WO2015062569A1 - Verfahren und vorrichtung zum herstellen von dreidimensionalen modellen mit bindersystem - Google Patents
Verfahren und vorrichtung zum herstellen von dreidimensionalen modellen mit bindersystem Download PDFInfo
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- WO2015062569A1 WO2015062569A1 PCT/DE2014/000546 DE2014000546W WO2015062569A1 WO 2015062569 A1 WO2015062569 A1 WO 2015062569A1 DE 2014000546 W DE2014000546 W DE 2014000546W WO 2015062569 A1 WO2015062569 A1 WO 2015062569A1
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- Prior art keywords
- binder
- powder
- layer
- solvent
- heat treatment
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/165—Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/30—Process control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/141—Processes of additive manufacturing using only solid materials
- B29C64/153—Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
- B29C64/245—Platforms or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
- B29C64/295—Heating elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/40—Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y40/00—Auxiliary operations or equipment, e.g. for material handling
- B33Y40/20—Post-treatment, e.g. curing, coating or polishing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/30—Organic material
- B23K2103/36—Wood or similar materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/30—Organic material
- B23K2103/42—Plastics
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0822—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using IR radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/251—Particles, powder or granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
- B29K2509/02—Ceramics
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
Definitions
- the invention relates to a method and a device as well as a binder system for producing three-dimensional models.
- European Patent EP 0 431 924 B1 describes a method for producing three-dimensional objects from computer data.
- a particulate material is applied in a thin layer on a platform and this selectively printed by means of a print head with a binder material.
- the particle area printed with the binder sticks and solidifies under the influence of the binder and optionally an additional hardener.
- the printed and solidified areas create a three-dimensional object.
- This object made of solidified particulate material is embedded after its completion in loose particulate material and is subsequently freed from it. This is done for example by means of a nipple. Thereafter, the desired objects remain, which are then affected by powder deposits, e.g. be freed by manual brushing.
- This process can process various particulate materials including, but not limited to, natural biological raw materials, polymeric plastics, metals, ceramics and sands.
- a binding system e.g. serve a solid in the particulate material. This is dissolved by a solvent ejected from the ink jet printhead. After the volatilization of the solvent, the particles adhere to the
- the component can be removed from the remaining loose powder after a certain waiting time. This waiting time is generally long because the solvent is only slowly released from the dissolved material.
- the components are often weak after unpacking and can be plastically deformed. The volatilization of the solvent creates a certain adhesion to the component, which must be removed after unpacking by hand.
- the solvent may additionally attack the printhead.
- the dissolution process with subsequent reconsolidation causes shrinkage in the component and thus geometry deviations.
- a solvent can also be loaded with molecules or particles and used. This can reduce the shrinkage. Similarly, the aggressiveness of the solvent can be reduced with the same component strength. However, the solvent must be completely removed before unpacking, and the problem with adhesions is also given here.
- Another possibility is the use of a system which chemically leads to a solidification of the imprinted liquid and thereby realizes the binding of the particles.
- the components of the system are kept separate in the system if possible. Only during the printing process does the desired solidification reaction occur.
- An example of such a system may be a method known as the cold resin process. In this case, an acid-coated sand is brought into contact with furfuryl alcohol. This leads to a chemical reaction that causes the formerly liquid components to become a cross-linked plastic.
- UV-curing systems are described in various ways in the literature. These have certain disadvantages depending on the chemical and physical hardness system. In UV-curing systems, for example, the layered, complete curing is a disadvantage, as this leads to distortion in the construction process. It is also disadvantageous that, if the irradiation is too hard, no layer composite is formed. Also, pure IR-curing systems suffer from this problem.
- the invention consists of a method for producing three-dimensional (3D) shaped bodies (components) by means of 3D printing methods.
- the invention consists of a device for carrying out the 3D printing method according to the invention.
- the invention consists of a binder system consisting of at least two components. Detailed description of the invention
- 3D printing processes are all processes known from the prior art which enable the construction of components in three-dimensional shapes and which are compatible with the process components and devices described, in particular powder-based processes, such as, for example, SLS (US Pat. Selective laser sintering).
- a "binder” or “binder system” in the context of the invention is composed of two components and generally refers to a novolak or resol system with a solvent.
- a novolak or resol system with a solvent.
- Special components and phenols are given in the description below.
- acids or bases are required, it being possible to use all the acids and bases known for novolacs and resols, which are known to the person skilled in the art.
- prepolymers contained in the binders of the invention may vary depending on the application and are adapted to the other material components such as particulate materials.
- particle materials All materials known for powder-based 3D printing, in particular sands, ceramic powders, metal powders, plastics, wood particles, fibrous materials, celluloses and / or lactose powders, may be used as "particle materials.”
- the particle material is preferably a dry free-flowing and a cohesive, cut-resistant powder ,
- thermosetting the particulate material is meant that the powder material applied to the construction field is held in its entirety within a particular temperature window.
- a “heating” or “heat treatment” after binder application in the sense of the invention is the selective heating of the binder-provided material regions for building up the component. The temperature is significantly increased in comparison with the ambient temperature and the tempered particulate material on the construction field.
- the selective heating according to the invention is carried out not earlier than after every second particle material application or after a constant or varying number of application steps.
- the particulate material is distributed uniformly over the construction field and smoothed out before another particle material application takes place.
- “selective binder application” or “selective binder system application” can be carried out after each particle material application or, depending on the requirements of the molding and for the optimization of the molding production, also take place irregularly, i. non-linear and parallel after each particle material application. "Selective binder application” or “Selective binder system application” can thus be adjusted individually and in the course of the production of moldings.
- Aftertreatment steps or “further treatment steps” in the sense of the invention are all processes known to the person skilled in the art with which the shaped body obtained by the 3D printing process can be subjected, such as, for example, a further heat treatment.
- “Shaped body” or “component” in the sense of the invention are all three-dimensional objects produced by means of the method according to the invention and / or the device according to the invention, which have a dimensional stability.
- any known 3D printing apparatus can be used, which contains the required components .
- Conventional components include coaters, construction field, means for moving the construction field or other components, metering device and Heating means and other components known in the art, which are therefore not discussed here.
- Metaling center for the particle layer application may be a mechanical or other kind of means suitable to measure the number of particle layer orders. This may be coupled to a controller for other components or functions and / or software.
- the invention relates to a method for producing a component (3D molded body), wherein (a) in a first step by means of powder coater (101) a particle layer is applied to a building platform (102), (b) in a second step by means of binder Dosing device (100) a binder (400) is selectively applied, (c) in a further step, the applied layer or layers by heat source (600) are subjected to a heat treatment, (d) the building platform (102) is lowered by a layer thickness or Powder coater (101) and optionally further device components is increased by one layer thickness, steps (a) to (d) are repeated until the component is constructed, wherein the heat treatment (c) is performed after each second or further layer application steps.
- the heat treatment is carried out at a temperature of 100 ° C to 170 ° C, preferably from 130 ° C to 160 ° C.
- the invention relates to a binder system suitable for an SD printing process, comprising or consisting of at least one adhesive and a solvent and optionally further additives.
- the binder system according to the invention preferably contains as adhesive a thermally postcrosslinkable prepolymer and as solvent one or more alcohols or / and water.
- the binder system according to the invention particularly preferably comprises or consists of a novolak and / or resol system and a solvent and optionally further additives.
- a binder system which contains a novolak and / or a resol system as used in the shell molding process has proved to be particularly suitable.
- solvents can be used, wherein the solvent is an alcohol, preferably ethanol and / or 2-propanol and / or an aqueous solution, preferably water and 2-propanol.
- the binder system according to the invention contains further additives which are selected from the group consisting of surfactants and defoamers.
- the binder system according to the invention is characterized in that the solvent is alcohol-based and preferably contains not more than 30% resin.
- the binder system of the invention further comprises up to 5% polyol, preferably glycol, propylene glycol or xylitol.
- the binder system of the present invention exhibits one or more of the following advantageous characteristics at room temperature: in the preferred embodiment, the viscosity is between 5-40 mPas, more preferably between 8-20 mPas, with a surface tension of 20-40 mN / m being preferred preferably from 25 to 35 mN / m. In a preferred embodiment, the vapor pressure of the binder system is not higher than 55 hPa, more preferably not higher than 40 hPa.
- the process according to the invention advantageously represents a chemical system of solvent and compound component in which, by selecting the specific components, it has surprisingly been achieved that high unpacking and final strengths can be achieved.
- advantageously by the absence of a reaction part in Particle material achieves a high edge sharpness without adhesions.
- an aggressive solvent is avoided and so advantageously the printhead is not exposed to the risk of damage. This guarantees continuous machine run times and avoids having to repair or replace machine parts.
- the avoidance of aggressive solvents required in other prior art processes has many practical advantages, such as reduced material and worker hazards, as well as positive economic consequences of continuous machine run times and the avoidance of damage to the printing presses.
- the heat treatment step is not carried out after each layer application and binder application, but is carried out only after every second, preferably after every second to seventh layer application.
- the heat treatment step is carried out after every second, preferably after every fourth to sixth layer application, most preferably after every fifth layer application.
- the curing process is therefore preferably performed in layers but not in each successive layer. Among other things, this leads to a faster workflow and thus to an accelerated production speed.
- the component can be produced in even better quality. It has been found to be advantageous if the particulate material is maintained at a temperature not lower than 50 ° C to 70 ° C, preferably not lower than 55 ° C to 65 ° C, most preferably not lower than 60 ° C .
- the component produced by the method according to the invention can be subjected to further known working steps, such as a further heat treatment step, preferably at a temperature of 150 ° C - 200 ° C. This heat treatment step preferably takes place after unpacking.
- the binder or the binder system described above is preferably used.
- the binder or the binder system is preferably applied selectively with a binder metering device and selectively solidifies the particulate material.
- the method has the advantage that almost all materials known in 3D printing processes can be used.
- the particulate material is selected from the group consisting of sands, ceramic powders, metal powders, plastics, wood particles, fiber materials, celluloses and / or lactose powders. More preferably, the particulate material is a dry, free-flowing powder, a cohesive, cut-resistant powder, or a liquid-based dispersion.
- the particulate material (the sand) also does not have to be pretreated or premixed.
- the residual sand which does not form the component, can be reused and recycled easily in the process. It eliminates an otherwise necessary mixing or expensive cleaning steps.
- the binder fraction can vary globally, but also selectively within the geometry, via the printing resolution. This is also not possible with known methods of the prior art, since any mixing ratios of the reactants during printing are no longer in the optimum range, which leads to quality problems.
- An example in this regard is the furan system, since the acid causes problems without the right amount of reactant in the sand.
- the invention is a 3D printing apparatus comprising (a) a powder coater (101), a build platform (102), at least one binder dosing device (100), at least one heat source (600), preferably an IR Emitter (604), preferably a lifting device (605) for lowering and raising the building platform (102) or the powder coating (101) and optionally other components, such as the binder metering device (100) and the heat source (600), preferably a suction device (606), and counting means (607) for counting the applied particle powder layers.
- the device additionally comprises a contact heater (602) or hot air device (608).
- the binder metering device may consist of, for example, an ink jet printhead which selectively meters the binder into the build field in individually retrievable drops.
- the binder metering device can also consist of a strand metering system, wherein the binder is metered as a thin switchable beam selectively on the construction field.
- the device according to the invention and the method according to the invention can be used in all 3D printing processes, preferably in powder-based 3D printing.
- Figure 1 Schematic representation of the components of a powder-based SD printer as a cut oblique.
- Figure 2 Sequence of a conventional 3D printing process with the use of a layer-wise radiation curing.
- FIG. 3 Sequence of a building process with radiation hardening, which does not occur every layer.
- FIG. 6 Chemical reaction equation for the solidification of a novolak system with a source of formaldehyde under the action of heat
- FIG. 7 Details of the reaction
- the basic features of the invention use a system for the layered construction of models with Tintenstrahl horrtechnlk.
- the process according to the prior art is structured as follows: A powder layer is applied to a construction platform and leveled. Subsequently, the layer is printed according to the layer data of the 3D model with a fluid. The printed areas change one or more properties (strength, water solubility, etc.). Usually, the material solidifies through a bonding component in the liquid binder (e.g., an adhesive). Then the build platform is lowered and the process starts again.
- a bonding component in the liquid binder e.g., an adhesive
- the printability of a liquid with an ink jet printhead requires a very low viscosity.
- the liquid compound components usually have to be diluted.
- solvents are generally used. If each layer by means of z. B. heats radiation, the surface temperature of the layer to be printed is also very high. As a result, the solvent evaporates very quickly. The binder can not penetrate deep enough into the layer and thus join the layers together. The building leafs apart.
- the method according to the invention and the device according to the invention it is advantageously possible to produce a stable, edge-resistant and well-defined structure if, for example, it is cured only after every fifth layer application.
- the solidification is completed only after sufficient diffusion of the compound component (binder / binder system) completed.
- the evaporation of the solvent of the fifth layer does not affect the structure surprisingly.
- the system according to the invention is closely based on the powder-based 3D printing.
- the machine technology of the device according to the invention is extended according to the requirements of the method according to the invention.
- the device according to the invention has a powder coater. With this particulate material is applied to a build platform and smoothed ( Figure 2 (a)).
- the applied particulate material can consist of various materials. For example, sand, ceramic powder, metal powder, plastic, wood particles, fiber material, celluloses, lactose powder, etc. may be used. The flow properties of these materials can vary greatly.
- Various coating techniques allow for the layer formation of dry, free-flowing powders via cohesive, cut-resistant powders to liquid-based dispersions. The height of the powder layers is determined by the build platform. It is lowered after applying a coat. During the next coating process, the resulting volume is filled and the supernatant smoothed. The result is a nearly perfectly parallel and smooth layer of defined height.
- the layer is printed with a liquid by means of an inkjet printhead (FIG. 2 (b)).
- the printed image corresponds to the section through the component in the current height of the device.
- the liquid impinges on the particulate material and slowly diffuses into it.
- the layer is solidified by the process according to the invention (FIG. 2 (c)).
- an IR emitter can be felt on the construction field. This can be coupled to the axis of the coating system. During heating, the solvent evaporates. With flammable liquids, the evaporating material is sucked off immediately.
- the control of a machine according to the invention can count the layers and change the process only after every other layer, for example, and trigger a solidification travel (FIG. 3).
- the energy input can also be estimated on the basis of measured data and the frequency of the consolidation runs can be adapted. Examples of this are solidification runs after three, four, five or six layers of the particulate material and preferably the binder.
- As a disturbance of such a scheme are essentially the imprinted quantities of liquid to call, which vary depending on the layer image. In this case, instead of regulating sensor data, it is also possible to link the information within the controller.
- FIG. 4 shows by way of example a drop which penetrates into the powder (particle material). After steps (a) - (d), the penetration depth is large enough to bond the layers. The diffusion then slows down quickly, as the drop has disappeared as a reservoir. If you print on a too-preheated layer, the solvent boils suddenly and the binder becomes highly viscous. As a result, it remains at the level of Figure 4 (b) stand. There is no composite layer.
- the powder can be preheated. Suitable for this purpose are contact heaters, hot air or IR emitters. This preheating allows It is easy to control the IR solidification process with small lamp powers and to achieve high process speeds.
- the build platform is lowered by one layer thickness (FIG. 2 (d)). Repeating the above steps will create the complete part.
- Novolaks are known from the application as a coating of sand called croning resin. Finished solutions of such resins and curing additives as are used for the coating of sand can be obtained, for example, from Wilsontenes-Albertus Chemische Werke GmbH. In preliminary tests, alcohol-based solutions proved to be easy to process owing to their viscosity and their compatibility with the novolak system by means of the ink-jet printing technique, the resin content preferably being less than 30%.
- additives such as surfactants, defoamers and fine adjustment of the viscosity up to 5% polyols such as glycol, propylene glycol or xylitol may be added.
- glycol, propylene glycol or xylitol may be added.
- the curing additive must be significantly removed from the room temperature in its starting temperature, so that no unwanted reactions start.
- the printing solution thus set is then introduced in layers and selectively by means of a printhead in the particulate material, wherein the particulate material has a temperature of preferably at least 60 ° C during the entire construction process.
- the evaporation rate of the excess solvent is increased due to the temperature of the sand and is continuously removed in the constant suction stream.
- the actual curing process is carried out by further heat input to the printed particulate material, preferably by means of an IR lamp, wherein the temperature briefly rises above 160 ° C.
- This exposure process is preferably repeated every five layers, the construction process always ending with an exposure process.
- a shows Significant color change of the printed areas on ocher to brown to the polymerization.
- the components are preferably left in the unprinted particulate material for one hour. Subsequently, preferably for further increase in strength, the unpacked components are stored in the oven at a temperature between 150 ° C and 200 ° C for another hour.
- the system is characterized in particular by the fact that the components can be easily removed from the non-printed sand and are very sharp edged.
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14809756.1A EP3062992B1 (de) | 2013-10-30 | 2014-10-29 | Verfahren zum herstellen von dreidimensionalen modellen mit bindersystem |
CN201480057655.0A CN105658416A (zh) | 2013-10-30 | 2014-10-29 | 使用粘合剂系统生产三维模型的方法和装置 |
ES14809756T ES2930346T3 (es) | 2013-10-30 | 2014-10-29 | Procedimiento para producir modelos tridimensionales con sistema aglutinante |
US15/029,759 US10786945B2 (en) | 2013-10-30 | 2014-10-29 | Method and device for producing three-dimensional models using a binding agent system |
KR1020167010887A KR102250448B1 (ko) | 2013-10-30 | 2014-10-29 | 바인더 에이전트 시스템을 이용하여 삼차원 모델을 생산하기 위한 방법 및 디바이스 |
US17/018,247 US11541596B2 (en) | 2013-10-30 | 2020-09-11 | Method and device for producing three-dimensional models using a binding agent system |
US18/145,466 US20230131987A1 (en) | 2013-10-30 | 2022-12-22 | Binder system and devices for 3-d printing and articles produced therefrom |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016184448A1 (de) * | 2015-05-20 | 2016-11-24 | Voxeljet Ag | Phenolharzverfahren |
CN107273065A (zh) * | 2016-03-30 | 2017-10-20 | 佳能株式会社 | 管理系统及其方法 |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10085198D2 (de) | 2000-09-25 | 2003-08-21 | Generis Gmbh | Verfahren zum Herstellen eines Bauteils in Ablagerungstechnik |
US10226919B2 (en) | 2007-07-18 | 2019-03-12 | Voxeljet Ag | Articles and structures prepared by three-dimensional printing method |
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US9868255B2 (en) * | 2014-03-18 | 2018-01-16 | Stratasys, Inc. | Electrophotography-based additive manufacturing with pre-sintering |
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DE102014007584A1 (de) | 2014-05-26 | 2015-11-26 | Voxeljet Ag | 3D-Umkehrdruckverfahren und Vorrichtung |
EP3174651B1 (de) | 2014-08-02 | 2020-06-17 | voxeljet AG | Verfahren und gussform, insbesondere zur verwendung in kaltgussverfahren |
JP2016055517A (ja) * | 2014-09-09 | 2016-04-21 | セイコーエプソン株式会社 | 三次元造形物の製造方法、三次元造形用材料セットおよび三次元造形物 |
DE102015006533A1 (de) | 2014-12-22 | 2016-06-23 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Schichtaufbautechnik |
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EP3271146B1 (de) * | 2015-05-15 | 2021-06-30 | Hewlett-Packard Development Company, L.P. | Koaleszenzmittelkonzentrationen und contone-dichten für dreidimensionale objekte |
CN104959613B (zh) * | 2015-07-10 | 2017-02-22 | 北京科技大学 | 一种3d打印用料浆喷雾固化定型方法 |
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DE102015015353A1 (de) | 2015-12-01 | 2017-06-01 | Voxeljet Ag | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Bauteilen mittels Überschussmengensensor |
CN106042408A (zh) * | 2016-06-22 | 2016-10-26 | 武汉易制科技有限公司 | 一种用于3d打印的粉末材料及粉末3d打印成形方法 |
US11305490B2 (en) * | 2016-07-22 | 2022-04-19 | Hewlett-Packard Development Company, L.P. | Additive manufacturing with traversing irradiation region |
CA3031403A1 (en) * | 2016-09-21 | 2018-03-29 | Sergey SINGOV | 3d printer |
CN109906140A (zh) * | 2016-10-19 | 2019-06-18 | 株式会社大赛璐 | 立体造型用组合物、立体造型物的制造方法以及立体造型物 |
DE102016013610A1 (de) | 2016-11-15 | 2018-05-17 | Voxeljet Ag | Intregierte Druckkopfwartungsstation für das pulverbettbasierte 3D-Drucken |
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US11389867B2 (en) | 2017-02-24 | 2022-07-19 | Hewlett-Packard Development Company, L.P. | Three-dimensional (3D) printing |
JP6961972B2 (ja) * | 2017-03-24 | 2021-11-05 | 富士フイルムビジネスイノベーション株式会社 | 立体形状成形装置、情報処理装置及びプログラム |
CN108929113B (zh) * | 2017-05-24 | 2021-11-12 | 赵晴堂 | 一种三维增材成形材料的制造方法 |
DE102018004545A1 (de) * | 2017-06-16 | 2018-12-20 | Additive elements GmbH | Verfahren zum Aufbau von Kunststoff-Bauteilen |
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DE102017006860A1 (de) | 2017-07-21 | 2019-01-24 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Spektrumswandler |
EP3621756A4 (de) | 2017-07-31 | 2020-12-23 | Hewlett-Packard Development Company, L.P. | Brauner körper mit einem metallnanopartikelbindemittel |
CN111465482A (zh) * | 2017-12-19 | 2020-07-28 | 科思创德国股份有限公司 | 制造处理过的3d打印物件的方法 |
CN109968670B (zh) * | 2017-12-27 | 2021-02-02 | 立方通达实业(天津)有限公司 | 一种便于取件的3d打印机工作台 |
CN108707891A (zh) * | 2018-05-18 | 2018-10-26 | 李长明 | 一种电子元器件用金属功能材料制造技术设备 |
WO2020089491A1 (es) * | 2018-10-31 | 2020-05-07 | Barberan Latorre Jesus Francisco | Método para producir una estructura tridimensional sobre una cara de un sustrato plano, sustrato obtenible y dispositivo para producir el sustrato según el método |
DE102018220611B4 (de) | 2018-11-29 | 2022-02-10 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Thermisch vernetzbare Zusammensetzung zur Verwendung als Bindemittel im Binder-Jetting-Verfahren |
DE102019000796A1 (de) | 2019-02-05 | 2020-08-06 | Voxeljet Ag | Wechselbare Prozesseinheit |
DE102019007595A1 (de) | 2019-11-01 | 2021-05-06 | Voxeljet Ag | 3d-druckverfahren und damit hergestelltes formteil unter verwendung von ligninsulfat |
WO2023086908A1 (en) * | 2021-11-10 | 2023-05-19 | Brigham Young University | Method and system for generating a three-dimensional object with edge definition |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0431924B1 (de) | 1989-12-08 | 1996-01-31 | Massachusetts Institute Of Technology | Dreidimensionale Drucktechniken |
EP1524049A2 (de) * | 2003-10-14 | 2005-04-20 | Hewlett-Packard Development Company, L.P. | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Formkörpern in einem Solid Free Form Verfahren |
DE102006038858A1 (de) * | 2006-08-20 | 2008-02-21 | Voxeljet Technology Gmbh | Selbstaushärtendes Material und Verfahren zum schichtweisen Aufbau von Modellen |
Family Cites Families (335)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2261344C3 (de) | 1972-12-15 | 1979-05-31 | Karl Becker Kg Maschinenfabrik, 3525 Oberweser | Vorrichtung zum Ablegen von körnigem Saatgut im Erdreich in Verbindung mit Einzelkornsämaschinen |
US4247508B1 (en) | 1979-12-03 | 1996-10-01 | Dtm Corp | Molding process |
US4591402A (en) | 1981-06-22 | 1986-05-27 | Ltv Aerospace And Defense Company | Apparatus and method for manufacturing composite structures |
FR2511149A1 (fr) | 1981-08-04 | 1983-02-11 | Roussel Uclaf | Dispositif et procede de dosage de quantites predeterminees d'au moins un produit |
US4711669A (en) | 1985-11-05 | 1987-12-08 | American Cyanamid Company | Method of manufacturing a bonded particulate article by reacting a hydrolyzed amylaceous product and a heterocyclic compound |
DE3221357A1 (de) | 1982-06-05 | 1983-12-08 | Plasticonsult GmbH Beratungsgesellschaft für Kunststoff- und Oberflächentechnik, 6360 Friedberg | Verfahren zur herstellung von formen und kernen fuer giesszwecke |
JPS60180643A (ja) | 1984-02-29 | 1985-09-14 | Nissan Motor Co Ltd | 鋳物砂用粘結剤に用いる崩壊助剤 |
US4665492A (en) | 1984-07-02 | 1987-05-12 | Masters William E | Computer automated manufacturing process and system |
US4575330A (en) | 1984-08-08 | 1986-03-11 | Uvp, Inc. | Apparatus for production of three-dimensional objects by stereolithography |
JPS62275734A (ja) | 1986-05-26 | 1987-11-30 | Tokieda Naomitsu | 立体形成方法 |
US5263130A (en) | 1986-06-03 | 1993-11-16 | Cubital Ltd. | Three dimensional modelling apparatus |
US4752352A (en) | 1986-06-06 | 1988-06-21 | Michael Feygin | Apparatus and method for forming an integral object from laminations |
US5296062A (en) | 1986-10-17 | 1994-03-22 | The Board Of Regents, The University Of Texas System | Multiple material systems for selective beam sintering |
US5076869A (en) | 1986-10-17 | 1991-12-31 | Board Of Regents, The University Of Texas System | Multiple material systems for selective beam sintering |
US5017753A (en) | 1986-10-17 | 1991-05-21 | Board Of Regents, The University Of Texas System | Method and apparatus for producing parts by selective sintering |
US5147587A (en) | 1986-10-17 | 1992-09-15 | Board Of Regents, The University Of Texas System | Method of producing parts and molds using composite ceramic powders |
US5155324A (en) | 1986-10-17 | 1992-10-13 | Deckard Carl R | Method for selective laser sintering with layerwise cross-scanning |
KR960008015B1 (ko) | 1986-10-17 | 1996-06-19 | 보드 오브 리젼츠, 디 유니버시티 오브 텍사스 시스템 | 선택적 소결에 의한 부품의 제조 방법 및 장치 |
US4944817A (en) | 1986-10-17 | 1990-07-31 | Board Of Regents, The University Of Texas System | Multiple material systems for selective beam sintering |
US4863538A (en) | 1986-10-17 | 1989-09-05 | Board Of Regents, The University Of Texas System | Method and apparatus for producing parts by selective sintering |
US4752498A (en) | 1987-03-02 | 1988-06-21 | Fudim Efrem V | Method and apparatus for production of three-dimensional objects by photosolidification |
US5047182A (en) | 1987-11-25 | 1991-09-10 | Ceramics Process Systems Corporation | Complex ceramic and metallic shaped by low pressure forming and sublimative drying |
IL109511A (en) | 1987-12-23 | 1996-10-16 | Cubital Ltd | Three-dimensional modelling apparatus |
US5772947A (en) | 1988-04-18 | 1998-06-30 | 3D Systems Inc | Stereolithographic curl reduction |
CA1337955C (en) | 1988-09-26 | 1996-01-23 | Thomas A. Almquist | Recoating of stereolithographic layers |
AU4504089A (en) | 1988-10-05 | 1990-05-01 | Michael Feygin | An improved apparatus and method for forming an integral object from laminations |
US5637175A (en) | 1988-10-05 | 1997-06-10 | Helisys Corporation | Apparatus for forming an integral object from laminations |
JP2738017B2 (ja) | 1989-05-23 | 1998-04-08 | ブラザー工業株式会社 | 三次元成形装置 |
GB2233928B (en) | 1989-05-23 | 1992-12-23 | Brother Ind Ltd | Apparatus and method for forming three-dimensional article |
US5248456A (en) | 1989-06-12 | 1993-09-28 | 3D Systems, Inc. | Method and apparatus for cleaning stereolithographically produced objects |
US5134569A (en) | 1989-06-26 | 1992-07-28 | Masters William E | System and method for computer automated manufacturing using fluent material |
US5216616A (en) | 1989-06-26 | 1993-06-01 | Masters William E | System and method for computer automated manufacture with reduced object shape distortion |
JPH0336019A (ja) | 1989-07-03 | 1991-02-15 | Brother Ind Ltd | 三次元成形方法およびその装置 |
US5431967A (en) | 1989-09-05 | 1995-07-11 | Board Of Regents, The University Of Texas System | Selective laser sintering using nanocomposite materials |
US5156697A (en) | 1989-09-05 | 1992-10-20 | Board Of Regents, The University Of Texas System | Selective laser sintering of parts by compound formation of precursor powders |
US5284695A (en) | 1989-09-05 | 1994-02-08 | Board Of Regents, The University Of Texas System | Method of producing high-temperature parts by way of low-temperature sintering |
AU643700B2 (en) | 1989-09-05 | 1993-11-25 | University Of Texas System, The | Multiple material systems and assisted powder handling for selective beam sintering |
US5053090A (en) | 1989-09-05 | 1991-10-01 | Board Of Regents, The University Of Texas System | Selective laser sintering with assisted powder handling |
US5182170A (en) | 1989-09-05 | 1993-01-26 | Board Of Regents, The University Of Texas System | Method of producing parts by selective beam interaction of powder with gas phase reactant |
DE3930750A1 (de) | 1989-09-14 | 1991-03-28 | Krupp Medizintechnik | Gusseinbettmasse, einbettmassenmodell, gussform und verfahren zur verhinderung des aufbluehens von einbettmassenmodellen und gussformen aus einer gusseinbettmasse |
US5136515A (en) | 1989-11-07 | 1992-08-04 | Richard Helinski | Method and means for constructing three-dimensional articles by particle deposition |
US5387380A (en) | 1989-12-08 | 1995-02-07 | Massachusetts Institute Of Technology | Three-dimensional printing techniques |
DE3942859A1 (de) | 1989-12-23 | 1991-07-04 | Basf Ag | Verfahren zur herstellung von bauteilen |
GB9007199D0 (en) | 1990-03-30 | 1990-05-30 | Tioxide Group Plc | Preparation of polymeric particles |
US5127037A (en) | 1990-08-15 | 1992-06-30 | Bynum David K | Apparatus for forming a three-dimensional reproduction of an object from laminations |
US5126529A (en) | 1990-12-03 | 1992-06-30 | Weiss Lee E | Method and apparatus for fabrication of three-dimensional articles by thermal spray deposition |
DE4102260A1 (de) | 1991-01-23 | 1992-07-30 | Artos Med Produkte | Vorrichtung zur herstellung beliebig geformter koerper |
US5506607A (en) | 1991-01-25 | 1996-04-09 | Sanders Prototypes Inc. | 3-D model maker |
US5740051A (en) | 1991-01-25 | 1998-04-14 | Sanders Prototypes, Inc. | 3-D model making |
US6175422B1 (en) | 1991-01-31 | 2001-01-16 | Texas Instruments Incorporated | Method and apparatus for the computer-controlled manufacture of three-dimensional objects from computer data |
JP3104307B2 (ja) | 1991-06-28 | 2000-10-30 | ソニー株式会社 | グラビア印刷用版材 |
US5252264A (en) | 1991-11-08 | 1993-10-12 | Dtm Corporation | Apparatus and method for producing parts with multi-directional powder delivery |
US5269982A (en) | 1992-02-12 | 1993-12-14 | Brotz Gregory R | Process for manufacturing a shaped product |
IT1254974B (it) | 1992-06-18 | 1995-10-11 | Bayer Italia Spa | Granulati compositi, scorrevoli,idrofobi,un procedimento per la loro preparazione nonche' loro impiego |
US5342919A (en) | 1992-11-23 | 1994-08-30 | Dtm Corporation | Sinterable semi-crystalline powder and near-fully dense article formed therewith |
US5352405A (en) | 1992-12-18 | 1994-10-04 | Dtm Corporation | Thermal control of selective laser sintering via control of the laser scan |
DE4300478C2 (de) | 1993-01-11 | 1998-05-20 | Eos Electro Optical Syst | Verfahren und Vorrichtung zum Herstellen eines dreidimensionalen Objekts |
US6146567A (en) | 1993-02-18 | 2000-11-14 | Massachusetts Institute Of Technology | Three dimensional printing methods |
DE4305201C1 (de) | 1993-02-19 | 1994-04-07 | Eos Electro Optical Syst | Verfahren zum Herstellen eines dreidimensionalen Objekts |
US5433261A (en) | 1993-04-30 | 1995-07-18 | Lanxide Technology Company, Lp | Methods for fabricating shapes by use of organometallic, ceramic precursor binders |
US5427722A (en) | 1993-06-11 | 1995-06-27 | General Motors Corporation | Pressure slip casting process for making hollow-shaped ceramics |
DE4325573C2 (de) | 1993-07-30 | 1998-09-03 | Stephan Herrmann | Verfahren zur Erzeugung von Formkörpern durch sukzessiven Aufbau von Pulverschichten sowie Vorichtung zu dessen Durchführung |
US5398193B1 (en) | 1993-08-20 | 1997-09-16 | Alfredo O Deangelis | Method of three-dimensional rapid prototyping through controlled layerwise deposition/extraction and apparatus therefor |
US5518680A (en) | 1993-10-18 | 1996-05-21 | Massachusetts Institute Of Technology | Tissue regeneration matrices by solid free form fabrication techniques |
US5490962A (en) | 1993-10-18 | 1996-02-13 | Massachusetts Institute Of Technology | Preparation of medical devices by solid free-form fabrication methods |
US5418112A (en) | 1993-11-10 | 1995-05-23 | W. R. Grace & Co.-Conn. | Photosensitive compositions useful in three-dimensional part-building and having improved photospeed |
DE4400523C2 (de) | 1994-01-11 | 1996-07-11 | Eos Electro Optical Syst | Verfahren und Vorrichtung zum Herstellen eines dreidimensionalen Objekts |
US5518060A (en) | 1994-01-25 | 1996-05-21 | Brunswick Corporation | Method of producing polymeric patterns for use in evaporable foam casting |
DE4440397C2 (de) | 1994-11-11 | 2001-04-26 | Eos Electro Optical Syst | Verfahren zum Herstellen von Gußformen |
JP3215881B2 (ja) * | 1994-05-27 | 2001-10-09 | イーオーエス ゲゼルシャフト ミット ベシュレンクテル ハフツング イレクトロ オプティカル システムズ | 鋳込み技術に使用される方法 |
US5503785A (en) | 1994-06-02 | 1996-04-02 | Stratasys, Inc. | Process of support removal for fused deposition modeling |
US6048954A (en) | 1994-07-22 | 2000-04-11 | The University Of Texas System Board Of Regents | Binder compositions for laser sintering processes |
US5639402A (en) | 1994-08-08 | 1997-06-17 | Barlow; Joel W. | Method for fabricating artificial bone implant green parts |
US5616631A (en) | 1994-08-17 | 1997-04-01 | Kao Corporation | Binder composition for mold making, binder/curing agent composition for mold making, sand composition for mold making, and process of making mold |
US5555176A (en) | 1994-10-19 | 1996-09-10 | Bpm Technology, Inc. | Apparatus and method for making three-dimensional articles using bursts of droplets |
US5717599A (en) | 1994-10-19 | 1998-02-10 | Bpm Technology, Inc. | Apparatus and method for dispensing build material to make a three-dimensional article |
US5482659A (en) | 1994-12-22 | 1996-01-09 | United Technologies Corporation | Method of post processing stereolithographically produced objects |
JP3839479B2 (ja) | 1995-02-01 | 2006-11-01 | スリーディー システムズ インコーポレーテッド | 3次元物体の高速断面積層方法 |
GB9501987D0 (en) | 1995-02-01 | 1995-03-22 | Butterworth Steven | Dissolved medium rendered resin (DMRR) processing |
US5573721A (en) | 1995-02-16 | 1996-11-12 | Hercules Incorporated | Use of a support liquid to manufacture three-dimensional objects |
DE19511772C2 (de) | 1995-03-30 | 1997-09-04 | Eos Electro Optical Syst | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objektes |
DE29506204U1 (de) | 1995-04-10 | 1995-06-01 | Eos Electro Optical Syst | Vorrichtung zum Herstellen eines dreidimensionalen Objektes |
DE19514740C1 (de) | 1995-04-21 | 1996-04-11 | Eos Electro Optical Syst | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objektes |
DE19515165C2 (de) | 1995-04-25 | 1997-03-06 | Eos Electro Optical Syst | Vorrichtung zum Herstellen eines Objektes mittels Stereolithographie |
DE19525307C2 (de) | 1995-07-12 | 2003-04-03 | Eichenauer Gmbh & Co Kg F | Formmasse zur Herstellung von Gießkernen und Verfahren zur Herstellung eines Gießkerns |
DE19528215A1 (de) | 1995-08-01 | 1997-02-06 | Thomas Dipl Ing Himmer | Verfahren zur Herstellung von dreidimensionalen Modellen und Formen |
DE19530295C1 (de) | 1995-08-11 | 1997-01-30 | Eos Electro Optical Syst | Vorrichtung zur schichtweisen Herstellung eines Objektes mittels Lasersintern |
US5837960A (en) | 1995-08-14 | 1998-11-17 | The Regents Of The University Of California | Laser production of articles from powders |
BR9610750A (pt) | 1995-09-27 | 1999-07-13 | 3D Systems Inc | Método e aparelho de modelagem por deposição seletiva para formação de objetos tridimensionais e suportes |
US6305769B1 (en) | 1995-09-27 | 2001-10-23 | 3D Systems, Inc. | Selective deposition modeling system and method |
US6270335B2 (en) | 1995-09-27 | 2001-08-07 | 3D Systems, Inc. | Selective deposition modeling method and apparatus for forming three-dimensional objects and supports |
US5943235A (en) | 1995-09-27 | 1999-08-24 | 3D Systems, Inc. | Rapid prototyping system and method with support region data processing |
US5749041A (en) | 1995-10-13 | 1998-05-05 | Dtm Corporation | Method of forming three-dimensional articles using thermosetting materials |
DE19545167A1 (de) | 1995-12-04 | 1997-06-05 | Bayerische Motoren Werke Ag | Verfahren zum Herstellen von Bauteilen oder Werkzeugen |
US5660621A (en) | 1995-12-29 | 1997-08-26 | Massachusetts Institute Of Technology | Binder composition for use in three dimensional printing |
AU1673797A (en) | 1996-02-20 | 1997-09-10 | Mikuni Corporation | Method for producing granulated material |
ATE220958T1 (de) | 1996-03-06 | 2002-08-15 | Guild Ass Inc | Vorrichtung zum herstellen eines dreidimensionalen körpers |
US5747105A (en) | 1996-04-30 | 1998-05-05 | Owens Corning Fiberglas Technology Inc. | Traversing nozzle for applying granules to an asphalt coated sheet |
US6596224B1 (en) | 1996-05-24 | 2003-07-22 | Massachusetts Institute Of Technology | Jetting layers of powder and the formation of fine powder beds thereby |
GB9611582D0 (en) | 1996-06-04 | 1996-08-07 | Thin Film Technology Consultan | 3D printing and forming of structures |
US5824250A (en) | 1996-06-28 | 1998-10-20 | Alliedsignal Inc. | Gel cast molding with fugitive molds |
US6316060B1 (en) | 1996-08-20 | 2001-11-13 | Pacifica Papers Inc. | Metering coatings |
US5902441A (en) | 1996-09-04 | 1999-05-11 | Z Corporation | Method of three dimensional printing |
US7332537B2 (en) | 1996-09-04 | 2008-02-19 | Z Corporation | Three dimensional printing material system and method |
US6007318A (en) | 1996-12-20 | 1999-12-28 | Z Corporation | Method and apparatus for prototyping a three-dimensional object |
US7037382B2 (en) | 1996-12-20 | 2006-05-02 | Z Corporation | Three-dimensional printer |
US6989115B2 (en) | 1996-12-20 | 2006-01-24 | Z Corporation | Method and apparatus for prototyping a three-dimensional object |
DE29701279U1 (de) | 1997-01-27 | 1997-05-22 | Eos Electro Optical Syst | Vorrichtung mit einer Prozeßkammer und einem in der Prozeßkammer hin und her bewegbaren Element |
CA2288201A1 (en) | 1997-03-31 | 1998-10-08 | Therics, Inc. | Method for dispensing of powders |
US5940674A (en) | 1997-04-09 | 1999-08-17 | Massachusetts Institute Of Technology | Three-dimensional product manufacture using masks |
DE19715582B4 (de) | 1997-04-15 | 2009-02-12 | Ederer, Ingo, Dr. | Verfahren und System zur Erzeugung dreidimensionaler Körper aus Computerdaten |
NL1006059C2 (nl) * | 1997-05-14 | 1998-11-17 | Geest Adrianus F Van Der | Werkwijze en inrichting voor het vervaardigen van een vormlichaam. |
US5997795A (en) | 1997-05-29 | 1999-12-07 | Rutgers, The State University | Processes for forming photonic bandgap structures |
DE19723892C1 (de) | 1997-06-06 | 1998-09-03 | Rainer Hoechsmann | Verfahren zum Herstellen von Bauteilen durch Auftragstechnik |
DE19726778A1 (de) | 1997-06-24 | 1999-01-14 | Cerdec Ag | Verfahren zur Herstellung keramischer und glasiger Beschichtungen, elektrostatisch applizierbares Beschichtungspulver hierfür und seine Verwendung |
ES2324063T3 (es) | 1998-01-29 | 2009-07-29 | Amino Corporation | Aparato para conformado de materiales de lamina sin matriz. |
DE19805437A1 (de) | 1998-02-11 | 1999-08-12 | Bosch Gmbh Robert | Dosiervorrichtung für rieselfähiges Schüttgut |
US6355196B1 (en) | 1998-03-16 | 2002-03-12 | Vantico Inc. | Process for producing direct tooling mold and method for using the same |
US5989476A (en) | 1998-06-12 | 1999-11-23 | 3D Systems, Inc. | Process of making a molded refractory article |
JP3518726B2 (ja) | 1998-07-13 | 2004-04-12 | トヨタ自動車株式会社 | 積層造形方法及び積層造形用レジン被覆砂 |
US6476122B1 (en) | 1998-08-20 | 2002-11-05 | Vantico Inc. | Selective deposition modeling material |
DE19846478C5 (de) | 1998-10-09 | 2004-10-14 | Eos Gmbh Electro Optical Systems | Laser-Sintermaschine |
US20030114936A1 (en) | 1998-10-12 | 2003-06-19 | Therics, Inc. | Complex three-dimensional composite scaffold resistant to delimination |
US6363606B1 (en) * | 1998-10-16 | 2002-04-02 | Agere Systems Guardian Corp. | Process for forming integrated structures using three dimensional printing techniques |
DE19853834A1 (de) | 1998-11-21 | 2000-05-31 | Ingo Ederer | Verfahren zum Herstellen von Bauteilen durch Auftragstechnik |
JP2000211918A (ja) | 1999-01-20 | 2000-08-02 | Yazaki Corp | 軽量アルミナ粒子の製造方法 |
FR2790418B1 (fr) | 1999-03-01 | 2001-05-11 | Optoform Sarl Procedes De Prot | Procede de prototypage rapide permettant l'utilisation de materiaux pateux, et dispositif pour sa mise en oeuvre |
US6259962B1 (en) | 1999-03-01 | 2001-07-10 | Objet Geometries Ltd. | Apparatus and method for three dimensional model printing |
DE19911399C2 (de) | 1999-03-15 | 2001-03-01 | Joachim Heinzl | Verfahren zum Ansteuern eines Piezo-Druckkopfes und nach diesem Verfahren angesteuerter Piezo-Druckkopf |
TW554348B (en) | 1999-05-13 | 2003-09-21 | Shinetsu Chemical Co | Conductive powder and making process |
US6405095B1 (en) | 1999-05-25 | 2002-06-11 | Nanotek Instruments, Inc. | Rapid prototyping and tooling system |
US6165406A (en) | 1999-05-27 | 2000-12-26 | Nanotek Instruments, Inc. | 3-D color model making apparatus and process |
DE19928245B4 (de) | 1999-06-21 | 2006-02-09 | Eos Gmbh Electro Optical Systems | Einrichtung zum Zuführen von Pulver für eine Lasersintereinrichtung |
US6722872B1 (en) | 1999-06-23 | 2004-04-20 | Stratasys, Inc. | High temperature modeling apparatus |
US6401001B1 (en) | 1999-07-22 | 2002-06-04 | Nanotek Instruments, Inc. | Layer manufacturing using deposition of fused droplets |
US6972115B1 (en) | 1999-09-03 | 2005-12-06 | American Inter-Metallics, Inc. | Apparatus and methods for the production of powders |
US6658314B1 (en) | 1999-10-06 | 2003-12-02 | Objet Geometries Ltd. | System and method for three dimensional model printing |
DE19948591A1 (de) | 1999-10-08 | 2001-04-19 | Generis Gmbh | Rapid-Prototyping - Verfahren und - Vorrichtung |
EP1415792B1 (de) | 1999-11-05 | 2014-04-30 | 3D Systems Incorporated | Verfahren und Zusammenstellungen für dreidimensionales Drucken |
CA2388046A1 (en) | 1999-11-05 | 2001-05-17 | Z Corporation | Material systems and methods of three-dimensional printing |
US6395811B1 (en) | 1999-11-11 | 2002-05-28 | 3D Systems, Inc. | Phase change solid imaging material |
US6133353A (en) | 1999-11-11 | 2000-10-17 | 3D Systems, Inc. | Phase change solid imaging material |
GB9927127D0 (en) | 1999-11-16 | 2000-01-12 | Univ Warwick | A method of manufacturing an item and apparatus for manufacturing an item |
DE19957370C2 (de) | 1999-11-29 | 2002-03-07 | Carl Johannes Fruth | Verfahren und Vorrichtung zum Beschichten eines Substrates |
FR2802128B1 (fr) | 1999-12-10 | 2002-02-08 | Ecole Nale Sup Artes Metiers | Dispositif de depose de couches minces de matiere en poudre ou pulverulente et procede adapte |
TWI228114B (en) | 1999-12-24 | 2005-02-21 | Nat Science Council | Method and equipment for making ceramic work piece |
DE19963948A1 (de) | 1999-12-31 | 2001-07-26 | Zsolt Herbak | Verfahren zum Modellbau |
US7300619B2 (en) | 2000-03-13 | 2007-11-27 | Objet Geometries Ltd. | Compositions and methods for use in three dimensional model printing |
DE60014714T2 (de) | 2000-03-24 | 2006-03-02 | Voxeljet Technology Gmbh | Verfahren zum Herstellen eines Bauteils in Ablagerunstechnik |
KR100838878B1 (ko) | 2000-04-14 | 2008-06-16 | 제트 코포레이션 | 입체물의 삼차원 인쇄용 조성물 |
US20010050031A1 (en) | 2000-04-14 | 2001-12-13 | Z Corporation | Compositions for three-dimensional printing of solid objects |
JP2001334583A (ja) | 2000-05-25 | 2001-12-04 | Minolta Co Ltd | 三次元造形装置 |
DE10026955A1 (de) | 2000-05-30 | 2001-12-13 | Daimler Chrysler Ag | Materialsystem zur Verwendung beim 3D-Drucken |
SE520565C2 (sv) | 2000-06-16 | 2003-07-29 | Ivf Industriforskning Och Utve | Sätt och apparat vid framställning av föremål genom FFF |
US6619882B2 (en) | 2000-07-10 | 2003-09-16 | Rh Group Llc | Method and apparatus for sealing cracks in roads |
US6500378B1 (en) | 2000-07-13 | 2002-12-31 | Eom Technologies, L.L.C. | Method and apparatus for creating three-dimensional objects by cross-sectional lithography |
DE10085198D2 (de) | 2000-09-25 | 2003-08-21 | Generis Gmbh | Verfahren zum Herstellen eines Bauteils in Ablagerungstechnik |
DE10047614C2 (de) | 2000-09-26 | 2003-03-27 | Generis Gmbh | Vorrichtung zum schichtweisen Aufbau von Modellen |
DE10047615A1 (de) | 2000-09-26 | 2002-04-25 | Generis Gmbh | Wechselbehälter |
DE10049043A1 (de) | 2000-10-04 | 2002-05-02 | Generis Gmbh | Verfahren zum Entpacken von in ungebundenem Partikelmaterial eingebetteten Formkörpern |
DE10053741C1 (de) | 2000-10-30 | 2002-02-21 | Concept Laser Gmbh | Vorrichtung zum Sintern, Abtragen und/oder Beschriften mittels elektromagnetischer gebündelter Strahlung |
US20020111707A1 (en) | 2000-12-20 | 2002-08-15 | Zhimin Li | Droplet deposition method for rapid formation of 3-D objects from non-cross-linking reactive polymers |
US20020090410A1 (en) | 2001-01-11 | 2002-07-11 | Shigeaki Tochimoto | Powder material removing apparatus and three dimensional modeling system |
US6896839B2 (en) | 2001-02-07 | 2005-05-24 | Minolta Co., Ltd. | Three-dimensional molding apparatus and three-dimensional molding method |
DE10105504A1 (de) | 2001-02-07 | 2002-08-14 | Eos Electro Optical Syst | Vorrichtung zur Behandlung von Pulver für eine Vorrichtung zum Herstellen eines dreidimensionalen Objekts, Vorrichtung zum Herstellen eines dreidimensionalen Objekts und Verfahren zum Herstellen eines dreidimensionalen Objekts |
DE20122639U1 (de) | 2001-02-07 | 2006-11-16 | Eos Gmbh Electro Optical Systems | Vorrichtung zum Herstellen eines dreidimensionalen Objekts |
GB0103754D0 (en) | 2001-02-15 | 2001-04-04 | Vantico Ltd | Three-dimensional structured printing |
GB0103752D0 (en) | 2001-02-15 | 2001-04-04 | Vantico Ltd | Three-Dimensional printing |
US6939489B2 (en) | 2001-03-23 | 2005-09-06 | Ivoclar Vivadent Ag | Desktop process for producing dental products by means of 3-dimensional plotting |
DE10117875C1 (de) | 2001-04-10 | 2003-01-30 | Generis Gmbh | Verfahren, Vorrichtung zum Auftragen von Fluiden sowie Verwendung einer solchen Vorrichtung |
CA2442855A1 (en) | 2001-04-12 | 2002-10-24 | Therics, Inc. | Method and apparatus for engineered regenerative biostructures |
US20020155254A1 (en) | 2001-04-20 | 2002-10-24 | Mcquate William M. | Apparatus and method for placing particles in a pattern onto a substrate |
US6616030B2 (en) | 2001-05-07 | 2003-09-09 | West Bond, Inc. | Gantry mounted ultrasonic wire bonder with orbital bonding tool head |
GB0112675D0 (en) | 2001-05-24 | 2001-07-18 | Vantico Ltd | Three-dimensional structured printing |
DE10128664A1 (de) | 2001-06-15 | 2003-01-30 | Univ Clausthal Tech | Verfahren und Vorrichtung zur Herstellung von keramischen Formförpern |
JP2003052804A (ja) | 2001-08-09 | 2003-02-25 | Ichiro Ono | インプラントの製造方法およびインプラント |
US6841116B2 (en) | 2001-10-03 | 2005-01-11 | 3D Systems, Inc. | Selective deposition modeling with curable phase change materials |
JP2003136605A (ja) | 2001-11-06 | 2003-05-14 | Toshiba Corp | 製品の作成方法及びその製品 |
GB2382798A (en) | 2001-12-04 | 2003-06-11 | Qinetiq Ltd | Inkjet printer which deposits at least two fluids on a substrate such that the fluids react chemically to form a product thereon |
SE523394C2 (sv) | 2001-12-13 | 2004-04-13 | Fcubic Ab | Anordning och förfarande för upptäckt och kompensering av fel vid skiktvis framställning av en produkt |
US7005293B2 (en) | 2001-12-18 | 2006-02-28 | Agilent Technologies, Inc. | Multiple axis printhead adjuster for non-contact fluid deposition devices |
US6713125B1 (en) | 2002-03-13 | 2004-03-30 | 3D Systems, Inc. | Infiltration of three-dimensional objects formed by solid freeform fabrication |
DE10216013B4 (de) | 2002-04-11 | 2006-12-28 | Generis Gmbh | Verfahren und Vorrichtung zum Auftragen von Fluiden |
DE10222167A1 (de) | 2002-05-20 | 2003-12-04 | Generis Gmbh | Vorrichtung zum Zuführen von Fluiden |
DE10224981B4 (de) | 2002-06-05 | 2004-08-19 | Generis Gmbh | Verfahren zum schichtweisen Aufbau von Modellen |
WO2003106148A1 (de) | 2002-06-18 | 2003-12-24 | Daimlerchrysler Ag | Partikel und verfahren für die herstellung eines dreidimensionalen gegenstandes |
DE10227224B4 (de) | 2002-06-18 | 2005-11-24 | Daimlerchrysler Ag | Verwendung eines Granulates zum Herstellen eines Gegenstandes mit einem 3D-Binderdruck-Verfahren |
JP2005536324A (ja) | 2002-06-18 | 2005-12-02 | ダイムラークライスラー・アクチェンゲゼルシャフト | 処理精度を増大させたレーザ焼結法、及びその方法に用いられる粒子 |
US6986654B2 (en) | 2002-07-03 | 2006-01-17 | Therics, Inc. | Apparatus, systems and methods for use in three-dimensional printing |
DE10235434A1 (de) | 2002-08-02 | 2004-02-12 | Eos Gmbh Electro Optical Systems | Vorrichtung und Verfahren zum Herstellen eins dreidimensionalen Objekts mittels eines generativen Fertigungsverfahrens |
US6722822B2 (en) | 2002-08-20 | 2004-04-20 | The Young Industries, Inc. | System for pneumatically conveying bulk particulate materials |
US20040038009A1 (en) | 2002-08-21 | 2004-02-26 | Leyden Richard Noel | Water-based material systems and methods for 3D printing |
JP4069245B2 (ja) | 2002-08-27 | 2008-04-02 | 富田製薬株式会社 | 造形法 |
US7087109B2 (en) | 2002-09-25 | 2006-08-08 | Z Corporation | Three dimensional printing material system and method |
US20040112523A1 (en) | 2002-10-15 | 2004-06-17 | Crom Elden Wendell | Three dimensional printing from two dimensional printing devices |
US20040084814A1 (en) | 2002-10-31 | 2004-05-06 | Boyd Melissa D. | Powder removal system for three-dimensional object fabricator |
US6742456B1 (en) | 2002-11-14 | 2004-06-01 | Hewlett-Packard Development Company, L.P. | Rapid prototyping material systems |
US7153454B2 (en) | 2003-01-21 | 2006-12-26 | University Of Southern California | Multi-nozzle assembly for extrusion of wall |
US7497977B2 (en) | 2003-01-29 | 2009-03-03 | Hewlett-Packard Development Company, L.P. | Methods and systems for producing an object through solid freeform fabrication by varying a concentration of ejected material applied to an object layer |
WO2004073961A2 (de) | 2003-02-18 | 2004-09-02 | Daimlerchrysler Ag | Beschichtete pulverpartikel für die herstellung von dreidimensionalen körpern mittels schichtaufbauender verfahren |
DE602004023667D1 (de) | 2003-03-10 | 2009-12-03 | Kuraray Co | Binderfasern aus polyvinylalkohol und diese fasern enthaltendes papier und vliesstoff |
JP2004321332A (ja) | 2003-04-22 | 2004-11-18 | Kohjin Co Ltd | 消臭機能を有する材料及びその製造方法 |
ATE530331T1 (de) | 2003-05-21 | 2011-11-15 | Z Corp | Thermoplastisches pulvermaterialsystem für appearance models von 3d-drucksystemen |
EP1628831A2 (de) | 2003-05-23 | 2006-03-01 | Z Corporation | Gerät und verfahren zum 3d-drucken |
US7435072B2 (en) | 2003-06-02 | 2008-10-14 | Hewlett-Packard Development Company, L.P. | Methods and systems for producing an object through solid freeform fabrication |
US7807077B2 (en) | 2003-06-16 | 2010-10-05 | Voxeljet Technology Gmbh | Methods and systems for the manufacture of layered three-dimensional forms |
DE10327272A1 (de) | 2003-06-17 | 2005-03-03 | Generis Gmbh | Verfahren zum schichtweisen Aufbau von Modellen |
US20050012247A1 (en) | 2003-07-18 | 2005-01-20 | Laura Kramer | Systems and methods for using multi-part curable materials |
US7120512B2 (en) | 2003-08-25 | 2006-10-10 | Hewlett-Packard Development Company, L.P. | Method and a system for solid freeform fabricating using non-reactive powder |
US20050074511A1 (en) | 2003-10-03 | 2005-04-07 | Christopher Oriakhi | Solid free-form fabrication of solid three-dimesional objects |
US7348075B2 (en) | 2003-10-28 | 2008-03-25 | Hewlett-Packard Development Company, L.P. | System and method for fabricating three-dimensional objects using solid free-form fabrication |
US7455805B2 (en) | 2003-10-28 | 2008-11-25 | Hewlett-Packard Development Company, L.P. | Resin-modified inorganic phosphate cement for solid freeform fabrication |
US7381360B2 (en) | 2003-11-03 | 2008-06-03 | Hewlett-Packard Development Company, L.P. | Solid free-form fabrication of three-dimensional objects |
FR2865960B1 (fr) | 2004-02-06 | 2006-05-05 | Nicolas Marsac | Procede et machine pour realiser des objets en trois dimensions par depot de couches successives |
US20050219942A1 (en) | 2004-02-11 | 2005-10-06 | Kris Wallgren | Low profile mixing plant for particulate materials |
US7608672B2 (en) | 2004-02-12 | 2009-10-27 | Illinois Tool Works Inc. | Infiltrant system for rapid prototyping process |
DE102004008168B4 (de) | 2004-02-19 | 2015-12-10 | Voxeljet Ag | Verfahren und Vorrichtung zum Auftragen von Fluiden und Verwendung der Vorrichtung |
DE102004014806B4 (de) | 2004-03-24 | 2006-09-14 | Daimlerchrysler Ag | Rapid-Technologie-Bauteil |
US7435763B2 (en) | 2004-04-02 | 2008-10-14 | Hewlett-Packard Development Company, L.P. | Solid freeform compositions, methods of application thereof, and systems for use thereof |
WO2005097476A2 (en) | 2004-04-02 | 2005-10-20 | Z Corporation | Methods and apparatus for 3d printing |
DE102004020452A1 (de) | 2004-04-27 | 2005-12-01 | Degussa Ag | Verfahren zur Herstellung von dreidimensionalen Objekten mittels elektromagnetischer Strahlung und Auftragen eines Absorbers per Inkjet-Verfahren |
DE102004025374A1 (de) | 2004-05-24 | 2006-02-09 | Technische Universität Berlin | Verfahren und Vorrichtung zum Herstellen eines dreidimensionalen Artikels |
US7331948B2 (en) | 2004-06-18 | 2008-02-19 | Medtronic, Inc. | Catheter and catheter fabrication method |
JP4239915B2 (ja) * | 2004-07-16 | 2009-03-18 | セイコーエプソン株式会社 | マイクロレンズの製造方法およびマイクロレンズの製造装置 |
US7387359B2 (en) | 2004-09-21 | 2008-06-17 | Z Corporation | Apparatus and methods for servicing 3D printers |
JP4635618B2 (ja) | 2005-01-19 | 2011-02-23 | セイコーエプソン株式会社 | 充填方法、及び液体吐出装置 |
ITMI20050459A1 (it) | 2005-03-21 | 2006-09-22 | Montangero & Montangero S R L | Dispositivo di movimentazione al suolo di un corpo |
ITPI20050031A1 (it) | 2005-03-22 | 2006-09-23 | Moreno Chiarugi | Metodo e dispositivo per la realizzazione automatica di strutture di edifici in conglomerato |
US7357629B2 (en) | 2005-03-23 | 2008-04-15 | 3D Systems, Inc. | Apparatus and method for aligning a removable build chamber within a process chamber |
DE102005022308B4 (de) | 2005-05-13 | 2007-03-22 | Eos Gmbh Electro Optical Systems | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objekts mit einem beheizten Beschichter für pulverförmiges Aufbaumaterial |
US20060257579A1 (en) | 2005-05-13 | 2006-11-16 | Isaac Farr | Use of a salt of a poly-acid to delay setting in cement slurry |
US20060254467A1 (en) | 2005-05-13 | 2006-11-16 | Isaac Farr | Method for making spray-dried cement particles |
US20070045891A1 (en) | 2005-08-23 | 2007-03-01 | Valspar Sourcing, Inc. | Infiltrated Articles Prepared by a Laser Sintering Method and Method of Manufacturing the Same |
JP2007062334A (ja) | 2005-09-02 | 2007-03-15 | Fujifilm Corp | セルロースアシレート樹脂フィルム及びその製造方法 |
CA2622617A1 (en) | 2005-09-20 | 2007-04-12 | Pts Software Bv | An apparatus for building a three-dimensional article and a method for building a three-dimensional article |
DE102006040305A1 (de) | 2005-09-20 | 2007-03-29 | Daimlerchrysler Ag | Verfahren zur Herstellung eines dreidimensionalen Gegenstandes sowie damit hergestellter Gegenstand |
US7296990B2 (en) | 2005-10-14 | 2007-11-20 | Hewlett-Packard Development Company, L.P. | Systems and methods of solid freeform fabrication with translating powder bins |
DE102005056260B4 (de) | 2005-11-25 | 2008-12-18 | Prometal Rct Gmbh | Verfahren und Vorrichtung zum flächigen Auftragen von fließfähigem Material |
US20070126157A1 (en) | 2005-12-02 | 2007-06-07 | Z Corporation | Apparatus and methods for removing printed articles from a 3-D printer |
JP4247501B2 (ja) | 2005-12-27 | 2009-04-02 | 富田製薬株式会社 | 型の製造方法 |
US7621474B2 (en) | 2006-03-14 | 2009-11-24 | National Gypsum Properties, Llc | Method and apparatus for calcining gypsum |
EP2001656B1 (de) | 2006-04-06 | 2014-10-15 | 3D Systems Incorporated | Set zur herstellung dreidimensionaler objekte durch verwendung elektromagnetischer strahlung |
US7828022B2 (en) | 2006-05-26 | 2010-11-09 | Z Corporation | Apparatus and methods for handling materials in a 3-D printer |
DE102006029298B4 (de) | 2006-06-23 | 2008-11-06 | Stiftung Caesar Center Of Advanced European Studies And Research | Materialsystem für das 3D-Drucken, Verfahren zu seiner Herstellung, Granulat hergestellt aus dem Materialsystem und dessen Verwendung |
DE102006030350A1 (de) | 2006-06-30 | 2008-01-03 | Voxeljet Technology Gmbh | Verfahren zum Aufbauen eines Schichtenkörpers |
US20080018018A1 (en) | 2006-07-20 | 2008-01-24 | Nielsen Jeffrey A | Solid freeform fabrication methods and systems |
JP5108884B2 (ja) | 2006-07-27 | 2012-12-26 | アルカム アーベー | 3次元物体を生成する方法および装置 |
DE202006016477U1 (de) | 2006-10-24 | 2006-12-21 | Cl Schutzrechtsverwaltungs Gmbh | Vorrichtung zum Herstellen eines dreidimensionalen Objektes |
DE102006053121B3 (de) | 2006-11-10 | 2007-12-27 | Eos Gmbh Electro Optical Systems | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objektes mittels eines Beschichters für pulverförmiges Aufbaumaterial |
DE102006055326A1 (de) | 2006-11-23 | 2008-05-29 | Voxeljet Technology Gmbh | Vorrichtung und Verfahren zur Förderung von überschüssigem Partikelmaterial beim Aufbau von Modellen |
WO2008073297A2 (en) | 2006-12-08 | 2008-06-19 | Z Corporation | Three dimensional printing material system and method using peroxide cure |
PL1935652T3 (pl) | 2006-12-21 | 2010-09-30 | Agfa Nv | Sposób drukowania strumieniowego i zestawy tuszów |
US8167999B2 (en) | 2007-01-10 | 2012-05-01 | 3D Systems, Inc. | Three-dimensional printing material system with improved color, article performance, and ease of use |
JP4869155B2 (ja) | 2007-05-30 | 2012-02-08 | 株式会社東芝 | 物品の製造方法 |
DE102007033434A1 (de) | 2007-07-18 | 2009-01-22 | Voxeljet Technology Gmbh | Verfahren zum Herstellen dreidimensionaler Bauteile |
US10226919B2 (en) | 2007-07-18 | 2019-03-12 | Voxeljet Ag | Articles and structures prepared by three-dimensional printing method |
US20100279007A1 (en) | 2007-08-14 | 2010-11-04 | The Penn State Research Foundation | 3-D Printing of near net shape products |
DE102007040755A1 (de) | 2007-08-28 | 2009-03-05 | Jens Jacob | Lasersintervorrichtung sowie Verfahren zum Herstellen von dreidimensionalen Objekten durch selektives Lasersintern |
ITPI20070108A1 (it) | 2007-09-17 | 2009-03-18 | Enrico Dini | Metodo perfezionato per la realizzazione automatica di strutture di conglomerato |
DE102007047326B4 (de) | 2007-10-02 | 2011-08-25 | CL Schutzrechtsverwaltungs GmbH, 96215 | Vorrichtung zum Herstellen eines dreidimensionalen Objektes |
DE102007049058A1 (de) | 2007-10-11 | 2009-04-16 | Voxeljet Technology Gmbh | Materialsystem und Verfahren zum Verändern von Eigenschaften eines Kunststoffbauteils |
DE102007050679A1 (de) | 2007-10-21 | 2009-04-23 | Voxeljet Technology Gmbh | Verfahren und Vorrichtung zum Fördern von Partikelmaterial beim schichtweisen Aufbau von Modellen |
DE102007050953A1 (de) | 2007-10-23 | 2009-04-30 | Voxeljet Technology Gmbh | Vorrichtung zum schichtweisen Aufbau von Modellen |
JP5146010B2 (ja) | 2008-02-28 | 2013-02-20 | 東レ株式会社 | セラミックス成形体の製造方法およびこれを用いたセラミックス焼結体の製造方法 |
WO2009145069A1 (ja) | 2008-05-26 | 2009-12-03 | ソニー株式会社 | 造形装置および造形方法 |
DE102008058378A1 (de) | 2008-11-20 | 2010-05-27 | Voxeljet Technology Gmbh | Verfahren zum schichtweisen Aufbau von Kunststoffmodellen |
US7887264B2 (en) | 2008-12-11 | 2011-02-15 | Uop Llc | Apparatus for transferring particles |
WO2010075112A1 (en) | 2008-12-15 | 2010-07-01 | össur hf | Noise reduction device for articulating joint, and a limb support device having the same |
US8545209B2 (en) | 2009-03-31 | 2013-10-01 | Microjet Technology Co., Ltd. | Three-dimensional object forming apparatus and method for forming three-dimensional object |
JP5364439B2 (ja) | 2009-05-15 | 2013-12-11 | パナソニック株式会社 | 三次元形状造形物の製造方法 |
DE102009030113A1 (de) | 2009-06-22 | 2010-12-23 | Voxeljet Technology Gmbh | Verfahren und Vorrichtung zum Zuführen von Fluiden beim schichtweisen Bauen von Modellen |
US20100323301A1 (en) | 2009-06-23 | 2010-12-23 | Huey-Ru Tang Lee | Method and apparatus for making three-dimensional parts |
ES2386602T3 (es) | 2009-08-25 | 2012-08-23 | Bego Medical Gmbh | Dispositivo y procedimiento para la producción continua generativa |
DE102009055966B4 (de) | 2009-11-27 | 2014-05-15 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102009056696B4 (de) | 2009-12-02 | 2011-11-10 | Prometal Rct Gmbh | Baubox für eine Rapid-Prototyping-Anlage |
US9505931B2 (en) | 2009-12-21 | 2016-11-29 | Basf Se | Composite pavement structure |
US8211226B2 (en) | 2010-01-15 | 2012-07-03 | Massachusetts Institute Of Technology | Cement-based materials system for producing ferrous castings using a three-dimensional printer |
DE102010006939A1 (de) | 2010-02-04 | 2011-08-04 | Voxeljet Technology GmbH, 86167 | Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102010013733A1 (de) | 2010-03-31 | 2011-10-06 | Voxeljet Technology Gmbh | Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102010013732A1 (de) | 2010-03-31 | 2011-10-06 | Voxeljet Technology Gmbh | Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102010014969A1 (de) | 2010-04-14 | 2011-10-20 | Voxeljet Technology Gmbh | Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102010015451A1 (de) | 2010-04-17 | 2011-10-20 | Voxeljet Technology Gmbh | Verfahren und Vorrichtung zum Herstellen dreidimensionaler Objekte |
DE102010027071A1 (de) | 2010-07-13 | 2012-01-19 | Voxeljet Technology Gmbh | Vorrichtung zum Herstellen dreidimensionaler Modelle mittels Schichtauftragstechnik |
US8282380B2 (en) | 2010-08-18 | 2012-10-09 | Makerbot Industries | Automated 3D build processes |
DE102010056346A1 (de) * | 2010-12-29 | 2012-07-05 | Technische Universität München | Verfahren zum schichtweisen Aufbau von Modellen |
DE102011007957A1 (de) | 2011-01-05 | 2012-07-05 | Voxeljet Technology Gmbh | Vorrichtung und Verfahren zum Aufbauen eines Schichtenkörpers mit wenigstens einem das Baufeld begrenzenden und hinsichtlich seiner Lage einstellbaren Körper |
US8536547B2 (en) | 2011-01-20 | 2013-09-17 | Accuray Incorporated | Ring gantry radiation treatment delivery system with dynamically controllable inward extension of treatment head |
DE202011003443U1 (de) * | 2011-03-02 | 2011-12-23 | Bego Medical Gmbh | Vorrichtung zur generativen Herstellung dreidimensionaler Bauteile |
EP2522683B1 (de) * | 2011-05-10 | 2013-12-11 | Hüttenes-Albertus Chemische-Werke GmbH | Kieselsäurenestermodifizierte Phenol/Formaldehyd-Novolake und ihre Verwendung bei der Herstellung von harzbeschichteten Substraten |
WO2012164078A2 (de) | 2011-06-01 | 2012-12-06 | Bam Bundesanstalt Für Materialforschung Und- Prüfung | Verfahren zum herstellen eines formkörpers sowie vorrichtung |
DE102011105688A1 (de) | 2011-06-22 | 2012-12-27 | Hüttenes-Albertus Chemische Werke GmbH | Verfahren zum schichtweisen Aufbau von Modellen |
DE102011111498A1 (de) | 2011-08-31 | 2013-02-28 | Voxeljet Technology Gmbh | Vorrichtung zum schichtweisen Aufbau von Modellen |
DE102011053205B4 (de) | 2011-09-01 | 2017-05-24 | Exone Gmbh | Verfahren zum herstellen eines bauteils in ablagerungstechnik |
DE102011119338A1 (de) | 2011-11-26 | 2013-05-29 | Voxeljet Technology Gmbh | System zum Herstellen dreidimensionaler Modelle |
JP6066447B2 (ja) | 2011-12-14 | 2017-01-25 | 株式会社リコー | トナー並びにこれを用いた画像形成方法 |
US8789490B2 (en) | 2012-01-20 | 2014-07-29 | Sso Venture Partners, Llc | System and method of pointillist painting |
DE102012004213A1 (de) | 2012-03-06 | 2013-09-12 | Voxeljet Technology Gmbh | Verfahren und Vorrichtung zum Herstellen dreidimensionaler Modelle |
DE102012010272A1 (de) | 2012-05-25 | 2013-11-28 | Voxeljet Technology Gmbh | Verfahren zum Herstellen dreidimensionaler Modelle mit speziellen Bauplattformen und Antriebssystemen |
DE102012012363A1 (de) | 2012-06-22 | 2013-12-24 | Voxeljet Technology Gmbh | Vorrichtung zum Aufbauen eines Schichtenkörpers mit entlang des Austragbehälters bewegbarem Vorrats- oder Befüllbehälter |
US9168697B2 (en) | 2012-08-16 | 2015-10-27 | Stratasys, Inc. | Additive manufacturing system with extended printing volume, and methods of use thereof |
DE102012020000A1 (de) | 2012-10-12 | 2014-04-17 | Voxeljet Ag | 3D-Mehrstufenverfahren |
DE102013004940A1 (de) | 2012-10-15 | 2014-04-17 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von dreidimensionalen Modellen mit temperiertem Druckkopf |
DE102012022859A1 (de) | 2012-11-25 | 2014-05-28 | Voxeljet Ag | Aufbau eines 3D-Druckgerätes zur Herstellung von Bauteilen |
DE102012024266A1 (de) | 2012-12-12 | 2014-06-12 | Voxeljet Ag | Reinigungsvorrichtung zum Entfernen von an Bauteilen oder Modellen anhaftendem Pulver |
KR102097109B1 (ko) | 2013-01-21 | 2020-04-10 | 에이에스엠 아이피 홀딩 비.브이. | 증착 장치 |
WO2014125379A2 (en) | 2013-02-15 | 2014-08-21 | Matthew Fagan | Methods and systems for a plasma machine for the processing of all long steel product including universal beams using a gantry style plate cutting machine |
DE102013003303A1 (de) | 2013-02-28 | 2014-08-28 | FluidSolids AG | Verfahren zum Herstellen eines Formteils mit einer wasserlöslichen Gussform sowie Materialsystem zu deren Herstellung |
US9403725B2 (en) | 2013-03-12 | 2016-08-02 | University Of Southern California | Inserting inhibitor to create part boundary isolation during 3D printing |
CN103231513B (zh) * | 2013-04-01 | 2015-03-18 | 杭州笔水画王电子科技有限公司 | 3d打印方法及3d打印机 |
DE102013005855A1 (de) | 2013-04-08 | 2014-10-09 | Voxeljet Ag | Materialsystem und Verfahren zum Herstellen dreidimensionaler Modelle mit stabilisiertem Binder |
DE102013019716A1 (de) | 2013-11-27 | 2015-05-28 | Voxeljet Ag | 3D-Druckverfahren mit Schlicker |
DE102013018031A1 (de) | 2013-12-02 | 2015-06-03 | Voxeljet Ag | Wechselbehälter mit verfahrbarer Seitenwand |
DE102013020491A1 (de) | 2013-12-11 | 2015-06-11 | Voxeljet Ag | 3D-Infiltrationsverfahren |
DE102013021091A1 (de) | 2013-12-18 | 2015-06-18 | Voxeljet Ag | 3D-Druckverfahren mit Schnelltrockenschritt |
EP2886307A1 (de) | 2013-12-20 | 2015-06-24 | Voxeljet AG | Vorrichtung, Spezialpapier und Verfahren zum Herstellen von Formteilen |
DE102013021891A1 (de) | 2013-12-23 | 2015-06-25 | Voxeljet Ag | Vorrichtung und Verfahren mit beschleunigter Verfahrensführung für 3D-Druckverfahren |
DE102014004692A1 (de) | 2014-03-31 | 2015-10-15 | Voxeljet Ag | Verfahren und Vorrichtung für den 3D-Druck mit klimatisierter Verfahrensführung |
DE102014007584A1 (de) | 2014-05-26 | 2015-11-26 | Voxeljet Ag | 3D-Umkehrdruckverfahren und Vorrichtung |
EP3174651B1 (de) | 2014-08-02 | 2020-06-17 | voxeljet AG | Verfahren und gussform, insbesondere zur verwendung in kaltgussverfahren |
DE102014011544A1 (de) | 2014-08-08 | 2016-02-11 | Voxeljet Ag | Druckkopf und seine Verwendung |
DE102014014895A1 (de) | 2014-10-13 | 2016-04-14 | Voxeljet Ag | Verfahren und Vorrichtung zur Herstellung von Bauteilen in einem Schichtbauverfahren |
DE102014018579A1 (de) | 2014-12-17 | 2016-06-23 | Voxeljet Ag | Verfahren zum Herstellen dreidimensionaler Formteile und Einstellen des Feuchtegehaltes im Baumaterial |
DE102015006533A1 (de) | 2014-12-22 | 2016-06-23 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Schichtaufbautechnik |
DE102015003372A1 (de) | 2015-03-17 | 2016-09-22 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Doppelrecoater |
DE102015006363A1 (de) | 2015-05-20 | 2016-12-15 | Voxeljet Ag | Phenolharzverfahren |
DE102015008860A1 (de) | 2015-07-14 | 2017-01-19 | Voxeljet Ag | Vorrichtung zum Justieren eines Druckkopfes |
DE102015011503A1 (de) | 2015-09-09 | 2017-03-09 | Voxeljet Ag | Verfahren zum Auftragen von Fluiden |
DE102015011790A1 (de) | 2015-09-16 | 2017-03-16 | Voxeljet Ag | Vorrichtung und Verfahren zum Herstellen dreidimensionaler Formteile |
DE102015014964A1 (de) | 2015-11-20 | 2017-05-24 | Voxeljet Ag | Verfahren und Vorrichtung für 3D-Druck mit engem Wellenlängenspektrum |
DE102015015353A1 (de) | 2015-12-01 | 2017-06-01 | Voxeljet Ag | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Bauteilen mittels Überschussmengensensor |
DE102015016464B4 (de) | 2015-12-21 | 2024-04-25 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen |
DE102016002777A1 (de) | 2016-03-09 | 2017-09-14 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Baufeldwerkzeugen |
DE102016013610A1 (de) | 2016-11-15 | 2018-05-17 | Voxeljet Ag | Intregierte Druckkopfwartungsstation für das pulverbettbasierte 3D-Drucken |
DE102017006860A1 (de) | 2017-07-21 | 2019-01-24 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Spektrumswandler |
CN109055212B (zh) * | 2018-08-03 | 2022-05-03 | 浙江大学 | 一种多组分同轴打印喷头 |
-
2013
- 2013-10-30 DE DE201310018182 patent/DE102013018182A1/de not_active Ceased
-
2014
- 2014-10-29 US US15/029,759 patent/US10786945B2/en active Active
- 2014-10-29 WO PCT/DE2014/000546 patent/WO2015062569A1/de active Application Filing
- 2014-10-29 EP EP14809756.1A patent/EP3062992B1/de active Active
- 2014-10-29 KR KR1020167010887A patent/KR102250448B1/ko active IP Right Grant
- 2014-10-29 CN CN202010871045.1A patent/CN112060573A/zh active Pending
- 2014-10-29 CN CN201480057655.0A patent/CN105658416A/zh active Pending
- 2014-10-29 ES ES14809756T patent/ES2930346T3/es active Active
-
2020
- 2020-09-11 US US17/018,247 patent/US11541596B2/en active Active
-
2022
- 2022-12-22 US US18/145,466 patent/US20230131987A1/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0431924B1 (de) | 1989-12-08 | 1996-01-31 | Massachusetts Institute Of Technology | Dreidimensionale Drucktechniken |
EP1524049A2 (de) * | 2003-10-14 | 2005-04-20 | Hewlett-Packard Development Company, L.P. | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Formkörpern in einem Solid Free Form Verfahren |
DE102006038858A1 (de) * | 2006-08-20 | 2008-02-21 | Voxeljet Technology Gmbh | Selbstaushärtendes Material und Verfahren zum schichtweisen Aufbau von Modellen |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016184448A1 (de) * | 2015-05-20 | 2016-11-24 | Voxeljet Ag | Phenolharzverfahren |
KR20180011153A (ko) * | 2015-05-20 | 2018-01-31 | 복셀젯 아게 | 페놀 수지 방법 |
CN107708972A (zh) * | 2015-05-20 | 2018-02-16 | 沃克斯艾捷特股份有限公司 | 酚醛树脂的方法 |
US10843404B2 (en) | 2015-05-20 | 2020-11-24 | Voxeljet Ag | Phenolic resin method |
KR102482824B1 (ko) * | 2015-05-20 | 2022-12-28 | 복셀젯 아게 | 페놀 수지 방법 |
CN107273065A (zh) * | 2016-03-30 | 2017-10-20 | 佳能株式会社 | 管理系统及其方法 |
US10712726B2 (en) | 2016-03-30 | 2020-07-14 | Canon Kabushiki Kaisha | Management system and method thereof |
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US20160263828A1 (en) | 2016-09-15 |
US20200406602A1 (en) | 2020-12-31 |
KR20160078355A (ko) | 2016-07-04 |
EP3062992A1 (de) | 2016-09-07 |
KR102250448B1 (ko) | 2021-05-11 |
ES2930346T3 (es) | 2022-12-13 |
DE102013018182A1 (de) | 2015-04-30 |
US11541596B2 (en) | 2023-01-03 |
EP3062992B1 (de) | 2022-08-17 |
CN112060573A (zh) | 2020-12-11 |
US10786945B2 (en) | 2020-09-29 |
CN105658416A (zh) | 2016-06-08 |
US20230131987A1 (en) | 2023-04-27 |
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