WO2017145924A1 - Imprint device, operating method for same, and method for manufacturing article - Google Patents

Abstract

Provided is an imprint device that forms a pattern on a substrate (101) by curing imprint material in a state in which the imprint material on the substrate is in contact with a mold, wherein the imprint device is provided with: a substrate chuck (102) having a substrate holding area for holding the substrate; a peripheral member (113) disposed so as to surround the side surfaces of the substrate held by the substrate chuck; and a control unit for controlling a cleaning process for cleaning at least part of an area of the peripheral member using a cleaning member (170) that includes a charged unit. The cleaning process includes an operation for moving the cleaning member relative to the peripheral member in a state in which the charged unit faces the at least part of the area of the peripheral member so that particles in the area are adsorbed by the charged unit.

Description

Imprint apparatus, operation method thereof, and article manufacturing method

The present invention relates to an imprint apparatus, an operation method thereof, and an article manufacturing method.

An imprint technique in which a pattern is formed on a substrate by curing the imprint material in a state where a mold (mold) is in contact with the imprint material arranged on the substrate has attracted attention. The mold is formed with a pattern of concave portions. When the mold is brought into contact with the imprint material on the substrate, the concave portions are filled with the imprint material by capillary action. A purge gas is supplied to the space between the substrate and the mold in order to promote the filling of the imprint material into the recess and to prevent the imprint material from being inhibited from being hardened by air (oxygen). When the imprint material is sufficiently filled in the recess, energy such as light or heat is applied to the imprint material. As a result, the imprint material is cured, and the pattern formed of the recesses formed in the mold is transferred to the imprint material on the substrate. After the imprint material is cured, the mold is pulled away from the imprint material.

When the mold is pulled away from the cured imprint material on the substrate, the mold can be charged. An electrostatic force (Coulomb force) acts on the particles by the electric field formed by the charging, and thereby the particles can be attracted to the mold and attached to the mold. The particles may enter from the outside of the chamber of the imprint apparatus, or may be generated in the chamber due to friction between the machine elements, friction between the machine elements and the substrate or the original plate, or the like. Alternatively, in order to place an uncured imprint material on the substrate, a mist of the imprint material is generated when the imprint material is discharged from the discharge port, and particles are generated as the imprint material solidifies. It is possible that

Japanese Patent Application Laid-Open No. 2014-175340 provides a foreign matter trapping area in a mold and charges the foreign matter catching area to remove foreign matter existing in the atmosphere and / or on the substrate when the substrate is transported to the transfer position. It is described to do. In JP-A-2015-149390, a pattern portion and a first conductive film are provided on a first surface of a mold, a second conductive film is provided on a second surface, and charges are applied to the first conductive film and the second conductive film. It describes that particles near the pattern portion are attracted to the first conductive film by storing them.

If the pattern is formed by bringing the mold into contact with the imprint material on the substrate while the particles are attached to the mold, a pattern having a defect may be formed, or the substrate and / or the mold may be damaged. On the other hand, in order to efficiently supply the purge gas to the space between the substrate and the mold, it has been studied to arrange a peripheral member so as to surround the side surface of the substrate. By providing the peripheral member, the volume of the space under the mold can be reduced, and the purge gas can be efficiently maintained in the space.

However, when the peripheral member is disposed, the peripheral member can face the mold at a close distance when the substrate is moved after the mold is pulled away from the imprint material on the substrate. Since the electrostatic force is inversely proportional to the square of the distance, the electrostatic force acting on the particles on the peripheral member is considerably larger than the electrostatic force acting on the particles on the substrate holding part when there is no peripheral member. Can be. Particles can adhere to the peripheral member through the processing of a large number of substrates. Of these particles, particles adhering to the peripheral member with a weak adhesive force can be easily detached from the peripheral member and attached to the mold by the electrostatic force acting on the peripheral member.

The present invention provides an advantageous technique for reducing pattern defects and substrate and / or mold damage that may occur due to particles that are easily detached from peripheral members.

One aspect of the present invention relates to an imprint apparatus that forms a pattern on a substrate by curing the imprint material while the mold is in contact with the imprint material on the substrate. At least one of the peripheral members using a substrate chuck having a substrate holding region for holding the substrate, a peripheral member disposed so as to surround a side surface of the substrate held by the substrate chuck, and a cleaning member including a charging unit. A control unit that controls a cleaning process for cleaning a part of the area, wherein the cleaning process places the cleaning member in the state in which the charging unit is opposed to at least a part of the peripheral member. Movement of causing the particles in the region to be attracted to the charging unit by being moved relative to each other.

The figure which shows typically the structure of a part of imprint apparatus of one Embodiment of this invention. The figure which shows typically the structure of the imprint apparatus of one Embodiment of this invention. The figure which illustrates a cleaning member. The figure which illustrates a cleaning member. The figure which illustrates a cleaning member. The figure explaining the holding | maintenance part holding a cleaning member. The figure which illustrates a peripheral member. The figure which illustrates the cleaning process of a peripheral member. The figure which illustrates the cleaning process of a peripheral member. The figure which illustrates the cleaning process of a peripheral member. The figure which illustrates the cleaning process of a peripheral member. The figure which illustrates the cleaning sequence of a peripheral part. The figure which illustrates the cleaning process of a substrate chuck. The figure which illustrates the cleaning sequence of a substrate chuck. The figure which shows typically the structure of the imprint apparatus of 2nd Embodiment of this invention. The figure which shows the structural example of a cleaning member. The figure which illustrates operation | movement of the imprint apparatus of 2nd Embodiment of this invention. The figure which illustrates the structure of another cleaning member. Furthermore, the figure which illustrates the structure of another cleaning member. The figure explaining the cleaning of the peripheral member by the cleaning member shown by FIG. The figure explaining the cleaning of the peripheral member by the cleaning member shown by FIG. The figure which shows the static elimination of the type | mold of 3rd Embodiment of this invention. The figure which shows the static elimination of the type | mold of 3rd Embodiment of this invention.

Hereinafter, an imprint apparatus and an operation method thereof according to the present invention will be described through exemplary embodiments with reference to the accompanying drawings.

FIG. 2 illustrates the configuration of the imprint apparatus IMP according to one embodiment of the present invention. The imprint apparatus IMP transfers the pattern of the mold 100 to the substrate 101 by imprinting. In other words, the imprint apparatus IMP transfers the pattern of the mold 100 onto the imprint material (transfer material) on the substrate 101 by imprinting. The imprint means that the imprint material is cured by bringing the mold into contact with the imprint material. The mold 100 has a pattern composed of recesses. The pattern 100 is filled with the imprint material by bringing the mold 100 into contact with the imprint material (uncured resin) on the substrate 101. In this state, the imprint material is cured by applying energy for curing the imprint material. As a result, the pattern of the mold 100 is transferred to the imprint material, and a pattern made of the cured imprint material is formed on the substrate 101.

The imprint material is a curable composition that is cured by applying energy for curing the imprint material. The imprint material may mean a cured state or an uncured state. As the energy for curing, for example, electromagnetic waves, heat, or the like can be used. The electromagnetic wave can be, for example, light (for example, infrared rays, visible rays, ultraviolet rays) having a wavelength selected from a range of 10 nm to 1 mm.

The curable composition is typically a composition that is cured by light irradiation or by heating. Among these, the photocurable composition that is cured by light can contain at least a polymerizable compound and a photopolymerization initiator. Further, the photocurable composition may additionally contain a non-polymerizable compound or a solvent. The non-polymerizable compound may be at least one selected from the group of, for example, a sensitizer, a hydrogen donor, an internal release agent, a surfactant, an antioxidant, and a polymer component.

In this specification and the accompanying drawings, directions are shown in an XYZ coordinate system in which a direction parallel to the surface of the substrate 101 is an XY plane. In the XYZ coordinate system, the directions parallel to the X, Y, and Z axes are the X, Y, and Z directions, respectively, and rotation around the X axis, rotation around the Y axis, and rotation around the Z axis are θX and θY, respectively. , ΘZ. The control or drive related to the X axis, Y axis, and Z axis means control or drive related to the direction parallel to the X axis, the direction parallel to the Y axis, and the direction parallel to the Z axis, respectively. The control or drive related to the θX axis, θY axis, and θZ axis relates to rotation around an axis parallel to the X axis, rotation around an axis parallel to the Y axis, and rotation around an axis parallel to the Z axis. Means control or drive. The position is information that can be specified based on the coordinates of the X axis, Y axis, and Z axis, and the posture is information that can be specified by relative rotation with respect to the θX axis, θY axis, and θZ axis. Positioning means controlling position and / or attitude.

The imprint apparatus IMP includes a substrate driving mechanism SDM that positions the substrate 101. The substrate driving mechanism SDM can include, for example, a substrate chuck 102, a peripheral member 113, a fine movement mechanism 114, a coarse movement mechanism 115, and a base structure 116. . The substrate chuck 102 has a substrate holding region for holding the substrate 101, and can hold the substrate 101 by suction (for example, vacuum suction or electrostatic suction). The fine movement mechanism 114 can include a fine movement stage that supports the substrate chuck 102 and the peripheral member 113 and a drive mechanism that drives the fine movement stage. The peripheral member 113 is disposed around a region where the substrate 101 is disposed so as to surround the side surface of the substrate 101. The peripheral member 113 can have an upper surface having a height equal to the upper surface of the substrate 101. The peripheral member 113 may be divided into a plurality of members. Further, all or a part of the plurality of members may be arranged apart from each other or may be arranged so as to contact each other.

The fine movement mechanism 114 is a mechanism that finely drives the substrate 101 by finely driving the substrate chuck 102. The coarse movement mechanism 115 is a mechanism that coarsely drives the substrate 101 by roughly driving the fine movement mechanism 114. The base structure 116 supports the coarse movement mechanism 115, the fine movement mechanism 114, the substrate chuck 102, and the peripheral member 113. The substrate drive mechanism SDM can be configured to drive the substrate 101 with respect to a plurality of axes (for example, three axes of the X axis, the Y axis, and the θZ axis), for example. The position of the part (fine movement stage) integrated with the substrate chuck 102 in the fine movement mechanism 114 is monitored by a measuring instrument 117 such as an interferometer.

The imprint apparatus IMP includes a mold drive mechanism MDM that positions the mold 100, and the mold drive mechanism MDM may include a mold chuck 110, a drive mechanism 109, and a peripheral member 151. The peripheral member 151 is disposed around a region where the mold 100 is disposed so as to surround the side surface of the mold 100. The mold driving mechanism MDM and the peripheral member 151 can be supported by the support structure 108. The mold chuck 110 can hold the mold 100 by suction (for example, vacuum suction or electrostatic suction). The drive mechanism 109 drives the mold 100 by driving the mold chuck 110. For example, the mold driving mechanism MDM can be configured to drive the mold 100 about a plurality of axes (for example, six axes of X axis, Y axis, Z axis, θX axis, θY axis, and θZ axis).

The substrate drive mechanism SDM and the mold drive mechanism MDM constitute a drive unit that performs relative positioning between the substrate 101 and the mold 100. The drive unit adjusts the relative position between the substrate 101 and the mold 100 with respect to the X axis, the Y axis, the θX axis, the θY axis, and the θZ axis, and also adjusts the relative position between the substrate 101 and the mold 100 with respect to the Z axis. The adjustment of the relative position between the substrate 101 and the mold 100 with respect to the Z-axis includes operations of contact and separation between the imprint material on the substrate 101 and the mold 100.

The imprint apparatus IMP may include a dispenser (supply unit) 111 that applies, disposes, or supplies an uncured imprint material on the substrate 101. The dispenser 111 can be configured to arrange an imprint material on the substrate 101 in the form of a plurality of droplets, for example. The dispenser 111 can be supported by the support structure 108.

The imprint apparatus IMP may include a curing unit 104 that cures the imprint material by irradiating the imprint material on the substrate 101 with light such as UV light. The imprint apparatus IMP may also include a camera 103 for observing the imprint state. The light emitted from the curing unit 104 is reflected by the mirror 105, passes through the mold 100, and can be applied to the imprint material. The camera 103 can be configured to observe an imprint state, for example, a contact state between the imprint material and the mold 100 via the mold 100 and the mirror 105.

The imprint apparatus IMP may include alignment scopes 107a and 107b for detecting a relative position between the mark on the substrate 101 and the mark on the mold 100. The alignment scopes 107 a and 107 b can be disposed on the upper structure 106 supported by the support structure 108. The imprint apparatus IMP may include an off-axis scope 112 for detecting the positions of a plurality of marks on the substrate 101. The off-axis scope 112 can be supported by the support structure 108.

The imprint apparatus IMP may include one or a plurality of purge gas supply units 118a and 118b. The purge gas supply units 118 a and 118 b may be disposed around the mold chuck 110 so as to surround the mold chuck 110. The purge gas supply units 118 a and 118 b supply the purge gas to the space between the substrate 101 and the mold 100. The purge gas supply units 118a and 118b can be supported by the support structure 108, for example. As the purge gas, a gas that does not inhibit the curing of the imprint material, for example, a gas including at least one of helium gas, nitrogen gas, and a condensable gas (for example, pentafluoropropane (PFP)) may be used. The configuration in which the peripheral members 113 and 151 are provided is advantageous for efficiently filling the space between the substrate 101 and the mold 100 with the purge gas.

The imprint apparatus IMP includes a chamber 190, and each of the above components can be disposed in the chamber 190. In addition, the imprint apparatus IMP may include a main control unit (control unit) 126, an imprint control unit 120, an irradiation control unit 121, a scope control unit 122, a dispenser control unit 123, a purge gas control unit 124, and a substrate control unit 125. . The main controller 126 controls the imprint controller 120, the irradiation controller 121, the scope controller 122, the dispenser controller 123, the purge gas controller 124, and the substrate controller 125. The imprint control unit 120 controls the mold driving mechanism MDM. The irradiation control unit 121 controls the curing unit 104. The scope control unit 122, the alignment scopes 107a and 107b, and the off-axis scope 112 are controlled. The dispenser control unit 123 controls the dispenser 111. The purge gas control unit 124 controls the purge gas supply units 118a and 118b. The substrate controller 125 controls the substrate drive mechanism SDM.

FIG. 1 schematically shows a part of the imprint apparatus IMP shown in FIG. Particles 150 can enter the internal space of the chamber 190. Further, in the chamber 190, the particles 150 may be generated due to mutual friction between the machine elements, friction between the machine elements and the substrate or the original plate, or the like. Alternatively, when the imprint material is discharged from the discharge port in order for the dispenser 111 to place the uncured imprint material on the substrate 101, a mist of the imprint material is generated and the imprint material is solidified. Particles 150 can be generated.

The particles 150 can adhere to the upper surface of the peripheral member 113 and the like. The adhesion strength of the particles 150 that adhere to the peripheral member 113 varies. When the particles 150 adhering to the peripheral member 113 do not leave the peripheral member 113, pattern defects and substrate and / or mold damage due to the particles 150 adhering to the substrate 101 or the mold 100 do not occur. On the other hand, when the particles 150 attached to the peripheral member 113 are detached from the peripheral member 113, the particles 150 may adhere to the substrate 101 or the mold 100, or may be sandwiched between the substrate 101 and the mold 100.

When the mold 100 is pulled away from the cured imprint material on the substrate 101, the mold 100 can be charged. An electrostatic force (Coulomb force) acts on the particles 150 by the electric field formed by the charging, and thereby the particles 150 can be attracted to the mold 100 and attached to the mold 100. Since the upper surface of the peripheral member 113 can have the same height as the upper surface of the substrate 101, the distance between the mold 100 and the upper surface of the peripheral member 113 is considerably small. Since the electrostatic force is inversely proportional to the square of the distance, the electrostatic force acting on the particles on the peripheral member 113 is more than the electrostatic force acting on the substrate chuck 102 and the members existing in the vicinity thereof when there is no peripheral member 113. Can be quite large. A large number of particles 150 may adhere to the peripheral member 113 through the processing of the large number of substrates 101.

Therefore, in the imprint apparatus IMP, a cleaning process for cleaning at least a part of the peripheral member 113 using the cleaning member 170 including the charging unit is executed. The cleaning process can be performed by the main control unit (control unit) 126 controlling the driving of the cleaning member 170 including the charging unit. In the cleaning process, the cleaning member 170 is moved relative to the region with the charged portion of the cleaning member 170 facing at least a part of the peripheral member 113 to charge the particles 150 in the region. The operation of adsorbing to the part may be included. Here, the particles 150 adhering to the peripheral member 113 with a weak adhesive force can be separated from the peripheral member 113 by the electrostatic force when the cleaning member 170 including the charging unit faces and adhere to the charging unit. . Typically, the cleaning process is performed in a state where there is no imprint material on the substrate 101, and the dispenser 111 does not supply the imprint material on the substrate 101 during the cleaning process.

FIG. 1 shows a state where the cleaning process is performed in a state where the substrate 101 exists on the substrate holding area 1021 of the substrate chuck 102, but the state where the substrate 101 does not exist on the substrate holding area 1021. A cleaning process may be performed. The substrate holding region 1021 may be a region that entirely contacts the substrate 101, or may be a region that partially contacts the substrate 101. In the latter, the portion in contact with the substrate 101 can have pins and / or rings.

Here, as an example, consider the case where the mold 100 is charged to −3 KV by pulling the mold 100 away from the cured imprint material on the substrate 101. It is assumed that the peripheral member 113 is grounded and has a ground potential. It is assumed that the gap between the peripheral member 113 and the mold 100 is 1 mm. In this case, the direction of the electric field is upward (positive direction of the Z axis), and the intensity of the electric field is 3 kV / mm. In this example, it is desirable to charge the charging portion so that the potential V of the charging portion of the cleaning member 170 is lower than −3 kV (V <−3 kV). In the cleaning process, the charging portion of the cleaning member 170 is charged, and the cleaning member 170 is moved relative to the region in a state where the charging portion is opposed to at least a partial region of the peripheral member 113. As a result of this cleaning process, the particles 150 attached to the region with a weak adhesion force are pulled away from the region, attracted to the charging unit, and captured by the charging unit.

By reducing the gap between the peripheral member 113 and the charging part of the cleaning member 170 in the cleaning process, the electric field between the peripheral member 113 and the charging part can be increased, and the effect of the cleaning process can be enhanced. For example, the gap between the mold 100 and the peripheral member 113 when the substrate 101 is moved to supply the imprint material onto the substrate 101 by the dispenser 111 is GN, and the gap between the peripheral member 113 and the charging unit in the cleaning process is set. If GC, then GN> GC. The gap between the peripheral member 113 and the charging portion of the cleaning member 170 in the cleaning process can be set to 0.8 mm or less, for example.

The cleaning member 170 can be held by the holding unit 119. The holding unit 119 may have any structure that can hold the cleaning member 170. For example, the holding unit 119 may be a movable member such as a robot arm, a fixed member, or the mold chuck 110. May be substituted.

FIGS. 3A to 3C show an example of the cleaning member 170. FIG. In the first example shown in FIG. 3A, the cleaning member 170 includes a support 131 and a charging unit 132 supported by the support 131. The charging unit 132 can be prepared by, for example, charging a dielectric member made of quartz or the like. The dielectric member is charged by bringing the dielectric member into contact with the imprint material disposed on the dummy substrate, and curing the imprint material by the curing unit 104, and then separating the dielectric member from the imprint material. Can be made by. The dummy substrate is a substrate that can be placed on the substrate chuck 102 instead of the substrate 101. The support 131 and the charging unit 132 may be made of the same material.

Since the charge amount can be increased when the surface area in contact with the imprint material is larger, the charging unit 132 may have a pattern (unevenness) on the surface. The cleaning member 170 including the support body 131 and the charging unit 132 may be, for example, a waste of the mold 100 (for example, a used or non-standard mold). Alternatively, the cleaning member 170 including the support 131 and the charging unit 132 has a pattern density higher than that of the mold 100 for manufacturing an article and is advantageous in increasing the charge amount (for example, for inspection of the imprint apparatus IMP). It may be the type of waste used). In addition, a non-use means an article that is not used for its original purpose.

In the second example shown in FIG. 3B, the cleaning member 170 includes a support 131 and an electret 133 supported by the support 131. An electret is a substance that continues to form an electric field, and can be formed by, for example, injecting and fixing a charge in a dielectric such as a polymer material. Methods for injecting charges into electrets include a method of solidifying the polymer material while applying a high voltage between electrodes sandwiching the polymer material in a molten state, a method using corona discharge, and a method using ion implantation. . In the method of applying a voltage between the electrodes, the electret is charged with positive and negative polarities on the surface that is in contact with each electrode. In the method using corona discharge, the electret is charged with negative polarity. Generally, electrets are charged with a positive polarity.

In the first example, since the excessive charge is distributed on the surface of the dielectric member constituting the charging unit 132, the charge amount is reduced depending on the environment. On the other hand, the electret employed in the second example can hold the charge semi-permanently because the charge is injected into the dielectric material. In the example shown in FIG. 3B, the electret 133 is provided on the entire lower surface of the support 131, but the electret 133 may be provided only on a part of the lower surface. Further, as described in the first example, an electret may be arranged on the lower surface of the mold waste.

Examples of the material for the electret include (a) a polymer material such as acrylic resin, nylon, and fluororesin, and (b) an inorganic film such as SiO ₂ , SiO ₂ / Si _x N _y laminated film. Fluorocarbon resins include Teflon AF (registered trademark, manufactured by DuPont) and CYTOP (registered trademark, manufactured by Asahi Glass Co., Ltd.) as organic electret films that can be formed by spin coating. In particular, CYTOP is characterized by a high surface charge density.

It is also possible to use a structure in which the electrode is covered with a dielectric as the charging portion. If the charged part is composed of an exposed electrode and the particles are metal, the particles attached to the charged part will have the same polarity as the electrode due to charge exchange and will be separated by repulsive force. I can't. Therefore, by covering the electrode with a dielectric, even metal particles can be captured by the charging unit while preventing charge exchange.

In the third example shown in FIG. 3C, the cleaning member 170 includes a support 131, a negative charging unit 134 and a positive charging unit 135 supported by the support 131. As the negative charging unit 134 and the positive charging unit 135, the electret described in the second example can be employed. By providing the negative charging unit 134 charged negatively and the positive charging unit 135 charged positive, particles adhering to the peripheral member 113 can be removed regardless of the polarity of the particles.

Referring to FIG. 4, the holding unit 119 that holds the cleaning member 170 will be supplemented. As described above, the holding unit 119 only needs to be able to hold the cleaning member 170. For example, the holding unit 119 may be a movable member such as a robot arm, a fixed member, or the mold chuck 110. May be substituted.

In one example, the holding unit 119 may be a component of the maintenance unit 136. The maintenance unit 136 may be a unit for removing and attaching the substrate chuck 102, for example. Since the substrate chuck 102 can be contaminated or worn by contact with the substrate 101, it can be replaced using the maintenance unit 136. The maintenance unit 136 has a holding mechanism for holding the substrate chuck 102, and the holding mechanism can be used as the holding unit 119. The substrate chuck 102 is not replaced simultaneously with the cleaning process of the peripheral member 113. Therefore, there is no special disadvantage caused by holding the cleaning member 170 by the maintenance unit 136 and performing the cleaning process. Also, holding the cleaning member 170 by the maintenance unit 136 and performing the cleaning process contributes to simplification of the configuration of the imprint apparatus IMP.

When the cleaning process is performed with the cleaning member 170 held by the mold chuck 110, the cleaning member 170 can be transported to the mold chuck 110 using a transport mechanism that transports the mold 100 to the mold chuck 110.

FIG. 5 is a top view of the peripheral member 113, and FIG. 5 illustrates the shape of the peripheral member 113. In the example shown in FIG. 5, the outer shape of the peripheral member 113 is a square, but this is an example, and the peripheral member 113 can have various outer shapes. The peripheral member 113 has an opening surrounding the side surface of the substrate 101, and the shape of the opening conforms to the outer shape of the substrate 101.

The peripheral member 113 may have a continuous part with a smooth surface and a discontinuous part with a non-smooth surface. For example, a reference mark for measuring a relative position between the mold 100 and the reference of the imprint apparatus IMP can be arranged on the peripheral member 113. When light is used as the energy for curing, the peripheral member 113 can be provided with an illuminometer for measuring the illuminance of light. Therefore, a groove or a step may exist between the member or unit represented by the reference mark and the illuminometer and the peripheral member 113. Further, when the peripheral member 113 is constituted by a plurality of divided parts, there may be a groove or a step between the parts. Also, a groove or a step can be formed by a fastening portion for fastening the peripheral member 113 to the fine movement mechanism 114. Such grooves and steps are examples of discontinuous portions whose surfaces are not smooth. On the other hand, a flat upper surface is an example of a continuous portion having a smooth surface. The main control unit 126 performs cleaning so that the total time for which the charged portion of the cleaning member 170 is opposed to the discontinuous portion per unit area is longer than the total time for which the charged portion of the cleaning member 170 is opposed to the continuous portion per unit area. The process can be controlled.

In the imprint apparatus IMP, an imprint sequence (pattern formation method) configured by a plurality of imprint cycles can be executed in order to form a pattern with an imprint material on a plurality of shot areas of the substrate 101. Each imprint cycle includes a step of placing the imprint material on the substrate 101 by the dispenser 111, a step of bringing the mold 100 into contact with the imprint material, a step of curing the imprint material, and the mold 100 from the cured imprint material. The step of separating may be included.

FIG. 5 illustrates the positional relationship among the peripheral member 113, the mold 100, and the dispenser 111 when the imprint material is arranged by the dispenser 111 with respect to a certain shot area of the substrate 101. A pattern area of the mold 100 (area having a pattern to be transferred to the substrate 101) is located on the peripheral member 113.

In the period during which the imprint sequence is executed, that is, in the period in which the pattern is formed in each of the plurality of shot areas of the substrate, the area 140 is an area that can face the pattern area of the mold 100. The region 140 is a region that easily serves as a particle supply source for the pattern region of the mold 100 in the imprint sequence in the entire upper surface of the peripheral member 113. Therefore, when the target of the cleaning process is limited to a part of the area rather than the entire upper surface of the peripheral member 113, the cleaning process should be performed on at least the area including the area 140.

In one example, the mold drive mechanism MDM that drives the mold 100 is located in the first direction (minus direction of the X axis) when viewed from the dispenser 111. The region 140 is a region located on the first azimuth side of the upper surface of the peripheral member 113 with respect to the side surface on the first azimuth side of the substrate 101 held by the substrate chuck 102.

FIGS. 6A to 6D illustrate a cleaning process in which the cleaning member 170 is moved relative to the region with the charging unit of the cleaning member 170 facing at least a part of the region of the peripheral member 113. . In the example shown in FIG. 6A, the main control unit 126 controls the cleaning process so that the region 140 of the peripheral member 113 is selectively cleaned. Such a cleaning process is advantageous for shortening the time required for the cleaning process. In the example shown in FIG. 6B, the main control unit 126 controls the cleaning process so that the entire area of the peripheral member 113 is cleaned. The relative movement of the charging portion of the cleaning member 170 with respect to the peripheral member 113 in the cleaning process can be a continuous repetition of a predetermined operation unit as illustrated in FIGS. 6A and 6B. The motion unit is, for example, relative movement in a direction parallel to a first direction (for example, the X-axis direction) and relative to a second direction (for example, the Y-axis direction) that intersects the first direction. Movement.

In the example shown in FIG. 6C, the relative movement path of the charging unit of the cleaning member 170 with respect to the peripheral member 113 includes a plurality of loops surrounding the substrate holding region 1021. Here, the plurality of loops have different distances from the substrate holding region 1021. In the example shown in FIG. 6C, the path does not pass through the substrate holding area 1021, but the path may pass through the substrate holding area 1021.

6D, the peripheral member 113 has discontinuous portions 141, 142, 143 such as grooves and / or steps, and other continuous portions. Since particles are more easily captured by the discontinuous portions 141, 142, and 143 than the continuous portions, a larger number of particles can exist in the discontinuous portions 141, 142, and 143 than the continuous portions. The main controller 126 determines that the total time for which the charging portion of the cleaning member 170 is opposed to the discontinuous portions 141, 142, 143 per unit area is the total time for which the charging portion of the cleaning member 170 is opposed to the continuous portion per unit area. The cleaning process can be controlled to be longer.

The main control unit 126 can execute the cleaning process after executing an imprint process for forming a pattern on the substrate by imprinting and executing the imprint process in response to the command, for example. Alternatively, the main control unit 126 may be performed at an idle time when the article is not manufactured. Alternatively, the main control unit 126 may perform the cleaning process every time a set number of substrates are processed, or may perform the cleaning process every time one substrate is processed. In addition, the main control unit 126 may perform a cleaning process each time a pattern is formed on a shot area, for example.

Also, an evaluation for confirming the necessity of executing the cleaning process may be performed, and the cleaning process may be executed based on the result. For example, a pattern (first sample) is formed by imprinting one or a plurality of shot areas using an evaluation mold, and then the mold is charged and then the mold is opposed to the peripheral member 113. The member 113 is moved. Then, using the mold, a pattern (second sample) is formed by imprinting on one or a plurality of shot regions. The state of the peripheral member 113 can be evaluated by comparing the number of defects of the first sample and the second sample.

FIG. 7 illustrates a cleaning sequence for the peripheral member 113. This cleaning sequence is controlled by the main controller 126. In step S <b> 201, the main control unit 126 instructs a transport mechanism (not shown) to hold the cleaning member 170 in the holding unit 119. In step S202, the main control unit 126 determines the type of the cleaning member 170. The type of the cleaning member 170 can be determined by, for example, an identifier given to the cleaning member 170. Alternatively, the type of the cleaning member 170 can be determined based on the result of measuring the charge amount of the charging portion of the cleaning member 170 using a measuring instrument that measures the surface potential.

As shown in FIG. 3A, a type that causes charging through contact and separation of the dielectric member with respect to the imprint material is referred to as a non-persistent type. In addition, a type using an electret as illustrated in FIGS. 3B and 3C is referred to as a continuous type. If it is determined in step S202 that the cleaning member 170 is a non-sustainable type, the process proceeds to step S203, and if the cleaning member 170 is determined to be a continuous type, the process proceeds to step S206.

In step S203, the main control unit 126 instructs a transfer mechanism (not shown) to transfer the dummy substrate onto the substrate chuck 102. In step S204, the main control unit 126 controls the substrate driving mechanism SDM and the dispenser 111 so that the imprint material is disposed on the dummy substrate. In step S205, the main control unit 126 makes the dielectric member of the cleaning member 170 contact the imprint material on the dummy substrate, cures the imprint material by the curing unit 104, and pulls the dielectric member away from the cured imprint material. Control dummy imprint. By this dummy imprint, the dielectric member is charged to prepare a charging portion. For the continuous type cleaning member 170, the charging process as in steps S203 to S205 is not required.

In step S206, the main control unit 126 performs a cleaning process for the peripheral member 113. Specifically, the main control unit 126 moves (scans) the cleaning member 170 relative to the region with the charging unit of the cleaning member 170 facing at least a part of the region of the peripheral member 113. . As a result, the particles 150 in the region are separated from the region and are attracted to the charging unit, whereby the region is cleaned.

In step S207, the main control unit 126 instructs a transport mechanism (not shown) to carry out the cleaning member 170. Here, when the dedicated holding unit 119 for holding the cleaning member 170 is provided, the steps S201 and S207 are unnecessary, and the state where the cleaning member 170 is held by the holding unit 119 can be maintained.

The above-described cleaning process may be applied to a cleaning process for removing particles from the substrate chuck 102 (substrate holding region 1021) as illustrated in FIG. The substrate holding region 1021 of the substrate chuck 102 can have pins and / or rings for supporting the substrate 101. When particles adhere to the pins and / or rings, the substrate 101 is deformed, and a defect may occur in the formed pattern.

Therefore, the main control unit 126 can be configured to control the cleaning process of the substrate chuck 102 (substrate holding region 1021). In this cleaning process, the cleaning member 170 is moved relative to the substrate chuck 102 with the charging portion of the cleaning member 170 facing the substrate chuck 102, whereby the particles 150 of the substrate chuck 102 are attracted to the charging portion. Is done.

FIG. 9 illustrates a cleaning sequence for the substrate chuck 102. This cleaning sequence is controlled by the main controller 126. In step S <b> 211, when the substrate 101 is on the substrate chuck 102, the main control unit 126 instructs a transfer mechanism (not shown) to carry out the substrate 101. In step S212, the main control unit 126 instructs a transport mechanism (not shown) to hold the cleaning member 170 in the holding unit 119. In step S213, the main control unit 126 determines the type of the cleaning member 170. If it is determined in step S213 that the cleaning member 170 is a non-sustained type, the process proceeds to step S214, and if the cleaning member 170 is determined to be a continuous type, the process proceeds to step S218.

In step S214, the main control unit 126 instructs a transfer mechanism (not shown) to transfer the dummy substrate onto the substrate chuck 102. In step S215, the main control unit 126 controls the substrate driving mechanism SDM and the dispenser 111 so that the imprint material is disposed on the dummy substrate. In step S216, the main control unit 126 causes the dielectric member of the cleaning member 170 to contact the imprint material on the dummy substrate, cures the imprint material by the curing unit 104, and pulls the dielectric member away from the cured imprint material. Control dummy imprint. By this dummy imprint, the dielectric member is charged to prepare a charging portion. In step S217, the main control unit 126 instructs a transfer mechanism (not shown) to carry out the dummy substrate from the substrate chuck 102. For the continuous type cleaning member 170, the process for charging as in steps S214 to S217 is unnecessary.

In step S218, the main control unit 126 executes a cleaning process for the substrate chuck 102. Specifically, the main control unit 126 moves (scans) the cleaning member 170 relative to the substrate chuck 102 with the charging unit of the cleaning member 170 facing at least a part of the region of the substrate chuck 102. Let Accordingly, the particles 150 in the region of the substrate chuck 102 are detached from the substrate chuck 102 and are attracted to the charging unit, whereby the region of the substrate chuck 102 is cleaned.

In step S219, the main control unit 126 instructs a transport mechanism (not shown) to carry out the cleaning member 170. Here, when the dedicated holding unit 119 that holds the cleaning member 170 is provided, the steps S212 and S219 are unnecessary, and the state where the cleaning member 170 is held by the holding unit 119 can be maintained.

The main control unit 126 is, for example, a PLD (abbreviation of Programmable Logic Device) such as an FPGA (abbreviation of Field Programmable Gate Array), or an ASIC (Abbreviation of Application Specific Integrated or Program). It can be constituted by a general-purpose computer or a combination of all or part of them. Similarly, the other control units 120 to 125 may be configured by a PLD such as an FPGA, an ASIC, a general-purpose computer incorporating a program, or a combination of all or a part thereof.

Hereinafter, an article manufacturing method will be described. Here, as an example, an article manufacturing method for manufacturing devices (semiconductor integrated circuit elements, liquid crystal display elements, etc.) as articles will be described. The article manufacturing method includes a step of forming a pattern on a substrate (wafer, glass plate, film-like substrate) using the above-described imprint apparatus. Further, the manufacturing method may include a step of processing (for example, etching) the substrate on which the pattern is formed. In the case of manufacturing other articles such as patterned media (recording media) and optical elements, the manufacturing method may include other processes for processing a substrate on which a pattern is formed instead of etching. The article manufacturing method of this embodiment is advantageous in at least one of the performance, quality, productivity, and production cost of the article as compared with the conventional method.

(Second Embodiment)
The cleaning process can be performed (a) before executing the imprint process, (b) when the imprint apparatus is in an idle state, or (c) after processing a set number of substrates. Hereinafter, an example will be described in which the cleaning process is performed in parallel with a series of imprint operations without specially providing time for the cleaning process by arranging the charging unit at a specific position of the imprint apparatus IMP. To do.

FIG. 10 illustrates the configuration of the imprint apparatus IMP according to the second embodiment of the present invention. The cleaning member 170 is disposed so that the mold 100 is positioned between the cleaning member 170 and the dispenser 111. For example, the cleaning member 170 can be held by a peripheral member 151 disposed around the mold chuck 110. As illustrated in FIG. 11, the cleaning member 170 includes a charging unit 171.

In the second embodiment, the cleaning member 170 is disposed so that the mold 100 is positioned between the cleaning member 170 and the dispenser 111. As a result, in a sequence in which the shot area to be imprinted is moved below the dispenser 111 and then moved below the mold 100, a part of the area 140 shown in FIG. The Such a sequence is sequentially performed on a plurality of shot areas, so that the entire area 140 can be cleaned by the cleaning member 170. Therefore, the time required for cleaning the peripheral member 113 is reduced. This contributes to an improvement in throughput related to pattern formation by imprint.

Here, the width L2 of the charging portion 171 in the direction orthogonal to the direction in which the cleaning member 170, the mold 100, and the dispenser 111 are arranged is preferably larger than the width L1 of the pattern portion 160 of the mold 100 from the viewpoint of efficiency of cleaning. .

FIG. 12 exemplarily shows the operation of the imprint apparatus IMP of the second embodiment. Here, the charging unit 171 of the cleaning member 170 is in a charged state when an operation for charging is performed, and is uncharged by an operation for discharging. However, the charging unit 171 that does not require such an operation may be used, and in this case, steps S201 and S205 described below are unnecessary. In a simple example, the charging unit 171 is made of a conductor, and a charged state can be obtained by supplying a charge to the charging unit 171, and a non-charged state can be obtained by extracting the charge from the charging unit 171.

First, in step S221, the main control unit 126 puts the charging unit 171 into a charged state. Next, in step S222, the main control unit 126 controls the dispenser 111 and the substrate driving mechanism SDM so that the imprint material is disposed in the shot area to be imprinted. At this time, the shot area to be imprinted is arranged below the dispenser 111. Next, in step S223, the main control unit 126 controls the substrate drive mechanism SDM so that the shot area to be imprinted is disposed under the mold 100. In steps S222 and S223, a region of the surface of the peripheral member 113 that faces the charging unit 171 of the cleaning member 170 is cleaned.

Next, in step S224, the main controller 126 first controls the mold drive mechanism MDM so that the imprint material on the shot area to be imprinted and the mold 100 come into contact with each other. Next, in step S024, the main control unit 126 controls the curing unit 104 to cure the imprint material, and then controls the mold driving mechanism MDM to separate the cured imprint material and the mold 100 from each other. . Next, in step S225, the main control unit 126 puts the charging unit 171 into an uncharged state.

Next, in step S226, the main control unit 126 determines whether imprinting has been completed for all shot areas on the substrate. If there is a shot area that has not yet been imprinted, the process returns to step S221 to execute another shot. Repeat the process for the region. On the other hand, when the imprint for all the shot regions is completed, in step S227, the main control unit 126 determines whether the imprint for all the substrates is completed. If there is a shot area that has not yet been imprinted, the main control unit 126 returns to step S201 and repeats the process for another substrate.

In order to clean a wider region of the peripheral member 113 with the cleaning member 170, it is useful to employ a cleaning member 170 having a wider area as illustrated in FIG. The cleaning member 170 illustrated in FIG. 13 has a shape surrounding the mold 100 in all directions.

However, various mechanisms can be arranged around the mold 100. In this case, it may be difficult to employ the cleaning member 170 that surrounds the mold 100 in all directions. As a mechanism that can be arranged around the mold 100, for example, a mechanism that deforms the mold 100 by applying a force to the side surface of the mold 100, a mechanism that adjusts the inclination of the mold 100, and a part of the mold drive mechanism MDM are configured. A mechanism etc. can be mentioned.

FIG. 14 shows an example in which additional cleaning members 180 and 181 are provided in addition to the cleaning member 170. That is, FIG. 14 shows an example in which a plurality of cleaning members 170, 180, and 181 are provided. As illustrated in FIG. 15A, the cleaning member 180 cleans a part of the region 300 in the peripheral member 113, and as illustrated in FIG. 15B, the cleaning member 181 includes the other member in the peripheral member 113. The region 310 is cleaned. As described above, by providing a plurality of cleaning members and sharing a region to be cleaned by the plurality of cleaning members, it is possible to suppress an increase in size of the imprint apparatus IMP. Here, the cleaning member 170 can be used to clean the peripheral member 113 in parallel with the imprint for a plurality of shot regions of the substrate 101. On the other hand, the cleaning members 180 and 181 can be used in a dedicated cleaning sequence that can be executed during a period when imprinting on the substrate 101 is not performed, for example, during maintenance or idling.

(Third embodiment)
The imprint apparatus IMP desirably includes a static elimination mechanism that neutralizes the charged mold 100 when the mold 100 is pulled away from the cured imprint material. For example, the neutralization of the mold 100 can be performed using an ionizer. There are various types of ionizers such as a corona discharge method and an energy ray irradiation method (for example, an X-ray irradiation method and an α-ray irradiation method). In general, the corona discharge method may cause generation of particles. Therefore, the X-ray irradiation method or the α-ray irradiation method is suitable for removing the mold 100 while maintaining the cleanliness. Since the space between the mold 100 and the substrate 101 is a very narrow space, it is difficult to arrange an ionizer around the space and directly irradiate the mold 100 with X-rays or α rays. . Except for the method of directly irradiating the mold 100 with X-rays or α-rays, the gas is ionized by irradiating the gas with X-rays or α-rays, and the ionized gas is supplied to the space below the mold 100 There is a method to do. However, the ionized gas has a reduced ion concentration while passing through a pipe and a nozzle, and further a path from the nozzle to the space between the mold 100 and the substrate 101. In some cases, a sufficient ion concentration cannot be maintained. In such a case, the mold 100 cannot be discharged efficiently.

Therefore, in this embodiment, the charge removal gas is supplied from the purge gas supply unit 118. The neutralizing gas may be supplied from a gas supply unit different from the purge gas supply unit 118. As shown in FIG. 16A, the charge-removing gas is preferably filled in the space around the mold 100 before the pattern portion 160 of the mold 100 is separated from the cured imprint material. The purge gas supply by the purge gas supply unit 118 may be stopped before the pattern unit 160 is separated if the space around the mold 100 is sufficiently filled with the neutralization gas, or the supply may be continued during the separation. It may be. As a result, as shown in FIG. 16B, in the step of separating the pattern portion 160 from the cured imprint material, the surrounding neutralizing gas is drawn into the gap between the pattern portion 160 and the substrate 101 and replaced.

The neutralizing gas needs to contain a gas whose mean free path for electrons is longer than that of air. Specifically, a rare gas that is a monoatomic molecule is preferable as the static elimination gas, but in particular, helium having the longest mean free path among the rare gases is preferable. Electrons existing in the electric field are carried to the anode side by the electric field and collide with gas molecules in the middle. At this time, if the electrons are sufficiently accelerated and collide with gas molecules in a state where the energy is higher than the ionization energy of the gas, ionization occurs and an electron-cation pair is generated. The generated electrons are also accelerated by the electric field and ionize the gas molecules. In this way, a phenomenon in which a large amount of electron-cation pairs is generated by successive ionization is called an electron avalanche. In a gas with a long mean free path for electrons, the accelerating electrons do not collide with gas molecules on the way and are accelerated to a high energy state. Therefore, a gas having a long mean free path for electrons is more likely to cause an electron avalanche even in a low electric field than air, and can be discharged before a large voltage is accumulated in the mold 100.

Further, since the gas for discharging is generally highly diffusive, it can also be used as a purge gas for the imprint space when the imprint material is filled in the pattern portion 160. Here, the voltage of the charging unit 171 when an electric field is generated between the charging unit 171 of the cleaning member 170 and the peripheral member 113 to perform the cleaning process on the peripheral member 113 will be described. When a neutralizing gas enters the gap between the charging unit 171 to which the voltage is applied and the peripheral member 113 and an electron avalanche occurs, a large amount of electrons or cations are supplied to the surface of the charging unit 171 and the voltage of the charging unit 171 decreases. And the cleaning effect is reduced. Therefore, the voltage of the charging unit 171 needs to be set so that the electric field strength generated between the charging unit 171 and the peripheral member 113 is equal to or lower than the electric field strength at which discharge occurs through the charge removal gas. Therefore, a voltage control unit 172 that controls the voltage applied to the charging unit 171 can be provided. The voltage control unit 172 sets the voltage applied to the charging unit 171 so that the electric field strength generated between the charging unit 171 and the peripheral member 113 is equal to or lower than the electric field strength at which discharge occurs through the charge removal gas. Whether or not an electronic avalanche occurs between the charging unit 171 and the peripheral member 113 depends on the electric field strength and the type of the neutralizing gas, and therefore the distance between the charging unit 171 and the peripheral member 113 and the type of the neutralizing gas. Thus, the value of the voltage applied to the charging unit 171 may be determined. That is, the value of the voltage applied to the charging unit 171 varies depending on the type of the charge eliminating gas and the distance between the charging unit 171 and the peripheral member 113.

The voltage of the mold 100 is maintained below the voltage at which discharge occurs through the static elimination gas after the step of separating from the cured imprint material by the static elimination gas. Therefore, the cleaning of the peripheral member 113 with the cleaning member 170 having the charging unit 171 set to the above voltage can prevent the particles 150 from adhering to the mold 100.

In addition, while the discharge gas is not supplied from the purge gas supply unit 118, the voltage applied to the charging unit 171 is such that the electric field strength generated between the charging unit 171 and the peripheral member 113 is discharged through the discharge gas. It may be set to a value higher than the electric field strength. For example, while the imprint process is not performed, the charging unit 171 may be set to a higher voltage than during the imprint process, and the cleaning process may be performed. Even during the imprint process, while the neutralizing gas is not supplied, the voltage of the charging unit 171 may be increased to improve the cleaning effect.

The present invention is not limited to the above embodiment, and various changes and modifications can be made without departing from the spirit and scope of the present invention. Therefore, in order to make the scope of the present invention public, the following claims are attached.

The present application is Japanese Patent Application No. 2016-036315 filed on Feb. 26, 2016, Japanese Patent Application No. 2016-225379 filed on Nov. 18, 2016, and Japanese Patent Application filed on Feb. 3, 2017. The priority is claimed on the basis of Japanese Patent Application No. 2017-018915, the entire contents of which are incorporated herein by reference.

IMP: imprint apparatus, 100: mold, 101: substrate, 102: substrate chuck, 113: peripheral member, 131: support, 132-135: charging unit, 150: particle, 170: cleaning member

Claims (29)

1. An imprint apparatus for forming a pattern on a substrate by curing the imprint material in a state where a mold is in contact with the imprint material on the substrate,
   A substrate chuck having a substrate holding region for holding the substrate;
   A peripheral member arranged to surround a side surface of the substrate held by the substrate chuck;
   A control unit for controlling a cleaning process for cleaning at least a part of the peripheral member using a cleaning member including a charging unit, and
   In the cleaning process, particles in the region are moved to the charging unit by moving the cleaning member relative to the peripheral member in a state where the charging unit is opposed to at least a part of the peripheral member. Including the action of adsorbing,
   An imprint apparatus characterized by that.
2. The relative movement of the charging unit with respect to the peripheral member includes a relative movement in a direction parallel to a first direction and a relative movement in a second direction intersecting the first direction. Including repetition of
   The imprint apparatus according to claim 1.
3. A path of relative movement of the charging unit with respect to the peripheral member includes a plurality of loops surrounding the substrate holding region, and the plurality of loops have different distances from the substrate holding region.
   The imprint apparatus according to claim 1.
4. A supply unit for supplying the imprint material on the substrate, and a mold drive mechanism for driving the mold,
   The mold drive mechanism is located in the first direction as viewed from the supply unit,
   The region includes a region located on the first azimuth side of a side surface on the first azimuth side of the substrate held by the substrate chuck in the upper surface of the peripheral member.
   The imprint apparatus according to any one of claims 1 to 3, wherein:
5. The cleaning process is performed in a state where there is no imprint material on the substrate,
   The supply unit does not supply an imprint material on the substrate during the cleaning process.
   The imprint apparatus according to claim 4.
6. The control unit executes the cleaning process after executing an imprint process for forming a pattern on the substrate by imprinting and before executing the imprint process in response to the command.
   The imprint apparatus according to claim 1.
7. The peripheral member has a continuous part with a smooth surface and a discontinuous part with a non-smooth surface, and the control unit is a unit of a total time in which the charging part is opposed to the discontinuous part per unit area. Longer than the total time of facing the charging part to the continuous part per area,
   The imprint apparatus according to claim 1, wherein the apparatus is an imprint apparatus.
8. A mold chuck that holds a mold; and a holding unit that holds the cleaning member; and the control unit executes the cleaning process in a state where the cleaning member is held by the holding unit.
   The imprint apparatus according to claim 1, wherein the imprint apparatus is any one of claims 1 to 7.
9. The cleaning process is performed in a state where the cleaning member is held by a mold chuck that holds a mold.
   The imprint apparatus according to claim 1, wherein the imprint apparatus is any one of claims 1 to 7.
10. The gap between the charging unit and the peripheral member in the cleaning process is smaller than the gap between the mold and the peripheral member when the substrate is moved to supply the imprint material onto the substrate.
    The imprint apparatus according to claim 1, wherein the apparatus is an imprint apparatus.
11. The cleaning process is performed with a gap between the charging unit and the peripheral member of 0.8 mm or less.
    The imprint apparatus according to claim 1, wherein the imprint apparatus is any one of claims 1 to 10.
12. The charging unit includes a charged dielectric member,
    The imprint apparatus according to claim 1, wherein the imprint apparatus is any one of claims 1 to 11.
13. The charging unit includes an electret,
    The imprint apparatus according to claim 1, wherein the imprint apparatus is any one of claims 1 to 11.
14. The charging unit includes an electret that holds a positive charge and an electret that holds a negative charge.
    The imprint apparatus according to claim 1, wherein the imprint apparatus is any one of claims 1 to 11.
15. The control unit controls an operation of attracting particles of the substrate chuck to the charging unit by moving the charging unit relative to the substrate chuck in a state where the substrate is not held by the substrate chuck. ,
    The imprint apparatus according to claim 1, wherein the imprint apparatus is any one of claims 1 to 14.
16. An operation method for operating an imprint apparatus, the imprint apparatus comprising: a substrate chuck for holding a substrate; and a peripheral member disposed so as to surround a side surface of the substrate held by the substrate chuck;
    The operation method is as follows:
    Performing a cleaning process for cleaning at least a partial region of the peripheral member using a cleaning member including a charging unit;
    Supplying an imprint material onto the substrate held by the substrate chuck, and forming a pattern on the substrate by curing the imprint material in a state where a mold is in contact with the imprint material; Including,
    In the cleaning process, particles in the region are moved to the charging unit by moving the cleaning member relative to the peripheral member in a state where the charging unit is opposed to at least a part of the peripheral member. Including the action of adsorbing,
    A method of operating an imprint apparatus.
17. An article manufacturing method comprising:
    Forming a pattern on a substrate using the imprint apparatus according to any one of claims 1 to 15,
    Processing the substrate on which the pattern is formed;
    An article manufacturing method comprising:
18. An article manufacturing method comprising:
    Operating the imprint apparatus by the operation method according to claim 16, and forming a pattern on a substrate using the imprint apparatus;
    Processing the substrate on which the pattern is formed;
    An article manufacturing method comprising:
19. The cleaning member is disposed such that a mold is positioned between a dispenser that supplies an imprint material on the substrate and the cleaning member.
    The imprint apparatus according to claim 1, wherein the imprint apparatus is any one of claims 1 to 15.
20. The control unit performs control for bringing the charging unit of the cleaning member into a charged state or an uncharged state.
    The imprint apparatus according to claim 19.
21. The controller is configured to charge the charging unit before supplying the imprint material to the substrate by the dispenser.
    The imprint apparatus according to claim 20.
22. The width of the charging portion in the direction orthogonal to the direction in which the cleaning member and the dispenser are arranged is larger than the width of the pattern area of the mold,
    The imprint apparatus according to any one of claims 19 to 21, wherein the imprint apparatus according to any one of claims 19 to 21 is provided.
23. A gas supply unit for supplying a gas for discharging the mold;
    A voltage control unit for controlling a voltage applied to the charging unit;
    The imprint apparatus according to claim 1, further comprising:
24. The voltage control unit sets a voltage applied to the charging unit such that an electric field strength generated between the charging unit and the peripheral member is equal to or lower than an electric field strength at which discharge occurs through the gas;
    The imprint apparatus according to claim 23.
25. The voltage applied to the charging unit varies depending on the type of gas or the distance between the charging unit and the peripheral member.
    The imprint apparatus according to claim 24, wherein:
26. The static elimination of the mold is performed by replacing the gap between the mold and the imprint material separated from the cured imprint material with the gas.
    The imprint apparatus according to any one of claims 23 to 25, wherein:
27. The gas includes a gas whose mean free path for electrons is longer than air.
    The imprint apparatus according to any one of claims 23 to 26, wherein:
28. The gas includes helium;
    The imprint apparatus according to any one of claims 23 to 26, wherein:
29. The voltage control unit discharges the voltage applied to the charging unit while the gas supply unit does not supply the gas and the electric field strength generated between the charging unit and the peripheral member through the gas. Set to be higher than the electric field strength that occurs,
    The imprint apparatus according to claim 23.

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