ES2719750T3 - Proceso para la retirada de sodio de aceite de disulfuro - Google Patents
Proceso para la retirada de sodio de aceite de disulfuro Download PDFInfo
- Publication number
- ES2719750T3 ES2719750T3 ES15761919T ES15761919T ES2719750T3 ES 2719750 T3 ES2719750 T3 ES 2719750T3 ES 15761919 T ES15761919 T ES 15761919T ES 15761919 T ES15761919 T ES 15761919T ES 2719750 T3 ES2719750 T3 ES 2719750T3
- Authority
- ES
- Spain
- Prior art keywords
- ppm
- sodium
- disulfide oil
- oil
- stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011734 sodium Substances 0.000 title claims abstract description 75
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 title claims abstract description 66
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims abstract description 66
- 229910052708 sodium Inorganic materials 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 62
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 239000011148 porous material Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 5
- 101100352919 Caenorhabditis elegans ppm-2 gene Proteins 0.000 claims 1
- 239000003921 oil Substances 0.000 description 71
- 235000019198 oils Nutrition 0.000 description 71
- 239000003463 adsorbent Substances 0.000 description 19
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 15
- 239000003915 liquefied petroleum gas Substances 0.000 description 15
- 239000011593 sulfur Substances 0.000 description 15
- 229910052717 sulfur Inorganic materials 0.000 description 15
- 238000006477 desulfuration reaction Methods 0.000 description 14
- 230000023556 desulfurization Effects 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 12
- 239000000571 coke Substances 0.000 description 11
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 5
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 4
- 239000002551 biofuel Substances 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000004227 thermal cracking Methods 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- CETBSQOFQKLHHZ-UHFFFAOYSA-N Diethyl disulfide Chemical compound CCSSCC CETBSQOFQKLHHZ-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- -1 dialkyl disulfides Chemical class 0.000 description 2
- 150000002019 disulfides Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 208000003173 lipoprotein glomerulopathy Diseases 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 150000008427 organic disulfides Chemical class 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical group [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/26—Separation; Purification; Stabilisation; Use of additives
- C07C319/28—Separation; Purification
- C07C319/30—Separation; Purification from the by-products of refining mineral oils
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IB2015/051846 WO2015136491A1 (en) | 2014-03-14 | 2015-03-13 | A process for the removal of sodium from di-sulfide oil |
| IN852MU2014 IN2014MU00852A (https=) | 2014-03-14 | 2015-03-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2719750T3 true ES2719750T3 (es) | 2019-07-12 |
Family
ID=54071022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES15761919T Active ES2719750T3 (es) | 2014-03-14 | 2015-03-13 | Proceso para la retirada de sodio de aceite de disulfuro |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US9790175B2 (https=) |
| EP (1) | EP3116853B1 (https=) |
| ES (1) | ES2719750T3 (https=) |
| IN (1) | IN2014MU00852A (https=) |
| WO (1) | WO2015136491A1 (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10240096B1 (en) | 2017-10-25 | 2019-03-26 | Saudi Arabian Oil Company | Integrated process for activating hydroprocessing catalysts with in-situ produced sulfides and disulphides |
| US11459513B2 (en) | 2021-01-28 | 2022-10-04 | Saudi Arabian Oil Company | Steam cracking process integrating oxidized disulfide oil additive |
| WO2025141385A1 (en) * | 2023-12-28 | 2025-07-03 | Reliance Industries Limited | Process for removal of sodium from di-sulfide oil using zeolite adsorbent |
| WO2025141383A1 (en) * | 2023-12-28 | 2025-07-03 | Reliance Industries Limited | Process for removal of sodium from di-sulfide oil using activated carbon as adsorbent |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE607986C (de) * | 1931-05-13 | 1935-01-17 | Standard Oil Dev Co | Verfahren zur Gewinnung von organischen Disulfiden |
| DE1155453B (de) * | 1959-04-24 | 1963-10-10 | Universal Oil Prod Co | Verfahren zur Abtrennung von Merkaptanen aus sauren OElen |
| WO2001096499A1 (en) * | 2000-06-10 | 2001-12-20 | Sk Corporation | The method for using disulfide mixture as a sulfiding agent |
| CN1245488C (zh) | 2001-11-13 | 2006-03-15 | 北京三聚环保新材料有限公司 | 工业化精制液化石油气的方法 |
| WO2005111175A1 (en) * | 2004-05-17 | 2005-11-24 | Indian Petrochemicals Corporation Limited | Process for thermal cracking hydrocarbons |
| US7833499B2 (en) * | 2007-06-14 | 2010-11-16 | Merichem Company | Separation process |
| US9302204B2 (en) * | 2012-08-14 | 2016-04-05 | Uop Llc | Process for purifying a disulfide oil and an apparatus relating thereto |
-
2015
- 2015-03-13 ES ES15761919T patent/ES2719750T3/es active Active
- 2015-03-13 WO PCT/IB2015/051846 patent/WO2015136491A1/en not_active Ceased
- 2015-03-13 IN IN852MU2014 patent/IN2014MU00852A/en unknown
- 2015-03-13 US US15/121,535 patent/US9790175B2/en active Active
- 2015-03-13 EP EP15761919.8A patent/EP3116853B1/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP3116853A4 (en) | 2017-11-15 |
| EP3116853B1 (en) | 2019-01-09 |
| US20160362363A1 (en) | 2016-12-15 |
| US9790175B2 (en) | 2017-10-17 |
| EP3116853A1 (en) | 2017-01-18 |
| WO2015136491A1 (en) | 2015-09-17 |
| IN2014MU00852A (https=) | 2015-09-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2402043T3 (es) | Desulfuración profunda de nafta en dos etapas con formación reducida de mercaptanos | |
| ES2719750T3 (es) | Proceso para la retirada de sodio de aceite de disulfuro | |
| ES2881659T3 (es) | Materiales de desulfuración | |
| EP2032677B1 (en) | Catalytic hydrodeoxygenation of an oxygenate feedstock | |
| US7901486B2 (en) | Removal of heavy metals from hydrocarbon gases | |
| US7785461B2 (en) | Process for selective hydrodesulfurization of naphtha | |
| JP2004513214A (ja) | 低硫黄燃料 | |
| RU2016129141A (ru) | Регулирование уровня серы дегидрогенизацией пропана | |
| ES2655285T3 (es) | Tratamiento térmico para eliminación de mercaptanos de la nafta | |
| RU2008145518A (ru) | Двухстадийный способ обессеривания олефиновых бензинов, содержащих мышьяк | |
| AU2009296778B2 (en) | Mercury removal process | |
| BR112014017691A2 (pt) | processo e catalisador para produção de hidrogênio | |
| US20180245006A1 (en) | Copper adsorbent for acetylene converter guard bed | |
| JP2008525586A (ja) | 段間分離を含む、選択的水素化脱硫およびメルカプタン分解プロセス | |
| JP5755999B2 (ja) | 脱硫剤の製造方法、脱硫剤、および、炭化水素の脱硫方法 | |
| US9550167B2 (en) | Method for preparing hollow carbon structure using cracking reaction of heavy hydrocarbon fraction | |
| JP4767169B2 (ja) | オレフィン飽和に対する水素化脱硫の選択性を向上するためのオレフィン質ナフサ原料ストリームからの窒素除去 | |
| JP5911551B2 (ja) | 脱硫剤の製造方法および炭化水素の脱硫方法 | |
| RU2547480C1 (ru) | Адсорбент для удаления сераорганических соединений из жидкого углеводородного топлива и способ его получения | |
| CN119702081A (zh) | 一种焦化粗苯加氢精制的协同催化剂及其制备方法和用途 | |
| US12420257B2 (en) | Silicon trapping mass | |
| WO2009111715A3 (en) | A catalyst and process for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock | |
| US11000821B2 (en) | Enhancement of reduction resistance for manganese oxide adsorbents | |
| RU2015149238A (ru) | Активация паром самоактивирующегося катализатора процесса гидрообработки | |
| KR20140080803A (ko) | 액상 연료의 탈황 장치 및 이를 이용한 탈황 방법 |