WO2016134557A1 - 转印纸用转印胶及转印纸 - Google Patents

转印纸用转印胶及转印纸 Download PDF

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Publication number
WO2016134557A1
WO2016134557A1 PCT/CN2015/073918 CN2015073918W WO2016134557A1 WO 2016134557 A1 WO2016134557 A1 WO 2016134557A1 CN 2015073918 W CN2015073918 W CN 2015073918W WO 2016134557 A1 WO2016134557 A1 WO 2016134557A1
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parts
transfer
transfer paper
following components
weight
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PCT/CN2015/073918
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English (en)
French (fr)
Inventor
马留生
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苏州帅马金属制品有限公司
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Publication of WO2016134557A1 publication Critical patent/WO2016134557A1/zh

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382—Contact thermal transfer or sublimation processes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

Definitions

  • the invention relates to a transfer adhesive and a transfer paper in the field of home decoration.
  • the transfer adhesive of the existing transfer paper has a poor transfer effect, the pattern is not firmly adhered, and the color is easily discolored, resulting in chromatic aberration.
  • the temperature control technology in the printing process also has higher requirements and is not easy to operate.
  • Transfer adhesive for transfer paper characterized by comprising the following components by weight: 42-47 parts of vinyl acetate, 4-7 parts of polyvinyl alcohol, 3-5 parts of dibutyl phthalate , octanol 0.9-1.1 parts, ammonium persulfate 0.08-0.12 parts, and water 44.8-45.0 parts.
  • the transfer paper transfer adhesive is composed of the following components in parts by weight: vinyl acetate 42-47 parts, polyvinyl alcohol 4-7 parts, dibutyl phthalate 3-5 parts , octanol 0.9-1.1 parts, ammonium persulfate 0.08-0.12 parts, and water 44.8-45.0 parts.
  • the transfer paper transfer adhesive is composed of the following components in parts by weight: 45 parts of vinyl acetate, 5 parts of polyvinyl alcohol, 4 parts of dibutyl phthalate, and 1 part of octanol. 0.1 parts of ammonium persulfate and 44.9 parts of water.
  • a transfer paper comprising a substrate paper, a printed layer coated on the surface of the substrate paper, and a glue layer disposed on an upper surface of the printed layer, the glue layer being composed of the transfer adhesive of any of the above aspects .
  • the printing layer comprises the following components in parts by weight: isobutyl alcohol 48-52 parts, methanol 19-21 parts, disperse dye 19-21 parts, polyvinyl butyral 9 -11 copies.
  • the printed layer is composed of the following components in parts by weight: 48-52 parts of isobutanol, 19-21 parts of methanol, 19-21 parts of disperse dye, and 9-11 parts of polyvinyl butyral.
  • the printed layer is composed of the following components in parts by weight: 50 parts of isobutanol, 20 parts of methanol, 20 parts of disperse dye, and 10 parts of polyvinyl butyral.
  • the transfer adhesive for transfer paper of the present invention is composed of a unique formula, which achieves the purpose of enhancing the firmness of the transfer pattern, avoiding discoloration, and improving the transfer effect.
  • the transfer paper of the transfer adhesive of the present invention if the printing layer formulation of the present invention is also used, the transfer effect can be further enhanced.
  • the transfer adhesive for transfer paper consists of the following components in parts by weight: 45 parts of vinyl acetate, 5 parts of polyvinyl alcohol, 4 parts of dibutyl phthalate, 1 part of octanol, ammonium persulfate 0.1 part, and 44.9 parts of water.
  • the transfer paper comprises a base paper, a printed layer coated on the surface of the base paper, and a glue layer provided on the upper surface of the printed layer, and the adhesive layer is composed of the transfer adhesive of the first embodiment.
  • the printed layer was composed of the following components in terms of parts by weight: 50 parts of isobutanol, 20 parts of methanol, 20 parts of disperse dye, and 10 parts of polyvinyl butyral.
  • Both the transfer adhesive and the transfer paper can be prepared by a common method in the industry.
  • the transfer adhesive is obtained by mixing the respective components.
  • the transfer paper may be firstly mixed with the components of the printing layer and then coated on the surface of the substrate paper, and after the printing layer is dried, the transfer adhesive layer is applied.
  • the transfer adhesive for transfer paper differs from Example 1 in that it consists of the following components in terms of parts by weight: 42 parts of vinyl acetate, 4 parts of polyvinyl alcohol, and 3 parts of dibutyl phthalate. 0.9 parts of octanol, 0.08 parts of ammonium persulfate, and 44.8 parts of water.
  • the transfer paper of the present embodiment 2 was used for the transfer paper, and the printed layer was composed of the following components in terms of parts by weight: 48 parts of isobutanol, 19 parts of methanol, 19 parts of disperse dye, and 9 parts of polyvinyl butyral. .
  • the transfer adhesive for transfer paper differs from Example 1 in that it consists of the following components in terms of parts by weight: 47 parts of vinyl acetate, 7 parts of polyvinyl alcohol, and 5 parts of dibutyl phthalate. 1.1 parts of octanol, 0.12 parts of ammonium persulfate, and 45.0 parts of water.
  • the transfer paper of the present embodiment 3 was used for the transfer paper, and the printed layer was composed of the following components in terms of parts by weight.
  • Composition 52 parts of isobutanol, 21 parts of methanol, 21 parts of disperse dye, and 11 parts of polyvinyl butyral.
  • disperse dye in the present invention can be made of materials commonly used in the industry.

Abstract

一种转印纸用转印胶及使用该转印胶的转印纸。该转印胶包括按重量份计的以下组分：醋酸乙烯酯42-47份，聚乙烯醇4-7份，邻苯二甲酸二丁酯3-5份，辛醇0.9-1.1份，过硫酸铵0.08-0.12份，和水44.8-45.0份。使用该转印胶的转印纸，包括基材纸，涂覆于所述基材纸表面的印刷层，以及设于所述印刷层上表面的转印胶层。通过使用该转印胶，能够加强转印图案牢固度，避免变色，提高转印效果。

Description

转印纸用转印胶及转印纸 技术领域
本发明涉及一种家装领域的转印胶及转印纸。
背景技术
在家装领域，常常需要于板材表面转印图案来达到一定的视觉效果，但是现有转印纸的转印胶，其转印效果较差，图案附着不牢，容易变色，造成色差，对于转印过程中的温控技术也有较高的要求，不易操作。
发明内容
转印纸用转印胶，其特征是，包括按重量份比例计的以下组分：醋酸乙烯酯42-47份，聚乙烯醇4-7份，邻苯二甲酸二丁酯3-5份，辛醇0.9-1.1份，过硫酸铵0.08-0.12份，和水44.8-45.0份。
优选的，转印纸用转印胶，由按重量份比例计的以下组分组成：醋酸乙烯酯42-47份，聚乙烯醇4-7份，邻苯二甲酸二丁酯3-5份，辛醇0.9-1.1份，过硫酸铵0.08-0.12份，和水44.8-45.0份。
优选的，转印纸用转印胶，由按重量份比例计的以下组分组成：醋酸乙烯酯45份，聚乙烯醇5份，邻苯二甲酸二丁酯4份，辛醇1份，过硫酸铵0.1份，和水44.9份。
转印纸，包括基材纸，涂覆于所述基材纸表面的印刷层，以及设于所述印刷层上表面的胶层，所述胶层由上述任一方案所述转印胶构成。
优选的，转印纸中，所述印刷层包括按重量份比例计的以下组分：异丁醇48-52份、甲醇19-21份、分散染料19-21份、聚乙烯缩丁醛9-11份。
优选的，所述印刷层由按重量份比例计的以下组分组成：异丁醇48-52份、甲醇19-21份、分散染料19-21份、聚乙烯缩丁醛9-11份。
优选的，所述印刷层由按重量份比例计的以下组分组成：异丁醇50份、甲醇20份、分散染料20份、聚乙烯缩丁醛10份。
本发明所达到的有益效果：
1.本发明的转印纸用转印胶，以特有的配方组成，达到加强转印图案牢固度，避免变色的目的，提高转印效果。
2.使用本发明转印胶的转印纸，如果也使用本发明的印刷层配方，可进一步增强转印效果。
具体实施方式
下面结合实施例对本发明作进一步描述。
实施例1
转印纸用转印胶，由按重量份比例计的以下组分组成：醋酸乙烯酯45份，聚乙烯醇5份，邻苯二甲酸二丁酯4份，辛醇1份，过硫酸铵0.1份，和水44.9份。
转印纸，包括基材纸，涂覆于基材纸表面的印刷层，以及设于印刷层上表面的胶层，胶层由本实施例1转印胶构成。
其中，印刷层由按重量份比例计的以下组分组成：异丁醇50份、甲醇20份、分散染料20份、聚乙烯缩丁醛10份。
转印胶和转印纸的制备均可采用本行业通用方法，具体的，本实施例中，转印胶由各相应组分混合而得。转印纸可先将印刷层各组分混匀后涂覆在基材纸表面，待印刷层干燥后，再涂覆转印胶层而成。
实施例2
转印纸用转印胶，与实施例1的区别在于，由按重量份比例计的以下组分组成：醋酸乙烯酯42份，聚乙烯醇4份，邻苯二甲酸二丁酯3份，辛醇0.9份，过硫酸铵0.08份，和水44.8份。
转印纸使用本实施例2的转印胶，且印刷层由按重量份比例计的以下组分组成：异丁醇48份、甲醇19份、分散染料19份、聚乙烯缩丁醛9份。
实施例3
转印纸用转印胶，与实施例1的区别在于，由按重量份比例计的以下组分组成：醋酸乙烯酯47份，聚乙烯醇7份，邻苯二甲酸二丁酯5份，辛醇1.1份，过硫酸铵0.12份，和水45.0份。
转印纸使用本实施例3的转印胶，且印刷层由按重量份比例计的以下组分 组成：异丁醇52份、甲醇21份、分散染料21份、聚乙烯缩丁醛11份。
需要说明的是，本发明中分散染料可以采用本行业通用的材料。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和变形，这些改进和变形也应视为本发明的保护范围。

Claims (7)

  1. 转印纸用转印胶，其特征是，包括按重量份比例计的以下组分：醋酸乙烯酯42-47份，聚乙烯醇4-7份，邻苯二甲酸二丁酯3-5份，辛醇0.9-1.1份，过硫酸铵0.08-0.12份，和水44.8-45.0份。
  2. 根据权利要求1所述的一种转印纸用转印胶，其特征是，由按重量份比例计的以下组分组成：醋酸乙烯酯42-47份，聚乙烯醇4-7份，邻苯二甲酸二丁酯3-5份，辛醇0.9-1.1份，过硫酸铵0.08-0.12份，和水44.8-45.0份。
  3. 根据权利要求2所述的一种转印纸用转印胶，其特征是，由按重量份比例计的以下组分组成：醋酸乙烯酯45份，聚乙烯醇5份，邻苯二甲酸二丁酯4份，辛醇1份，过硫酸铵0.1份，和水44.9份。
  4. 转印纸，其特征是，包括基材纸，涂覆于所述基材纸表面的印刷层，以及设于所述印刷层上表面的胶层，所述胶层由权利要求1-3任一项所述转印胶构成。
  5. 根据权利要求4所述的一种转印纸，其特征是，所述印刷层包括按重量份比例计的以下组分：异丁醇48-52份、甲醇19-21份、分散染料19-21份、聚乙烯缩丁醛9-11份。
  6. 根据权利要求5所述的一种转印纸，其特征是，所述印刷层由按重量份比例计的以下组分组成：异丁醇48-52份、甲醇19-21份、分散染料19-21份、聚乙烯缩丁醛9-11份。
  7. 根据权利要求6所述的一种转印纸，其特征是，所述印刷层由按重量份比例计的以下组分组成：异丁醇50份、甲醇20份、分散染料20份、聚乙烯缩丁醛10份。
PCT/CN2015/073918 2015-02-28 2015-03-10 转印纸用转印胶及转印纸 WO2016134557A1 (zh)

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CN102797174A (zh) * 2012-08-28 2012-11-28 无锡赛丽特纺织科技有限公司 一种高色牢度的转移印花的方法
CN103571345A (zh) * 2013-07-03 2014-02-12 天津市天之胶防火材料有限公司 一种强力白乳胶

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Publication number Priority date Publication date Assignee Title
CN2298132Y (zh) * 1997-05-28 1998-11-25 沈阳乐喜印花有限责任公司 新型转印纸
CN102019781A (zh) * 2010-09-16 2011-04-20 东莞市宜彩工艺品制作有限公司 一种水转印贴膜及其工艺
CN102009123A (zh) * 2010-12-14 2011-04-13 青岛顺联集装箱部件制造有限公司 一种汽车横梁消失模的制造方法及其使用方法
CN102029358A (zh) * 2010-12-14 2011-04-27 青岛顺联集装箱部件制造有限公司 一种用于制造集装箱角件的消失模及其制造、使用方法
CN102250564A (zh) * 2010-12-21 2011-11-23 刘青 白乳胶的制作方法
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CN202099966U (zh) * 2011-01-05 2012-01-04 广东盈然木业有限公司 磁性保健板材及其应用的地板
CN102660180A (zh) * 2012-05-05 2012-09-12 林慈泰 一种水性装饰涂料及其涂布方法
CN102797173A (zh) * 2012-08-28 2012-11-28 无锡赛丽特纺织科技有限公司 一种高光照色牢度的转移印花的方法
CN102797174A (zh) * 2012-08-28 2012-11-28 无锡赛丽特纺织科技有限公司 一种高色牢度的转移印花的方法
CN103571345A (zh) * 2013-07-03 2014-02-12 天津市天之胶防火材料有限公司 一种强力白乳胶

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