation treatment, spraying treatment on plant seeds, smearing treatment on plant seeds, immersion treatment in plant seeds or powder on plant seeds
  • clothing processing for example, clothing processing.
  • the compositions of the present invention usually exhibit sufficient efficacy in any application method utilized by those skilled in the art.
  • plant disease pests In order to control plant diseases or plant pests (which may be simply referred to as “plant disease pests” in the present specification), (1) an agricultural and horticultural composition containing tolprocarb and a partner in the present invention as active ingredients Or (2) an agricultural and horticultural composition containing tolprocarb as an active ingredient and an agricultural and horticultural composition containing the partner in the present invention as an active ingredient, or (3) tolprocarb After applying any one of the composition for agriculture and horticulture containing as an active ingredient and the composition for agriculture and horticulture containing the other agent in this invention as an active ingredient, applying the other composition is mentioned. .
  • Time (period) until the other composition is sprayed after applying either one of the composition for agriculture and horticulture containing tolprocarb as an active ingredient and the composition for agriculture and horticulture containing the partner in the present invention as an active ingredient ) Is not particularly limited as long as it has an effect of controlling plant pests. For example, it is 1 minute to 2 weeks after applying any one of the compositions, and preferably any one of the compositions is applied. 5 minutes to 1 week, and more preferably 10 minutes to 3 days after applying any one of the compositions.
  • Which agricultural or horticultural composition is used first is not particularly limited as long as it has an effect of controlling plant pests, but it is appropriately selected according to the target plant pests, plants, and other environments related to application. Can be determined.
  • an agricultural and horticultural composition containing tolprocarb and the partner in the present invention as an active ingredient can be used to control plant pests.
  • the order of application, the order of application, the time until application (period), and the number of applications are not particularly limited as long as they have the effect of controlling plant pests, but the target plant pests, plants, and other environments related to application Depending on the situation, it can be appropriately selected and determined.
  • the agricultural and horticultural composition of the present invention can be prepared by containing tolprocarb and the partner of the present invention in a high concentration.
  • This high-concentration composition can be diluted with water and used as a spray liquid.
  • the composition for agricultural and horticultural use of the present invention can also be prepared as a mixture by mixing a composition containing tolprocarb in a high concentration and a composition containing the partner in the present invention in a high concentration at the time of use.
  • This high concentration composition can be diluted with water and used as a spray liquid (tank mix method).
  • the application amount and application concentration of the agricultural and horticultural composition containing tolprocarb and the partner in the present invention as an active ingredient are not particularly limited as long as they have an effect of controlling plant pests, and the target crops, target pests, pests are not limited.
  • the dosage form of the compound, the application method, various environmental conditions, and the like it can be appropriately selected and determined.
  • the amount of active ingredient is usually 10 to 10,000 g per hectare, and preferably 25 to 5,000 g per hectare.
  • the dilution ratio is usually 5 to 50,000 times, preferably 10 to 20,000 times. Yes, more preferably 15 to 10,000 times.
  • seed disinfection is performed using the composition, the amount used is usually 0.001 to 50 g, preferably 0.01 to 10 g, per 1 kg of seed.
  • the composition is applied to an appropriate carrier at an appropriate concentration. After dilution, the treatment can be performed. When contacting the said composition with a plant seed, you may immerse a plant seed in the said composition as it is.
  • the composition can be used after being diluted to an appropriate concentration in an appropriate carrier and then dipped, dressed, sprayed or smeared on plant seeds.
  • the amount of the composition used in the powder coating, spraying and smearing treatment is usually about 0.05 to 50%, preferably 0.1 to 30% of the dry plant seed weight. The amount used is not limited to these ranges, and can be determined by appropriately selecting according to the type of plant seed to be treated.
  • Suitable carriers include, for example, liquid carriers in organic solvents such as water or ethanol; inorganics such as bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, amorphous silica, ammonium sulfate, etc.
  • organic solvents such as water or ethanol
  • inorganics such as bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, amorphous silica, ammonium sulfate, etc.
  • vegetable organic substances such as soybean flour, wood flour, sawdust, wheat flour, lactose, sucrose, and glucose: or solid carriers such as urea can be mentioned, but are not limited thereto.
  • the plant individual means one that lives without exercising by photosynthesis.
  • rice, wheat, barley, corn, grape, apple, pear, peach, sweet cherry, oyster , Citrus, soybean, green beans, strawberry, potato, cabbage, lettuce, tomato, cucumber, eggplant, watermelon, sugar beet, spinach, sweet pea, pumpkin, sugar cane, tobacco, sweet pepper, sweet potato, taro, konjac, oilseed rape, cotton, sunflower, A tulip, chrysanthemum, turf, etc. are mentioned, but it is not limited to these.
  • the agricultural and horticultural composition of the present invention can be suitably used for controlling rice diseases or rice pests.
  • the plant seed in the present specification means one that stores nutrients for germination of young plants and is used for agricultural propagation.
  • corn, soybean, cotton, rice, sugar beet, wheat, Seeds such as barley, sunflower, tomato, cucumber, eggplant, spinach, sweet pea, pumpkin, sugar cane, tobacco, pepper, rapeseed; seeds such as taro, potato, sweet potato, konjac; edible lily, bulbs such as tulip, and raccoon Seed ball, etc .; or plants produced by artificial manipulation of genes, etc., for example, soy, corn, cotton, etc.
  • the agricultural and horticultural composition of the present invention can be suitably used for controlling rice seed diseases or rice seed diseases and pests.
  • composition of the present invention can be used in combination with other pesticides, acaricides, nematicides, fungicides, herbicides, plant growth regulators, and other agricultural chemicals, soil conditioners or fertilizers. It is also possible to prepare a mixed preparation with these.
  • fungicides insecticides, acaricides, nematicides include, for example, allethrin, tetramethrin, resmethrin, phenothrin, framethrin, permethrin, cypermethrin, deltamethrin, cyhalothrin, cyfluthrin, fenpropatrin, tralomethrin, cyclo Protorin, flucitrinate, fulvalinate, acrinatrin, tefluthrin, bifenthrin, enpentrin, beta cyfluthrin, cypermethrin, fenvalerate, esfenvalerate, flubrocitrinate, methfluthrin, profluthrin, dimefluthrin, fulbrocis linate, Silafluophene, insect repellent extract, etofenprox, halfenprox, DD
  • the agricultural and horticultural composition comprising the tolprocarb of the present invention as an active ingredient is applied to rice pests, other insecticides and fungicides exhibiting high effects on the main rice pests; Since mixing is useful for exerting an effect on a wider range of plant pests, tricyclazole, fusalide, kasugamycin, ferimzone, EDDP, isoprothiolane, penthiopyrad, tebufloquine, metminostrobin, orisatrobin, diclosimet , Thianidyl, probenazole, acibenzoral-S-methyl, isotianil, flutolanil, mepronil, pencyclon, azoxystrobin, validamycin, furametopil, dichromedin, tifluzamide, chlorantraniliprole, cimeconazole Benomyl, fludioxonil, iprodione, TPN, hydroxyisoxazole, o
  • composition and control method of the present invention are effective against, for example, the following types of plant pests. Examples of specific pests to be controlled by the present invention are shown below.
  • Plant diseases include, for example, rice blast (Pyricularia oryzae), blight (Thanatephorus cucumeris (Frank) Donk), sesame leaf blight (Cochliobolus miyabeanus), idiotic seedling (Gibberella seedling) spp., Fusarium spp., Trichoderma spp., Rhizopus spp., Rhizoctonia solani, etc., rice rot (Claviceps virens), smut (Tilletia barellayana) f.sp.tritici), rust disease (Puccinia st) iiformis; Puccinia graminis, Puccinia recondita, Puccinia hordei), Madarahabyo (Pyrenophora
  • Rhizoctonia spp Rhizoctonia spp, rust disease (Puccinia sorghi), sesame leaf blight (Cochliobolus heterostrohus), smut (Ustilago Mayolism), anthracnose (Colletotrichum gram) viticola), rust disease (Phakopsora ampelopsidis), powdery mildew (Uncinula necator), black rot (Elsinoe ampelina), late rot (Glomerella cinulata), black rot (Guibivalh disease) soot Spot disease (Zygophiala jamaicensis), gray mold disease (Botrytis cinereaa), shoot blight (Diaporthedium medusaea), purple leaf blight (Helicobasidium mumpa), white scab (Reselliria cinerea) disease , Black spot disease (Venturia inaequalis), spotted leaf defoliation (Alternaria altern
  • Preferable diseases for which the composition for agricultural and horticultural use of the present invention exerts effects include rice blast (Pyricularia oryzae) and rice leaf blight (Thanatephorus cucumeris (Frank) Donk), and particularly preferable diseases are rice.
  • rice blast Pane oryzae
  • rice leaf blight Tehanatephorus cucumeris (Frank) Donk
  • particularly preferable diseases are rice.
  • An example is rice blast (Pyricularia oryzae).
  • examples of the pests include, for example, Hari nematode: ANGUINIDAE, Bengrass nematode (Anguina agritis), Wheat nematode (Anguina tritici), Imogusaresenchu (Dylenchus destructor), and YL.
  • Pratylenchenidae such as Tyrenchorhynchus martini and Tyrenchorhynchus sp., Hirschmanniella imamuri, Rice Henrimuchu schmanniella oryzae), South Negu Saleh nematode (Pratylenchus coffeae), lily of the valley Negu Saleh nematode (Pratylenchus convallariae), chrysanthemum Negu Saleh nematode (Pratylenchus fallax), tea Negu Saleh nematode (Pratylenchus loosi), wheat Negu Saleh nematode (Pratylenchus neglectus), Northern Negu Saleh nematode (Pratylenchus penntrans), Negusaresenchu (Pratylenchus sp.), Etc., as HOPLOLAMIDAE, Namila nematode (Helicotyrenchus dihystera), Chara
  • DORYLAIMIDA LONGIDORIDAE, Longidorus martini, Longidorus sp., IDH , Trichodorus sp., Etc. Acarina (ACARINA): as TARSONEMIDAE, Chanohokoridani (Polyphagotarsonemus latus), cyclamen dust mites (Steneotarsonemau pallidus), such as Microstegium vimineum dust mites (Tarsonemus waitei), as PYEMOTIDAE, such as Shiramidani (Pyemotes ventricosus), as EUPODIDAE, such as Mugidani (Penthaleus major), As TENUIPALPIDAE, there is a grape spider spider mite (Brevipalpus lewisi), a tea spider spider mite (Brevipalpus obobatus), a pineapple spider spider mite (Dolichottranychus florodanus), an oyster Such
  • THYSANURA As LEPIMATATEDAE, Yamato Shimi (Ctenolepisma villosa), Shiiyo Shimi (Lepisma saccharina), Madara Shimi (Thermobia domestica), etc.
  • Orthoptera as BLATTIDAE, American cockroach (Periplaneta americana), black cockroach (Periplaneta fuliginosa), such as Yamato cockroach (Periplaneta japonica), as BLATTELLIDAE, German cockroach (Blattella germanica), such as Princess German cockroach (Blattella lituricollis), as TETTIGONIIDAE , Homocoryphis jezoensis, Homocoryhus lineeosus, GRYLLOTALPIDAE, Kelly (Gryllotalpa sp.), ACRIDIDAE, etc.
  • Thysanoptera (THYSANOPTERA): as THRIPIDAE, grasses thrips (Anaphothrips obscurus), thorns but-thrips (Chirothrips manicatus), tea Roh black thrips (Dendrothrips minowai), Hirazuhanaazamiuma (Frankliniella intonsa), lily flower thrips (Frankliniella lilivora), Croton thrips ( Heliotrips haemorrhoidalis, Cosmos thrips abdominalis, Soybean thrips (Mycterothrips glycines), Pseudoendendrot rips mori), yellow tea thrips (Scirtothrips dorsalis), red Obi thrips (Selenothrips rubrocinctus), rice thrips (Stenchaetothrips biformis), green onions black thrips (Thrips alli
  • HEMIPTERA As PENTATOMIDAE, Carpocoris purpureipennis, T. terridium moth, D. moss. Eysarcoris lewisi), Scarab beetle (Eysarcoris parvus), Shirahoshi stink bug (Eysarcoris ventralis), Glutenia physalis (Glaucias submuctus) Worms (Halyomorpha mista), Inekamemushi (Lagynotomus elongatus), order Hemiptera (Nezara antennata), southern green stink bug (Nezara viridula), Piezodorus stink bug (Piezodorus hybneri), Plautia crossota stali (Plautia stali), rice black bug (Scotinophara lurida) , Sardine stink bug (Stariodes iwasakii), etc., as COREIDAE (Cletus tri
  • ALYDIDAE RHOPALIDAE Aeschineles maculatus, Lichohysus hyalinus, etc.
  • LYGAEIDAE Caverelius sacchari vulgaris, Shi (Macropes obnubilus), Hirata gourd Naga bug (Pachybrachius luridus), Black-footed bombardier Naga bug (Paromius exguus), such as co spring gourd Naga bug (Togo hemipterus), as Pyrrhocoridae, red-spotted stink bug (Dysdercus cingulatus), Anthrenus red Hoshi stink bug (Dysdercus poecilus)
  • Kikugunbai Gakugunbai (Galeatus spinifrons), Yanagigunbai (Metasalis populi), Kusungumbai (Stephanitis fascicaria), Nashigumbai (Stephanitis sashii), Tsutsugumbai ephanitis pyr
  • Kurumigunbai Uhlerites latius
  • MIRIDAE Acyrthosiphon Miridae
  • Butyrate beard black Miridae Adelphocoris triannulatus
  • Koaokasumikame Apolygus lucorum
  • blacktip reef shark Ao Miridae Apolygus spinolai, red beetle turtle (Creontides pallidifer), tobacco turtle (Cyrtopeltis tennuis), giant beetle turtle (Ectometopterus micanthulus), black beetle turtle (Halticiell) us insularis), apple black Miridae (Heterocordylus flavipes), Makiba Miridae (Lygus disponsi), Madara Miridae (Lygus saundersi), sugar beet Miridae (orthotylus flavosparsus), Mugikasum
  • APHROPHORIDAE Maekiawafuki (Aphrophora costalis), Matsuawafuki (Aphrophora flavipes), Budouawafuki (Aphrophora intermedia), Princess lid ten Naga Awa butterbur (Clovia punctata), such as Hosoawafuki (Philaenus spumarius), as TETTIGELLIDAE, blacktip reef shark giant leafhoppers (Bothrogonia japonica), Cicella viridis, etc., CICADELLIDAE, Aguriahana quercus, Alantoidia aruneti, Apheliona ferruginea, Arboridia apicaris, Edwardsia flavocens, Empharma esco As for DELTOCEPHALIDAE, such as rice leafhopper (Thaia subrufa), citrus yellow leafhopper (Zyginella citri), pineto leafhopper (Macrosteles fascifonis), leafhopper
  • Lepidoptera (LEPIDOPTERA): Koumoriga (Endoclyta excrecens), macular bats (Endoclyta sinensis), white Ten bats (Palpifer sexnotata), Barahamaki (Acleris comariana), apple Coca summer fruit tortrix (Adoxophyes orana fasciata), smaller tea tortrix (Adoxophyes sp .), Apples brevipicanus, Midekakumonmonaki (Archips fuscopupraneus), Kakimon oyster (Archips xylostaneus), Bactra furfuranane, Asaha reipalpana), Kurimiga (Cydia kurokoi), chestnut green sink bur (Eucoenogenes aestuosa), oriental fruit moth (Grapholita molesta), Chahamaki (Homona magnanima), apple fruit moth (Hoshimoa adumbratana), soybean pod borer,
  • Hymenoptera Japanese bee wasp (Athalia japonica), bee (Athalia rosae tuficornis), apple bee (Arge mary), agula beco (Arge pagaur), D Diptera: Tipula aino, Bradysia agretis, Asphondylia sp., Ac (Dacus cucurbitae), D Cherry Leaf Spot fruit fly (Rhacochlaena japonica), Inemigiwabae (Hydrellia griseola), rice click Kimi Giwa fly (Hydrellia sasakii), cherry fruit fly (Drosophila suzukii), Inekimoguribae (Chlorops oryzae), Mugikimoguribae (Meromuza nigriven ris), rice leafminer (Agromyza oryzae), the pea (Chromatomyia horticola), eggplant leafminer (Liri
  • Formulation Example 1 Simple Emulsion 1 part of methanol (MeOH) was added to 9 parts of dimethyl sulfoxide (abbreviation DMSO) (solvent 1). To 1 part of the drug listed in Table 1 or 2, 200 parts of solvent 1 was added and dissolved to obtain simple emulsions. These simple emulsions were used alone, or toluprocarb-containing simple emulsions and other simple emulsions were mixed at a predetermined concentration and suspended in water, and used in the test.
  • DMSO dimethyl sulfoxide
  • Formulation Example 2 Granule (G1) 30 parts of Torprocarb, 22 parts of bentonite, 45 parts of talc and 3 parts of Solpol 5060 (surfactant: Toho Chemical Co., Ltd.) are uniformly kneaded, granulated with a basket granulator, dried and granulated 100 parts of the agent were obtained.
  • Formulation Example 3 Granule (G2) After mixing 15 parts of the present compound (B1-7), 60 parts of bentonite, 21 parts of talc, 1 part of sodium dodecylbenzenesulfonate, 1 part of polyoxyethylene alkylaryl ether and 2 parts of sodium ligninsulfonate, an appropriate amount of water is mixed. And kneaded uniformly, granulated with a basket granulator and dried to obtain 100 parts of granules.
  • Emulsion (EC) An emulsion was obtained by uniformly mixing 20 parts of the present compound (B1-11), 55 parts of xylene, 20 parts of N, N-dimethylformamide, and 5 parts of Solpol 2680 (surfactant).
  • Formulation Example 7 Flowable (FL) 40 parts of the present compound (B2-4-1), 5 parts of Solpol 3353 (nonionic surfactant: trade name, Toho Chemical Co., Ltd.), 5 parts of 1% aqueous solution of xanthan gum, 40 parts of water, 10 parts of ethylene glycol Ingredients other than the active ingredient were uniformly dissolved, and then the compound of the present invention was added and stirred well, followed by wet grinding with a sand mill to obtain a flowable agent.
  • Solpol 3353 nonionic surfactant: trade name, Toho Chemical Co., Ltd.
  • Comparative Formulation Example 3 Granule (G2) After mixing 15 parts of azoxystrobin, 60 parts of bentonite, 21 parts of talc, 1 part of sodium dodecylbenzenesulfonate, 1 part of polyoxyethylene alkylaryl ether and 2 parts of sodium lignin sulfonate, an appropriate amount of water is added and homogeneous. The mixture was kneaded, granulated with a basket granulator and dried to obtain 100 parts of a granule.
  • Test Example 1 Rice Blast Prevention Test (Spray Test) In the greenhouse, rice (variety: Kofu) planted in a plastic pot with a diameter of 5 cm was grown to the 3-4 leaf stage. The simple emulsions prepared in Formulation Example 1 and Comparative Formulation Example 1 were singly or mixed and suspended in water so that the concentrations shown in Table 1 were obtained, and the suspension was sprayed. After the drug solution was dried, a conidial spore suspension prepared from blast fungus previously cultured on oatmeal medium was spray-inoculated. Thereafter, the pot was placed in a humid chamber in an artificial inoculation room (20-23 ° C.), taken out the next day, and moved to a greenhouse. The control effect was investigated 8 days after inoculation. In the survey, the severity of the disease was investigated, and the control value and the theoretical value based on the Colby equation were calculated. The results are shown in Table 1.
  • the criteria for disease severity are as follows. Degree of disease occurrence: Assessed without disease (sickness area rate 0%) as 0, withering (sickness area rate 100%) as 3, and evaluated in 0.1 increments according to the lesion area rate.
  • the synergistic effect was determined by the Colby equation (see Weeds 15 (1967), 2022).
  • X theoretical value
  • Test Example 2 Rice blight prevention test (dispersion test) In the greenhouse, rice (variety: Kofu) planted in a plastic pot with a diameter of 5 cm was grown to the 4-5 leaf stage. The simple emulsions prepared in Formulation Example 1 and Comparative Formulation Example 1 were singly or mixed and suspended in water so that the concentrations shown in Table 2 were obtained, and the suspension was sprayed. After the chemical solution was dried, the blight fungus previously cultured on the buckwheat medium was placed and inoculated on the rice strain. Thereafter, the pot was placed in a humid chamber in an artificial inoculation chamber (22-27 ° C.), taken out the next day, and moved to a greenhouse. The control effect was investigated 6 days after inoculation. In the survey, the severity of the disease was investigated, and the control value and the theoretical value based on the Colby equation were calculated. The results are shown in Table 2.
  • the criteria for disease severity are as follows. Degree of disease occurrence: 0 for no disease, 3 for untreated lesions, and evaluated in 0.1 increments according to the lesion area rate.
  • the synergistic effect was determined by the Colby equation (see Weeds 15 (1967), 2022).
  • X theoretical value
  • composition for agricultural and horticultural use of the present invention against toll procarb, compound B1 group or compound B4 group against various plant pests for example, rice blast disease (Pyricularia oryzae) or rice leaf blight (Thanatephorus cucumeris (Frank) Donk
  • rice blast disease Pieris oryzae
  • rice leaf blight Rice leaf blight

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Composition agricole/horticole contenant, en tant que principes actifs : (a) le tolprocarb ; et (b) au moins un composé choisi parmi les composés prescrits inclus dans les groupes de composés B1-B4 ou un sel de ceux-ci.
PCT/JP2017/015765 2016-04-20 2017-04-19 Composition agricole/horticole WO2017183664A1 (fr)

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JPWO2017061483A1 (ja) * 2015-10-09 2018-07-26 日本曹達株式会社 農園芸用殺菌剤組成物
WO2019221089A1 (fr) * 2018-05-16 2019-11-21 日本曹達株式会社 Agent de réduction de phytotoxicité
JPWO2019163946A1 (ja) * 2018-02-23 2020-04-09 三井化学アグロ株式会社 殺菌性化合物を有効成分とする薬害軽減剤、並びに該薬害軽減剤と除草性化合物を含む薬害軽減された除草性組成物
EP3701794A1 (fr) * 2019-02-28 2020-09-02 BASF Agro B.V. Procédé de lutte contre un champignon phytopathogène choisi parmi rhizoctonia solani, magnaporthe grisea, helminthosporium oryzae, xanthomonas oryzae pv.oryza, sclerotium oryzae ou saro-cladium oryzae dans le riz par des compositions comprenant du méfentrifluconazole
US10791738B1 (en) 2019-04-26 2020-10-06 Sumitomo Chemical Company, Limited Composition and method for protecting plant against disease and pest
JP2021094010A (ja) * 2019-12-18 2021-06-24 日本農薬株式会社 ネギ科植物の病害防除方法
JP2021521150A (ja) * 2018-04-13 2021-08-26 バイエル・アクチエンゲゼルシヤフト 殺虫性、殺菌性及び殺ダニ性を有する活性成分組み合わせ

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JP2015214554A (ja) * 2015-06-11 2015-12-03 住友化学株式会社 植物病害及び有害節足動物防除組成物及び植物病害及び有害節足動物の防除方法

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JP2015199758A (ja) * 2015-06-15 2015-11-12 住友化学株式会社 農薬用組成物及び植物の生長を促進する方法

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EP3360415A4 (fr) * 2015-10-09 2019-04-03 Nippon Soda Co., Ltd. Composition fongicide pour l'agriculture et l'horticulture
US10463043B2 (en) 2015-10-09 2019-11-05 Nippon Soda Co., Ltd. Fungicide composition for agricultural and horticultural use
JPWO2017061483A1 (ja) * 2015-10-09 2018-07-26 日本曹達株式会社 農園芸用殺菌剤組成物
JPWO2019163946A1 (ja) * 2018-02-23 2020-04-09 三井化学アグロ株式会社 殺菌性化合物を有効成分とする薬害軽減剤、並びに該薬害軽減剤と除草性化合物を含む薬害軽減された除草性組成物
JP2021521150A (ja) * 2018-04-13 2021-08-26 バイエル・アクチエンゲゼルシヤフト 殺虫性、殺菌性及び殺ダニ性を有する活性成分組み合わせ
JP7437318B2 (ja) 2018-04-13 2024-02-22 バイエル・アクチエンゲゼルシヤフト 殺虫性、殺菌性及び殺ダニ性を有する活性成分組み合わせ
JP7261794B2 (ja) 2018-05-16 2023-04-20 日本曹達株式会社 薬害軽減剤
KR20210005103A (ko) * 2018-05-16 2021-01-13 닛뽕소다 가부시키가이샤 약해 경감제
CN112272518A (zh) * 2018-05-16 2021-01-26 日本曹达株式会社 药害减轻剂
JPWO2019221089A1 (ja) * 2018-05-16 2021-05-27 日本曹達株式会社 薬害軽減剤
WO2019221089A1 (fr) * 2018-05-16 2019-11-21 日本曹達株式会社 Agent de réduction de phytotoxicité
CN112272518B (zh) * 2018-05-16 2022-06-07 日本曹达株式会社 药害减轻剂
KR102540089B1 (ko) 2018-05-16 2023-06-05 닛뽕소다 가부시키가이샤 약해 경감제
EP3701794A1 (fr) * 2019-02-28 2020-09-02 BASF Agro B.V. Procédé de lutte contre un champignon phytopathogène choisi parmi rhizoctonia solani, magnaporthe grisea, helminthosporium oryzae, xanthomonas oryzae pv.oryza, sclerotium oryzae ou saro-cladium oryzae dans le riz par des compositions comprenant du méfentrifluconazole
WO2020217956A1 (fr) * 2019-04-26 2020-10-29 Sumitomo Chemical Company, Limited Composition et procédé pour protéger des plantes contre des maladies et des organismes nuisibles
US10791738B1 (en) 2019-04-26 2020-10-06 Sumitomo Chemical Company, Limited Composition and method for protecting plant against disease and pest
JP2021094010A (ja) * 2019-12-18 2021-06-24 日本農薬株式会社 ネギ科植物の病害防除方法
JP7459427B2 (ja) 2019-12-18 2024-04-02 日本農薬株式会社 ネギ科植物の病害防除方法

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