WO2017038920A1 - 粘着シート - Google Patents
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- WO2017038920A1 WO2017038920A1 PCT/JP2016/075607 JP2016075607W WO2017038920A1 WO 2017038920 A1 WO2017038920 A1 WO 2017038920A1 JP 2016075607 W JP2016075607 W JP 2016075607W WO 2017038920 A1 WO2017038920 A1 WO 2017038920A1
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- WIPO (PCT)
- Prior art keywords
- pressure
- sensitive adhesive
- adhesive sheet
- mass
- resin
- Prior art date
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/50—Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the subgroups H01L21/06 - H01L21/326, e.g. sealing of a cap to a base of a container
- H01L21/56—Encapsulations, e.g. encapsulation layers, coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
Definitions
- the present invention relates to an adhesive sheet.
- Patent Document 1 discloses a heat-resistant pressure-sensitive adhesive tape for manufacturing a semiconductor device, which is used when a substrate-less semiconductor chip that does not use a metal lead frame is sealed with a resin. Are listed.
- An object of the present invention is to provide an adhesive sheet that can prevent resin leakage when sealing a semiconductor chip attached to the adhesive sheet.
- a pressure-sensitive adhesive sheet used for sealing a semiconductor element on a pressure-sensitive adhesive sheet comprising a base material and a pressure-sensitive adhesive layer containing a pressure-sensitive adhesive.
- the storage elastic modulus at 100 ° C. of the layer is A (Pa) and the thickness of the pressure-sensitive adhesive layer is B (m)
- the numerical value calculated by the following relational expression (1) is 1.5 ⁇ 10 ⁇ 5 or more.
- the pressure-sensitive adhesive sheet according to one embodiment of the present invention preferably has a numerical value calculated by the following relational expression (2) of 1.5 ⁇ 10 ⁇ 10 or more.
- the storage elastic modulus of the substrate at 100 ° C. is preferably 1 ⁇ 10 7 Pa or more.
- the pressure-sensitive adhesive layer preferably contains an acrylic pressure-sensitive adhesive composition or a silicone-based pressure-sensitive adhesive composition.
- the acrylic pressure-sensitive adhesive composition contains an acrylic copolymer mainly composed of 2-ethylhexyl acrylate.
- the silicone-based pressure-sensitive adhesive composition contains an addition polymerization type silicone resin.
- an adhesive sheet that can prevent resin leakage when sealing a semiconductor chip attached to the adhesive sheet.
- FIG. 1 shows a schematic cross-sectional view of the pressure-sensitive adhesive sheet 10 of the present embodiment.
- the pressure sensitive adhesive sheet 10 has a base material 11 and a pressure sensitive adhesive layer 12 containing a pressure sensitive adhesive.
- the base material 11 has the 1st base material surface 11a and the 2nd base material surface 11b on the opposite side to the 1st base material surface 11a.
- the adhesive layer 12 is laminated
- a release sheet RL is laminated as shown in FIG.
- the shape of the pressure-sensitive adhesive sheet 10 can take any shape such as a tape shape and a label shape.
- the pressure-sensitive adhesive sheet 10 has a numerical value calculated by the following relational expression (1) of 1 when the storage elastic modulus at 100 ° C. of the pressure-sensitive adhesive layer 12 is A (Pa) and the thickness of the pressure-sensitive adhesive layer 12 is B (m). .5 ⁇ 10 ⁇ 5 or more.
- the storage elastic modulus of the pressure-sensitive adhesive layer is a value measured at a frequency of 1 Hz by a torsional shear method using a dynamic viscoelasticity measuring device.
- the numerical value calculated by the relational expression (1) is 1.5 ⁇ 10 ⁇ 5 or more, resin leakage occurs when the pressure-sensitive adhesive sheet of this embodiment is used as a support for sealing a semiconductor chip. Can be prevented.
- the numerical value calculated by the relational expression (1) is preferably 2.0 ⁇ 10 ⁇ 5 or more, more preferably 5.0 ⁇ 10 ⁇ 5 or more.
- the upper limit of the numerical value calculated by the relational expression (1) is not particularly limited.
- the pressure-sensitive adhesive sheet is preferably 1.0 ⁇ 10 ⁇ 2 or less because the pressure-sensitive adhesive sheet can be easily produced at low cost.
- the pressure-sensitive adhesive sheet 10 preferably has a numerical value calculated by the following relational expression (2) of 1.5 ⁇ 10 ⁇ 10 or more, more preferably 5.0 ⁇ 10 ⁇ 10 or more, and particularly preferably 1. It is 0 ⁇ 10 ⁇ 9 or more.
- the substrate 11 is a member that supports the pressure-sensitive adhesive layer 12.
- a sheet material such as a synthetic resin film can be used.
- synthetic resin films include polyethylene film, polypropylene film, polybutene film, polybutadiene film, polymethylpentene film, polyvinyl chloride film, vinyl chloride copolymer film, polyethylene terephthalate film, polyethylene naphthalate film, polybutylene terephthalate film.
- examples of the substrate 11 include these cross-linked films and laminated films.
- the base material 11 preferably includes a polyester-based resin, and more preferably includes a material having a polyester-based resin as a main component.
- the material having a polyester-based resin as a main component means that the ratio of the mass of the polyester-based resin to the total mass of the material constituting the substrate is 50% by mass or more.
- the polyester resin may be, for example, any resin selected from the group consisting of polyethylene terephthalate resin, polybutylene terephthalate resin, polyethylene naphthalate, polybutylene naphthalate resin, and copolymer resins of these resins.
- a polyethylene terephthalate resin is more preferable.
- a polyethylene terephthalate film or polyethylene naphthalate is preferable, and a polyethylene terephthalate film is more preferable.
- the oligomers contained in the polyester film are derived from polyester-forming monomers, dimers, trimers, and the like.
- the storage elastic modulus at 100 ° C. of the substrate 11 is preferably 1 ⁇ 10 7 Pa or more, and more preferably 1 ⁇ 10 8 Pa or more, from the viewpoint of dimensional stability during processing.
- the upper limit of the storage elastic modulus at 100 ° C. of the substrate 11 is preferably 1 ⁇ 10 12 Pa or less from the viewpoint of workability.
- the storage elastic modulus at 100 degreeC of the base material 11 can be measured by the method as shown below, for example. That is, the base material 11 is cut into a strip shape (size: about 20 mm ⁇ 5 mm) to prepare a test piece. And about this test piece, the storage elastic modulus in 100 degreeC can be measured with a frequency of 11 Hz using a viscoelasticity measuring apparatus (TA instrument Co., Ltd. product, DMA Q800).
- the first substrate surface 11a may be subjected to at least one surface treatment such as a primer treatment, a corona treatment, and a plasma treatment.
- the first base material surface 11a of the base material 11 may be subjected to an adhesive treatment by applying an adhesive.
- the pressure-sensitive adhesive used for the pressure-sensitive adhesive treatment of the substrate include acrylic, rubber-based, silicone-based, and urethane-based pressure-sensitive adhesives.
- the thickness of the substrate 11 is preferably 10 ⁇ m or more and 500 ⁇ m or less, more preferably 15 ⁇ m or more and 300 ⁇ m or less, and further preferably 20 ⁇ m or more and 250 ⁇ m or less.
- the pressure-sensitive adhesive layer 12 includes a pressure-sensitive adhesive composition.
- the pressure-sensitive adhesive contained in this pressure-sensitive adhesive composition is not particularly limited, and various types of pressure-sensitive adhesives can be applied to the pressure-sensitive adhesive layer 12.
- Examples of the adhesive contained in the adhesive layer 12 include rubber-based, acrylic-based, silicone-based, polyester-based, and urethane-based.
- the kind of adhesive is selected in consideration of the use and the kind of adherend to be attached.
- the pressure-sensitive adhesive layer 12 preferably contains an acrylic pressure-sensitive adhesive composition or a silicone-based pressure-sensitive adhesive composition.
- the acrylic pressure-sensitive adhesive composition preferably contains an acrylic copolymer containing 2-ethylhexyl acrylate as a main monomer. .
- the acrylic copolymer and the adhesion promoter are included.
- the acrylic copolymer is preferably a copolymer having 2-ethylhexyl acrylate as a main monomer.
- the adhesion aid preferably contains acetylcitrate triester or a rubber-based material having a reactive group as a main component.
- 2-ethylhexyl acrylate is the main monomer, and the ratio of the mass of the copolymer component derived from 2-ethylhexyl acrylate to the total mass of the acrylic copolymer is 50% by mass or more. Means.
- the proportion of the copolymer component derived from 2-ethylhexyl acrylate in the acrylic copolymer is preferably 50% by mass or more and 95% by mass or less, and 60% by mass or more and 95% by mass or less. It is more preferable that it is 80 mass% or more and 95 mass% or less, and it is still more preferable that it is 85 mass% or more and 93 mass% or less.
- the proportion of the copolymer component derived from 2-ethylhexyl acrylate is 50% by mass or more, the adhesive strength does not become too high after heating, and the adhesive sheet is more easily peeled off from the adherend, and 80% by mass or more. If it is, it will become still easier to peel. If the proportion of the copolymer component derived from 2-ethylhexyl acrylate is 95% by mass or less, the initial adhesive force is insufficient and the substrate is deformed during heating, or the adhesive sheet is peeled off from the adherend due to the deformation. Can be prevented.
- the type and number of copolymer components other than 2-ethylhexyl acrylate in the acrylic copolymer are not particularly limited.
- a functional group-containing monomer having a reactive functional group is preferable.
- a reactive functional group of a 2nd copolymer component when using the crosslinking agent mentioned later, it is preferable that it is a functional group which can react with the said crosslinking agent.
- This reactive functional group is preferably at least one substituent selected from the group consisting of, for example, a carboxyl group, a hydroxyl group, an amino group, a substituted amino group, and an epoxy group. These substituents are more preferable, and a carboxyl group is still more preferable.
- Examples of the monomer having a carboxyl group include ethylenically unsaturated carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, itaconic acid, and citraconic acid.
- carboxyl group-containing monomers acrylic acid is preferable from the viewpoint of reactivity and copolymerization.
- a carboxyl group-containing monomer may be used independently and may be used in combination of 2 or more type.
- Examples of the monomer having a hydroxyl group include, for example, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, (meth) acrylic acid 2 And (meth) acrylic acid hydroxyalkyl esters such as hydroxybutyl, 3-hydroxybutyl (meth) acrylate, and 4-hydroxybutyl (meth) acrylate.
- 2-hydroxyethyl (meth) acrylate is preferred from the viewpoint of hydroxyl reactivity and copolymerization.
- a hydroxyl-containing monomer may be used independently and may be used in combination of 2 or more type.
- “(meth) acrylic acid” is a notation used to represent both “acrylic acid” and “methacrylic acid”, and the same applies to other similar terms.
- Examples of the acrylate ester having an epoxy group include glycidyl acrylate and glycidyl methacrylate.
- Examples of other copolymer components in the acrylic copolymer include (meth) acrylic acid alkyl esters having an alkyl group with 2 to 20 carbon atoms.
- Examples of the (meth) acrylic acid alkyl ester include, for example, ethyl (meth) acrylate, propyl (meth) acrylate, n-butyl (meth) acrylate, n-pentyl (meth) acrylate, and (meth) acrylic acid n.
- Examples of other copolymer components in the acrylic copolymer include, for example, alkoxyalkyl group-containing (meth) acrylic acid ester, (meth) acrylic acid ester having an aliphatic ring, and (meth) acrylic acid having an aromatic ring.
- alkoxyalkyl group-containing (meth) acrylic acid ester examples include methoxymethyl (meth) acrylate, methoxyethyl (meth) acrylate, ethoxymethyl (meth) acrylate, and ethoxyethyl (meth) acrylate.
- examples of the (meth) acrylic acid ester having an aliphatic ring include cyclohexyl (meth) acrylate.
- examples of the (meth) acrylic acid ester having an aromatic ring examples include phenyl (meth) acrylate.
- non-crosslinkable acrylamides examples include acrylamide and methacrylamide.
- Examples of the (meth) acrylic acid ester having a non-crosslinkable tertiary amino group include (meth) acrylic acid (N, N-dimethylamino) ethyl and (meth) acrylic acid (N, N-dimethylamino). Propyl. These monomers may be used independently and may be used in combination of 2 or more type.
- a carboxyl group-containing monomer or a hydroxyl group-containing monomer is preferable as the second copolymer component, and acrylic acid is more preferable.
- the acrylic copolymer contains a copolymer component derived from 2-ethylhexyl acrylate and a copolymer component derived from acrylic acid
- the copolymer component derived from acrylic acid occupies the total mass of the acrylic copolymer.
- the mass ratio is preferably 1% by mass or less, and more preferably 0.1% by mass or more and 0.5% by mass or less. If the ratio of acrylic acid is 1 mass% or less, when an adhesive composition contains a crosslinking agent, crosslinking of the acrylic copolymer can be prevented from proceeding too quickly.
- the acrylic copolymer may contain a copolymer component derived from two or more kinds of functional group-containing monomers.
- the acrylic copolymer may be a ternary copolymer.
- an acrylic copolymer obtained by copolymerizing 2-ethylhexyl acrylate, a carboxyl group-containing monomer and a hydroxyl group-containing monomer is preferable, and this carboxyl group-containing monomer is preferable.
- the hydroxyl group-containing monomer is preferably 2-hydroxyethyl acrylate.
- the ratio of the copolymer component derived from 2-ethylhexyl acrylate in the acrylic copolymer is 80% by mass or more and 95% by mass or less, and the ratio of the mass of the copolymer component derived from acrylic acid is 1% by mass or less.
- the balance is preferably a copolymer component derived from 2-hydroxyethyl acrylate.
- the weight average molecular weight (Mw) of the acrylic copolymer is preferably from 300,000 to 2,000,000, more preferably from 600,000 to 1,500,000, and even more preferably from 800,000 to 1,200,000. preferable. If the weight average molecular weight Mw of the acrylic copolymer is 300,000 or more, the acrylic copolymer can be peeled without a residue of the adhesive on the adherend. When the weight average molecular weight Mw of the acrylic copolymer is 2 million or less, it can be reliably attached to the adherend.
- the weight average molecular weight Mw of the acrylic copolymer is a standard polystyrene equivalent value measured by a gel permeation chromatography (GPC) method.
- the acrylic copolymer can be produced according to a conventionally known method using the above-mentioned various raw material monomers.
- the form of copolymerization of the acrylic copolymer is not particularly limited, and any of a block copolymer, a random copolymer, and a graft copolymer may be used.
- the content of the acrylic copolymer in the pressure-sensitive adhesive composition is preferably 40% by mass or more and 90% by mass or less, and more preferably 50% by mass or more and 90% by mass or less.
- the adhesion assistant contains, as a main component, an acetyl citrate triester (for example, acetyl tributyl citrate) or a rubber-based material having a reactive group (hereinafter sometimes referred to as “reactive adhesion assistant”). Is preferred.
- the pressure-sensitive adhesive composition contains an acetyl citrate triester or a reactive pressure-sensitive auxiliary, the adhesive residue can be reduced.
- the content of the adhesion assistant in the pressure-sensitive adhesive composition is preferably 3% by mass or more and 50% by mass or less, and more preferably 5% by mass or more and 30% by mass or less.
- the content rate of the adhesion promoter in an adhesive composition is 3 mass% or more, generation
- including acetyl citrate triester as a main component means that the ratio of the mass of acetyl citrate triester to the total mass of the adhesion promoter exceeds 50 mass%.
- including a rubber-based material having a reactive group as a main component means that the proportion of the mass of the rubber-based material having a reactive group in the total mass of the adhesive aid exceeds 50% by mass. To do.
- the ratio of the rubber-based material having a reactive group in the adhesion assistant is preferably more than 50% by mass, and more preferably 80% by mass or more. It is also preferable that the adhesion assistant is made of a rubber-based material having a substantially reactive group.
- the reactive group is preferably one or more functional groups selected from the group consisting of a hydroxyl group, an isocyanate group, an amino group, an oxirane group, an acid anhydride group, an alkoxy group, an acryloyl group, and a methacryloyl group. More preferably.
- the reactive group possessed by the rubber material may be one type or two or more types.
- the rubber-based material having a hydroxyl group may further have the aforementioned reactive group.
- the number of reactive groups may be one per molecule constituting the rubber-based material, or two or more.
- the hydrogenated product of a polybutadiene type resin and a polybutadiene type resin is preferable, and the hydrogenated product of a polybutadiene type resin is more preferable.
- the polybutadiene-based resin include resins having 1,4-repeating units, resins having 1,2-repeating units, and resins having both 1,4-repeating units and 1,2-repeating units.
- the hydrogenated product of the polybutadiene resin of the present embodiment includes a hydride of a resin having these repeating units.
- the polybutadiene resin and the hydrogenated product of the polybutadiene resin preferably have reactive groups at both ends.
- the reactive groups at both ends may be the same or different.
- the reactive groups at both ends are preferably one or more functional groups selected from the group consisting of a hydroxyl group, an isocyanate group, an amino group, an oxirane group, an acid anhydride group, an alkoxy group, an acryloyl group, and a methacryloyl group. More preferred is a hydroxyl group.
- both ends are hydroxyl groups.
- examples of the acetylcitrate triester-based adhesion assistant include tributyl acetylcitrate (ATBC).
- the pressure-sensitive adhesive composition according to this embodiment preferably contains a cross-linked product obtained by cross-linking a composition containing a cross-linking agent in addition to the acrylic copolymer and the pressure-sensitive adhesive aid.
- the solid content of the pressure-sensitive adhesive composition substantially consists of a cross-linked product obtained by cross-linking the above-mentioned acrylic copolymer, the pressure-sensitive adhesive aid, and the cross-linking agent as described above.
- “substantially” means that the solid content of the pressure-sensitive adhesive composition is composed only of the cross-linked product, excluding trace amounts of impurities that are inevitably mixed in the pressure-sensitive adhesive.
- examples of the crosslinking agent include an isocyanate crosslinking agent, an epoxy crosslinking agent, an aziridine crosslinking agent, a metal chelate crosslinking agent, an amine crosslinking agent, and an amino resin crosslinking agent.
- These cross-linking agents may be used alone or in combination of two or more.
- a crosslinking agent (isocyanate-based crosslinking agent) containing a compound having an isocyanate group as a main component is preferable.
- isocyanate-based crosslinking agent examples include 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 1,3-xylylene diisocyanate, 1,4-xylylene diisocyanate, diphenylmethane-4,4′-diisocyanate, Polyvalent isocyanates such as diphenylmethane-2,4'-diisocyanate, 3-methyldiphenylmethane diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, dicyclohexylmethane-2,4'-diisocyanate, and lysine isocyanate Compounds.
- Polyvalent isocyanates such as diphenylmethane-2,4'-diisocyanate, 3-methyldiphenylmethane diisocyanate, hexamethylene diisocyan
- the polyisocyanate compound may be a trimethylolpropane adduct-type modified product of the above-described compound, a burette-type modified product reacted with water, or an isocyanurate-type modified product having an isocyanurate ring.
- the crosslinking agent containing a compound having an isocyanate group as a main component means that the ratio of the mass of the compound having an isocyanate group to the total mass of the components constituting the crosslinking agent is 50% by mass or more. means.
- the content of the crosslinking agent in the pressure-sensitive adhesive composition is preferably 0.1 parts by mass or more and 20 parts by mass or less, more preferably 1 part by mass or more with respect to 100 parts by mass of the acrylic copolymer. 15 parts by mass or less, more preferably 5 parts by mass or more and 10 parts by mass or less. If content of the crosslinking agent in an adhesive composition is in such a range, the adhesiveness of the layer (adhesive layer) containing an adhesive composition and a to-be-adhered body (for example, base material) will be improved. It is possible to shorten the curing period for stabilizing the adhesive property after the production of the adhesive sheet.
- the isocyanate-based crosslinking agent is more preferably a compound having an isocyanurate ring (isocyanurate-type modified product).
- the compound having an isocyanurate ring is preferably blended in an amount of 0.7 to 1.5 equivalents with respect to the hydroxyl equivalent of the acrylic copolymer. If the compounding quantity of the compound which has an isocyanurate ring is 0.7 equivalent or more, the adhesive strength will not become too high after heating, the adhesive sheet will be easily peeled off, and the adhesive residue can be reduced. If the compounding quantity of the compound which has an isocyanurate ring is 1.5 equivalent or less, it can prevent that an initial stage adhesive force becomes low too much, or can prevent a sticking fall.
- the pressure-sensitive adhesive composition in this embodiment contains a crosslinking agent
- the pressure-sensitive adhesive composition preferably further contains a crosslinking accelerator.
- the crosslinking accelerator is preferably selected and used as appropriate according to the type of the crosslinking agent.
- the pressure-sensitive adhesive composition contains a polyisocyanate compound as a crosslinking agent
- a silicone-type adhesive composition contains an addition polymerization type silicone resin.
- a silicone pressure-sensitive adhesive composition containing an addition polymerization type silicone resin is referred to as an addition reaction type silicone pressure-sensitive adhesive composition.
- the addition reaction type silicone pressure-sensitive adhesive composition contains a main agent and a crosslinking agent.
- the addition reaction type silicone pressure-sensitive adhesive composition has an advantage that it can be used only by primary curing at a low temperature and does not require secondary curing at a high temperature.
- the conventional peroxide-curing silicone pressure-sensitive adhesive requires secondary curing at a high temperature such as 150 ° C. or higher. Therefore, by using the addition reaction type silicone pressure-sensitive adhesive composition, it is possible to produce a pressure-sensitive adhesive sheet at a relatively low temperature, use the base material 11 having excellent energy economy and relatively low heat resistance. Thus, the pressure-sensitive adhesive sheet 10 can be manufactured. Further, since no by-product is produced during curing unlike the peroxide-curing silicone pressure-sensitive adhesive, there are no problems such as odor and corrosion.
- the addition reaction type silicone pressure-sensitive adhesive composition is usually composed of a main agent composed of a mixture of a silicone resin component and a silicone rubber component, a hydrosilyl group (SiH group) -containing crosslinking agent, and a curing catalyst used as necessary.
- the silicone resin component is an organopolysiloxane having a network structure obtained by hydrolyzing organochlorosilane or organoalkoxysilane and then performing a dehydration condensation reaction.
- the silicone rubber component is a diorganopolysiloxane having a linear structure.
- both the silicone resin component and the silicone rubber component are a methyl group, an ethyl group, a propyl group, a butyl group, a phenyl group, and the like.
- Some of the aforementioned organo groups are vinyl, hexenyl, allyl, butenyl, pentenyl, octenyl, (meth) acryloyl, (meth) acryloylmethyl, (meth) acryloylpropyl, and cyclohexenyl.
- Substituting with an unsaturated group such as a group.
- An organo group having a vinyl group that is easily available industrially is preferred.
- crosslinking proceeds by an addition reaction between an unsaturated group and a hydrosilyl group to form a network structure, thereby exhibiting adhesiveness.
- the number of unsaturated groups such as vinyl groups is usually from 0.05 to 3.0, preferably from 0.1 to 2.5, per 100 organo groups.
- organopolysiloxane described above examples include KS-3703 manufactured by Shin-Etsu Chemical Co., Ltd. (the number of vinyl groups is 0.6 per 100 methyl groups), Toray Dow Corning BY23-753 manufactured by the company (the number of vinyl groups is 0.1 per 100 methyl groups), and BY24-162 (the number of vinyl groups is 1.4 per 100 methyl groups) Some).
- SD4560PSA, SD4570PSA, SD4580PSA, SD4584PSA, SD4585PSA, SD4587L, and SD4592PSA manufactured by Toray Dow Corning can also be used.
- organopolysiloxane which is a silicone resin component
- silicone rubber component KS-3800 (manufactured by Shin-Etsu Chemical Co., Ltd.) 7.6 for 100 methyl groups), BY24-162 made by Toray Dow Corning (number of vinyl groups is 1.4 for 100 methyl groups), BY24- 843 (having no unsaturated group) and SD-7292 (the number of vinyl groups is 5.0 with respect to 100 methyl groups).
- Specific examples of the addition reaction type silicone as described above are described in, for example, JP-A-10-219229.
- the crosslinking agent is usually 0.5 to 10 hydrogen atoms bonded to silicon atoms, preferably 1 or more to one unsaturated group such as a vinyl group of the silicone resin component and the silicone rubber component. It mix
- the number By setting the number to 0.5 or more, the reaction between the unsaturated group such as a vinyl group and the hydrosilyl group does not proceed completely, thereby preventing poor curing.
- the addition reaction type silicone pressure-sensitive adhesive composition preferably contains a curing catalyst together with the above addition reaction type silicone component (main agent comprising a silicone resin component and a silicone rubber component) and a crosslinking agent.
- This curing catalyst is used to accelerate the hydrosilylation reaction between the unsaturated group in the silicone resin component and the silicone rubber component and the Si—H group in the crosslinking agent.
- the curing catalyst is a platinum-based catalyst, that is, chloroplatinic acid, an alcohol solution of chloroplatinic acid, a reaction product of chloroplatinic acid and an alcohol solution, a reaction product of chloroplatinic acid and an olefin compound, chloroplatinic acid and vinyl Examples thereof include a reaction product with a group-containing siloxane compound, a platinum-olefin complex, a platinum-vinyl group-containing siloxane complex, and a platinum-phosphorus complex.
- Specific examples of the curing catalyst as described above are described in, for example, JP-A-2006-28311 and JP-A-10-147758. More specifically, commercially available products include SRX-212 manufactured by Toray Dow Corning, PL-50T manufactured by Shin-Etsu Chemical Co., Ltd., and the like.
- the blending amount of the curing catalyst is usually 5 mass ppm or more and 2000 ppm or less, preferably 10 mass ppm or more and 500 mass ppm or less with respect to the total amount of the silicone resin component and the silicone rubber component as platinum content.
- curability is lowered and the crosslinking density is reduced, that is, the adhesive force and the cohesive force (holding force) are prevented from being reduced. While preventing, the stability of an adhesive layer can be hold
- the addition reaction type silicone pressure-sensitive adhesive composition an adhesive force is exhibited even at room temperature by blending the above-mentioned components, but the addition reaction type silicone pressure-sensitive adhesive composition is applied to the substrate 11 or a release sheet RL described later. After coating and bonding the base material 11 and the release sheet RL, heating or irradiating active energy rays to promote the crosslinking reaction of the silicone resin component and the silicone rubber component with the crosslinking agent can improve the stability of the adhesive force. From the aspect, it is preferable.
- the heating temperature is usually 60 ° C. or higher and 140 ° C. or lower, preferably 80 ° C. or higher and 130 ° C. or lower. Heating at 60 ° C. or higher prevents inadequate adhesion due to insufficient crosslinking between the silicone resin component and the silicone rubber component, and heating at 140 ° C. or lower can cause heat shrinkage and wrinkles on the base sheet. It is possible to prevent deterioration and discoloration.
- an active energy ray having energy quanta in an electromagnetic wave or a charged particle beam that is, an active light such as an ultraviolet ray or an electron beam
- an active light such as an ultraviolet ray or an electron beam
- a photopolymerization initiator is not required.
- a photopolymerization initiator is present.
- the photopolymerization initiator in the case of irradiation with ultraviolet rays is not particularly limited, and any photopolymerization initiator that has been conventionally used in ultraviolet curable resins can be appropriately selected and used. it can.
- photopolymerization initiator examples include benzoins, benzophenones, acetophenones, ⁇ -hydroxy ketones, ⁇ -amino ketones, ⁇ -diketones, ⁇ -diketone dialkyl acetals, anthraquinones, thioxanthones, and other compounds. Is mentioned. These photopolymerization initiators may be used alone or in combination of two or more. Further, the amount used is usually 0.01 parts by mass or more and 30 parts by mass or less, preferably 0.05 parts by mass with respect to 100 parts by mass of the total amount of the addition reaction type silicone component and the crosslinking agent used as the main agent. It is selected in the range of 20 parts by mass or less.
- a pressure-sensitive adhesive sheet having a stable adhesive force can be obtained by crosslinking by irradiation with heat or active energy rays.
- the acceleration voltage of the electron beam is generally 130 kV or more and 300 kV or less, preferably 150 kV or more and 250 kV or less. Irradiation at an acceleration voltage of 130 kV or more can prevent the silicone resin component and the silicone rubber component from being insufficiently cross-linked, resulting in insufficient adhesive force. By irradiation at an acceleration voltage of 300 kV or less, the adhesive It can prevent that a layer and a base material sheet deteriorate or discolor. A preferable range of the beam current is 1 mA or more and 100 mA or less.
- the dose of the irradiated electron beam is preferably 1 Mrad to 70 Mrad, and more preferably 2 Mrad to 20 Mrad. Irradiation with a dose of 1 Mrad or more can prevent the pressure-sensitive adhesive layer and the base sheet from being deteriorated or discolored, and can prevent the adhesiveness from becoming insufficient due to insufficient crosslinking. By irradiating with a dose of 70 Mrad or less, it is possible to prevent the cohesive force from being reduced due to deterioration or discoloration of the pressure-sensitive adhesive layer, and it is possible to prevent the base sheet from being deteriorated or contracted. The irradiation amount in the case of ultraviolet irradiation is appropriately selected.
- the light amount is from 100 mJ / cm 2 to 500 mJ / cm 2 and the illuminance is from 10 mW / cm 2 to 500 mW / cm 2 .
- Heating and irradiation with active energy rays are preferably performed in a nitrogen atmosphere in order to prevent reaction inhibition by oxygen.
- the pressure-sensitive adhesive composition may contain other components as long as the effects of the present invention are not impaired.
- other components that can be included in the pressure-sensitive adhesive composition include organic solvents, flame retardants, tackifiers, ultraviolet absorbers, light stabilizers, antioxidants, antistatic agents, antiseptics, antifungal agents, and plastics. Agents, antifoaming agents, colorants, fillers, wettability adjusting agents and the like.
- the addition reaction type silicone pressure-sensitive adhesive composition may contain non-reactive polyorganosiloxanes such as polydimethylsiloxane and polymethylphenylsiloxane as additives.
- the pressure-sensitive adhesive composition according to this embodiment include the following pressure-sensitive adhesive compositions, but the present invention is not limited to such examples.
- an acrylic copolymer, a pressure-sensitive adhesive aid, and a crosslinking agent are included, and the acrylic copolymer is at least 2-ethylhexyl acrylate, a carboxyl group-containing monomer.
- An adhesive composition is mentioned.
- an acrylic copolymer, a pressure-sensitive adhesive aid, and a crosslinking agent are included, and the acrylic copolymer is at least 2-ethylhexyl acrylate, a carboxyl group-containing monomer.
- an acrylic copolymer, an adhesion assistant, and a crosslinking agent are included, and the acrylic copolymer includes at least 2-ethylhexyl acrylate, acrylic acid, and acrylic.
- a certain adhesive composition is mentioned.
- an acrylic copolymer, an adhesion assistant, and a crosslinking agent are included, and the acrylic copolymer includes at least 2-ethylhexyl acrylate, acrylic acid, and acrylic.
- a pressure-sensitive adhesive composition which is an acrylic copolymer obtained by copolymerizing 2-hydroxyethyl acid, wherein the pressure-sensitive adhesive aid is a hydroxylated hydrogenated polybutadiene at both ends, and the cross-linking agent is an isocyanate-based cross-linking agent Is mentioned.
- an acrylic copolymer, an adhesion assistant, and a crosslinking agent are included, and the acrylic copolymer includes at least 2-ethylhexyl acrylate, acrylic acid, and acrylic.
- a pressure-sensitive adhesive composition which is an acrylic copolymer obtained by copolymerizing 2-hydroxyethyl acid, wherein the pressure-sensitive adhesive aid is tributyl acetylcitrate (ATBC), and the cross-linking agent is an isocyanate-based cross-linking agent Things.
- the proportion of the copolymer component derived from 2-ethylhexyl acrylate in the acrylic copolymer is 80% by mass or more and 95% by mass or less.
- the proportion of the mass of the copolymer component derived from the group-containing monomer is preferably 1% by mass or less, and the remainder is preferably another copolymer component.
- the other copolymer component is a copolymer derived from a hydroxyl group-containing monomer. It preferably contains a polymer component.
- the thickness of the pressure-sensitive adhesive layer 12 is appropriately determined according to the use of the pressure-sensitive adhesive sheet 10.
- the thickness of the pressure-sensitive adhesive layer 12 is preferably 5 ⁇ m or more and 60 ⁇ m or less, and more preferably 10 ⁇ m or more and 50 ⁇ m or less. If the thickness of the pressure-sensitive adhesive layer 12 is too thin, the pressure-sensitive adhesive layer 12 may not follow the irregularities on the circuit surface of the semiconductor chip, and a gap may be generated. For example, an interlayer insulating material and a sealing resin may enter the gap, and the wiring connection electrode pad on the chip circuit surface may be blocked.
- the pressure-sensitive adhesive layer 12 When the thickness of the pressure-sensitive adhesive layer 12 is 5 ⁇ m or more, the pressure-sensitive adhesive layer 12 easily follows the unevenness of the chip circuit surface, and the generation of a gap can be prevented. If the thickness of the pressure-sensitive adhesive layer 12 is too thick, the semiconductor chip sinks into the pressure-sensitive adhesive layer, and there is a risk that a step between the semiconductor chip portion and the resin portion that seals the semiconductor chip occurs. If such a step occurs, the wiring may be disconnected during rewiring. If the thickness of the pressure-sensitive adhesive layer 12 is 60 ⁇ m or less, a step is hardly generated.
- the release sheet RL is not particularly limited.
- the release sheet RL preferably includes a release substrate and a release agent layer formed by applying a release agent on the release substrate.
- the release sheet RL may include a release agent layer only on one side of the release substrate, or may include a release agent layer on both sides of the release substrate.
- the release substrate include a paper substrate, a laminated paper obtained by laminating a thermoplastic resin such as polyethylene on the paper substrate, and a plastic film.
- the paper substrate include glassine paper, coated paper, and cast coated paper.
- plastic film examples include polyester films such as polyethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate, and polyolefin films such as polypropylene and polyethylene.
- release agent examples include olefin-based resins, rubber-based elastomers (for example, butadiene-based resins and isoprene-based resins), long-chain alkyl-based resins, alkyd-based resins, fluorine-based resins, and silicone-based resins. .
- the thickness of the release sheet RL is not particularly limited.
- the thickness of the release sheet RL is usually 20 ⁇ m or more and 200 ⁇ m or less, and preferably 25 ⁇ m or more and 150 ⁇ m or less.
- the thickness of the release agent layer is not particularly limited.
- the thickness of the release agent layer is preferably 0.01 ⁇ m or more and 2.0 ⁇ m or less, and preferably 0.03 ⁇ m or more and 1.0 ⁇ m or less. More preferred.
- the thickness of the plastic film is preferably 3 ⁇ m or more and 50 ⁇ m or less, and more preferably 5 ⁇ m or more and 40 ⁇ m or less.
- the pressure-sensitive adhesive sheet 10 preferably exhibits the following pressure-sensitive adhesive strength after heating.
- the pressure-sensitive adhesive sheet 10 is adhered to an adherend (copper foil or polyimide film), heated at 100 ° C. and 30 minutes, subsequently heated at 180 ° C. and 30 minutes, and further at 190 ° C. and 1 ° C.
- the adhesive strength of the adhesive layer 12 to the copper foil at room temperature and the adhesive strength of the adhesive layer 12 to the polyimide film at room temperature are 0.7 N / 25 mm or more and 2.0 N / 25 mm, respectively. The following is preferable.
- the adhesive sheet 10 can be prevented from peeling off from the adherend when the substrate or adherend is deformed by heating. Moreover, if the adhesive force after a heating is 2.0 N / 25mm or less, peeling force will not become high too much and it will be easy to peel the adhesive sheet 10 from a to-be-adhered body.
- room temperature is a temperature of 22 ° C. or higher and 24 ° C. or lower.
- the adhesive force is a value measured by a 180 ° peeling method at a peeling speed (pulling speed) of 300 mm / min and a width of the adhesive sheet of 25 mm.
- the manufacturing method of the adhesive sheet 10 is not particularly limited.
- the adhesive sheet 10 is manufactured through the following processes. First, the pressure-sensitive adhesive composition is applied on the first base material surface 11a of the base material 11 to form a coating film. Next, this coating film is dried to form the pressure-sensitive adhesive layer 12. Then, release sheet RL is stuck so that adhesive layer 12 may be covered.
- another manufacturing method of the adhesive sheet 10 it manufactures through the following processes. First, an adhesive composition is applied on the release sheet RL to form a coating film. Next, the coating film is dried to form the pressure-sensitive adhesive layer 12, and the first base material surface 11 a of the base material 11 is bonded to the pressure-sensitive adhesive layer 12.
- the pressure-sensitive adhesive composition When the pressure-sensitive adhesive composition is applied to form the pressure-sensitive adhesive layer 12, it is preferable to prepare and use a coating liquid (pressure-sensitive adhesive liquid for application) by diluting the pressure-sensitive adhesive composition with an organic solvent.
- the organic solvent include toluene, ethyl acetate, and methyl ethyl ketone.
- the method for applying the coating liquid is not particularly limited. Examples of the coating method include spin coating, spray coating, bar coating, knife coating, roll knife coating, roll coating, blade coating, die coating, and gravure coating.
- the coating liquid In order to prevent the organic solvent and the low boiling point component from remaining in the pressure-sensitive adhesive layer 12, it is preferable to apply the coating liquid to the substrate 11 or the release sheet RL, and then heat and dry the coating film.
- a crosslinking agent When a crosslinking agent is blended in the pressure-sensitive adhesive composition, it is preferable to heat the coating film in order to promote the crosslinking reaction, improve the cohesive force, and develop the adhesiveness
- the pressure-sensitive adhesive sheet 10 is used when sealing a semiconductor element.
- the pressure-sensitive adhesive sheet 10 is not mounted on a metal lead frame, and is preferably used when sealing a semiconductor element that is stuck on the pressure-sensitive adhesive sheet 10.
- the pressure-sensitive adhesive sheet 10 is not used when sealing a semiconductor element mounted on a metal lead frame, but seals a semiconductor element that is stuck to the pressure-sensitive adhesive layer 12.
- a panel scale package Panel Scale Package
- WLP wafer Level Package
- the pressure-sensitive adhesive sheet 10 includes a step of attaching a frame member in which a plurality of openings are formed to the pressure-sensitive adhesive sheet 10; a step of attaching a semiconductor chip to the pressure-sensitive adhesive layer 12 exposed at the openings of the frame member; It is preferably used in a process having a step of covering the semiconductor chip with a sealing resin and a step of thermosetting the sealing resin.
- the manufacturing method of the semiconductor device according to the present embodiment includes a step of attaching the frame member 20 in which a plurality of openings 21 are formed on the adhesive sheet 10 (adhesive sheet attaching step), and an opening 21 of the frame member 20.
- a step of bonding the semiconductor chip CP to the exposed adhesive layer 12 (bonding step), a step of covering the semiconductor chip CP with the sealing resin 30 (sealing step), and a step of thermosetting the sealing resin 30 ( (Thermosetting step).
- each step will be described.
- the frame member 20 is formed in a lattice shape and has a plurality of openings 21.
- the frame member 20 is preferably formed of a material having heat resistance. Examples of the material of the frame member include metals such as copper and stainless steel, and heat resistant resins such as polyimide resin and glass epoxy resin.
- the opening 21 is a hole that penetrates the front and back surfaces of the frame member 20.
- the shape of the opening 21 is not particularly limited as long as the semiconductor chip CP can be accommodated in the frame.
- the depth of the hole of the opening 21 is not particularly limited as long as the semiconductor chip CP can be accommodated.
- FIG. 2B shows a schematic diagram for explaining a step of attaching the semiconductor chip CP to the adhesive layer 12.
- the semiconductor chip CP is manufactured, for example, by performing a back grinding process for grinding the back surface of the semiconductor wafer on which the circuit is formed and a dicing process for dividing the semiconductor wafer into individual pieces.
- a semiconductor chip CP semiconductor element
- the dicing apparatus is not particularly limited, and a known dicing apparatus can be used.
- the dicing conditions are not particularly limited. Note that a laser dicing method, a stealth dicing method, or the like may be used instead of the dicing method using a dicing blade.
- an expanding process may be performed in which the dicing sheet is extended to widen the interval between the plurality of semiconductor chips CP.
- the semiconductor chip CP can be picked up using a conveying means such as a collet. Further, by performing the expanding process, the adhesive force of the adhesive layer of the dicing sheet is reduced, and the semiconductor chip CP can be easily picked up.
- the energy ray polymerizable compound is blended in the adhesive composition or the adhesive layer of the dicing sheet, the energy ray polymerizable compound is applied to the adhesive layer by irradiating the adhesive layer from the substrate side of the dicing sheet. Harden.
- the energy ray polymerizable compound When the energy ray polymerizable compound is cured, the cohesive force of the adhesive layer is increased, and the adhesive force of the adhesive layer can be reduced.
- the energy rays include ultraviolet rays (UV) and electron beams (EB), and ultraviolet rays are preferable.
- UV ultraviolet rays
- EB electron beams
- the energy beam irradiation may be performed at any stage after the semiconductor wafer is pasted and before the semiconductor chip is peeled off (pickup). For example, the energy beam may be irradiated before or after dicing, or the energy beam may be irradiated after the expanding step.
- the material of the sealing resin 30 is a thermosetting resin, and examples thereof include an epoxy resin.
- the epoxy resin used as the sealing resin 30 may include, for example, a phenol resin, an elastomer, an inorganic filler, a curing accelerator, and the like.
- the method for covering the semiconductor chip CP and the frame member 20 with the sealing resin 30 is not particularly limited. In the present embodiment, an embodiment using a sheet-like sealing resin 30 will be described as an example.
- the sheet-like sealing resin 30 is placed so as to cover the semiconductor chip CP and the frame member 20, and the sealing resin 30 is heated and cured to form the sealing resin layer 30A. In this way, the semiconductor chip CP and the frame member 20 are embedded in the sealing resin layer 30A.
- the sheet-shaped sealing resin 30 it is preferable to seal the semiconductor chip CP and the frame member 20 by a vacuum laminating method. By this vacuum laminating method, it is possible to prevent a gap from being generated between the semiconductor chip CP and the frame member 20.
- the temperature condition range for heat curing by the vacuum laminating method is, for example, 80 ° C. or more and 120 ° C. or less.
- a laminated sheet in which the sheet-shaped sealing resin 30 is supported by a resin sheet such as polyethylene terephthalate may be used.
- the resin sheet may be peeled off from the sealing resin 30 and the sealing resin 30 may be heat-cured.
- Examples of such a laminated sheet include an ABF film (manufactured by Ajinomoto Fine Techno Co., Ltd.).
- a transfer molding method may be employed.
- the semiconductor chip CP and the frame member 20 adhered to the pressure-sensitive adhesive sheet 10 are accommodated inside the mold of the sealing device.
- a fluid resin material is injected into the mold to cure the resin material.
- the heating and pressure conditions are not particularly limited.
- a temperature of 150 ° C. or higher and a pressure of 4 MPa to 15 MPa are maintained for 30 seconds to 300 seconds.
- the pressure is released, the cured product is taken out from the sealing device, and left in an oven, and a temperature of 150 ° C. or higher is maintained for 2 hours to 15 hours. In this way, the semiconductor chip CP and the frame member 20 are sealed.
- the first heat pressing process may be performed before the process of thermosetting the sealing resin 30 (thermosetting process).
- the semiconductor chip CP and the pressure-sensitive adhesive sheet 10 with the frame member 20 covered with the sealing resin 30 are sandwiched between the plate-like members from both sides, and pressed under conditions of a predetermined temperature, time, and pressure. .
- the sealing resin 30 is easily filled into the gap between the semiconductor chip CP and the frame member 20.
- corrugation of 30 A of sealing resin layers comprised with the sealing resin 30 can also be planarized by implementing a heat press process.
- the plate member for example, a metal plate such as stainless steel can be used.
- the sealing body 50 When the pressure-sensitive adhesive sheet 10 is peeled after the thermosetting step, the semiconductor chip CP and the frame member 20 sealed with the sealing resin 30 are obtained. Hereinafter, this may be referred to as a sealing body 50.
- FIG. 2D The schematic diagram explaining the process of sticking the reinforcing member 40 to the sealing body 50 is shown by FIG. 2D.
- a rewiring process and a bumping process for forming a rewiring layer on the exposed circuit surface of the semiconductor chip CP are performed.
- a step of sticking the reinforcing member 40 to the sealing body 50 may be performed.
- FIG. 2D the sealing body 50 is supported in a state of being sandwiched between the adhesive sheet 10 and the reinforcing member 40.
- the reinforcing member 40 includes a heat-resistant reinforcing plate 41 and a heat-resistant adhesive layer 42.
- the reinforcing plate 41 include a plate-like member containing a heat resistant resin such as a polyimide resin and a glass epoxy resin.
- the adhesive layer 42 adheres the reinforcing plate 41 and the sealing body 50.
- the adhesive layer 42 is appropriately selected according to the material of the reinforcing plate 41 and the sealing resin layer 30A.
- the adhesive layer 42 is preferably a glass cloth including a thermoplastic resin.
- the thermoplastic resin contained bismaleimide triazine resin (BT resin) is preferable.
- the adhesive layer 42 is sandwiched between the sealing resin layer 30A of the sealing body 50 and the reinforcing plate 41, and is further sandwiched by plate members from the reinforcing plate 41 side and the adhesive sheet 10 side, respectively. It is preferable to carry out a second hot pressing step of pressing under the conditions of temperature, time, and pressure.
- the sealing body 50 and the reinforcing member 40 are temporarily fixed by the second heating press process. In order to cure the adhesive layer 42 after the second heat pressing step, it is preferable to heat the temporarily fixed sealing body 50 and the reinforcing member 40 under conditions of a predetermined temperature and time.
- the conditions for heat curing are appropriately set according to the material of the adhesive layer 42, and are, for example, 185 ° C., 80 minutes, and 2.4 MPa.
- a metal plate such as stainless steel can be used as the plate-like member.
- FIG. 2E The schematic explaining the process of peeling the adhesive sheet 10 is shown by FIG. 2E.
- peeling angle (theta) is not specifically limited, It is preferable to peel the adhesive sheet 10 with peeling angle (theta) of 90 degree
- the peeling angle ⁇ is preferably 90 degrees or more and 180 degrees or less, and more preferably 135 degrees or more and 180 degrees or less.
- the reinforcing member 40 When the reinforcing member 40 is attached, the reinforcing member 40 is peeled off from the sealing body 50 at the stage where the support by the reinforcing member 40 becomes unnecessary after the rewiring process and the bumping process are performed. Thereafter, the sealing body 50 is separated into individual semiconductor chips CP (individualization step).
- a method for dividing the sealing body 50 into individual pieces is not particularly limited.
- the semiconductor wafer can be separated into pieces by the same method as that used when dicing the semiconductor wafer.
- the step of dividing the sealing body 50 into pieces may be performed in a state where the sealing body 50 is adhered to a dicing sheet or the like.
- the pressure-sensitive adhesive sheet 10 that can prevent resin leakage when sealing the semiconductor chip attached to the pressure-sensitive adhesive sheet. Moreover, according to the manufacturing method of the semiconductor device using the said adhesive sheet 10, a resin leak can be prevented and it can prevent that a chip
- the adhesive sheet 10 may be a single wafer or may be provided in a state where a plurality of adhesive sheets 10 are laminated.
- the pressure-sensitive adhesive layer 12 may be covered with the base material 11 of another pressure-sensitive adhesive sheet to be laminated.
- the adhesive sheet 10 may be a long sheet or may be provided in a state of being wound in a roll. The pressure-sensitive adhesive sheet 10 wound up in a roll shape can be used by being unwound from a roll and cut into a desired size.
- the sealing resin 30 is a thermosetting resin
- the present invention is not limited to such a mode.
- the sealing resin 30 may be an energy ray curable resin that is cured by energy rays such as ultraviolet rays.
- the adhesive sheet 10 may be used in a method for manufacturing a semiconductor device that seals a semiconductor element without using a frame member.
- the adhesive liquids for application in Examples 1 to 9 and Comparative Example 1 were applied to a release film (“PET3801” manufactured by Lintec Corporation) using a comma coater (registered trademark) and dried (drying conditions: 90 ° C., 90 Second, and 115 ° C., 90 seconds) to form a layer having a thickness of 30 ⁇ m, which was laminated to prepare a measurement sample having a thickness of 1 mm and a diameter of 8 mm.
- the storage elastic modulus (Pa) at 100 ° C. of the obtained measurement sample was measured by a torsional shear method using a viscoelasticity measuring device (MCR manufactured by Anton Paar Japan). The heating rate was 5 ° C./min, and the measurement frequency was 1 Hz.
- Sealing conditions were such that the preheating temperature of the vacuum heating and pressure laminator table and the diaphragm were both 100 ° C., and the sealing was performed for 60 seconds by vacuuming, 30 seconds in the Dynamic press mode, and 10 seconds in the Static press mode. . After that, the state of the interface between the chip and the pressure-sensitive adhesive sheet is confirmed with a digital microscope through the pressure-sensitive adhesive sheet, and if the interlayer insulating resin penetrates 10 ⁇ m or more from the chip end part between the chip and the pressure-sensitive adhesive sheet, there is a leakage, and less than 10 ⁇ m The case was assumed to be no leakage.
- Example 1 Preparation of adhesive sheet.
- the following materials polymer, pressure-sensitive adhesive, cross-linking agent, and diluting solvent) were blended and sufficiently stirred, and the pressure-sensitive adhesive liquid for application according to Example 1 (pressure-sensitive adhesive composition) Prepared).
- Acrylic ester copolymer 40 parts by mass (solid content)
- the acrylic ester copolymer was prepared by copolymerizing 92.8% by mass of 2-ethylhexyl acrylate, 7.0% by mass of 2-hydroxyethyl acrylate, and 0.2% by mass of acrylic acid.
- -Adhesion aid hydroxylated hydrogenated polybutadiene at both ends (manufactured by Nippon Soda Co., Ltd .; GI-1000), 5 parts by mass (solid content)
- Crosslinking agent Aliphatic isocyanate having hexamethylene diisocyanate (isocyanurate-type modified product of hexamethylene diisocyanate; manufactured by Nippon Polyurethane Industry Co., Ltd .; Coronate HX), 3.5 parts by mass (solid content)
- Diluting solvent Methyl ethyl ketone was used, and the solid content concentration of the coating adhesive solution was adjusted to 30% by mass.
- pressure-sensitive adhesive layer 38 Preparation of pressure-sensitive adhesive layer 38 ⁇ m transparent polyethylene terephthalate provided with a silicone release layer so that the thickness of the prepared pressure-sensitive adhesive liquid for coating after drying using a comma coater (registered trademark) is 50 ⁇ m. It is applied to the release layer side of a release film consisting of a film [manufactured by Lintec Corporation; SP-PET382150], heated at 90 ° C. for 90 seconds, and then heated at 115 ° C. for 90 seconds to dry the coating film. To produce a pressure-sensitive adhesive layer.
- Example 2 The pressure-sensitive adhesive sheet according to Example 2 used 5 parts by mass (solid content) of tributyl acetyl citrate (ATBC) [manufactured by Taoka Chemical Co., Ltd.] as a pressure-sensitive adhesive contained in the pressure-sensitive adhesive layer. It was produced in the same manner as in Example 1 except that the prepared adhesive liquid for application was applied so that the thickness after drying was 30 ⁇ m.
- ATBC tributyl acetyl citrate
- Example 3 The adhesive sheet according to Example 3 was used except that 5 parts by mass (solid content) of tributyl acetyl citrate (ATBC) [manufactured by Taoka Chemical Industry Co., Ltd.] was used as an adhesive aid contained in the adhesive layer. This was produced in the same manner as in Example 1.
- ATBC tributyl acetyl citrate
- Example 4 (1) Preparation of pressure-sensitive adhesive composition
- a silicone-based pressure-sensitive adhesive was used.
- Silicone-based adhesive A (SD4580PSA) 18 parts by mass (solid content) 40 parts by mass (solid content) of silicone-based adhesive B (SD-4487L), Catalyst A (NC-25CAT) 0.3 parts by mass (solid content)
- Catalyst B (CAT-SRX-212) 0.65 parts by mass (solid content)
- Primer (BY-24-712) 5 parts by mass (solid content) was mixed with toluene as a diluent solvent so that the solid content was 20% by mass and stirred sufficiently to prepare a coating pressure-sensitive adhesive liquid (pressure-sensitive adhesive composition) according to Example 4.
- the materials used for the pressure-sensitive adhesive composition of Example 4 are all manufactured by Toray Dow Corning Co., Ltd.
- Example 5 A pressure-sensitive adhesive sheet was produced in the same manner as in Example 4 except that the pressure-sensitive adhesive liquid for application was applied and dried so that the thickness after drying was 30 ⁇ m.
- Example 6 A pressure-sensitive adhesive sheet was prepared in the same manner as in Example 4 except that the coating pressure-sensitive adhesive solution was coated and dried so that the thickness after drying was 40 ⁇ m.
- Example 7 A pressure-sensitive adhesive sheet was produced in the same manner as in Example 4 except that the pressure-sensitive adhesive liquid for application was applied and dried so that the thickness after drying was 50 ⁇ m.
- Example 8 A pressure-sensitive adhesive sheet was produced in the same manner as in Example 1 except that the polymer of Example 1 was changed to the following composition.
- the acrylic ester copolymer comprises a copolymer of 80.8% by mass of 2-ethylhexyl acrylate, 12% by mass of acryloylmorpholine, 7.0% by mass of 2-hydroxyethyl acrylate, and 0.2% by mass of acrylic acid. Prepared by polymerization.
- Example 9 A pressure-sensitive adhesive sheet was prepared in the same manner as in Example 8 except that the thickness of the pressure-sensitive adhesive in Example 8 was changed to 20 ⁇ m.
- Example 1 A pressure-sensitive adhesive sheet was prepared in the same manner as in Example 4 except that the coating pressure-sensitive adhesive solution was coated and dried so that the thickness after drying was 10 ⁇ m.
- Table 1 shows the evaluation results of the adhesive sheets according to Examples 1 to 9 and Comparative Example 1.
- the numerical value calculated by A ⁇ B 2 was less than 1.5 ⁇ 10 ⁇ 5 , so it is considered that resin leakage could not be prevented.
- the pressure-sensitive adhesive sheets according to Examples 1 to 9 have a numerical value calculated by A ⁇ B 2 of 1.5 ⁇ 10 ⁇ 5 or more, so it is considered that resin leakage could be prevented.
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US11987731B2 (en) | 2018-08-10 | 2024-05-21 | Dow Toray Co., Ltd. | Organopolysiloxane composition for forming pressure sensitive adhesive layer, and use of same |
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SG11202009374YA (en) * | 2018-03-30 | 2020-10-29 | Mitsui Chemicals Tohcello Inc | Method for manufacturing electronic device |
CN110561877A (zh) * | 2018-06-05 | 2019-12-13 | 通用矽酮股份有限公司 | 一种硅胶弹性体及其制造方法 |
CN112352027A (zh) * | 2018-06-13 | 2021-02-09 | 琳得科株式会社 | 粘合片 |
JP7200961B2 (ja) * | 2020-03-06 | 2023-01-10 | 味の素株式会社 | 半導体装置の製造方法、及び、樹脂シート |
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JP6759218B2 (ja) | 2020-09-23 |
TWI709634B (zh) | 2020-11-11 |
JPWO2017038922A1 (ja) | 2018-06-14 |
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KR20180048569A (ko) | 2018-05-10 |
JP6719476B2 (ja) | 2020-07-08 |
WO2017038921A1 (ja) | 2017-03-09 |
TW201723123A (zh) | 2017-07-01 |
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JPWO2017038920A1 (ja) | 2018-06-21 |
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