WO2014171291A1 - 燃料電池システム及び燃料電池システムの制御方法 - Google Patents
燃料電池システム及び燃料電池システムの制御方法 Download PDFInfo
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04268—Heating of fuel cells during the start-up of the fuel cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M16/00—Structural combinations of different types of electrochemical generators
- H01M16/003—Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers
- H01M16/006—Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers of fuel cells with rechargeable batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04537—Electric variables
- H01M8/04544—Voltage
- H01M8/04559—Voltage of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04537—Electric variables
- H01M8/04574—Current
- H01M8/04589—Current of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04865—Voltage
- H01M8/0488—Voltage of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04895—Current
- H01M8/0491—Current of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04925—Power, energy, capacity or load
- H01M8/0494—Power, energy, capacity or load of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04925—Power, energy, capacity or load
- H01M8/04947—Power, energy, capacity or load of auxiliary devices, e.g. batteries, capacitors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells
Definitions
- the present invention relates to a fuel cell system and a control method for the fuel cell system.
- JP2000-357526A discloses a conventional fuel cell system that estimates a current-voltage characteristic of a fuel cell based on an output voltage detected while changing the output current of the fuel cell.
- the fuel cell After starting the fuel cell system, the fuel cell is warmed up by driving the auxiliary machine with the power generated by the fuel cell, and the vehicle is allowed to run after the IV characteristic of the fuel cell reaches the desired IV characteristic. ing. Therefore, the IV characteristic is estimated from the time when the fuel cell is warmed up, and when the estimated IV characteristic becomes a desired IV characteristic, the vehicle is allowed to run as quickly as possible so that the vehicle can be run as early as possible. I'm considering doing that.
- the present invention has been made paying attention to such a problem, and an object thereof is to ensure the estimation accuracy of IV characteristics while suppressing the occurrence of voltage drop.
- a fuel cell system that generates power by supplying an anode gas and a cathode gas to a fuel cell.
- the fuel cell system includes an auxiliary machine connected to the fuel cell, and a warm-up power control means for controlling the power generated by the fuel cell by adjusting the power supplied to the auxiliary machine when the fuel cell is warmed up, IV characteristic estimation means for temporarily reducing the power supplied to the auxiliary machine during the warm-up of the fuel cell and estimating the IV characteristic of the fuel cell based on at least two sets of current values and voltage values at that time Prepare.
- FIG. 1 is a schematic diagram of a fuel cell system according to an embodiment of the present invention.
- FIG. 2 is a diagram illustrating the relationship between the temperature of the fuel cell stack and the current-voltage characteristics of the fuel cell stack.
- FIG. 3 is a diagram illustrating a method for estimating the IV characteristic of the fuel cell stack at the time of starting the fuel cell system.
- FIG. 4 is a diagram for explaining the reason for acquiring data while reducing the output current.
- FIG. 5 is a control block diagram for setting a target output current according to an embodiment of the present invention.
- FIG. 6 is a time chart showing the operation of the output current and generated power controlled by the control block diagram of FIG.
- FIG. 7 is a flowchart illustrating IV characteristic estimation control according to an embodiment of the present invention.
- FIG. 8 is a flowchart for explaining the transient IV characteristic estimation processing.
- FIG. 9 is a flowchart for explaining steady-state IV characteristic estimation processing.
- an electrolyte membrane is sandwiched between an anode electrode (fuel electrode) and a cathode electrode (oxidant electrode), an anode gas containing hydrogen in the anode electrode (fuel gas), and a cathode gas containing oxygen in the cathode electrode (oxidant) Electricity is generated by supplying gas.
- the electrode reaction that proceeds in both the anode electrode and the cathode electrode is as follows.
- Anode electrode 2H 2 ⁇ 4H + + 4e ⁇ (1)
- Cathode electrode 4H + + 4e ⁇ + O 2 ⁇ 2H 2 O (2)
- the fuel cell generates an electromotive force of about 1 volt by the electrode reactions (1) and (2).
- a fuel cell When a fuel cell is used as a power source for automobiles, it requires a large amount of power, so it is used as a fuel cell stack in which several hundred fuel cells are stacked. Then, a fuel cell system that supplies anode gas and cathode gas to the fuel cell stack is configured, and electric power for driving the vehicle is taken out.
- FIG. 1 is a schematic diagram of a fuel cell system 100 according to an embodiment of the present invention.
- the fuel cell system 100 includes a fuel cell stack 1, a cathode gas supply / discharge device 2, an anode gas supply / discharge device 3, a power system 4, and a controller 5.
- the fuel cell stack 1 is formed by stacking several hundred fuel cells, and receives the supply of anode gas and cathode gas to generate electric power necessary for driving the vehicle.
- the fuel cell stack 1 includes an anode electrode side output terminal 11 and a cathode electrode side output terminal 12 as terminals for taking out electric power.
- the cathode gas supply / discharge device 2 is a device that supplies cathode gas to the fuel cell stack 1 and discharges cathode off-gas discharged from the fuel cell stack 1 to the outside air.
- the cathode gas supply / discharge device 2 includes a cathode gas supply passage 21, a filter 22, a cathode compressor 23, a cathode gas discharge passage 24, and a cathode pressure regulating valve 25.
- the cathode gas supply passage 21 is a passage through which the cathode gas supplied to the fuel cell stack 1 flows.
- the cathode gas supply passage 21 has one end connected to the filter 22 and the other end connected to the cathode gas inlet hole of the fuel cell stack 1.
- the filter 22 removes foreign matters in the cathode gas taken into the cathode gas supply passage 21.
- the cathode compressor 23 is provided in the cathode gas supply passage 21.
- the cathode compressor 23 takes in air (outside air) as cathode gas through the filter 22 into the cathode gas supply passage 21 and supplies it to the fuel cell stack 1.
- the cathode gas discharge passage 24 is a passage through which the cathode off gas discharged from the fuel cell stack 1 flows. One end of the cathode gas discharge passage 24 is connected to the cathode gas outlet hole of the fuel cell stack 1, and the other end is an open end.
- the cathode pressure regulating valve 25 is provided in the cathode gas discharge passage 22.
- the opening of the cathode pressure regulating valve 25 is controlled to an arbitrary opening by the controller 5 and adjusts the pressure of the cathode gas supplied to the fuel cell stack 1 to a desired pressure.
- the anode gas supply / discharge device 3 is a device that supplies anode gas to the fuel cell stack 1 and discharges anode off-gas discharged from the fuel cell stack 1 to the cathode gas discharge passage 24.
- the anode gas supply / discharge device 3 includes a high-pressure tank 31, an anode gas supply passage 32, a pressure regulating valve 33, an anode gas discharge passage 34, and a purge valve 35.
- the high pressure tank 31 stores the anode gas supplied to the fuel cell stack 1 in a high pressure state.
- the anode gas supply passage 32 is a passage for supplying the anode gas discharged from the high-pressure tank 31 to the fuel cell stack 1.
- the anode gas supply passage 32 has one end connected to the high pressure tank 31 and the other end connected to the anode gas inlet hole of the fuel cell stack 1.
- the pressure regulating valve 33 is provided in the anode gas supply passage 32.
- the pressure regulating valve 33 is controlled to be opened and closed by the controller 5 and adjusts the pressure of the anode gas flowing out from the high-pressure tank 31 to the anode gas supply passage 32 to a desired pressure.
- the anode gas discharge passage 34 is a passage through which the anode off gas discharged from the fuel cell stack 1 flows.
- the anode gas discharge passage 34 has one end connected to the anode gas outlet hole of the fuel cell stack 1 and the other end connected to the cathode gas discharge passage 24.
- the purge valve 35 is provided in the anode gas discharge passage 34.
- the purge valve 35 is controlled to be opened and closed by the controller 5 and controls the flow rate of the anode off gas discharged from the anode gas discharge passage 34 to the cathode gas discharge passage 24.
- the power system 4 includes a current sensor 41, a voltage sensor 42, a travel motor 43, an inverter 44, a battery 45, and a DC / DC converter 46.
- the current sensor 41 detects a current (hereinafter referred to as “output current”) taken from the fuel cell stack 1.
- the voltage sensor 42 detects an inter-terminal voltage (hereinafter referred to as “output voltage”) between the anode electrode side output terminal 11 and the cathode electrode side output terminal 12.
- the traveling motor 43 is a three-phase AC synchronous motor in which a permanent magnet is embedded in a rotor and a stator coil is wound around a stator.
- the travel motor 43 functions as an electric motor that is driven to rotate by receiving electric power supplied from the fuel cell stack 1 and the battery 45, and power generation that generates electromotive force at both ends of the stator coil during deceleration of the vehicle in which the rotor is rotated by external force. Function as a machine.
- the inverter 44 is composed of a plurality of semiconductor switches such as IGBTs (Insulated Gate Bipolar Transistors).
- the semiconductor switch of the inverter 44 is controlled to be opened / closed by the controller 5, whereby DC power is converted into AC power or AC power is converted into DC power.
- the traveling motor 43 functions as an electric motor
- the inverter 44 converts the combined DC power of the power generated by the fuel cell stack 1 and the output power of the battery 45 into three-phase AC power and supplies it to the traveling motor 43.
- the traveling motor 43 functions as a generator, the regenerative power (three-phase alternating current power) of the traveling motor 43 is converted into direct current power and supplied to the battery 45.
- the battery 45 charges the surplus power generated by the fuel cell stack 1 (output current ⁇ output voltage) and the regenerative power of the traveling motor 43.
- the electric power charged in the battery 45 is supplied to auxiliary machines such as the cathode compressor 23 and the traveling motor 43 as necessary.
- the DC / DC converter 46 is a bidirectional voltage converter that raises and lowers the output voltage of the fuel cell stack 1. By controlling the output voltage of the fuel cell stack 1 by the DC / DC converter 46, the output current of the fuel cell stack 1, and thus the generated power, is controlled.
- the controller 5 includes a microcomputer having a central processing unit (CPU), a read only memory (ROM), a random access memory (RAM), and an input / output interface (I / O interface).
- the controller 5 detects an accelerator stroke sensor 51 that detects the amount of depression of the accelerator pedal (hereinafter referred to as “accelerator operation amount”) and the charge amount of the battery 45. Signals from various sensors necessary for controlling the fuel cell system 100 such as the battery temperature sensor 53 are input.
- FIG. 2 is a diagram showing the relationship between the temperature of the fuel cell stack 1 and the current-voltage characteristics of the fuel cell stack 1 (hereinafter referred to as “IV characteristics”).
- IV characteristics the IV characteristic indicated by a solid line is the IV characteristic after the warm-up of the fuel cell stack 1 is completed (hereinafter referred to as “reference IV characteristic”).
- the IV characteristics of the fuel cell stack 1 change according to the temperature of the fuel cell stack 1, and the lower the temperature of the fuel cell stack 1, the more the output current with the same current value is taken out from the fuel cell. When the output voltage is low. That is, the power generation efficiency of the fuel cell stack 1 decreases as the temperature of the fuel cell stack 1 decreases.
- the fuel cell stack is increased when the required power of the travel motor 43 increases and the output current of the fuel cell stack 1 increases.
- the output voltage of 1 may be lower than the minimum voltage.
- the minimum voltage is a voltage value set in advance by experiments or the like, and is a voltage value at which the traveling motor 43 cannot be driven when the output voltage of the fuel cell stack 1 falls below the minimum voltage.
- the travel permission current is a value obtained by adding a predetermined margin to the minimum value of the output current assumed when the travel motor 43 is driven to start or travel the vehicle, and is set in advance through experiments or the like. It is.
- the electric parts that can be energized during warm-up without travel permission are limited to auxiliary equipment such as the cathode compressor 23 other than the travel motor 43 and a heater that heats the cooling water for cooling the fuel cell stack 1 and the battery 45. . That is, at the time of warm-up when the travel permission is not issued, it is not possible to take out from the fuel cell stack 1 an output current that is greater than or equal to the current that can flow to the auxiliary equipment and the battery 45.
- the maximum value of the output current at the time of warm-up when the travel permission is not issued (hereinafter referred to as “maximum current before travel permission”) is the current that can be supplied to the accessory (hereinafter referred to as “auxiliary consumption current”) Although the current that can be passed through the battery 45 (hereinafter referred to as “charging current”) is added, the maximum current before travel permission is smaller than the travel permission current.
- the IV characteristics of the fuel cell stack 1 are estimated while the fuel cell stack 1 is warmed up.
- the output voltage of the battery stack 1 has an IV characteristic that does not fall below the minimum voltage, the vehicle is allowed to run.
- FIG. 3 is a diagram for explaining a method for estimating the IV characteristics of the fuel cell stack 1 when the fuel cell system 100 is started.
- the solid line indicates the reference IV characteristic.
- a broken line indicates an actual IV characteristic (hereinafter referred to as an “actual IV characteristic”) at a certain point during warm-up when the travel permission is not issued.
- the output current is fluctuated within a certain amount or more from the IV estimated lower limit current to the maximum current before travel permission (hereinafter referred to as “data acquisition region”), Reference voltage and actual output voltage data corresponding to at least two output current values are acquired, and the slope A and intercept B of equation (3) are calculated by the successive least square method.
- FIG. 4 is a diagram for explaining the reason for acquiring data while lowering the output current.
- FIG. 4A shows the transition of the actual IV characteristics of the fuel cell stack 1 when the fuel cell system 100 is started up, the IV characteristics estimated based on the data acquired while increasing the output current, and the output. It is a figure which shows IV characteristic (broken line) estimated based on the data acquired, reducing an electric current.
- FIG. 4B is a diagram illustrating a voltage difference between the reference IV characteristic, the actual IV characteristic, and the estimated IV characteristic in accordance with the output current.
- the IV characteristic gradually recovers toward the reference IV characteristic even while the output current is fluctuated by a certain amount or more and the data is acquired. Therefore, as shown in FIG. 4A, when the actual IV characteristic at the start of data acquisition is compared with the actual IV characteristic at the end of data acquisition, the IV characteristic at the end of data acquisition is more at the start of data acquisition. The IV characteristics are better than the IV characteristics.
- the IV characteristic estimated based on the data acquired while increasing the output current in the data acquisition region is better than the actual IV characteristic at the end of data acquisition. Become. If travel permission is issued based on an IV characteristic that is better than the actual IV characteristic, when the output current increases due to vehicle travel, the output voltage falls below the minimum voltage required to drive the vehicle travel motor. There is a fear.
- the slope A and the expression A in the expression (3) are based on the data acquired at an arbitrary output current value.
- the intercept B is calculated, the calculated slope A is larger than the slope of a linear function of the voltage difference ⁇ V between the reference voltage and the voltage on the actual IV characteristic at the end of data acquisition.
- the IV characteristic estimated based on the data acquired while reducing the output current in the data acquisition region is worse than the actual IV characteristic at the end of data acquisition. It becomes. If the travel permission is issued based on an IV characteristic that is worse than the actual IV characteristic, even if the output current increases due to vehicle travel, the output voltage is not likely to fall below the minimum voltage.
- the change rate of the output current can be made faster than when the output current is increased. Therefore, since the change of the IV characteristic during acquisition of the data necessary for the IV characteristic is small, the estimation accuracy of the IV characteristic can be ensured.
- the IV characteristics are estimated based on the data acquired while reducing the output current.
- FIG. 5 is a control block diagram for setting the target output current according to the present embodiment.
- the target auxiliary machine power consumption calculation unit 61 calculates a target value of power consumed by each auxiliary machine such as the cathode compressor 23 (hereinafter referred to as “target auxiliary machine power consumption”). During warm-up when travel permission is not issued, the target auxiliary machine power consumption is set to a predetermined warm-up target power consumption. In this embodiment, the target power consumption during warm-up is set to the power when the power consumption of each auxiliary machine is maximized.
- the target auxiliary power generation power calculation unit 62 receives target auxiliary machine power consumption and target travel motor supply power.
- the reached target generated power calculation unit 62 calculates the sum of the target auxiliary machine power consumption and the target travel motor supply power as the reached target generated power.
- the target travel motor supply power increases as the accelerator operation amount increases, and becomes zero during warm-up when the travel permission is not issued regardless of the accelerator operation amount.
- the basic target output current calculation unit 63 is input with the target generated power and the actual generated power (actual output current ⁇ actual output voltage).
- the basic target output current calculation unit 63 calculates the target value of the generated power when changing the actual generated power toward the reached target generated power based on the deviation between the reached target generated power and the actual generated power. Calculate as Further, the target value of the output current required to make the generated power the basic target generated power is calculated as the basic target output current.
- Battery charge amount and battery temperature are input to the chargeable / dischargeable power calculation unit 64.
- the chargeable / dischargeable power calculation unit 64 is based on the battery charge amount and the battery temperature, and can be charged to the battery 45 (hereinafter “chargeable power”) and can be taken out from the battery 45 (hereinafter referred to as “dischargeable power”). .) Is calculated.
- the basic target generated power, chargeable power, and dischargeable power are input to the IV estimation target current calculation unit 65. Based on these input values, the IV estimation target current calculation unit 65 calculates the target value of the output current when estimating the IV characteristics (hereinafter referred to as “IV estimation target current”), and performs the IV estimation. Outputs a flag ON / OFF signal. When the fuel cell system is started, the IV estimation execution flag is set to OFF. The detailed contents of the IV estimation target current calculation unit 65 will be described later with reference to FIGS.
- the target output current calculation unit 66 receives an IV estimation target current and a basic target output current. If the IV estimation execution flag is ON, the target output current calculation unit 66 calculates the IV estimation target output current as the target output current. On the other hand, if the IV estimation execution flag is OFF, the basic target output current is calculated as the target output current.
- FIG. 6 is a time chart showing the operation of the output current and generated power controlled by the control block diagram of FIG.
- the broken line A indicates the basic target generated power.
- a broken line B indicates power obtained by adding chargeable power to basic target generated power (hereinafter referred to as “upper limit generated power”).
- a broken line C indicates power obtained by subtracting dischargeable power from basic target generated power (hereinafter referred to as “lower limit generated power”).
- the alternate long and short dash line D is the target generated power at the time of warming up, ie, the target power consumption at the time of warming up, for which driving permission is not issued after the fuel cell system is activated.
- An alternate long and short dash line E is the power obtained by adding the chargeable power to the target target generated power, and the upper limit generated power after the auxiliary machine power consumption has increased to the target target generated power (hereinafter referred to as “steady-state upper limit generated power”). It is.
- the alternate long and short dash line F is the power obtained by subtracting the dischargeable power from the target target generated power, and the lower limit generated power after the auxiliary machine power consumption has increased to the target target generated power (hereinafter referred to as “the lower limit generated power during normal operation”). It is.
- a broken line A indicates a basic target output current.
- a broken line B indicates an output current (hereinafter, referred to as “upper limit output current”) I c1 required for setting the generated power to the upper limit generated power.
- a broken line C indicates an output current (hereinafter, referred to as “lower limit output current”) I c2 required for setting the generated power to the lower limit generated power.
- the output current can be varied between the lower limit output current I c2 and the upper limit output current I c1 .
- alternate long and short dash line D is the output current required to make the generated power the upper limit generated power during normal operation, that is, the maximum current before permission to travel.
- An alternate long and short dash line E is an output current (hereinafter referred to as “steady-state lower limit current”) It1 required to set the generated power to the lower-limit steady-state generated power.
- a one-dot chain line F is the IV estimation lower limit current I c3 .
- the target power consumption during warm-up is set as the target output output power, and the target value for setting the generated power to the target power consumption during warm-up. Is set as the basic target generated power.
- the basic target output current is set as the target output current, and the output current is the basic as shown in FIG. Control is performed to achieve the target output current.
- the output current of the fuel cell stack 1 reaches the steady-state lower limit current I t1 , and at time t1, the difference between the upper limit output current I c1 and the steady-state lower limit current I t1 is predetermined when the IV characteristic is estimated. becomes equal to or larger than a predetermined current swing width [Delta] I t required to ensure accuracy, IV estimation execution flag is set to oN. Then, an upper limit output current at time t1 (hereinafter referred to as “target current at load increase”) It2 is set as the IV estimation target current.
- target current at load increase an upper limit output current at time t1 (hereinafter referred to as “target current at load increase”) It2 is set as the IV estimation target current.
- the IV estimation target current is set as the target output current, and as shown in FIG. 6A , the output current is controlled to become the target current I t2 at the time of increasing the load.
- the steady-state limit current I t1 is set to the target current for IV estimation, and the output current to the steady state limit current I t1 at a predetermined change rate change
- the steady-state limit current I t1 acquires a plurality of data of the reference voltage and the actual output voltage corresponding to any output current value.
- the IV characteristic is estimated based on the acquired parameter. Then, the IV estimation execution flag is set to OFF, and control is performed again so that the output current becomes the basic target output current.
- FIG. 7 is a flowchart illustrating IV characteristic estimation control according to this embodiment.
- step S1 the controller 5 calculates a steady-state lower limit current It1 .
- the steady-state lower limit generated power is calculated by subtracting the dischargeable power from the target target generated power at the time of warm-up when travel permission is not issued (target power consumption at the time of warm-up). Then, the output current required for making the generated power the lower limit generated power at the steady state is calculated as the lower limit current I t1 at the steady state.
- step S2 whether the controller 5, the difference between the upper limit output current I c1 and steady-state lower current I t1 has become the current swing width ⁇ It than necessary to ensure a predetermined accuracy when estimating the IV characteristics Determine whether or not.
- step S3 the controller 5 performs a transient IV characteristic estimation process.
- the transient IV characteristic estimation process is a first IV characteristic estimation process that is performed after the fuel cell system 100 is started, and is performed during a transient period before the auxiliary machine power consumption reaches the warm-up target power consumption. This is an IV characteristic estimation process. Details of the transient IV characteristic estimation processing will be described later with reference to FIG.
- step S4 the controller 5 determines whether or not the IV characteristic is estimated in the transient IV characteristic estimation process.
- the controller 5 performs the process of step S5 if the IV characteristics are estimated, and otherwise performs the process of step S8.
- step S5 the controller 5 determines whether or not the output voltage when the travel permission current is extracted from the fuel cell stack 1 is lower than the minimum voltage, based on the IV characteristics estimated in the transient IV characteristics estimation process. If the output voltage when the travel permission current is taken out from the fuel cell stack 1 is not lower than the minimum voltage, the controller 5 performs the process of step S6. On the other hand, if the output voltage when the travel permission current is taken out from the fuel cell stack 1 is lower than the minimum voltage, the process of step S7 is performed.
- step S6 the controller 5 issues a vehicle travel permission.
- step S7 the controller 5 sets the interval period t int from the execution of the transient IV characteristic estimation process to the execution of the steady-state IV characteristic estimation process described later to zero.
- step S8 the controller 5 performs a steady-state IV characteristic estimation process.
- the steady-state IV characteristic estimation process is a second or subsequent IV characteristic estimation process performed after the transient IV characteristic estimation process is performed, and basically the auxiliary machine power consumption has reached the warm-up target power consumption. This is an IV characteristic estimation process performed at a later time. Details of the constant IV characteristic estimation process will be described later with reference to FIG.
- step S9 the controller 5 determines whether or not the output voltage when the travel permission current is taken out from the fuel cell stack 1 is lower than the minimum voltage, based on the IV characteristics estimated by the steady-state IV characteristics estimation process. If the output voltage when the travel permission current is taken out from the fuel cell stack 1 is not lower than the minimum voltage, the controller 5 performs the process of step S6. On the other hand, if the output voltage when the travel permission current is taken out from the fuel cell stack 1 is lower than the minimum voltage, the process of step S10 is performed.
- step S10 the controller 5 sets the interval period t int to the variable value t m1 .
- the variable value t m1 is set so that the IV characteristic estimated by the steady-state IV characteristic estimation process is shorter as the IV characteristic is closer to the reference IV characteristic, that is, the IV characteristic is recovered.
- FIG. 8 is a flowchart for explaining the IV characteristic estimation process during transition.
- step S31 the controller 5 sets the IV estimation execution flag to ON.
- step S32 the controller 5 determines the upper limit output current when the difference between the upper limit output current I c1 and the lower limit current limit current I t1 is equal to or greater than a predetermined current swing width ⁇ It (hereinafter referred to as “target current during load increase”). .) and I t2, the current maximum output current I c1, smaller the ones of sets as the target current for IV estimation.
- the target current I t2 at the time of load increase is basically set as the target current for IV estimation. Of the target current I t2 at the time of load increase and the current upper limit output current I c1 , The smaller one is set as the IV estimation target current for the following reason.
- step S33 the controller 5 determines whether or not a predetermined time has elapsed after the output current reaches the IV estimation target current set in step S32. If the predetermined time has not elapsed since the output current reached the IV estimation target current, the controller 5 performs the process of step S34, and if it has elapsed, performs the process of step S37.
- step S34 the controller 5 performs a voltage drop determination. Specifically, it is determined whether or not the output voltage is less than a predetermined voltage drop determination value when the output current is held at the IV estimation target current. If the output voltage is less than the predetermined voltage drop determination value, the controller 5 performs the process of step S35 to stop the transient IV characteristic estimation process. On the other hand, if the output voltage is equal to or higher than the predetermined voltage drop determination value, the process returns to step S32.
- step S35 the controller 5 sets the IV estimation execution flag to OFF and stops the transient IV characteristic estimation processing. Then, the basic target output current is set as the target output current, and the output current is controlled to the basic target output current.
- step S36 the controller 5 sets the interval period t int to a predetermined fixed value t m2 .
- the fixed value t m2 is a value larger than the variable value t m1 described above.
- the value obtained by subtracting the current swing width [Delta] I t from the current output current I r is, if less than the lower limit output current I c2 and IV estimated lower limit current I c3, in step S43 in order to stop the transient IV characteristic estimation process Process
- step S38 the controller 5, a value obtained by subtracting the current swing width [Delta] I t from the current output current I r, the lower limit output current I c2, the larger of the sets as a target current for IV estimation, output The current is decreased toward the target current for IV estimation at a predetermined change rate.
- step S39 the controller 5 acquires data on the reference voltage and the actual output voltage while reducing the output current.
- step S40 the controller 5 determines whether or not the output current has decreased to the target current for IV estimation set in step S38. If the output current has decreased to the IV estimation target current, the controller 5 performs the process of step S41, and otherwise returns to the process of step S39 to acquire the above three parameters.
- step S41 the controller 5 ends the acquisition of the reference voltage and actual output voltage data, and estimates the IV characteristics based on the acquired data.
- step S42 the controller 5 sets the IV estimation execution flag to OFF, sets the basic target output current as the target output current, and controls the output current to the basic target output current.
- step S43 the controller 5 sets the IV estimation execution flag to OFF and stops the transient IV characteristic estimation processing. Then, the basic target output current is set as the target output current, and the output current is controlled to the basic target output current.
- step S44 the controller 5 sets the interval period t int to zero.
- FIG. 9 is a flowchart illustrating the steady-state IV characteristic estimation process.
- step S81 the controller 5 determines whether or not the elapsed time since the interval period t int is set is longer than the set interval period t int .
- the controller 5 repeats the process until the interval period t int has elapsed, the process of step S82 if elapsed interval period t int.
- Step S82 the controller 5 determines whether or not the difference between the upper limit output current I c1 and the larger of the lower limit output current I c2 and the IV estimated lower limit current I c3 is equal to or greater than the current swing width ⁇ It.
- the controller 5 performs an upper limit output current I c1, and the larger the lower limit output current I c2 and IV estimated lower limit current I c3, difference processing of step S83 if the current swing width [Delta] I t or more, otherwise In this case, this process is continued until the current swing width ⁇ It becomes equal to or greater than.
- step S83 the controller 5 sets the IV estimation execution flag to ON.
- step S84 the controller 5 determines the upper limit output current I c1 when the difference between the upper limit output current I c1 and the larger of the lower limit output current I c2 and the IV estimated lower limit current I c3 is equal to or greater than the current swing width ⁇ It.
- the smaller of c1 and the current upper limit output current Ic1 is set as a target current for IV estimation at the time of increasing the load.
- step S85 the controller 5 determines whether or not a predetermined time has elapsed after the output current reaches the target current for IV estimation at the time of load increase set in step S84.
- the controller 5 performs the process of step S86 if the predetermined time has not elapsed since the output current reached the target current for IV estimation at the time of increasing the load, and performs the process of step S89 if it has elapsed.
- step S86 the controller 5 performs a voltage drop determination. Specifically, it is determined whether or not the output voltage is less than a predetermined voltage drop determination value when the output current is held at the target current for IV estimation at the time of increasing the load. If the output voltage is less than the predetermined voltage drop determination value, the controller 5 performs the process of step S87 to perform the steady-state IV characteristic estimation process again after a predetermined interval period has elapsed. On the other hand, if the output voltage is equal to or higher than the predetermined voltage drop determination value, the process returns to step S84.
- step S87 the controller 5 sets the IV estimation execution flag to OFF, sets the basic target output current as the target output current, and controls the output current to the basic target output current.
- step S88 the controller 5 sets the interval period t int to a predetermined fixed value t m2 , and then returns to step S81 and starts the IV characteristic estimation process again after the set interval period elapses.
- step S89 the controller 5, the value obtained by subtracting the current swing width [Delta] I t from the current output current I r is determined whether the lower limit output current I c2 and IV estimated lower-limit current I c3 above. Controller 5, minus the current output current I r a predetermined current swing width [Delta] I t is, performs the processing of step S90, if the lower limit output current I c2 and IV estimated lower-limit current I c3 above. Meanwhile, the value from the current output current I r minus the predetermined current swing width [Delta] I t is, if less than the lower limit output current I c2 and IV estimated lower limit current I c3, the process of step S95.
- step S90 the controller 5 compares the value obtained by subtracting the current swing width [Delta] I t from the current output current I r, the lower limit output current I c2, the larger of, as the target current for IV estimation during load lowering It is set and the output current is decreased at a predetermined rate of change toward the target current for IV estimation at the time of load reduction.
- step S91 the controller 5 acquires data on the reference voltage and the actual output voltage while reducing the output current.
- step S92 the controller 5 determines whether or not the output current has decreased to the target current for IV estimation at the time of load reduction set in step S89. If the output current has decreased to the target current for IV estimation at the time of load reduction, the controller 5 performs the process of step S93, and otherwise returns to the process of step 91 to acquire data.
- step S93 the controller 5 ends the acquisition of the reference voltage and actual output voltage data and estimates the IV characteristics.
- step S94 the controller 5 sets the IV estimation execution flag to OFF, sets the basic target output current as the target output current, and controls the output current to the basic target output current.
- step S95 the controller 5 sets the IV estimation execution flag to OFF. Then, the basic target output current is set as the target output current to control the output current to the basic target output current, and the process returns to step S82 to start the IV characteristic estimation process again.
- the output current of the fuel cell stack 1 is reduced based on the data (reference voltage and actual output voltage) acquired at an arbitrary output current value while reducing the output current of the fuel cell stack 1.
- the IV characteristics were estimated.
- the IV characteristic estimated based on the data acquired while reducing the output current of the fuel cell stack 1 is an IV characteristic that is worse than the actual IV characteristic at the end of data acquisition.
- the target value of the generated power is basically set to the target power consumption during warm-up, and the power consumption of each auxiliary machine such as the cathode compressor 21 is set.
- the fuel cell stack 1 is caused to generate electric power in a state in which self-heating is actively used, thereby promoting warm-up.
- the generated power is made larger than the target power consumption during warm-up to increase the output current. Later, the output current was reduced, and the IV characteristics of the fuel cell stack 1 were estimated based on data acquired when the output current was reduced.
- the power generated by the fuel cell stack 1 is supplied to the battery 45 to increase the output current, and then the output current is reduced.
- the IV characteristic can be estimated while suppressing the deterioration of the warm-up performance.
- the IV characteristic is estimated from the transition time before the auxiliary machine power consumption reaches the warm-up target power consumption.
- the IV characteristic can be estimated earlier than when the IV characteristic is estimated after the auxiliary power consumption reaches the target power consumption during warm-up.
- the lower limit output current also increases with the increase in auxiliary machine power consumption while the output current is reduced. since rises, there is a possibility that the accuracy of the IV characteristic is lowered can not be secured predetermined current swing width [Delta] I t.
- the lower limit current I t1 during steady state that is, the minimum value of the output current that can be taken in steady state after the auxiliary machine power consumption reaches the target power consumption during warm-up is calculated.
- the lower limit current I t1 when secured a predetermined current swing width [Delta] I t as a reference intends to perform IV estimation.
- the constant lower limit current I t1 can be rephrased as the maximum value of the lower limit output current during the transition.
- the accuracy of the IV characteristics can be ensured even during a transition. Therefore, when the IV characteristic is suddenly recovered during warm-up, the vehicle travel permission can be issued quickly.
- the upper limit output current I c1 and the steady-state lower limit current It1 are calculated according to the state of the battery such as the battery charge amount, so that overcharge and overdischarge of the battery 45 can be prevented.
- the battery 45 can be prevented from deteriorating.
- the IV estimation was started by controlling the output current to the target current I t2 at the time of increasing the load, but if it is determined that the output current has reached the steady-state lower limit current I t1 , the output current is increased. IV estimation may be started. Also by this, the same effect as the above embodiment can be obtained.
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Abstract
Description
本発明は燃料電池システム及び燃料電池システムの制御方法に関する。
カソード電極 : 4H+ +4e- +O2 →2H2O …(2)
ΔV=A×I+B …(3)
Claims (5)
- アノードガス及びカソードガスを燃料電池に供給して発電させる燃料電池システムであって、
前記燃料電池に接続される補機と、
前記燃料電池の暖機時に、前記補機への供給電力を調整して前記燃料電池の発電電力を制御する暖機時電力制御手段と、
前記燃料電池の暖機中に、前記補機への供給電力を一時的に小さくして、その時の少なくとも2組の電流値と電圧値に基づいて、前記燃料電池のIV特性を推定するIV特性推定手段と、
を備える燃料電池システム。 - 前記補機は、
前記燃料電池の余剰電力を貯えるバッテリ、及び、前記燃料電池の発電時に駆動される電気部品であり、
前記IV特性推定手段は、
前記暖機時電力制御手段によって前記電気部品の消費電力を調整して前記燃料電池の出力電流が所定の暖機時目標出力電流となるように前記燃料電池の発電電力を制御している暖機中に、前記バッテリへの電力供給によって前記燃料電池の出力電流を上げた後に出力電流を低下させ、出力電流を低下させている時の少なくとも2組の電流値と電圧値に基づいて、前記燃料電池のIV特性を推定する、
請求項1に記載の燃料電池システム。 - 前記IV特性推定手段は、
前記燃料電池の出力電流を前記暖機時目標出力電流に向けて徐々に上昇させている過渡時において、前記燃料電池の出力電流に前記バッテリの充電可能電流を加えた上限出力電流と、前記暖機時目標出力電流から前記バッテリの放電可能電流を引いた定常時下限出力電流と、の差が所定値以上となったときに、前記バッテリへの電力供給を開始して前記燃料電池の出力電流を上げる、
請求項2に記載の燃料電池システム。 - 前記IV特性推定手段は、
前記燃料電池の出力電流を前記暖機時目標出力電流に向けて徐々に上昇させている過渡時において、前記燃料電池の出力電流が、前記暖機時目標出力電流から前記バッテリの放電可能電流を引いた定常時下限出力電流以上となったときに、前記バッテリへの電力供給を開始して前記燃料電池の出力電流を上げる、
請求項2に記載の燃料電池システム。 - アノードガス及びカソードガスを燃料電池に供給して発電させ、前記燃料電池に接続される補機を備える燃料電池システムの制御方法であって、
前記燃料電池の暖機時に、前記補機への供給電力を調整して前記燃料電池の発電電力を制御する暖機時電力制御工程と、
前記燃料電池の暖機中に、前記補機への供給電力を一時的に小さくして、その時の少なくとも2組の電流値と電圧値に基づいて、前記燃料電池のIV特性を推定するIV特性推定工程と、
を備える燃料電池システムの制御方法。
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US14/784,767 US9812722B2 (en) | 2013-04-16 | 2014-03-27 | Fuel cell system and control method for fuel cell system |
CA2909284A CA2909284C (en) | 2013-04-16 | 2014-03-27 | Fuel cell system with estimate of current/voltage characteristics during warm-up |
EP14784799.0A EP2988353B1 (en) | 2013-04-16 | 2014-03-27 | Fuel-cell system and method for controlling fuel-cell system |
CN201480021920.XA CN105144451B (zh) | 2013-04-16 | 2014-03-27 | 燃料电池系统和燃料电池系统的控制方法 |
JP2015512387A JP5971408B2 (ja) | 2013-04-16 | 2014-03-27 | 燃料電池システム及び燃料電池システムの制御方法 |
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CN106374123B (zh) * | 2015-07-23 | 2019-05-10 | 丰田自动车株式会社 | 燃料电池系统 |
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JPWO2014171291A1 (ja) | 2017-02-23 |
CN105144451B (zh) | 2017-07-18 |
US9812722B2 (en) | 2017-11-07 |
EP2988353A1 (en) | 2016-02-24 |
CA2909284A1 (en) | 2014-10-23 |
EP2988353A4 (en) | 2016-03-16 |
US20160064754A1 (en) | 2016-03-03 |
CA2909284C (en) | 2018-05-01 |
EP2988353B1 (en) | 2018-03-14 |
CN105144451A (zh) | 2015-12-09 |
JP5971408B2 (ja) | 2016-08-17 |
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