WO2015122722A1 - 공중합체 및 이를 포함하는 유기 태양 전지 - Google Patents
공중합체 및 이를 포함하는 유기 태양 전지 Download PDFInfo
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- WO2015122722A1 WO2015122722A1 PCT/KR2015/001491 KR2015001491W WO2015122722A1 WO 2015122722 A1 WO2015122722 A1 WO 2015122722A1 KR 2015001491 W KR2015001491 W KR 2015001491W WO 2015122722 A1 WO2015122722 A1 WO 2015122722A1
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Abstract
Description
활성층 | VOC(V) | JSC (mA/cm2) | FF (%) | PCE(%) | |
실험예 1 | 공중합체1/PC61BM = 1:2 | 0.85 | 10.3 | 60.4 | 5.29 |
실험예 2 | 공중합체2/PC61BM = 1:2 | 0.89 | 9.1 | 58.2 | 4.71 |
실험예 3 | 공중합체3/PC61BM = 1:2 | 0.84 | 10.0 | 56.0 | 4.70 |
실험예 4 | 공중합체4/PC61BM = 1:2 | 0.79 | 8.6 | 61.0 | 4.14 |
실험예 5 | 공중합체5/PC61BM = 1:2 | 0.88 | 9.8 | 57.8 | 4.98 |
비교실험예 1 | 공중합체6/PC61BM = 1:2 | 0.81 | 7.2 | 56.3 | 3.28 |
비교실험예 2 | 공중합체7/PC61BM = 1:2 | 0.81 | 6.6 | 59.7 | 3.19 |
비교실험예 3 | 공중합체8/PC61BM = 1:2 | 0.85 | 8.6 | 43.0 | 3.14 |
비교실험예 4 | 공중합체8/PC61BM = 1:3 | 0.78 | 6.2 | 42 | 2.05 |
비교실험예 5 | 공중합체9/PC61BM = 1:2 | 0.68 | 0.9 | 50.1 | 0.32 |
Claims (16)
- 하기 화학식 1로 표시되는 제1 단위;하기 화학식 2로 표시되는 제2 단위; 및하기 화학식 3으로 표시되는 제 3단위를 포함하는 공중합체:[화학식 1][화학식 2][화학식 3]화학식 1 내지 3에 있어서,a 및 b는 각각 1 내지 3의 정수이고,a가 2 이상인 경우, 2 이상의 L1은 서로 동일하거나 상이하며,b가 2 이상인 경우, 2 이상의 L2는 서로 동일하거나 상이하고,L1 및 L2는 서로 동일하거나 상이하고, 각각 독립적으로 공액 구조며,R1 및 R2는 서로 동일하거나 상이하고, 각각 독립적으로, 상기 L1 및 L2의 공액 구조에 치환되는 치환기로, 수소; 중수소; 할로겐기; 니트릴기; 니트로기; 이미드기; 아미드기; 히드록시기; 치환 또는 비치환된 알킬기; 치환 또는 비치환된 시클로알킬기; 치환 또는 비치환된 알콕시기; 치환 또는 비치환된 아릴옥시기; 치환 또는 비치환된 알킬티옥시기; 치환 또는 비치환된 아릴티옥시기; 치환 또는 비치환된 알킬술폭시기; 치환 또는 비치환된 아릴술폭시기; 치환 또는 비치환된 알케닐기; 치환 또는 비치환된 실릴기; 치환 또는 비치환된 붕소기; 치환 또는 비치환된 알킬아민기; 치환 또는 비치환된 아랄킬아민기; 치환 또는 비치환된 아릴아민기; 치환 또는 비치환된 헤테로아릴아민기; 치환 또는 비치환된 아릴기; 및 N, O 및 S 원자 중 1개 이상을 포함하는 치환 또는 비치환된 헤테로고리기로 이루어진 군으로부터 1 또는 2 이상이 선택되고,X1 및 X2는 서로 동일하거나 상이하고, 각각 독립적으로 CRR', NR, O, SiRR', PR, S, GeRR', Se 또는 Te이며,R, R' 및 R3 내지 R5는 서로 동일하거나 상이하고, 각각 독립적으로 수소; 중수소; 할로겐기; 니트릴기; 니트로기; 이미드기; 아미드기; 히드록시기; 치환 또는 비치환된 알킬기; 치환 또는 비치환된 시클로알킬기; 치환 또는 비치환된 알콕시기; 치환 또는 비치환된 아릴옥시기; 치환 또는 비치환된 알킬티옥시기; 치환 또는 비치환된 아릴티옥시기; 치환 또는 비치환된 알킬술폭시기; 치환 또는 비치환된 아릴술폭시기; 치환 또는 비치환된 알케닐기; 치환 또는 비치환된 실릴기; 치환 또는 비치환된 붕소기; 치환 또는 비치환된 알킬아민기; 치환 또는 비치환된 아랄킬아민기; 치환 또는 비치환된 아릴아민기; 치환 또는 비치환된 헤테로아릴아민기; 치환 또는 비치환된 아릴기; 또는 N, O 및 S 원자 중 1개 이상을 포함하는 치환 또는 비치환된 헤테로고리기이다.
- 청구항 1에 있어서,공액 구조는 아릴렌기; N, O, S, Se, Te, Ge 및 P 원자 중 1 개 이상을 포함하는 방향족 헤테로고리기; 또는 1 또는 2 이상의 비닐렌기를 포함하는 것인 공중합체.
- 청구항 1에 있어서,R1 및 R2는 서로 동일하거나 상이하고, 각각 독립적으로 치환 또는 비치환된 탄소수 1 내지 20의 직쇄 또는 분지쇄의 알킬기; 또는 치환 또는 비치환된 탄소수 1 내지 20의 직쇄 또는 분지쇄의 알콕시기인 것인 공중합체.
- 청구항 1에 있어서,R3 내지 R5는 서로 동일하거나 상이하고, 각각 독립적으로 수소; 또는 치환 또는 비치환된 탄소수 1 내지 20의 직쇄 또는 분지쇄의 알킬기인 것인 공중합체.
- 청구항 1에 있어서,상기 제1 단위, 제2 단위 및 제3 단위의 몰수의 합에 대하여, 상기 제1 단위와 제3 단위의 합의 몰비는 0.5 이상인 것인 공중합체.
- 청구항 1에 있어서,상기 공중합체의 수평균 분자량은 500 g/mol 내지 1,000,000 g/mol인 공중합체.
- 청구항 1에 있어서,상기 공중합체의 분자량 분포는 1 내지 100인 공중합체.
- 청구항 1에 있어서,상기 공중합체는 랜덤 공중합체인 것인 공중합체.
- 제1 전극; 상기 제1 전극과 대향하여 구비되는 제2 전극; 및 상기 제1 전극과 상기 제2 전극 사이에 구비되고, 광활성층을 포함하는 1층 이상의 유기물층을 포함하고, 상기 유기물층 중 1층 이상은 청구항 1 내지 9 중 어느 하나의 항에 따른 공중합체를 포함하는 것인 유기 태양 전지.
- 청구항 10에 있어서,상기 유기물층은 정공 수송층, 정공 주입층 또는 정공 수송과 정공 주입을 동시에 하는 층을 포함하고,상기 정공 수송층, 정공 주입층 또는 정공 수송과 정공 주입을 동시에 하는 층은 상기 공중합체를 포함하는 유기 태양 전지.
- 청구항 10에 있어서,상기 유기물층은 전자주입층, 전자 수송층 또는 전자 주입과 전자 수송을 동시에 하는 층을 포함하고,상기 전자주입층, 전자 수송층 또는 전자 주입과 전자 수송을 동시에 하는 층은 상기 공중합체를 포함하는 유기 태양 전지.
- 청구항 10에 있어서,상기 광활성층은 전자 주개 및 전자 받개로 이루어진 군에서 선택되는 1 또는 2 이상을 포함하고,상기 전자 주개는 상기 공중합체를 포함하는 것인 유기 태양 전지.
- 청구항 13에 있어서,상기 전자 주개 및 전자 받개는 벌크 헤테로 정션(BHJ)을 구성하는 것인 유기 태양 전지.
- 청구항 10에 있어서,상기 광활성층은 n 형 유기물층 및 p 형 유기물층을 포함하는 이층 박막(bilayer) 구조이며,상기 p형 유기물층은 상기 공중합체를 포함하는 것인 유기 태양 전지.
- 청구항 10에 있어서,상기 유기 태양 전지는 정공주입층, 정공수송층, 정공차단층, 전하발생층, 전자차단층, 전자주입층 및 전자수송층으로 이루어진 군에서 선택되는 1 또는 2 이상의 유기물층을 더 포함하는 것인 유기 태양 전지.
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KR (1) | KR101631017B1 (ko) |
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WO2017155362A1 (ko) * | 2016-03-11 | 2017-09-14 | 주식회사 엘지화학 | 유기 태양전지 및 이의 제조방법 |
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KR101687807B1 (ko) * | 2014-10-27 | 2017-01-02 | 주식회사 엘지화학 | 유기 태양전지용 잉크 조성물 및 이를 이용한 유기 태양전지 제조방법 |
KR101968899B1 (ko) * | 2016-01-27 | 2019-04-15 | 주식회사 엘지화학 | 공중합체 및 이를 포함하는 유기 태양 전지 |
KR102074550B1 (ko) * | 2016-09-13 | 2020-02-06 | 주식회사 엘지화학 | 공중합체 및 이를 포함하는 유기 태양 전지 |
CN110168762B (zh) * | 2017-06-23 | 2023-05-19 | 株式会社Lg化学 | 有机太阳能电池 |
US11283033B2 (en) * | 2018-03-09 | 2022-03-22 | Lg Chem, Ltd. | Composition for organic layer of organic solar cell and organic solar cell |
CN113831509B (zh) * | 2020-06-23 | 2022-09-23 | 南开大学 | 可溶液处理的共价有机框架材料及其制备方法和用途 |
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Also Published As
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JP6174803B2 (ja) | 2017-08-02 |
TWI550929B (zh) | 2016-09-21 |
TW201543730A (zh) | 2015-11-16 |
US20160204349A1 (en) | 2016-07-14 |
CN105473635A (zh) | 2016-04-06 |
EP3018160A4 (en) | 2017-01-04 |
EP3018160B1 (en) | 2020-07-15 |
EP3018160A1 (en) | 2016-05-11 |
KR101631017B1 (ko) | 2016-06-15 |
US9660194B2 (en) | 2017-05-23 |
KR20150096339A (ko) | 2015-08-24 |
CN105473635B (zh) | 2017-11-28 |
JP2016525627A (ja) | 2016-08-25 |
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