WO2015098265A1 - Composition d'agent nettoyant en poudre - Google Patents

Composition d'agent nettoyant en poudre Download PDF

Info

Publication number
WO2015098265A1
WO2015098265A1 PCT/JP2014/078322 JP2014078322W WO2015098265A1 WO 2015098265 A1 WO2015098265 A1 WO 2015098265A1 JP 2014078322 W JP2014078322 W JP 2014078322W WO 2015098265 A1 WO2015098265 A1 WO 2015098265A1
Authority
WO
WIPO (PCT)
Prior art keywords
less
mass
acid
component
water
Prior art date
Application number
PCT/JP2014/078322
Other languages
English (en)
Japanese (ja)
Inventor
石塚仁
黎俊傑
吉岡佐知子
Original Assignee
花王株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 花王株式会社 filed Critical 花王株式会社
Priority to CN201480062759.0A priority Critical patent/CN105745316B/zh
Publication of WO2015098265A1 publication Critical patent/WO2015098265A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers

Definitions

  • Japanese Patent Application Laid-Open No. 2007-238861 exhibits excellent cleaning power against food-derived oil stains due to alkali components, but when used in a dishwasher or in a “speed course”, alkali components remain in the dishes after use. In some cases, slipping occurred. For this reason, there has been a demand for a further improvement in cleaning power that can suppress sliminess even in detergents for dishwashers.
  • the condition of the cleaning pH after dilution with water described later is important.
  • citric acid, malonic acid, maleic acid, fumaric acid, formic acid, oxalic acid, propionic acid, lactic acid, acetic acid, malic acid, tartaric acid, succinic acid, glycolic acid, benzoic acid, salicylic acid, phthalic acid, 1,2,3 A carboxylic acid selected from benzenetricarboxylic acid, 1,2,4,5-benzenetetracarboxylic acid and salts thereof, citric acid, malonic acid, succinic acid, maleic acid, fumaric acid, tartaric acid, malic acid, 1 , 2,3-benzenetricarboxylic acid, 1,2,4,5-benzenetetracarboxylic acid, and carboxylic acids selected from salts thereof are more preferable, citric acid, malonic acid, succinic acid, maleic acid, 1,2 More preferred are carboxylic acids selected from 1,3-benzenetricarboxylic acid, 1,2,4,5-benzenetetracarboxylic acid, and salts
  • the mass ratio of component (d) / component (a) is preferably 0/100 or more, and preferably 70/30 or less, more preferably 60/40 or less, more preferably 50/50 or less, more preferably Is 40/60 or less, more preferably 30/70 or less.
  • the lower limit value of the mass ratio of the component (d) / the component (a) is preferably 5/95 or more, more preferably 10/90 or more, more preferably 15/85 or more.
  • the mass ratio of component (d) / component (a) is the mass ratio of the content of component (d) to the content of component (a).
  • the powder cleaning composition of the present invention has a pH of 2.5 or higher, preferably 2.6 or higher, more preferably 2.6 or higher when diluted 300-fold with 20 ° C. water from the viewpoint of safety for hands during cleaning.
  • From the viewpoint of detergency against oil stains it is 6.5 or less, preferably 6.0 or less, more preferably 5.5 or less, and more preferably 5.0 or less.
  • the inorganic carbonate having a solubility in 100 g of water at 20 ° C. of less than 0.1 g does not lower the pH at the time of washing, and therefore can be arbitrarily blended in such an amount that does not impair the effects of the present invention. .
  • the solubility of this inorganic carbonate is less than 0.1 g, preferably 0.05 g or less, and more preferably 0.02 g or less.
  • the content of the inorganic carbonate having a solubility in 100 g of water at 20 ° C. of less than 0.1 g is preferably 5% by mass or more, more preferably 8% by mass or more, more preferably 10% by mass in the composition. % Or more.
  • Contaminated dish 0.7 g of egg yolk applied as uniformly as possible to a ceramic dish with a diameter of 103 mm and denatured at 115 ° C. for 1 hour
  • Water used hardness 10 ° dH, alkalinity 100 mg / L (CaCO 3 equivalent), pH 7.5 Water, 2.2L
  • Washing machine Panasonic dishwasher (model NP-60SS5)
  • Cleaning course Speed course detergent composition added amount: 6g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne une composition d'agent nettoyant en poudre contenant (a) un tensioactif anionique, (b) un acide carboxylique dont la constante de dissociation d'acide primaire est située entre 1 et 5, valeurs extrêmes comprises, la constante de dissociation acide maximale est de 7 ou moins et le poids moléculaire est situé entre 46 et 5000, valeurs extrêmes comprises, et (c) une ou plusieurs espèces de composés choisies parmi les sulfates inorganiques et les composés halogénés inorganiques, chacune dans une plage prédéterminée. La composition d'agent nettoyant en poudre présente une teneur de 10 % en masse ou moins de carbonate inorganique dont la solubilité est de 0,1 g ou plus dans 100 g d'eau à 20°C. La composition d'agent nettoyant en poudre contient, dans un rapport massique spécifique et servant de (a), un sel d'ester d'alkylsulfate et une ou plusieurs espèces choisies parmi les sels d'ester de polyoxyéthylène-alkylsulfate spécifiques et les alkylbenzènesulfonates spécifiques. Le rapport (a)/(b) massique est situé entre 1 et 40, valeurs extrêmes comprises. La composition d'agent nettoyant en poudre présente une teneur totale de 4 % en masse ou moins de matériau granulé de protéase prédéterminée et de matériau granulé de cellulase prédéterminée. Lorsque la composition d'agent nettoyant en poudre est diluée 300 fois dans de l'eau à 20°C, le pH est situé entre 2,5 et 6,5, valeurs extrêmes comprises.
PCT/JP2014/078322 2013-12-27 2014-10-24 Composition d'agent nettoyant en poudre WO2015098265A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201480062759.0A CN105745316B (zh) 2013-12-27 2014-10-24 粉末清洁剂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2013271109 2013-12-27
JP2013-271109 2013-12-27

Publications (1)

Publication Number Publication Date
WO2015098265A1 true WO2015098265A1 (fr) 2015-07-02

Family

ID=53478144

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2014/078322 WO2015098265A1 (fr) 2013-12-27 2014-10-24 Composition d'agent nettoyant en poudre

Country Status (3)

Country Link
JP (1) JP6249413B2 (fr)
CN (1) CN105745316B (fr)
WO (1) WO2015098265A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017119734A (ja) * 2015-12-28 2017-07-06 花王株式会社 繊維製品の手洗い用固形洗浄剤組成物
US20230042815A1 (en) * 2021-07-29 2023-02-09 Henkel IP & Holding GmbH Powdered Cleaning Composition Having Improved Dissolution

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6614956B2 (ja) * 2015-12-15 2019-12-04 花王株式会社 自動食器洗浄機用固体洗浄剤組成物
HUE046263T2 (hu) * 2016-10-03 2020-02-28 Procter & Gamble Egy porlasztva szárított mosószerrészecske gyártására szolgáló eljárás
CN113621448A (zh) * 2021-08-16 2021-11-09 安徽德正堂药业有限公司 一种环保型洗涤材料的配方及工艺

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007016116A (ja) * 2005-07-07 2007-01-25 Kao Corp 衣料用洗浄剤
JP2007522336A (ja) * 2004-02-23 2007-08-09 ザ プロクター アンド ギャンブル カンパニー アニオン性洗浄性界面活性剤、スルファミン酸及び／又はその水溶性塩類を含む洗濯洗剤組成物
JP2010529250A (ja) * 2007-06-11 2010-08-26 ザ プロクター アンド ギャンブル カンパニー 有益剤含有送達粒子
JP2013519757A (ja) * 2010-02-10 2013-05-30 ザ プロクター アンド ギャンブル カンパニー キレート剤の存在下で高安定性を有するアミラーゼ変異体を含む洗浄組成物

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1075505A1 (fr) * 1998-03-27 2001-02-14 Novozymes A/S Composition de nettoyage acide renfermant une protease acide
EP1824954A1 (fr) * 2004-11-19 2007-08-29 The Procter and Gamble Company Compositions acides detergentes pour le lavage du linge
JP4841976B2 (ja) * 2006-03-10 2011-12-21 花王株式会社 食器洗浄機用洗浄剤組成物
CA2860083C (fr) * 2012-01-18 2016-08-30 The Procter & Gamble Company Compositions detergentes acides pour lessive
JP2013213184A (ja) * 2012-03-09 2013-10-17 Kao Corp 粉末洗浄剤組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007522336A (ja) * 2004-02-23 2007-08-09 ザ プロクター アンド ギャンブル カンパニー アニオン性洗浄性界面活性剤、スルファミン酸及び／又はその水溶性塩類を含む洗濯洗剤組成物
JP2007016116A (ja) * 2005-07-07 2007-01-25 Kao Corp 衣料用洗浄剤
JP2010529250A (ja) * 2007-06-11 2010-08-26 ザ プロクター アンド ギャンブル カンパニー 有益剤含有送達粒子
JP2013519757A (ja) * 2010-02-10 2013-05-30 ザ プロクター アンド ギャンブル カンパニー キレート剤の存在下で高安定性を有するアミラーゼ変異体を含む洗浄組成物

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017119734A (ja) * 2015-12-28 2017-07-06 花王株式会社 繊維製品の手洗い用固形洗浄剤組成物
US20230042815A1 (en) * 2021-07-29 2023-02-09 Henkel IP & Holding GmbH Powdered Cleaning Composition Having Improved Dissolution

Also Published As

Publication number Publication date
CN105745316A (zh) 2016-07-06
JP2015143329A (ja) 2015-08-06
JP6249413B2 (ja) 2017-12-20
CN105745316B (zh) 2018-09-11

Similar Documents

Publication Publication Date Title
JP6249413B2 (ja) 粉末洗浄剤組成物
JP2018536058A (ja) 分岐状アルキルサルフェート界面活性剤及び短鎖非イオン性界面活性剤を含有する洗浄組成物
JP6581785B2 (ja) 硬質表面用液体洗浄剤組成物およびそれを用いる食器類の洗浄方法、並びに医療器具の洗浄方法
JPH0873890A (ja) 液体硬表面洗浄剤組成物
JP3481615B2 (ja) 衣料の洗濯方法及びそのための洗浄剤組成物
US20170240845A1 (en) Laundry Detergent Composition with Vinegar
JP4302975B2 (ja) 粉末漂白洗浄剤組成物
JP2937635B2 (ja) 自動食器洗浄機用洗浄剤
EP3417041B1 (fr) Composition de lavage comprenant un principe anti-mousse activable au rinçage
JP6339131B2 (ja) 衣料用粉末洗浄剤組成物
JP4015779B2 (ja) 食器洗浄機用洗浄剤組成物
US3794589A (en) Chemical compositions for general cleaning
JP3370409B2 (ja) 風呂釜・排水管用洗浄剤組成物
JP6605952B2 (ja) 繊維製品の手洗い用固形洗浄剤組成物
JP5876023B2 (ja) 衣料用粉末洗剤組成物
JP6188196B2 (ja) 食器洗い機用洗浄剤
JP6184024B2 (ja) 粒状洗剤
JP5702451B2 (ja) 硬質表面用液体洗浄剤組成物
JP6249424B2 (ja) 衣料用粉末洗浄剤組成物
JP2001064698A (ja) 自動食器洗浄機用洗浄剤組成物
JP2021017590A (ja) 粒状洗浄剤組成物
JP2001107092A (ja) 自動食器洗浄機用洗浄剤
US8822398B2 (en) Detergent compositions comprising a polydimethylsiloxane on sodium acetate foam control agent and methods of making
JP2020125388A (ja) 衣料用液体洗浄剤組成物
JP2004002869A (ja) 衣料の洗濯方法及びそのための洗浄剤組成物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 14874755

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: IDP00201603364

Country of ref document: ID

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 14874755

Country of ref document: EP

Kind code of ref document: A1