Classifications

• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
  • C07C319/26—Separation; Purification; Stabilisation; Use of additives
  • C07C319/28—Separation; Purification
  • C07C319/30—Separation; Purification from the by-products of refining mineral oils

Definitions

• the present disclosure relates to a process for obtaining di-sulfide oil having sodium level below 0.1 ppm.
• Di-sulfide oil is a low value by-product of Liquefied Petroleum Gas (LPG) desulfurization process.
• LPG Liquefied Petroleum Gas
• LPG laden with mercaptan is treated with NaOH solution in the presence of a homogeneous catalyst to extract mercaptans from the LPG.
• the di-sulfide oil which is produced as a waste or as a by-product stream during the LPG desulfurization process comprises a relatively high concentration of sodium which makes the di-sulfide oil inappropriate for a number of applications.
• the relatively high concentration of sodium may be due to the presence of unreacted R-S-Na or due to micro-emulsion formation of R-S-S-R with NaOH solution.
• the di-sulfide oil obtained from the LPG desulfurization process is sent to a hydrotreater for further processing as a low value stream. Notwithstanding the fact that the di-sulfide oil comprises a relatively high concentration of sodium, the presence of a minimum of 60% sulfur makes it a potential substitute for a number of sulfur containing high value chemical compounds which are used in a number of applications. However, the presence of a relatively high concentration of sodium prevents its use in other applications.
• a PCT Publication No. 2005/111175 discloses the use of sulfur oil which is a mixture of organic disulfides having C2-C4 for inhibiting coke formation on the surface and/or coils of a pyrolysis furnace.
• the sulfur oil used in the process of the aforementioned PCT application is a low value product obtained from LPG Mercaptan oxidation units and comprises relatively high concentration of sodium (around 1 ppm). The presence of relatively high level of sodium in the sulfur oil can be detrimental to the reactions wherein the sulfur oil is used.
• di-sulfide oil sulfur oil
• higher amount of sodium i.e. (> lppm) contained therein forms sodium oxide and deposits on the surface of the heater tube as a passive layer which inhibits heat transfer and results in coke formation on the heater tube.
• high amount of sodium present in the di-sulfide oil reacts with the hydrothermal cracking catalyst and forms a sodium aluminate layer on catalyst active sites.
• sodium reacts with active metals present in the catalyst composition and forms an alloy which eventually leads to reduced catalytic activity.
• Another object of the present disclosure is to provide a process for obtaining di-sulfide oil (sulfur oil) having sodium level below 0.1 ppm, the di-sulfide oil being obtained as a waste or as a by-product stream from the LPG desulfurization process.
• Still another object of the present disclosure is to provide a process for obtaining di-sulfide oil having sodium level below 0.1 ppm; the process being very simple, efficient and economical.
• Yet another object of the present disclosure is to provide a useful and economical alternative to the existing anti-coking additives and sulfiding agents which are used in a number of processes including, but not limited to, hydro-treating and hydro-processing.
• the present disclosure provides a process for obtaining di-sulfide oil having sodium level below 0.1 ppm, said process comprising passing a stream comprising di-sulfide oil having sodium level of 1 ppm through an alumina bed packed in a column, at a liquid hourly space velocity (LHSV) ranging from 0.5 to 5.0 hr "1 and at a pre-determined temperature to obtain a treated stream comprising di-sulfide oil having sodium level below 0.1 ppm.
• LHSV liquid hourly space velocity
• the liquid hourly space velocity (LHSV) can range from 0.5 to 2 hr "1 .
• liquid hourly space velocity ranges from 1.0 to 1.5 hr "1 .
• the pre-determined temperature can vary from 10 to 40 °C.
• the pre-determined temperature varies from 20 to 30 °C.
• the treated stream comprising di-sulfide oil can have sodium level below 0.05 ppm. In one embodiment, the treated stream comprising di-sulfide oil has sodium level below 0.02 ppm.
• the treated stream comprising di-sulfide oil has sodium level of 0.01 ppm.
• the alumina is characterized by the following properties: average particle size ranging from 0.3 to 0.7mm; pore volume ranging from 44.1 to 71.9 cm /100g; surface area ranging from 195 to 331 m 2 /g and density ranging from 543 to 829 kg/m 3.
• a stream comprising di-sulfide oil obtained as a waste or as a byproduct stream during the LPG desulfurization process, comprises a relatively high concentration of sodium which makes it unacceptable for a number of applications such as use as an anti-coking agent in thermo-cracking processes.
• the present process described herein below reduces the sodium content in di-sulfide oil streams to an amount which is even lower than the standard acceptable range of 1 ppm; thereby making the di-sulfide oil useful for a number of applications.
• the process of the present disclosure is most suitable for reducing the sodium content of the di-sulfide oil streams originally having sodium content of about 1 ppm.
• the disulfide oil stream has sodium content of more than 1 ppm, it is first made to undergo treatment in one way or the other, to obtain a stream having sodium content of about 1 ppm.
• the means of treatment mentioned herein above include processes such as dilution where the high sodium concentration stream is diluted with a low sodium concentration stream to yield a stream having an intermediate or the desired sodium concentration.
• the present disclosure provides a process for obtaining di-sulfide oil having sodium level below 0.1 ppm; the process comprising the steps of obtaining a stream comprising di-sulfide oil having sodium level of 1 ppm from LPG desulfurization units and passing the stream through an adsorbent bed under pre-determined operating conditions of volume, time and temperature to obtain a treated stream that comprises di-sulfide oil having sodium level below 0.1 ppm.
• the di-sulfide oil streams are obtained as a waste or a by-product stream from LPG desulfurization process.
• the di-sulfide oil in accordance with present disclosure comprises at least one C2-C4 containing alkyl disulfides selected from the group consisting of dimethyl disulfide, ethyl methyl disulfide, diethyl disulfide and the like.
• the adsorbent used in the process of the present disclosure is an inorganic oxide based adsorbent.
• Example of inorganic oxide based adsorbent suitable for the process of the present disclosure includes alumina.
• the inventors of the present disclosure have used multiple varieties of alumina which differ in their characteristic attributes such as density, pore volume and surface area in order to optimize the process of the present disclosure.
• the alumina which is useful for the purpose of the present disclosure is activated alumina with high adsorption capacity owing to its specific surface area and tailored pore size distribution.
• the alumina used in the process of the present disclosure is characterized by the following properties: average particle size ranging from 0.3 to 0.7mm; pore volume ranging from 44.1 to 71.9 cm 3 /100g; surface area ranging from 195 to 331 m 2 /g and density ranging from 543 to 829 kg/m . Further, the alumina used in the process of the present disclosure may be of different shapes such as spheres, extrudates, granules and rings.
• the alumina adsorbent is packed in a glass column fitted with a flow control stop cock.
• the stream comprising the di-sulfide oil is stored in a separating funnel provided at the top of the glass column.
• the stream is then passed though the column packed with the alumina adsorbent at a pre-determined liquid hourly space velocity and at a pre-determined temperature.
• the liquid hourly space velocity typically ranges from 0.5 to 5 hr 1 .
• the liquid hourly space velocity ranges from 0.5 to 2 hr "1 .
• the liquid hourly space velocity ranges from 1.0 to 1.5 hr _1 .
• the liquid hourly space velocity of the stream passing through the column packed with the alumina adsorbent is controlled though the column and the separating funnel stoppers.
• the pre-determined temperature typically ranges from 10 to 40 °C. In accordance with one of the embodiments of the present disclosure, the temperature ranges from 20 to 30 °C.
• the stream passing though the column packed with the alumina adsorbent is collected at every 2 hour interval (hereinafter referred to as a treated stream) and subjected to atomic absorption spectroscopy (AAS) and inductively coupled plasma mass spectroscopy (ICPMS) analysis to measure the sodium level.
• AAS atomic absorption spectroscopy
• ICPMS inductively coupled plasma mass spectroscopy
• AAS and ICPMS results show that the amount of sodium in the treated stream is below 0.1 ppm. In some experiments, the amount of the sodium in the treated stream was found to be below 0.05 ppm, in some other experiments it was found to be below 0.02 ppm and in some other, 0.01 ppm.
• the alumina based adsorbent used in the process of the present disclosure demonstrates excellent adsorption efficiency for the sodium metal present in the di-sulfide oil.
• the sodium removal efficiency of the alumina adsorbent typically ranges from 98.7 to 99.7 %.
• the alumina based adsorbent is capable of treating the di-sulfide oil which is at least 200 times the volume of alumina used.
• the efficiency of the treated stream containing di-sulfide oil having sodium level below 0.1 ppm was evaluated in a number of applications that include, but are not limited to, its use as an anti-coking additive in the thermal cracking process, as a sulfiding agent for the pre- sulfidization of catalysts used in the hydro-treating and hydro-cracking process and in the hydrogenation of non-edible vegetable oils to produce bio-fuels.
• Example- 1 Process for reducing sodium content in the di-sulfide oil in accordance with the present disclosure
• a stream comprising di-sulfide oil (sulfur oil), produced as a waste or as a by-product stream from mercaptan oxidation units of a refining complex was used in the following examples.
• Various properties of the stream are presented in Table 1.
• Table- 1 Characteristic properties of the di-sulfide oil (sulfur oil) used in the present process
• the oil obtained from mercaptan oxidation units of a refining complex was stored in a 1 liter separating funnel located at the top of a glass column (45 cm height and 3.2 cm diameter) containing alumina. 30 g (-48 ml) of alumina (Aj) was poured into the glass column having a flow control stop cock. The alumina having the following characteristic attributes was used: average particle size: 0.5 mm; density: 629 kg/m 3 ; pore volume: 68.9 cm 3 /100g and surface area: 195 m /g.
• the oil stream contained in the funnel was passed through the column at ambient temperature (25 °C) with a liquid hourly space velocity (LHSV) of 1.25 h "1 .
• LHSV liquid hourly space velocity
• the LHSV was controlled through the funnel and column stoppers.
• the stream after passing though the alumina bed (referred to as a treated stream) was collected at every 2 hours interval and subjected to AAS (atomic absorption spectroscopy) and inductively coupled plasma mass spectroscopy (ICPMS) for the measurement of Na level.
• AAS atomic absorption spectroscopy
• ICPMS inductively coupled plasma mass spectroscopy
• the amount of Na in the treated sample was found to be 0.01 ppm.
• Example-2 Process for reducing sodium content in di-sulfide oil in accordance with the present disclosure
• the treatment of the di-sulfide oil was carried out in the same manner as described in Example- 1, except that the alumina adsorbent that was used, had higher density, lower pore volume and lower surface area (A 2 ) [as compared to the alumina used in Example 1 (Aj)].
• Characteristic attributes of the alumina adsorbent used in the present Example (A 2 ) are provided herein under, in Table-2.
• the amount of Na in the treated stream was analyzed similar to example- 1 and was found to be 0.04 ppm.
• Example-3 Process for reducing sodium content in di-sulfide oil in accordance with the present disclosure
• the treatment of the di-sulfide oil was carried out in the same manner as described in example- 1 , except that the alumina adsorbent that was used, had lower density and higher pore volume and higher surface area (A 3 ) [as compared to the alumina used in Example 1 (Aj)]. Characteristic attributes of the alumina adsorbent used in the present Example (A 3 ) have already been provided in Table-2.
• the sodium removal efficiency of the alumina adsorbents Aj, A2 and A3 is provided in Table- 3.
• Example-4 Process for reducing sodium content in di-sulfide oil in accordance with the present disclosure
• the treatment of the di-sulfide oil was carried out in the same manner as described in example- 1, except that the liquid hourly space velocity (LHSV) of the di-sulfide oil stream was maintained at 2 hr 1 .
• the amount of Na in the treated di-sulfide oil was analyzed similar to example-1 and was found to be 0.04 ppm.
• Example-5 Laboratory process for reducing sodium content in di-sulfide oil in accordance with the present disclosure
• the treatment of the di-sulfide oil was carried out in the same manner as described in example-1, except the liquid hourly space velocity (LHSV) of the di-sulfide oil stream was maintained at 5 hr "1 .
• the amount of Na in the treated di-sulfide oil was analyzed similar to example-1 and was found to be 0.1 ppm.
• Example-6 Process for reducing sodium content in di-sulfide oil in accordance with the present disclosure
• the sodium removal efficiency of the present process can be proportionately improved by keeping the liquid hourly space velocity (LHSV) of the oil stream and the temperature conditions of the column constant.
• LHSV liquid hourly space velocity
• the sodium removal efficiency of the present process can be proportionately improved by keeping the type of alumina and the temperature conditions of the column constant.
• Varying temperature in the ambient temperature range does not affect the sodium removal efficiency of the present process, when the liquid hourly space velocity (LHSV) of the oil stream, the type of alumina and the temperature conditions of the column are maintained at a constant.
• LHSV liquid hourly space velocity
• the present disclosure relates to a process for removal of Na from di-sulfide oil and has several technical advancements, including but not limited to:
• DMDS di-methyl disulfide
• An economic alternative to the existing anti-coking agent for example di-methyl disulfide (DMDS)
• DMDS di-methyl disulfide
• An economic alternative to the existing sulfiding agents such as di-methyldisulfide (DMDS) used in the hydro-processing of non-edible vegetable oils to produce bio-jet or bio-diesel
• DMDS di-methyldisulfide

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• Oil, Petroleum & Natural Gas (AREA)
• Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

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• 2015
  • 2015-03-13 ES ES15761919T patent/ES2719750T3/es active Active
  • 2015-03-13 WO PCT/IB2015/051846 patent/WO2015136491A1/en not_active Ceased
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