WO2017110289A1 - 水分散体、コーティング液及び透過型スクリーンの製造方法 - Google Patents
水分散体、コーティング液及び透過型スクリーンの製造方法 Download PDFInfo
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- G—PHYSICS
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- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
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Definitions
- the present invention relates to a method for producing an aqueous dispersion, a coating liquid, and a transmission screen.
- transmissive screens that can project and display information such as advertisements while maintaining light transparency have attracted attention.
- the transmission type screen is used for, for example, a show window of a commercial building and a guide plate.
- the transmission type screen is attracting attention not only in the construction field but also in the automobile field.
- a transmissive screen as a head-up display (HUD) for projecting position information or the like onto a windshield of an automobile has been studied extensively in recent years.
- HUD head-up display
- transmissive screen a laminated glass type in which a hologram is enclosed between two pieces of glass, a film type in which a resin film containing high refractive index fine particles is pasted on the surface of a transparent substrate, and high refractive index fine particles are transparent Panel type that is kneaded into the substrate, coating type that forms a light scattering film by applying a dispersion liquid in which high refractive index fine particles are dispersed in a transparent dispersion medium to the surface of a transparent substrate such as glass It has been known. Among them, in particular, improvement of a highly transparent paint film type transmission screen is desired.
- transmission screens used for show windows, guide plates, etc. are often seen not only from the front but also from the diagonal. Therefore, it is required that the appearance of the screen surface is not cloudy, has good light scattering properties, and that the image on the screen surface can be clearly seen even from an oblique angle.
- Patent Document 1 discloses that nanodiamonds are surface-modified by oxidizing nanodiamonds in a supercritical fluid composed of water and / or alcohol, and the dispersibility of diamond fine particles in water and solvent is improved.
- An improved liquid composition containing fine diamond particles and a binder is disclosed.
- Patent Document 2 discloses a “nanodiamond composite” in which nanodiamond particles are coated (surface modified) with polyvinyl alcohol (PVA) and further dispersed in a cycloolefin polymer (COP). .
- PVA polyvinyl alcohol
- COP cycloolefin polymer
- the coating film type screen should not be peeled off. It is desired to have durability that can withstand use.
- the present invention has been made in view of the above circumstances, and is a coating liquid that achieves both high transparency visibility and excellent light scattering reflectivity and enables formation of a light scattering film having excellent durability.
- Another object of the present invention is to provide a method for producing a transmission screen using the same, and an aqueous dispersion capable of easily adjusting the coating liquid.
- the aqueous dispersion according to the present invention contains fine particles having a refractive index of 2.0 or more and an anionic polymer, and has a median diameter of 0.01 ⁇ m to 1.0 ⁇ m by a dynamic light scattering method.
- a coating liquid in which the high refractive index fine particles are well dispersed can be easily prepared. According to the coating liquid, it is possible to form a light scattering film that achieves both high transparency visibility and excellent light scattering reflectivity and excellent durability such as adhesion to a substrate and water resistance. .
- the fine particles contain at least one component selected from the group consisting of diamond, diamond derivatives, barium titanate, zirconium oxide, and titanium oxide. In this case, it becomes easy to improve the transparent visibility of the film formed from the coating liquid using the aqueous dispersion.
- the anionic polymer preferably has at least one anionic group selected from the group consisting of a carboxy group, a carboxylate group, a sulfo group and a sulfonate group.
- the dispersion stability of the high refractive index fine particles tends to be further improved.
- a coating liquid in which the high refractive index fine particles are further satisfactorily dispersed can be easily prepared. According to the coating liquid, it is possible to form a light scattering film having further excellent water resistance and moisture resistance.
- the anionic polymer preferably contains at least one resin selected from the group consisting of a polyurethane resin, an acrylic resin, and an acrylic urethane resin, which is water-soluble or water-dispersible.
- a polyurethane resin an acrylic resin
- an acrylic urethane resin which is water-soluble or water-dispersible.
- the polyurethane resin and the acrylic urethane resin preferably have a structural unit derived from at least one polyol component selected from the group consisting of polyester polyol and polycarbonate polyol.
- a coating solution that can form a light-scattering film that is more excellent in light resistance and adhesion to a substrate.
- the coating liquid according to the present invention contains fine particles having a refractive index of 2.0 or more and an anionic polymer, and has a median diameter of 0.01 to 1.0 ⁇ m by a dynamic light scattering method.
- the fine particles contain at least one component selected from the group consisting of diamond, diamond derivatives, barium titanate, zirconium oxide, and titanium oxide.
- the anionic polymer preferably has at least one anionic group selected from the group consisting of a carboxy group, a carboxylate group, a sulfo group, and a sulfonate group.
- the anionic polymer contains at least one resin selected from the group consisting of a polyurethane resin, an acrylic resin, and an acrylic urethane resin, which is water-soluble or water-dispersible.
- the polyurethane resin and the acrylic urethane resin preferably have a structural unit derived from at least one polyol component selected from the group consisting of polyester polyol and polycarbonate polyol.
- the coating liquid according to the present invention is preferably for a transmission screen.
- the method for manufacturing a transmission screen according to the present invention includes a step of coating the substrate with the coating liquid according to the present invention.
- the transmission screen manufactured by the manufacturing method according to the present invention is excellent in durability and can have good light scattering reflectivity without impairing the transparent visibility.
- the transmissive screen obtained by the method of the present invention is suitable as a transmissive screen for show windows and a head-up display screen placed in a harsh environment such as outdoors.
- the transmissive screen may be used for a head-up display.
- the coating liquid which makes it possible to form the light-scattering film which has high transparency visibility and the outstanding light-scattering reflectivity, and has the outstanding durability, and a transmissive screen using the same It is possible to provide a production method and an aqueous dispersion capable of easily adjusting the coating liquid.
- FIG. 1 is a schematic cross-sectional view showing an embodiment of a transmission screen according to the present invention. It is a schematic diagram for demonstrating the scattering direction of light when light injects into the transmissive screen which concerns on an Example.
- structural unit derived from A and B means “structural unit derived from A and structural unit derived from B”.
- the water dispersion according to the present embodiment includes fine particles having a refractive index of 2.0 or more and an anionic polymer.
- the median diameter of the aqueous dispersion by the dynamic scattering method is preferably 0.01 to 1.0 ⁇ m.
- the median diameter is 0.01 ⁇ m or more, it becomes easy to improve the light scattering reflectivity of the film formed from the coating liquid using the aqueous dispersion.
- the median diameter is 1.0 ⁇ m or less, it becomes easy to improve the dispersion stability of the aqueous dispersion and the transparent visibility of the film formed from the coating liquid using the aqueous dispersion.
- the median diameter is preferably 0.05 to 0.7 ⁇ m.
- the median diameter is a value obtained by measuring fine particles dispersed in an aqueous dispersion with a Zetasizer Nano ZS (manufactured by Malvern) at a measurement temperature of 25 ° C.
- fine particles also include secondary particles such as primary particles of fine particles and aggregates thereof.
- the refractive index of the fine particles contained in the light scattering film is preferably higher than that of the material constituting the film other than the fine particles.
- the refractive index of fine particles in this embodiment may be 2.0 or more, and preferably 2.3 or more.
- the refractive index of the fine particles may be 3.0 or less.
- such fine particles having a refractive index of 2.0 or more are defined as “high refractive index fine particles”.
- the refractive index of a fine particle is measured by the method as described in an Example.
- High refractive index fine particles include, for example, diamond (refractive index 2.4), diamond derivatives, barium titanate (refractive index 2.4), zirconium oxide (refractive index 2.4), and titanium oxide (refractive index 2.7). And fine particles containing at least one component selected from the group consisting of: When the high refractive index fine particles contain these components, it becomes easy to improve the transparent visibility of the film formed from the coating liquid using the aqueous dispersion. From the viewpoint of improving the compatibility with the anionic polymer, the high refractive index fine particles preferably contain diamond. Examples of the diamond derivative include fluorinated diamond and siliconized diamond.
- the high refractive index fine particles may contain a single type of component alone or may contain two or more types of components.
- the high refractive index fine particles may be an aggregate of fine particles containing diamond (diamond aggregate), for example.
- the aggregate of fine particles containing nanodiamond obtained by an explosion method may be an unpurified aggregate (unpurified product) or a purified product (purified product).
- unpurified product fine particles containing nanodiamond have a core / shell structure in which the surface of nanodiamond is covered with graphite-based carbon, and are colored black.
- the purified product is obtained by oxidizing the fine particles containing nanodiamond in the unpurified product and removing the phase (graphite phase) made of graphite hydrocarbons.
- a purified product is preferable from the viewpoint of obtaining a light scattering film with less coloring.
- the average particle diameter of the high refractive index fine particles is preferably 0.01 ⁇ m to 10 ⁇ m.
- the average particle diameter is 10 ⁇ m or less, high refractive index fine particles are unlikely to caking and the high refractive index fine particles tend to be uniformly dispersed.
- the average particle diameter of the fine particles is 0.01 ⁇ m or more, the light scattering reflectivity of the film formed from the coating liquid using the aqueous dispersion can be easily improved.
- caking refers to a phenomenon in which fine particles settle, accumulate, and solidify over time.
- the average particle diameter of the above-mentioned highly refractive fine particles is determined by observation with a transmission electron microscope (TEM), observation with a scanning electron microscope (SEM), or the like. Specifically, for any 50 or more highly refractive fine particles in the observation photograph, the particle diameter (diameter) of each particle is measured and obtained by arithmetically averaging them. In the observation photograph, when the shape of the highly refractive fine particle is not a perfect circle, the diameter of the maximum circumscribed circle of the cross section of the particle is measured as the particle diameter (diameter).
- TEM transmission electron microscope
- SEM scanning electron microscope
- the content of the high refractive index fine particles is preferably 1 to 50 parts by mass and more preferably 5 to 25 parts by mass with respect to 100 parts by mass of the anionic polymer.
- the content of the high refractive index fine particles is within the above range, the dispersion stability of the high refractive index fine particles is improved and the adhesion of the film formed from the coating liquid using the aqueous dispersion to the substrate is improved. Can be sufficient.
- an anionic polymer means a polymer having an anionic functional group (anionic group).
- the anionic polymer has at least one kind of anionic group selected from the group consisting of a carboxy group, a carboxylate group, a sulfo group, and a sulfonate group from the viewpoint of excellent dispersion stability of the high refractive index fine particles.
- an anionic polymer having a carboxy group and / or a carboxylate group, or an anionic polymer having a sulfo group and / or a sulfonate group is more preferable.
- An anionic polymer may have one kind of anionic group independently, and may have two or more kinds of anionic groups.
- the content of the anionic group in the anionic polymer is preferably 0.1 to 5.0% by mass, and preferably 0.2 to 2.5% by mass based on the total mass of the anionic polymer. More preferred.
- an aqueous dispersion having further excellent dispersion stability of the high refractive index fine particles can be easily obtained, and a light scattering film (transparent thin film layer) in a transmission screen described later is used. ) Can be further improved in water resistance and moisture resistance.
- the total content of the carboxy group and the carboxylate group is determined from the same viewpoint as the reason for the content of the anionic group. It is preferably 0.5 to 4.0% by mass, more preferably 0.7 to 2.5% by mass, based on the mass.
- the total content of the sulfo group and the sulfonate group is the same as the reason for the content of the anionic group, from the same viewpoint as the reason for the content of the anionic group.
- it is preferably 0.1 to 1.0% by mass, more preferably 0.2 to 1.0% by mass.
- the anionic polymer has a carboxyl group and / or a carboxylate group, and a sulfo group and / or a sulfonate group, from the same viewpoint as the reason for the content of the anionic group, the carboxyl group and the carboxylate group
- the total content is preferably 0.1 to 4.0% by mass based on the total mass of the anionic polymer, and the total content of sulfo groups and sulfonate groups is based on the total mass of the anionic polymer 0.1 to 1.0% by mass is preferable.
- the anionic polymer is preferably an aqueous resin such as a water-soluble resin or a water-dispersible resin.
- the water dispersibility means that the anionic polymer is a self-emulsifying type.
- the median diameter of the water-dispersible resin by a dynamic light scattering method is preferably 0.05 to 0.2 ⁇ m. In this case, the dispersion stability of the high refractive index fine particles can be made sufficient, and the water resistance and moisture resistance of the light scattering film (transparent thin film layer) in the transmission screen described later can be further improved. .
- An anionic polymer is a water-soluble or water-dispersible polyurethane resin, acrylic resin, acrylic urethane resin, from the viewpoint of improving the adhesion of a film formed from a coating liquid using a water dispersion to a substrate. It is preferable to include at least one resin selected from the group consisting of an acrylic silicon resin and a polyester resin, and is at least one selected from the group consisting of a polyurethane resin, an acrylic resin, and an acrylic urethane resin that is water-soluble or water-dispersible. It is more preferable to contain this resin. As the anionic polymer, one kind of these resins may be used alone, or two or more kinds may be used in combination.
- the anionic polymer contains at least one resin selected from the group consisting of a polyurethane resin and an acrylic urethane resin, which is water-soluble or water-dispersible
- the resin contains (a) an organic polyisocyanate (hereinafter referred to as “(a And a structural unit derived from (b) polyol (hereinafter referred to as “component (b)”). That is, the anionic polymer may be a condensation reaction product obtained by reacting the component (a) and the component (b).
- the component (a) is not particularly limited, and may be, for example, an aliphatic polyisocyanate, an alicyclic polyisocyanate, or an aromatic polyisocyanate having two or more isocyanate groups.
- organic polyisocyanates include aliphatic diisocyanate compounds such as hexamethylene diisocyanate, 1,5-pentamethylene diisocyanate, and trimethylhexamethylene diisocyanate; isophorone diisocyanate, hydrogenated xylylene diisocyanate, dicyclohexylmethane diisocyanate, norbornane diisocyanate, Alicyclic diisocyanate compounds such as 1,3-bis (isocyanatomethyl) cyclohexane; aromatic diisocyanate compounds such as tolylene diisocyanate, diphenylmethane diisocyanate, naphthalene diisocyanate, tolidine diisocyanate, xylylene diiso
- the component (a) preferably has a structural unit derived from an aliphatic diisocyanate compound or an alicyclic diisocyanate compound from the viewpoint of imparting no yellowing to a light scattering film (for example, a transparent thin film layer described later).
- a light scattering film for example, a transparent thin film layer described later.
- the aliphatic diisocyanate compound hexamethylene diisocyanate can be suitably used.
- As the alicyclic diisocyanate compound isophorone diisocyanate, dicyclohexylmethane diisocyanate, norbornane diisocyanate and 1,3-bis (isocyanatomethyl) cyclohexane can be preferably used.
- the polyurethane resin and the acrylic urethane resin may have one or more structural units derived from the component (a).
- the component (b) may be a compound having two or more hydroxyl groups.
- the component (b) include polyester polyol, polycarbonate polyol, acrylic polyol, polyether polyol, polyether ester polyol having an ether bond and an ester bond, silicone polyol, and fluorine polyol.
- polyester polyol and polycarbonate polyol are preferable from the viewpoint of further improving light resistance of a light scattering film (for example, a transparent thin film layer to be described later) and adhesion to a substrate, and the moisture resistance and water resistance of the light scattering film are preferable. From the viewpoint of further improvement, polycarbonate polyol is more preferable.
- polyester polyol examples include polyethylene adipate diol, polybutylene adipate diol, polyethylene butylene adipate diol, polyhexamethylene isophthalate adipate diol, polyethylene succinate diol, polybutylene succinate diol, polyethylene sebacate diol, and polybutylene sebacate diol.
- Examples include copolycondensates, polycondensates of nonanediol and dimer acid, and copolycondensates of ethylene glycol, adipic acid and dimer acid.
- the polycarbonate polyol is a polyol having a carbonate bond in the molecule and having two or more hydroxyl groups, and can be obtained, for example, by reacting a polyol with an organic carbonate compound or phosgene.
- polyols include 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, neopentyl glycol, Examples include 1,4-cyclohexanedimethanol, 1,10-decanediol and isosorbide.
- the polycarbonate polyol can have one or more structural units derived from the above polyols.
- the organic carbonate compound or phosgene include diphenyl carbonate.
- the polyurethane resin and the acrylic urethane resin may have one or two or more structural units derived from the component (b).
- the weight average molecular weight of the component (b) is preferably 500 to 5000, more preferably 1000 to 3000.
- the said weight average molecular weight can be obtained by measuring a hydroxyl value according to the terminal specified amount method.
- a water-soluble polyurethane resin or a water-dispersible polyurethane resin (hereinafter referred to as “aqueous polyurethane resin”) having an anionic group in the resin skeleton is preferable.
- aqueous polyurethane resin examples include (I) a polyurethane resin having a carboxy group and / or a carboxylate group (hereinafter referred to as “polyurethane resin A”), (II) a polyurethane resin having a sulfo group and / or a sulfonate group (hereinafter referred to as “polyurethane resin A”). "Polyurethane resin B”) can be suitably used.
- polyurethane resin A for example, a structural unit derived from the component (a), a structural unit derived from the component (b), (c) a compound having a carboxy group and two or more active hydrogen groups (hereinafter, A polyurethane resin having a structural unit derived from "(c) component”), a structural unit derived from (d) a polyamine compound having two or more amino groups and / or imino groups (hereinafter "(d) component”) are preferably used.
- the polyurethane resin A may have one type of structural unit derived from the component (a) alone or in combination of two or more types. The same applies to the component (b).
- the component may be a compound having a carboxy group and two or more active hydrogen groups.
- the active hydrogen group include a hydroxyl group.
- the compound applicable also to (c) component is considered as (c) component.
- component (c) examples include 2,2-dimethylolpropionic acid and 2,2-dimethylolbutanoic acid.
- the component (c) may be a polyester polyol having a pendant carboxy group obtained by reacting a diol having a carboxy group with an aromatic dicarboxylic acid, an aliphatic dicarboxylic acid or the like.
- the polyurethane resin A may have one or more structural units derived from the component (c).
- ethylenediamine, tetramethylenediamine, hexamethylenediamine, diethylenetriamine, triethylenetetramine, hydrazine, piperazine, diaminodiphenylmethane, tolylenediamine, xylylenediamine, isophoronediamine, norboranediamine and the like are contained in one molecule.
- Examples include polyamine compounds containing two or more primary and / or secondary amino groups.
- the polyurethane resin A may have one or more structural units derived from the component (d).
- the polyurethane resin A can be obtained, for example, by a method comprising a step of reacting the component (a), the component (b) and the component (c) and a step of subjecting the component (d) to a chain extension reaction.
- a neutralized product of the isocyanate group-terminated prepolymer A having a carboxylate group (hereinafter also referred to as “prepolymer A neutralized product”) is obtained.
- the prepolymer A is a reaction product of the component (a), the component (b), and the component (c), the structural unit derived from the component (a), the structural unit derived from the component (b), and the component (c). It has a derived structural unit.
- the neutralized prepolymer A has a carboxylate group (—COO—) in which the carboxy group derived from the component (c) is neutralized.
- the component (a), the component (b), and the component (c) may be used alone or in combination of two or more of the components (a), (b), and (c) described above.
- the obtained prepolymer A may be neutralized and simultaneously with the preparation of the prepolymer A (c )
- the carboxy group derived from the component may be neutralized.
- the neutralization of the carboxy group derived from the component (c) can be appropriately performed using a known method.
- the compound used for such neutralization is not particularly limited, and for example, trimethylamine, triethylamine, tri-n-propylamine, tributylamine, N-methyl-diethanolamine, N, N-dimethylmonoethanolamine, N, N -Amines such as diethyl monoethanolamine and triethanolamine; potassium hydroxide; sodium hydroxide; ammonia and the like.
- tertiary amines such as trimethylamine, triethylamine, tri-n-propylamine and tributylamine are preferable.
- a specific method for obtaining the neutralized prepolymer A is not particularly limited, and for example, it is produced by a conventionally known one-stage method (so-called one-shot method), a multi-stage isocyanate polyaddition reaction method, or the like. be able to.
- the reaction temperature at this time is preferably 40 to 150 ° C.
- the neutralized prepolymer A is emulsified and dispersed in water, and then the neutralized prepolymer A and the component (d) may be reacted.
- the method of emulsifying and dispersing the prepolymer A neutralized product in water is not particularly limited, and examples thereof include a method using an emulsifying device such as a homomixer, a homogenizer, and a disper.
- an emulsifying device such as a homomixer, a homogenizer, and a disper.
- the prepolymer A neutralized product is water-free by self-emulsification without using any emulsifier. Is preferably emulsified and dispersed.
- the prepolymer A neutralized product is emulsified and dispersed in a temperature range of room temperature (25 ° C.) to 40 ° C.
- the chain extension reaction of the prepolymer A neutralized product can be performed by adding the component (d) to the prepolymer A neutralized product or by adding the prepolymer A neutralized product to the component (d). it can.
- the chain extension reaction is preferably performed at a reaction temperature of 20 to 40 ° C.
- the chain extension reaction is usually completed in 30 to 120 minutes.
- polyurethane resin B examples include a structural unit derived from the component (a), a structural unit derived from the component (b), a structural unit derived from the component (d), and (e) an amino group and / or an imino group.
- a polyurethane resin having a structural unit derived from a polyamine compound having two or more and a sulfo group and / or a sulfonate group (hereinafter referred to as “component (e)”) is preferably used.
- the (a) component, the (b) component, and the (d) component may be the same as the above-described (a) component, (b) component, and (d) component.
- the polyurethane resin B may have one or more structural units derived from the component (a). The same applies to the component (b) and the component (d).
- the component (e) may be any compound having two or more amino groups and / or imino groups and having a sulfo group and / or a sulfonate group. And ethyl sodium) -ethanesulfonate, sodium 2- (3-aminopropylamino) -ethanesulfonate, sodium 2,4-diaminobenzenesulfonate, and the like.
- Polyurethane resin B may have one or more structural units derived from component (e).
- the polyurethane resin B can be obtained, for example, by a method comprising a step of reacting the component (a), the component (b) and the component (e) and a step of subjecting the component (d) to a chain extension reaction.
- a neutralized product of an isocyanate group-terminated prepolymer B having a sulfonate group (hereinafter also referred to as “prepolymer B neutralized product”) is obtained. It is done.
- the prepolymer B is a reaction product of the component (a), the component (b), and the component (e), the structural unit derived from the component (a), the structural unit derived from the component (b), and the component (e). It has a derived structural unit.
- the neutralized prepolymer B has a sulfonate group (—SO 3 —) in which the sulfo group derived from the component (e) is neutralized.
- the component (a), the component (b), and the component (e) may be used alone or in combination of two or more of the components (a), (b), and (e) described above.
- the specific method for obtaining the prepolymer B neutralized product is not particularly limited, and a method for obtaining the prepolymer A neutralized product except that the component (e) is used instead of the component (c) It may be the same.
- the prepolymer B neutralized product is emulsified and dispersed in water, and then the prepolymer B neutralized product and the component (d) may be reacted.
- the polyurethane resin B can be obtained as an emulsified dispersion of the polyurethane resin B.
- Water-based polyurethane resins satisfying these requirements are Evaphanol HA-15 (trade name, manufactured by Nikka Chemical Co., Ltd., polyether type) and Evaphanol HA-50C (products manufactured by Nikka Chemical Co., Ltd.), which are aqueous dispersions of aqueous polyurethane resins.
- Polycarbonate type As a water-dispersible acrylic urethane resin, Neo sticker 1200 (trade name, polyester type manufactured by Nikka Chemical Co., Ltd.), which is an aqueous dispersion of an acrylic urethane resin, is available.
- a polycarbonate type and a polyester type can be preferably used.
- the polyether type means having a structural unit derived from a polyether polyol. The same applies to polycarbonate and polyester systems.
- water-dispersible acrylic resins examples include Boncoat HY364 (trade name, manufactured by Dainippon Ink & Chemicals, Inc.) and Neokryl XK-12 (trade name, manufactured by DSM), which are aqueous dispersions of acrylic resin. .
- As the water dispersible acrylic silicon resin Kanebinol KD4 (trade name, manufactured by NSC Japan, Inc.), which is an aqueous dispersion of an acrylic silicon resin, is available.
- As the water-dispersible polyester resin Vylonal MD1245 (trade name, manufactured by Toyobo Co., Ltd.), which is an aqueous dispersion of the polyester resin, is available.
- the content of the anionic polymer in the aqueous dispersion is preferably 20 to 50% by mass, more preferably 25 to 45% by mass, based on the total mass of the aqueous dispersion.
- At least a part of the anionic polymer may be emulsified and dispersed in water.
- the aqueous dispersion contains water.
- the aqueous dispersion may contain a solvent other than water.
- the solvent other than water include alcohols such as methanol, ethanol and isopropyl alcohol; acetone, methyl ethyl ketone, ethyl acetate, petroleum ether, n-methylpyrrolidone, propylene glycol monomethyl ether acetate, ethylene glycol dimethyl ether, diethylene glycol dimethyl ether, ethylene glycol diethyl Examples include ether and diethylene glycol diethyl ether.
- the water content may be 70% by mass or more, 80% by mass or more, or 100% by mass based on the total amount of water and a solvent other than water.
- the aqueous dispersion may contain other components other than the high refractive index fine particles, the anionic polymer, and water.
- other components include antifoaming agents, preservatives, thickeners, and the like.
- the aqueous dispersion according to this embodiment can be used for various coating liquids.
- the aqueous dispersion according to the present embodiment can be used as a blending component of a coating liquid used for forming a light scattering film, for example.
- the aqueous dispersion according to the present embodiment can be suitably used for forming the transparent thin film layer in a transmission screen including a transparent thin film layer that is a light scattering film.
- aqueous dispersion is obtained by adding and dispersing high refractive index fine particles to an anionic polymer emulsified and dispersed in water.
- fine particles such as the above-mentioned diamond aggregate can be used.
- the method of emulsifying and dispersing the anionic polymer in water is not particularly limited, and examples thereof include a method using an emulsifying device such as a homomixer, a homogenizer, and a disper. Moreover, you may emulsify and disperse
- the high refractive index fine particles can be dispersed by, for example, a dispersion apparatus usually used for pigment dispersion or the like.
- the dispersing device is not particularly limited.
- dispersers homomixers (such as PRIMIX “TK HOMODdisper”) and planetary mixers, homogenizers (trade name “Cleamix” manufactured by M Technique) ”, PRIMIX brand name“ Fillmix ”, etc.), paint conditioner (Red Devil), ball mill, sand mill (Shinmaru Enterprises brand name“ Dino Mill ”, etc.), attritor, pearl mill (Eirich) Product name “DCP mill”, etc.), bead mill (product name “Easy Nano RMB” manufactured by Imex Co., Ltd.), media type disperser such as coball mill), wet jet mill (product name “Genus PY” manufactured by Genus) "Sugino Machine's brand name” Star " Media name disperser such as "Most", product name "Nanomizer” manufactured by Nano
- High-refractive-index fine particles that have been adjusted to a desired particle size in advance may be used, or the particle size may be adjusted when dispersed so that the final desired particle size is obtained.
- Such a fine particle dispersion process can be performed using, for example, a bead mill.
- the time (processing time) for dispersing the high refractive index fine particles can be appropriately adjusted according to the dispersing device.
- the treatment time is preferably 12 to 60 minutes from the viewpoint of easily adjusting the median diameter of the aqueous dispersion to the above-mentioned preferred range.
- the prepared aqueous dispersion may be dispersed again.
- the coating liquid according to this embodiment contains high refractive index fine particles, an anionic polymer, and water.
- the coating liquid which concerns on this embodiment may be a coating liquid formed by mix
- the median diameter of the coating liquid by the dynamic light scattering method is 0.01 to 1 ⁇ m from the viewpoint of excellent dispersion stability of the coating liquid and easy formation of a coating film (film formed from the coating liquid). Preferably, it is 0.05 to 0.7 ⁇ m, more preferably 0.1 to 0.3 ⁇ m.
- the median diameter is a value measured at a measurement temperature of 25 ° C. using Zetasizer Nano ZS (manufactured by Malvern).
- the dispersion treatment may be performed on the coating liquid after preparation so that the median diameter is in the above range.
- high refractive index fine particles and the anionic polymer contained in the coating liquid are the same as the high refractive index fine particles and the anionic polymer contained in the aqueous dispersion, respectively.
- the coating liquid may contain additives such as a leveling agent, a crosslinking agent, and a repellency inhibitor as necessary.
- leveling agent examples include various surfactants such as fluorine and acetylene glycol; alcohols such as methanol, ethanol and isopropyl alcohol; acetone, methyl ethyl ketone, ethyl acetate, petroleum ether, n-methylpyrrolidone, propylene glycol monomethyl.
- surfactants such as fluorine and acetylene glycol
- alcohols such as methanol, ethanol and isopropyl alcohol
- acetone methyl ethyl ketone, ethyl acetate, petroleum ether, n-methylpyrrolidone, propylene glycol monomethyl.
- solvents such as ether acetate, ethylene glycol dimethyl ether, diethylene glycol dimethyl ether, ethylene glycol diethyl ether, and diethylene glycol diethyl ether.
- crosslinking agent examples include a crosslinking agent reactive with a carboxy group, a water-dispersible polyisocyanate crosslinking agent, and the like.
- crosslinking agent reactive with the carboxy group examples include an aqueous oxazoline crosslinking agent, an aqueous polycarbodiimide crosslinking agent, and an aqueous epoxy resin crosslinking agent.
- the coating liquid containing the additive can be prepared by, for example, mixing the additive with the aqueous dispersion according to the present embodiment and then performing a dispersion treatment using the dispersion treatment apparatus.
- the coating liquid according to the present embodiment can be used as a material for a transmission screen, for example.
- a coating liquid (a coating liquid for a transmission screen) used as a material for the transmission screen will be described.
- the median diameter of the transmissive screen coating liquid by the dynamic light scattering method is 0.01 to from the viewpoint of excellent transparency visibility and light scattering reflectivity of the coating film (film formed from the transmissive screen coating liquid).
- the thickness is preferably 1 ⁇ m, more preferably 0.05 to 0.7 ⁇ m, still more preferably 0.1 to 0.3 ⁇ m.
- the high refractive index fine particles preferably contain diamond (refractive index 2.4) from the viewpoint of excellent compatibility with an anionic polymer and a wide viewing angle of the coating film to improve visibility.
- the content of the high refractive index fine particles in the transmission screen coating liquid is preferably 1 to 50 parts by mass, more preferably 5 to 25 parts by mass with respect to 100 parts by mass of the anionic polymer.
- the content of the high refractive index fine particles is within the above range, the dispersion stability of the high refractive index fine particles in the coating liquid can be sufficiently ensured, and has sufficient optical properties and adhesion to the substrate. Can be easily formed.
- the anionic polymer has at least one anionic group selected from the group consisting of a carboxy group, a carboxylate group, a sulfo group, and a sulfonate group from the viewpoint of forming a coating film that is more excellent in adhesion to a substrate. Is preferred.
- the anionic polymer is water-soluble or water-dispersible from the group consisting of polyurethane resin, acrylic resin and acrylic urethane resin from the viewpoint of improving the adhesion of the coating film to the substrate. It is preferable to include at least one selected resin.
- the anionic polymer contains at least one resin selected from the group consisting of a polyurethane resin and an acrylic urethane resin that is water-soluble or water-dispersible, the resin is light resistance of the coating film and adhesion to the substrate. From the viewpoint of further improving the properties, it is preferable to have a structural unit derived from at least one polyol component selected from the group consisting of polyester polyols and polycarbonate polyols.
- the anionic polymer preferably contains the above-described polyurethane resin A and / or polyurethane resin B.
- the preferred embodiments of polyurethane resin A and polyurethane resin B are the same as polyurethane resin A and polyurethane resin B in the aqueous dispersion.
- the content of the anionic polymer in the transmission screen coating liquid is preferably 5 to 50% by mass, based on the total mass of the transmission screen coating liquid, and 10 to 45% by mass. % Is more preferable.
- the transmissive screen coating liquid may contain the above-mentioned additives.
- the transmissive screen coating liquid according to the present embodiment light having both high transparency visibility and excellent light scattering reflectivity, and excellent durability such as adhesion to water and water resistance.
- a scattering film can be formed, whereby a transmission screen having both excellent optical characteristics and durability can be easily obtained.
- the coating liquid for transmissive screens according to this embodiment can be obtained using the above-described aqueous dispersion, and in this case, the coating liquid can be prepared more easily.
- the transmission screen according to the present embodiment includes a substrate and a transparent thin film layer that is provided on the substrate and is derived from the transmission liquid for the transmission screen according to the present embodiment. That is, the transparent thin film layer is formed by coating a substrate with a transmissive screen coating liquid.
- the transparent thin film layer according to this embodiment can function as a light scattering film.
- the transmissive screen according to the present embodiment includes a transparent thin film layer formed by the transmissive screen coating liquid according to the present embodiment, and thus has high transparency visibility and excellent light scattering reflectivity. It can have durability.
- FIGS. 1A and 1B are schematic cross-sectional views showing one aspect of a transmission screen according to the present embodiment.
- One aspect of the transmissive screen 1 includes a substrate 11 and a transparent thin film layer 12 provided on the substrate 11.
- the transparent thin film layer 12 may be provided on both main surfaces of the substrate 11.
- substrate 11b may be further provided on the transparent thin film layer 12 provided on the 1st board
- the material (base-material) constituting the substrate 11 is preferably at least one selected from the group consisting of glass and polymer resins.
- glass is not specifically limited, From the viewpoint of practicality, oxide glass such as silicate glass, phosphate glass, and borate glass can be used. Among these, silicate glass is preferable.
- the silicate glass include silicate glass, alkali silicate glass, soda lime glass, potassium lime glass, lead glass, barium glass, and borosilicate glass.
- the polymer resin a resin excellent in visible light permeability is preferably used.
- a thermoplastic resin, a thermosetting resin, an ionizing radiation curable resin, or the like can be used.
- examples of such polymer resins include polyester resins, acrylic resins, acrylic urethane resins, polyester acrylate resins, polyurethane acrylate resins, epoxy acrylate resins, urethane resins, epoxy resins, and polycarbonate resins.
- Cellulose resin, acetal resin, vinyl resin, polyethylene resin, polystyrene resin, polypropylene resin, polyamide resin, polyimide resin, melamine resin, phenol resin, silicone resin, fluorine resin, etc. Can be mentioned.
- the transparent thin film layer 12 includes high refractive index fine particles 10 and an anionic polymer (not shown). Specific examples of the high refractive index fine particles 10 and the anionic polymer are the same as the high refractive index fine particles and the anionic polymer of the aqueous dispersion described above.
- the thickness of the transparent thin film layer 12 in the transmissive screen 1 is preferably 0.2 to 400 ⁇ m, more preferably 0.5 to 30 ⁇ m from the viewpoint of sufficient transparency visibility and sharpness of the reflected image. It is preferably 1 to 10 ⁇ m, more preferably 4 to 7 ⁇ m.
- the transmission screen 1 according to the present embodiment is not limited to the above-described embodiment, and may be a transmission screen (transmission sheet) including only the transparent thin film layer 12, for example.
- the substrate include substrates made of glass, polymer resin, metal, and the like. These substrates may be subjected to surface treatment such as peeling treatment.
- One embodiment of the method for manufacturing the transmission screen 1 includes a step of coating the substrate 11 with the coating liquid for the transmission screen. Through this process, the transparent thin film layer 12 is formed on the substrate 11.
- Coating of the transmission screen coating liquid onto the substrate 11 can be performed by a known method.
- the coating method include spray coating, dip coating, spin coating, and screen printing.
- the coating liquid in order to adjust the median diameter of the coating liquid to a desired range, the coating liquid may be dispersed immediately before coating.
- the manufacturing method according to the present embodiment may include a step of drying the substrate 11 after coating the substrate 11 with a transmissive screen coating liquid.
- the drying temperature may be room temperature (25 ° C.) to 120 ° C.
- the first substrate 11 a may be coated with a transmissive screen coating liquid to form the transparent thin film layer 12, and then the second substrate 11 b may be laminated on the transparent thin film layer 12.
- a transparent screen (transmission type sheet) composed only of the transparent thin film layer 12 may be obtained by peeling off the transparent thin film layer 12 on the substrate 11 obtained by the above-described method.
- both high transparency visibility and excellent light scattering reflectivity are compatible, and the adhesion between the substrate 11 and the transparent thin film layer 12 and the durability of the transparent thin film layer 12 are excellent.
- a transmission screen 1 can be obtained.
- the series of steps for manufacturing the transmission screen 1 includes the step of preparing the aqueous dispersion according to the above-described embodiment, the transmission screen can be obtained more easily.
- the transmission screen 1 according to the present embodiment can be applied as it is to a head-up display screen that projects position information or the like on the windshield of an automobile.
- the product cooling rate was 280 ° C./min.
- the specific gravity of BD was 2.55 g / cm 3 and the median diameter (dynamic light scattering method) was 220 nm. From the specific gravity of BD, it was calculated that BD was composed of 76% by volume of graphite-based carbon and 24% by volume of diamond.
- the obtained BD was mixed with an aqueous nitric acid solution having a concentration of 60% by mass, and an oxidative decomposition treatment was performed under conditions of 160 ° C., 14 atm, and 20 minutes. Thereafter, an oxidizing etching process was performed under conditions of 130 ° C., 13 atm, and 1 hour.
- an oxidizing etching process was performed under conditions of 130 ° C., 13 atm, and 1 hour.
- By oxidative etching treatment particles from which graphite carbon was partially removed from BD were obtained. The particles were refluxed with ammonia at 210 ° C., 20 atm for 20 minutes, neutralized, and then allowed to settle naturally. Next, washing with 35 mass% nitric acid was performed by decantation. Further, after washing with water three times by decantation, it was dehydrated by centrifugation and dried by heating at 120 ° C. Thereby, diamond fine particles were obtained.
- the diamond fine particles were further dispersed in water and decanted. By repeating this operation, the diamond fine particles A having a relatively small particle size and the diamond fine particles B having a relatively large particle size at the precipitation portion were separated.
- the median diameter and refractive index of diamond fine particles A and diamond fine particles B by dynamic scattering were as follows. (1) Diamond fine particles A: median diameter 0.41 ⁇ m (dynamic light scattering method), refractive index 2.4 (2) Diamond fine particles B: median diameter 2.5 ⁇ m (dynamic light scattering method), refractive index 2.4
- the refractive index of the fine particles was measured by the following method. First, a fine particle powder such as nanodiamond and polymethyl methacrylate resin are weighed and mixed with N-methylpyrrolidone so as to have a predetermined volume fraction. Thereby, the fine particles are dispersed and the resin is dissolved to prepare a coating film-forming coating material. Next, this paint is applied onto a substrate using a spin coater to form a coating film (coating amount: 2 ⁇ L, coating film forming condition: 50 ° C. for 10 minutes). Subsequently, the refractive index of a coating film is measured using a thin film refractive index measuring apparatus.
- a fine particle powder such as nanodiamond and polymethyl methacrylate resin are weighed and mixed with N-methylpyrrolidone so as to have a predetermined volume fraction. Thereby, the fine particles are dispersed and the resin is dissolved to prepare a coating film-forming coating material.
- this paint is applied onto a substrate using a
- the same operation was performed by changing the volume fraction of the fine particle powder, and the obtained refractive index value was plotted with the horizontal axis representing the volume fraction of the fine particle powder and the vertical axis representing the refractive index of the coating film. Plot to. Each plotted measurement point is approximated by a straight line, and this straight line is extrapolated to a point where the volume fraction of the fine particle powder becomes 100%, and the refractive index value at that point (with the refractive index at the volume fraction of 0%) (Not the difference) is the refractive index of the fine particles.
- the obtained aqueous dispersion 1 was measured with a Zetasizer Nano ZS (trade name, manufactured by Malvern) at a measurement temperature of 25 ° C., and the median diameter was 0.164 ⁇ m. The median diameter was measured within 5 minutes after the preparation of the aqueous dispersion 1.
- Preparation Example 2 A uniform dispersion was obtained in the same manner as in Preparation Example 1 except that Evaphanol HA-15 (trade name, non-volatile content: 30.4% by mass of Nikka Chemical Co., Ltd.), which is a carbonate-based aqueous urethane resin dispersion, was used as the dispersion. An aqueous dispersion 2 was obtained. In the cocoons, there seemed to be almost no aggregates. When the aqueous dispersion 2 was measured in the same manner as in Preparation Example 1, the median diameter was 0.178 ⁇ m. Next, the aqueous dispersion 2 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, but almost no sediment was observed.
- Evaphanol HA-15 trade name, non-volatile content: 30.4% by mass of Nikka Chemical Co., Ltd.
- the aqueous dispersion 3 was measured in the same manner as in Preparation Example 1, the median diameter was 0.058 ⁇ m. Next, the aqueous dispersion 3 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, but almost no sediment was observed.
- Preparation Example 4 Uniform in the same manner as in Preparation Example 3 except that Evaphanol HA-170 (trade name, non-volatile content: 36.5% by mass, manufactured by Nikka Chemical Co., Ltd.), which is a carbonate-based aqueous urethane resin dispersion, was used as the dispersion. An aqueous dispersion 4 was obtained. Aggregates were not found in the cocoons. When the aqueous dispersion 4 was measured in the same manner as in Preparation Example 1, the median diameter was 0.041 ⁇ m. Next, the aqueous dispersion 4 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, but almost no sediment was observed.
- Evaphanol HA-170 trade name, non-volatile content: 36.5% by mass, manufactured by Nikka Chemical Co., Ltd.
- Preparation Example 5 A uniform aqueous dispersion 5 was obtained in the same manner as in Preparation Example 1 except that the diamond fine particles B were used in place of the diamond fine particles A. In the cocoons, there seemed to be almost no aggregates.
- the aqueous dispersion 5 was measured in the same manner as in Preparation Example 1, the median diameter was 0.563 ⁇ m.
- the aqueous dispersion 5 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, but almost no sediment was observed.
- Preparation Example 6 Preparation Example 1 except that 3 parts by mass of commercially available zirconium oxide (ZrO 2 ) fine particles (manufactured by Kanto Denka Kogyo Co., Ltd., median diameter: 12 nm, refractive index: 2.4) were used instead of diamond fine particles A
- ZrO 2 zirconium oxide
- the aqueous dispersion 6 was measured in the same manner as in Preparation Example 1, the median diameter was 0.037 ⁇ m.
- the aqueous dispersion 6 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, but almost no sediment was observed.
- Preparation Example 7 10 parts by mass of diamond fine particles A were used, and as a dispersion, Boncoat HY364 (trade name, non-volatile content: 45.2% by mass, manufactured by Dainippon Ink & Chemicals, Inc.) which is an aqueous acrylic-urethane composite resin dispersion.
- Boncoat HY364 trade name, non-volatile content: 45.2% by mass, manufactured by Dainippon Ink & Chemicals, Inc.
- a uniform aqueous dispersion 7 was obtained in the same manner as in Preparation Example 1 except that it was used. In the cocoons, there seemed to be almost no aggregates.
- the aqueous dispersion 7 was measured in the same manner as in Preparation Example 1, the median diameter was 0.172 ⁇ m.
- the aqueous dispersion 7 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, but almost no sediment was observed.
- Preparation Example 9 The amount of diamond fine particles A used was 10 parts by mass, and as a dispersion, Neoacryl XK-12 (trade name, manufactured by Dainippon Ink & Chemicals, Inc., nonvolatile content: 45.4%), which is an aqueous acrylic resin dispersion. ) was used in the same manner as in Preparation Example 1 to obtain a uniform aqueous dispersion 9. In the cocoons, there seemed to be almost no aggregates. When the aqueous dispersion 9 was measured in the same manner as in Preparation Example 1, the median diameter was 0.193 ⁇ m. Next, the aqueous dispersion 9 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, but almost no sediment was observed.
- Neoacryl XK-12 trade name, manufactured by Dainippon Ink & Chemicals, Inc., nonvolatile content: 45.4%
- Preparation Example 10 A uniform aqueous dispersion 10 was obtained in the same manner as in Preparation Example 1, except that the diamond fine particles B were used in place of the diamond fine particles A, and the treatment time by the homomixer was changed to 10 minutes. . Almost no agglomerates were collected in the cocoons.
- the aqueous dispersion 10 was measured in the same manner as in Preparation Example 1, the median diameter was 1.3 ⁇ m.
- the aqueous dispersion 10 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, sediment was confirmed.
- Neo sticker C-33 (trade name, non-volatile content: 36.5% by mass, manufactured by Nikka Chemical Co., Ltd.), which is a cationic aqueous urethane resin dispersion, was used, and the processing time with a homomixer was 10 minutes.
- a water dispersion 11 was prepared in the same manner as in Preparation Example 1 except that 1.7 g of agglomerates were collected in the basket.
- the aqueous dispersion 11 was measured in the same manner as in Preparation Example 1, the median diameter was 12 ⁇ m.
- the aqueous dispersion 11 was transferred to a 200 ml graduated cylinder and allowed to stand for 3 hours, it was separated into two layers.
- Preparation Example 12 An aqueous solution containing 8% by mass of polyvinyl alcohol was obtained by heating and mixing polyvinyl alcohol (trade name: PVA117, manufactured by Kuraray Co., Ltd.) and distilled water. Uniform water dispersion in the same manner as in Preparation Example 1 except that the amount of diamond fine particles A used was 3 parts by mass and that the aqueous solution containing 8% by mass of the polyvinyl alcohol was used as the dispersion. Body 12 was obtained. In the cocoons, there seemed to be almost no aggregates. When the aqueous dispersion 12 was measured in the same manner as in Preparation Example 1, the median diameter was 0.254 ⁇ m.
- the dispersion stability in Table 1 was defined as A when the dispersion stability was good, B when sediment was observed, and C when separated into two layers.
- Example 1 [Preparation of coating liquid for transmissive screen] 35 parts by mass of the aqueous dispersion 1 obtained in Preparation Example 1 was added to a beaker, and 55 parts by mass of ion-exchanged water was slowly added and diluted while stirring. Furthermore, 10 parts by mass of isopropyl alcohol was added dropwise over 5 minutes using a dropping funnel. After completion of dropping, the mixture was stirred and mixed for 30 minutes and treated with ultrasonic waves for 10 minutes. Through the above operation, a transmissive screen coating solution was prepared. When the obtained coating solution was measured with a Zetasizer Nano ZS (manufactured by Malvern) at a measurement temperature of 25 ° C., the median diameter was 0.158 ⁇ m. The measurement of the coating liquid was performed within 5 minutes after the preparation of the coating liquid.
- a Zetasizer Nano ZS manufactured by Malvern
- a polyester film (trade name: Lumirror U-34, manufactured by Toray Industries, Inc., thickness: 100 ⁇ m) was prepared as a substrate.
- the coating liquid obtained by the above operation was applied to the substrate using a bar coater. Subsequently, it dried for 3 minutes with a 100 degreeC warm air dryer, and obtained the transmissive screen.
- the thickness (film thickness) of the film (transparent thin film layer) in the obtained transmission screen was 5.0 ⁇ m.
- the thickness of the coating was measured by photographing a cross section of the coating on the substrate with a scanning electron microscope (trade name: S-5400, manufactured by Hitachi High-Technologies Corporation).
- Example 2 Except that the aqueous dispersion 2 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the coating solution was measured in the same manner as in Example 1, the median diameter was 0.181 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 4.5 ⁇ m.
- Example 3 Other than adding 2 parts by mass of NK Assist CI (trade name, manufactured by Nikka Chemical Co., Ltd.), a carbodiimide-based aqueous crosslinking agent, at the time of adding ion-exchanged water, and changing the amount of ion-exchanged water to 40 parts by mass
- a transmissive screen coating solution was prepared. When the coating solution was measured in the same manner as in Example 1, the median diameter was 0.187 ⁇ m. Next, a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 5.2 ⁇ m.
- Example 4 Except that the water dispersion 3 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the prepared transmission screen coating solution was measured with a Zetasizer Nano ZS (trade name, manufactured by Malvern) at a measurement temperature of 25 ° C., and the median diameter was 0.061 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 4.8 ⁇ m.
- Example 5 Except that the water dispersion 4 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the coating solution was measured in the same manner as in Example 1, the median diameter was 0.039 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 4.6 ⁇ m.
- Example 6 Except that the aqueous dispersion 5 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the coating solution was measured in the same manner as in Example 1, the median diameter was 0.476 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 5.3 ⁇ m.
- Example 7 Using the aqueous dispersion 6, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution. When the coating solution was measured in the same manner as in Example 1, the median diameter was 0.053 ⁇ m. Next, a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 4.7 ⁇ m.
- Example 8 Except that the water dispersion 7 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the coating solution was measured in the same manner as in Example 1, the median diameter was 0.162 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 5.1 ⁇ m.
- Example 9 Except that the water dispersion 8 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the coating solution was measured in the same manner as in Example 1, the median diameter was 0.066 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 6.7 ⁇ m.
- Example 10 Except that the water dispersion 9 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the coating solution was measured in the same manner as in Example 1, the median diameter was 0.186 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 5.4 ⁇ m.
- Example 11 A polyester film (trade name: Lumirror U-34, manufactured by Toray Industries, Inc., thickness: 100 ⁇ m) as a substrate, and a micro spray gun (trade name: NEO-77 micro spray gun + ST150 cup set, manufactured by Keiko Seisakusho Co., Ltd.) A transmissive screen was produced in the same manner as in Example 1 except that it was used and spray-coated. The thickness of the coating was 5.2 ⁇ m.
- Example 1 Comparative Example 1 Except that the water dispersion 10 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the coating solution was measured in the same manner as in Example 1, the median diameter was 1.20 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used.
- Example 2 Comparative Example 2 Except that the water dispersion 12 was used, the same operation as in Example 1 was performed to prepare a transmissive screen coating solution.
- the coating solution was measured in the same manner as in Example 1, the median diameter was 0.247 ⁇ m.
- a transmissive screen was produced in the same manner as in Example 1 except that the obtained coating liquid was used. The thickness of the coating was 4.9 ⁇ m.
- a having no defects in appearance such as film unevenness, white turbidity, cracks, and the like was designated as A
- B having defects in appearance such as film unevenness, white turbidity, cracks, and the like.
- Adhesive cellophane tape was applied to the coating surface, and the appearance of the coating film was observed when it was peeled off rapidly at an angle of 60 °, and evaluated according to the following criteria. In addition, when it is A, adhesiveness is the best. A: 95% or more of the coating remained on the film side. B: 80% or more of the coating remained on the film side. C: 50% or more and less than 80% of the coating remained on the film side. D: Less than 50% of the film remained on the film side.
- ⁇ Light scattering reflectivity evaluation> [Light scattering] 550 nm light is vertically incident on a transmission screen installed so that the film surface is perpendicular to the light beam from the projector, and the position of the detector is gradually changed from the vertical transmission position.
- the transmittance of light having a wavelength of 550 nm was measured when the inclination of the detector (detection angle, ⁇ in FIG. 2) was 10 °.
- a spectrophotometer ARSN-733 manufactured by JASCO Corporation was used as a measuring device. The larger the transmittance, the better the light scattering property.
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Abstract
Description
本実施形態に係る水分散体は、屈折率が2.0以上の微細粒子と、アニオン性ポリマーとを、含む。
本明細書において微細粒子には、微細粒子の一次粒子及びその凝集体などの二次粒子も包含される。
光散乱膜に含まれる微細粒子の屈折率は、微細粒子以外の膜を構成する材料よりも高い屈折率を有することが好ましい。一般に、アニオン性ポリマーの屈折率は1.5~1.6程度であるので、本実施形態における微細粒子の屈折率は2.0以上であってもよく、2.3以上であることが好ましい。入手容易性の観点から、微細粒子の屈折率は3.0以下であってもよい。本願明細書では、このような屈折率2.0以上の微細粒子を「高屈折率微細粒子」と定義する。なお、微細粒子の屈折率は、実施例に記載の方法で測定される。
本明細書においてアニオン性ポリマーとは、アニオン性の官能基(アニオン性基)を有するポリマーを意味する。アニオン性ポリマーは、高屈折率微細粒子の分散安定性に優れるという観点から、カルボキシ基、カルボキシレート基、スルホ基及びスルホネート基からなる群より選択される少なくとも1種のアニオン性基を有することが好ましい。これらの中でも、カルボキシ基及び/又はカルボキシレート基を有するアニオン性ポリマー、あるいは、スルホ基及び/又はスルホネート基を有するアニオン性ポリマーがより好ましい。アニオン性ポリマーは、1種のアニオン性基を単独で有するものであってよく、2種以上のアニオン性基を有するものであってもよい。
水性ポリウレタン樹脂としては、(I)カルボキシ基及び/又はカルボキシレート基を有するポリウレタン樹脂(以下、「ポリウレタン樹脂A)」という)、(II)スルホ基及び/又はスルホネート基を有するポリウレタン樹脂(以下、「ポリウレタン樹脂B」という)を好適に用いることができる。
ポリウレタン樹脂Aとしては、例えば、上記(a)成分に由来する構造単位、上記(b)成分に由来する構造単位、(c)カルボキシ基と2個以上の活性水素基とを有する化合物(以下、「(c)成分」という)に由来する構造単位、(d)アミノ基及び/又はイミノ基を2個以上有するポリアミン化合物(以下、「(d)成分」)に由来する構造単位を有するポリウレタン樹脂が好適に用いられる。
ポリウレタン樹脂Aは、例えば、(a)成分、(b)成分及び(c)成分を反応させる工程と、(d)成分を用いて鎖伸長反応させる工程と、を備える方法により得ることができる。
ポリウレタン樹脂Bとしては、例えば、(a)成分に由来する構造単位、(b)成分に由来する構造単位、(d)成分に由来する構造単位、及び(e)アミノ基及び/又はイミノ基を2個以上とスルホ基及び/又はスルホネート基とを有するポリアミン化合物(以下、「(e)成分」という)に由来する構造単位、を有するポリウレタン樹脂が好適に用いられる。
ポリウレタン樹脂Bは、例えば、(a)成分、(b)成分及び(e)成分を反応させる工程と、(d)成分を用いて鎖伸長反応させる工程と、を備える方法により得ることができる。
水分散体は水を含む。本発明の効果が損なわれない範囲であれば、水分散体は水以外の溶媒を含んでいてもよい。水以外の溶媒としては、例えば、メタノール、エタノール及びイソプロピルアルコール等のアルコール;アセトン、メチルエチルケトン、酢酸エチル、石油エーテル、n-メチルピロリドン、プロピレングリコールモノメチルエーテルアセテート、エチレングリコールジメチルエーテル、ジエチレングリコールジメチルエーテル、エチレングリコールジエチルエーテル並びにジエチレングリコールジエチルエーテルなどが挙げられる。
水分散体は、水に乳化分散したアニオン性ポリマーに、高屈折率微細粒子を添加し、分散させることで得られる。
本実施形態に係るコーティング液は、高屈折率微細粒子、アニオン性ポリマー、及び水を含む。本実施形態に係るコーティング液は、例えば、上述した水分散体を配合してなるコーティング液であってよい。また、上述した水分散体をそのまま本実施形態に係るコーティング液として用いてもよい。
透過型スクリーン用コーティング液の動的光散乱法によるメジアン径は、コーティング膜(透過型スクリーン用コーティング液から形成される膜)の透明視認性及び光散乱反射性に優れる観点から、0.01~1μmであることが好ましく、0.05~0.7μmであることがより好ましく、0.1~0.3μmであることが更に好ましい。
本実施形態に係る透過型スクリーンは、基板と、基板上に設けられた、本実施形態に係る透過型スクリーン用コーティング液に由来する透明薄膜層とを備える。すなわち、透明薄膜層は、透過型スクリーン用コーティング液を基板上にコーティングしてなる。本実施形態に係る透明薄膜層は光散乱膜として機能することができる。
透過型スクリーン1の製造方法の一態様は、基板11上に、上記透過型スクリーン用コーティング液をコーティングする工程を備える。当該工程により、基板11上に透明薄膜層12が形成される。
[ダイヤモンド微細粒子の作製]
まず、以下の方法により、ダイヤモンドを含む黒色の粉末(以下、「BD」という)を合成した。TNT(トリニトロトルエン)とRDX(シクロトリメチレントリニトロアミン)を60/40の質量比で含む0.65kgの爆発物を3m3の爆発チャンバー内で爆発させた。これにより、BDを保存するための雰囲気を形成した。その後、同様の条件で2回目の爆発を起こしBDを合成した。爆発生成物が膨張し熱平衡に達した後、15mmの断面を有する超音速ラバルノズルを通して、35秒間ガス混合物をチャンバーより流出させ、サイクロンでBDを捕獲した。チャンバー壁との熱交換及びガスにより行われた仕事(断熱膨張及び気化)のため、生成物の冷却速度は280℃/分であった。BDの比重は2.55g/cm3、メジアン径(動的光散乱法)は220nmであった。BDの比重から、BDは、76容積%のグラファイト系炭素と24容積%のダイヤモンドからなっていると算出された。
(1)ダイヤモンド微細粒子A:メジアン径0.41μm(動的光散乱法)、屈折率2.4
(2)ダイヤモンド微細粒子B:メジアン径2.5μm(動的光散乱法)、屈折率2.4
[水分散体の調製]
200mlステンレスポットに、分散液として、カーボネート系水性ウレタン樹脂分散液であるエバファノールHA-170(日華化学株式会社製商品名 不揮発分36.5質量%)100質量部を加えた。ここに、ダイヤモンド微細粒子A5質量部を加え、ホモミキサー(商品名:T.K HOMODisper(Model 2.5)、PRIMIX社製)を用いて、5000rpmで15分間処理を行った。その後、#2000紗にてろ過を行い、均一な水分散体1を得た。紗には、凝集物と思われるものはほとんど見られなかった。得られた水分散体1をゼータサイザーナノZS(マルバーン社製商品名)にて、25℃の測定温度で測定したところ、メジアン径は0.164μmであった。なお、メジアン径の測定は、水分散体1の調製後、5分以内に行った。
得られた水分散体1を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
分散液として、カーボネート系水性ウレタン樹脂分散液であるエバファノールHA-15(日華化学株式会社商品名 不揮発分30.4質量%)を用いたこと以外は、調製例1と同様にして、均一な水分散体2を得た。紗には、凝集物と思われるものはほとんど見られなかった。調製例1と同様にして水分散体2を測定したところ、メジアン径は0.178μmであった。次に、水分散体2を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
ダイヤモンド微細粒子Aをビーズミルにより微細粒子化分散処理した。ビーズミルによる分散は、アイメックス株式会社製のイージーナノRMB(商品名)を用いて行った。具体的には、0.1mm径のジルコニアビーズ50mlを充填した0.2Lのベッセルに、エステル系水性アクリルウレタン樹脂分散液であるネオステッカー1200(日華化学株式会社製商品名 不揮発分36.7質量%)100質量部を加えた。次いで、5m/sの周速で回転子を回転させながら、ダイヤモンド微細粒子Aを2質量部加え1時間処理を行った。その後、#2000紗にてろ過を行い、均一な水分散体3を得た。紗には、凝集物と思われるものは、ほとんど見られなかった。調製例1と同様にして水分散体3を測定したところ、メジアン径は0.058μmであった。次に、水分散体3を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
分散液として、カーボネート系水性ウレタン樹脂分散液であるエバファノールHA-170(日華化学株式会社製商品名 不揮発分36.5質量%)を用いたこと以外は、調製例3と同様にして、均一な水分散体4を得た。紗には、凝集物が見られなかった。調製例1と同様にして水分散体4を測定したところ、メジアン径は0.041μmであった。次に水分散体4を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
ダイヤモンド微細粒子Aに代えてダイヤモンド微細粒子Bを用いたこと以外は、調製例1と同様にして、均一な水分散体5を得た。紗には、凝集物と思われるものはほとんど見られなかった。調製例1と同様にして水分散体5を測定したところ、メジアン径は0.563μmであった。次に、水分散体5を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
ダイヤモンド微細粒子Aに代えて市販の酸化ジルコニウム(ZrO2)微細粒子(関東電化工業株式会社製、メジアン径:12nm、屈折率:2.4)3質量部を用いたこと以外は、調製例1と同様にして、均一な水分散体6を得た。紗には、凝集物と思われるものはほとんど見られなかった。調製例1と同様にして水分散体6を測定したところ、メジアン径は0.037μmであった。次に、水分散体6を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
ダイヤモンド微細粒子Aを10質量部用いたこと、及び、分散液として、水性アクリル-ウレタン複合樹脂分散液であるボンコートHY364(大日本インキ化学工業株式会社製商品名 不揮発分45.2質量%)を用いたこと以外は、調製例1と同様にして、均一な水分散体7を得た。紗には、凝集物と思われるものはほとんど見られなかった。調製例1と同様にして水分散体7を測定したところ、メジアン径は0.172μmであった。次に、水分散体7を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
ダイヤモンド微細粒子Aに代えて市販のチタン酸バリウム(BaTiO3)微細粒子(関東電化工業株式会社製、メジアン径:25nm、屈折率2.4)3質量部を用いたこと以外は、調製例1と同様にして、均一な水分散体8を得た。紗には、凝集物と見られるものはほとんど見られなかった。調製例1と同様にして水分散体8を測定したところ、メジアン径は0.054μmであった。次に、水分散体8を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
ダイヤモンド微細粒子Aの使用量を10質量部としたこと、及び、分散液として、水性アクリル樹脂分散液であるネオクリルXK-12(大日本インキ化学工業株式会社製商品名、不揮発分45.4%)を用いたこと以外は、調製例1と同様にして、均一な水分散体9を得た。紗には、凝集物と思われるものはほとんど見られなかった。調製例1と同様にして水分散体9を測定したところ、メジアン径は0.193μmであった。次に、水分散体9を200mlのメスシリンダーに移し、3時間静置したが、沈降物はほとんど見られなかった。
ダイヤモンド微細粒子Aに代えてダイヤモンド微細粒子Bを用いたこと、及び、ホモミキサーによる処理時間を10分間に変更したこと以外は、調製例1と同様にして、均一な水分散体10を得た。紗には、凝集物がほとんど回収されなかった。調製例1と同様にして水分散体10を測定したところ、メジアン径は1.3μmであった。次に、水分散体10を200mlのメスシリンダーに移し、3時間静置したところ、沈降物が確認された。
分散液として、カチオン系水性ウレタン樹脂分散液であるネオステッカーC-33(日華化学株式会社製商品名 不揮発分36.5質量%)を用いたこと、及び、ホモミキサーによる処理時間を10分間に変更したこと以外は、調製例1と同様にして、水分散体11を調製した。紗には、凝集物が1.7g回収された。調製例1と同様にして水分散体11を測定したところ、メジアン径は12μmであった。次に、水分散体11を200mlのメスシリンダーに移し、3時間静置したところ、二層に分離した。
ポリビニルアルコール(商品名:PVA117、クラレ株式会社製)と蒸留水を加熱混合することにより、ポリビニルアルコールを8質量%含有する水溶液を得た。ダイヤモンド微細粒子Aの使用量を3質量部としたこと、及び、分散液として、上記ポリビニルアルコールを8質量%含有する水溶液を用いたこと以外は、調製例1と同様にして、均一な水分散体12を得た。紗には、凝集物と思われるものはほとんど見られなかった。調製例1と同様にして水分散体12を測定したところ、メジアン径は0.254μmであった。
[透過型スクリーン用コーティング液の調製]
ビーカーに調製例1で得られた水分散体1を35質量部加え、攪拌しながらイオン交換水55質量部をゆっくりと加えて希釈した。さらに、滴下ロートを使用してイソプロピルアルコール10質量部を5分かけて滴下した。滴下終了後、続けて30分攪拌混合し、超音波で10分間処理した。上記操作により、透過型スクリーン用コーティング液を調製した。得られたコーティング液をゼータサイザーナノZS(マルバーン社製)にて、25℃の測定温度で測定したところ、メジアン径は0.158μmであった。なお、コーティング液の測定は、コーティング液の調製後、5分以内に行った。
基板として、ポリエステルフィルム(商品名:ルミラーU-34、東レ株式会社製、厚み:100μm)を用意した。バーコーターを用いて、上記操作により得られたコーティング液を当該基板に塗布した。次いで、100℃の温風乾燥機で3分間乾燥し、透過型スクリーンを得た。得られた透過型スクリーンにおける被膜(透明薄膜層)の厚み(膜厚)は、5.0μmであった。なお、本実施例において、被膜の厚みは、基板上の被膜の断面を走査型電子顕微鏡(商品名:S-5400、株式会社日立ハイテクノロジーズ製)で撮影して測定した。
水分散体2を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を調製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は0.181μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、4.5μmであった。
イオン交換水の添加時にカルボジイミド系水系架橋剤のNKアシストCI(日華化学株式会社製商品名)2質量部を加えたこと、及び、イオン交換水の使用量を40質量部に変更したこと以外は、実施例1と同様にして、透過型スクリーン用コーティング液を作製した。実施例1と同様にして、コーティング液を測定したところメジアン径は0.187μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、5.2μmであった。
水分散体3を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。作製した透過型スクリーン用コーティング液をゼータサイザーナノZS(マルバーン社製商品名)にて、25℃の測定温度で測定したところメジアン径0.061μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、4.8μmであった。
水分散体4を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は0.039μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、4.6μmであった。
水分散体5を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は0.476μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、5.3μmであった。
水分散体6を用いて、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は0.053μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、4.7μmであった。
水分散体7を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は0.162μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、5.1μmであった。
水分散体8を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は0.066μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、6.7μmであった。
水分散体9を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は0.186μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、5.4μmであった。
基板としてのポリエステルフィルム(商品名:ルミラーU-34、東レ株式会社製、厚み:100μm)に、マイクロスプレーガン(商品名:NEO-77マイクロスプレーガン+ST150カップセット、株式会社恵宏製作所製)を用いてスプレー塗布したこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは5.2μmであった。
水分散体10を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は1.20μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。
水分散体12を用いたこと以外は、実施例1と同様な操作を行い、透過型スクリーン用コーティング液を作製した。実施例1と同様にしてコーティング液を測定したところ、メジアン径は0.247μmであった。次いで、得られたコーティング液を用いたこと以外は、実施例1と同様にして、透過型スクリーンを作製した。被膜の厚みは、4.9μmであった。
本実施例1~10及び比較例1~2で得られた透過型スクリーンの品質を、以下に示す方法により評価した。結果を表2に示す。
目視にて被膜表面を観察し、膜むら、白濁、クラックなどの外観上の不具合が無いものをA、膜むら、白濁、クラックなどの外観上の不具合が有るものをBとした。
[密着性]
被膜面に粘着セロハンテープをはりつけ、角度60°で急速に剥がしたときの被膜の外観を観測し、以下の基準で評価した。なお、Aである場合に密着性が最も良好である。
A:被膜の95%以上がフィルム側に残った。
B:被膜の80%以上がフィルム側に残った。
C:被膜の50%以上80%未満がフィルム側に残った。
D:被膜の50%未満しかフィルム側に残らなかった。
作製した透過型スクリーンを20℃のイオン交換水に1週間浸漬した後、透明薄膜層の外観を観測し、以下の基準で透明性を評価した。なお、Aである場合に耐水性が最も良好である。
A:白化が全く見られない
B:白化がごくわずか見られる
C:わずかに白化
D:白化
[曇価(ヘーズ)及び全透過率]
JIS-R3212(2015年版)の規格に準拠して、ヘーズメーター(日本電色工業製、NDH2000)を用いて透過型スクリーンの曇価(ヘーズ)及び全透過率を測定した。
プロジェクタからの光線に対して膜面が垂直になるように設置した透過型スクリーンに、プロジェクタを用いて映像を投影した。プロジェクタと反対側からプロジェクタ側(プロジェクタ方向)の背景を観察し、以下の基準で透過性を評価した。なお、1である場合に透過性が最も良好である。
1:プロジェクタ方向の背景がきわめてくっきり見える。
2:プロジェクタ方向の背景がくっきりと見える。
3:プロジェクタ方向の背景がやや白っぽくなるが十分見える。
4:プロジェクタ方向の背景が白っぽくなるがわずかに見える。
5:プロジェクタ方向の背景が白っぽくなりほぼ見えない。
6:プロジェクタ方向の背景が全く見えない。
[光散乱性]
プロジェクタからの光線に対して膜面が垂直になるように設置した透過型スクリーンに、550nmの光を垂直入射し、検出器の位置を垂直透過位置から徐々に変化させていき、垂直入射面に対する検出器の傾き(検出角度、図2中のβ)が10°のときの波長550nmの光(前方散乱光Sf)の透過率を測定した。測定装置には、日本分光社の分光光度計ARSN-733を用いた。透過率が大きいほど、光散乱性が良好であると評価される。
プロジェクタからの光線に対して膜面が垂直になるように設置した透過型スクリーンに、プロジェクタを用いて映像を投影した。プロジェクタ側及びプロジェクタと反対側それぞれにおいて、プロジェクタからの光線に対して水平方向から、投影された映像の様子を目視し、以下の基準で映像の鮮鋭性を評価した。なお、評価が1である場合、映像の鮮鋭性が最も良好であることを意味する。
1:投射された映像の発色が極めて鮮やかで、輪郭が極めてはっきりと見える。
2:投射された映像の発色が鮮やかで、輪郭がはっきりと見える。
3:投影された映像の発色がよく、輪郭が十分見える。
4:投射された映像が全体的に白っぽく、輪郭が薄い。
5:投射された映像の色合いがほとんど区別できず、輪郭がほとんど認識できない。
6:投射された映像が見えない。
プロジェクタからの光線に対して膜面が垂直になるように設置した透過型スクリーンに、プロジェクタを用いて映像を投影した。プロジェクタ側及びプロジェクタの反対側それぞれにおいて、プロジェクタからの光線に対して斜め80°の方向(図2中、α及びβが80°となる方向)から、投影された映像の様子を目視し、以下の基準で視野角(80°)視認性を評価した。なお、評価が1である場合、視野角(80°)視認性が最も良好であることを意味する。
1:斜め80°方向からでも投射された映像の発色が鮮やかで、輪郭がはっきりと見える。
2:斜め80°方向からでも投射された映像の発色がよく、輪郭が十分見える。
3:斜め80°方向から映像が見えない。
10・・・微細粒子
11、11a、11b・・・基板
12・・・透明薄膜層
I・・・入射光
Sf・・・前方散乱光
Sb・・・後方散乱光
Claims (13)
- 屈折率が2.0以上の微細粒子と、アニオン性ポリマーとを、含み、
動的光散乱法によるメジアン径が、0.01~1.0μmである、水分散体。 - 前記微細粒子が、ダイヤモンド、ダイヤモンド誘導体、チタン酸バリウム、酸化ジルコニウム及び酸化チタニウムからなる群より選択される少なくとも一種の成分を含む、請求項1に記載の水分散体。
- 前記アニオン性ポリマーが、カルボキシ基、カルボキシレート基、スルホ基及びスルホネート基からなる群より選択される少なくとも1種のアニオン性基を有する、請求項1又は2に記載の水分散体。
- 前記アニオン性ポリマーが、水溶性又は水分散性である、ポリウレタン樹脂、アクリル樹脂及びアクリルウレタン樹脂からなる群より選択される少なくとも一種の樹脂を含む、請求項1~3のいずれか一項に記載の水分散体。
- 前記ポリウレタン樹脂及び前記アクリルウレタン樹脂が、ポリエステルポリオール及びポリカーボネートポリオールからなる群より選択される少なくとも一種のポリオール成分に由来する構造単位を有する、請求項4に記載の水分散体。
- 屈折率が2.0以上の微細粒子と、アニオン性ポリマーとを、含み、
動的光散乱法によるメジアン径が、0.01~1.0μmである、コーティング液。 - 前記微細粒子が、ダイヤモンド、ダイヤモンド誘導体、チタン酸バリウム、酸化ジルコニウム及び酸化チタニウムからなる群より選択される少なくとも一種の成分を含む、請求項6に記載のコーティング液。
- 前記アニオン性ポリマーが、カルボキシ基、カルボキシレート基、スルホ基及びスルホネート基からなる群より選択される少なくとも1種のアニオン性基を有する、請求項6又は7に記載のコーティング液。
- 前記アニオン性ポリマーが、水溶性又は水分散性である、ポリウレタン樹脂、アクリル樹脂及びアクリルウレタン樹脂からなる群より選択される少なくとも一種の樹脂を含む、請求項6~8のいずれか一項に記載のコーティング液。
- 前記ポリウレタン樹脂及び前記アクリルウレタン樹脂が、ポリエステルポリオール及びポリカーボネートポリオールからなる群より選択される少なくとも一種のポリオール成分に由来する構造単位を有する、請求項9に記載のコーティング液。
- 前記コーティング液が、透過型スクリーン用である、請求項6~10のいずれか一項に記載のコーティング液。
- 基板上に、請求項6~10のいずれか一項に記載のコーティング液をコーティングする工程を備える、透過型スクリーンの製造方法。
- 前記透過型スクリーンがヘッドアップディスプレー用である、請求項12に記載の透過型スクリーンの製造方法。
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