WO2017073513A1 - バラスト水処理装置及びバラスト水処理方法 - Google Patents
バラスト水処理装置及びバラスト水処理方法 Download PDFInfo
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- WO2017073513A1 WO2017073513A1 PCT/JP2016/081436 JP2016081436W WO2017073513A1 WO 2017073513 A1 WO2017073513 A1 WO 2017073513A1 JP 2016081436 W JP2016081436 W JP 2016081436W WO 2017073513 A1 WO2017073513 A1 WO 2017073513A1
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- ballast
- ballast water
- pipe
- water treatment
- sterilizing agent
- Prior art date
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63J—AUXILIARIES ON VESSELS
- B63J4/00—Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for
- B63J4/002—Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for for treating ballast water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/22—Control or regulation
- B01F35/2201—Control or regulation characterised by the type of control technique used
- B01F35/2202—Controlling the mixing process by feed-back, i.e. a measured parameter of the mixture is measured, compared with the set-value and the feed values are corrected
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B13/00—Conduits for emptying or ballasting; Self-bailing equipment; Scuppers
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/008—Control or steering systems not provided for elsewhere in subclass C02F
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/685—Devices for dosing the additives
- C02F1/687—Devices for dosing solid compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F21/00—Dissolving
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
- C02F1/004—Processes for the treatment of water whereby the filtration technique is of importance using large scale industrial sized filters
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/008—Originating from marine vessels, ships and boats, e.g. bilge water or ballast water
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/29—Chlorine compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/40—Liquid flow rate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Definitions
- the present invention relates to a ballast water treatment apparatus and a ballast water treatment method.
- ballast water in order to stabilize a ship such as a cargo ship in a state where no cargo is mounted, a countermeasure for filling seawater with ballast water in a ballast tank arranged in the ship is known.
- ⁇ As a method for sterilizing ballast water, there are a method of introducing chemicals and a method of irradiating with ultraviolet rays.
- Patent Document 1 a bypass pipe is connected in the middle of a main pipe connected to a ballast tank, and a disinfectant supply device that holds a disinfectant in the bypass pipe Has been placed.
- a part of the raw water flowing through the main pipe flows to the bypass pipe side.
- the disinfectant solution is obtained by dissolving the disinfectant previously arrange
- Ballast water is sterilized by joining this bactericide solution to the raw water flowing through the main pipe.
- the sterilizing component is supplied to the ballast water by allowing the ballast water taken into the ship to pass through a sterilizing agent supply apparatus in which a sterilizing agent has been introduced in advance. Then, the ballast water containing the sterilizing component is poured into the ballast tank.
- the temperature and quality of the seawater taken into the ship vary depending on the place where it is taken in and the time when it is taken in. Therefore, an appropriate amount of the bactericidal agent calculated in advance is input to the disinfectant supply device disclosed in Patent Document 1. It ’s difficult. For example, the amount of fungicide input is too much and the disinfectant remains undissolved, the disinfectant is dissolved too much and the disinfectant component becomes extremely high, or the amount of disinfectant input is too small and the bactericidal action in the ballast water is The problem of being insufficient is likely to occur.
- the disinfectant supply device disclosed in Patent Document 1 is configured so that the disinfectant supply device is removed from the bypass pipe when the disinfectant remains in the disinfectant supply device when the flooding to the ballast tank is completed. It cannot be taken out, and the disinfectant continues to be exposed to seawater (ballast water) in the bypass pipe. For this reason, even if the intake of seawater is stopped after the completion of flooding, the sterilizing component continues to be dissolved from the disinfectant in the seawater (ballast water) in the bypass pipe. As a result, the concentration of the sterilizing component in the bypass pipe becomes higher than expected, and there is a concern about an adverse effect on the sterilizing agent supply device and the bypass pipe.
- the disinfectant left undissolved in this way is a chlorine-based disinfectant
- a part of the disinfectant may be decomposed to lower the effective chlorine concentration, or toxic chlorine gas may be generated.
- the sterilizing component is a chlorine component
- the chlorine component may cause corrosion in the water treatment apparatus.
- An object of the present invention is to provide a ballast water treatment apparatus that easily adjusts the concentration of sterilizing components in ballast water within a desired range.
- a ballast water treatment apparatus supplies a ballast pipe that supplies ballast water to a ballast tank, and supplies a certain amount of bactericidal agent per unit time to the ballast pipe according to the flow rate of the ballast water that flows through the ballast pipe.
- a ballast water treatment method using this ballast water treatment apparatus includes a step of supplying ballast water from a ballast pipe to a ballast tank, and a constant amount of sterilization per unit time in the ballast pipe according to the flow rate of the ballast water flowing through the ballast pipe. Supplying an agent.
- ballast water treatment device that can easily adjust the concentration of the sterilizing component of ballast water within a desired range.
- FIG. 3 is a schematic cross-sectional view showing the bactericide supply means of the first embodiment. It is the schematic which shows the structure of the ballast water treatment apparatus which changed the attachment position of the density
- FIG. It is a typical perspective view which shows the modification of the disinfectant supply means of Embodiment 1.
- FIG. 5 is a cross-sectional view of FIG. 4. It is the schematic which shows the structure of the ballast water treatment apparatus of the comparative example 1.
- Embodiment 1 (Embodiment 1) [Ballast water treatment equipment] A configuration of a ballast water treatment apparatus 1 according to Embodiment 1 which is an embodiment of the present invention will be described with reference to FIG.
- the ballast water treatment device 1 is a device that is disposed on the ship, sterilizes the ballast water pumped into the ship, and leads to the ballast tank 60 disposed on the ship.
- the ballast water treatment apparatus 1 includes a ballast pipe 11, a ballast pump 10, a filtration apparatus 20 (filter), a sterilizing agent supply means 30, a supply pipe 36, a flow rate measurement unit 41, a concentration measurement unit 42, and a mixer. 50 and the control part 70 are mainly provided.
- the ballast pipe 11 is connected to the ballast tank 60 and constitutes a supply channel for guiding the seawater pumped into the ship to the ballast tank 60.
- the ballast pipe 11 has one pipe port through which seawater flows and the other pipe port connected to the ballast tank 60.
- the raw water (generally “seawater”) that becomes the ballast water flows into the ballast pipe 11 from one pipe port and flows into the ballast pipe 11 toward the other pipe port, thereby leading to the ballast tank 60. It is burned.
- This raw water (seawater) is stored as ballast water for stabilizing the hull in the ballast tank 60.
- ballast water the raw water (seawater) after being taken into the ballast pipe 11 may be referred to as “ballast water”.
- the ballast pump 10 is arranged on one side of the ballast pipe 11 and supplies the ballast water that has flowed into the ballast pipe 11 to the ballast tank 60.
- the filtration device 20 is disposed in the ballast pipe 11 on the downstream side (the ballast tank 60 side) in the ballast water flow direction with respect to the ballast pump 10.
- the filtration device 20 removes foreign matters, microorganisms, and the like contained in seawater by filtration.
- the filtering device 20 is preferably arranged on the upstream side of the disinfectant supply means 30. This is because the seawater (ballast water) after passing through the filtering device 20 has low turbidity and improved water quality, so that the disinfectant can be dissolved stably.
- the filtration device 20 may be arranged on the upstream side with respect to the ballast pump 10.
- the flow rate measuring unit 41 is disposed downstream of the filtration device 20 in the ballast pipe 11 and is a part that measures the flow rate of ballast water (seawater) flowing through the ballast pipe 11.
- the flow rate measuring unit 41 is not limited to the form disposed on the downstream side of the filtration device 20, and may be disposed on the upstream side of the filtration device 20, or may be disposed on the downstream side of the mixer 50. Information on the flow rate measured by the flow rate measurement unit 41 is transmitted to the control unit 70 described later.
- the sterilizing agent supply means 30 is provided at a position away from the ballast pipe 11, and is connected to the ballast pipe 11 on the downstream side of the filtration device 20 via the supply pipe 36. As shown in FIG. 2, the sterilizing agent supply means 30 includes a plurality of containers 31 partitioned by a partition in a top view lattice shape, and is configured so that an appropriate amount of the sterilizing agent can be put into the ballast pipe 11 from the containers.
- the container 31 here corresponds to the “accommodating portion” in the claims.
- each container 31 The internal volume of each container 31 is substantially the same, and a bottom plate 34 is attached to the lower side of each container 31 so as to be openable and closable.
- a certain amount of the sterilizing agent 33 suitable for one supply can be held.
- a certain amount of the sterilizing agent 33 in the container 31 falls by opening the bottom plate 34.
- the sterilizing agent 33 dropped from the container 31 is supplied to the ballast pipe 11 through the supply pipe 36 so as to be sucked into the flow of ballast water. That is, when the sterilizer 33 is housed in the container 31, it is not exposed to the ballast water, but is first introduced into the ballast water by opening the bottom plate 34.
- Opening and closing of the bottom plate 34 of each container 31 is controlled to open at predetermined time intervals by a control unit 70 described later. With this control, a certain amount of bactericidal agent per unit time can be supplied to the ballast pipe 11 via the supply pipe 36 according to the flow rate of the ballast water flowing through the ballast pipe 11.
- supplying a certain amount of bactericidal agent per unit time means that a certain weight of bactericidal agent is supplied from the bactericide supplying means 30 to the ballast pipe 11 per unit time during water treatment.
- the supply form is not particularly limited.
- 30 g of sterilizing agent may be supplied from the sterilizing agent supply means 30 to the ballast pipe 11 every 5 minutes, or 0.1 g of sterilizing agent may be continuously supplied from the sterilizing agent supply means 30 to the ballast pipe 11 every second. May be supplied.
- the unit time in the above-mentioned “sterilizer having a constant weight per unit time” depends on the volume of the ballast tank, the flow rate of the ballast water flowing through the ballast pipe 11, the concentration of the required sterilizing component, the effective chlorine concentration of the sterilizing agent, etc. Set accordingly. For example, when the unit time is set to 1 minute, it means that the weight of the disinfectant supplied to the ballast pipe 11 every 1 minute is constant. The shorter the unit time, the more uniform the bactericidal agent can be supplied to the ballast pipe 11, and the concentration of the bactericidal component in the ballast water can be stabilized.
- the ballast pipe 11 it is preferable to continuously supply 0.1 g of the bactericidal agent to the ballast pipe 11 every second, rather than collectively supplying 6 g of the bactericidal agent to the ballast pipe 11 every minute.
- the unit time is preferably 10 minutes or less, more preferably 5 minutes or less, still more preferably 3 minutes or less, and particularly preferably 1 minute or less.
- the supply pipe 36 is a pipe that connects the ballast pipe 11 downstream of the filtering device 20 and the bactericide supply means 30 and supplies the bactericide 33 in the bactericide supply means 30 to the ballast pipe 11.
- the sterilizing agent is supplied from the sterilizing agent supply means 30 to the ballast pipe 11 via the supply pipe 36, but the supply pipe 36 is not essential.
- the supply means 30 may be connected.
- the connecting portion of the sterilizing agent supply means 30 with the ballast pipe 11 that is, the tip portion of the sterilizing agent supply means 30
- the shape is preferably smaller than the inner diameter of the ballast pipe 11.
- the inner diameter of the distal end portion of the sterilizing agent supply means 30 is preferably not more than one fifth of the inner diameter of the ballast pipe 11 and more preferably not more than one tenth.
- the sterilizing agent supplying means supplies the sterilizing agent to the ballast pipe means a form in which the sterilizing agent is supplied to the ballast pipe 11 from the sterilizing agent supplying means 30 configured separately from the ballast pipe 11.
- positions a disinfectant supply means in the ballast piping 11 is not included. That is, the sterilizing agent supply means 30 supplies the sterilizing agent 33 held in a dry state to the ballast pipe 11 at appropriate intervals at the time of flooding in the ballast tank.
- the sterilizing component is supplied to the ballast tank by holding the sterilizing component in the ballast pipe 11 and dissolving the sterilizing component in the ballast water along with the flooding.
- the inner diameter of the ballast pipe 11 is sufficiently larger than the inner diameter of the supply pipe 36.
- the inner diameter of the supply pipe 36 is preferably 1/5 or less, more preferably, the inner diameter of the ballast pipe 11. 1/10 or less. Thereby, it can suppress that the ballast water which flows through the ballast piping 11 flows in into the disinfectant supply means 30 through the supply piping 36.
- the bactericidal agent 33 is not particularly limited as long as it acts on marine microorganisms, marine bacteria, and the like.
- a compound that generates hypochlorous acid or the like can be used.
- the compound that generates hypochlorous acid include calcium hypochlorite, chlorinated isocyanurate, and the like.
- chlorinated isocyanurate dichloroisocyanurate and / or trichloroisocyanuric acid is preferably used.
- a chlorinated isocyanurate is a compound having a structure in which a hydrogen atom bonded to a nitrogen atom of isocyanuric acid is substituted by a chlorine atom, and trichloroisocyanuric acid in which a hydrogen atom is substituted by three chlorine atoms (the following structural formula) (1)) and dichloroisocyanurate in which a hydrogen atom is substituted by two chlorine atoms (in the following structural formula (2), typical sodium dichloroisocyanurate is exemplified).
- These isocyanuric acid chlorides generate hypochlorous acid (HOCl) having bactericidal properties by dissolving in water.
- dichloroisocyanuric acid salt such as trichloroisocyanuric acid represented by the structural formula (1) or sodium dichloroisocyanuric acid represented by the structural formula (2).
- a sterilizing agent 33 can generate hypochlorous acid (HOCl) having sterilizing properties by dissolving in water, and sterilizing the ballast water in the ballast tank 60 with this hypochlorous acid.
- HOCl hypochlorous acid
- trichloroisocyanuric acid has low solubility in water, it is not easy to prepare a high-concentration solution.
- the active ingredient can be supplied little by little over a long period of time, and the effective chlorine concentration is 90%.
- trichloroisocyanuric acid and dichloroisocyanurate have high temperature stability, they are not easily deteriorated when stored at a high temperature of about 40 ° C., and can be used safely.
- trichloroisocyanuric acid and dichloroisocyanurate have an advantage that precipitates are hardly generated when dissolved in water.
- dichloroisocyanurate has an advantage that the solubility in water is high and ballast water containing the bactericide 33 can be prepared in a short time.
- trichloroisocyanuric acid When trichloroisocyanuric acid is used as the bactericide 33, it may be used as it is, or a disintegration aid may be added as necessary.
- a disintegration aid By adding a disintegration aid to the disinfectant 33, the disintegration aid is first dissolved in water and the shape of the disinfectant 33 is easily broken. In this way, the disinfectant 33 is easily dissolved in water by the disintegration of the disinfectant 33 in water.
- a well-known thing can be used suitably as a disintegration adjuvant, For example, carboxymethylcellulose salt etc. are mentioned.
- the disintegration aid is preferably contained in a mass proportion of 0.1 to 10% of the entire bactericidal agent 33.
- the total input amount of the sterilizing agent 33 is calculated based on the amount of ballast water submerged in the ballast tank 60 and the concentration of the sterilizing component.
- the amount of ballast water to be poured into the ballast tank 60 is 1000 tons
- the chlorine concentration set value is 10 mg / L
- the concentration of the bactericide 33 necessary to make the chlorine concentration 10 mg / L is 12 mg / L.
- the input amount of the bactericide 33 is calculated as 12 kg by the following formula.
- the sterilizing agent 33 calculated above is supplied to the ballast pipe 11 in one or more times according to the capacity of the container 31.
- the sterilizing agent supply means 30 includes 20 containers 31 and each container 31 has an internal volume capable of holding 100 g of sterilizing agent, if all the containers 31 are filled with the sterilizing agent, one filling operation is performed.
- the configuration in which the disinfectant supply means 30 opens the bottom plate 34 of the container 31 one by one every two minutes has been described, but a supply amount adjustment mechanism that adjusts the inner diameter and the inclination angle of the supply pipe 36 is provided. Is preferred.
- a supply amount adjustment mechanism that adjusts the inner diameter and the inclination angle of the supply pipe 36 is provided.
- all the bactericides 33 in the container 31 can be gradually supplied to the ballast pipe 11 when the bottom plate 34 is opened.
- the supply speed can be adjusted.
- the sterilizing agent 33 dropped from the container 31 can be supplied to the ballast pipe 11 at a constant speed.
- the ratio of the bactericide 33 to the amount of ballast water can be reduced. There is also a merit that it is difficult to cause unmelted residue.
- the form of the bactericidal agent 33 is not particularly limited, and may be any form of granules, powders, tablets, and / or pellets.
- a granular shape of 10 mm is preferred.
- a granular sterilizing agent with a diameter of 0.1 mm or more it is easy to handle because it is difficult to generate dust, and by using a sterilizing agent with a particle size of 10 mm or less, the dead volume at the time of measurement is reduced. While being able to reduce, it can suppress that a melt
- the mixer 50 is arranged on the downstream side of the connection portion with the supply pipe 36 in the ballast pipe 11. By stirring the ballast water after supplying the bactericide using the mixer 50, the bactericide can be easily dissolved in the ballast water, and the concentration of the bactericidal component in the ballast water can be made uniform.
- the concentration measuring unit 42 is a concentration measuring instrument that is attached to the ballast tank 60 as shown in FIG. 1 and measures the concentration of the sterilizing component of the ballast water in the ballast tank 60.
- concentration of the sterilizing component is correlated with the chlorine concentration.
- This chlorine concentration (mg / L) is measured as the total residual oxide (TRO: Total Residual Oxidant) concentration of ballast water.
- the TRO concentration can be measured by a measuring instrument using a DPD reagent.
- the concentration measuring unit 42 measures the concentration of the sterilizing component of the ballast water in the ballast tank 60.
- the concentration of the sterilizing component of the ballast water in the ballast tank 60 can be managed by feeding back the measurement result to the control unit 70 described later.
- the sterilizing component supply means 30 can supply an appropriate amount of the sterilizing component from the sterilizing agent supply means 30 to the ballast pipe 11.
- concentration of the disinfection component of the ballast water in the ballast tank 60 can be raised moderately.
- the concentration measuring unit 42 only needs to be able to detect the concentration of the sterilizing component stored in the ballast tank 60, and other types of sensors can be used in the same manner.
- the control unit 70 is connected to the sterilizing agent supply means 30, the flow rate measurement unit 41, and the concentration measurement unit 42, and is configured by a personal computer including a calculation unit, a storage unit, and the like.
- the control unit 70 acquires information on the flow rate of the ballast water measured by the flow rate measurement unit 41 and also acquires information on the concentration of the ballast water measured by the concentration measurement unit 42.
- the control unit 70 calculates a time interval for opening the bottom plate 34 of each container 31 based on these pieces of information.
- the control unit 70 sequentially opens the bottom plate 34 of each container 31 of the sterilizing agent supply means 30 based on the calculated time interval.
- the bactericide can be supplied to the ballast pipe 11 at an accurate timing. .
- concentration of the bactericidal component in ballast water can be adjusted to a desired range.
- ballast water treatment method Next, the ballast water treatment method according to the present embodiment that is performed using the ballast water treatment apparatus 1 will be described.
- ballast pump 10 seawater is pumped into the ballast pipe 11 as ballast water.
- the pumped ballast water is filtered by the filtering device 20 to remove foreign matters and the like.
- the flow rate measuring unit 41 measures the flow rate of the ballast water. Information measured by the flow rate measuring unit 41 is sent to the control unit 70.
- the control unit 70 uses the calculation unit of the control unit 70 to set each container of the bactericide supply means 30 The time interval for opening the 31 bottom plates 34 is calculated.
- the flow rate of ballast water is 300 m 3 / hour (5000 L / min)
- the weight of the disinfectant held in each container 31 is 100 g
- the effective chlorine concentration of the disinfectant is 50%
- the ballast tank When the effective chlorine concentration of the ballast water in 60 is set to 10 mg-TRO / L, the calculation unit in the control unit 70 calculates to supply 100 g of bactericidal agent to the ballast pipe 11 every minute according to the following formula. .
- control part 70 sets up an automatic program so that the bottom plate 34 of the container 31 of the disinfectant supply means 30 may be sequentially opened one by one at the time interval calculated by the calculation part as the ballast water starts to be taken in. And according to this automatic program, control part 70 opens bottom board 34 of each container 31 one by one. In this way, a certain amount of bactericidal agent is supplied to the ballast pipe 11 per unit time. Then, the bactericidal agent flows into the mixer 50 together with the ballast water flowing through the ballast pipe 11. In this mixer 50, the ballast water and the disinfectant are agitated. Thereby, the ballast water in which the concentration of the sterilizing component is made uniform can be poured into the ballast tank 60.
- the concentration of the sterilizing component is periodically measured by the concentration measuring unit 42 in the ballast water flooded in the ballast tank 60, and the measurement result is sent to the control unit 70.
- the control unit 70 determines whether the concentration measured by the concentration measuring unit 42 is within the reference range. This reference range is preset according to the processing capacity of the ballast water treatment device and the design of the ship. When the concentration measured by the concentration measuring unit 42 is out of the reference range, the control unit 70 notifies that fact to an alarm device not shown. The alarm device to which this information is transmitted issues a warning to the user. The user who receives this warning adjusts the unit time for supplying the disinfectant.
- concentration of the disinfection component of the ballast water in a ballast tank is measured.
- concentration of the sterilization component of ballast water can be adjusted in an appropriate range by feeding back the measurement result measured in the density
- the sterilizing agent supply means 30 configured to open the bottom plates of the plurality of containers 31 at regular time intervals has been described. However, a certain amount of sterilizing agent can be supplied to the ballast pipe 11 per unit time. If it is a thing, it will not be restricted only to the bactericide supply means 30 used in the said embodiment, Various methods can be used. For example, the container 31 having a certain volume may be filled with the sterilizing agent 33, and the entire amount of the sterilizing agent 33 in the container 31 may be supplied to the ballast pipe 11, or a predetermined amount of the sterilizing agent 33 may be weighed in the container 31. Then, the weighed disinfectant 33 may be supplied to the ballast pipe 11.
- the container 31 is not limited to the form shown in FIG.
- the container 31 may be a pipe that can be opened and closed by valves.
- a certain amount of sterilizing agent can be supplied to the ballast piping 11 per unit time by opening a valve below the piping at intervals of 1 minute for 5 seconds.
- the ballast water is prevented from flowing into the supply pipe 36 by making the inner diameter of the ballast pipe 11 larger than the inner diameter of the supply pipe 36.
- the present invention is not limited to this method. Instead, various methods such as providing an inflow prevention valve for preventing the ballast water from flowing into the disinfectant supply means 30 may be adopted.
- the bactericidal agent is supplied to the ballast pipe 11 as it is has been described.
- the bactericidal agent is once dissolved in the solvent after the bactericidal agent is once put into an appropriate amount of solvent. You may inject
- the flow rate measuring unit 41 is attached to the ballast pipe 11 on the downstream side of the filtration device 20, but the flow rate measuring unit 41 is a position where the flow rate of the ballast water flowing in the ballast pipe 11 can be measured. As long as the position is not limited.
- the control unit 70 calculates the timing and amount of supplying the bactericide from the bactericide supply means 30 to the ballast pipe 11 based on the measurement result of the flow rate of the ballast water by the flow rate measurement unit 41. It is not restricted only to such a form.
- the control unit 70 may calculate the timing and amount of supplying the sterilizing agent from the sterilizing agent supply means 30 to the ballast pipe 11 based on the concentration of the sterilizing component of the ballast water in the ballast tank 60 by the concentration measuring unit 42. Good. Specifically, when the concentration measuring unit 42 detects the concentration of the sterilizing component of the ballast water higher than the reference range, the control unit 70 reduces the amount of the sterilizing agent supplied from the sterilizing agent supply unit 30 to the ballast pipe 11.
- control unit 70 controls to increase the amount of the sterilizing agent supplied from the sterilizing agent supply means 30 to the ballast pipe 11. .
- the concentration measuring unit 42 may be attached to the ballast pipe 11 on the downstream side of the mixer 50 and on the upstream side of the ballast tank 60.
- the concentration measuring unit 42 By measuring the TRO concentration of the ballast water flowing through the ballast pipe 11 by the concentration measuring unit 42 at the position shown in FIG. 3, the TRO concentration of the ballast water drowned in the ballast tank 60 can be managed.
- the sterilizing agent supply means 30 of the above embodiment supplies the sterilizing agent 33 in the container 31 to the ballast pipe 11 by opening the bottom plate 34 of the container 31, but according to the flow rate of the ballast water flowing through the ballast pipe 11.
- the specific configuration of the sterilizing agent supply unit 30 is not particularly limited as long as a predetermined amount of the sterilizing agent 33 can be put into the ballast piping 11.
- the sterilizing agent supply unit 30 a shown in FIG. By providing, a certain amount of the bactericide 33 may be supplied to the ballast pipe 11 per unit time.
- the sterilizing agent supply means 30a supplies a constant amount of the sterilizing agent 33 per unit time to the ballast pipe 11 through the supply pipe 36, and as shown in FIG. 4, has a plate shape extending in one direction (longitudinal direction).
- a rectangular lower plate 34a having an opening 34b penetrating the front and back, and a pair of guides standing on the upper surface of the lower plate 34a at both ends in the width direction of the lower plate 34a and extending in the longitudinal direction
- a sterilizing agent containing member 31a slidably mounted on the upper surface of the lower plate 34a between the plate 37 and the pair of guide plates 37, and a supply piping for supplying the sterilizing agent dropped from the opening 34b to the ballast piping 11.
- the disinfectant accommodating member 31 a is a box-shaped body having a discharge opening on the bottom wall, and in this embodiment, a hollow member having a plurality of tubular accommodating portions 32 a inside. And has a flat ladder-like frame as a whole in plan view. That is, the disinfectant containing member 31a includes a plate-like long face plate 31b that comes into surface contact with the pair of guide plates 37, a pair of end face plates 31c that connect the end portions of the long face plate 31b, and the end face plate 31c. A plurality of partition plates 31d that are provided apart from each other and connect the long face plates 31b to each other are provided. Each of the accommodating portions 32a in the present embodiment is partitioned by the partition plates 31d so as to have the same capacity. And each accommodating part 32a is filled with the same weight bactericidal agent 33, respectively.
- the lower plate 34a is a plate-like member that supports the sterilizing agent containing member 31a and the sterilizing agent 33 in the containing portion 32a from below.
- the lower plate 34a is provided with an opening 34b penetrating in the vertical direction, and the sterilizing agent 33 in the accommodating portion 32a located above the opening 34b falls from the opening 34b to the supply pipe 36.
- the supply pipe 36 is a pipe that connects the opening 34 b of the lower plate 34 a and the ballast pipe 11, and is a flow path that guides the bactericide 33 that has dropped from the opening 34 b to the ballast pipe 11.
- the inner diameter of the supply pipe 36 at the connection portion between the supply pipe 36 and the ballast pipe 11 is sufficiently smaller than the inner diameter of the ballast pipe 11. For this reason, the ballast water flowing through the ballast pipe 11 does not flow into the supply pipe 36, and the bactericide 33 can be gradually supplied from the supply pipe 36 to the ballast pipe 11.
- the pair of guide plates 37 are plate-like members having the same shape provided to assist the disinfectant containing member 31a sliding in the longitudinal direction of the lower plate 34a.
- the distance between the pair of guide plates 37 is substantially the same as the length in the width direction of the disinfectant containing member 31a.
- the extruding member 35 extrudes the bactericide containing member 31a with respect to the lower plate 34a in the longitudinal direction of the lower plate 34a at a constant speed, and this extruding speed is controlled by the control unit 70.
- the control unit 70 calculates the extrusion speed of the extrusion member 35 based on the flow rate of the ballast water flowing through the ballast pipe 11, the TRO concentration, the effective chlorine concentration of the bactericide, and the weight of the bactericide 33 filled in each storage unit 32a. To do.
- the extrusion member 35 pushes out the disinfectant accommodating member 31a in the longitudinal direction at the extrusion speed calculated here. As a result, the bactericide containing member 31a slides in the longitudinal direction of the lower plate 34a.
- the sterilizing agent supply means 30a is not limited to the form shown in FIGS. 4 and 5 as long as the sterilizing agent 33 can be supplied at regular intervals.
- the sterilizing agent supply means 30a shown in FIGS. 4 and 5 can supply a constant amount of the sterilizing agent 33 per unit time to the ballast pipe 11 by adjusting the extrusion speed of the extruding member 35.
- the control mechanism can be configured more simply.
- ballast water treatment apparatus 1 the sterilizing agent supply means 30 is provided independently of the ballast pipe 11, so that the ballast water flowing through the ballast pipe 11 is not exposed to the sterilizing agent 33.
- a constant amount of sterilizing agent per unit time is supplied to the ballast piping 11 from the sterilizing agent supply means 30 provided independently of the ballast piping 11 according to the flow rate of the ballast water flowing through the ballast piping 11. . That is, when the flow rate of the ballast water flowing through the ballast pipe 11 is small, the amount of the sterilizing agent 33 supplied to the ballast pipe 11 can be reduced. And when the flow volume of the ballast water which flows through the ballast piping 11 is large, the quantity of the disinfectant 33 supplied to the ballast piping 11 can be increased.
- the ballast water treatment apparatus includes a control unit 70 that stops the supply of the sterilizing agent 33 to the ballast pipe 11 by the sterilizing agent supply means 30 when the supply of the ballast water to the ballast tank 60 is stopped. Further prepare.
- the ballast water treatment method of the above embodiment using such a control unit 70 is a step of stopping the step of supplying the sterilizing agent 33 to the ballast pipe 11 when the supply of ballast water to the ballast tank 60 is stopped. Further included.
- the apparatus further includes a flow rate measuring unit 41 that measures the flow rate of the ballast water flowing through the ballast pipe 11.
- the control unit 70 By measuring the flow rate of the ballast water by the flow rate measuring unit 41 and sending the measurement result to the control unit 70, the control unit 70 is based on information such as the flow rate of the ballast water, the weight of the bactericide, and the effective chlorine concentration. The timing for supplying the bactericide can be calculated. And the control part 70 can supply a fixed quantity of bactericides to the ballast piping 11 from the bactericide supply means 30 by the calculated time interval. As a result, a necessary amount of bactericidal agent can be supplied to the ballast pipe 11 in a certain amount according to the amount of ballast water taken up, so that the concentration of the bactericide in the ballast water can be easily adjusted within a desired range.
- the sterilizing agent supply unit 30 includes a plurality of containers 31 (an example of a storage unit) that holds a certain amount of sterilizing agent, and the control unit 70 is configured to sterilize a certain amount held in each of the containers 31.
- the agent 33 is controlled to be supplied to the ballast pipe 11 at regular intervals for each container 31.
- a certain amount of the bactericidal agent 33 can be reliably supplied to the ballast pipe 11.
- the sterilizing agent 33 that has not been supplied to the ballast pipe 11 is held in the container 31, it is possible to prevent the sterilizing agent 33 from being inadvertently exposed to the ballast water.
- the bactericidal agent 33 is a granule, it is difficult to generate dust and is easy to handle, and it is possible to suppress the dissolution rate of the bactericidal agent from becoming too slow.
- the disinfectant in the ballast water treatment apparatus is calcium hypochlorite or chlorinated isocyanurate, and more preferably the disinfectant is trichloroisocyanurate or dichloroisocyanurate.
- Such a bactericidal agent easily generates hypochlorous acid (HOCl) having bactericidal properties, and the ballast water in the ballast tank can be sterilized by this hypochlorous acid.
- the bactericidal agent 33 is trichloroisocyanuric acid, the active ingredient can be supplied in small amounts over a long period of time, and the bactericidal effect is easily obtained with a small amount because the effective chlorine concentration is very high at around 90%.
- dichloroisocyanurate since dichloroisocyanurate has a high solubility in water, ballast water containing a bactericidal agent can be prepared in a short time.
- dichloroisocyanurate sodium dichloroisocyanurate is preferably used.
- trichloroisocyanuric acid and dichloroisocyanurate have high temperature stability, they are hardly deteriorated when stored at a high temperature of about 40 ° C. and can be used safely.
- Example 1 In this example, a prototype treatment apparatus simulating the ballast water treatment apparatus 1 shown in FIG. 1 was used.
- a polyolefin filter having an opening of 40 ⁇ m was used as the filtration apparatus 20.
- the disinfectant supply means 30 has 30 containers having an internal volume enough to hold 2 g of disinfectant made of trichloroisocyanuric acid having a granule with a diameter of 2 mm, and 2 g of disinfectant was charged in each container in advance. Opening and closing of the bottom plate of each container is individually controlled by the control unit 70.
- the bottom plate 34 in the closed state holds the sterilizing agent 33 in the container 31.
- the sterilizing agent 33 in the container 31 is dropped and supplied to the ballast pipe 11.
- the TRO concentration of the ballast water in the ballast tank 60 was set to 10 ⁇ 1 mg / L, and water treatment was performed for 30 minutes in the following manner.
- the controller 70 controls the flow rate of natural seawater (167 L / min), the preset TRO concentration (10 mg / L), the effective chlorine concentration of trichloroisocyanuric acid (90%), and the weight of the disinfectant filled in each container (2 g ) Based on the following calculation, it was calculated that 2 g of the disinfectant should be introduced into the ballast pipe 11 at intervals of 65 seconds.
- control part 70 opens the bottom plate of one container of the disinfectant supply means 30 and introduces the disinfectant 2g in the container into the ballast pipe 11 with the start of the supply of natural seawater, and then the disinfectant at intervals of 65 seconds.
- An automatic program was set up so that the bottom plate of the container of the supply means 30 was opened one by one (that is, 2 g of disinfectant was supplied at intervals of 65 seconds).
- the ballast water and the bactericide were stirred by the mixer 50.
- the stirred ballast water was poured into the ballast tank 60.
- the time change was monitored by measuring the TRO concentration of the ballast water in the ballast tank 60 by the concentration measuring unit 42 every 5 minutes after the start of the ballast water uptake. The results are as shown in Table 1 below.
- Example 2 Example 2 was carried out except that a granule having a diameter of 2.5 mm was used, and a disinfectant containing 98% by mass of trichloroisocyanuric acid and 2% by mass of carboxymethylcellulose calcium salt (disintegration aid) was used. Water treatment was carried out in the same manner as in Example 1. Since the effective chlorine concentration of this disinfectant was 88%, the calculation unit in the control unit 70 calculated that 2 g of disinfectant should be introduced into the ballast pipe 11 at intervals of 63 seconds by the following calculation. The control unit 70 supplied 2 g of the bactericide to the ballast pipe 11 at a time interval of 63 seconds.
- Example 2 As in Example 1, the change in time of the TRO concentration of the ballast water in the ballast tank 60 was monitored at intervals of 5 minutes using the concentration measuring unit 42. The results are as shown in Table 1 below.
- Example 3 In this example, except that the disinfectant supply means 30 of the ballast water treatment apparatus of Example 1 was changed to the form shown in FIGS. 4 and 5, and the disinfectant 33 was changed to sodium dichloroisocyanurate, Ballast water was prepared in the same manner as in Example 1. In the present embodiment, the inclination of the supply pipe 36a is adjusted, and the inner diameter of the supply pipe 36a at the connection portion with the ballast pipe 11 is set to 1/30 of the inner diameter of the ballast pipe 11, and the supply pipe 36a to the ballast pipe 11 are set. The supply speed of the disinfectant 33 supplied to was adjusted.
- the disinfectant supply means 30a used in the present embodiment uses a disinfectant accommodating member 31a in which a plurality of accommodating portions 32a penetrating in the vertical direction are formed apart from each other, and granules having a diameter of 2 mm are provided in each accommodating portion 32a. 3 g of a disinfectant consisting of sodium dichloroisocyanurate was charged.
- the control unit 70 controls the flow rate of natural seawater (167 L / min), the preset TRO concentration (10 mg / L), the effective chlorine concentration of sodium dichloroisocyanurate (56%), and the disinfectant filled in each storage unit 32a. Based on the weight (3 g), it was calculated that 3 g of bactericidal agent should be introduced into the ballast pipe 11 at 1 minute intervals by the following calculation.
- control part 70 starts extrusion of the bactericidal agent accommodation member 31a by the extrusion member 35 at a fixed speed in the longitudinal direction of the lower board 34a with the start of supply of natural seawater, and accommodation of the bactericidal agent accommodation member 31a at intervals of 1 minute.
- An automatic program was set up so that the sections 32a were emptied one by one (that is, 3 g of bactericide was supplied at a uniform rate at 1 minute intervals).
- 3 g of the sterilizing agent 33 dropped from the opening 36 is uniformly supplied to the ballast pipe 11 in one minute.
- Example 3 As in Example 1, the time change of the TRO concentration of the ballast water in the ballast tank 60 was monitored at intervals of 5 minutes using the concentration measuring unit. The results are as shown in Table 1 below.
- FIG. 6 is a schematic diagram illustrating the configuration of the ballast water treatment apparatus of Comparative Example 1.
- the same reference numerals are given to the same parts as those in FIG. 1, and a dash (') is added to the end of the reference numerals for the parts that are partially changed. The difference is clarified by attaching.
- a sterilizing agent dissolving device 30 ′ was attached to the bypass line 12 instead of the sterilizing agent supply means 30.
- the bypass line 12 branches off from the ballast pipe 11 at the diversion point 2D on the downstream side of the flow rate measuring unit 41, and merges with the ballast pipe 11 at the confluence point 2E on the upstream side of the mixer 50.
- Natural seawater (ballast water) flowing through the bypass line 12 passes through the disinfectant dissolving device 30 ′ and returns to the ballast pipe 11.
- the disinfectant dissolving device 30 ′ is filled with a disinfectant 33 of 60 g of trichloroisocyanuric acid having a diameter of 2 mm, and the ballast water flowing through the ballast pipe 11 passes through the inside of the disinfectant dissolving device 30 ′ to disinfect.
- the ingredients are dissolved in the ballast water.
- a shutoff valve 25 is attached to each of the ballast pipe 11 and the bypass line 12 on the downstream side of the branch point 2D.
- the on / off valve 25 adjusts the flow rate of the ballast water flowing through the ballast pipe 11 and the bypass line 12.
- Example 1 In Comparative Example 1, as in Example 1, 10 tons of natural seawater was taken into the ballast pipe 11 at a flow rate of 167 L / min (10 tons / h), and the opening degree of the on-off valve 25 was adjusted, so that at the diversion point 2D, While 111 L / min corresponding to 2/3 of the captured natural seawater was passed through the ballast pipe 11, 56 L / min corresponding to 1/3 of the captured natural seawater was passed through the bypass line 12. The ballast water flowing through the bypass line 12 dissolves the sterilizing component by passing through the disinfectant dissolving device 30 ′, and then merges with the ballast pipe 11 at the confluence 2E and is stirred by the mixer 50 to the ballast tank 60. It was flooded.
- Comparative Example 1 As in Example 1, the change in time of the TRO concentration of the ballast water in the ballast tank 60 was monitored every 5 minutes using the concentration measuring unit 42. The results are as shown in Table 1 below.
- ballast water treatment apparatuses of Examples 1, 2, and 3 even after 30 minutes of water treatment, no abnormality occurs in the disinfectant that has not been charged into the ballast pipe 11, and the ballast water treatment apparatus has not yet entered the ballast tank 60. There was no dissolved disinfectant remaining. For this reason, no abnormality was seen in the ballast water treatment apparatus even after 1 hour had passed since the end of the water treatment. In contrast, in the ballast water treatment apparatus 1 ′ of Comparative Example 1, the semidissolved sterilizing agent 33 remained in the sterilizing agent dissolving apparatus 30 ′ after the 30 minutes of water treatment.
- ballast water treatment device When left in this state for 1 hour after the end of the water treatment, a strong chlorine odor drifts around the ballast water treatment device, and the device part (material: polypropylene) that has been in contact with the liquid is deformed by corrosion. It was. From this result, according to the present invention, it is possible to provide a ballast water treatment device that can prevent the semi-dissolved disinfectant from remaining after completion of the water treatment and can prevent the water treatment device from being corroded by the sterilizing component. It became clear that it was possible.
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Abstract
Description
[バラスト水処理装置]
本発明の一実施形態である実施形態1に係るバラスト水処理装置1の構成について、図1を参照して説明する。
上記各容器31の底板34の開閉は、後述する制御部70によって所定の時間間隔で開くように制御されている。この制御によってバラスト配管11を流れるバラスト水の流量に応じて単位時間当たりに一定量の殺菌剤を、供給配管36を経由してバラスト配管11に供給できる。
上記で算出された殺菌剤33は、容器31の容量に併せて1回または複数回に分けてバラスト配管11に供給される。例えば殺菌剤供給手段30が20個の容器31を含み、各容器31がそれぞれ100gの殺菌剤を保持し得る内部容積である場合、全ての容器31に殺菌剤を充填すると1回の充填作業で100g×20=2kgの殺菌剤33を殺菌剤供給手段30に充填することができる。この殺菌剤供給手段30の各容器31の底板を2分ごとに1つずつ開けることによってバラスト配管11に殺菌剤を100gずつ供給する場合、40分後に全ての容器の殺菌剤33がバラスト配管11に供給される。このため、40分ごとに2kgの殺菌剤を殺菌剤供給手段30に充填する作業を行うことになる。この作業を6回繰り返すことにより、12kgの殺菌剤をバラスト配管11に供給することができる。
次に、上記バラスト水処理装置1を用いて実施される本実施形態に係るバラスト水処理方法について説明する。
そして、制御部70は、バラスト水の取り込み開始とともに、演算部で算出した時間間隔で殺菌剤供給手段30の容器31の底板34を1つずつ順次開けるように自動プログラムを組む。そして、この自動プログラムに準じて、制御部70は、各容器31の底板34を順次開ける。このようにして単位時間当たりに一定量の殺菌剤をバラスト配管11に供給する。そして、殺菌剤はバラスト配管11を流れるバラスト水とともにミキサー50に流入される。このミキサー50においてバラスト水及び殺菌剤を攪拌する。これにより殺菌成分の濃度が均一化されたバラスト水をバラストタンク60に漲水することができる。
上記実施形態においては、複数の容器31の各底板を一定時間間隔で開く構成の殺菌剤供給手段30を説明したが、バラスト配管11に単位時間当たりに一定量の殺菌剤を供給することができるものであれば上記実施形態で用いた殺菌剤供給手段30のみに限られず、各種の手法を用いることができる。例えば一定の容積を有する容器31内に殺菌剤33を充填し、その容器31内の殺菌剤33の全量をバラスト配管11に供給してもよいし、所定量の殺菌剤33を容器31に秤量し、秤量した殺菌剤33をバラスト配管11に供給してもよい。容器31は、一定の容積を計量できるものであれば、図2に示す形態に限られず、例えば両端をバルブで開閉可能な配管であってもよい。配管を使用して殺菌剤を供給する場合、配管の下方のバルブを1分間隔で5秒ずつ開けることによって単位時間当たりに一定量の殺菌剤をバラスト配管11に供給することができる。
次に、上記バラスト水処理装置1及びバラスト水処理方法による作用効果について説明する。上記バラスト水処理装置1によれば、バラスト配管11とは別個独立して殺菌剤供給手段30が設けられているので、バラスト配管11を流れるバラスト水が殺菌剤33に晒されることがない。そして、バラスト配管11とは別個独立に設けられた殺菌剤供給手段30からバラスト配管11に対し、バラスト配管11を流れるバラスト水の流量に応じて単位時間当たり一定量の殺菌剤を供給している。すなわち、バラスト配管11を流れるバラスト水の流量が小さい場合には、バラスト配管11に供給する殺菌剤33の量を少なくすることができる。そして、バラスト配管11を流れるバラスト水の流量が大きい場合には、バラスト配管11に供給する殺菌剤33の量を多くすることができる。
本実施例では、図1に示すバラスト水処理装置1を模擬したプロトタイプの処理装置を用いた。図1のバラスト水処理装置において、濾過装置20には目開き40μmのポリオレフィンフィルターを用いた。殺菌剤供給手段30は、直径2mmの顆粒のトリクロロイソシアヌル酸からなる殺菌剤2gを保持できる程度の内部容積の容器を30個有しており、各容器に2gの殺菌剤を予め投入した。各容器の底板は、制御部70によってそれぞれ個別に開閉が制御されている。閉状態の底板34は殺菌剤33を容器31内に保持し、底板が開状態になると容器31内の殺菌剤33が落下してバラスト配管11に供給される。本実施例では、バラストタンク60内のバラスト水のTRO濃度が10±1mg/Lとなるように設定し、下記の要領で30分間水処理を行った。
そして、制御部70は、天然海水の供給開始とともに、殺菌剤供給手段30の1つの容器の底板を開けて容器内の殺菌剤2gをバラスト配管11に導入し、その後、65秒間隔で殺菌剤供給手段30の容器の底板を1つずつ開けるように(つまり65秒間隔で2gの殺菌剤を供給するように)自動プログラムを組んだ。
実施例2では、直径2.5mmの顆粒であり、98質量%のトリクロロイソシアヌル酸と、2質量%のカルボキシメチルセルロースカルシウム塩(崩壊助剤)とを含む殺菌剤を用いたことが異なる他は実施例1と同様にして水処理を行った。この殺菌剤の有効塩素濃度は88%であったため、制御部70における演算部は、下記の計算により2gの殺菌剤を63秒間隔でバラスト配管11に導入すべきと算出した。制御部70は、63秒の時間間隔で2gの殺菌剤をバラスト配管11に供給した。
実施例2においても、実施例1と同様に、濃度測定部42を用いてバラストタンク60内のバラスト水のTRO濃度の時間変化を5分間隔でモニタリングした。その結果は下記の表1に示す通りである。
本実施例では、実施例1のバラスト水処理装置の殺菌剤供給手段30を図4及び図5に示す形態に変更し、さらに殺菌剤33をジクロロイソシアヌル酸ナトリウムに変更したことが異なる他は、実施例1と同様にしてバラスト水を調製した。また、本実施例では、供給配管36aの傾きを調整するとともにバラスト配管11との接続部分における供給配管36aの内径をバラスト配管11の内径の1/30に設定し、供給配管36aからバラスト配管11に供給する殺菌剤33の供給速度を調整した。
そして、制御部70は、天然海水の供給開始とともに、押出部材35によって殺菌剤収容部材31aを下板34aの長手方向に一定速度で押し出しを開始し、1分間隔で殺菌剤収容部材31aの収容部32aが1つずつ空にするように(つまり1分間隔で3gの殺菌剤が均一速度で供給されるように)自動プログラムを組んだ。本実施例では、供給配管36aの内径及び傾きを調整しているので、開口部36から落下した3gの殺菌剤33が1分間で均一にバラスト配管11に供給された。
比較例1では、図1に示すバラスト水処理装置の構成に代えて、図6に示すバラスト水処理装置1’を用いた。図6は、比較例1のバラスト水処理装置の構成を示す概略図である。なお、図6における各部の参照番号の表記に関し、図1の各部と同一のものには同一の参照符号を付し、一部変更を加えたものには参照符号の末尾にダッシュ(’)を付すことでその違いを明確にしている。比較例1のバラスト水処理装置1’では、図6に示されるように、殺菌剤供給手段30に代えて殺菌剤溶解装置30’をバイパスライン12に取り付けた。
表1に示す結果から、実施例1、2及び3においては、天然海水の取り込みを開始してから30分経過後までバラストタンク60内のバラスト水のTRO濃度が10±1mg/Lの範囲内で推移したのに対し、比較例1においては、目標となるバラスト水のTRO濃度(10mg/L)に至らなかった。この結果から、本発明(実施例1、2及び3)によれば、バラスト水の殺菌成分濃度を所望の範囲内に調整しやすくなることが明らかとなった。
Claims (15)
- バラストタンクにバラスト水を供給するバラスト配管と、
前記バラスト配管を流れるバラスト水の流量に応じて単位時間当たり一定量の殺菌剤を前記バラスト配管に供給する殺菌剤供給手段と、を備える、バラスト水処理装置。 - 前記バラストタンクへのバラスト水の供給を停止する時に、前記殺菌剤供給手段による前記バラスト配管への前記殺菌剤の供給を停止する制御部をさらに備える、請求項1に記載のバラスト水処理装置。
- 前記バラスト配管を流れるバラスト水の流量を測定する流量測定部をさらに備え、
前記制御部は、前記流量測定部による測定結果に基づいて、前記殺菌剤供給手段から前記バラスト配管に供給する単位時間当たりの殺菌剤の重量を算出し、算出された前記殺菌剤の重量を、前記殺菌剤供給手段から前記バラスト配管に供給するように制御する、請求項2に記載のバラスト水処理装置。 - 前記殺菌剤供給手段は、一定量の前記殺菌剤を保持する複数の収容部を有し、
前記制御部は、前記収容部のそれぞれに保持された一定量の前記殺菌剤を、一定の間隔で前記バラスト配管に供給するように制御する、請求項2又は3に記載のバラスト水処理装置。 - 前記殺菌剤は、顆粒である、請求項1~4のいずれか一項に記載のバラスト水処理装置。
- 前記殺菌剤は、次亜塩素酸カルシウム及び/又は塩素化イソシアヌル酸塩である、請求項1~5のいずれか一項に記載のバラスト水処理装置。
- 前記殺菌剤は、トリクロロイソシアヌル酸である、請求項1~6のいずれか一項に記載のバラスト水処理装置。
- 前記殺菌剤は、ジクロロイソシアヌル酸塩である、請求項1~6のいずれか一項に記載のバラスト水処理装置。
- バラスト配管からバラストタンクにバラスト水を供給する工程と、
前記バラスト配管を流れる前記バラスト水の流量に応じて単位時間当たり一定量の殺菌剤を前記バラスト配管に供給する工程と、を含むことを特徴とする、バラスト水処理方法。 - 前記バラストタンクにバラスト水を供給する工程を停止した時に、前記バラスト配管に前記殺菌剤を供給する工程を停止する工程を含む、請求項9に記載のバラスト水処理方法。
- 前記バラスト配管を流れるバラスト水の流量を測定する工程と、
測定した前記バラスト水の流量に基づいて、前記バラスト配管に単位時間当たりに供給する殺菌剤の重量を算出する工程と、
算出した前記殺菌剤の重量に基づいて、前記バラスト配管に単位時間当たり一定量の殺菌剤を供給する工程と、をさらに含む、請求項9又は10に記載のバラスト水処理方法。 - 前記殺菌剤は、顆粒である、請求項9~11のいずれか一項に記載のバラスト水処理方法。
- 前記殺菌剤は、次亜塩素酸カルシウム及び/又は塩素化イソシアヌル酸塩である、請求項9~12のいずれか一項に記載のバラスト水処理方法。
- 前記殺菌剤は、トリクロロイソシアヌル酸である、請求項9~12のいずれか一項に記載のバラスト水処理方法。
- 前記殺菌剤は、ジクロロイソシアヌル酸塩である、請求項9~12のいずれか一項に記載のバラスト水処理方法。
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WO2021131956A1 (ja) * | 2019-12-27 | 2021-07-01 | 株式会社クラレ | バラスト水処理剤、ならびにそれを用いたバラスト水処理システムおよびバラスト水処理方法 |
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JP2021104501A (ja) * | 2019-12-27 | 2021-07-26 | 株式会社クラレ | バラスト水処理剤、ならびにそれを用いたバラスト水処理システムおよびバラスト水処理方法 |
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