WO2017143736A1 - Condensateur électrolytique en aluminium et son procédé de fabrication - Google Patents
Condensateur électrolytique en aluminium et son procédé de fabrication Download PDFInfo
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- WO2017143736A1 WO2017143736A1 PCT/CN2016/094921 CN2016094921W WO2017143736A1 WO 2017143736 A1 WO2017143736 A1 WO 2017143736A1 CN 2016094921 W CN2016094921 W CN 2016094921W WO 2017143736 A1 WO2017143736 A1 WO 2017143736A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrolytic capacitor
- aluminum electrolytic
- dispersion
- formula
- capacitor according
- Prior art date
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- 239000003990 capacitor Substances 0.000 title claims abstract description 41
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 36
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 239000006185 dispersion Substances 0.000 claims abstract description 49
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 33
- 239000002270 dispersing agent Substances 0.000 claims abstract description 22
- 239000002245 particle Substances 0.000 claims abstract description 15
- 230000003647 oxidation Effects 0.000 claims abstract description 9
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 9
- 150000001450 anions Chemical class 0.000 claims description 25
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 229920000123 polythiophene Polymers 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 11
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 10
- 229960002796 polystyrene sulfonate Drugs 0.000 claims description 10
- 239000011970 polystyrene sulfonate Substances 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- -1 carboxylic acid anion Chemical class 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- 229920000767 polyaniline Polymers 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 5
- 229920000128 polypyrrole Polymers 0.000 claims description 5
- 125000005156 substituted alkylene group Chemical group 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 125000003368 amide group Chemical group 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 150000002240 furans Chemical class 0.000 claims description 3
- 150000002596 lactones Chemical class 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 150000003077 polyols Chemical class 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 150000003951 lactams Chemical group 0.000 claims description 2
- 150000005846 sugar alcohols Chemical class 0.000 claims description 2
- 150000003457 sulfones Chemical class 0.000 claims description 2
- 150000003462 sulfoxides Chemical class 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims 1
- 239000002322 conducting polymer Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 229920000447 polyanionic polymer Polymers 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 4
- 238000002048 anodisation reaction Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- MAGFQRLKWCCTQJ-UHFFFAOYSA-N 4-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(C=C)C=C1 MAGFQRLKWCCTQJ-UHFFFAOYSA-N 0.000 description 1
- UJOBWOGCFQCDNV-UHFFFAOYSA-N Carbazole Natural products C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920001088 polycarbazole Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 1
- 229940057847 polyethylene glycol 600 Drugs 0.000 description 1
- 229920002098 polyfluorene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H01G9/028—Organic semiconducting electrolytes, e.g. TCNQ
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/0029—Processes of manufacture
- H01G9/0036—Formation of the solid electrolyte layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/042—Electrodes or formation of dielectric layers thereon characterised by the material
- H01G9/045—Electrodes or formation of dielectric layers thereon characterised by the material based on aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/15—Solid electrolytic capacitors
Definitions
- the present application relates to the field of capacitors, and in particular to an aluminum electrolytic capacitor and a method of manufacturing the same.
- the conductive polymer is a kind of polymer compound having a conjugated ⁇ bond structure, which is chemically or electrochemically doped to form an anion or a cation to form a conductive special polymer material, including polyacetylene, polythiophene, polypyrrole. , polyaniline, polyparaphenylene, polycarbazole and polyfluorene.
- conductive polymers have both the photoelectric properties of metal and semiconductor materials, good polymer stability and mechanical properties, relatively light weight, and ease of processing.
- the most successful conductive polymers currently used in the industrial field are polyaniline and polythiophene, especially poly(3,4-ethylenedioxythiophene) (PEDOT) among polythiophene derivatives, but also because of its high conductivity, Good environmental stability, transparency in doped state, etc., and widely used in electronic devices such as organic electro-display, organic solar cells and supercapacitors.
- PEDOT poly(3,4-ethylenedioxythiophene)
- the Chinese invention patent No. 200680033112.0 discloses a method for preparing an electrolytic capacitor, the method comprising at least the following steps: a) subjecting a porous electrode body of an electrode material to anodization to form a dielectric covering a surface of the electrode material; b) Applying a dispersion on the porous body, the porous body comprising at least a porous electrode body of an electrode material and a dielectric, the dispersion comprising at least particles and a dispersant of the conductive polymer; c) forming a solid electrolyte completely or partially covering the surface of the dielectric, The dispersant is at least partially removed and/or cured, the maximum anodization voltage of the porous electrode body during anodization is greater than 30 V, and the average particle diameter of the conductive polymer particles in the dispersion is from 1 to 100 nm.
- the pore size of the porous anode becomes larger, and the lower the voltage, the smaller the pore diameter, and the smaller the pore size, the more difficult the extraction is.
- the electrolytic capacitor of the above patent is used for a voltage lower than 30 V, the pore diameter of the porous anode is greatly reduced, so that normal discharge cannot be ensured.
- the technical problem to be solved by the present invention is to provide an aluminum electrolytic capacitor capable of ensuring that the aperture is at a certain size under a low voltage condition to facilitate discharge, and further provides a method for preparing the above aluminum electrolytic capacitor.
- the technical solution adopted by the present invention is:
- An aluminum electrolytic capacitor having an oxidation voltage of not more than 30 V, comprising a dispersion comprising a conductive polymer and a dispersant, the conductive polymer having an average particle diameter of 5 to 40 nm.
- the present invention also provides a method of preparing an aluminum electrolytic capacitor, the dispersion is applied to an electrode of the above-described aluminum electrolytic capacitor, and then the dispersant is partially or completely removed, or the dispersant is cured.
- the number of removals or curings is one or more times.
- the obtained aluminum electrolytic capacitor has the advantages of low loss, low equivalent series resistance, and low leakage.
- the most critical idea of the present invention is that, by controlling the average particle diameter of the conductive polymer to be 5-40 nm under the condition that the anodization voltage is not more than 30 V, the technical effect of easy discharge is achieved.
- the present invention provides an aluminum electrolytic capacitor having an oxidation voltage of not more than 30 V, including a dispersion, the dispersion comprising a conductive polymer and a dispersant, the conductive polymer having an average particle diameter of 5 -40 nm.
- the present invention also provides a method of preparing an aluminum electrolytic capacitor, the dispersion is applied to an electrode of the above-described aluminum electrolytic capacitor, and then the dispersant is partially or completely removed, or the dispersant is cured.
- the number of removals or curings is one or more times.
- the obtained aluminum electrolytic capacitor has the advantages of low loss, low equivalent series resistance, and low leakage.
- the conductive polymer includes a polythiophene derivative
- the polythiophene derivative includes There are repeating units of the formula I and/or formula II, which have the structural formula:
- A is an optionally substituted alkylene group having 1 to 5 carbon atoms
- R is an optionally substituted direct bond having 5 to 12 carbon atoms or A branched cycloalkyl group, an optionally substituted straight or branched aryl group having 6 to 14 carbon atoms, an optionally substituted linear or branched aralkyl group having 7 to 18 carbon atoms, optionally substituted A linear or branched hydroxyalkyl group having a carbon number of 1 to 4 or a hydroxyl group
- X is an integer of 0-8.
- A binds to several A groups, these groups may be the same or different.
- the polythiophene derivative of the present invention may be a repeating unit having a composition of the formula I, a repeating unit having a composition of the formula II, or a repeating unit having a composition of the formula I and the formula II.
- the polythiophene derivative may be an optionally substituted polythiophene, and preferably the above-mentioned repeating unit having a composition of the following formula I and/or formula II.
- the polythiophene derivative of the above structure can be better matched with the pore size of the anode to further improve the ease of discharge.
- the conductive polymer further includes at least one of a polypyrrole derivative and a polyaniline derivative.
- the dispersion further comprises a polymeric anion.
- the polymeric anion is a polymeric carboxylic acid anion or a polymeric sulfonate anion. More preferably, the polymeric anion is a polystyrene sulfonate anion having a molecular weight of from 1000 to 1,000,000.
- a polymeric anion is added to the dispersion, and the polyanion can be used as a composite ion, which is compounded with polythiophene and then dispersed into water.
- the polyanion can also act as a dopant to control the molecular weight of the polystyrene sulfonate anion to be 1000- 1000000, the polythiophene can be better dispersed in water.
- the polystyrenesulfonate anion has a molecular weight of 20,000 to 200,000.
- the dispersing agent is an organic solvent and/or water.
- the dispersion further includes at least one of a crosslinking agent, a surfactant, and an additive selected from the group consisting of an ether, a lactone, an amide group, a lactam group, a sulfone, a sulfoxide, a sugar, At least one of a sugar derivative, a sugar alcohol, a furan derivative, a glycol, and a polyol.
- a crosslinking agent selected from the group consisting of an ether, a lactone, an amide group, a lactam group, a sulfone, a sulfoxide, a sugar, At least one of a sugar derivative, a sugar alcohol, a furan derivative, a glycol, and a polyol.
- crosslinking agent and the surfactant may be those commonly used in the prior art as crosslinking agents and surfactants.
- the addition of the crosslinking agent, the surfactant and the additive respectively have an effect of effectively crosslinking and lowering the surface tension.
- the dispersion has a pH of 1.5-7, and the dispersion has a viscosity of not more than 500 cps at 20 °C.
- the pH and viscosity of the dispersion can be controlled as described above. More preferably, the pH of the dispersion is 2 to 5, and the viscosity can be tested at 60 rpm.
- the pH in the dispersion can be adjusted by adding an acid or a base; the step of "applying the dispersion and then partially or completely removing the dispersant or curing the dispersant" can be carried out once or repeatedly. More than two times.
- An aluminum electrolytic capacitor of the embodiment wherein an anode of the aluminum electrolytic capacitor has an oxidation voltage of 25 V, comprising a dispersion comprising a conductive polymer, a dispersant, and a polymeric anion, further comprising an additive, wherein the additive is A mixture of an ether, a lactone, an amide group, a furan derivative, and a polyol.
- the dispersion had a pH of 1.5 and the dispersion had a viscosity of 500 cps at 20 °C.
- the conductive polymer had an average particle diameter of 5 nm.
- the conductive polymer includes a polythiophene derivative, and further includes a polypyrrole derivative.
- the polymeric anion is a polystyrene sulfonate anion, the polystyrene sulfonate anion has a molecular weight of 1000, and the dispersing agent is water.
- the polythiophene derivative includes a repeating unit having the composition of the following formula I, and the structural formula of the formula I is:
- A is an optionally substituted alkylene group having 1 carbon atom
- R is an optionally substituted straight or branched cycloalkyl group having 5 carbon atoms, optionally substituted a linear aryl group having 6 carbon atoms, an optionally substituted linear aralkyl group having 7 carbon atoms, an optionally substituted linear hydroxyalkyl group having 1 carbon atom or a hydroxyl group
- X is 0.
- An aluminum electrolytic capacitor of the embodiment wherein an anode of the aluminum electrolytic capacitor has an oxidation voltage of 15 V, and includes a dispersion comprising a conductive polymer, a dispersant, and a polymerization anion, and further comprising an additive, wherein the additive is ether.
- the pH of the dispersion was 7, and the viscosity of the dispersion at 20 ° C was 400 cps.
- the conductive polymer had an average particle diameter of 40 nm.
- the conductive polymer includes a polythiophene derivative, and further includes a polypyrrole derivative and a polyaniline derivative.
- the polymeric anion is a polystyrene sulfonate anion, the polystyrene sulfonate anion has a molecular weight of 1,000,000, and the dispersing agent is an organic solvent.
- the polythiophene derivative includes a repeating unit having the composition of the following formula II, and the structural formula of the formula II is:
- A is an optionally substituted alkylene group having 5 carbon atoms
- R is an optionally substituted branched cycloalkyl group having 12 carbon atoms, optionally substituted carbon atoms Is a branched aryl group of 14, an optionally substituted branched aralkyl group having 18 carbon atoms, an optionally substituted branched hydroxyalkyl group having 4 carbon atoms or a hydroxyl group
- X is 8.
- An aluminum electrolytic capacitor of the embodiment wherein an anode of the aluminum electrolytic capacitor has an oxidation voltage of 5 V, and includes a dispersion comprising a conductive polymer, a dispersant, and a polymeric anion, and further comprising an additive, wherein the additive is Amide group.
- the dispersion had a pH of 4 and the dispersion had a viscosity of 200 cps at 20 °C.
- the conductive polymer had an average particle diameter of 20 nm.
- the conductive polymer includes a polythiophene derivative, and further includes a polyaniline derivative.
- the polymeric anion is a polystyrene sulfonate anion having a molecular weight of 800,000 and the dispersing agent is water.
- the polythiophene derivative includes a repeating unit having the composition of the following formula I and formula II, wherein the formula of the formula I is:
- A is an optionally substituted alkylene group having 2 carbon atoms; and R is an optionally substituted linear cycloalkyl group having 8 carbon atoms.
- R is an optionally substituted linear cycloalkyl group having 8 carbon atoms.
- Table 1 is a performance test table in which the cores of the four specifications contain the dispersion B.
- Example 1 100 g of the poly(3,4-dialkoxythiophene) polyanion dispersion of Example 1, 5 g of dimethyl sulfoxide, 5 g of polyethylene glycol 400, 0.5 g of 3-glycidoxy trimethoxysilane (Silquest A-187), 2 g of sorbitol, 0.5 g of Dynol 604 (Air product) were mixed in a glass beaker with a magnetic stirrer to form a dispersion C.
- Table 2 is a performance test table in which the cores of the four specifications contain the dispersion C.
- Example 1 100 g of the poly(3,4-dialkoxythiophene) polyanion dispersion of Example 1, 5 g of dimethyl sulfoxide, 5 g of polyethylene glycol 200, 0.5 g of 3-glycidoxytrimethoxysilane (Silquest A-187), 2 g xylitol, 0.5 g Dynol 604 (Air product) were mixed in a glass beaker with a magnetic stirrer to form a dispersion D.
- the cores of the four specifications were separately contained in Dispersion D, and then dried at 120 ° C and tested for their properties.
- Table 3 is a performance test table in which the cores of the four specifications contain the dispersion D.
- the aluminum electrolytic capacitor of the present application has a capacitance of 219-380 ⁇ F, a DF value of 1.4-1.8%, and an equivalent series resistance of 5-9 m ⁇ , and has an easy discharge, low loss, and low equivalent series resistance. And the advantage of low leakage.
- the aluminum electrolytic capacitor provided by the present application has the advantages of easy discharge, low loss, low equivalent series resistance, and low leakage.
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacturing & Machinery (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
L'invention concerne un condensateur électrolytique en aluminium et son procédé de fabrication. Un potentiel d'oxydation d'une anode du condensateur électrolytique en aluminium ne dépasse pas 30V et comprend une dispersion comprenant un polymère électroconducteur et un dispersant. Ledit polymère électroconducteur présente une taille particulaire moyenne de 5 à 40 nm. Le condensateur électrolytique en aluminium présente les avantages d'une fabrication facile, d'une faible perte, d'une faible résistance équivalente série et d'un faible courant de fuite.
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CN201610102588.0 | 2016-02-25 | ||
CN201610102588.0A CN105761938B (zh) | 2016-02-25 | 2016-02-25 | 一种铝电解质电容器及其制备方法 |
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WO2017143736A1 true WO2017143736A1 (fr) | 2017-08-31 |
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CN105761938B (zh) * | 2016-02-25 | 2019-02-15 | 深圳新宙邦科技股份有限公司 | 一种铝电解质电容器及其制备方法 |
JP7100029B2 (ja) * | 2017-05-31 | 2022-07-12 | 綜研化学株式会社 | 導電性高分子固体電解コンデンサの製造方法及び導電性高分子 |
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CN104952621A (zh) * | 2015-05-04 | 2015-09-30 | 深圳新宙邦科技股份有限公司 | 铝电解电容器用电解液及使用该电解液的铝电解电容器 |
CN105761938A (zh) * | 2016-02-25 | 2016-07-13 | 深圳新宙邦科技股份有限公司 | 一种铝电解质电容器及其制备方法 |
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