WO2017049652A1 - 一种有机发光器件 - Google Patents

一种有机发光器件 Download PDF

Info

Publication number
WO2017049652A1
WO2017049652A1 PCT/CN2015/090934 CN2015090934W WO2017049652A1 WO 2017049652 A1 WO2017049652 A1 WO 2017049652A1 CN 2015090934 W CN2015090934 W CN 2015090934W WO 2017049652 A1 WO2017049652 A1 WO 2017049652A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
extraction layer
light
light extraction
light emitting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2015/090934
Other languages
English (en)
French (fr)
Inventor
徐超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TCL China Star Optoelectronics Technology Co Ltd
Original Assignee
Shenzhen China Star Optoelectronics Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen China Star Optoelectronics Technology Co Ltd filed Critical Shenzhen China Star Optoelectronics Technology Co Ltd
Priority to US14/893,806 priority Critical patent/US9887389B2/en
Priority to KR1020187008478A priority patent/KR20180041746A/ko
Priority to GB1805333.0A priority patent/GB2558456B/en
Priority to JP2018514448A priority patent/JP6626570B2/ja
Priority to DE112015006924.0T priority patent/DE112015006924T5/de
Publication of WO2017049652A1 publication Critical patent/WO2017049652A1/zh
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80—Constructional details
    • H10K59/875—Arrangements for extracting light from the devices
    • H10K59/879—Arrangements for extracting light from the devices comprising refractive means, e.g. lenses
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/85—Arrangements for extracting light from the devices
    • H10K50/858—Arrangements for extracting light from the devices comprising refractive means, e.g. lenses
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14—Carrier transporting layers
    • H10K50/15—Hole transporting layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14—Carrier transporting layers
    • H10K50/16—Electron transporting layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/85—Arrangements for extracting light from the devices
    • H10K50/856—Arrangements for extracting light from the devices comprising reflective means
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass

Definitions

  • the present invention relates to the field of liquid crystal display technologies, and in particular, to an organic light emitting device.
  • the organic light emitting diode display has the advantages of self-luminous, wide viewing angle, fast response speed, high contrast, low energy consumption, etc., and has become the focus of the next generation display technology.
  • FIG. 1 is a schematic structural view of a conventional organic light emitting diode display, as shown in FIG. 1, which includes a glass substrate 10, an anode layer 11 under the glass substrate, a light emitting layer 12 under the anode layer, and a light emitting layer.
  • Cathode layer 13 due to the light generated from the luminescent layer, affected by factors such as reflection and refraction of the anode layer, the glass substrate, and the air surface layer, most of the photons escape from the side of the organic light emitting diode (as shown in the figure).
  • the dotted line in 1 shows that most of the light does not escape into the air above the glass substrate, resulting in a decrease in photon utilization, thereby limiting the development of the organic light emitting diode display.
  • an organic light emitting device including:
  • the mixed light extraction layer includes a second light extraction layer and a third light extraction layer; the third light extraction layer is located on the second light extraction layer;
  • the refractive index of the material of the third light extraction layer is smaller than the refractive index of the material of the base substrate, and the refractive index of the material of the base substrate is smaller than the refractive index of the material of the second light extraction layer;
  • a first electrode layer under the first light extraction layer for outputting holes under voltage driving
  • a light emitting layer under the first electrode layer wherein the light emitting layer is configured to generate light under excitation of holes of the first electrode layer and electrons of the second electrode layer;
  • a second electrode layer under the light emitting layer for outputting electrons under voltage driving
  • the first light extraction layer is configured to conduct light emitted from the light emitting layer onto the base substrate;
  • the mixed light extraction layer is configured to conduct light emitted from the base substrate to the mixed light
  • the air above the layer is extracted to increase the light utilization rate of the light-emitting layer;
  • the refractive index of the material of the first light extraction layer is greater than the refractive index of the material of the first electrode layer.
  • the cross-sectional shape of the second light extraction layer is zigzag.
  • the cross section of the second light extraction layer includes a plurality of first triangular cells, the first triangular cells having two first bottom corners and one first vertex angle; the first The angle of the bottom angle is obtained from the refractive index of the material of the second extraction layer.
  • the cross-sectional shape of the first light extraction layer is also zigzag.
  • the first light extraction layer has a cross-sectional shape of a plurality of second triangular units, the second triangular unit has two second bottom angles and a second top angle; the second The angle of the bottom angle is obtained according to the refractive index of the material of the first extraction layer.
  • the material of the first extraction layer is zinc oxide or titanium oxide.
  • the material of the first extraction layer and the material of the mixed light extraction layer are both transparent materials.
  • the organic light emitting device further includes a reflective layer, the reflective layer being located under the second electrode layer.
  • an organic light emitting device including:
  • a first electrode layer under the first light extraction layer for outputting holes under voltage driving
  • the light emitting layer is configured to generate light under excitation of holes of the first electrode layer and electrons of the second electrode layer;
  • a second electrode layer under the light emitting layer for outputting electrons under voltage driving
  • the first light extraction layer is configured to conduct light emitted from the light emitting layer onto the base substrate;
  • the mixed light extraction layer is configured to conduct light emitted from the base substrate to the mixed light The air above the layer is extracted to increase the light utilization efficiency of the luminescent layer.
  • a material of the first light extraction layer has a refractive index greater than a refractive index of a material of the first electrode layer.
  • the mixed light extraction layer includes a second light extraction layer and a third light extraction layer; the third light extraction layer is located on the second light extraction layer;
  • the refractive index of the material of the third light extraction layer is smaller than the refractive index of the material of the base substrate, and the refractive index of the material of the base substrate is smaller than the refractive index of the material of the second light extraction layer.
  • the cross-sectional shape of the second light extraction layer is zigzag.
  • the cross section of the second light extraction layer includes a plurality of first triangular cells, the first triangular cells having two first bottom corners and one first vertex angle; the first The angle of the bottom angle is obtained from the refractive index of the material of the second extraction layer.
  • the cross-sectional shape of the first light extraction layer is also zigzag.
  • the first light extraction layer has a cross-sectional shape of a plurality of second triangular units, the second triangular unit has two second bottom angles and a second top angle; the second The angle of the bottom angle is obtained according to the refractive index of the material of the first extraction layer.
  • the material of the first extraction layer is zinc oxide or titanium oxide.
  • the material of the first extraction layer and the material of the mixed light extraction layer are both transparent materials.
  • the organic light emitting device further includes a reflective layer, the reflective layer being located under the second electrode layer.
  • the organic light-emitting device of the present invention light emitted from the light-emitting layer is transmitted to the substrate by adding a light-light extracting layer on both sides of the glass substrate; and the light emitted from the substrate is transmitted to the display region, thereby improving The light utilization rate of the luminescent layer.
  • FIG. 1 is a schematic structural view of a prior art organic light emitting diode display
  • FIG. 2 is a schematic structural view of an organic light emitting device of the present invention.
  • FIG. 3 is a schematic structural view of a first step of a method for fabricating an organic light emitting device of the present invention
  • FIG. 4 is a schematic structural view of a second step of the method for fabricating an organic light emitting device of the present invention.
  • FIG. 5 is a schematic structural view of a third step of a method for fabricating an organic light emitting device according to the present invention.
  • FIG. 6 is a schematic structural view of a fourth step of the method for fabricating an organic light emitting device of the present invention.
  • FIG. 7 is a schematic structural view of a fifth step of the method for fabricating an organic light emitting device of the present invention.
  • FIG. 8 is a schematic structural view of a sixth step of the method for fabricating an organic light emitting device of the present invention.
  • FIG. 9 is a schematic structural view of a seventh step of the method for fabricating the organic light emitting device of the present invention.
  • FIG. 2 is a schematic structural view of an organic light emitting device according to the present invention.
  • the organic light emitting device of the present invention comprises a substrate substrate 10, a mixed light extraction layer, a first light extraction layer 21, a first electrode layer 11, a light emitting layer 12, and a second electrode layer 13;
  • the substrate 10 is, for example, a glass substrate; the mixed light extraction layers 22, 23 are located on the substrate 10; the first light extraction layer 21 is located below the substrate 10;
  • the first electrode layer 11 is located below the first light extraction layer 21; the first electrode layer 11 is, for example, an anode, and when the voltage is driven, the first electrode layer 11 outputs holes; For example, a transparent conductive film is used as the anode;
  • the luminescent layer 12 is located below the first electrode layer 11; the luminescent layer 12 is configured to generate light under the electron excitation of the holes of the first electrode layer 11 and the second electrode layer 13, ie When a hole in which a voltage is injected into the anode and an electron of the cathode are combined in the light-emitting layer, the organic material is excited to emit light.
  • the material of the light-emitting layer is, for example, tris(8-hydroxyquinoline) aluminum; the second electrode layer 13 is located below the light-emitting layer 12; and the second electrode layer 13 is, for example, a cathode, when driven by a voltage At the time, the second electrode layer 13 outputs electrons, such as a Mg/Ag alloy as a cathode.
  • the organic light emitting device further includes a hole transport layer, an electron transport layer; the hole transport layer is located between the first electrode layer 11 and the light emitting layer 12; and the electron transport layer is located at the light emitting layer 12 And the second electrode layer 13 Between.
  • the material of the hole transport layer may be a triarylamine.
  • the first light extraction layer 21 is configured to conduct light emitted from the light emitting layer 12 onto the base substrate 10; the mixed light extraction layer is used to conduct light emitted from the base substrate 10 to A display area (in the air above the mixed light extraction layer) to increase the light utilization efficiency of the light-emitting layer.
  • a reflective layer 24 is further disposed under the second electrode layer 13; the reflective layer 24 may be made of aluminum; and the light under the luminescent layer is conducted above the luminescent layer to further enhance the light. Utilization rate.
  • the mixed light extraction layer includes a second light extraction layer 22 and a third light extraction layer 23; the third light extraction layer 23 is located on the second light extraction layer 22.
  • the refractive index of the material of the first light extraction layer 21 is greater than the refractive index of the material of the first electrode layer 11.
  • the higher the refractive index of the material the stronger the ability to refract incident light; when the above relationship is satisfied, the light on the first electrode layer can be more conducted to the substrate.
  • the cross-sectional shape of the first light extraction layer 21 is zigzag. Since the zigzag shape is more conducive to the refraction of light than other shapes, when the shape of the first light extraction layer is zigzag, the refractive power of the first electrode layer can be further improved.
  • the cross section of the first light extraction layer 21 includes a plurality of second triangular units (such as triangular saw teeth), the second triangular unit has two second bottom angles and one second top angle; The angle of the two bottom angles is obtained from the refractive index of the material of the first extraction layer.
  • second triangular units such as triangular saw teeth
  • the angle of the two bottom angles is obtained from the refractive index of the material of the first extraction layer.
  • the material of the first extraction layer 11 is zinc oxide or titanium dioxide. Since the refractive indices of the two materials are relatively large, the refractive power of the light emitted from the first extraction layer can be enhanced.
  • the material of the first extraction layer and the material of the mixed light extraction layer are both transparent materials, so that light generated by the luminescent layer is allowed to diffuse into the air.
  • the refractive index of the material of the second light extraction layer 22 is greater than the refractive index of the material of the base substrate 10, and the refractive index of the material of the base substrate 10 is greater than that of the third light extraction layer 23.
  • the refractive index of the material When the refractive index of the material of the second light extraction layer 22 is greater than the refractive index of the material of the base substrate 10, the light emitted from the substrate substrate can be more conducted to the second light extraction layer; When the refractive index of the material of the base substrate 10 is greater than the refractive index of the material of the third light extraction layer 23, the light emitted by the second light extraction layer may be more transmitted to the mixed light extraction layer. In the upper air, that is, in the display area; further improve the utilization of light.
  • the cross-sectional shape of the second light extraction layer 22 is zigzag. Since the zigzag shape is more conducive to the refraction of light than other shapes, when the shape of the second light extraction layer is zigzag, the refractive power of the base substrate can be further improved.
  • the cross section of the second light extraction layer 22 includes a plurality of first triangular units (such as triangular saw teeth), the first triangular unit having two first bottom corners and one first vertex angle;
  • the angle of a bottom angle is obtained from the refractive index of the material of the second extraction layer.
  • the manufacturing method of the above organic light emitting device includes:
  • an entire second light extraction layer 22' is formed on the base substrate 10 by, for example, coating.
  • the second light extraction layer 22' is patterned to obtain a sawtooth second light extraction layer 22;
  • the zigzag second light extraction layer 22 is obtained, for example, by imprinting.
  • the third light extraction layer 23 is formed on the zigzag second light extraction layer 22;
  • the third light extraction layer 23 can be formed by coating to complete the fabrication of the mixed light extraction layer.
  • a whole layer of the first light extraction layer 21' is formed under the base substrate 10 by, for example, coating.
  • the first light extraction layer 21' is patterned to obtain a sawtooth first light extraction layer 21;
  • the zigzag first light extraction layer 21 is obtained, for example, by imprinting.
  • the first electrode layer 11 is fabricated under the zigzag first light extraction layer 21;
  • the material of the first electrode layer 11 is, for example, indium tin oxide.
  • the light-emitting layer 12 is formed under the first electrode layer 11;
  • the material of the light-emitting layer is, for example, tris(8-hydroxyquinoline)aluminum.
  • the second electrode layer 13 is located below the light-emitting layer 12; the second electrode layer 13 is, for example, a cathode, such as a Mg/Ag alloy as a cathode.
  • the organic light-emitting device of the present invention light emitted from the light-emitting layer is transmitted to the substrate by adding a light-light extracting layer on both sides of the glass substrate; and the light emitted from the substrate is transmitted to the display region, thereby improving The light utilization rate of the luminescent layer.

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

一种有机发光器件，其包括：混合光提取层（22、23）、衬底基板（10）、第一光提取层（21）、第一电极层（11）、发光层（12）、第二电极层（13）；其中所述第一光提取层（21）用于将所述发光层（12）出射的光线传导到所述衬底基板（10）上；所述混合光提取层（22、23）用于将所述衬底基板（10）出射的光线传导到所述混合光提取层（22、23）上方的空气中，以提高所述发光层（12）的光线利用率。

Description

一种有机发光器件 技术领域
本发明涉及液晶显示器技术领域，特别是涉及一种有机发光器件。
 背景技术
有机发光二极管显示器具有自发光、视角广、反应速度快、对比度高、低能耗等优点，成为下一代显示技术的焦点。
图1给出现有的有机发光二极管显示器的结构示意图，如图1所示，其包括玻璃衬底10，位于玻璃衬底下方的阳极层11、位于阳极层下方的发光层12、位于发光层下方的阴极层13；然而由于从发光层产生的光，受到阳极层、玻璃衬底、及空气表面层的反射和折射等因素的影响，使得大部分光子从有机发光二极管的侧面逸出（如图1中虚线所示），即大部分光线不能逸出至玻璃衬底上方的空气中，导致光子利用率降低，从而限制了有机发光二极管显示器的发展。
因此，有必要提供一种有机发光器件，以解决现有技术所存在的问题。
 技术问题
本发明的目的在于提供一种有机发光器件，以解决现有机发光器件光子利用率较低的技术问题。
 技术解决方案
为解决上述技术问题，本发明构造了一种有机发光器件，其包括：
衬底基板；
混合光提取层，位于所述衬底基板上；所述混合光提取层包括第二光提取层和第三光提取层；所述第三光提取层位于所述第二光提取层上；所述第三光提取层的材料的折射率小于所述衬底基板的材料的折射率，所述衬底基板的材料的折射率小于所述第二光提取层的材料的折射率；
第一光提取层，位于所述衬底基板下；
第一电极层，位于所述第一光提取层下，所述第一电极层用于在电压驱动下输出空穴；
发光层，位于所述第一电极层下，所述发光层用于在所述第一电极层的空穴和所述第二电极层的电子的激发下，产生光线；以及
第二电极层，位于所述发光层下，所述第二电极层用于在电压驱动下输出电子；
其中所述第一光提取层用于将所述发光层出射的光线传导到所述衬底基板上；所述混合光提取层用于将所述衬底基板出射的光线传导到所述混合光提取层上方的空气中，以提高所述发光层的光线利用率；所述第一光提取层的材料的折射率大于所述第一电极层的材料的折射率。
在本发明的有机发光器件中，所述第二光提取层的截面形状为锯齿形。
在本发明的有机发光器件中，所述第二光提取层的截面包括多个第一三角单元，所述第一三角单元具有两个第一底角和一个第一顶角；所述第一底角的角度根据所述第二提取层的材料的折射率得到。
在本发明的有机发光器件中，所述第一光提取层的截面形状也为锯齿形。
在本发明的有机发光器件中，所述第一光提取层的截面形状多个第二三角单元，所述第二三角单元具有两个第二底角和一个第二顶角；所述第二底角的角度根据所述第一提取层的材料的折射率得到。
在本发明的有机发光器件中，所述第一提取层的材料为氧化锌或者二氧化钛。
在本发明的有机发光器件中，所述第一提取层的材料和所述混合光提取层的材料都为透明材料。
在本发明的有机发光器件中，所述有机发光器件还包括反射层，所述反射层位于所述第二电极层的下方。
为解决上述技术问题，本发明构造了一种有机发光器件，其包括：
衬底基板；
混合光提取层，位于所述衬底基板上；
第一光提取层，位于所述衬底基板下；
第一电极层，位于所述第一光提取层下，所述第一电极层用于在电压驱动下输出空穴；
发光层，位于所述第一电极层下；所述发光层用于在所述第一电极层的空穴和所述第二电极层的电子的激发下，产生光线；以及
第二电极层，位于所述发光层下，所述第二电极层用于在电压驱动下输出电子；
其中所述第一光提取层用于将所述发光层出射的光线传导到所述衬底基板上；所述混合光提取层用于将所述衬底基板出射的光线传导到所述混合光提取层上方的空气中，以提高所述发光层的光线利用率。
在本发明的有机发光器件中，所述第一光提取层的材料的折射率大于所述第一电极层的材料的折射率。
在本发明的有机发光器件中，所述混合光提取层包括第二光提取层和第三光提取层；所述第三光提取层位于所述第二光提取层上；
所述第三光提取层的材料的折射率小于所述衬底基板的材料的折射率，所述衬底基板的材料的折射率小于所述第二光提取层的材料的折射率。
在本发明的有机发光器件中，所述第二光提取层的截面形状为锯齿形。
在本发明的有机发光器件中，所述第二光提取层的截面包括多个第一三角单元，所述第一三角单元具有两个第一底角和一个第一顶角；所述第一底角的角度根据所述第二提取层的材料的折射率得到。
在本发明的有机发光器件中，所述第一光提取层的截面形状也为锯齿形。
在本发明的有机发光器件中，所述第一光提取层的截面形状多个第二三角单元，所述第二三角单元具有两个第二底角和一个第二顶角；所述第二底角的角度根据所述第一提取层的材料的折射率得到。
在本发明的有机发光器件中，所述第一提取层的材料为氧化锌或者二氧化钛。
在本发明的有机发光器件中，所述第一提取层的材料和所述混合光提取层的材料都为透明材料。
在本发明的有机发光器件中，所述有机发光器件还包括反射层，所述反射层位于所述第二电极层的下方。
 有益效果
本发明的有机发光器件，通过在玻璃衬底的两侧分别增加一光光提取层，将发光层出射的光线传导到衬底基板上；再将衬底基板出射的光线传导到显示区域，提高了发光层的光线利用率。
 附图说明
图1为现有技术的有机发光二极管显示器的结构示意图；
图2为本发明的有机发光器件的结构示意图；
图3为本发明的有机发光器件制作方法的第一步的结构示意图；
图4为本发明的有机发光器件制作方法的第二步的结构示意图；
图5为本发明的有机发光器件制作方法的第三步的结构示意图；
图6为本发明的有机发光器件制作方法的第四步的结构示意图；
图7为本发明的有机发光器件制作方法的第五步的结构示意图；
图8为本发明的有机发光器件制作方法的第六步的结构示意图；
图9为本发明的有机发光器件制作方法的第七步的结构示意图。
 本发明的最佳实施方式
以下各实施例的说明是参考附加的图式，用以例示本发明可用以实施的特定实施例。本发明所提到的方向用语，例如「上」、「下」、「前」、「后」、「左」、「右」、「内」、「外」、「侧面」等，仅是参考附加图式的方向。因此，使用的方向用语是用以说明及理解本发明，而非用以限制本发明。在图中，结构相似的单元是以相同标号表示。
请参照图2，图2为本发明的有机发光器件的结构示意图。
如图2所示，本发明的有机发光器件包括衬底基板10、混合光提取层、第一光提取层21、第一电极层11、发光层12、第二电极层13；
所述衬底基板10譬如为玻璃衬底；所述混合光提取层22、23，位于所述衬底基板10上；所述第一光提取层21，位于所述衬底基板10的下方；
所述第一电极层11位于所述第一光提取层21的下方；所述第一电极层11譬如为阳极，当在电压驱动下，所述第一电极层11输出空穴； 譬如采用透明导电膜作阳极；
所述发光层12位于所述第一电极层11的下方；所述发光层12用于在所述第一电极层11的空穴和所述第二电极层13的电子激发下产生光线，即当电压注入阳极的空穴与阴极的电子在所述发光层结合时，激发有机材料而发光。所述发光层的材料譬如为三(8-羟基喹啉)铝；所述第二电极层13位于所述发光层12的下方；所述第二电极层13譬如为阴极，当在电压驱动下时，所述第二电极层13输出电子，譬如采用Mg/Ag合金作阴极。
所述有机发光器件还包括空穴传输层、电子传输层；所述空穴传输层位于所述第一电极层11和所述发光层12之间；所述电子传输层位于所述发光层12和所述第二电极层13 之间。所述空穴传输层的材料可为三芳胺。
其中所述第一光提取层21用于将所述发光层12出射的光线传导到所述衬底基板10上；所述混合光提取层用于将所述衬底基板10出射的光线传导到显示区域（混合光提取层上方的空气中），以提高所述发光层的光线利用率。
优选地，在所述第二电极层13的下方还设置有反射层24；所述反射层24的材料可为铝；用于将发光层下方的光线传导到发光层的上方，进一步提高光线的利用率。
优选地，所述混合光提取层包括第二光提取层22和第三光提取层23；所述第三光提取层23位于所述第二光提取层22上。
优选地，所述第一光提取层21的材料的折射率大于所述第一电极层11的材料的折射率。由于材料的折射率越高，使入射光发生折射的能力越强；当满足上述关系时，可以将所述第一电极层上的光线更多地传导到所述衬底基板上。
优选地，所述第一光提取层21的截面形状为锯齿形。由于锯齿形比其他形状更利于光线的折射，当第一光提取层的形状为锯齿状时，可进一步提高所述第一电极层的折射能力。
优选地，所述第一光提取层21的截面包括多个第二三角单元（譬如三角形的锯齿），所述第二三角单元具有两个第二底角和一个第二顶角；所述第二底角的角度根据所述第一提取层的材料的折射率得到。为了使得所述第一提取层的材料的折射率大于所述第一电极层的材料的折射率，需要将上述三角形的锯齿的底角按照所述第一提取层的材料的折射率设置。
优选地，所述第一提取层11的材料为氧化锌或者二氧化钛。由于这两种材料的折射率比较大，可以增强第一提取层出射光的折射能力。
优选地，所述第一提取层的材料和所述混合光提取层的材料都为透明材料，以便于所述发光层产生的光线透出到空气中。
优选地，所述第二光提取层22的材料的折射率大于所述衬底基板10的材料的折射率，所述衬底基板10的材料的折射率大于所述第三光提取层23的材料的折射率。当所述第二光提取层22的材料的折射率大于所述衬底基板10的材料的折射率，可使从衬底基板出射的光线更多地被传导到所述第二光提取层；当所述衬底基板10的材料的折射率大于所述第三光提取层23的材料的折射率时，可以将所述第二光提取层出射的光线更多地被传导到混合光提取层上方的空气中，即显示区域中；进一步提高光线的利用率。
优选地，所述第二光提取层22的截面形状为锯齿形。由于锯齿形比其他形状更利于光线的折射，当第二光提取层的形状为锯齿状时，可进一步提高所述衬底基板的折射能力。
优选地，所述第二光提取层22的截面包括多个第一三角单元（譬如三角形的锯齿），所述第一三角单元具有两个第一底角和一个第一顶角；所述第一底角的角度根据所述第二提取层的材料的折射率得到。为了使得所述第二提取层的材料的折射率大于所述第一电极层的材料的折射率，需要将上述三角形的锯齿的底角按照所述第二提取层的材料的折射率设置。
上述有机发光器件的制作方法包括：
S101、在衬底基板10上制作整层第二光提取层22’；
如图3所示，譬如通过涂布方式在所述衬底基板10上形成整层第二光提取层22’。
S102、对所述第二光提取层22’进行图形化处理得到锯齿状的第二光提取层22；
如图4所示，譬如通过压印方式得到所述锯齿状的第二光提取层22。
S103、在所述锯齿状的第二光提取层22上制作所述第三光提取层23；
如图5所示，在所述锯齿状的第二光提取层22上，可通过涂布方式制作所述第三光提取层23，以完成所述混合光提取层的制作。
S104、在衬底基板10下制作整层第一光提取层21’；
如图6所示，譬如通过涂布方式在所述衬底基板10下形成整层第一光提取层21’。
S105、对所述第一光提取层21’进行图形化处理得到锯齿状的第一光提取层21；
如图7所示，譬如通过压印方式得到所述锯齿状的第一光提取层21。
S106、在所述锯齿状的第一光提取层21下制作所述第一电极层11；
如图8所示，所述第一电极层11的材料譬如为铟锡氧化物。
S107、在所述第一电极层11的下方制作所述发光层12；
如图9所示，所述发光层的材料譬如为三(8-羟基喹啉)铝。
S108、在所述发光层12的下方制作所述第二电极层13以及反射层24。
如图2所示，所述第二电极层13位于所述发光层12的下方；所述第二电极层13譬如为阴极，譬如采用Mg/Ag合金作阴极。
本发明的有机发光器件，通过在玻璃衬底的两侧分别增加一光光提取层，将发光层出射的光线传导到衬底基板上；再将衬底基板出射的光线传导到显示区域，提高了发光层的光线利用率。
综上所述，虽然本发明已以优选实施例揭露如上，但上述优选实施例并非用以限制本发明，本领域的普通技术人员，在不脱离本发明的精神和范围内，均可作各种更动与润饰，因此本发明的保护范围以权利要求界定的范围为准。

Claims (18)

  1. 一种有机发光器件，其包括：
    衬底基板；
    混合光提取层，位于所述衬底基板上；所述混合光提取层包括第二光提取层和第三光提取层；所述第三光提取层位于所述第二光提取层上；所述第三光提取层的材料的折射率小于所述衬底基板的材料的折射率，所述衬底基板的材料的折射率小于所述第二光提取层的材料的折射率；
    第一光提取层，位于所述衬底基板下；
    第一电极层，位于所述第一光提取层下，所述第一电极层用于在电压驱动下输出空穴；
    发光层，位于所述第一电极层下，所述发光层用于在所述第一电极层的空穴和所述第二电极层的电子的激发下，产生光线；以及
    第二电极层，位于所述发光层下，所述第二电极层用于在电压驱动下输出电子；
    其中所述第一光提取层用于将所述发光层出射的光线传导到所述衬底基板上；所述混合光提取层用于将所述衬底基板出射的光线传导到所述混合光提取层上方的空气中，以提高所述发光层的光线利用率；所述第一光提取层的材料的折射率大于所述第一电极层的材料的折射率。
  2. 根据权利要求1所述的有机发光器件，其中所述第二光提取层的截面形状为锯齿形。
  3. 根据权利要求2所述的有机发光器件，其中所述第二光提取层的截面包括多个第一三角单元，所述第一三角单元具有两个第一底角和一个第一顶角；所述第一底角的角度根据所述第二提取层的材料的折射率得到。
  4. 根据权利要求1所述的有机发光器件，其中所述第一光提取层的截面形状也为锯齿形。
  5. 根据权利要求4所述的有机发光器件，其中所述第一光提取层的截面形状多个第二三角单元，所述第二三角单元具有两个第二底角和一个第二顶角；所述第二底角的角度根据所述第一提取层的材料的折射率得到。
  6. 根据权利要求1所述的有机发光器件，其中所述第一提取层的材料为氧化锌或者二氧化钛。
  7. 根据权利要求1所述的有机发光器件，其中所述第一提取层的材料和所述混合光提取层的材料都为透明材料。
  8. 根据权利要求1所述的有机发光器件，其中所述有机发光器件还包括反射层，所述反射层位于所述第二电极层的下方。
  9. 一种有机发光器件，其包括：
    衬底基板；
    混合光提取层，位于所述衬底基板上；
    第一光提取层，位于所述衬底基板下；
    第一电极层，位于所述第一光提取层下，所述第一电极层用于在电压驱动下输出空穴；
    发光层，位于所述第一电极层下，所述发光层用于在所述第一电极层的空穴和所述第二电极层的电子的激发下，产生光线；以及
    第二电极层，位于所述发光层下，所述第二电极层用于在电压驱动下输出电子；
    其中所述第一光提取层用于将所述发光层出射的光线传导到所述衬底基板上；所述混合光提取层用于将所述衬底基板出射的光线传导到所述混合光提取层上方的空气中，以提高所述发光层的光线利用率。
  10. 根据权利要求9所述的有机发光器件，其中所述第一光提取层的材料的折射率大于所述第一电极层的材料的折射率。
  11. 根据权利要求9所述的液晶显示面板，其中所述混合光提取层包括第二光提取层和第三光提取层；所述第三光提取层位于所述第二光提取层上；
    所述第三光提取层的材料的折射率小于所述衬底基板的材料的折射率，所述衬底基板的材料的折射率小于所述第二光提取层的材料的折射率。
  12. 根据权利要求11所述的有机发光器件，其中所述第二光提取层的截面形状为锯齿形。
  13. 根据权利要求12所述的有机发光器件，其中所述第二光提取层的截面包括多个第一三角单元，所述第一三角单元具有两个第一底角和一个第一顶角；所述第一底角的角度根据所述第二提取层的材料的折射率得到。
  14. 根据权利要求9所述的有机发光器件，其中所述第一光提取层的截面形状也为锯齿形。
  15. 根据权利要求14所述的有机发光器件，其中所述第一光提取层的截面形状多个第二三角单元，所述第二三角单元具有两个第二底角和一个第二顶角；所述第二底角的角度根据所述第一提取层的材料的折射率得到。
  16. 根据权利要求9所述的有机发光器件，其中所述第一提取层的材料为氧化锌或者二氧化钛。
  17. 根据权利要求9所述的有机发光器件，其中所述第一提取层的材料和所述混合光提取层的材料都为透明材料。
  18. 根据权利要求9所述的有机发光器件，其中所述有机发光器件还包括反射层，所述反射层位于所述第二电极层的下方。
PCT/CN2015/090934 2015-09-22 2015-09-28 一种有机发光器件 Ceased WO2017049652A1 (zh)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US14/893,806 US9887389B2 (en) 2015-09-22 2015-09-28 Organic light emitting device
KR1020187008478A KR20180041746A (ko) 2015-09-22 2015-09-28 유기 발광 소자
GB1805333.0A GB2558456B (en) 2015-09-22 2015-09-28 Organic light-emitting device
JP2018514448A JP6626570B2 (ja) 2015-09-22 2015-09-28 有機発光素子
DE112015006924.0T DE112015006924T5 (de) 2015-09-22 2015-09-28 Organische Leuchtdiode

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201510609232.1A CN105244453B (zh) 2015-09-22 2015-09-22 一种有机发光器件
CN201510609232.1 2015-09-22

Publications (1)

Publication Number Publication Date
WO2017049652A1 true WO2017049652A1 (zh) 2017-03-30

Family

ID=55042016

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2015/090934 Ceased WO2017049652A1 (zh) 2015-09-22 2015-09-28 一种有机发光器件

Country Status (7)

Country Link
US (1) US9887389B2 (zh)
JP (1) JP6626570B2 (zh)
KR (1) KR20180041746A (zh)
CN (1) CN105244453B (zh)
DE (1) DE112015006924T5 (zh)
GB (1) GB2558456B (zh)
WO (1) WO2017049652A1 (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105895826B (zh) * 2016-06-17 2019-01-25 深圳市华星光电技术有限公司 一种自发光器件、制备方法及显示装置
JP6871705B2 (ja) * 2016-09-29 2021-05-12 デクセリアルズ株式会社 光学体、光学体の製造方法、および発光装置
CN106981581A (zh) * 2017-02-08 2017-07-25 广东工业大学 一种提高光取出率的有机电致发光器件

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009146654A (ja) * 2007-12-12 2009-07-02 Nippon Zeon Co Ltd 面光源装置及びその製造方法
JP2009211868A (ja) * 2008-03-03 2009-09-17 Dainippon Printing Co Ltd 発光素子からの光取出し構造
CN103518422A (zh) * 2011-04-27 2014-01-15 吉坤日矿日石能源株式会社 有机el元件用的光取出透明基板及使用其的有机el元件
CN103633256A (zh) * 2013-12-13 2014-03-12 广州新视界光电科技有限公司 阶梯增透结构式有机电致发光器件及其制备方法
KR20150046422A (ko) * 2013-10-21 2015-04-30 한국산업기술대학교산학협력단 다기능성 봉지막을 갖는 플렉시블 ｏｌｅｄ

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7202504B2 (en) * 2004-05-20 2007-04-10 Semiconductor Energy Laboratory Co., Ltd. Light-emitting element and display device
JP2006092936A (ja) * 2004-09-24 2006-04-06 Toyota Industries Corp 有機ｅｌ装置
US7911133B2 (en) * 2007-05-10 2011-03-22 Global Oled Technology Llc Electroluminescent device having improved light output
KR20100026247A (ko) * 2008-08-29 2010-03-10 삼성모바일디스플레이주식회사 유기전계발광소자 및 그의 제조방법
JP5731830B2 (ja) * 2010-01-19 2015-06-10 パナソニック株式会社 面状発光装置
JP2011159394A (ja) * 2010-01-29 2011-08-18 Toppan Printing Co Ltd 光学部材、エレクトロルミネッセンス素子、エレクトロルミネッセンス表示装置、エレクトロルミネッセンス照明装置
JP2012015023A (ja) * 2010-07-02 2012-01-19 Toppan Printing Co Ltd Ｅｌ素子及びこれを備えた照明装置、ディスプレイ装置、液晶ディスプレイ装置
JP2012204103A (ja) * 2011-03-24 2012-10-22 Toshiba Corp 有機電界発光素子、表示装置および照明装置
JP2012227122A (ja) * 2011-04-04 2012-11-15 Rohm Co Ltd 有機ｅｌ装置
KR101654360B1 (ko) 2012-06-22 2016-09-05 코닝정밀소재 주식회사 유기 발광소자용 기판 및 그 제조방법
TWI472076B (zh) * 2012-07-31 2015-02-01 三菱麗陽股份有限公司 Ｅｌ元件用光取出膜、面發光體及ｅｌ元件用光取出膜的製造方法
WO2014031421A1 (en) * 2012-08-22 2014-02-27 3M Innovative Properties Company Transparent oled light extraction
US10468633B2 (en) * 2013-06-05 2019-11-05 Universal Display Corporation Microlens array architectures for enhanced light outcoupling from an OLED array
WO2015029203A1 (ja) * 2013-08-30 2015-03-05 株式会社日立製作所 有機発光装置
CN103490020A (zh) * 2013-09-30 2014-01-01 京东方科技集团股份有限公司 有机电致发光器件及其制作方法、显示装置、照明装置
CN203690349U (zh) * 2013-12-26 2014-07-02 京东方科技集团股份有限公司 Oled显示面板
CN104091898B (zh) * 2014-07-30 2018-06-01 上海天马有机发光显示技术有限公司 有机发光显示面板及其制造方法
CN104393179A (zh) * 2014-10-16 2015-03-04 京东方科技集团股份有限公司 一种有机电致发光器件、照明装置、显示装置
CN104362260A (zh) * 2014-11-18 2015-02-18 上海交通大学 一种利用微结构提高光萃取效率的oled器件
CN104766927B (zh) * 2015-04-30 2018-01-02 京东方科技集团股份有限公司 有机发光二极管器件及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009146654A (ja) * 2007-12-12 2009-07-02 Nippon Zeon Co Ltd 面光源装置及びその製造方法
JP2009211868A (ja) * 2008-03-03 2009-09-17 Dainippon Printing Co Ltd 発光素子からの光取出し構造
CN103518422A (zh) * 2011-04-27 2014-01-15 吉坤日矿日石能源株式会社 有机el元件用的光取出透明基板及使用其的有机el元件
KR20150046422A (ko) * 2013-10-21 2015-04-30 한국산업기술대학교산학협력단 다기능성 봉지막을 갖는 플렉시블 ｏｌｅｄ
CN103633256A (zh) * 2013-12-13 2014-03-12 广州新视界光电科技有限公司 阶梯增透结构式有机电致发光器件及其制备方法

Also Published As

Publication number Publication date
GB201805333D0 (en) 2018-05-16
JP6626570B2 (ja) 2019-12-25
GB2558456A (en) 2018-07-11
KR20180041746A (ko) 2018-04-24
GB2558456B (en) 2020-07-15
DE112015006924T5 (de) 2018-07-12
US9887389B2 (en) 2018-02-06
CN105244453A (zh) 2016-01-13
CN105244453B (zh) 2017-08-25
JP2018527725A (ja) 2018-09-20
US20170256749A1 (en) 2017-09-07

Similar Documents

Publication Publication Date Title
KR100840098B1 (ko) 유기전계발광 소자 및 그의 제조 방법
WO2013189299A1 (zh) 一种氮化镓基发光二极管
Wang et al. 55‐1: Invited Paper: Self‐Assembled Cathode Patterning in AMOLED for Under‐Display Camera
CN110071225A (zh) 显示面板及制作方法
CN106654047A (zh) Oled显示面板及其制作方法
WO2014056241A1 (zh) 有机发光二极管器件及相应的显示装置
WO2019100455A1 (zh) 一种柔性触控显示屏及其制作方法
JP5653730B2 (ja) 平板表示装置及びその製造方法
WO2017049652A1 (zh) 一种有机发光器件
CN103779390A (zh) 一种柔性显示基板及其制备方法
US9190426B2 (en) Display device and method of manufacturing the same
WO2016050023A1 (zh) 有机电致发光器件及其制备方法和具有该器件的显示器
US7977126B2 (en) Method of manufacturing organic light emitting device having photo diode
WO2020224139A1 (zh) 显示面板及其制作方法
WO2020253255A1 (zh) 显示面板、其制备方法及显示装置
US20050156261A1 (en) Optical sensor and display
US20170352711A1 (en) Manufacturing method of tft backplane and tft backplane
WO2017049685A1 (zh) 一种 oled 发光器件及显示装置
CN110098237A (zh) 显示面板及制作方法
US8450127B2 (en) Light emitting semiconductor diode
US11744123B2 (en) Array substrate and display device with light blocking layer including scattering particles
KR102094143B1 (ko) 유기발광다이오드 표시장치의 제조방법
WO2020224141A1 (zh) 显示面板及其制作方法
WO2018176517A1 (zh) Oled显示面板以及oled显示装置
WO2015089923A1 (zh) 阵列基板、液晶面板及阵列基板的制作方法

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 14893806

Country of ref document: US

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 15904528

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2018514448

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 112015006924

Country of ref document: DE

ENP Entry into the national phase

Ref document number: 20187008478

Country of ref document: KR

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 201805333

Country of ref document: GB

Kind code of ref document: A

Free format text: PCT FILING DATE = 20150928

122 Ep: pct application non-entry in european phase

Ref document number: 15904528

Country of ref document: EP

Kind code of ref document: A1