WO2016143487A1 - 無灰炭の製造方法 - Google Patents
無灰炭の製造方法 Download PDFInfo
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- WO2016143487A1 WO2016143487A1 PCT/JP2016/054933 JP2016054933W WO2016143487A1 WO 2016143487 A1 WO2016143487 A1 WO 2016143487A1 JP 2016054933 W JP2016054933 W JP 2016054933W WO 2016143487 A1 WO2016143487 A1 WO 2016143487A1
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- coal
- solvent
- solid
- slurry
- ashless coal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/40—Particle separators, e.g. dust precipitators, using edge filters, i.e. using contiguous impervious surfaces
- B01D46/403—Particle separators, e.g. dust precipitators, using edge filters, i.e. using contiguous impervious surfaces of helically or spirally wound bodies
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/543—Distillation, fractionation or rectification for separating fractions, components or impurities during preparation or upgrading of a fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/544—Extraction for separating fractions, components or impurities during preparation or upgrading of a fuel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/547—Filtration for separating fractions, components or impurities during preparation or upgrading of a fuel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/04—Raw material of mineral origin to be used; Pretreatment thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/06—Methods of shaping, e.g. pelletizing or briquetting
Definitions
- the present invention relates to a method for producing ashless coal.
- Coal is widely used as a raw material for thermal power generation and boiler fuel or chemicals, and as one of the environmental measures, development of a technology for efficiently removing ash in coal is strongly desired.
- HPC ash-free charcoal
- Attempts have also been made to use ashless coal as coking coal for ironmaking coke such as blast furnace coke.
- a method for producing ashless coal As a method for producing ashless coal, a method has been proposed in which a solution containing a coal component soluble in a solvent (hereinafter also referred to as a solvent-soluble component) is separated from a slurry by using a gravity sedimentation method (for example, Japanese Patent Laid-Open No. 2009-2009) -227718).
- This method includes a slurry preparation step in which coal and a solvent are mixed to prepare a slurry, and an extraction step in which the slurry obtained in the slurry preparation step is heated to extract a solvent-soluble component.
- this method includes a solution separation step for separating the solution in which the solvent-soluble component is dissolved from the slurry from which the solvent-soluble component has been extracted in the extraction step, and an ashless by separating the solvent from the solution separated in the solution separation step. And an ashless coal acquisition step for obtaining charcoal.
- the slurry obtained in the slurry preparation process is heated to a predetermined temperature and supplied to the extraction tank. And the slurry supplied to the extraction tank is hold
- the solvent-soluble component in the extraction step may be polymerized to form a residue due to temperature rise, and may not be extracted as a solvent-soluble component in the solution separation step. For this reason, there exists a possibility that the extraction rate of ashless coal may fall.
- the “extraction rate” means the ratio of the mass of manufactured ashless coal to the mass of coal as a raw material.
- This invention is made
- the invention made to solve the above problems includes a step of preparing a slurry by mixing coal and a solvent, a step of eluting a coal component soluble in a solvent from coal by heating the slurry, and a slurry after the elution
- a method for producing ashless coal comprising: a step of separating a solution in which a coal component is dissolved from a solution; and a step of obtaining ashless coal from a solution separated in the separation step by evaporation separation of a solvent, wherein the separation step is eluted It is characterized by being performed simultaneously with the process.
- the said ashless coal manufacturing method performs the said separation process simultaneously with an elution process, it is hard to produce the polymerization by the temperature rise of a solvent soluble component at a separation process, and can raise the elution amount of the solvent soluble component in an elution process. . Therefore, the ashless coal manufacturing method can increase the extraction rate of ashless coal.
- the above separation step may be performed during the heating process of the elution step.
- polymerization by the temperature rise of a solvent soluble component can further be suppressed, and the extraction rate of ashless coal further increases.
- the above separation process may be performed continuously.
- the polymerization by the temperature rise of a solvent soluble component can be further suppressed, without retaining a solvent soluble component in a storage tank etc., the extraction rate of ashless coal is Further increase.
- a solid-liquid separator provided with a filter-like cylinder and a spiral channel disposed along the inner surface of the filter-like cylinder may be used.
- the apparatus used for the separation step can be simplified, and the cost of the ashless coal production apparatus can be reduced.
- dissolved is isolate
- the filter-like cylindrical body is a mesh shape using a metal wire.
- a mesh-like material using a metal wire for the filter-like cylindrical body in this way, it is difficult to clog the filter and no support material such as a reinforcing wire is required, so that the coal component dissolves easily and reliably. Solution can be separated.
- the solid-liquid separator further includes a recovery tube that encloses the filter-like cylindrical body and recovers the solution, and the recovery tube discharges the solution to the side surface on the upstream side of the spiral flow path. It is good to have.
- the temperature of the solution is higher on the downstream side.
- ashless coal is a type of modified coal obtained by reforming coal, and a modified coal that removes ash and insoluble components from coal as much as possible using a solvent. It is.
- the ashless coal may contain ash as long as the fluidity and expansibility of the ashless coal are not significantly impaired.
- coal contains ash content of 7% by mass or more and 20% by mass or less, but ashless coal may contain ash content of about 2% by mass, and in some cases about 5% by mass.
- “Ash” means a value measured in accordance with JIS-M8812: 2004.
- the method for producing ashless coal of the present invention can increase the extraction rate of ashless coal by performing the separation step simultaneously with the elution step.
- the ashless coal production apparatus 1 in FIG. 1 includes a solvent supply unit 10, a coal supply unit 20, a preparation unit 30, a solid-liquid separation unit 40, a first solvent separation unit 50, and a second solvent separation unit 60. Is mainly provided.
- the solvent supply unit 10 supplies the solvent to the preparation unit 30.
- the solvent supply unit 10 mainly includes a solvent tank 11 and a pump 12.
- the solvent tank 11 stores a solvent to be mixed with coal supplied from the coal supply unit 20.
- the solvent mixed with coal will not be specifically limited if coal is melt
- the bicyclic aromatic compound derived from coal is used suitably. Since this bicyclic aromatic compound has a basic structure similar to the structural molecule of coal, it has a high affinity with coal and can obtain a relatively high extraction rate.
- the bicyclic aromatic compound derived from coal include methyl naphthalene oil and naphthalene oil, which are distilled oils of by-products when carbon is produced by carbonization to produce coke.
- the boiling point of the solvent is not particularly limited.
- the lower limit of the boiling point of the solvent is preferably 180 ° C., more preferably 230 ° C.
- the upper limit of the boiling point of the solvent is preferably 300 ° C and more preferably 280 ° C.
- the pump 12 is disposed in a pipe connected to the preparation unit 30.
- the pump 12 pumps the solvent stored in the solvent tank 11 to the preparation unit 30 via the supply pipe 70.
- the type of the pump 12 is not particularly limited as long as the solvent can be pumped to the preparation unit 30 through the supply pipe 70.
- a positive displacement pump or a non-positive displacement pump can be used. More specifically, a diaphragm pump or a tube diaphragm pump can be used as the positive displacement pump, and a spiral pump or the like can be used as the non-positive displacement pump.
- the coal supply unit 20 supplies coal to the preparation unit 30.
- the coal supply unit 20 is arranged in a normal pressure hopper 21 used in a normal pressure state, a pressure hopper 22 used in a normal pressure state and a pressure state, and a pipe connecting the normal pressure hopper 21 and the pressure hopper 22. It has the 1st valve 23 provided, and the 2nd valve 24 arrange
- a pressurization line 25 for supplying a gas such as nitrogen gas and an exhaust line 26 for exhausting the gas are connected to the pressurization hopper 22.
- the coal stored in the normal pressure hopper 21 is first transferred to the pressure hopper 22 by opening the first valve 23 with the second valve 24 closed. At this time, the pressure hopper 22 is in a normal pressure state. Next, the first valve 23 is closed, and a gas such as nitrogen gas is supplied to the pressurization hopper 22 through the pressurization line 25. As a result, the piping from the first valve 23 to the second valve 24 including the pressure hopper 22 is pressurized, and the inside of the pressure hopper 22 is in a pressurized state. At this time, it is preferable to pressurize so that the pressure in the pressure hopper 22 is equal to or higher than the pressure in the supply pipe 70. Then, the coal in the pressure hopper 22 is supplied to the supply pipe 70 by opening the second valve 24.
- the pressurization line 25 and the exhaust line 26 are connected to the pressurization hopper 22, but the pressurization hopper is provided between the first valve 23 and the second valve 24. You may be connected to piping etc. other than 22.
- first valve 23 and the second valve 24 are not particularly limited.
- first valve 23 and the second valve 24 for example, a gate valve, a ball valve, a flap valve, a rotary valve, and the like are used. Can be used.
- coal supplied from the coal supply unit 20 various quality coals can be used.
- bituminous coal with a high extraction rate or cheaper inferior quality coal (subbituminous coal or lignite) is preferably used.
- finely pulverized coal means, for example, coal in which the mass ratio of coal having a particle size of less than 1 mm to the mass of the entire coal is 80% or more.
- lump coal can also be used as the coal supplied from the coal supply unit 20.
- “coal” means, for example, coal in which the mass ratio of coal having a particle size of 5 mm or more to the mass of the entire coal is 50% or more.
- particle size refers to a value measured in accordance with the JIS-Z8815 (1994) general screening test rules.
- a metal mesh screen defined in JIS-Z8801-1 (2006) can be used.
- a coal containing a large amount of inferior coal as the coal supplied from the coal supply unit 20.
- 80 mass% is preferred and 90 mass% is more preferred.
- the ratio of the inferior quality coal contained in the coal to supply is less than the said minimum, there exists a possibility that the time which elutes a solvent soluble component may become long.
- the lower limit of the carbon content of the inferior coal is preferably 70% by mass. Moreover, as an upper limit of the carbon content rate of the said inferior coal, 85 mass% is preferable and 82 mass% is more preferable. When the carbon content of the inferior coal is less than the lower limit, the elution rate of the solvent-soluble component may be reduced. On the other hand, when the carbon content of the inferior coal exceeds the upper limit, the cost of supplied coal may increase.
- coal supplied from the coal supply unit 20 to the preparation unit 30 coal obtained by mixing a small amount of solvent into a slurry may be used.
- the coal is easily mixed with the solvent in the preparation unit 30, and the coal can be dissolved more quickly.
- the amount of the solvent to be mixed at the time of forming the slurry is large, the amount of heat for heating the slurry to the elution temperature in the solid-liquid separation unit 40 becomes unnecessarily large, which may increase the manufacturing cost.
- the preparation unit 30 obtains a slurry by mixing the solvent supplied from the solvent supply unit 10 and the coal supplied from the coal supply unit 20.
- the preparation unit 30 has a preparation tank 31.
- the solvent and coal are supplied to the preparation tank 31 through a supply pipe 70.
- the preparation tank 31 mixes the supplied solvent and coal to form a slurry, and stores this slurry.
- the said preparation tank 31 has the stirrer 31a.
- the preparation tank 31 maintains the mixed state of the slurry by holding the mixed slurry while stirring with the stirrer 31a.
- the lower limit of the coal concentration on the basis of anhydrous carbon in the slurry in the preparation tank 31 is preferably 10% by mass, and more preferably 13% by mass.
- the upper limit of the coal concentration is preferably 25% by mass, and more preferably 20% by mass.
- the solvent-soluble component is saturated in the solvent, and thus the elution rate of the solvent-soluble component may be reduced. Therefore, from the solvent supply unit 10, the solvent is supplied in such an amount that the ratio of the amount of coal to the total amount of the coal supplied from the coal supply unit 20 and the solvent supplied from the solvent supply unit 10 falls within the coal concentration range. It is preferable to supply.
- the solid-liquid separation unit 40 elutes the solvent-soluble component from the coal by heating the slurry, and separates the solution in which the coal component is dissolved from the slurry after the elution.
- the solid-liquid separator 40 mainly includes a heater 41 and a solid-liquid separator 42.
- the heater 41 heats the slurry that passes through the solid-liquid separator 42. Therefore, the heater 41 is disposed along the solid-liquid separator 42 outside the solid-liquid separator 42. In order to increase the temperature of the slurry flowing into the solid-liquid separator 42 to a desired temperature, a part of the piping on the upstream side of the solid-liquid separator 42 may be heated by the heater 41. Solvent-soluble components are eluted from coal by this heating.
- the heater 41 is not particularly limited as long as it can heat the slurry passing through the solid-liquid separator 42, and examples thereof include a resistance heater and an induction heating coil. Moreover, you may heat using a heat medium.
- a slurry that passes through the solid-liquid separator 42 can be heated by arranging a heating tube around the solid-liquid separator 42 and supplying a heating medium such as steam or oil to the heating tube.
- the lower limit of the temperature of the slurry after heating by the heater 41 is preferably 300 ° C, more preferably 350 ° C.
- the upper limit of the temperature of the slurry is not particularly limited as long as it is a temperature at which elution is possible, but 420 ° C. is preferable, and 400 ° C. is more preferable.
- the temperature of the slurry is less than the lower limit, the bonds between the molecules constituting the coal cannot be sufficiently weakened, and the elution rate may decrease.
- the temperature of the slurry exceeds the upper limit, the amount of heat for maintaining the temperature of the slurry becomes unnecessarily large, which may increase the manufacturing cost.
- the heater 41 heats the slurry flowing in the solid-liquid separator 42 so as to reach a temperature in the above range while passing through the solid-liquid separator 42.
- the heating time in the solid-liquid separator 42 is not particularly limited, but is, for example, not less than 10 minutes and not more than 120 minutes.
- the temperature of the slurry before passing through the heater 41 is about 100 ° C. Therefore, the heater 41 is preferably one that can heat the solvent at a heating rate of about 3 ° C. or more and 100 ° C. or less per minute.
- the solid-liquid separator 42 allows the slurry mixed in the preparation tank 31 to flow in, separates the solution in which the coal component is dissolved by filtration, and discharges the solid content concentrate containing the solvent-insoluble component.
- the solvent-insoluble component is an elution residue mainly composed of ash and insoluble coal insoluble in the solvent, and also includes the solvent used for elution.
- the solid-liquid separator 42 has a cylindrical shape and is erected so that its central axis is parallel to the vertical direction. As shown in FIG. 2, the solid-liquid separator 42 includes a filter-like cylinder 43, a spiral channel 44 disposed along the inner surface of the filter-like cylinder 43, and the filter-like cylinder 43. And a recovery pipe 47 to be provided.
- the spiral flow path 44 is disposed in a spiral shape in the axial direction between the core material 45 coaxially disposed in the filter-shaped cylindrical body 43 and the inner wall of the filter-shaped cylindrical body 43 and the core material 45.
- the spiral guide 46 is used. The slurry flows from the upper part of the solid-liquid separator 42 and passes through the spiral flow path 44.
- the filter-like cylindrical body 43 constitutes the outer wall of the spiral channel 44 and separates the solution in which the coal component is dissolved from the slurry flowing through the spiral channel 44 by filtration. Then, the separated solution flows out to the outside of the filter-like cylindrical body 43.
- the filter-like cylindrical body 43 is not particularly limited as long as it can separate the solution in which the coal component is dissolved from the slurry, but a mesh-like one using a metal wire, a ceramic wire, or a non-woven fabric can be used.
- the mesh-like thing using a metal wire is preferable.
- the metal wire preferably uses stainless steel (particularly SUS316).
- the lower limit of the mesh nominal opening when using a mesh-like material using a metal wire for the filter-like cylindrical body 43 is preferably 0.5 ⁇ m, and more preferably 1 ⁇ m.
- the upper limit of the nominal mesh opening of the mesh is preferably 30 ⁇ m, and more preferably 20 ⁇ m.
- the filter may be clogged.
- the nominal mesh opening of the mesh exceeds the upper limit, coal components other than the solvent-soluble component may pass through the filter-like cylindrical body 43.
- the core material 45 has a columnar shape and is disposed coaxially in the filter-like cylindrical body 43.
- the core material 45 constitutes the inner wall of the spiral flow path 44.
- the material of the core material 45 is not particularly limited, but metal, ceramic, or the like can be used.
- the spiral guide 46 has a wire shape.
- the spiral guide 46 is disposed between the inner wall of the filter-like cylindrical body 43 and the core member 45 so as to be spirally wound around the core member 45 in the axial direction. It is in contact.
- a spiral channel 44 is formed between the spiral guide 46 and the spiral guide 46 facing the spiral guide 46.
- the material of the spiral guide 46 is not particularly limited, but may be the same as the material of the core material 45, for example. By making the material of the spiral guide 46 the same as the material of the core material 45, the core material 45 and the spiral guide 46 can be integrally formed.
- the average diameter (wire diameter) of the spiral guide 46 coincides with the width of the spiral flow path 44 and is equal to half the difference between the inner diameter of the filter-like cylindrical body 43 and the diameter of the core material 45.
- the minimum interval (spiral interval) between the spiral guide 46 and the opposing spiral guide 46 is substantially constant throughout the spiral flow path 44.
- the lower limit of the linear flow rate of the slurry passing through the spiral flow path 44 is preferably 0.5 m / s, and more preferably 1 m / s. Moreover, as an upper limit of the said linear flow velocity, 20 m / s is preferable and 10 m / s is more preferable. When the linear flow velocity is less than the lower limit, the shearing force in the solid-liquid separator 42 is lowered, and the filter-like cylindrical body 43 may be clogged. On the other hand, when the linear flow velocity exceeds the upper limit, the shear force in the solid-liquid separator 42 becomes too large, and erosion may occur.
- the solution in which the solvent-soluble component dissolved from the slurry while flowing through the spiral flow path 44 and flowing out from the filter-shaped cylindrical body 43 is dissolved is recovered by the recovery tube 47.
- the solid concentrate containing the solvent-insoluble component is discharged from the downstream side of the solid-liquid separator 42 after passing through the spiral flow path 44.
- the material of the collection tube 47 that collects the solution is not particularly limited, and metals, ceramics, and the like can be used.
- the collection tube 47 has a collection hole 48.
- the recovery hole 48 is a hole for taking out a solution in which the coal component is dissolved.
- a pipe connected to the first solvent separation unit 50 is connected to the recovery hole 48.
- the recovery tube 47 may have a recovery hole 48 on the upstream side surface of the spiral flow path 44 as shown in FIG.
- the temperature of the solution is higher on the downstream side.
- the recovery hole 48 on the side surface on the upstream side of the spiral flow path 44, the downstream solution having a high temperature is recovered while moving to the upstream side of the spiral flow path 44. Therefore, heat exchange between the solution and the slurry passing through the spiral flow path 44 is performed, and the heating efficiency of the slurry flowing in the spiral flow path 44 can be improved.
- the lower limit of the internal pressure of the solid-liquid separator 42 is preferably 1.4 MPa, and more preferably 1.7 MPa. Moreover, as an upper limit of the internal pressure of the solid-liquid separator 42, 3 MPa is preferable and 2.3 MPa is more preferable. When the internal pressure of the solid-liquid separator 42 is less than the lower limit, it may be difficult to separate the solution due to vaporization of the solvent. On the other hand, when the internal pressure of the solid-liquid separator 42 exceeds the above upper limit, it is necessary to design the solid-liquid separator 42 with a high pressure resistance, which may increase the manufacturing cost of the solid-liquid separator 42.
- “internal pressure of the solid-liquid separator” is an internal pressure of the recovery pipe 47 of the solid-liquid separator 42.
- the upper limit of the difference (filtration pressure) between the supply pressure of the slurry at the inlet of the spiral flow path 44 and the pressure on the outer surface side of the filter-like cylindrical body 43 is preferably 1 MPa. When the filtration pressure exceeds the upper limit, the filter-like cylindrical body 43 may be deformed.
- the passing time of the slurry in the solid-liquid separator 42 is not particularly limited as long as the time required for the slurry to be heated by the heater 41 and the solvent-soluble component to be eluted into the solvent is ensured. It is possible to be from 120 minutes to 120 minutes. Therefore, the flow rate of the slurry in the solid-liquid separator 42 can be 30 mm / min or more and 100 mm / min or less.
- the ashless coal production apparatus 1 discharges the solution containing the solvent-soluble component from the recovery hole 48 while continuously supplying the slurry into the solid-liquid separation unit 40, and solidifies the solid content concentrate containing the solvent-insoluble component.
- the liquid can be discharged from the downstream side of the liquid separator 42. Thereby, continuous solid-liquid separation processing becomes possible.
- the first solvent separator 50 evaporates and separates the solvent from the solution separated by the solid-liquid separator 40 to obtain ashless coal (HPC).
- a separation method including a general distillation method or an evaporation method (spray drying method or the like) can be used.
- the separated and recovered solvent can be circulated to the upstream piping from the preparation tank 31 and repeatedly used.
- ashless coal substantially free of ash can be obtained from the solution.
- the ashless coal thus obtained has an ash content of 5% by mass or less or 1% by mass or less, contains almost no ash, has no moisture, and exhibits a higher calorific value than, for example, raw coal. Furthermore, ashless coal has a significantly improved softening and melting property, which is a particularly important quality as a raw material for iron-making coke, and exhibits fluidity far superior to, for example, raw material coal. Therefore, ashless coal can be used as a blended coal for coke raw materials.
- the second solvent separator 60 evaporates and separates the solvent from the solid concentrate separated by the solid-liquid separator 40 to obtain by-product coal (RC).
- a general distillation method or evaporation method can be used as in the separation method of the first solvent separation unit 50.
- the separated and recovered solvent can be circulated to a pipe upstream from the preparation tank 31 and repeatedly used.
- by-product charcoal in which solvent-insoluble components including ash and the like are concentrated from the solid concentrate can be obtained.
- By-product charcoal does not show softening and melting properties, but the oxygen-containing functional groups are eliminated. Therefore, this blended coal can also be used as a part of the blended coal of the coke raw material. The coal blend may be discarded without being collected.
- the ashless coal manufacturing method includes a step of supplying a solvent (solvent supply step), a step of supplying coal (coal supply step), a step of preparing a slurry by mixing coal and a solvent (preparation step), In the process of eluting the coal component soluble in the solvent from the coal by heating the slurry (elution process), the process of separating the solution in which the coal component is dissolved from the slurry after the elution (separation process), and the separation process A step of obtaining ashless coal from the separated solution by evaporation of the solvent (ashless coal acquisition step), and a step of obtaining byproduct charcoal by evaporation of the solvent from the solid concentrate separated in the above separation step (subsidiary A raw charcoal acquisition step).
- solvent supply process In the solvent supply step, the solvent is supplied to the preparation unit 30. Specifically, the solvent stored in the solvent tank 11 is pumped to the preparation unit 30 through the supply pipe 70 by the pump 12.
- coal supply process In the coal supply process, the coal stored in the coal supply unit 20 is supplied to the preparation unit 30. At this time, coal is supplied to the preparation unit 30 in a state where the inside of the pressure hopper 22 is pressurized so that the solvent can be smoothly supplied into the supply pipe 70 connected to the preparation unit 30.
- the separation step the solution in which the coal component is dissolved is separated from the slurry after the elution. This step is performed simultaneously and continuously in the temperature rising process of the elution step. Specifically, the solution in which the coal component being heated in the elution step is dissolved is filtered by the filter-like cylindrical body 43 and separated into the recovery tube 47. The separated solution is recovered from the recovery hole 48. In addition, a solid concentrate containing a solvent-insoluble component remains in the filter-like cylindrical body 43 and is discharged from the downstream side of the solid-liquid separator 42.
- ashless coal acquisition process In the ashless coal acquisition step, ashless coal is obtained from the solution separated in the separation step by evaporative separation. Specifically, the solution separated by the solid-liquid separation unit 40 is supplied to the first solvent separation unit 50, and the solvent is evaporated by the first solvent separation unit 50 to separate the solvent and ashless coal.
- by-product coal acquisition process In the by-product charcoal acquisition step, by-product coal is obtained by evaporation separation from the solid content concentrate separated in the separation step. Specifically, the solid concentrate separated by the solid-liquid separation unit 40 is supplied to the second solvent separation unit 60, and the solvent is evaporated by the second solvent separation unit 60 to separate the solvent and by-product coal. .
- the said ashless coal manufacturing method performs the said separation process simultaneously with an elution process, it is hard to produce the polymerization by the temperature rise of a solvent soluble component at a separation process, and can raise the elution amount of the solvent soluble component in an elution process. . Therefore, the ashless coal manufacturing method can increase the extraction rate of ashless coal.
- the said ashless coal manufacturing method performs the said isolation
- the said ashless coal manufacturing method performs the said separation process by a continuous process, since it can further suppress the polymerization by the temperature rise of a solvent soluble component, without retaining a solvent soluble component in a storage tank etc., The extraction rate of ashless coal is further increased.
- the manufacturing method of the said ashless coal can simplify the apparatus used for a separation process by using the said solid-liquid separator 42 at the said separation process, and can reduce the cost of the manufacturing apparatus of ashless coal. Moreover, since the solution which the coal component melt
- the ashless coal production apparatus 2 in FIG. 3 has seven stages of solid-liquid separators 42a to 42g connected in series as the solid-liquid separator 40a.
- the ashless coal production apparatus 2 has the same configuration as the ashless coal production apparatus 1 in FIG. 1 except for the solid-liquid separation unit 40a. Omitted.
- the solid-liquid separator 40a includes seven stages of solid-liquid separators 42a to 42g connected in series, and heaters 41a to 41g corresponding to the respective solid-liquid separators 42a to 42g.
- heaters 41a to 41g As the plurality of heaters 41a to 41g, heaters similar to the heater 41 in the first embodiment can be used.
- the lower limit of the temperature of the slurry after heating by the heater 41a (first stage heater 41a) for heating the first stage solid-liquid separator 42a is preferably 90 ° C, more preferably 95 ° C.
- the upper limit of the temperature of the slurry by the first stage heater 41a is preferably 110 ° C., more preferably 105 ° C.
- the lower limit of the temperature of the slurry after heating by the heater 41g (final stage heater 41g) for heating the final stage solid-liquid separator 42g is preferably 300 ° C, and more preferably 350 ° C.
- the upper limit of the temperature of the slurry by the final stage heater 41g is preferably 420 ° C, and more preferably 400 ° C.
- the heating temperature of the heaters 41a to 41g for heating the solid-liquid separators 42a to 42g in each stage is set for each solid-liquid separator, and is higher on the downstream side.
- the heating temperature of the heaters 41a to 41g in each stage can be set to a temperature higher by 45 ° C. or more and 55 ° C. or less than that of the previous stage, for example.
- the first-stage solid-liquid separator 42a flows the slurry mixed in the preparation tank 31 from the upstream side, separates the solution in which the coal component is dissolved by filtration, and removes the solid content concentrate in which the unnecessary coal component is concentrated in the solvent. Discharge from the downstream side. Further, the solid-liquid separators 42b to 42g from the second stage to the final stage (seventh stage) are the solutions in which the solid component discharged from the previous solid-liquid separator flows from the upstream side and the coal components are dissolved. Is separated by filtration, and a solid content concentrate in which a coal component unnecessary for the solvent is concentrated is discharged from the downstream side. In this way, the seven-stage solid-liquid separators 42a to 42g are connected in series.
- the solution separated by the solid-liquid separators 42a to 42g in each stage flows into the first solvent separation unit 50 and is discharged from the solid-liquid separator 42g in the final stage (seventh stage). Flows into the second solvent separator 60.
- the solid-liquid separators 42a to 42g can have the same configuration and dimensions as the solid-liquid separator 42 of the first embodiment.
- the separation step is performed simultaneously with the elution step.
- the slurry that has flowed into the first-stage solid-liquid separator 42 a is eluted from the coal with a solvent that is soluble in a solvent by the first-stage heater 41 a, and the solution in which the heated coal component is dissolved is filtered through the filter-like cylinder 43. And separated into a collection tube 47. Further, a solid concentrate containing a component that is insoluble in the solvent at the heating temperature of the heater 41a remains in the filter-like cylindrical body 43, and is discharged from the downstream side of the first-stage solid-liquid separator 42a.
- the solid concentrate discharged by the first-stage solid-liquid separator 42a is caused to flow into the second-stage solid-liquid separator 42b.
- the coal component soluble in the solvent is eluted from the coal by the second stage heater 41 b, and the solution in which the coal component being heated is dissolved is filtered by the filter-like cylindrical body 43 and separated into the recovery pipe 47.
- the heating temperature of the second stage heater 41b is higher than the heating temperature of the first stage heater 41a, coal components that are insoluble at the first stage heating temperature but are dissolved at the second stage heating temperature are separated. can do.
- the coal component newly eluted in the second stage can be prevented from being polymerized with the coal component eluted in the first stage.
- the solid concentrate of the previous stage is introduced into the solid-liquid separators 42c to 42g of the third to seventh stages, heated to a temperature higher than that of the previous stage, and the solution in which the coal components are dissolved is sequentially separated.
- the heating temperature of the plurality of solid-liquid separators 42a to 42g is increased toward the downstream side, so that the coal component soluble in the solvent at each heating temperature. Can be sequentially separated, polymerization of solvent-soluble components can be further suppressed, and the extraction rate of ashless coal is further increased.
- the manufacturing method of the ashless coal of this invention is not limited to the said embodiment.
- the solid-liquid separator is erected so that the central axis thereof is parallel to the vertical direction.
- the central axis of the solid-liquid separator is parallel to the vertical direction.
- the solid-liquid separator may be arranged so that its central axis is parallel to the horizontal direction.
- the slurry flows from the upper part of the solid-liquid separator.
- the slurry may flow from the lower part of the solid-liquid separator.
- the recovery pipe has the recovery hole on the side surface on the upstream side of the spiral flow path
- the recovery hole may be provided on another position, for example, the side surface on the downstream side of the spiral flow path. Good.
- the separation step is performed in the temperature raising process of the elution step, but may be performed immediately after the temperature raising step.
- the method performed immediately after the temperature raising process include a method in which the slurry is heated by a preheater or the like immediately before flowing the slurry into the solid-liquid separator.
- the solid-liquid separator may be provided with a warmer that keeps the temperature at a temperature at which the solid-liquid separator is eluted instead of the heater.
- a solid-liquid separator may be used.
- examples of other solid-liquid separators include a centrifugal separator and a separator by gravity sedimentation.
- the separation step may not be performed by continuous processing, and for example, batch processing may be performed in which slurry is stored and separated in a solid-liquid separator. .
- the number of stages connected in series is not limited to seven stages, but two stages or more and six stages or less, or eight stages or more. It may be connected in series.
- a structure which uses one solid-liquid separator and makes heating temperature high toward the downstream of a spiral flow path As a configuration in which the heating temperature is increased toward the downstream side of the spiral channel, for example, a plurality of heaters arranged in series with respect to the spiral channel are used, and the heating temperature of each heater is increased toward the downstream side. It can be realized by controlling as described above.
- the heating temperature of the plurality of solid-liquid separators is increased toward the downstream side, but a solid-liquid separator having the same or lower temperature as the upstream side may be included.
- the solid-liquid separators from the second stage to the last stage let the solid content concentrate discharged from the previous solid-liquid separator flow, but the solvent is added to the solid content concentrate. Then, a solution having a slurry concentration adjusted may be flowed in.
- the preparation unit has the preparation tank.
- the present invention is not limited to this configuration, and the preparation tank may be omitted as long as the solvent and coal can be mixed.
- the preparation tank may be omitted and a line mixer may be provided between the supply pipe and the solid-liquid separation unit.
- the coal supply unit is not limited to the above-described configuration, and any other unit can be used as long as the coal can be smoothly supplied to the supply pipe while preventing the solvent from flowing back from the supply pipe to the coal supply unit. It is good also as a structure of.
- the ashless coal production method can improve the extraction rate of ashless coal by performing the separation step at the same time as the elution step, and is therefore suitable as a method for obtaining ashless coal from coal. Can be used.
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Abstract
Description
図1の無灰炭製造装置1は、溶剤供給部10と、石炭供給部20と、調製部30と、固液分離部40と、第1溶剤分離部50と、第2溶剤分離部60とを主に備える。
上記溶剤供給部10は、溶剤を調製部30へ供給する。溶剤供給部10は、図1に示すように溶剤タンク11及びポンプ12を主に備える。
溶剤タンク11は、石炭供給部20から供給される石炭と混合する溶剤を貯蔵する。石炭と混合する溶剤は、石炭を溶解するものであれば特に限定されないが、例えば石炭由来の2環芳香族化合物が好適に用いられる。この2環芳香族化合物は、基本的な構造が石炭の構造分子と類似していることから石炭との親和性が高く、比較的高い抽出率を得ることができる。石炭由来の2環芳香族化合物としては、例えば石炭を乾留してコークスを製造する際の副生油の蒸留油であるメチルナフタレン油、ナフタレン油等を挙げることができる。
上記ポンプ12は、調製部30へ接続する配管に配設されている。ポンプ12は、溶剤タンク11に貯蔵されている溶剤を供給管70を介して調製部30へ圧送する。
上記石炭供給部20は、石炭を調製部30へ供給する。石炭供給部20は、常圧状態で使用される常圧ホッパ21、常圧状態及び加圧状態で使用される加圧ホッパ22、常圧ホッパ21と加圧ホッパ22とを接続する配管に配設される第1弁23、及び加圧ホッパ22と供給管70とを接続する配管に配設される第2弁24を有している。加圧ホッパ22には、窒素ガス等のガスを供給する加圧ライン25と、このガスを排気する排気ライン26とが接続されている。
上記調製部30は、溶剤供給部10から供給される溶剤と石炭供給部20から供給される石炭との混合によりスラリーを得る。調製部30は、調製槽31を有している。
上記調製槽31には、供給管70を介して上記溶剤及び石炭が供給される。調製槽31は、供給された溶剤及び石炭を混合してスラリーとし、このスラリーを貯留する。また、上記調製槽31は、撹拌機31aを有している。調製槽31は、混合したスラリーを撹拌機31aで撹拌しながら保持することによりスラリーの混合状態を維持する。
固液分離部40は、上記スラリーの加熱により溶剤可溶成分を石炭から溶出させ、上記溶出後のスラリーから石炭成分が溶解した溶液を分離する。固液分離部40は、加熱器41と、固液分離器42とを主に有する。
加熱器41は、固液分離器42内を通過するスラリーを加熱する。従って、加熱器41は、固液分離器42の外側に固液分離器42に沿って配設される。固液分離器42に流入するスラリーの温度を所望の温度に高めておくため、固液分離器42の上流側の配管の一部を加熱器41で加熱してもよい。この加熱により溶剤可溶成分を石炭から溶出する。
固液分離器42は、調製槽31で混合したスラリーを流入させ、石炭成分が溶解した溶液を濾過により分離すると共に、溶剤不溶成分を含む固形分濃縮液を排出する。ここで、溶剤不溶成分とは、主に溶剤に不溶な灰分と不溶石炭とで構成されており、溶出に用いた溶剤も含まれている溶出残分をいう。
第1溶剤分離部50は、固液分離部40で分離された上記溶液から、溶剤を蒸発分離させて無灰炭(HPC)を得る。
第2溶剤分離部60は、固液分離部40で分離された上記固形分濃縮液から、溶剤を蒸発分離させて副生炭(RC)を得る。
当該無灰炭の製造方法は、溶剤を供給する工程(溶剤供給工程)と、石炭を供給する工程(石炭供給工程)と、石炭及び溶剤の混合によりスラリーを調製する工程(調製工程)と、上記スラリーの加熱により溶剤に可溶な石炭成分を石炭から溶出させる工程(溶出工程)と、上記溶出後のスラリーから石炭成分が溶解した溶液を分離する工程(分離工程)と、上記分離工程で分離した溶液から溶剤の蒸発分離により無灰炭を得る工程(無灰炭取得工程)と、上記分離工程で分離された固形分濃縮液からの溶剤の蒸発分離により副生炭を得る工程(副生炭取得工程)とを備える。以下、図1の無灰炭製造装置1を用いる当該無灰炭の製造方法について説明する。
上記溶剤供給工程では、溶剤を調製部30へ供給する。具体的には、溶剤タンク11に貯蔵する溶剤をポンプ12により供給管70を介して調製部30へ圧送する。
上記石炭供給工程では、石炭供給部20に貯蔵する石炭を調製部30へ供給する。このとき、調製部30に接続する供給管70内へスムーズに溶剤を供給できるよう、加圧ホッパ22内を加圧した状態で石炭を調製部30へ供給する。
上記調製工程では、上記溶剤供給工程及び上記石炭供給工程により供給される溶剤及び石炭を調製槽31により混合してスラリーとする。
上記溶出工程では、上記スラリーの加熱により溶剤に可溶な石炭成分を石炭から溶出させる。具体的には、加熱器41により固液分離器42内の螺旋状流路44を通過するスラリーを加熱し、可溶な石炭成分を溶剤に溶出する。
上記分離工程では、上記溶出後のスラリーから石炭成分が溶解した溶液を分離する。この工程は、上記溶出工程の昇温過程で同時かつ連続的に行われる。具体的には、上記溶出工程で加熱中の石炭成分が溶解した溶液をフィルター状円筒体43により濾過し、回収管47に分離する。分離した上記溶液は、回収孔48から回収される。また、フィルター状円筒体43内には溶剤不溶成分を含む固形分濃縮液が残留し、固液分離器42の下流側から排出される。
上記無灰炭取得工程では、上記分離工程で分離された溶液から蒸発分離により無灰炭を得る。具体的には、固液分離部40で分離された溶液を第1溶剤分離部50に供給し、第1溶剤分離部50で溶剤を蒸発させて溶剤と無灰炭とに分離する。
上記副生炭取得工程では、上記分離工程で分離された固形分濃縮液から蒸発分離により副生炭を得る。具体的には、固液分離部40で分離された固形分濃縮液を第2溶剤分離部60に供給し、第2溶剤分離部60で溶剤を蒸発させて溶剤と副生炭とに分離する。
当該無灰炭の製造方法は、上記分離工程を溶出工程と同時に行うので、分離工程で溶剤可溶成分の温度上昇による重合が生じ難く、溶出工程での溶剤可溶成分の溶出量を上昇できる。従って、当該無灰炭の製造方法は、無灰炭の抽出率を高められる。
図3の無灰炭製造装置2は、固液分離部40aとして直列に接続される7段の固液分離器42a~42gを有する。無灰炭製造装置2は、固液分離部40a以外は、上記図1の無灰炭製造装置1と同様の構成であるため、固液分離部40a以外については同一符号を付して説明を省略する。
固液分離部40aは、直列に接続される7段の固液分離器42a~42gと、それぞれの固液分離器42a~42gに対応する加熱器41a~41gを有する。
複数の上記加熱器41a~41gとしては、それぞれ第一実施形態における加熱器41と同様の加熱器を用いることができる。
初段の固液分離器42aは、調製槽31で混合したスラリーを上流側から流入し、石炭成分が溶解した溶液を濾過により分離すると共に、溶剤に不要な石炭成分が濃縮した固形分濃縮液を下流側から排出する。また、2段目から最終段(7段目)の固液分離器42b~42gは、前段の固液分離器により排出された固形分濃縮液を上流側から流入し、石炭成分が溶解した溶液を濾過により分離すると共に、溶剤に不要な石炭成分が濃縮した固形分濃縮液を下流側から排出する。このように7段の固液分離器42a~42gは、直列に接続される。
以下、図3の無灰炭製造装置2を用いる当該無灰炭の製造方法について説明する。なお、溶剤供給工程、石炭供給工程、調製工程、無灰炭取得工程及び副生炭取得工程は、上記図1の無灰炭製造装置1を用いた場合と同様であるため、説明を省略する。
当該無灰炭の製造方法は、分離工程を溶出工程と同時に行う。まず、初段の固液分離器42aに流入したスラリーを初段の加熱器41aにより溶剤に可溶な石炭成分を石炭から溶出させ、加熱中の石炭成分が溶解した溶液をフィルター状円筒体43により濾過し、回収管47に分離する。また、フィルター状円筒体43内には加熱器41aの加熱温度では溶剤不溶である成分を含む固形分濃縮液が残留し、初段の固液分離器42aの下流側から排出される。
図3の無灰炭製造装置2を用いる当該無灰炭の製造方法は、固液分離器42a~42gの加熱温度を固液分離器毎に設定するので、それぞれの固液分離器42a~42gで溶出される成分を変えることができる。このため、無灰炭製造装置2を用いる当該無灰炭の製造方法は、分子量分布の異なる成分、軟化点や溶融性の異なる成分等を容易に分離して得ることができる。
なお、本発明の無灰炭の製造方法は、上記実施形態に限定されるものではない。
本出願は、2015年3月6日出願の日本特許出願(特願2015-044799)に基づくものであり、その内容はここに参照として取り込まれる。
10 溶剤供給部
11 溶剤タンク
12 ポンプ
20 石炭供給部
21 常圧ホッパ
22 加圧ホッパ
23 第1弁
24 第2弁
25 加圧ライン
26 排気ライン
30 調製部
31 調製槽
31a 撹拌機
40、40a 固液分離部
41、41a、41b、41c、41d、41e、41f、41g 加熱器
42、42a、42b、42c、42d、42e、42f、42g 固液分離器
43 フィルター状円筒体
44 螺旋状流路
45 芯材
46 螺旋ガイド
47 回収管
48 回収孔
50 第1溶剤分離部
60 第2溶剤分離部
70 供給管
Claims (8)
- 石炭及び溶剤の混合によりスラリーを調製する工程と、
上記スラリーの加熱により溶剤に可溶な石炭成分を石炭から溶出させる工程と、
上記溶出後のスラリーから石炭成分が溶解した溶液を分離する工程と、
上記分離工程で分離した溶液から溶剤の蒸発分離により無灰炭を得る工程とを備える無灰炭の製造方法であって、
上記分離工程を溶出工程と同時に行うことを特徴とする無灰炭の製造方法。 - 上記分離工程を溶出工程の昇温過程で行う請求項1に記載の無灰炭の製造方法。
- 上記分離工程を連続処理で行う請求項1に記載の無灰炭の製造方法。
- 上記分離工程で、フィルター状円筒体と、このフィルター状円筒体の内側面に沿って配設される螺旋状流路とを備える固液分離器を用いる請求項3に記載の無灰炭の製造方法。
- 上記フィルター状円筒体が、金属線を用いたメッシュ状のものである請求項4に記載の無灰炭の製造方法。
- 上記固液分離器が、上記フィルター状円筒体を内包し、上記溶液を回収する回収管をさらに備え、
上記回収管が、上記螺旋状流路の上流側の側面に上記溶液を排出する回収孔を有する請求項4に記載の無灰炭の製造方法。 - 直列に接続される複数の上記固液分離器を用い、これらの複数の固液分離器の加熱温度を固液分離器毎に設定する請求項4に記載の無灰炭の製造方法。
- 上記複数の固液分離器の加熱温度を下流側ほど高くする請求項7に記載の無灰炭の製造方法。
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CA2973946A CA2973946A1 (en) | 2015-03-06 | 2016-02-19 | Method for manufacturing ashless coal |
US15/552,533 US20180044603A1 (en) | 2015-03-06 | 2016-02-19 | Method for manufacturing ashless coal |
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US (1) | US20180044603A1 (ja) |
JP (1) | JP6426502B2 (ja) |
KR (1) | KR101968032B1 (ja) |
CN (1) | CN107406781B (ja) |
AU (1) | AU2016230455B2 (ja) |
CA (1) | CA2973946A1 (ja) |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53102282A (en) * | 1977-02-17 | 1978-09-06 | Unitika Ltd | Filter for fludized bed |
JPS5474801A (en) * | 1977-11-08 | 1979-06-15 | Bergwerksverband Gmbh | Method and apparatus for solvent extraction of carbonaceous solid material such as coal |
JP2014189739A (ja) * | 2013-03-28 | 2014-10-06 | Kobe Steel Ltd | 無灰炭の製造装置および無灰炭の製造方法 |
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KR100961981B1 (ko) * | 2007-11-22 | 2010-06-08 | 한국에너지기술연구원 | 용매의 열적추출에 의한 청정석탄의 제조 방법 및 그 장치 |
JP5334433B2 (ja) | 2008-03-19 | 2013-11-06 | 株式会社神戸製鋼所 | 無灰炭の製造方法 |
KR101032276B1 (ko) * | 2009-08-28 | 2011-05-06 | 한국에너지기술연구원 | 탈황공정을 포함한 청정석탄의 제조 방법 |
AU2012359380B2 (en) * | 2011-12-28 | 2015-07-02 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Ash-free coal production method |
JP2013249360A (ja) * | 2012-05-31 | 2013-12-12 | Kobe Steel Ltd | 無灰炭の製造方法 |
CN204036897U (zh) * | 2014-06-23 | 2014-12-24 | 苏州美生环保科技有限公司 | 一种固液分离装置 |
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- 2016-02-19 AU AU2016230455A patent/AU2016230455B2/en not_active Ceased
- 2016-02-19 KR KR1020177023650A patent/KR101968032B1/ko active IP Right Grant
- 2016-02-19 CA CA2973946A patent/CA2973946A1/en not_active Abandoned
- 2016-02-19 US US15/552,533 patent/US20180044603A1/en not_active Abandoned
- 2016-02-19 CN CN201680012766.9A patent/CN107406781B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53102282A (en) * | 1977-02-17 | 1978-09-06 | Unitika Ltd | Filter for fludized bed |
JPS5474801A (en) * | 1977-11-08 | 1979-06-15 | Bergwerksverband Gmbh | Method and apparatus for solvent extraction of carbonaceous solid material such as coal |
JP2014189739A (ja) * | 2013-03-28 | 2014-10-06 | Kobe Steel Ltd | 無灰炭の製造装置および無灰炭の製造方法 |
Also Published As
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AU2016230455A1 (en) | 2017-08-31 |
AU2016230455B2 (en) | 2018-02-15 |
CN107406781B (zh) | 2020-09-29 |
JP6426502B2 (ja) | 2018-11-21 |
KR101968032B1 (ko) | 2019-04-10 |
US20180044603A1 (en) | 2018-02-15 |
CN107406781A (zh) | 2017-11-28 |
KR20170108077A (ko) | 2017-09-26 |
JP2016164224A (ja) | 2016-09-08 |
CA2973946A1 (en) | 2016-09-15 |
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