WO2016080109A1 - Composition de shampooing - Google Patents

Composition de shampooing Download PDF

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Publication number
WO2016080109A1
WO2016080109A1 PCT/JP2015/078755 JP2015078755W WO2016080109A1 WO 2016080109 A1 WO2016080109 A1 WO 2016080109A1 JP 2015078755 W JP2015078755 W JP 2015078755W WO 2016080109 A1 WO2016080109 A1 WO 2016080109A1
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mass
content
shampoo composition
pearl pigment
component
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PCT/JP2015/078755
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English (en)
Japanese (ja)
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幸治 二宮
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ライオン株式会社
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust

Definitions

  • the present invention relates to a shampoo composition.
  • the shampoo composition can easily give a high-class feeling.
  • the pearl pigment has a large specific gravity, and the dispersion stability with time deteriorates. As a result, there is a problem that it tends to impair the sense of quality.
  • the ethylene glycol distearate when the ethylene glycol distearate is contained, the ethylene glycol distearate exhibits a pearly feeling due to an optical effect due to the precipitation of fine crystals, and therefore is inferior to the pearl pigment in terms of a high-quality feeling.
  • the fine crystals tend to have poor temporal stability at high temperatures, and when they are placed in a high temperature place such as a bathroom, they settle and deteriorate the sense of quality.
  • the present invention makes it a subject to solve the said various problems in the past and to achieve the following objectives. That is, the present invention has good detergency, foaming speed, foam creaminess, smoothness of hair upon rinsing, and softness of hair after drying, high quality, high temperature storage stability, and high temperature.
  • An object of the present invention is to provide a shampoo composition having excellent dispersion stability of a pearl pigment during storage.
  • the (B) cationized guar gum and the (B) cationized guar gum by containing (B) cationized guar gum and (C1) ethylene glycol distearate,
  • (C1) ethylene glycol distearate interacts, the (C1) ethylene glycol distearate which is an organic powder contained in a fine crystalline state does not settle even when stored at high temperature,
  • (C2) pearl pigment which is an inorganic powder, is added to give a high-class feeling, the precipitation of (C2) pearl pigment is prevented, high-temperature storage stability, and dispersion of pearl pigment during high-temperature storage It is excellent in stability and can give a high-class feeling by a pearling agent comprising (C1) ethylene glycol distearate and (C2) pearl pigment. It was found that kill.
  • This invention is based on the said knowledge by this inventor, and as a means for solving the said subject, it is as follows. That is, ⁇ 1> (A) (A1) at least one selected from polyoxyethylene alkyl ether sulfates and (A2) alkyl sulfates, (B) a cationized guar gum, and (C) (C1) ethylene glycol distearate and (C2) a pearling agent comprising a pearl pigment, The mass ratio (C1 / C2) of the content (% by mass) of (C1) ethylene glycol distearate and the content (% by mass) of (C2) pearl pigment is 0.2 to 30.
  • a shampoo composition characterized.
  • the content of at least one selected from (A) (A1) polyoxyethylene alkyl ether sulfate and (A2) alkyl sulfate is 10% by mass to 25% by mass
  • (B) the content of cationized guar gum is 0.1% by mass to 2.8% by mass
  • (C1) The content of ethylene glycol distearate is 1.2% by mass to 3.5% by mass
  • (C2) The content of the pearl pigment is 0.2% by mass to 3.9% by mass
  • the mass ratio (C1 / C2) of the content (mass%) of (C1) ethylene glycol distearate and the content (mass%) of (C2) pearl pigment is 0.3 to 7.5. It is a shampoo composition as described in said ⁇ 1>.
  • the component (A) includes both (A1) polyoxyethylene alkyl ether sulfate and (A2) alkyl sulfate,
  • the mass ratio (A1 / A2) of the content (mass%) of the (A1) polyoxyethylene alkyl ether sulfate and the content (mass%) of the (A2) alkyl sulfuric acid is 0.1 to 12.
  • ⁇ 4> (C2) The shampoo composition according to any one of ⁇ 1> to ⁇ 3>, wherein the pearl pigment has a number average particle diameter of 15 ⁇ m to 80 ⁇ m.
  • the conventional problems can be solved and the object can be achieved.
  • Detergency, speed of foaming, creaminess of foam, smoothness of hair during rinsing, and hair after drying It is possible to provide a shampoo composition having good softness and excellent in high-grade feeling, high-temperature storage stability, and excellent pearl pigment dispersion stability during high-temperature storage.
  • FIG. 1 is a photograph showing the appearance of a shampoo composition containing Example (C1) ethylene glycol distearate and (C2) pearl pigment.
  • FIG. 2 is a photograph showing the appearance of a shampoo composition containing (C1) ethylene glycol distearate, which is Comparative Example 4.
  • the shampoo composition of the present invention comprises (A) (A1) polyoxyethylene alkyl ether sulfate, and (A2) at least one selected from alkyl sulfate, (B) cationized guar gum, and (C) (C1 ) A gallic acid glycoside comprising a pearlizing agent comprising ethylene glycol distearate and (C2) a pearl pigment, and further comprising (D) a diglucosyl gallic acid skeleton, and (E) nonion It contains a functional surfactant and other components.
  • component (A) (A1) polyoxyethylene alkyl ether sulfate and (A2) alkyl sulfate one type may be used alone, or two or more types may be used in combination. Among these, it is preferable to use the polyoxyethylene alkyl ether sulfate of the component (A1) and the alkyl sulfate of the component (A2) in combination from the creamy properties of the foam and the smoothness of the hair during rinsing. .
  • Polyoxyethylene alkyl ether sulfate >> The number of carbon atoms in the alkyl group moiety of the polyoxyethylene alkyl ether sulfate of component (A1) is preferably 10-18, more preferably 12-16.
  • the average added mole number of ethylene oxide of the polyoxyethylene alkyl ether sulfate of the component (A1) is preferably 1 to 5 and more preferably 2 to 3 from the viewpoints of detergency and smoothness of hair during rinsing. .
  • a salt of the polyoxyethylene alkyl ether sulfate of said (A1) component there is no restriction
  • the polyoxyethylene alkyl ether sulfate as the component (A1) is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include compounds represented by the following general formula (a1).
  • R 1 represents an alkyl group, and the carbon number of the alkyl group is preferably 10 to 18, preferably 12 to 16, in terms of detergency and smoothness of hair during rinsing. Is more preferable.
  • M 1 is an alkali metal, ammonium, or alkanolamine, and among these, alkali metal and ammonium are preferable from the viewpoint of detergency and smoothness of hair during rinsing. Sodium and ammonium are more preferable, and ammonium is particularly preferable.
  • m represents the average number of moles of ethylene oxide added, and m is preferably 1 to 5 and preferably 2 to 3 in terms of detergency and smoothness of the hair during rinsing. More preferred.
  • polyoxyethylene alkyl ether sulfate of the component (A1) examples include polyoxyethylene (1-5) capryl ether sulfate, polyoxyethylene (1-5) lauryl ether sulfate, polyoxyethylene (1 to 5) Myristyl ether sulfate, polyoxyethylene (1-5) palmityl ether sulfate, polyoxyethylene (1-5) stearyl ether sulfate, and the like. These may be used alone or in combination of two or more.
  • polyoxyethylene (3) ammonium lauryl ether sulfate and polyoxyethylene (2) sodium lauryl ether sulfate are more preferable from the viewpoint of detergency and smoothness of hair during rinsing, and polyoxyethylene (3) lauryl.
  • Ether ammonium sulfate is particularly preferred.
  • the numerical value in said () shows the average addition mole number of ethylene oxide.
  • polyoxyethylene alkyl ether sulfate of (A1) a commercially available product may be used, or an appropriately synthesized product may be used.
  • commercially available products include, for example, trade name: Texapon ALES 70 (polyoxyethylene (3) ammonium lauryl ether sulfate, manufactured by BASF), trade name: Sinoline SPE-1250 (polyoxyethylene (2) sodium lauryl ether sulfate, new Nippon Rika Co., Ltd.). These may be used alone or in combination of two or more.
  • Texapon ALES 70 polyoxyethylene (3) ammonium lauryl ether sulfate, manufactured by BASF
  • the numerical value in said () shows the average addition mole number of ethylene oxide.
  • the content of the polyoxyethylene alkyl ether sulfate (A1) is preferably 2% by mass to 18% by mass with respect to the total amount of the shampoo composition from the viewpoint of detergency and smoothness of the hair during rinsing. 6 mass% to 18 mass% is more preferable. When the content is less than 2% by mass, the detergency may be insufficient, and when the content exceeds 18% by mass, the smoothness of the hair during rinsing may be insufficient.
  • Alkyl sulfate >> The alkyl sulfate salt of the component (A2) is contained in order to improve detergency.
  • the number of carbon atoms in the alkyl group portion of the alkyl sulfate of the component (A2) is preferably 10 to 18, and more preferably 12 to 16, from the viewpoints of detergency and smoothness of hair during rinsing.
  • the alkyl sulfate of the component (A2) is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include compounds represented by the following general formula (a2).
  • R 2 represents an alkyl group, and the carbon number of the alkyl group is preferably 10 to 18, preferably 12 to 16, in terms of detergency and smoothness of hair during rinsing. Is more preferable.
  • M 2 is an alkali metal, ammonium, or alkanolamine, and among these, alkali metal and ammonium are preferable from the viewpoint of detergency and smoothness of hair during rinsing. Sodium and ammonium are more preferable, and ammonium is particularly preferable.
  • alkyl sulfate of the component (A2) examples include capryl sulfate, lauryl sulfate, myristyl sulfate, palmityl sulfate, and stearyl sulfate. These may be used alone or in combination of two or more. Among these, lauryl sulfate is preferable, ammonium lauryl sulfate and sodium lauryl sulfate are more preferable, and ammonium lauryl sulfate is particularly preferable in terms of detergency and smoothness of hair during rinsing.
  • alkyl sulfate (A2) a commercially available product may be used, or an appropriately synthesized product may be used.
  • the commercial products include trade name: Texapon ALS 70 (ammonium lauryl sulfate, manufactured by BASF), trade name: Texapon K12 (sodium lauryl sulfate, manufactured by BASF), and the like. These may be used alone or in combination of two or more.
  • the trade name: Texapon ALS 70 (ammonium lauryl sulfate, manufactured by BASF) is preferable from the viewpoint of detergency and smoothness of hair during rinsing.
  • the content of the alkyl sulfate (A2) is preferably 1% by mass to 18% by mass, and preferably 3% by mass with respect to the total amount of the shampoo composition from the viewpoints of detergency and smoothness of the hair during rinsing. More preferably, it is ⁇ 16% by mass. If the content is less than 1% by mass, the detergency may be insufficient, and if it exceeds 18% by mass, the smoothness of the hair during rinsing may be insufficient.
  • the total content of the content (mass%) of the polyoxyethylene alkyl ether sulfate (A1) and the content (mass%) of the alkyl sulfate (A2) is as follows. From the viewpoints of creaminess of foam, smoothness of hair during rinsing, storage stability at high temperature, and dispersion stability of pearl pigments during storage at high temperature, 5% by mass to 30% by mass with respect to the total amount of the shampoo composition. 10 mass% to 25 mass% is more preferable.
  • the content is less than 5% by mass, detergency, speed of foaming, creaminess of foam, smoothness of hair during rinsing, high-temperature storage stability, and dispersion stability of pearl pigments during high-temperature storage
  • the amount exceeds 30% by mass, the high temperature storage stability and the dispersion stability of the pearl pigment during high temperature storage may be insufficient.
  • the mass ratio (A1 / A2) between the content (mass%) of the polyoxyethylene alkyl ether sulfate (A1) and the content (mass%) of the alkyl sulfate (A2) is: From the viewpoint of creaminess and smoothness of the hair at the time of rinsing, 0.1 to 12 is preferable, and 0.5 to 6 is more preferable. When the mass ratio (A1 / A2) is less than 0.1, the smoothness of the hair at the time of rinsing may be insufficient, and when it exceeds 12, the creamy property of the foam may be insufficient. is there.
  • ⁇ (B) Cationized guar gum> The cationized guar gum of the component (B) is contained in order to improve the smoothness of the hair during rinsing and the dispersion stability of the pearl pigment during high temperature storage.
  • the cationized guar gum of the component (B) may also be called guar hydroxypropyltrimonium chloride, O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum, or the like.
  • the cationized guar gum of the said (B) component means what added the cationic functional group to the guar gum, and the cationization degree of a cationized guar gum changes with the addition degree of the said cationic functional group.
  • the cationic functional group is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a structure derived from a cationizing agent such as glycidyltrimethylammonium chloride.
  • the nitrogen content of the cationized guar gum as the component (B) is preferably 1% by mass to 1.8% by mass from the viewpoint of the smoothness of the hair during rinsing and the dispersion stability of the pearl pigment during high temperature storage. 1.20% by mass to 1.45% by mass is more preferable.
  • the nitrogen content is less than 1% by mass, the smoothness of the hair at the time of rinsing may be insufficient.
  • it exceeds 1.8% by mass the dispersion stability of the pearl pigment during high-temperature storage is increased. It may be insufficient.
  • Examples of the method for measuring the nitrogen content include the Kjeldahl method.
  • the Kjeldahl method can be measured, for example, by decomposing the cationized guar gum of the component (B) with sulfuric acid to give ammonium sulfate and quantifying the ammonia.
  • Qi-drug raw material standard 2006 “Pharmaceutical Daily)” general test method 44. It can be measured with reference to the method described in the nitrogen determination method.
  • the weight average molecular weight of the cationized guar gum as the component (B) is preferably 100,000 to 3,000,000 from the viewpoint of the smoothness of the hair during rinsing and the dispersion stability of the pearl pigment during high temperature storage. 200,000 to 1,500,000 are more preferred. When the weight average molecular weight is less than 100,000, the dispersion stability of the pearl pigment during high-temperature storage may be insufficient, and when it exceeds 3,000,000, the smoothness of the hair during rinsing may occur. It may be insufficient.
  • the weight average molecular weight can be measured using GPC-MALLS. A sample solution diluted with a mobile phase having a pure cationized guar gum concentration of about 1,000 ppm (0.1% by mass) is obtained from TSK.
  • a wavelength of about 633 nm can be measured with a multi-angle light scattering detector using a 0.5 mol / L sodium perchlorate solution as a mobile phase.
  • polyethylene glycol having a known molecular weight can be used as a standard product.
  • the cationized guar gum of the component (B) can be synthesized, for example, by reacting guar gum with a cationizing agent such as glycidyltrimethylammonium chloride.
  • a cationizing agent such as glycidyltrimethylammonium chloride.
  • Examples of the cationized guar gum of the component (B) include compounds represented by the following general formula (b1).
  • R ⁇ 3 > shows each independently the group represented by a hydrogen atom or the following general formula (b2), and has group represented by the following general formula (b2) at least. N is 4 to 5,000.
  • X represents a halogen atom
  • examples of the halogen atom include a chlorine atom, a bromine atom, a fluorine atom, and an iodine atom.
  • a chlorine atom is preferable.
  • a commercially available product can be used as the cationized guar gum of the component (B).
  • the commercially available product include trade name: JAGUAR C-14S (nitrogen content: 1.41% by mass), trade name: JAGUAR series such as JAGUAR Excel (nitrogen content: 1.46% by mass), trade name: JAGUAR C-500 (nitrogen content: 1.33% by mass), JAGUAR C17 (nitrogen content: 1.75% by mass)
  • the nitrogen content of the cationized guar gum is more preferably in the range of 1.20% by mass to 1.45% by mass.
  • the content of the cationized guar gum of the component (B) is based on the total amount of the shampoo composition from the viewpoint of smoothness of hair during rinsing, high temperature storage stability, and dispersion stability of pearl pigments during high temperature storage. 0.08% by mass to 4% by mass is preferable, and 0.1% by mass to 2.8% by mass is more preferable. When the content is less than 0.08% by mass, the smoothness of the hair at the time of rinsing and the dispersion stability of the pearl pigment at the time of high-temperature storage may be insufficient, and when it exceeds 4% by mass, The high temperature storage stability and the dispersion stability of the pearl pigment during high temperature storage may be insufficient.
  • the pearlizing agent of the component (C) is contained in order to improve the sense of quality.
  • the pearlizing agent of the component (C) is composed of, for example, (C1) ethylene glycol distearate and (C2) pearl pigment from the viewpoint of high quality.
  • ethylene glycol distearate ethylene glycol distearate
  • the ethylene glycol distearate as the component (C1) is contained in order to improve the smoothness of the hair during rinsing, the dispersion stability of the pearl pigment during high temperature storage, and the high-class feeling.
  • the ethylene glycol distearate of the component (C1) can impart a high-class feeling to the shampoo composition by being dispersed as crystals in the shampoo composition.
  • ethylene glycol distearate of the component (C1) a commercially available product can be used.
  • the commercially available product include a trade name: Genapol PMS (manufactured by Clariant Japan Ltd.); BASF); trade name: Tegin G1100, trade name: Tegin EGS (above, Evonik) and the like, for example, ethylene glycol distearate (melting point: 58 ° C.
  • an ethylene glycol distearate dispersion containing a crystal of a pearlizing agent composed of ethylene glycol distearate by cooling the mixture dispersed and mixed in the surfactant aqueous solution held above to a melting point or lower.
  • a high-class feeling is imparted.
  • the volume-based median diameter of the ethylene glycol distearate of the component (C1) is 0.5 ⁇ m to 0.5 ⁇ m in view of smoothness of hair during rinsing, high temperature storage stability, and pearl pigment dispersion stability during high temperature storage. 8 ⁇ m is preferable, and 1 ⁇ m to 5 ⁇ m is more preferable. When the volume-based median diameter is less than 0.5 ⁇ m, the smoothness of hair during rinsing, high-temperature storage stability, and dispersion stability of pearl pigments during high-temperature storage may be insufficient, and 8 ⁇ m If it exceeds, smoothness of the hair during rinsing may be insufficient.
  • the volume-based median diameter of the ethylene glycol distearate (C1) component can be obtained by measuring crystals in the ethylene glycol distearate dispersion.
  • volume based median diameter obtained as D 50, obtains the volume-based particle size distribution as cumulative% of particle size scale, means a particle size cumulative percent of obtained particle size distribution curve is 50%, 50% Also called particle size.
  • the volume-based median diameter is set in the shampoo composition by using, for example, a laser diffraction particle size distribution measuring device (trade name: SALD-7000, manufactured by Shimadzu Corporation) and a relative refractive index with respect to water of 1.08.
  • SALD-7000 laser diffraction particle size distribution measuring device
  • the volume-based median diameter can be calculated by measuring the particle size distribution of the concentrated (C1) component-containing dispersion prepared in advance before the addition.
  • the content of ethylene glycol distearate as the component (C1) is shampoo composition from the viewpoint of smoothness of hair at the time of rinsing, high-quality feeling, high temperature storage stability, and pearl pigment dispersion stability at high temperature storage.
  • 0.5 mass% to 5 mass% is preferable with respect to the total amount, and 1.2 mass% to 3.5 mass% is more preferable.
  • the content is less than 0.5% by mass, the smoothness of the hair at the time of rinsing, a high-class feeling, and the pearl pigment dispersion stability at high temperature storage may be insufficient, and when the content exceeds 5% by mass. , Storage stability at high temperature, and dispersion stability of the pearl pigment during storage at high temperature may be insufficient.
  • the pearl pigment as the component (C2) is contained in order to improve the high-quality feeling and high-temperature storage stability.
  • the pearl pigment of the component (C2) has a glittering radiant shine due to light reflected at the boundary between the inner layer having a high refractive index and the inner layer having a low refractive index and the outer layer surrounding the inner layer. Creates a pearly luster that gives off a high-class feel.
  • the pearl pigment of component (C2) include mica titanium, titanium oxide-coated talc, fish scale foil, colored mica titanium, and sericite (mica).
  • the pearl pigment may be subjected to various surface treatments. These may be used alone or in combination of two or more. Among these, mica and titanium mica are preferable, and titanium mica is more preferable from the viewpoint of high-grade feeling and high-temperature storage stability.
  • the “number average particle size” of the pearl pigment of the component (C2) is preferably 15 ⁇ m to 80 ⁇ m, more preferably 40 ⁇ m to 60 ⁇ m, from the viewpoint of high quality and high temperature storage stability.
  • the “number average particle size” can be measured using, for example, a laser diffraction particle size distribution analyzer (trade name: Malvern Mastersizer S, manufactured by Malvern).
  • the specific gravity of the pearl pigment as the component (C2) is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 1 to 5, more preferably 2 to 3 from the viewpoint of high-temperature storage stability. . When the specific gravity is less than 1 or exceeds 5, the high-temperature storage stability may be insufficient.
  • the specific gravity can be measured with reference to, for example, “Standard Test Method for Evaluating Mica Pigments” (ASTM D-716-86).
  • pearl pigment of the component (C2) commercially available products may be used, or those appropriately synthesized may be used.
  • Commercially available products of titanium mica include trade name: Timica Silver Sparkle 5000 (“number average particle diameter”: 34 ⁇ m, specific gravity: 2.8), trade name: Timica Sparkle 110P (“number average particle diameter”: 41 ⁇ m, specific gravity).
  • Examples of commercially available products of the mica include, for example, trade name: Rona Flair Silk Mica (“number average particle diameter”: 21 ⁇ m, specific gravity: 2.6, manufactured by MERCK), trade name: Sanshin Sericite S200 (“number average particle” Diameter ”: 15 ⁇ m, specific gravity: 2.6, manufactured by Sanshin Mining Co., Ltd.) and the like. These may be used alone or in combination of two or more. Among these, from the viewpoint of high-grade feeling and high-temperature storage stability, the “number average particle diameter” is a more preferable range of 40 ⁇ m to 60 ⁇ m, and the specific gravity of the pearl pigment is a more preferable range of 2 to 3, and mica titanium.
  • the product name: Timica Sparkle 110P, and the product name: Timica Extra Large Sparkle 110S are particularly preferable.
  • the content of the pearl pigment as the component (C2) is preferably 0.1% by mass to 5% by mass and preferably 0.2% by mass with respect to the total amount of the shampoo composition from the viewpoints of high quality and high temperature storage stability. % To 3.9% by mass is more preferable. When the content is less than 0.1% by mass or exceeds 5% by mass, the high-quality feeling and high-temperature storage stability may be insufficient.
  • the content of the pearlizing agent of the component (C) is preferably 1.5% by mass to 7% by mass with respect to the total amount of the shampoo composition from the viewpoint of high-quality feeling and high-temperature storage stability, and is 1.7%. A mass% to 5.1 mass% is more preferred. When the content is less than 1.5% by mass, the sense of quality may be insufficient, and when it exceeds 7% by mass, the high-temperature storage stability may be insufficient.
  • FIG. 1 is a photograph showing the appearance of the shampoo composition containing Example (C1) ethylene glycol distearate and (C2) pearl pigment.
  • Example (C1) ethylene glycol distearate and (C2) pearl pigment.
  • the ethylene glycol distearate which is the component (C1) which is a pearlizing agent, and the pearl pigment which is the component (C2) shines brightly. I understand that.
  • FIG. 2 is a photograph showing the appearance of a shampoo composition containing ethylene glycol distearate, which is Comparative Example 4. As shown in FIG. 2, it can be seen that in the shampoo composition 10, ethylene glycol distearate, which is a pearling agent, has a pearly luster but does not have a glittering shine.
  • Mass ratio (C1 / C2) As the mass ratio (C1 / C2) of the content (% by mass) of (C1) ethylene glycol distearate and the content (% by mass) of (C2) pearl pigment, the smoothness of the hair during rinsing, From the viewpoint of high-grade feeling, high-temperature storage stability, and dispersion stability of the pearl pigment during high-temperature storage, it is from 0.2 to 30, and preferably from 0.3 to 7.5. When the mass ratio (C1 / C2) is less than 0.2, the high-quality feeling, high-temperature storage stability, and dispersion stability of the pearl pigment during high-temperature storage are insufficient. The smoothness of hair, high-quality feeling, high-temperature storage stability, and the dispersion stability of pearl pigments during high-temperature storage are insufficient.
  • the mass ratio (C1 / C2) is a value obtained by rounding off the second decimal place.
  • the mass ratio [C2 / (B + C1)] is 0.03 to from the viewpoint of the smoothness of the hair during rinsing, high quality, high temperature storage stability, and dispersion stability of the pearl pigment during high temperature storage. 5 is preferable, and 0.1 to 2.6 is more preferable.
  • the mass ratio [C2 / (B + C1)] is less than 0.03, the high-class feeling may be insufficient. When it exceeds 5, the hair smoothness during rinsing, high-temperature storage stability, and high temperature The dispersion stability of the pearl pigment during storage may be insufficient.
  • a gallic acid glycoside having a diglucosyl gallic acid skeleton >
  • the (D) component gallic acid glycoside having a diglucosyl gallic acid skeleton is contained to improve the softness of the hair after drying.
  • Examples of the (D) component gallic acid glycoside having a diglucosyl gallic acid skeleton include gallic acid methyl ester-3-glucoside, gallic acid methyl ester-4-glucoside, gallic acid propyl ester-3-glucoside, and gallic acid.
  • diglycosides such as gallic acid-3,4-diglucoside and gallic acid-3,5-diglucoside are preferable, and gallic acid-3,4-diglucoside is preferred. More preferred.
  • the gallic acid glycoside having a diglucosyl gallic acid skeleton as the component (D) a commercially available product may be used, or an appropriately synthesized product may be used.
  • brand name: DGA made by Mitsui Chemicals, Inc.
  • the content of the gallic acid glycoside having a diglucosyl gallic acid skeleton as the component (D) is 0. 0 with respect to the total amount of the shampoo composition in terms of hair softness after drying and high-temperature storage stability. 01 mass% to 7.5 mass% is preferable, and 0.05 mass% to 3 mass% is more preferable. When the content is less than 0.01% by mass, the softness of the hair after drying may be insufficient, and when it exceeds 7.5% by mass, the high-temperature storage stability may be insufficient. There is.
  • Nonionic surfactant As the component (E) is contained in order to improve the speed of foaming.
  • Examples of the (E) component nonionic surfactant include polyglyceryl laurate and polyglyceryl myristate.
  • Examples of the polyglyceryl laurate include polyglyceryl-10 laurate, pentaglyceryl monolaurate, polyglyceryl laurate-6, decaglycerol monolaurate, and the like. These may be used alone or in combination of two or more. Among these, from the viewpoint of rapid foaming, polyglyceryl-10 laurate and polyglyceryl-6 laurate are preferable, and polyglyceryl-10 laurate is more preferable.
  • polyglyceryl myristate examples include polyglyceryl-10 myristate, pentaglyceryl monomyristate, polyglyceryl-6 myristate, decaglyceryl monomyristate, and the like. These may be used alone or in combination of two or more. Among these, from the viewpoint of rapid foaming, polyglyceryl-10 myristate and polyglyceryl-6 myristate are preferable, and polyglyceryl-10 myristate is more preferable.
  • polyglyceryl-10 laurate, polyglyceryl-6 laurate, polyglyceryl-10 myristate, and polyglyceryl-6 myristate are cosmetic ingredient display names defined by the Japan Cosmetic Industry Association.
  • nonionic surfactant of the component (E) a commercially available product may be used, or an appropriately synthesized product may be used.
  • the commercially available product include polyglyceryl laurate, trade name: Sunsoft M-12J (polyglyceryl-10 laurate), trade name: Sunsoft M-12JW (polyglyceryl-10 laurate), and more Product name: NIKKOL Decaglyn 1-L (polyglyceryl laurate-10), product name: NIKKOL Hexaglyn 1-L (polyglyceryl laurate-6) (above, manufactured by Nikko Chemicals Corporation); monolauric acid As decaglycerin, trade name: Sunsoft Q-125-C (decaglycerin monolaurate, manufactured by Taiyo Chemical Co., Ltd.), and as polyglyceryl myristate, trade name: Sunsoft Q-14S (polyglyceryl-10 myristate, Taiyo Chemical Co., Ltd.) Name: NI
  • the content of the nonionic surfactant as the component (E) is preferably 0.1% by mass to 10% by mass with respect to the total amount of the shampoo composition from the viewpoint of quick foaming and high-temperature storage stability. 0.3 mass% to 8 mass% is more preferable.
  • the content is less than 0.1% by mass, the foaming speed may be insufficient in an environment where there is a lot of sebum.
  • the content exceeds 10% by mass, the high-temperature storage stability becomes insufficient. Sometimes.
  • the shampoo composition of the present invention can contain other components used in ordinary shampoo compositions.
  • the other component contained in the shampoo composition of this invention is not limited to the said other component.
  • oil component examples include castor oil, olive oil, cacao oil, hydrogenated palm oil, coconut oil, coconut oil, tree wax, jojoba oil, grape seed oil, avocado oil and the like, or their ester compounds; mink oil, Animal fats such as egg yolk oil; waxes such as beeswax, whale wax, lanolin, hydrogenated lanolin, carnauba wax, candelilla wax; hydrocarbons such as liquid paraffin, squalane, microcrystalline wax, ceresin wax, paraffin wax, petroleum jelly Natural and synthetic fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid, isostearic acid, behenic acid; glycerol tri-2-ethylhexanoate, 2-ethylhexyl stearate, butyl stearate, isopropyl myristate, Isopro palmitate Le, octyldodecyl myristate, octyld
  • alcohols examples include natural and synthetic higher alcohols such as cetyl alcohol, oleyl alcohol, stearyl alcohol, hexyl decanol, octyl decanol, and lauryl alcohol.
  • humectant examples include 1,3-butanediol, isoprene glycol, 1,2-pentanediol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, diethylene glycol monoalkyl ether, polyethylene glycol (average molecular weight of 190 to 1,650), polypropylene glycol, polyethylene glycol / polypropylene glycol, hydrogenated castor oil (30EO), glycerin, diglycerin, triglycerin, polyglycerin, sorbitol and the like.
  • thickener examples include natural polymers such as sodium alginate, xanthan gum, aluminum silicate, quince seed extract, tragacanth gum and starch; semi-synthetic polymers such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose and soluble starch.
  • Molecules Synthetic polymer compounds such as carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, methacryloylethylbetaine / methacrylic acid ester copolymer, and the like.
  • preservative examples include benzoate, sorbate, dehydroacetate, p-hydroxybenzoate, 2,4,4′-trichloro-2′-hydroxydiphenyl ether, 3,4,4′-trichlorocarbani Lido, benzalkonium chloride, hinokitiol, resorcin, methylchloroisothiazolinone / methylisothiazolinone solution (trade name: Caisson CG, manufactured by Rohm and Haas Japan), salicylic acid, pentanediol, phenoxyethanol, ethanol, etc. Can be mentioned.
  • antioxidant examples include dibutylhydroxytoluene, butylhydroxyanisole, ascorbic acid and the like.
  • examples of the chelating agent include disodium ethylenediaminetetraacetate, ethylenediaminetetraacetate, hexametaphosphate, and gluconic acid.
  • Examples of the pH adjuster include sodium hydroxide, potassium hydroxide, citric acid, sodium citrate, succinic acid, triethanolamine, aqueous ammonia, triisopropanolamine, phosphoric acid, glycolic acid and the like.
  • Examples of the ultraviolet absorbing / scattering agent include 2-hydroxy-4-methoxybenzophenone, octyldimethylparaaminobenzoate, ethylhexylparamethoxycynamate, titanium oxide, kaolin, and talc.
  • Examples of the vitamins include vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, vitamin U, carnitine, ferulic acid, ⁇ -oryzanol, ⁇ -lipoic acid, Examples include orotic acid and derivatives thereof.
  • amino acids examples include glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine, and derivatives thereof. It is done.
  • fragrance and the fragrance composition examples include the fragrance ingredients described in paragraphs [0021] to [0035] of JP-A-2003-300811, and the fragrance described in paragraph [0050] of JP-A-2003-300811. Solvents for use.
  • the content of the fragrance composition is preferably 0.005% by mass to 40% by mass and more preferably 0.01% by mass to 10% by mass with respect to the total amount of the shampoo composition.
  • the said (A) component, the said (B) component, the said (C1) component, and the said The shampoo composition can be produced by adding the component (C2) and, if necessary, the component (D), the component (E), and the other components, and stirring and mixing them.
  • the said (C1) component, the (C1) component containing dispersion liquid is prepared beforehand with the preparation method of the following (C1) component containing dispersion liquid, and the content of the said (C1) component in the said shampoo composition is a place. It is preferable to add so that it may become fixed quantity.
  • the mixture is passed through an external heat exchanger, and the cooled mixture is cooled back to the dispersion mixing tank to cool the inside of the dispersion mixing tank to below the melting point of the ethylene glycol distearate.
  • a crystalline product of ethylene glycol distearate is precipitated, and a (C1) component-containing dispersion liquid in which the final concentration of (C1) ethylene glycol distearate becomes a predetermined concentration can be obtained.
  • a high-class feeling can be imparted by adding the (C1) component-containing dispersion so that the concentration of the (C1) component in the shampoo composition is a predetermined concentration.
  • the viscosity of the shampoo composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 5 Pa ⁇ s to 10 Pa ⁇ s at 30 ° C.
  • the viscosity adjusting agent is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include hexylene glycol and ethanol. If the viscosity is less than 5 Pa ⁇ s or exceeds 10 Pa ⁇ s, the speed of foaming may be insufficient.
  • As the viscosity for example, using a viscometer (BM type viscometer, manufactured by Tokyo Keiki Co., Ltd.) Using 4 rotors, measurement can be performed at 30 rpm for 20 seconds.
  • the pH of the shampoo composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 4 to 7 at 30 ° C.
  • the pH can be measured at 30 ° C. using, for example, a pH meter (trade name: HM-30G, manufactured by Toa DKK Corporation).
  • the pH adjuster is not particularly limited and may be appropriately selected depending on the intended purpose. For example, citric acid, sodium citrate, succinic acid, sulfuric acid, 2-amino-2-methyl-1-propanol, mono Ethanolamine or a salt thereof is exemplified.
  • the shampoo composition can be used by filling a container.
  • the container is not particularly limited and can be appropriately selected according to the purpose.
  • aluminum laminate tube, EVAL tube, aluminum tube, glass-deposited plastic tube tube, mechanical or differential pressure dispenser container, squeeze Examples include containers, laminate film containers, dropper containers, bottle containers, and pump-type containers.
  • the material of the laminate film include polyethylene, polyethylene terephthalate, polyester, biaxially stretched polypropylene, unstretched polypropylene, polyacrylonitrile, synthetic resin such as ethylene-vinyl acetate copolymer, paper, aluminum vapor-deposited plastic, and the like. .
  • the laminate film generally has two or more layers, and generally 2 to 5 layers are preferred in consideration of strength, flexibility, weather resistance and the like.
  • the material of the bottle is appropriately selected from, for example, polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile / styrene resin, ABS resin, polyamide resin, and glass.
  • the structure of the container is preferably a single layer or a layer structure of two or more layers.
  • a shampoo for example, a shampoo, a dandruff removal shampoo, a rinse-in shampoo (conditioning shampoo), a body shampoo, a hand soap, a facial cleanser Shampoos and body shampoos are preferable from the viewpoint of imparting a high-class feeling.
  • a shampoo it can be used not only for human hair but also for animal hair such as pets.
  • shampoo compositions of Examples 1 to 61 and Comparative Examples 1 to 10 were prepared by a conventional method. Specifically, (A1) component and / or (A2) component, (B) component, (C1) component, (C2) component, and common components other than purified water in purified water, 4. Add component (D) and component (E), adjust the viscosity to 30 Pa at 30 ° C. for 30 minutes at 25 ° C., 7 Pa ⁇ s, and adjust the pH to 30 ° C. with citric acid and sodium citrate. 8 to obtain a shampoo composition.
  • the (C1) component containing dispersion liquid was prepared with the following method previously, and it added so that content of the said (C1) component in the said shampoo composition might become predetermined amount. That is, when 1.5 mass% of the component (C1) was contained in the shampoo composition, 33.3 mass% of the dispersion containing 4.5 mass% of the component (C1) was added to the purified water.
  • the (C1) component-containing dispersion contains the component (A1) and / or the component (A2), but the content (% by mass) described in the examples and comparative examples is the above (C1 )
  • the pH was measured after 30 minutes at 30 ° C. using a pH meter (HM-30R, manufactured by Toa DKK Corporation).
  • component-containing dispersion- As a manufacturing method of the said (C1) component containing dispersion liquid, it can manufacture by the method as described in international publication 2014/0734562. Specifically, at least one of (A1) polyoxyethylene lauryl ether ammonium sulfate 10 mass% to 22 mass% and (A2) ammonium lauryl sulfate 5 mass% to 11 mass% and purified water are dissolved in the dispersion mixing tank. (C1) ethylene glycol distearate melted at 80 ° C. was gradually added with stirring to the aqueous solution, and the mixture was kept at 80 ° C. The mixture was uniformly dispersed and mixed at 0 ° C. to obtain a mixture.
  • the mixture is passed through an external heat exchanger, and the inside of the dispersion and mixing tank is cooled to 35 ° C. by circulating cooling to return the cooled mixture to the dispersion and mixing tank (C1) ethylene glycol distear Crystals of a rate are precipitated to obtain a (C1) component-containing dispersion (ethylene glycol distearate 1 to 5) having a final concentration of (C1) ethylene glycol distearate of 4.5 to 10% by mass. It was.
  • the agitation was dispersed and mixed using a three-one motor (trade name: HEIDEN FBL1200, manufactured by Shinto Kagaku Co., Ltd.), a four-row inclined paddle and a homomixer (Primix Co., Ltd.).
  • the volume-based median diameter of the component (C1) was measured using a laser diffraction particle size distribution analyzer (trade name: SALD-7000, manufactured by Shimadzu Corporation) in the dispersion containing the component (C1).
  • Detergency was evaluated based on the following evaluation criteria by the number of respondents who answered “they have detergency” among the 20 female specialized panels.
  • “having detergency” means that the scalp and hair sebum is removed and the skin feels clean.
  • Creamy property of foam was evaluated based on the following evaluation criteria by the number of respondents who answered “foam is creamy” among 20 women-specialized panels.
  • bubbles are creamy means that 6 mL of each shampoo composition is taken, the palms are rubbed together so that the palms of both hands are reciprocated, and the appearance of the bubbles is visually observed when both hands are reciprocated 10 times. It means that the bubbles are fine and soft when observed.
  • the pearl pigment is dispersed more in the lower layer than the upper layer of the glass vial container, and slightly on the bottom.
  • X The pearl pigment is considerably dispersed in the lower layer compared to the upper layer of the glass vial container, and is also settled at the bottom.
  • the shampoo composition of the present invention has good detergency, quick foaming, foam creaminess, smoothness of hair when rinsed, and softness of hair after drying.
  • it since it is excellent in dispersion stability of pearl pigments during high-temperature storage, it can be suitably used for, for example, shampoo, dandruff shampoo, rinse-in shampoo (conditioning shampoo), body shampoo, hand soap, and facial cleanser.
  • shampoo it can be suitably used for animal hair such as pets as well as human hair.

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Abstract

L'invention concerne une composition de shampooing comprenant a) au moins un composant choisi parmi (A1) un sulfate d'éther alkylique de polyoxyéthylène et (A2) un sulfate d'alkyle, (B) de la gomme de guar cationique et (C) un agent nacrant comprenant (C1) du distéarate d'éthylèneglycol et (C2) un pigment nacré, dans laquelle le rapport de la quantité (% en masse) (C1) de distéarate d'éthylèneglycol à celle du pigment nacré (C2) (c'est-à-dire, C1/C2) est compris entre 0,2 et 30 en masse.
PCT/JP2015/078755 2014-11-21 2015-10-09 Composition de shampooing WO2016080109A1 (fr)

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CN110960433A (zh) * 2019-11-12 2020-04-07 澳宝化妆品（惠州）有限公司 一种含长条状结晶的组合物及其应用

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JPH04243812A (ja) * 1990-06-20 1992-08-31 Unilever Nv シャンプー組成物
JPH0543431A (ja) * 1991-08-16 1993-02-23 Kao Corp 化粧料
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JPH10195498A (ja) * 1996-12-27 1998-07-28 Lion Corp 液体洗浄剤組成物
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JP2005504822A (ja) * 2001-10-03 2005-02-17 ザ プロクター アンド ギャンブル カンパニー カチオン性ポリマー及び粒子を含有するシャンプー
JP2005089571A (ja) * 2003-09-16 2005-04-07 Shiseido Co Ltd 洗浄料組成物
WO2014046300A2 (fr) * 2012-09-20 2014-03-27 Kao Corporation Composition nettoyante pour la peau ou les cheveux
WO2014073456A1 (fr) * 2012-11-08 2014-05-15 ライオン株式会社 Compositon de shampooing
WO2014148245A1 (fr) * 2013-03-21 2014-09-25 ライオン株式会社 Composition de shampooing

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Publication number Priority date Publication date Assignee Title
JPS5260810A (en) * 1975-11-14 1977-05-19 Lion Corp Detergent composition
JPH04243812A (ja) * 1990-06-20 1992-08-31 Unilever Nv シャンプー組成物
JPH0543431A (ja) * 1991-08-16 1993-02-23 Kao Corp 化粧料
JPH07501077A (ja) * 1991-11-22 1995-02-02 リチャードソン、ビックス、インコーポレーテッド 組合せパーソナルクレンジング及びモイスチャライジング組成物
JPH10195498A (ja) * 1996-12-27 1998-07-28 Lion Corp 液体洗浄剤組成物
JP2003530446A (ja) * 2000-04-11 2003-10-14 ノベオン・アイピー・ホールディングズ・コーポレイション 安定した水性界面活性剤組成物
JP2005504822A (ja) * 2001-10-03 2005-02-17 ザ プロクター アンド ギャンブル カンパニー カチオン性ポリマー及び粒子を含有するシャンプー
JP2005089571A (ja) * 2003-09-16 2005-04-07 Shiseido Co Ltd 洗浄料組成物
WO2014046300A2 (fr) * 2012-09-20 2014-03-27 Kao Corporation Composition nettoyante pour la peau ou les cheveux
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Publication number Priority date Publication date Assignee Title
CN110960433A (zh) * 2019-11-12 2020-04-07 澳宝化妆品（惠州）有限公司 一种含长条状结晶的组合物及其应用
CN110960433B (zh) * 2019-11-12 2023-03-03 澳宝化妆品（惠州）有限公司 一种含长条状结晶的组合物及其应用

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