WO2016002594A1 - Composition pesticide et son application - Google Patents

Composition pesticide et son application Download PDF

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Publication number
WO2016002594A1
WO2016002594A1 PCT/JP2015/068167 JP2015068167W WO2016002594A1 WO 2016002594 A1 WO2016002594 A1 WO 2016002594A1 JP 2015068167 W JP2015068167 W JP 2015068167W WO 2016002594 A1 WO2016002594 A1 WO 2016002594A1
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group
halogen atoms
atoms
atom
optionally
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PCT/JP2015/068167
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English (en)
Japanese (ja)
Inventor
赤山　敦夫
将司 亀崎
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住友化学株式会社
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Publication of WO2016002594A1 publication Critical patent/WO2016002594A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06—Coating or dressing seed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A01N43/52—1,3-Diazoles; Hydrogenated 1,3-diazoles condensed with carbocyclic rings, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Definitions

  • the present invention relates to a pest control composition and a pest control method.
  • Patent Documents 1 to 3 Conventionally, many compounds are known as active ingredients of pest control compositions (see, for example, Patent Documents 1 to 3 and Non-Patent Document 1).
  • An object of the present invention is to provide a pest control composition having an excellent control effect against pests.
  • the present inventors have found that the pest control composition contains a compound represented by the following formula (1) or the following formula (2): Has been found to have excellent control effects against pests. That is, the present invention is as follows.
  • a 1a represents —NR 8a —, an oxygen atom or a sulfur atom
  • a 2a represents a nitrogen atom or ⁇ CR 9a —
  • a 3a represents a nitrogen atom or ⁇ CR 10a —
  • R 1a has a C1-C6 chain hydrocarbon group which may have one or more atoms or groups selected from group X a or one or more atoms or groups selected from group Y a
  • R 2a , R 3a , R 4a and R 5a are the same or different and are one or more atoms selected from a C1-C6 chain hydrocarbon group which may have one or more halogen atoms and group Za or a phenyl group which may have a group
  • one or more atoms may be 5-membered heterocyclic group having a group selected from the group Z a, or one or more atoms selected from the group Z a
  • R 6a and R 7a do not represent a hydrogen atom at the same time, and in —S (O) m R 11a , when m is 1 or 2, R 11a does not represent a hydrogen atom.
  • a 1a is —NH— or —N (CH 3 ) —,
  • a 2a and A 3a are ⁇ CH—,
  • R 1a is a methyl group,
  • R 2a , R 3a , R 4a and R 5a are hydrogen atoms.
  • R 6a and R 7a are the same or different and may have one or more atoms or groups selected from group X a C6 chain hydrocarbon group, one or more atoms or phenyl group which may have a group selected from the group Z, may have one or more atoms or groups selected from the group Z a 5 A membered heterocyclic group, a 6-membered heterocyclic group optionally having one or more atoms or groups selected from the group Za, —OR 11a , —S (O) m R 11a , —S (O) 2 NR 11a R 12a, -NR 11a R 12a, -NR 11a CO 2 R 12a, -NR 11a C (O) R 12a, -CO 2 H, -C (O) R 11a, cyano group, nitro It represents group, a bromine atom, an iodine atom, a -SF 5 or a hydrogen atom.
  • Group X a a C1-C6 alkoxy group which may have one or more halogen atoms, a C2-C6 alkenyloxy group which may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms.
  • C2-C6 alkoxycarbonyl group which may have one, C3-C6 cycloalkyl group which may have one or more halogen atoms, cyano group, hydroxy And the group consisting of halogen atoms.
  • Group Y a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens
  • Group Z a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens C1-C6 alkylsulfanyl group which may have an atom, C1-C6 alkylsulfinyl group which may have one or more halogen atoms, C1-C6 which may have one or more halogen atoms C6 alkylsulfonyl group, C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, C2-C6 alkoxycarbonyl group optionally having one or more halogen atoms, one or more halogens A C1-C6 alkylamino group optionally having one atom, a C2-C8 dialkylamino group optionally having one or more halogen atoms, a halogen atom, a cyano group, and Group consisting of
  • Group W a a C1-C6 alkoxy group that may have one or more halogen atoms, a C2-C6 alkenyloxy group that may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms.
  • a pest control composition comprising one or more compounds selected from Group A to Group D.
  • Formula (2) [Where: A 1b represents —NR 7b —, an oxygen atom or a sulfur atom, A 2b represents a nitrogen atom or ⁇ CR 8b —, A 3b represents a nitrogen atom or ⁇ CR 9b —, R 1b has a C1-C6 chain hydrocarbon group which may have one or more atoms or groups selected from group X b or one or more atoms or groups selected from group Y b.
  • R 2b , R 3b and R 4b are each a C1-C6 chain hydrocarbon group optionally having one or more atoms or groups selected from group Xb , and one or more atoms or groups selected from group Z
  • R 10b when m is 1 or 2, R 10b does not represent a hydrogen atom.
  • Group X b a C1-C6 alkoxy group which may have one or more halogen atoms, a C2-C6 alkenyloxy group which may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms.
  • a C2-C6 alkoxycarbonyl group which may have one, one or more halogen atoms or one or more C1-C3 alkyl groups which may have one or more C1-C3 alkyl groups.
  • Group Y b C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens A group consisting of a C2-C6 alkenyloxy group optionally having one atom, a C2-C6 alkynyloxy group optionally having one or more halogen atoms, and a halogen atom.
  • Group Z b C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens C1-C6 alkylsulfanyl group which may have an atom, C1-C6 alkylsulfinyl group which may have one or more halogen atoms, C1-C6 which may have one or more halogen atoms C6 alkylsulfonyl group, C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, C2-C6 alkoxycarbonyl group optionally having one or more halogen atoms, one or more halogens A C1-C6 alkylamino group optionally having one atom, a C2-C8 dialkylamino group optionally having one or more halogen atoms, a halogen atom, a cyano group, and Group consisting of
  • Group W b a C1-C6 alkoxy group that may have one or more halogen atoms, a C2-C6 alkenyloxy group that may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C2-C6 alkyl which may have one or more halogen atoms
  • a pest control composition comprising one or more compounds selected from Group A to Group D.
  • the pest control composition according to [1] wherein the content ratio of the compound to one or more compounds selected from Group D is 100: 1 to 1: 100 by weight.
  • the ratio of the content of the present compound (2) or a salt of the present compound (2) and one or more compounds selected from group A to group D is 100: 1 to 1: 100 by weight.
  • a method for controlling pests comprising a step of applying an effective amount of the pest control composition according to any one of [1] to [4] to a plant or soil for cultivating the plant.
  • the pest control method according to [4] wherein the plant is a seed, a bulb, or a seedling.
  • the pest control method according to [4] wherein the plant is corn, soybean, cotton, wheat, sugar beet, rape or rice.
  • pests can be controlled.
  • the pest control composition of the present invention comprises the present compound (1) or the present compound (2) (hereinafter, the present compound (1) and the present compound (2) may be referred to as the present compound), groups A to A. And one or more compounds selected from Group D.
  • Me represents a methyl group
  • Et represents an ethyl group
  • Pr represents a propyl group
  • iPr represents an isopropyl group
  • tBu represents a tert-butyl group
  • CyPr represents cyclopropyl
  • CyBu represents a cyclobutyl group
  • 2-F-Ph represents a 2-fluorophenyl group
  • 3-F-Ph represents a 3-fluorophenyl group
  • 4-F-Ph represents a 4-fluorophenyl group
  • 2-CF 3 -Ph represents a 2-trifluoromethylphenyl group
  • 3-CF 3 -Ph represents a 3-trifluoromethylphenyl group
  • 4-CF 3 -Ph represents 4-trifluoromethylphenyl
  • 2-Cl-Ph represents a 2-chlorophenyl group
  • 3-Cl-Ph represents a 3-chlorophenyl group
  • 4-Cl-Ph represents a 4-chlorophenyl group
  • 2- O 2 -Ph represents a 2-nitrophenyl group
  • 3-NO 2 -Ph represents a 3-nitrophenyl group
  • 2-CN-Ph represents 2-cyanophenyl group
  • Me represents a methyl group
  • Et represents an ethyl group
  • Pr represents a propyl group
  • iPr represents an isopropyl group
  • Bu represents a butyl group
  • tBu represents a tert-butyl group.
  • CycPr represents a cyclopropyl group
  • CycBu represents a cyclobutyl group
  • CycPen represents a cyclopentyl group
  • CycHex represents a cyclohexyl group
  • Ph represents a phenyl group
  • 2-CF 3 -Ph 2-trifluoro Represents a methylphenyl group
  • 3-CF 3 -Ph represents a 3-trifluoromethylphenyl group
  • 4-CF 3 -Ph represents a 4-trifluoromethylphenyl group
  • 3-CF 3 -triazolyl represents 3-trimethyl.
  • the symbol in a formula represents the combination as described in the following [Table 3A].
  • this compound having the combination of substituents described in [Table 3A] is represented by the numbers described in [Table 3A].
  • the compound of No. 1004 in [Table 3A] is referred to as the present compound 1004.
  • R 1 and R 2 in the formula represent the combinations described in [Table 3B] below.
  • this compound having the combination of substituents described in [Table 3B] is represented by the numbers described in [Table 3B].
  • the compound of No. 1072 in [Table 3B] is referred to as the present compound 1072.
  • a compound represented by formula (2C) A 1 , R 1 and R 2 in the formula represent the combinations described in [Table 3C] below.
  • this compound having the combination of substituents described in [Table 3C] is represented by the numbers described in [Table 3C].
  • the compound of No. 1078 in [Table 3C] is referred to as the present compound 1078.
  • R 1 and R 2 in the formula represent the combinations described in [Table 3D] below.
  • this compound having the combination of substituents described in [Table 3D] is represented by the numbers described in [Table 3D].
  • the compound of number 1090 in [Table 3D] is referred to as the present compound 1090.
  • the present compound may take the form of a salt, and can be produced, for example, by mixing with an acid such as hydrochloric acid, sulfuric acid, methanesulfonic acid and the like.
  • the present compound or a salt of the present compound can be formulated alone or mixed with other pesticidal active ingredients and applied by the methods described herein.
  • the agricultural chemical formulation containing this compound or the salt of this compound and the agricultural chemical formulation containing another agricultural chemical active ingredient can be mixed, and can be applied by the method as described in this specification.
  • the formulated present compound or a salt of the present compound and the formulated other pesticidal active ingredient can also be applied at regular intervals without mixing.
  • the present compound or a salt of the present compound can be formulated into a crystalline or amorphous form and applied by the method described herein.
  • the composition of the present invention may be a simple mixture of the present compound or a salt of the present compound and one or more compounds selected from Group A to Group D. Usually, the present compound or a salt of the present compound and Group A are used. To a mixture with one or more compounds selected from Group D, a solid carrier, a liquid carrier, a surfactant, etc. are mixed, and if necessary, formulation adjuvants such as a fixing agent, a dispersing agent, a stabilizer are added.
  • Wettable powder granular wettable powder, aqueous solvent, flowable, granule, fine granule, powder, dry flowable, emulsion, aqueous liquid, oil, microcapsule and the like.
  • These preparations usually contain 0.1 to 99% by weight, preferably 0.2 to 90% by weight in total of the present compound or a salt of the present compound and one or more compounds selected from Group A to Group D. To do.
  • These preparations may be a combination of two or more preparations composed of a single component, a preparation composed of two or more kinds of components, or a combination thereof.
  • the preparations when two or more kinds of preparations are combined and applied to plants or soil where plants are cultivated, the preparations may be applied separately, or the preparations may be mixed and applied. Moreover, the dosage form of each formulation may be the same or different. When each preparation is applied separately, it may be applied after a certain period, such as several hours to several days. The order of applying each formulation may be arbitrary.
  • the content ratio of the present compound or a salt of the present compound and one or more compounds selected from Group A to Group D in the composition of the present invention is not particularly limited, but the present compound or the salt of the present compound
  • the total amount of one or more compounds selected from Group A to Group D with respect to 1,000 parts by weight is usually 1 to 100,000 parts by weight, preferably 10 to 10,000 parts by weight.
  • the solid support examples include clays (for example, kaolin, diatomaceous earth, synthetic hydrous silicon oxide, wax clay, bentonite, acid clay), talc, and other inorganic minerals (for example, sericite, quartz powder, sulfur powder, Activated carbon, calcium carbonate, hydrated silica), pumice, calcite, marine stone, dolomite, olivine, pyroxene, feldspar, feldspar, alumina, vermiculite, perlite, etc.), elastomer, plastic, ceramics, metal, sawdust, corn
  • the liquid carrier examples include water, alcohols (for example, methanol, ethanol), and ketones (for example, acetone, methyl ethyl ketone).
  • Aromatic hydrocarbons eg, benzene, toluene, xylene, ethylben Methyl naphthalenes
  • aliphatic hydrocarbons eg n-hexane, cyclohexanone, kerosene
  • esters eg ethyl acetate, butyl acetate
  • nitriles eg acetonitrile, isobutyl nitrile
  • ethers eg , Dioxane, diisopropyl ether
  • acid amides for example, dimethylformamide, dimethylacetamide
  • halogenated hydrocarbons for example, dichloroethane, trichloroethylene, carbon tetrachloride
  • surfactant examples include alkyl sulfates, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers and polyoxyethylene compounds thereof, polyoxyethylene glycol ethers, polyhydric alcohol esters, sugar alcohol derivatives. Is mentioned.
  • formulation adjuvants include, for example, fixing agents, dispersants, antifoaming agents, stabilizers, preservatives, specifically casein, gelatin, polysaccharides (eg, starch, arabic gum, cellulose derivatives, alginic acid), Lignin derivatives, bentonite, saccharides, synthetic water-soluble polymers (eg, polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylic acids), PAP (isopropyl acid phosphate), BHT (2,6-di-tert-butyl-4-methylphenol) ), BHA (mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol), vegetable oil, mineral oil, fatty acid or ester thereof.
  • fixing agents e.g, fixing agents, dispersants, antifoaming agents, stabilizers, preservatives, specifically casein, gelatin, polysaccharides (eg, starch, arabic gum, cellulose
  • a coloring agent to a formulation.
  • the colorant include a red pigment, a blue pigment, a green pigment, and a yellow pigment. Specific examples include monazole red, cyanine green, Prussian blue, and brilliant blue.
  • granules and fine granules it is easy to check the granules and fine granules at the time of application or after application.
  • addition of a colorant is preferred because it is easy to confirm the treatment.
  • glycerin, ethylene glycol and propylene glycol may be added as antifreeze agents.
  • composition of the present invention When the composition of the present invention is used for pest control, its application rate can vary widely depending on the application time, application location, application method, etc., but the application rate is usually about 10,000 m 2 .
  • the total amount of this compound or a salt of this compound and one or more compounds selected from Group A to Group D is 1 to 10,000 g.
  • the composition of the present invention is formulated into an emulsion, wettable powder, flowable agent, etc., the total of this compound or a salt of this compound and one or more compounds selected from Group A to Group D is usually used.
  • the solution is diluted with water to a concentration of 0.01 to 10,000 ppm, and granules, powders and the like are usually applied as they are.
  • pests for which the composition of the present invention is effective include harmful animals such as harmful insects and harmful mites.
  • harmful animals include the following.
  • Hemiptera small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), Sejirounka (Sogatella furcifera), planthoppers such as corn planthopper (Peregrinus maidis), green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), Rice green leafhopper (Nepotettix nigropictus), Inazuma leafhopper (Recilia dosalis), Chanomidorihimebokoba (Empoaska onukii), Potato leaf hopper (Empoasca fabaye), corn Leaf hopper (Dalbulus maidis), Sugarcane froghopper (Mahanarva posticata), Sugarcane root spittlebug (Mahanarva fimbriolota), white giant leafhopper (Cofana spectra), cross di leafhopper (Nephotettix nigropic
  • White-tailed white-spotted moths such as Trialeurodes vaporariorum, Tobacco whiteflies (Bemisia tabaci), citrus whiteflies (Dialeurodes citri), Akanocaratus spiniferus, etc. lla aurantii), San Jose scale insect (Comstockcaspis perniciosa), Citrus snow scale (Unaspis citri), Ruby leaf beetle (Ceroplastes rubens), Iceria purusi cuco nak Scale insects such as stag beetle (Pseudauracapsis pentagona), tattle-my Lee bug (Brevennia rehi), citrus leaf lice (Diaphorina citri), pear lice (Psylla pyristoga papura) Whales such as Bilecerca cockerelli, Gunby beetles such as Stephanitis nasi, bedbugs such as Cimectularus and Giant Cicada (Quesa
  • Lepidoptera rice stem borer (Chilo suppressalis), Darkheaded stm borer (Chilo polychrysus), Sankameiga (Tryporyza incertulas), network Thailand Mei Chu (Chilo polychrysus), Shiromeichuu (Scirpophaga innotata), Yellow stem borer (Scirpophaga incertulas), Pink borer ( Sesamia inferens), Rupela albinella, Cnaphalococcus medinalis, Marasmia paternis, Marasmia exigna, Cotton moth (Notarcha derogata) Madarameiga (Plodia interpunctella), the European corn borer (Ostrinia furnacalis), high Madara Roh moth (Hellula undalis), Shibatsutoga (Pediasia teterrellus), Rice case worm (Nymphula depunctalis), Marasmia genus, Hop vine borer
  • Thysanoptera western flower thrips (Frankliniella occidentalis), Minami thrips (Thrips peri), yellow tea thrips (Scirtothrips dorsalis), green onion thrips (Thrips tabaci), Hirazuhanaazamiuma (Frankliniella intonsa), western flower thrips (Frankliniella occidentalis) Inekuda Thrips such as thrips (Haplotrips acculeatus), rice thrips (Stenchaethrips biformis) and the like.
  • Diptera pests Drosophila, Delia antiqua, Sugar beet root maggot (Tetenops myopae), Agromyza, Agromyza, Agromyza, Agromyza , Leafworms (Liriomyza trifoliii), leafworms (Chromatomyia horticola), leafworms (Chlorops oryzae), and citrus cuits. a), fruit fly, Hydralia sasakii, and other species of fruit fly, Such as butterflies and black mushrooms. Drosophila such as Hessian fly (Mayetiola destructor) and Inosinia oryzae, Drosophila such as Diopsis macrophtala, Common cranefly (Tipula eurae)
  • Coleoptera pests Western Corn Rootworm (Diabrotica virgifera virgifera), southern corn rootworm (Diabrotica undecimpunctata howardi), Northern Corn rootworm (Diabrotica barberi), Mexican Corn Rootworm Diabrotica virgifera zeae), Banded Cucumber Beetle (Diabrotica balteata LeConte) , San Antonio Beetle (Diabrotica speciosa), Cucurbit Beetle (Diabrotica speciosa), Bean Leaf Beetle (Cerotoma trifurcata), Serial Leaf Beet (Oulema melanopus), cucurbit leaf beetle (Aulacophora femoralis), Kisujinomihamushi (Phyllotreta striolata), Colorado potato beetle (Leptinotarsa decemlineata), Inedorooimushi (Oulema oryzae), Grape Korasupisu (Colaspis brunne
  • Orthoptera pests locust (Locusta migratoria), mole crickets (Gryllotalpa africana), Sydney Tobi grasshopper (Dociostaurus maroccanus), Australian Plague Locust (Chortoicetes terminifera), Akatobibatta (Nomadacris septemfasciata), Brown Locust (Locustana pardalina), Tree Locust (Anacridium melanorhodon), Italian Locust (Calliptamusalitalicus), Differential glasshopper (Melanoplus differentialialis), Twostr ped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-Legged grasshopper (Melanoplus femurrubrum), Clearwinged grasshopper (Camnula pellucida), desert Watari grasshopper (Schistocerca gregaria), Yellow-winged locust (Gastrimarg
  • Hymenopteran pests such as wasp (Athalia rosae) and Japanese bee (Athalia japonica). Fire Ants. Hachiriari such as Brown's leaf-cutting ant (Atta's capiguara).
  • Nematodes rice Shin Galle nematode (Aphelenchoides besseyi), strawberry menu nematode (Nothotylenchus acris), sweet potato root-knot nematode (Meloidogyne incognita), northern root-knot nematode (Meloidogyne hapla), Java root-knot nematode (Meloidogyne javanica), soybean cyst nematode (Heterodera glycines), Potato cyst nematode (Globodera rostochiensis), southern nematode nematode (Pratylenchus coffeae), barley nematode nematode (Pratylenchus neglectus), Meloidogyne java ica, Meloidogyne incognita, Rotylenchulus reniformis, Pratylenchus brachyurus and the like.
  • Termite pests Reticulites speratus, Termite terminator (Coptoptermes formosanus), American termite terminus (Incitermes minors), Cyptotermes domesticus, Owantosistorus Glypoptermes satsumensis, Glyptotermes nakajimai, Caterpillars (Glypoptermes fuscus), Gyptotermes kodamai, Shimotoshiroari (Glyptotermes kushimensis), giant termite (Hodotermopsis japonica), Kou Shu Ye termite (Coptotermes guangzhoensis), Amami termites (Reticulitermes miyatakei), R.
  • Acarina pests two-spotted spider mite (Tetranychus urticae), Kanzawa spider mite (Tetranychus kanzawai), citrus red mite (Panonychus citri), Ringohadani (Panonychus ulmi), Origonikasu genus and Southern Turkey spider mites (Brevipalpus phoenicis) mites such as, tangerine rust mite (Aculops pelekassi) , Ryukyu citrus mite (Phyllocoptruta citri), tomato rust mite (Aculops lycopersici), green rustic mite (Calacarus carinatus), green rusted mite (Acaphylla theavagran), mite riophyes chibaensis), Fushidani such as apple rust mite (Aculus Louendali), dust mite such as Chanohokoridani (Polyphagotarsonemus latus), southern Hime Himehadani such as spider
  • Lip and limb class Geeu (Thereunema hilgendorfi), Tobizukade (Scorpendra subspinipes) and the like. Double leg class: Oxidus gracilis, Nedyopus tambanus, etc. Isopods: Armadillium vulgare, etc. Gastropoda: Limax marginatus, Limax flavus, etc.
  • the target harmful insects and harmful ticks may be insects and ticks with reduced drug sensitivity or developed drug resistance to Group B insecticides / acaricides.
  • the drug sensitivity is greatly reduced or the drug resistance is greatly developed, it is desirable to use the composition of the present invention containing an insecticide / acaricide other than the target insecticide / acaricide.
  • composition of the present invention can also be used to protect plants from plant diseases when one or more compounds selected from Group A are used.
  • Examples of plant diseases in which the composition of the present invention has a controlling effect include the following.
  • Rice diseases rice blast (Magnaporthe grisea), sesame leaf blight (Cochliobolus miyabeanus), blight (Rhizoctonia solai), idiom ade (infestation) pv.Oryzae), seedling blight (Fusarium avenacerum, F. solani, Pythium arrhenom, P. gramicola, P. spinosum, Rhizopus chinensis, R.
  • brown stripe disease Pseudomonas avenae Mannell
  • leaf sheath browning disease Pseudomonas marginolus
  • scab Entyloma dactylidis Ciferri
  • white silkworm Sclerotium rolfsiii
  • rice blast Alternaria oryzaerumus, Pseudocochliolus, Pseudocochliol) Phytoplasma (Mycoplasma organizum)
  • Brachysporium disease Curvularia sengalense
  • Leaf blight Phaeosphateria oryzae
  • Gray leaf blight Hendersonia oryzum
  • spot disease Cochliobolus sativus
  • panicle disease Epicoccum hyalopes
  • bacterial blight Gibberella fujikuroi
  • brown leaf blight Methoda
  • Achlya spp. Phytophthora spp. Dictyuchus spp.
  • Mouse mold disease Alternaria oryzae
  • rust-colored mycorrhizal disease Sclerotium sp.
  • Sasara disease Sphaerulina miyakei
  • red sclerotia Waitea arumia disease
  • Neocapnodium tanakae Aureobasidium pullulans, Pseudocochliobolus lunatus, Sphaerulina oryzina leaf, B. scoparium), leaf rot (Acrocylindrium oryzae), leaf brown spot (Pyrenochaeta sp).
  • Wheat diseases powdery mildew (Erysiphe graminis), red mold disease (Fusarium gramaminerum, F. avenacerum, F. culmorum, Microdochium nitrid, red rust (Puccinia isp.
  • Ustilago nuda Ustilago nuda
  • cloud disease Rhynchosporium secalis
  • reticular disease Pyrenophora teres
  • spot disease Cochliobolus sativus
  • leafy leaf disease Pyrenophora graminea
  • Rhizonia a Diseases of corn: smut (Ustilago maydis), sesame leaf blight (Cochliobolus heterostrohus), leprosy (Gloeocercospora sorgi), southern rust (Puccinia polysorii), gray leaf spot disease Rhizoctonia solani due to seedling.
  • pirina Black spot (Alternaria alternata Japan pearpathotype), Red scab (Gymnosporangium haraeumum), disease Peach diseases: Monilinia fracticola, black scab (Cladosporium carpophilum), Phomopsis spoilage (Phomopsis sp.). Grape diseases: black scab (Elsinoe ampelina), late rot (Glomerella cinulata), powdery mildew (Uncinula apelopidais), black rot (Gikonivaladi) .
  • Oyster diseases Anthracnose (Gloeosporium kaki), deciduous leaf disease (Cercospora kaki, Mycosphaerella nawae). Diseases of cucurbits: Anthracnose (Colletotrichum lagenarium), powdery mildew (Sphaerotheca furiginea), vine blight (Mycosphaerella meloniis), vine scab (Fusarium oxysporum), por disease (fusarium oxysporum) ), Seedling blight (Pythium sp.); Diseases of tomato: Alternaria solani, leaf mold (Cladosporium fulvum), plague (Phytophthora infestans).
  • Pea disease powdery mildew (Erysiphe pisi). Potato diseases: Alternaria solani, Phytophthora infestans, Sputum rot septica, Spongosporia subteranean f.
  • Strawberry disease powdery mildew (Sphaerotheca humuli), anthracnose (Glomerella singulata). Tea diseases: net blast (Exobasidium reticulatum), white scab (Elsinoe leucospila), ring spot disease (Pestarotropis sp.), Anthracnose (Colletotrichum theae-sinensis).
  • Tobacco disease Alternaria longipes, powdery mildew (Erysiphe cichoracearum), anthracnose (Colletotrichum tabacum), downy mildew (Peronospora tabacina), epidemic (Phytophyti. Diseases of oilseed rape: Sclerotinia sclerotiorum, Rhizoctonia solani, Rhizoctonia solani. Cotton Diseases: Rhizoctonia solani caused by Rhizoctonia spp., Mildew fungus (Mycosphaerella areola), Black rot rot disease (Thielaviopsis basis caused by Thielaviopsis spp.). Coffee disease: Rust (Hemileia vastatrix).
  • Banana disease Sigatoka disease (Mycosphaerella fijiensis, Mycosphaerella musicola). Sunflower disease: downy mildew (Plasmopara halstedii). Aspergillus genus, Penicillium genus, Fusarium genus, Gibberella genus, Trichoderma genus, Thielaviopsis genus, Rhizopus genus, Mucor genus, Corticium genus, Poma genus, Rhizoctonia genus Disease.
  • the pathogenic bacterium or pathogenic bacterium causing the target disease may be a pathogenic bacterium or pathogenic bacterium having reduced drug sensitivity to a group A fungicide or having developed drug resistance.
  • the drug sensitivity is greatly reduced or the drug resistance is greatly developed, it is desirable to use the composition of the present invention containing a bactericide other than the bactericide to be targeted.
  • composition of the present invention can also be used to protect plants from plant diseases caused by insect-borne viruses.
  • Examples of plant diseases caused by insect-borne viruses having the control effect of the composition of the present invention include the following.
  • Rice dwarf disease (Rice waika virus), Tungue disease (Rice tungro spheroid virus), Rice tungro bacilliform virus, Rice grassy stun disease (Rice gluten virulence) Disease (Rice stripe virus), black stripe strangled dwarf disease, southern rice black-streaked disease (rice leaf disease), rice R Rice hoja blanka virus), white leaf disease of rice (White l af disease of rice), yellow dwarf virus, red disease (Rice penyakit merah virus), rice yellow disease (Rice yellow stunt virus), transition yellowing disease (Rice Yellow Motor Virus), rice necrosis mosaic virus, rice dwarf stunt virus, wheat northern mosaic disease, northern birth mosaic disease.
  • Virus wheat yellow leaf disease (W heat yellow dwarf virus), Oat sterile dwarf (Oat sterile dwarf virus), Wheat stream mosaic (Wheat stream mosaic virus) Maize mosaic (Maize dwarf mosaic virus), Maize stripe disease (maize stripe tenuivirus), Maize chlorotic dwarf (Maize chlorotic dwarf virus), Maize chlorotic mottle (maize chlorotic mottle virus), Maize rayado fino (maize rayado fino marafivirus), Corn stunt (Corn stun spiroplasma), Maize bushy stunt (Maize bushy stunt phytoplasma), sugarcane mosaic disease (Sugarcane mosaic virus), Soybean mild mosaic virus, Mosaic disease (Alfalfa Mosaic virus, Bean yellow-spot mosaic virus, Soybean mosaic virus, Bean yellowfish) Bean common mosaic virus, Peanut stunt virus, Southern bean mosaic virus, Soybean dwarf luteovirus-, Milk-vetch dwarf lutebird-Birtuo lutus ottle virus
  • Agricultural crops corn, rice, wheat, barley, rye, triticale, oat, sorghum, cotton, soybeans, peanuts, peanuts, cypress (green beans), lentils, azuki bean, cowpea, mung bean, safflower beans, bamboo bean, moss bean, tepareen Broad bean, pea, chickpea, lentil, lupine, bean, buckwheat, sugar beet, rape, sunflower, sugar cane, tobacco, etc.
  • Vegetables Eggplant vegetables (eggplants, tomatoes, peppers, peppers, bell peppers, potatoes, etc.), Cucurbitaceae vegetables (cucumbers, pumpkins, zucchini, watermelon, melon, squash, etc.), cruciferous vegetables (radish, turnip, horseradish, Kohlrabi, Chinese cabbage, cabbage, mustard, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, garlic, artichoke, lettuce, etc.), Lily family vegetables (eg, leek, onion, garlic, asparagus, etc.), Aceraceae vegetables (carrot, parsley) , Celery, American Bow Fu, etc.), red crustacean vegetables (spinach, chard, etc.), perilla vegetables (perilla, mint, basil, lavender, etc.), strawberry, sweet potato, yam, taro, etc.
  • Trees other than fruit trees Cha, mulberry, flowering trees, street trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, redwood, fu, sycamore, zelkova, black bean, peach tree, Tsuga, rat, pine, Spruce, yew) etc.
  • the above-mentioned plant may be a plant bred by hybrid technology.
  • a plant bred by hybrid technology is a first-generation hybrid obtained by crossing two varieties of varieties, and generally has a hybrid strength (generally, yield potential) with a trait superior to that of both parents. Plant with the characteristics of increasing, resistance to biological and abiotic stress factors, etc.).
  • the above-mentioned plant may be a plant imparted with resistance by genetic recombination technology.
  • Such varieties of plants include PPO inhibitors such as flumioxazin, 4-hydroxyphenylpyruvate dioxygenase inhibitors such as isoxaflutole, acetolactate synthase such as imazetapyr and thifensulfuron methyl (hereinafter abbreviated as ALS).
  • PPO inhibitors such as flumioxazin, 4-hydroxyphenylpyruvate dioxygenase inhibitors such as isoxaflutole, acetolactate synthase such as imazetapyr and thifensulfuron methyl (hereinafter abbreviated as ALS).
  • EPSP 5-enolpyruvylshikimate-3-phosphate synthase
  • EPSP 5-enolpyruvylshikimate-3-phosphate synthase
  • glyphosate glutamine synthetase inhibitors
  • glutamine synthetase inhibitors such as glufosinate
  • auxin types such as 2,4-D and dicamba
  • plants to which tolerance to herbicides such as herbicides and bromoxynil have been imparted by classical breeding methods or genetic engineering techniques are also included.
  • corn, rice, wheat, sunflower, canola and the like resistant to an imidazolinone-based ALS-inhibiting herbicide such as imazetapir are trade names of Clearfield (registered trademark).
  • Sold examples include sulfonylurea ALS-inhibiting herbicide-resistant STS soybeans such as thifensulfuron methyl.
  • SR corn and the like are examples of plants to which tolerance has been imparted to acetyl CoA carboxylase inhibitors such as trion oxime and aryloxyphenoxypropionic acid herbicides by classical breeding methods.
  • Examples of plants imparted with resistance by genetic recombination techniques include glyphosate-resistant corn, soybean, cotton, sugar beet, rapeseed, alfalfa, etc., RoundUpReady (registered trademark), Agriure (registered trademark) GT, Gly- Already sold under a trade name such as Tol (registered trademark).
  • glufosinate-resistant corn, soybean, cotton, rapeseed, and the like obtained by gene recombination techniques are available and are already sold under trade names such as LibertyLink (registered trademark).
  • Optimum® GAT® which is resistant to both glyphosate and ALS inhibitors.
  • Optimum® GAT® which is resistant to both glyphosate and ALS inhibitors.
  • imidazolinone-type ALS inhibitor-resistant soybean which has been developed under the name of Culture (registered trademark).
  • bromoxynyl-resistant cotton by genetic recombination technology, which is already sold under the trade name BXN (registered trademark).
  • a gene encoding allyloxyalkanoate dioxygenase was introduced, and phenoxy acid herbicides such as 2,4-D, MCPA, dicloprop, mecoprop, and quizalofop, haloxyhop, fluazihop, diclohop, phenoxy Plants that are resistant to aryloxyphenoxypropionic acid herbicides such as saprop, metamihop, cihalohop, and clodinahop can be created (Wright et al. 2010: Proceedings of National Academy of Science. 107 (47): ⁇ 20245).
  • the “plant” includes a plant that can synthesize, for example, a selective toxin known in the genus Bacillus, using a gene recombination technique.
  • Toxins expressed in such transgenic plants include insecticidal proteins derived from Bacillus cereus and Bacillus popilliae; Cry1Ab, Cry1Ac, Cry1F derived from Bacillus thuringiensis ⁇ -endotoxin such as Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, insecticidal protein such as VIP1, VIP2, VIP3 or VIP3A; nematicidal insecticidal protein; scorpion toxin, spider toxin, bee toxin or insect-specific neurotoxin Toxins produced by animals; filamentous fungal toxins; plant lectins; agglutinins; trypsin inhibitors, serine protease inhibitors, protease inhibitors such as patat
  • Hybrid toxins are produced by new combinations of different domains of these proteins using recombinant techniques.
  • Cry1Ab lacking a part of the amino acid sequence is known.
  • the modified toxin one or more amino acids of the natural toxin are substituted.
  • these toxins and recombinant plants capable of synthesizing these toxins are EP-A-0 374 753, WO 93/07278, WO 95/34656, EP-A-0 427 529, EP-A-0 451 878, WO 03/052073 and the like.
  • Toxins contained in these recombinant plants particularly confer resistance to Coleoptera and Lepidoptera pests.
  • genetically modified plants that contain one or more insecticidal pest resistance genes and express one or more toxins are already known, and some are commercially available.
  • transgenic plants include YieldGard® (a corn variety expressing Cry1Ab toxin), YieldGard® Rootworm (a corn variety expressing Cry3Bb1 toxin), YieldGard® Plus (Cry1Ab and Cry3Bb1 Corn varieties that express toxins), Herculex® I (corn varieties that express phosphinotricin N-astilyltransferase (PAT) to confer resistance to Cry1Fa2 toxin and glufosinate), NuCOTN33B (Cry1Ac toxin) Cotton varieties), Bollgard (registered trademark) I (cotton varieties expressing Cry1Ac toxin), Bollgard (registered trademark) II (cotton varieties expressing Cry1Ac and Cry2Ab toxin), BollGard (registered trademark) III (Cry1Ac and Cotton
  • RNAi is an example of a gene recombination technique that provides nematode resistance.
  • the “plant” includes those imparted with an ability to produce an anti-pathogenic substance having a selective action using a gene recombination technique.
  • PR proteins and the like are known as examples of anti-pathogenic substances (PRPs, EP-A-0 392 225).
  • anti-pathogenic substances and genetically modified plants that produce them are described in EP-A-0 392 225, WO 95/33818, EP-A-0 353 191 and the like.
  • Examples of anti-pathogenic substances expressed in such genetically modified plants include, for example, sodium channel inhibitors and calcium channel inhibitors (KP1, KP4, KP6 toxins produced by viruses, etc.) are known.
  • Ion channel inhibitors include stilbene synthase; bibenzyl synthase; chitinase; glucanase; PR protein; peptide antibiotics, heterocyclic antibiotics, protein factors involved in plant disease resistance (called plant disease resistance genes, WO No. 03/000906)) and other anti-pathogenic substances produced by microorganisms.
  • plant disease resistance genes WO No. 03/000906
  • plant disease resistance genes protein factor involved in plant disease resistance
  • plant disease resistance genes called plant disease resistance genes, WO No. 03/000906
  • plant disease resistance genes called plant disease resistance genes, WO No. 03/000906
  • plant disease resistance genes called plant disease resistance genes, WO No. 03/000906
  • plant disease resistance genes called plant disease resistance genes, WO No. 03/000906
  • plant disease resistance genes called plant disease resistance genes, WO No. 03/000906
  • useful traits such as oil component modification and amino acid content enhancing traits using genetic recombination techniques. Examples include VISTIVE
  • the above-mentioned “plant” is a line to which two or more traits relating to herbicide resistance, pest resistance, disease resistance, etc. as described above are imparted using classical breeding techniques or genetic recombination techniques, Also included are strains to which two or more properties of the parent strain are imparted by crossing genetically modified plants having similar or different properties. Examples of such plants include Smart stax (registered trademark).
  • the above-mentioned classic herbicide traits or herbicide resistance genes, insecticidal pest resistance genes, anti-pathogenic substance production genes, useful traits such as oil component modification and amino acid content enhancement traits Combined stack varieties are also included. Also included are plants into which RNAi technology has been introduced.
  • the plant used may be planted or planted with plant seeds, bulbs or seedlings.
  • bulbs include bulbs, bulbs, rhizomes, tubers, tuberous roots, root support bodies or stem fragments, and so-called seed pods are included.
  • the seedlings include cuttings in addition to those grown from plant seeds or bulbs.
  • Plant seeds, bulbs or seedlings are preferably treated with a fungicide, but are not necessary. When treating with a fungicide, it is used after treating plant seeds or bulbs with one or more fungicides.
  • Commercially treated plant seeds or bulbs or the like may be purchased and used, or seedlings grown from the treated plant seeds or bulbs or the like may be purchased and used. As described later, those treated with the present composition containing the present compound or a salt of the present compound and a fungicide compound may be used.
  • Examples of the method of applying the composition of the present invention to plants include application to plant stems and leaves, flower vases, ears, fruits, trunks, branches or crowns, application to plant seeds or bulbs, and application to seedlings. .
  • Examples of the application method of the composition of the present invention to plant stems and leaves, flower vases, ears, fruits, tree trunks, branches, or crowns include spraying, coating, and injection.
  • Examples of spraying methods include human sprayers and power sprayers.
  • ground spraying using a boom sprayer or a crumb sprayer, air spraying using an unmanned helicopter, air spraying, and the like can be given.
  • the application to the seedling is an application in the seedling raising period of the plant to be transplanted or planted, and examples of the method include spraying, dipping, and irrigation.
  • Examples of the application method to a place where a plant is cultivated or planned to be cultivated or a place where a pest lives or is expected to live include soil treatment, hydroponic liquid treatment, and the like.
  • the soil refers to a plant cultivation carrier, particularly a support for growing roots
  • the material is not particularly limited, but may be any material that can grow a plant, so-called soil, seedling mat, water.
  • Specific materials may include, for example, sand, pumice, vermiculite, diatomaceous earth, gel material, polymer material, rock wool, glass wool, wood chip, bark and the like.
  • When applied to the soil it can be applied to the surface by spraying, irrigation, dripping, etc., or mixed into the soil by covering or plowing after treatment on the surface, and then injected into the soil using an injector It is. These treatments can be performed after mixing with agricultural materials such as paste fertilizer.
  • application sites include holes or grooves when planting seeds, bulbs or seedlings, plant sources, strains, intercostals, the entire surface of plant growth, water surface, nursery beds, and the like.
  • the composition of the present invention is mixed with the soil before plant seeds, bulbs or seedlings are seeded or planted, or the composition of the present invention is mixed with the plant seeds or bulbs seeded or planted in the soil. It is also preferable to cover with dry soil.
  • the soil treatment in the present invention refers to, for example, controlling pests directly by applying an active ingredient to the rhizosphere of a plant to be protected from damage such as feeding by pests, or roots inside the plant body.
  • This is a method of controlling the pests by osmotically transferring active ingredients from, etc., specifically, for example, planting treatment (planting hole spraying, planting hole soil mixing), plant source processing (stock source spraying, strain source) Soil admixture, strainer irrigation, seedling treatment in the latter half of the seedling season), grooving treatment (spreading grooving, mixing grooving soil), cropping treatment (spreading, sprinkling soil mixing, sprinkling of growing season), sowing Temporal row treatment (spreading at the time of sowing, mixing with the soil at the time of sowing), full treatment (spreading the whole soil, blending with the whole soil), side treatment, water surface treatment (full water surface application, frame water surface application), other soil spraying Treatment (growth of leaves during
  • Hydroponic liquid treatment is, for example, by applying an active ingredient to hydroponic liquid etc. in order to infiltrate and transfer from the root etc. into the plant body of the plant to be protected from damage such as feeding by pests, etc.
  • This is a method for protecting plants from damage caused by pests.
  • Specific examples include mixing of hydroponic liquid and mixing of hydroponic liquid.
  • Examples of the method of applying the composition of the present invention to plant seeds or bulbs include preparations containing active ingredients in plant seeds or bulbs or methods of coating, smearing or applying diluted solutions thereof, and preparations containing active ingredients.
  • the amount of the compound to be treated is usually 0.2 to 5000 g, preferably 0.5 to 1000 g, per 100 kg of plant seeds or bulbs.
  • Preferred dosage forms are aqueous liquid suspension preparations such as emulsions, wettable powders, flowables, and microcapsules.
  • An aqueous suspension of granule wettable powder and dry flowable powder is also preferable.
  • composition of the present invention is treated with plant seeds or bulbs
  • a composition containing at least one fungicide among the compositions of the present invention it is particularly preferable to use a composition containing at least one fungicide among the compositions of the present invention.
  • commercially treated plant seeds or bulbs may be purchased and used.
  • this invention composition when processing this invention composition to a plant seed or a bulb, you may process manganese, copper, zinc, etc. simultaneously.
  • Plant seeds or bulbs treated with the composition of the present invention are sown or planted in a field by a usual method.
  • composition of the present invention can effectively control a wide range of subjects in a cereal field, a vegetable field, a flower field, an orchard, or a non-agricultural land where normal or non-tillage cultivation is performed.
  • a sugarcane stem fragment that has been cut so as to have one node may be used, and the size of the sugarcane stem fragment may be 2 cm.
  • One having 15 to 15 cm, preferably 3 to 8 cm may be used.
  • Sugarcane cultivation techniques using such stem fragments are known (WO09 / 000398, WO09 / 000399, WO09 / 000400, WO09 / 000401, WO09 / 000402) and are implemented under the trade name of Prene (registered trademark).
  • the composition of the present invention When the composition of the present invention is applied to rice, it may be applied to a nursery, may be applied to paddy fields, or may be applied to rice seeds.
  • the nursery includes a nursery box or a rice seedling tray and a nursery.
  • the application time of the composition of the present invention is not particularly limited as long as it is a period from the sowing of rice to the time of transplanting, for example, pre-soiling pretreatment at sowing, post-soaking treatment at sowing, greening Phase treatment, transplantation day treatment, and transplantation simultaneous treatment can be mentioned. It may be applied 5 days before transplantation to the day before transplantation, and can be applied at any time during the period from seeding to transplantation.
  • the period from sowing to transplanting varies depending on young seedlings (seedlings around 2.5 leaf stage), medium seedlings (seedlings around 3.5 leaf stage) or adult seedlings (seedlings around 4.5 leaf stage), and
  • the seedling period varies depending on weather conditions, etc., but it can be applied in any case.
  • a preparation of the composition of the present invention for example, a kneaded granule or a sand coating granule may be sprayed on the seedling box, or a solution obtained by diluting the preparation of the composition of the present invention may be irrigated to the seedling box.
  • the composition of the present invention can also be applied by mixing with floor soil or covering soil.
  • the seedling culture medium is not particularly limited as long as it is a soil for rice seedlings, and a seedling mat other than soil may be used.
  • the seedlings to which this compound is applied may be cultivated by pool seedlings.
  • the method of applying to paddy fields is not particularly limited, but the method of applying the composition of the present invention as it is or as a preparation to be applied to rice foliage, the method of applying to paddy soil, and the surface of flooded paddy fields. The method of applying etc. are mentioned.
  • Preparations to be used include preparations to be applied as they are, such as powders and fine granules, and flowables, dry flowables, wettable powders, granule wettable powders, SE drugs, aqueous solvents, granular aqueous solvents, liquids, microscopic products Preparations that are diluted and sprayed, such as emmaffusion agents, EW agents, oil agents, surf agents, or emulsions.
  • the spraying device may be any device that is normally used, and a hand-spreading device, a power spreader, a cruising player, a radio control helicopter, a manned helicopter, and the like can be used. Moreover, you may spray by hand, without using an apparatus.
  • a method of applying to paddy soil a method of treating the whole surface of paddy soil (entire treatment), a method of treating a groove provided when sowing rice (seeding groove treatment), 0-10 cm directly under rice seeds And a method of treating in the vicinity of rice lines or seeds in the form of streaks or dots (side treatment).
  • it can be mixed with or simultaneously with agricultural materials such as paste fertilizer and granular fertilizer.
  • the timing of applying the composition of the present invention may be before sowing or transplanting rice, may be simultaneous with sowing or transplanting, or may be immediately after sowing or transplanting. When applying simultaneously with sowing or transplanting, it may be applied using an attachment attached to the sowing machine or transplanting machine, or by other methods. Further, in the case of full surface treatment, it may be a period until water injection after sowing or transplanting, an intermediate drying period, or an intermittent irrigation period.
  • the soil surface of the paddy field may be dry, or the soil surface may be moist but free of flooding (water depth 0 cm). When it is applied to the surface of a flooded paddy field, it can be applied at any time from sowing or transplanting to harvesting, as long as the water depth is maintained by normal rice management.
  • the rice seed is composed of iron powder and iron oxide. It may be surface-treated with a coating material such as powder, calcium peroxide, or molybdenum compound. These coating materials can be used alone or in combination at any ratio, and if necessary, additives such as calcined gypsum are added for the purpose of increasing the amount or improving fixation to rice seeds. be able to.
  • Rice seed means rice seed in a state prior to sowing in a paddy field.
  • Rice seeds to which the composition of the present invention has been applied can be cultivated by direct sowing in dry fields, wet fields, and paddy fields, or may be cultivated by sowing seedling boxes.
  • the preparation of the composition of the present invention can be applied to rice seeds by applying it, but before sowing rice seeds are immersed in a solution containing the composition of the present invention, or after germination, a solution containing the composition of the present invention is sprayed. It may be processed. In any treatment method, a safener may be used in combination.
  • sterilized seeds can be used to control seed infectious pests regardless of whether they are applied to seedlings, paddy fields, or seeds.
  • chemical pesticides such as prochloraz, triflumizole, pefurazoate, oxolinic acid, ipconazole, fludioxonil, kasugamycin monohydrochloride, cupric hydroxide, basic copper chloride, fenitrothion, cartap hydrochloride, or Trichoderma atrobilide, Seeds that have been soaked, smeared or powdered with agents containing microorganisms such as Talaromyces flavus, Pseudomonas CAB-02, and Bacillus simplex as active ingredients can be used.
  • agents containing microorganisms such as Talaromyces flavus, Pseudomonas CAB-02, and Bacillus simplex as active ingredients can be used.
  • weeds generated in paddy fields can be controlled by applying a herbicidal active compound.
  • the time when the herbicidal active compound is applied is not particularly limited as long as phytotoxicity to rice by the herbicidal active compound does not cause a problem.
  • herbicidally active compounds that can be used in paddy fields include azisulfuron, bensulfuron-methyl, chlorimuron-ethyl, cyclosulfamuron, and ethoxysulfuron. , Flucetosulfuron, halosulfuron-methyl, imazosulfuron, orthosulfamuron, propylsulfuron, propylsulfuron, propylsulfuron Cinosulfuron, metsulfuron-methyl, methazosulfuron, bentiocarb, molinate, esprocarb, piribatecarb (Butachlor), pretilachlor, tenylchlor (theny1ch1or), simethrin, dimethamethrin, methyl-daimuron, propanil, propanil Mefenacet, flufenacet, chromeprop, naproanilide, brombutide, diimuron, enzybone,
  • Rice for which the composition of the present invention can be used refers to the cultivated species Oryza sativa, Oryza glaberrima, and hybrids thereof among the annual plants of the genus Oryza, which are any of Japonica, Java, and Indica. Moreover, any of sticky rice, sticky rice, sake rice, and feed rice may be used. Rice varieties are not particularly limited, and may be varieties produced by crossing or cultivars produced by genetic recombination techniques. When applied to varieties imparted with resistance to pests, it can be a particularly labor-saving control method.
  • resistant varieties include resistance genes Bph1, bph2, Bph3, bph4, bph5, bph6, bph7, bph8, Bph9, Bph10, bph11, bph12, bph13, Bph14, bph15, Bph16, Bph17, Bph18, bph19, bph20. , Bph21, Bph25, Bph26, Bph27, etc.
  • One or more herbicidal active compounds may be treated in paddy fields, crop fields, orchards or non-agricultural lands.
  • the composition of the present invention and the herbicidal active compound may be applied simultaneously or separately. When applying separately, you may apply on the same day or another day.
  • the herbicidal active compound is usually mixed with a carrier such as a solid carrier or a liquid carrier, and if necessary, a preparation such as a surfactant. A supplement is added to form a preparation.
  • Examples of methods for treating herbicidal active compounds in paddy fields, crop fields, orchards, or non-agricultural lands include, for example, a method of spraying herbicidal active compounds on soil in paddy fields, crop fields, orchard fields and after weeding active compounds. The method of spraying on weeds.
  • the amount of the herbicidal active compound used in the step of treating the herbicidal active compound in paddy fields, crop fields, orchards or non-agricultural lands is usually 5 to 5000 g per 10000 m 2 , preferably 10 to 1000 g per 10000 m 2 , more preferably 20 to 500 g per 10,000 m 2 .
  • an adjuvant may be mixed to treat the herbicidal active compound.
  • two or more herbicidal active compounds may be applied simultaneously or separately. When applying separately, you may apply on the same day or another day.
  • one or more types of safeners can be applied in combination with the herbicide.
  • the method of applying the safener is not particularly limited, but can be applied together with the herbicide. In this case, a preparation containing the herbicide and safener may be used alone, or the herbicide may be used. You may use together the formulation containing and the formulation containing a safener.
  • plant seeds or bulbs treated with a safener can be used. Plant seeds or bulbs may be used after being treated with one or more safeners, or seeds treated with a commercially available safener may be purchased and used.
  • the herbicidal active compound before sowing or planting plant seeds, bulbs or seedlings 50 days before sowing or planting to just before sowing or planting, preferably 30 days before sowing or planting to immediately before sowing or planting, more preferably The herbicidal active compound is treated from 20 days before sowing or planting to just before sowing or planting, more preferably from 10 days before sowing or planting to just before sowing or planting.
  • the herbicidal active compound When the herbicidal active compound is treated after sowing or planting plant seeds, bulbs or seedlings, the herbicidal active compound is preferably treated immediately after sowing or planting to 50 days after sowing or planting, more preferably immediately after sowing to 3 days after sowing.
  • the herbicidal active compound can also be treated simultaneously with sowing or planting of plant seeds, bulbs or seedlings.
  • As a specific treatment time in the case of treating the herbicidal active compound after sowing of soybean seeds for example, the period from before germination to flowering of soybean can be mentioned.
  • the period is preferably from the period before emergence of soybean to the period of 6 double leaves, and more preferably from the period before emergence of soybean to the period of 3 complex leaves.
  • the specific treatment time is from before emergence to the 12th leaf stage, preferably from before emergence to the 8th leaf stage, more preferably from 6 minutes before the emergence. Until the leaf stage.
  • the leaf age of corn is determined by the leaf color method (Leaf Collar Method).
  • the herbicidal active compound When the herbicidal active compound is treated before sowing of the cotton seed, the herbicidal active compound is treated 50 days before sowing to immediately before sowing, preferably 30 days before sowing, immediately before sowing, more preferably 20 days before sowing to immediately before sowing.
  • the herbicidal active compound is treated after sowing of the cotton seed, the herbicidal active compound is treated immediately after sowing to 70 days after sowing, preferably 30 days after sowing to 50 days after sowing.
  • the specific treatment time when the herbicidal active compound is treated after sowing of the cotton seed includes, for example, the period before the cotton emergence to the flowering time. Preferably, the period from the start of tree planting to the base of cotton is 20 cm from the base.
  • the herbicidal active compound When the herbicidal active compound is treated before sugarcane planting, it is 40 days before to just before sowing or planting, preferably 30 days to just before sowing or planting, more preferably the day of sowing or planting.
  • the herbicidally active compound is treated 20 days before to immediately before.
  • herbicidal active compounds examples include the following.
  • Herbicidal active compounds Clodinahop, clodinahop-propargyl, cihalohop, cyhalohop-butyl, diclohop, diclopop, dicyclopmethyl , Phenoxaprop-ethyl, phenoxaprop-P, phenoxaprop-P-ethyl, fluazifop, fluazifop-blu P (fluazifop-P), fluazifop Pbutyl (fluazifop-P-butyl), haloxyhop, haloxyhop-methyl, haloxyhop-P, haloxyhop-P-methyl, metamihop, metamihop Quizahopop (di), Quizalohop-diyl, Quizalofop-diyl, Quizalofop-dixy, Quizalofop-dixy, Quizal
  • triphenphane maleic hydrazide, triafamon, ACN, phenoxasulfone, haluxifen Plant growth regulators: hymexazole, paclobutrazol, uniconazole, uniconazole-P, inabenfide, prohexadione-cium Propene (1-methylcyclopropene), trinexapac and gibberellins.
  • Safeners Benoxacor, cloquintoset, cloquintocet-mexyl, cyometrinil, cyprosulfamide (dipromide), dichlormid (di) Dietholate, fenchlorazole, fenchlorazole-ethyl, fenchlorim, flurazole, fluxofenim, flilazole xadifen), isoxadifen-ethyl (isoxadifen-ethyl), mefenpyr (mefenpyr), mefenpyr-diethyl (mefenpyr-diethyl), Mefeneto (mephenate), naphthalate Rick polyanhydride (naphthalic anhydride) and oxabetrinil (oxabetrinil).
  • Herbicidal active compounds are in particular flumioxazin, sulfentrazone, saflufenacyl, oxyfluorfen, fomesafen, fomesafen sodium, glufosinate ammonium salt, chlorimuron ethyl, chloransrammethyl, pyroxasulfone, imazetapyram ammonium salt, Metribuzin, 2,4-D, 2,4-D butyl ester, 2,4-D dimethylammonium salt, 2,4-D diolamine salt, 2,4-D ethylhexyl ester, 2,4-D isooctyl Ester, 2,4-D isopropylammonium salt, 2,4-D sodium salt, 2,4-D triisopropanolamine salt, 2,4-D choline salt, dicamba, dicambadiglycolamine salt, dicamba dimethylammonium salt Dicamba isopropyl ammonium salt Dicamba potassium,
  • weeds that can be controlled include the following. Nettle weeds: Ultica urens Polygonaceae weeds: wild buckwheat (Polygonum convolvulus), Sanaetade (Polygonum lapathifolium), the United States smartweed (Polygonum pensylvanicum), Harutade (Polygonum persicaria), knotweed (Polygonum longisetum), Polygonum aviculare (Polygonum aviculare), Haimichiyanagi (Polygonum arenastrum), Japanese knotweed ( Polygonum cuspidatum), Rumex japonicus, Rumex crispus, Rumex obtusifolius, Rumex acetosa Physalis Weed: Physalis (Portulaca oleracea) Weeping weeds: Stellaria media, Cerastium holosteoides, Cerastium glomeratum, Spergula arvensis, Silene gallic Pomegranate
  • Convolvulaceae weeds morning glory (Ipomoea nil), American morning glory (Ipomoea hederacea), Ipomoea purpurea (Ipomoea purpurea), tall American morning glory (. Ipomoea hederacea var integriuscula), beans morning glory (Ipomoea lacunosa), Hoshiasagao (Ipomoea triloba), Noasagao ( Ipomoea acuminata), Ipomoea hedefifolia, Ibarumou (Ipomoea coccinea), Ipomoea quamoclit, Ipomoea aporia Grandifolia a aristolochiafolia), Maple bus morning glory (Ipomoea cairica), field bindweed (Convolvulus arvensis), Kohirugao (Calystegia hederacea), morning glory (Calystegia japonica), Tsut
  • composition of the present invention By applying the composition of the present invention, depending on the plant species or plant varieties, their growth location and growth conditions (soil, climate, growth season, nutrient), improvement of plant seedling establishment rate, improvement of growth, high temperature or low temperature Improved tolerance or tolerance, drought, over-humidity, increased tolerance to salt in water or soil, improved flowering ability, improved harvestability, accelerated maturation, increased yield, seed or fruit Number, size or weight increase, plant height increase, plant weight increase, leaf green color improvement, healthy leaf number increase, leaf area increase, faster flowering, flowering number or fruit number Increased fruit set rate, improved quality of harvested product and / or increased nutritional value, increased sugar content in fruit, increased gluten strength, improved storage stability of harvested product and / or In some cases, workability can be improved.
  • Examples of the bactericides included in Group A include the following.
  • DMI fungicide demethylation inhibitor
  • Etaconazole fenarimol, fenbuconazole, fluquinconazole, flusilazole, flutriazole, hexaconazole (hexaazole) onazole, imazalil, imibenconazole, ipconazole, metconazole, microbutanol, nupomolazole, nupomolazole (Oxpoconazole fumarate), pefrazoate (pefurazolate), penconazole, prochloraz, propiconazole, prothioconazole pilozopyrazole pyrisoxazole, simeconazole, tebuconazole, tetraconazole, triadifoline, triadimol, triflumenol etc;
  • Anilinopyrimidine fungicides cyprodinil, mepanipyrim, pyrimethanil and the like; (6) Phenylpyrrole fungicide fenpiclonil, fludioxonil and the like;
  • QoI inhibitors azoxystrobin, cumoxystrobin, dimoxystrobin, enoxastrobin, famoxadone, fenamidone, fenamidone Robin (fenaminestrobin), flufenoxystrobin, fluoxastrobin, cresoxime-methyl, mandestrobin, methinostrobin, metminostrobin Coxystrobin, pyraclostrobin, pyramethostrobin, pyraoxystrobin, pyribencarb, triclopyrtroprinb, triclopyrtrobine -Methyl-2- [2- (2,5-dimethylphenoxy) methyl] phenyl-2-methoxyacetamide (including racemic or enantiomers, mixtures of R and S enantiomers in any proportions) etc;
  • PA fungicide phenylamide fungicide
  • Metalaxyl, Metalaxyl M, Mexoroxyl PA fungicide (phenylamide fungicide) Benalaxyl, Benalaxyl M or Kiraxyl (furalaxyl), Metalaxyl, Metalaxyl M, Mexoroxyl,
  • SDHI fungicides benodanil, benzovindiflupyr, bixafen, boscalid, carboxin, fenfuram, fluolil, fluopiram Fluxapyroxad, furametopyr, isofetamid, isopyrazam, mepronil, oxycarboxin, pentipyr ne), thifluzamide (thifluzamide), compounds represented by the following formula (a);
  • Microbial materials Agrobacterium radiobactor, strain 84, etc., Bacillus amyloliquefaciens, Bacillus pumilus GF, Baculus pumulus C Strain), Bacillus subtilis synonyms for Bacillus amyloliquefaciens, QST713 strain, FZB24 strain, MBI600 strain, D747 strain, HAI0404 strain, Y1336 strain, varioborx 4526 strain, etc.), Erwinia carotovora (Erwinia carotovora, CGE234M403 strain, etc.), Pseudomonas fluorescens (G7090 strain, etc.), Talaromyces flavus (Talaromyces flavus) Atrobilide (Trichoderma atroviride, SKT-1 strain, etc.) etc .;
  • Nereistoxin compounds Bensultap, cartap, cartap hydrochloride, thiocyclam, thiosultap-2 sodium salt or thiosultap-disodium salt bis Salt or monosultap or monosultap, etc .;
  • Neonicotinoid compounds Acetamiprid, clothianidin, dinotefuran, flupyradifurone, thiapyrid (im) cloprid (imi) thiamethoxam) etc .;
  • Benzoylurea compounds bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexflufluron, hexflufluron (Lufenuron), novaluron, noviflumuron, teflubenzuron, triflumuron, etc .;
  • Phenylpyrazole compounds Ethiprole, fipronil, flufiprole, etc .;
  • Microbial material Bacillus thuringiensis, var. Aizawai, var. Kurstaki, var. franrensis, var. ) Derived live spores, produced crystal toxins, and mixtures thereof, Bacillus sphaericus, Beauveria bassiana, GHA strains, etc. , Pekir Myces Relaci Eggplant (Paecilomyces lilacinus), Pecilomyces tenuipes, Trichoderma harzianum, Verticillium lecani, etc .;
  • Nematicidal active compounds dazomet, fluensulfone, fothiazate, imiciafos, metham, potashsite antifate, tartardite fate Arthrobotrys dactyroides, Bacillus films (Bacilus farmus, I-1582 strain (hereinafter abbreviated as Bf bacterium), etc.), Bacillus megaterium, Hiltella rosirisells Hillstera Mi Nesotensis (Hirsutella minnesotensis), Monacrosporium phymatopagus (Monosporus phymatopagus), Pasteuria nishizawae (hereinafter abbreviated as Pn bacteria) Lithium Chlamydosporium, Harpin protein and the like;
  • acaricidal active compounds acequinocyl, amitraz, benzoximate, bifenazate, bromopropylate, chinomethenotine, chinomethenozine (Cynopyrafen), cyflumethofen, cyhexatin or tricyclohexyltin hydrochloride, dicofol, etoxazole, phenazafen (tin) de), fenpyroximate, fluacrylpyrim, fluazuron, fluphenoxystrobin, phenthiazopy, fluthiazox pyrimidfen, pyriminostrobin, spirodiclofen, spiromesifen, tebufenpyrad, tetradiphon, etc .;
  • insecticides abamectin, emamectin benzoate, lepimectin, milbemectin, spinetoram, spinosad, aphido, aphido (Aluminum phosphide), calcium phosphide, hydrogen phosphine, zinc phosphide, azadirachtin, buprofezin, chlorfenapir picrin, cyromazine, diafenthiuron, DNOC, phenoxycarb, flometoquin, flonicamid, hydramethylhydrone indoxacarb, quinoprene, metaflumizone, methoprene, methoxychlor, methylbromide, methoxadiazine, metoxadiazine yrazophos, pyridalyl, pyrifluquinazone, pyriproxyfen, sodium fluoride, sulfidyl, sulf
  • Examples of the safeners included in Group C include the following. Benoxacol, cloquintoset, cloquintocet-mexyl, thiomethrinil, cyprosulfonide, dichlormidol, dichlormidol , Fenchlorazole, fenchlorazole-ethyl, fenchlorim, flurazole, fluxofenim, furilazole, isoxadifen ), Isoxadifen-ethyl (isoxadifen-ethyl), mefenpyr (Mefenpyr), mefenpyr-diethyl (mefenpyr-diethyl), Mefenato (Mephenate), naphthalate Rick polyanhydride (naphthalic anhydride), oxabetrinil (Oxabetrinil) or the like.
  • Examples of plant growth regulators included in Group D include the following. Chlormequat-chloride, etephon, gibberellins, gibberellin A3 (gibberellin A3, etc.), hymexazole, i-de-de-methyl-p methylcyclopropylene, paclobutrazol, prohexadione, prohexadione calcium, trinexapac, trinexapac-ethyl, trinexapacol conazole), uniconazole P (uniconazole-P), 4-oxo-4- (2-phenylethyl) aminobutyric acid (4-oxo-4- (2-phenylethyl) aminobutyric acid), 5- (trifluoromethyl) benzo [ b] Methyl thiophene-2-carboxylate and the like.
  • composition of the present invention may further contain a compound such as anthraquinone used as a bird repellent.
  • Each of the above-mentioned compounds included in the above-mentioned group A to group D is a known compound, and is described in, for example, “THE PESTICIDE MANUAL—15th EDITION (published by BCPC) ISBN 978-1-901396-18-8”. Has been. These compounds can be produced by a production method described in a patent document or non-patent document cited in “THE PESTICIDE MANUAL”, or a related document, or can be obtained from a commercially available formulation.
  • the number of one or more compounds selected from Group A to Group D can be 1 to 6 (eg, 1, 2, 3, 4, 5, 6).
  • the pest control method of the present invention applies an effective amount of the present compound and one or more compounds selected from Group A to Group D to the plant or the soil where the plant is grown.
  • the present invention control method applies an effective amount of the present compound and one or more compounds selected from Group A to Group D to the plant or the soil where the plant is grown.
  • Examples of such plants include plant foliage, plant seeds, plant bulbs and plant seedlings.
  • the present compound and one or more compounds selected from group A to group D may be applied separately to the plant or soil where the plant is cultivated at the same time. From the viewpoint, it is applied as the composition of the present invention.
  • the mixing ratio (weight ratio) between the present compound and one or more compounds selected from Group A to Group D is the type of plant to be protected, the type and occurrence of pests to be controlled. It varies depending on the frequency, formulation, application time, application method, application location, weather conditions and the like.
  • compositions having the combinations described in [Table 4a] to [Table 4f] are represented by the numbers described in [Table 4a] to [Table 4f].
  • the composition of No. 1 in [Table 4a] is referred to as the present composition 1.
  • * described in the column of component 1 represents any one of the present compounds 1 to 1095, and the numbers described in [] in the column of each component are It means the weight part of each component in the present composition.
  • the present composition 1 represents the present composition 1-1 to the present composition 1-1095 in which any one of the present compound 1 to the present compound 1095 is 2 parts by weight.
  • compositions aa1 to aa8 each composition having the same composition as (hereinafter referred to as the present compositions aa1 to aa8).
  • compositions ab1 to ab13 Each composition having the same composition as that of No. 26 (hereinafter referred to as the present compositions ab1 to ab13).
  • present compositions ac1 to ac13 Each composition having the same composition (hereinafter referred to as the present compositions ac1 to ac13).
  • composition is the same as the present compositions 2, 7, 12, 13, 15, 18, 19, 23 and 26 in [Table 4a] except that 0.75 part of triflumezopyrine was used instead of 1.5 parts of clothianidin.
  • Each composition hereinafter referred to as the present compositions af1 to af9).
  • composition ba1 Each composition having the same composition as the present compositions 27, 30, 31, 34, 35 and 37 in [Table 4b] except that 3 parts of fenitrothion was used instead of 0.5 parts of clothianidin (hereinafter referred to as the present composition ba1) ⁇ Written as ba6).
  • compositions 28, 30, 32 and 37 in [Table 4b] using 1 part of tricyclazole instead of 1.5 parts of fusaride hereinafter referred to as the present compositions bb1 to bb4) .
  • compositions 33, 34, 36 and 37 in [Table 4b] using 0.5 parts of tricyclazole instead of 2 parts of ferrimzone (hereinafter referred to as the present compositions bc1 to bc4) .)
  • compositions ca1 to ca7 Each composition having the same composition as the present compositions 38, 41, 43, 44, 45, 46 and 47 in [Table 4c] except that tricyclazole was used in place of the fusalide (hereinafter referred to as the present compositions ca1 to ca7) .)
  • the combination is referred to as the present composition c.
  • compositions db50 and db51 The same composition as the present compositions 50, 51, 55 to 84 in [Table 4d] except that 10 parts of Pn bacteria were added to the present compositions 50, 51, 55 to 84, and x80 (hereinafter referred to as the present compositions db50 and db51). , Db55 to db84, xb80.)
  • compositions da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84, xc80 except that 10 parts of clothiazinine was added to the compositions da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84, xc80 Same composition (hereinafter referred to as the present compositions daa55 to daa84, xaa80, dba55 to dba84, xba80, dca55 to dca84, xca80)
  • compositions da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84 except that 10 parts of cyantraniliprole were added to the compositions da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84, xc80.
  • the same composition as xc80 hereinafter referred to as the present compositions dab55 to dab84, xab80, dbb55 to dbb84, xbb80, dcb55 to dcb84, xcb80)
  • the same composition as the present compositions 85 to 799 in [Table 4e] except that one component in the component 2 row of the present compositions 85 to 799 was omitted hereinafter referred to as the present compositions ex85 to ex799).
  • the same composition as the present composition 85 to 799 in [Table 4e] except that one component in the component 3 row of the present composition 85 to 799 was excluded hereinafter referred to as the present composition ey85 to ey799).
  • the same composition as the present composition 85 to 799 in [Table 4e] except that one component in the component 4 row of the present composition 85 to 799 was omitted hereinafter referred to as the present composition ez85 to ez799).
  • the same composition as the present composition 85-799, ex85-ex799, ey85-ey799, ez85-ez799 except that 10 parts of Pn bacteria were added to the present composition 85-799 hereinafter, the present compositions eb85-eb799, ebx85- (Indicated as ebx799, eby85 to e
  • This composition ex85 to ex799, ey85 to ey799, ez85 to ez799, ea85 to ea799, eax85 to eax799, ea85 to eee799, eaz85 to eaz799, eb85 to eb799, eby7 e7 to e99e, , Ecx85 to ecx799, ecy85 to ecy799, ecz85 to ecz799, except that 10 parts of clothiazinine was added to this composition ex85 to ex799, ey85 to ey799, ez85 to ez799, ea85 to ea799, eax85 to e99799, eaz799, eb85 to eb799, ebx85 to ebx799, eby85 to
  • each composition using a mixture of ⁇ 1 2 parts and ⁇ 2 0.05 parts instead of ⁇ 1 2 parts is collectively referred to as present composition ey. Any one combination of each composition contained in this composition ex and each composition contained in this composition ey is described as this composition e.
  • compositions fa800 to fa864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of tifluzamide (hereinafter referred to as the present compositions fa800 to fa864).
  • compositions fb800 to fb864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of penflufen (hereinafter referred to as the present compositions fb800 to fb864).
  • compositions fc800 to fc864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of sedaxane (hereinafter referred to as the present compositions fc800 to fc864).
  • compositions fd800 to fd864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of floxapyroxide (hereinafter referred to as the present compositions fd800 to fd864).
  • compositions fe800 to fe864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of fluopyram (hereinafter referred to as the present compositions fe800 to fe864).
  • compositions ff800 to ff864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts ethaboxam is a mixture of 2 parts ethaboxam and 2 parts metalaxyl (hereinafter referred to as the present compositions ff800 to ff864).
  • compositions fg800 to fg864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of ethaboxam was changed to 2 parts of metalaxyl (hereinafter referred to as the present compositions fg800 to fg864).
  • compositions fh800 to fh864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of ethaboxam was changed to 2 parts of metalaxyl M (hereinafter referred to as the present compositions fh800 to fh864).
  • compositions fj800 to fj864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of ethaboxam was changed to 2 parts of fluorpicolide (hereinafter referred to as the present compositions fj800 to fj864).
  • compositions fk800 to fk864 Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of ethaboxam was changed to 2 parts of oxathiapiproline (hereinafter referred to as the present compositions fk800 to fk864).
  • the present compositions 800a to 864a the present compositions
  • each composition using a mixture of ⁇ 1 2 parts and ⁇ 2 0.05 parts instead of ⁇ 1 2 parts is collectively referred to as the present composition fy. Any one combination of each composition contained in this composition fx and each composition contained in this composition fy is described as this composition f.
  • Formulation Example 1 Any one of the present composition c, the present composition d, the present composition e, and the present composition f is described in the above [Table 4c], [Table 4d], [Table 4e], or [Table 4f]. Parts by weight, 35 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1) and water were mixed to make a total amount of 100 parts. Obtain a flowable formulation.
  • Formulation Example 3 Any one of the present composition c, the present composition d, the present composition e, and the present composition f is described in the above [Table 4c], [Table 4d], [Table 4e], or [Table 4f].
  • the total weight is 100 parts by adding 1 part by weight, 3 parts of calcium lignin sulfonate, 2 parts of sodium lauryl sulfate, and the remainder of the synthetic silicon hydrated silicon, and pulverize and mix well to obtain each wettable powder.
  • Formulation Example 4 Add any one of the present composition a by weight, the synthetic silicon hydroxide fine powder 1 part, 2 parts calcium lignin sulfonate, 30 parts bentonite and the balance of kaolin clay as described in [Table 4a]. To 100 parts and mix. Next, an appropriate amount of water is added to the mixture, and the mixture is further stirred, granulated by a granulator, and dried by ventilation to obtain each granule.
  • Formulation Example 5 A powder is obtained by mixing any one of the present compositions b with 100 parts by weight, adding 10 parts by weight of talc and 10 parts of talc and the remainder of kaolin clay as described in [Table 4b] etc.
  • Formulation Example 6 Any one of the present composition c, the present composition d, the present composition e, and the present composition f is described in the above [Table 4c], [Table 4d], [Table 4e], or [Table 4f]. 1 part by weight, 15 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1) and water are mixed to make a total amount of 100 parts. Obtain a flowable formulation.
  • each treated seed is treated. obtain. Further, each treated seed can also be obtained by adding 180 grams of oxabetrinyl to 200 ml of each flowable preparation prepared in Preparation Example 1 or 2 and performing a similar smearing treatment.
  • each treated seed is treated. obtain.
  • each treated seed can be obtained by adding 40 grams of fluxofenim to 200 ml of each flowable preparation prepared in Formulation Example 1 or 2, followed by a smear treatment.
  • Each treated seed is treated by smearing 10 ml of each flowable formulation prepared in Formulation Example 1 or 2 on 10 kg of dried corn seed using a rotary seed processing machine (seed dresser, Hans-Ulrich Hege GmbH). obtain.
  • the corn may be a genetically modified corn containing a glyphosate resistance gene or a Bt crystal toxin protein gene.
  • Application example 4 40 kg of each flowable preparation prepared in Formulation Example 1 or 2 is smeared on 10 kg of dried corn seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH), thereby treating each treated seed. obtain.
  • a rotary seed treatment machine seed dresser, Hans-Ulrich Hege GmbH
  • Application Example 6 Treated seeds are obtained by applying 50 g of each wettable powder prepared in Formulation Example 3 to 10 kg of dried corn seeds.
  • Application example 7 By applying 20 ml of each flowable preparation prepared in Preparation Example 1 or 2 to 10 kg of dried soybean seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH), each treated seed is treated. obtain.
  • the soybean may be a genetically modified soybean containing a glyphosate resistance gene or a Bt crystal toxin protein gene.
  • Application example 8 By subjecting 10 kg of dried soybean seeds to 100 ml of each flowable preparation prepared in Formulation Example 1 or 2, using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), each treated seed is treated. obtain.
  • each treated seed is treated. obtain.
  • the cotton may be a genetically modified cotton containing a glyphosate resistance gene or a Bt crystal toxin protein gene.
  • the oilseed rape may be a genetically modified oilseed rape including a glyphosate resistance gene or a Bt crystal toxin protein gene.
  • Application Example 12 50 kg of each dry seed prepared in Formulation Example 1 or 2 is smeared on 10 kg of dried wheat seeds using a rotary seed processing machine (seed dresser, Hans-Ulrich Hege GmbH), thereby treating each treated seed. obtain
  • Test example 1 The corn seeds obtained in Application Example 3 are sown at 15 cm intervals to a depth of 5 cm using a seeder.
  • a high control effect can be obtained against diabrotica pests such as Western corn rootworm, and larvae of the clicks typified by the genus Agriotes and Melanotus (collectively referred to as wire worms).
  • the preparation treated with corn seeds contains a fungicide, the fungicide can have a high control effect against diseases with a control effect.
  • Test example 2 By sowing the soybean seeds obtained in Application Example 7, it is possible to obtain a high control effect against the fly larvae.
  • the preparation treated with soybean contains a bactericidal agent, a high controlling effect can be obtained against diseases for which the bactericidal agent has a controlling effect.
  • nematode control agent When nematode control agent is contained, a high control effect can be acquired with respect to sweet potato nematode.
  • Test example 3 By sowing the oilseed rape seeds obtained in Application Example 10, it is possible to obtain a high control effect against flea beetle larvae. When a fungicide is contained in the preparation treated with oilseed rape seeds, it is possible to obtain a high control effect against diseases for which the fungicide has a control effect.
  • Test example 4 During the seedling period such as seeding or transplanting, the granules obtained in Formulation Example 4 are sprayed on a seedling box at the same time as rice seeding, and the seedling is covered with soil and grown.
  • the seed pods used are seed sterilized with a mixture of ipconazole and cupric hydroxide before sowing.
  • 2.5 Rice seedlings grown in the leaf stage are transplanted to paddy fields using a rice planting machine. After transplanting, spray paddy rice herbicide.
  • a high control effect can be obtained for rice weevil, rice beetle, white planthopper, white-tailed planthopper, white-bellied planthopper, leafhopper leafhopper, white-tailed beetle, wing-bellied moth, yellow-tailed moth, locust.
  • the preparation contains a bactericidal agent, it is possible to obtain a high control effect for diseases in which the bactericidal agent has a control effect, such as rice blast and blight.
  • Test Example 5 In Test Example 4, instead of the granule obtained in Formulation Example 4, a solution obtained by diluting the flowable obtained in Formulation Example 1 or 2 was applied to a rice seedling grown at the 3.5 leaf stage as a watering device. Irrigated using, and transplanted to paddy field with rice planting machine. A high control effect can be obtained for rice weevil, rice beetle, white planthopper, white-tailed planthopper, white-bellied planthopper, leafhopper leafhopper, white-tailed beetle, wing-bellied moth, yellow-tailed moth, locust.
  • Test Example 6 Rice seed cake obtained by applying the diluted solution of the flowable agent obtained in Formulation Example 1 is sown in a paddy field.
  • a high control effect can be obtained for rice weevil, rice beetle, white planthopper, white-tailed planthopper, white-bellied planthopper, leafhopper leafhopper, white-tailed beetle, wing-bellied moth, yellow-tailed moth, locust.
  • the preparation contains a bactericidal agent, it is possible to obtain a high control effect for diseases in which the bactericidal agent has a control effect, such as rice blast and blight.

Abstract

La présente invention concerne une composition pesticide qui contient un composé représenté par la formule (1) ou un composé représenté par la formule (2), ou un N-oxyde de celui-ci, et un ou plusieurs composés choisis parmi les groupes A à D ci-dessous, et qui présente un excellent effet de lutte contre les nuisibles. Groupe A : bactéricide ; groupe B : insecticide/acaricide ; groupe C : phytoprotecteur ; groupe D : régulateur de la croissance des plantes
PCT/JP2015/068167 2014-07-04 2015-06-24 Composition pesticide et son application WO2016002594A1 (fr)

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CN114450280A (zh) * 2019-09-20 2022-05-06 先正达农作物保护股份公司 具有含硫和亚砜亚胺取代基的杀有害生物活性杂环衍生物
US11324221B2 (en) 2016-02-01 2022-05-10 Sumitomo Chemical Company, Limited Pest control composition and pest control method

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