WO2014178403A1 - チューブ用積層体 - Google Patents
チューブ用積層体 Download PDFInfo
- Publication number
- WO2014178403A1 WO2014178403A1 PCT/JP2014/061991 JP2014061991W WO2014178403A1 WO 2014178403 A1 WO2014178403 A1 WO 2014178403A1 JP 2014061991 W JP2014061991 W JP 2014061991W WO 2014178403 A1 WO2014178403 A1 WO 2014178403A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- laminate
- layer
- tube
- ink
- adhesive
- Prior art date
Links
- 239000010410 layer Substances 0.000 claims abstract description 105
- 239000002344 surface layer Substances 0.000 claims abstract description 36
- 229920000098 polyolefin Polymers 0.000 claims abstract description 24
- 230000001070 adhesive effect Effects 0.000 claims abstract description 21
- 239000000853 adhesive Substances 0.000 claims abstract description 20
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 20
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 20
- 239000012790 adhesive layer Substances 0.000 claims abstract description 18
- 229920005862 polyol Polymers 0.000 claims abstract description 16
- 150000003077 polyols Chemical class 0.000 claims abstract description 16
- 239000000758 substrate Substances 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 15
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 11
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 11
- -1 polyethylene terephthalate Polymers 0.000 claims description 10
- 229920005906 polyester polyol Polymers 0.000 claims description 3
- 125000004185 ester group Chemical group 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 69
- 238000007639 printing Methods 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 13
- 229920001684 low density polyethylene Polymers 0.000 description 13
- 239000004702 low-density polyethylene Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 229920000092 linear low density polyethylene Polymers 0.000 description 12
- 239000004707 linear low-density polyethylene Substances 0.000 description 12
- 230000032683 aging Effects 0.000 description 11
- 229920002799 BoPET Polymers 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 230000035882 stress Effects 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000000565 sealant Substances 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 4
- 238000003475 lamination Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 2
- 238000003854 Surface Print Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 238000009820 dry lamination Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- WVWYODXLKONLEM-UHFFFAOYSA-N 1,2-diisocyanatobutane Chemical compound O=C=NC(CC)CN=C=O WVWYODXLKONLEM-UHFFFAOYSA-N 0.000 description 1
- ZGDSDWSIFQBAJS-UHFFFAOYSA-N 1,2-diisocyanatopropane Chemical compound O=C=NC(C)CN=C=O ZGDSDWSIFQBAJS-UHFFFAOYSA-N 0.000 description 1
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
- PQDIQKXGPYOGDI-UHFFFAOYSA-N 1,3,5-triisocyanatobenzene Chemical compound O=C=NC1=CC(N=C=O)=CC(N=C=O)=C1 PQDIQKXGPYOGDI-UHFFFAOYSA-N 0.000 description 1
- JVYYFIRXDYRPNE-UHFFFAOYSA-N 1,3,6-triisocyanatohexane Chemical compound O=C=NCCCC(N=C=O)CCN=C=O JVYYFIRXDYRPNE-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- IKYNWXNXXHWHLL-UHFFFAOYSA-N 1,3-diisocyanatopropane Chemical compound O=C=NCCCN=C=O IKYNWXNXXHWHLL-UHFFFAOYSA-N 0.000 description 1
- QHEQAMSORGNVEX-UHFFFAOYSA-N 1,4,8-triisocyanatooctane Chemical compound O=C=NCCCCC(N=C=O)CCCN=C=O QHEQAMSORGNVEX-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- DFPJRUKWEPYFJT-UHFFFAOYSA-N 1,5-diisocyanatopentane Chemical compound O=C=NCCCCCN=C=O DFPJRUKWEPYFJT-UHFFFAOYSA-N 0.000 description 1
- VAGFVLBAZGSOAC-UHFFFAOYSA-N 1,6,11-triisocyanatoundecane Chemical compound O=C=NCCCCCC(N=C=O)CCCCCN=C=O VAGFVLBAZGSOAC-UHFFFAOYSA-N 0.000 description 1
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 1
- VVIOCXLZVIAWTH-UHFFFAOYSA-N 1,6-diisocyanato-3-(isocyanatomethyl)hexane Chemical compound O=C=NCCCC(CN=C=O)CCN=C=O VVIOCXLZVIAWTH-UHFFFAOYSA-N 0.000 description 1
- FELBNCXDZSNTIX-UHFFFAOYSA-N 1,8-diisocyanato-4-(isocyanatomethyl)-2,4,7-trimethyloctane Chemical compound O=C=NCC(C)CCC(C)(CN=C=O)CC(C)CN=C=O FELBNCXDZSNTIX-UHFFFAOYSA-N 0.000 description 1
- LHNAURKRXGPVDW-UHFFFAOYSA-N 2,3-diisocyanatobutane Chemical compound O=C=NC(C)C(C)N=C=O LHNAURKRXGPVDW-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000012939 laminating adhesive Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- AYLRODJJLADBOB-UHFFFAOYSA-N methyl 2,6-diisocyanatohexanoate Chemical compound COC(=O)C(N=C=O)CCCCN=C=O AYLRODJJLADBOB-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
Definitions
- the present invention relates to a laminated body for forming a tube container.
- PET polyethylene terephthalate
- Patent Document 1 describes that an aluminum oxide vapor-deposited PET film and a PET film provided with a printed layer are bonded by a dry lamination method using a two-component polyester adhesive (Patent Document 1). Paragraphs [0025] and [0031]).
- the laminate described in Patent Document 1 actually includes a layer structure of PET film // printing layer / PET film.
- the symbol “/” represents an extrusion laminate, and the symbol “//” represents a dry laminate adhesive.
- the ink composition is printed on a base material, and the printed surface of the base material and the sealant film are laminated via a laminating adhesive. It has a layer structure of adhesive / ink layer / base material.
- Patent Document 2 describes that when the laminate strength between the surface layer and the ink layer is 1.0 N / 15 mm or more, it reaches a practical level.
- the laminated body for a tube described in Patent Document 1 has a problem in that when a stress is applied during molding of the shoulder portion of the tube, the printed layer is agglomerated and peeled and the surface layer film is rolled.
- Patent Document 1 since the laminate for a tube described in Patent Document 1 always requires a dry laminate of an aluminum oxide vapor-deposited PET film and a PET film provided with a printing layer, there is still room for studying handling properties and economy. is there.
- Patent Document 2 does not describe the use of the tube container. Even if an attempt is made to form a tube container using the packaging material described in Patent Document 2, if the laminate strength between the surface layer and the ink layer is 1.0 N / 15 mm, this occurs when the shoulder portion of the tube is molded. The surface layer is expected to peel off because it cannot withstand the stress.
- an object of the present invention is to provide a laminated body for a tube having a high laminate strength between a surface layer and a printed layer and capable of forming the printed layer by surface printing, and a tube container using the same.
- the present inventors can solve the above-mentioned problems by adopting surface printing, forming a UV ink layer on the polyolefin surface of the substrate, and providing a specific adhesive layer between the UV ink layer and the surface layer. And the present invention was completed. That is, the present invention is as follows. [1] A laminated body for a tube including a laminated surface layer, an adhesive layer, a UV ink layer, and a base material laminated body, wherein the adhesive layer is a two-component type of a polyol having an ester portion and a polyisocyanate.
- the tube laminate which is formed of an adhesive and has a surface in contact with the UV ink layer of the substrate laminate formed of polyolefin.
- the laminate strength is improved between the surface layer and the UV ink layer, it is possible to prevent cohesive peeling and prevent the surface layer from being lifted due to stress. Furthermore, a print pattern can be formed even on the seam portion of the tube, and in particular, the print pattern can be formed on the entire surface of the base material laminate to ensure the design of the tube container. Therefore, according to this invention, the process which prints UV ink on all the surfaces of a base-material laminated body, ie, a full print, can be achieved.
- FIG. 1 is a schematic cross-sectional view of a tube laminate described in Patent Document 1.
- FIG. 2A is a schematic cross-sectional view of the extruded laminate described in Patent Document 2
- FIG. 2B is a schematic cross-sectional view of the dry laminate described in Patent Document 2.
- FIG. 3 is a schematic cross-sectional view of a tube laminate according to an embodiment of the present invention.
- the tube laminate has a layer structure of surface layer / adhesive layer / UV ink layer / substrate laminate. As shown in FIG. 3, the surface layer (13), the adhesive layer (6), the UV ink layer (14), and the substrate laminate (15) are directed from the front side to the back side of the tube laminate (12). They are stacked in order. Moreover, a base-material laminated body (15) contains parts (15b) other than a polyolefin surface (15a) and a polyolefin surface (15a).
- the surface layer is a layer that becomes the outermost layer when a tube is formed from the tube laminate.
- the surface layer may be a single layer or a laminate in which a plurality of layers are laminated, and may include a plurality of layers of the same type.
- the surface layer may include at least one film and optionally a printed layer, a foil stamping layer, an adhesive layer, a barrier layer, a sealant layer, and any combination thereof.
- the printing layer, the foil stamping layer, the adhesive layer, the barrier layer, and the sealant layer can be respectively disposed in at least a part of the layer or film in which these layers are laminated.
- the surface layer preferably contains a polyolefin, more preferably a polyethylene film, from the viewpoint of low-temperature sealability (seal strength).
- polyethylene film examples include a low density polyethylene (LDPE) film, a linear low density polyethylene (LLDPE) film, a medium density polyethylene (MDPE) film, and a high density polyethylene (HDPE) film.
- LDPE low density polyethylene
- LLDPE linear low density polyethylene
- MDPE medium density polyethylene
- HDPE high density polyethylene
- the adhesive layer is a layer for adhering the surface layer and the UV ink layer, and is formed by applying a two-component adhesive.
- the application amount of the two-component adhesive is preferably 3 g / m 2 or more in order to ensure adhesive strength and prevent peeling of the laminate during tubing and to obtain predetermined content resistance.
- the application amount of the two-component adhesive is preferably 5 g / m 2 or less in order to prevent poor drying and generation of a strange odor due to the residual solvent in consideration of the upper limit of economy and adhesive strength.
- the two-component adhesive is a combination of a polyol having an ester moiety and a polyisocyanate.
- the “polyol having an ester moiety” and “polyisocyanate” will be described below.
- the polyol having an ester moiety has heat resistance, strong initial tack, and excellent content resistance.
- the initial tack is a property of exhibiting adhesive force by forming a bond immediately after contact with the adherend, and is also referred to as initial adhesiveness.
- the polyol having an ester portion is superior in content resistance as compared with the polyol having an ether portion, it is possible to prevent the tube container from being broken from the side seam after the tube container is filled with the content.
- the adhesive strength of the two-component adhesive before the crosslinking with the polyisocyanate proceeds depends on the cohesive energy of the main agent, and thus has a higher cohesive strength than the polyol having an ether moiety. Polyols having ester moieties are considered advantageous in initial adhesion.
- the polyol having an ester moiety is preferably a polyester polyol from the viewpoint of crosslinking with isocyanate.
- a polyisocyanate is a compound having at least two isocyanate groups, and is crosslinked with a polyol to form an oligomer or polymer.
- polyisocyanate for example, when producing a laminate for a tube that produces a high-class feeling by utilizing design properties, such as a raw material of silver, use an aliphatic polyisocyanate having excellent light resistance. Is preferred.
- aliphatic polyisocyanate examples include trimethylene diisocyanate, tetramethylene diisocyanate, hexamethylene diisocyanate, pentamethylene diisocyanate, 1,2-propylene diisocyanate, 1,2-butylene diisocyanate, 2,3-butylene diisocyanate, 1,3- Aliphatic diisocyanates such as butylene diisocyanate, 2,4,4- or 2,2,4-trimethylhexamethylene diisocyanate, dimer acid diisocyanate, methyl 2,6-diisocyanatohexanoate; 2,6-diisocyanatohexanoic acid 2-isocyanatoethyl, 1,6-diisocyanato-3-isocyanatomethylhexane, 1,4,8-triisocyanatooctane, 1,6,11-triisocyanatoundecane, 1 Aliphatic triisocyanates such as 8-diis,
- aromatic polyisocyanate it is preferable to use an aromatic polyisocyanate in order to ensure content resistance.
- aromatic polyisocyanate examples include m-phenylene diisocyanate, p-phenylene diisocyanate, 4,4′-diphenyl diisocyanate, 1,5-naphthalene diisocyanate, 2,4-tolylene diisocyanate, or 2,6-tolylene diisocyanate, Aromatic diisocyanates such as 4,4′-toluidine diisocyanate, 4,4′-diphenyl ether diisocyanate; triphenylmethane-4,4 ′, 4 ′′ -triisocyanate, 1,3,5-triisocyanatobenzene, 2, Aromatic triisocyanates such as 4,6-triisocyanatotoluene; aromatic tetraisocyanates such as 4,4′-diphenylmethane-2,2 ′, 5,5′-tetraisocyanate and the like.
- Aromatic diisocyanates such as 4,4′-toluidine diisocyanate,
- the UV ink layer is a layer formed of UV ink, and is disposed on the surface layer side of the substrate.
- Examples of the UV ink layer include a printing layer.
- the UV ink layer may be disposed at a position corresponding to the seal portion on the surface of the substrate laminate, and in particular, may be disposed on the entire surface of the substrate laminate.
- UV ink is an ultraviolet curable ink, and it is difficult to cause ink cracking and fading when sealing a laminate for a tube.
- Ink cracking refers to a phenomenon in which a print pattern formed with ink cracks.
- a UV ink layer may be formed by covering the printed surface of the substrate laminate with a single UV ink, and printing a single UV ink or multiple UV inks on the printed surface of the substrate laminate. Thus, a UV ink layer having a pattern, gradation, or the like may be formed.
- UV ink contains a photopolymerizable polymer, optionally a monomer, a photopolymerization initiator, and a colorant.
- the colorant include pigments and dyes.
- the UV ink preferably has light resistance and heat resistance, and is a UV flexo ink in order to ensure printing reproducibility with respect to a substrate having various surface characteristics, for example, against a polyolefin substrate. It is more preferable.
- polyisocyanate to the UV ink in order to improve the adhesion of the UV ink to the base material layer and to suppress cohesive peeling. It is preferable to add polyisocyanate to the UV ink because a crosslinked structure can be formed between the UV ink layer and the base material layer or between the UV ink layer and the adhesive layer.
- the polyisocyanate contained in the UV ink may be the same as that contained in the two-component adhesive as described above.
- the initial laminate strength between the UV ink layer and the surface layer is preferably 3.0 N / 15 mm or more, and 6.0 N / 15 mm or more. More preferably.
- the initial laminate strength refers to the laminate strength measured 30 minutes after the completion of lamination.
- the substrate laminate is a layer printed with UV ink.
- the surface in contact with the UV ink layer of the substrate laminate is formed of polyolefin.
- the base material laminated body may contain arbitrary layers.
- the substrate laminate may be a single layer or a multilayer, and may be formed of one or a plurality of polyolefin films.
- the substrate laminate preferably includes a polyolefin film so that the polyolefin film becomes the innermost layer when a tube is formed from the laminate for a tube.
- the polyolefin film may be the same as that contained in the surface layer as described above.
- Examples of the layer included in the substrate laminate include a barrier layer, a polyethylene terephthalate (PET) film, and a sealant layer.
- a barrier layer a polyethylene terephthalate (PET) film
- PET polyethylene terephthalate
- the substrate laminate preferably includes a PET film in a portion other than the surface in contact with the UV ink layer.
- barrier layer examples include a metal foil layer and a metal / inorganic vapor deposition layer.
- the sealant layer may be formed of, for example, a polyolefin such as LDPE or LLDPE.
- the tube laminate can be manufactured by a method comprising the following steps: A printing step of printing a UV ink on the substrate laminate to form a UV ink layer; A lamination step of laminating a surface layer on the UV ink layer via an adhesive to obtain a laminate; and an aging step of aging the laminate to obtain a laminate for a tube.
- a substrate laminate having a polyolefin surface is prepared.
- UV ink may be printed at a location corresponding to the seal portion on the polyolefin surface, and in particular, UV ink may be printed on the entire polyolefin surface.
- the printing process can be performed by flexographic printing using UV flexographic ink.
- the lamination step can be performed by dry lamination using a two-component adhesive of a polyol having an ester moiety and a polyisocyanate.
- the aging step may be continued until the laminate strength between the surface layer and the UV ink layer does not substantially vary, and can be performed, for example, at 40 ° C. for 6 days.
- the laminated body for a tube of the present invention not only can improve the laminate strength between the surface layer and the UV ink layer and prevent the ink layer from cohesive peeling and the surface layer from being lifted by stress, but also to the seam portion of the tube.
- a tube container is a container which has the trunk
- the tube container can be filled with contents such as chemicals, cosmetics and food.
- contents include toothpaste, moisturizing cream, sunscreen and the like.
- the tube container can be manufactured by a method comprising the following steps: The tube laminate is rolled so that the back layer is inside, and the ends of the laminate are overlapped and sealed to obtain a trunk; and the shoulder and the periphery of the opening of the trunk The process of combining the head which has a cap part, and obtaining a tube container.
- LLDPE Layer structure of LLDPE (50) / LDPE (80) / EAA (20) / AL (12) / EMAA (30) / PET (12) // LLDPE (100) in order from the front side to the back side (in parentheses) (A number represents a thickness in ⁇ m) and a substrate having a width of 200 mm and a length of 800 m was prepared.
- the printed layer was formed by flexographic printing UV ink on the front side of the substrate.
- the printed layer and the surface layer were dry laminated via an adhesive in accordance with the following production conditions to obtain a laminated body for a tube.
- Production conditions Line speed: 30 m / min
- the laminated body for tubes was LLDPE (90) // printed layer-LLDPE (50) / LDPE (80) / EAA (20) / in order from the front side to the back side. It had a layer structure of AL (12) / EMAA (30) / PET (12) // LLDPE (100).
- Comparative Example 2 a commercially available laminate for a tube having a gravure printing layer was prepared.
- Commercially available laminates for tubes are LLDPE (35) / LLDPE / LDPE (20) / PET-printed layer / LDPE (25) / white LDPE (100) / PETSiO x (12) / in order from the front side to the back side. It had a layer configuration of EMAA / LLDPE (80).
- the initial laminate strength between the surface layer and the UV ink layer was measured using a strograph (for EL) manufactured by Toyo Seiki Co., Ltd. according to the following measurement conditions. (Measurement condition) Between gripping tools: 50mm Tensile speed: 150 mm / min Peeling type: T-peeling
- the laminated body for tubes after aging was cut into a width of 15 mm and a length of 150 mm to obtain a test piece.
- Comparative Example 1 using an ether-based main agent, the initial laminate strength was insufficient, so that laminate lifting occurred when stress was applied to the original fabric. Therefore, the tube laminate of Comparative Example 1 has insufficient handling properties.
- Comparative Example 2 ink layer aggregation peeling or PET surface peeling was observed after aging. Accordingly, the tube laminate of Comparative Example 2 is expected to cause surface layer peeling when an external force is applied to the end face during molding of the shoulder portion or the like.
- the laminate for a tube of the present invention can be used for manufacturing a tube container.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Tubes (AREA)
- Wrappers (AREA)
Abstract
Description
[1] 積層されている表層、接着剤層、UVインキ層及び基材積層体を含むチューブ用積層体であって、前記接着剤層は、エステル部分を有するポリオールとポリイソシアネートとの2液型接着剤で形成されており、かつ前記基材積層体の前記UVインキ層と接する面は、ポリオレフィンで形成されている、チューブ用積層体。
[2] 前記UVインキ層は、ポリイソシアネートを含むUVインキで形成されている、[1]に記載のチューブ用積層体。
[3] 前記エステル部分を有するポリオールは、ポリエステルポリオールである、[1]又は[2]に記載のチューブ用積層体。
[4] 前記表層と前記UVインキ層の間の初期ラミネート強度が、3.0N/15mm以上である、[1]~[3]のいずれか1項に記載のチューブ用積層体。
[5] 前記表層は、ポリオレフィンを含む、[1]~[4]のいずれか1項に記載のチューブ用積層体。
[6] 前記UVインキは、UVフレキソインキである、[2]に記載のチューブ用積層体。
[7] 前記基材積層体は、ポリエチレンテレフタレートフィルムを含む、[1]~[6]のいずれか1項に記載のチューブ用積層体。
[8] 前記UVインキ層が、前記基材積層体の表面のシール部に対応する箇所に配置されている、[1]~[7]のいずれか1項に記載のチューブ用積層体。
[9] 前記UVインキ層が、前記基材積層体の表面の全てに配置されている、[1]~[8]のいずれか1項に記載のチューブ用積層体。
[10] [1]~[9]のいずれか1項に記載のチューブ用積層体で形成された胴部を有するチューブ容器。
チューブ用積層体は、表層/接着剤層/UVインキ層/基材積層体、という層構成を有する。図3に示されるように、表層(13)、接着剤層(6)、UVインキ層(14)、基材積層体(15)は、チューブ用積層体(12)の表側から裏側に向かって順に積層されている。また、基材積層体(15)は、ポリオレフィン面(15a)とポリオレフィン面(15a)以外の部分(15b)を含む。
表層は、チューブ用積層体からチューブを形成したときに最外層となる層である。表層は、単層、又は複数の層が積層されている積層体でよく、また複数の同じ種類の層を含んでよい。表層は、少なくとも1つのフィルムと、随意に、印刷層、箔押し層、接着剤層、バリア層、シーラント層及びこれらの任意の組み合わせとを含んでよい。印刷層、箔押し層、接着剤層、バリア層及びシーラント層は、これらの層が積層される層又はフィルムの少なくとも一部分にそれぞれ配置されることができる。表層は、低温シール性(シール強度)の観点から、ポリオレフィンを含むことが好ましく、ポリエチレンフィルムであることがより好ましい。
接着剤層は、表層とUVインキ層を接着するための層であり、かつ2液型接着剤を塗布することにより形成される。
エステル部分を有するポリオールは、耐熱性と、強い初期タックを有し、かつ耐内容物性に優れる。なお、初期タックは、被着材と接触させた直後から結合を形成して接着力を発揮する性質であり、初期接着性とも呼ばれる。
ポリイソシアネートは、少なくとも2つのイソシアネート基を有する化合物であり、ポリオールと架橋してオリゴマー又はポリマーを形成する。
UVインキ層は、UVインキで形成されている層であり、かつ基材よりも表層側に配置されている。UVインキ層としては、例えば、印刷層などが挙げられる。UVインキ層は、基材積層体の表面のシール部に対応する箇所に配置されていてよく、特に、基材積層体の表面の全てに配置されていてよい。
基材積層体は、UVインキを印刷される層である。基材積層体のUVインキ層と接する面は、ポリオレフィンで形成されている。
チューブ用積層体は、以下の工程を含む方法により製造されることができる:
基材積層体にUVインキを印刷して、UVインキ層を形成する印刷工程;
UVインキ層の上に接着剤を介して表層を積層して、積層体を得る積層工程;及び
積層体をエージングして、チューブ用積層体を得るエージング工程。
チューブ容器は、チューブ用積層体で形成された胴部を有する容器である。
チューブ用積層体を、裏層が内側となるように丸めながら、積層体の端部同士を重ね合せてシールして、胴部を得る工程;及び
胴部の開口部の周縁に、肩部及びキャップ部を有する頭部を結合させて、チューブ容器を得る工程。
実施例1~4及び比較例1について、下記表1に示される通りに、UVインキ、接着剤及び表層を用意した。
FDFL:紫外線硬化型フレキソインキの商品名(東洋インキ株式会社製)
添加剤:ヘキサメチレンジイソシアネート
TM-277:エステル系主剤の商品名(東洋モートン株式会社製)
A-310:エステル系主剤の商品名(三井化学株式会社製)
A-620:エステル系主剤の商品名(三井化学株式会社製)
A-969V:エーテル系主剤の商品名(三井化学株式会社製)
cat-RT86:脂肪族硬化剤の商品名(東洋モートン株式会社製)
cat-10L:芳香族硬化剤の商品名(東洋モートン株式会社製)
A-3:芳香族硬化剤の商品名(三井化学株式会社製)
A-65:脂肪族硬化剤の商品名(三井化学株式会社製)
A-8:芳香族硬化剤の商品名(三井化学株式会社製)
L-103:LLDPEフィルムの商品名(アイセロ化学株式会社製:厚さ90μm)
(製造条件)
ライン速度:30m/分
接着剤塗布量:3.5g/m2
1.表層(ポリオレフィン)とUVインキ層の間の初期ラミネート強度測定
実施例1~4及び比較例1のチューブ用積層体を作製してから30分後に、チューブ用積層体を幅15mm及び長さ150mmに切断して、試験片を得た。
(測定条件)
掴み具間:50mm
引張速度:150mm/分
剥離の種類:T字剥離
実施例1~4並びに比較例1及び2のチューブ用積層体を、40℃で6日間に亘ってエージングした。
表2から、ポリエステル系主剤を使用した実施例1~4では、ラミネート直後でも、十分なラミネート強度が得られることが分かる。
表2から、基材のポリオレフィン(LLDPE)面にUVインキを表刷りしている実施例1~4は、PET基材に裏刷りしているグラビア原反(比較例2)と比較して、インキ塗布面が柔軟なので、応力緩和により凝集剥離又は表層剥離を起こさず、エージング後も十分なラミネート強度を確保できることが分かる。
2 表側
3 裏側
4 ポリエチレン層
5 ポリエチレンテレフタレート層
6 接着剤層
7 印刷層
8 押出し積層体
9 ドライラミネート体
10 アンカー剤層
11 ポリプロピレン層
12 チューブ用積層体
13 表層
14 UVインキ層
15 基材積層体
15a ポリオレフィン面
15b ポリオレフィン面以外の部分
Claims (10)
- 積層されている表層、接着剤層、UVインキ層及び基材積層体を含むチューブ用積層体であって、前記接着剤層は、エステル部分を有するポリオールとポリイソシアネートとの2液型接着剤で形成されており、かつ前記基材積層体の前記UVインキ層と接する面は、ポリオレフィンで形成されている、チューブ用積層体。
- 前記UVインキ層は、ポリイソシアネートを含むUVインキで形成されている、請求項1に記載のチューブ用積層体。
- 前記エステル部分を有するポリオールは、ポリエステルポリオールである、請求項1又は2に記載のチューブ用積層体。
- 前記表層と前記UVインキ層の間の初期ラミネート強度が、3.0N/15mm以上である、請求項1~3のいずれか1項に記載のチューブ用積層体。
- 前記表層は、ポリオレフィンを含む、請求項1~4のいずれか1項に記載のチューブ用積層体。
- 前記UVインキは、UVフレキソインキである、請求項2に記載のチューブ用積層体。
- 前記基材積層体は、ポリエチレンテレフタレートフィルムを含む、請求項1~6のいずれか1項に記載のチューブ用積層体。
- 前記UVインキ層が、前記基材積層体の表面のシール部に対応する箇所に配置されている、請求項1~7のいずれか1項に記載のチューブ用積層体。
- 前記UVインキ層が、前記基材積層体の表面の全てに配置されている、請求項1~8のいずれか1項に記載のチューブ用積層体。
- 請求項1~9のいずれか1項に記載のチューブ用積層体で形成された胴部を有するチューブ容器。
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015514867A JP5791851B2 (ja) | 2013-04-30 | 2014-04-30 | チューブ用積層体 |
SG11201508440QA SG11201508440QA (en) | 2013-04-30 | 2014-04-30 | Laminate for tubes |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013-095316 | 2013-04-30 | ||
JP2013095316 | 2013-04-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014178403A1 true WO2014178403A1 (ja) | 2014-11-06 |
Family
ID=51843527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2014/061991 WO2014178403A1 (ja) | 2013-04-30 | 2014-04-30 | チューブ用積層体 |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP5791851B2 (ja) |
MY (1) | MY174697A (ja) |
SG (1) | SG11201508440QA (ja) |
WO (1) | WO2014178403A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015182616A1 (ja) * | 2014-05-30 | 2015-12-03 | 共同印刷株式会社 | チューブ用積層体及びチューブ容器 |
WO2016021282A1 (ja) * | 2014-08-08 | 2016-02-11 | 共同印刷株式会社 | チューブ用積層体及びチューブ容器 |
JP7482678B2 (ja) | 2020-05-12 | 2024-05-14 | 共同印刷株式会社 | ラミネートチューブ用積層体 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0585032A (ja) * | 1991-07-04 | 1993-04-06 | Tdk Corp | 難接着性プラスチツク基体用印刷インキ、同基体の印刷物、及び同基体への印刷方法 |
JPH11179863A (ja) * | 1997-12-19 | 1999-07-06 | Toppan Printing Co Ltd | ラミネートチューブ用積層シート |
JP2000272633A (ja) * | 1999-01-21 | 2000-10-03 | Oji Yuka Synthetic Paper Co Ltd | 袋状容器 |
JP2005306415A (ja) * | 2004-04-20 | 2005-11-04 | Dainippon Printing Co Ltd | ラミネ−トチュ−ブ容器 |
JP2012071419A (ja) * | 2010-09-27 | 2012-04-12 | Asahi Kasei E-Materials Corp | 積層物 |
JP2012144290A (ja) * | 2011-01-14 | 2012-08-02 | Dainippon Printing Co Ltd | 歯磨チューブ用積層材および歯磨き用チューブ容器 |
-
2014
- 2014-04-30 WO PCT/JP2014/061991 patent/WO2014178403A1/ja active Application Filing
- 2014-04-30 MY MYPI2015703553A patent/MY174697A/en unknown
- 2014-04-30 SG SG11201508440QA patent/SG11201508440QA/en unknown
- 2014-04-30 JP JP2015514867A patent/JP5791851B2/ja active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0585032A (ja) * | 1991-07-04 | 1993-04-06 | Tdk Corp | 難接着性プラスチツク基体用印刷インキ、同基体の印刷物、及び同基体への印刷方法 |
JPH11179863A (ja) * | 1997-12-19 | 1999-07-06 | Toppan Printing Co Ltd | ラミネートチューブ用積層シート |
JP2000272633A (ja) * | 1999-01-21 | 2000-10-03 | Oji Yuka Synthetic Paper Co Ltd | 袋状容器 |
JP2005306415A (ja) * | 2004-04-20 | 2005-11-04 | Dainippon Printing Co Ltd | ラミネ−トチュ−ブ容器 |
JP2012071419A (ja) * | 2010-09-27 | 2012-04-12 | Asahi Kasei E-Materials Corp | 積層物 |
JP2012144290A (ja) * | 2011-01-14 | 2012-08-02 | Dainippon Printing Co Ltd | 歯磨チューブ用積層材および歯磨き用チューブ容器 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015182616A1 (ja) * | 2014-05-30 | 2015-12-03 | 共同印刷株式会社 | チューブ用積層体及びチューブ容器 |
JP6067186B2 (ja) * | 2014-05-30 | 2017-01-25 | 共同印刷株式会社 | チューブ用積層体及びチューブ容器 |
WO2016021282A1 (ja) * | 2014-08-08 | 2016-02-11 | 共同印刷株式会社 | チューブ用積層体及びチューブ容器 |
JP6067193B2 (ja) * | 2014-08-08 | 2017-01-25 | 共同印刷株式会社 | チューブ用積層体及びチューブ容器 |
JP7482678B2 (ja) | 2020-05-12 | 2024-05-14 | 共同印刷株式会社 | ラミネートチューブ用積層体 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2014178403A1 (ja) | 2017-02-23 |
MY174697A (en) | 2020-05-08 |
JP5791851B2 (ja) | 2015-10-07 |
SG11201508440QA (en) | 2015-11-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9731480B2 (en) | Printed polyester film based laminate, method of making and application thereof | |
US7244496B2 (en) | Tamper evident flow wrap | |
WO2018062331A1 (ja) | 積層体 | |
EP3196145B1 (en) | Multilayer film for disposable pocket warmer wrapper and disposable pocket warmer | |
US10695215B2 (en) | Multilayer film for disposable body warmer outer bag, and disposable body warmer | |
JP5791851B2 (ja) | チューブ用積層体 | |
JP2018530454A (ja) | フレキシブル包装材料 | |
JP6067186B2 (ja) | チューブ用積層体及びチューブ容器 | |
JP6255845B2 (ja) | 包装用積層レトルト材及びそれを用いた包装用レトルト体並びに包装用レトルトレーザー印字体 | |
WO2018034350A1 (ja) | 液体用紙容器の製造方法及び液体用紙容器 | |
EP3339026A1 (en) | An adhesive ink composition | |
KR20170000170A (ko) | 도용 방지용 알루미늄 라미네이트 다층 시트의 제조방법 및 그 도용 방지용 알루미늄 라미네이트 다층 시트 | |
JP5263899B2 (ja) | 透明ガスバリアフイルム | |
WO2005014701A1 (ja) | 熱可塑性樹脂フィルム | |
JP6003228B2 (ja) | ブランク | |
BR102015012729A2 (pt) | método de fabricação de uma estrutura de papel cartão altamente resistente a umidade, substrato de papel cartão e seus usos | |
JP6067193B2 (ja) | チューブ用積層体及びチューブ容器 | |
WO2016181827A1 (ja) | 紫外線吸収層を有する包装用積層体 | |
JP7088128B2 (ja) | チューブ容器用シール材およびチューブ容器 | |
WO2024048347A1 (ja) | 積層体、包装袋、及び積層体の製造方法 | |
WO2022196211A1 (ja) | 包装材、包装袋及び包装体 | |
JP2006321495A (ja) | 液体紙容器 | |
US20150190842A1 (en) | Method and Device for Printing Films | |
JP6473681B2 (ja) | ラミネートシュリンクフィルムの製造方法 | |
JP4426171B2 (ja) | 熱圧着ラミネートフィルムの製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 14792311 Country of ref document: EP Kind code of ref document: A1 |
|
DPE2 | Request for preliminary examination filed before expiration of 19th month from priority date (pct application filed from 20040101) | ||
ENP | Entry into the national phase |
Ref document number: 2015514867 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: IDP00201507006 Country of ref document: ID |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 14792311 Country of ref document: EP Kind code of ref document: A1 |