WO2016026321A1 - Batterie rechargeable à ions d'aluminium et procédé de préparation associé - Google Patents

Batterie rechargeable à ions d'aluminium et procédé de préparation associé Download PDF

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Publication number
WO2016026321A1
WO2016026321A1 PCT/CN2015/076947 CN2015076947W WO2016026321A1 WO 2016026321 A1 WO2016026321 A1 WO 2016026321A1 CN 2015076947 W CN2015076947 W CN 2015076947W WO 2016026321 A1 WO2016026321 A1 WO 2016026321A1
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WO
WIPO (PCT)
Prior art keywords
aluminum ion
ion battery
aluminum
positive electrode
rechargeable
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PCT/CN2015/076947
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English (en)
Chinese (zh)
Inventor
焦树强
孙浩博
王伟
王俊香
刘勇
余智静
Original Assignee
北京科技大学
北京金吕能源科技有限公司
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Application filed by 北京科技大学, 北京金吕能源科技有限公司 filed Critical 北京科技大学
Publication of WO2016026321A1 publication Critical patent/WO2016026321A1/fr

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/56—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

La présente invention se rapporte au domaine du recyclage de source d'énergie. L'invention concerne une batterie rechargeable à ions d'aluminium et son procédé de préparation. La batterie comprend une anode, une cathode, un électrolyte liquide d'ions d'aluminium et un matériau de diaphragme; l'anode est un matériau de carbone à structure de graphite; la cathode est d'aluminium à haut degré de pureté; et l'électrolyte liquide d'ions d'aluminium est un mélange de chlorure d'aluminium anhydre et d'un composé 3-méthylimidazole à un rapport molaire de 1,1:1 à 1,6:1. Le procédé de préparation de la batterie consiste à : usiner le matériau de carbone à structure de graphite du matériau d'anode sous forme de feuilles, à l'aide d'une feuille métallique inerte comme un collecteur de courant pour fixer le matériau d'anode, et recouvrir le matériau d'anode avec le diaphragme pour servir d'anode; une feuille découpée d'aluminium à haut degré de pureté sert de cathode après son nettoyage; et formuler l'électrolyte liquide d'ions d'aluminium comprenant des ions Al3+ se déplaçant librement. L'anode, la cathode et l'électrolyte liquide d'ions d'aluminium sont assemblés dans une batterie dans une boîte à gants. La batterie présente une capacité élevée et une bonne stabilité de circulation, et peut être utilisée dans les domaines de l'électronique, des communications et des véhicules électriques.
PCT/CN2015/076947 2014-08-22 2015-04-20 Batterie rechargeable à ions d'aluminium et procédé de préparation associé WO2016026321A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410419495.1A CN104241596A (zh) 2014-08-22 2014-08-22 一种可充电铝离子电池及其制备方法
CN201410419495.1 2014-08-22

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WO2016026321A1 true WO2016026321A1 (fr) 2016-02-25

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CN (1) CN104241596A (fr)
WO (1) WO2016026321A1 (fr)

Cited By (3)

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CN109923725A (zh) * 2016-11-08 2019-06-21 Eth苏黎世公司 铝-离子液体-石墨-电池
CN114196996A (zh) * 2021-11-30 2022-03-18 淄博火炬能源有限责任公司 LiCu/石墨复合极片及离子液体电沉积制备LiCu/石墨复合极片的方法
CN115832424A (zh) * 2023-02-16 2023-03-21 北京科技大学 适用于有机正极的铝离子电池电解质、电池及其制备工艺

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US9843070B2 (en) 2014-02-28 2017-12-12 The Board Of Trustees Of The Leland Stanford Junior University Ultra-fast rechargeable metal-ion battery
CN104241596A (zh) * 2014-08-22 2014-12-24 北京科技大学 一种可充电铝离子电池及其制备方法
CN104810544A (zh) * 2015-04-20 2015-07-29 北京科技大学 一种可充电铝离子电池及其制备方法
CN104868179B (zh) * 2015-05-13 2017-11-17 北京科技大学 一种可充放电铝离子熔盐电池及其制备方法
CN104993130A (zh) * 2015-05-25 2015-10-21 石嘴山市天和创润新材料科技有限公司 一种非水溶液铝离子二次电池及其制备方法
CN104952629B (zh) * 2015-06-08 2019-05-10 深圳博磊达新能源科技有限公司 一种铝电容电池及其制备方法
CN106548878B (zh) * 2015-09-22 2018-08-10 南京绿索电子科技有限公司 一种使用离子液体电解液的超级电容器
CN106887636A (zh) * 2015-12-15 2017-06-23 中国科学院苏州纳米技术与纳米仿生研究所 基于导电聚合物正极的铝离子电池及其制备方法
CN105810947B (zh) * 2016-04-29 2019-02-12 深圳博磊达新能源科技有限公司 一种铝离子电池正极材料、电极及铝离子电池
CN105826543A (zh) * 2016-05-10 2016-08-03 哈尔滨工业大学（威海） 铝-聚苯胺二次电池
KR102043331B1 (ko) 2016-05-17 2019-11-11 인더스트리얼 테크놀로지 리서치 인스티튜트 금속 이온 배터리
CN106450269B (zh) * 2016-11-11 2019-10-11 中国科学院金属研究所 一种铝离子二次电池正极材料、制备方法及其应用
CN106602062A (zh) * 2016-12-08 2017-04-26 浙江大学 一种石墨烯气凝胶正极材料的制备方法及其在铝离子电池中的应用
TWI611618B (zh) 2016-12-16 2018-01-11 財團法人工業技術研究院 金屬離子電池
US10483542B2 (en) * 2017-02-16 2019-11-19 Global Graphene Group, Inc. Aluminum secondary battery having an exfoliated graphite-based high-capacity cathode and manufacturing method
US10629948B2 (en) * 2017-03-05 2020-04-21 Global Graphene Group, Inc. Aluminum secondary battery having a high-capacity and high-rate capable cathode and manufacturing method
CN108376795B (zh) * 2018-04-04 2020-08-18 天津大学 一种无枝晶、高倍率的铝离子电池
CN108615933A (zh) * 2018-05-16 2018-10-02 东莞市振华新能源科技有限公司 一种基于新型正极材料的铝离子电池及其制备方法
CN109301245B (zh) * 2018-09-18 2022-02-25 上海交通大学 铝石墨双离子电池及其制备方法
CN109378444A (zh) * 2018-10-15 2019-02-22 杭州高烯科技有限公司 一种铝离子电池及其正极的制备方法
CN109786725A (zh) * 2019-03-25 2019-05-21 江苏大学 独立自支撑正极材料及其制备方法以及铝离子电池及其制备方法
CN110289444A (zh) * 2019-06-24 2019-09-27 北京科技大学 一种采用液态金属镓为负极的铝离子电池
CN110492178B (zh) * 2019-08-23 2021-01-15 山东大学 一种铝离子电池电解液、电池及应用
CN112164828A (zh) * 2020-09-22 2021-01-01 同济大学 一种纤维状柔性铝离子电池及其制备方法
CN112635760A (zh) * 2020-12-22 2021-04-09 同济大学 一种可充电的富勒烯-铝离子安全电池
CN116169280A (zh) * 2023-03-07 2023-05-26 北京工业大学 用于铝离子电池正极的高熵化合物及其制备方法

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Publication number Priority date Publication date Assignee Title
CN109923725A (zh) * 2016-11-08 2019-06-21 Eth苏黎世公司 铝-离子液体-石墨-电池
CN114196996A (zh) * 2021-11-30 2022-03-18 淄博火炬能源有限责任公司 LiCu/石墨复合极片及离子液体电沉积制备LiCu/石墨复合极片的方法
CN114196996B (zh) * 2021-11-30 2023-09-15 淄博火炬能源有限责任公司 LiCu/石墨复合极片及离子液体电沉积制备LiCu/石墨复合极片的方法
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CN115832424B (zh) * 2023-02-16 2023-04-11 北京科技大学 适用于有机正极的铝离子电池电解质、电池及其制备工艺

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