WO2014168175A1 - はんだ回路基板の製造方法、はんだ回路基板及び電子部品の実装方法 - Google Patents
はんだ回路基板の製造方法、はんだ回路基板及び電子部品の実装方法 Download PDFInfo
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- WO2014168175A1 WO2014168175A1 PCT/JP2014/060279 JP2014060279W WO2014168175A1 WO 2014168175 A1 WO2014168175 A1 WO 2014168175A1 JP 2014060279 W JP2014060279 W JP 2014060279W WO 2014168175 A1 WO2014168175 A1 WO 2014168175A1
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- solder
- resist
- circuit board
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- manufacturing
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Definitions
- the present invention relates to a solder circuit board manufacturing method, a solder circuit board, and an electronic component mounting method.
- This circuit pattern is formed on a plastic substrate, a ceramic substrate, or an insulating substrate coated with plastic or the like.
- the following method is known as a method of joining the lead terminal of an electronic component to a predetermined part of a circuit pattern when manufacturing such an electronic circuit.
- a solder layer is previously formed on the surface of the conductive circuit electrode on the substrate, and a solder paste or flux is printed on a predetermined portion on the solder layer.
- a method is known in which an electronic component is placed on a solder layer while repositioning the lead terminal and the solder paste and reflowed to perform solder bonding.
- mounting by a flip chip bonder is also known in which a solder layer formed on a solder substrate and a gold stud bump formed on a bare chip side are heated while being superposed and pressed to melt the solder for mounting.
- FC Flip Chip
- a plating method, a hot air leveler (HAL) method, or a solder powder paste is applied to a substrate to form a circuit pattern (hereinafter referred to as a solder circuit) using a solder film.
- a method of reprinting the paste and reflowing the paste has been used.
- the plating method since it is difficult to increase the thickness of the solder layer, the bonding strength of the electronic component to the circuit pattern is weakened, and the electronic component may be peeled off the substrate.
- Patent Document 1 discloses that adhesiveness is selectively applied to the exposed portion of the metal circuit on the printed wiring board.
- a method of forming a solder circuit by forming a pressure-sensitive adhesive portion and attaching a solder powder to the pressure-sensitive adhesive portion and then heating the printed wiring board to melt the solder powder is disclosed.
- solder layer When manufacturing a solder circuit board on which the above solder circuit is formed, it is not necessary to form a solder layer on the entire metal circuit surface. In other words, the solder layer may be formed only on the portion of the metal circuit where the electronic component is joined. If the solder layer is formed on the surface of the metal circuit other than that portion, the solder alloy that is the material of the solder layer is wasted. become. Further, since the solder alloy moves to a portion where the width of the metal circuit is wide due to the influence of the surface tension at the time of melting, the thickness of the solder layer at that portion increases.
- a circuit pattern 2 made of metal is formed on the surface of the substrate 1.
- the surface of the circuit pattern 2 excluding the joint portion 3 with the electronic component is covered with a solder resist 4.
- adhesiveness is provided to the surface of the circuit pattern 2 of the junction location 3, and the adhesion part 5 is formed.
- the solder powder 6 is adhered to the adhesive portion 5.
- a solder layer 7 is formed as shown in FIG. 1 (e), and a solder circuit board 8 is manufactured.
- the solder circuit 11 formed by the solder layer 7 is pressed on the solder layer 7 while being aligned with the electrode portion 10 of the electronic component 9 while being heated with a flip chip bonder. Dissolve. Then, as shown in FIG. 1G, a mounting substrate 12 is manufactured in which the electronic component 9 is bonded to the solder circuit 13 after the solder circuit substrate 8 is melted.
- the protrusion provided on the electrode portion 10 is called a stud bump, and is provided to stabilize the bonding with the solder layer 7.
- the solder resist 4 pattern shown in FIG. It is necessary to make it. However, there is a limit to the miniaturization of the solder resist pattern that is generally used.
- a resin for fixing the electronic component 9 is usually filled between the electronic component 9 and the solder resist 4 shown in FIG. 1 (g).
- the electrode portion 10 of the electronic component 9 is reduced. Inevitably, it was difficult to get enough space.
- a fine pitch is used when a bare chip is used as an electronic component, it is necessary to form electrode portions in two or more rows due to the influence of stud bumps formed on the bare chip.
- the electrode part of the electronic component has become smaller and the distance between the electronic component and the substrate has become increasingly difficult.
- a resin that can withstand the melting temperature of the solder is used for the solder resist as well as the photolithographic technique can be applied with high accuracy.
- the melting temperature of solder usually exceeds 200 ° C., but the types of resins that can withstand such temperatures are limited, and among these limited types of resins, resins that can be used for fine patterning by photolithography technology There were few.
- the present invention relates to the following.
- a resist forming step for partially covering the surface of the conductive circuit electrode on the printed wiring board with a resist, and applying adhesive to the portion of the surface of the conductive circuit electrode that is not covered with the resist An adhesive portion forming step to be formed, a solder attaching step for attaching solder powder to the adhesive portion, a resist removing step for removing the resist, and a first heating step for melting the solder powder by heating the printed wiring board And a method of manufacturing a solder circuit board.
- a resist forming step for partially covering the surface of the conductive circuit electrode on the printed wiring board with a resist, and applying adhesive to the portion of the surface of the conductive circuit electrode not covered with the resist An adhesive part forming step to be formed, a resist removing process for removing the resist, a solder attaching step for attaching solder powder to the adhesive part, and a first heating step for heating the printed wiring board to melt the solder powder And a method of manufacturing a solder circuit board.
- solder circuit board manufacturing method (5) The solder according to any one of (1) to (4), wherein the resist is an alkali developing type, and the resist is removed using an alkaline liquid in the resist removing step. A method of manufacturing a circuit board. (6) The solder powder is Sn—Pb solder powder, the heating temperature in the first heating step is in the range of 200 ° C. to 350 ° C., and the heating temperature in the second heating step is 100 ° C. to 180 ° C. 6.
- the method for producing a solder circuit board according to any one of the above items (2) to (5), wherein (7)
- the solder powder is Sn—Ag solder powder
- the heating temperature in the first heating step is in the range of 250 ° C. to 350 ° C.
- the heating temperature in the second heating step is 100 ° C. to 180 ° C. 6.
- the conductive circuit electrode is made of a copper alloy, and in the adhesion part forming step, the copper alloy, a benzotriazole derivative, a naphthotriazole derivative, an imidazole derivative, a benzimidazole derivative, a mercaptobenzothiazole derivative.
- An electronic component mounting method comprising: an electronic component joining step.
- the resist is removed after the solder powder is attached to the adhesive portion, or the solder powder is attached to the adhesive portion after the resist is removed, and then the solder powder is melted. . Therefore, there is no resist on the substrate when the solder is melted, and there is no need to use a heat resistant resist. Therefore, the range of selection of the resist can be expanded, and for example, the resist most suitable for the fine pitch can be selected. Thereby, a solder circuit with a fine pitch can be formed. Further, since no solder resist is present in the mounting part of the electronic component, the stud bump of the electronic component can be lowered.
- FIG. 7 is a view showing a conventional method for manufacturing a solder circuit board, in which (a) to (g) are cross-sectional views.
- BRIEF DESCRIPTION OF THE DRAWINGS It is a figure which shows the manufacturing method of the solder circuit board which is 1st embodiment of this invention, Comprising: (a)-(h) is sectional drawing.
- FIG. 9 is a view showing a conventional method for manufacturing a solder circuit board, in which (a) to (c) are cross-sectional views.
- FIG. 1 is a diagram showing a method for manufacturing a solder circuit board according to an embodiment of the present invention, wherein (a) to (c) are cross-sectional views.
- a method for manufacturing a solder circuit board according to the present embodiment includes a resist forming step of partially covering a surface of a conductive circuit electrode on a printed wiring board with a resist, and a conductive circuit.
- the manufacturing method of the present embodiment includes a second heating step for increasing the adhesion of the solder powder to the adhesive portion immediately after the solder attaching step.
- the manufacturing method of the present embodiment includes an electronic component joining step for joining the electrode portion of the electronic component and the solder circuit of the solder circuit board after the first heating step.
- a wiring board or the like can be used.
- a plastic substrate, a plastic film substrate, a glass cloth substrate, a paper substrate epoxy resin substrate, a substrate in which a metal plate is laminated on a ceramic substrate, or an insulating substrate in which a metal base material is coated with plastic or ceramics can be cited. It is done.
- examples of the conductive substance include copper or a copper alloy, but the conductive substance is not limited thereto, and any substance can be used as long as it can impart tackiness with a tackifier compound described later.
- examples of such a conductive material include materials containing, for example, Ni, Sn, Ni—Al, solder alloys, etc. in addition to copper.
- the surface 25 a of the circuit pattern 25 excluding the junction 26 of the electronic component of the printed wiring board 24 is covered with a resist 27.
- the resist 27 used in the manufacturing method of the present embodiment is a resist having a property that can sufficiently protect a portion of the surface 25a of the circuit pattern 25 that is not imparted with adhesiveness in the adhesive portion forming step described later, and A resist that does not alter the tackifier compound is used.
- a resist applicable to fine patterning using a photolithography technique can be used even if it does not have heat resistance at the melting temperature of the solder powder. As a result, it is possible to form a fine pattern joint portion 26 on the substrate 24 with a fine pitch.
- a resist 27 that does not alter the tackifier compound that is reacted on the surface 25a of the circuit pattern 25. Since the tackifying compound exemplified later has alkali resistance, it is preferable to use an alkali development type material, that is, a resist made of an alkali-soluble resin, as the resist 27. Examples of such resists include PVA photoresists, polyoxyalkylene photoresists, and polyether ester photoresists. Examples of the developer for the resist 27 include tetramethylammonium hydroxide (TMAH), tetrabutylammonium hydroxide (TBAH), and an ammonium salt.
- TMAH tetramethylammonium hydroxide
- TBAH tetrabutylammonium hydroxide
- the adhesive portion 28 is formed by imparting adhesiveness to the surface 25a of the circuit pattern 25 of the joint portion (portion not covered with the resist 27) 26 of the electronic component. To do. Specifically, as described below, the adhesive portion 28 can be formed by reacting the tackifier compound on the surface 25a of the circuit pattern 25 at the joint portion 26.
- a tackifier compound that is highly reactive with respect to the conductive substance forming the circuit pattern 25.
- preferred tackifying compounds include, for example, benzotriazole derivatives, naphthotriazole derivatives, imidazole derivatives, benzimidazole derivatives, mercaptobenzothiazole derivatives, and benzothiazole thio fatty acids. It is done. These tackifier compounds are particularly reactive to copper, but can also impart tackiness to other conductive materials.
- the benzotriazole derivative suitably used in the production method of the present embodiment is represented by the general formula (1).
- R1 to R4 in the general formula (1) are independently a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, an alkoxy group, F, Br, Cl, I, a cyano group, an amino group, or an OH group.
- the benzotriazole derivative represented by the general formula (1) becomes more tacky as the number of carbon atoms of R1 to R4 increases. Therefore, R1 to R4 preferably have 5 to 16 carbon atoms.
- the naphthotriazole derivative suitably used in the production method of the present embodiment is represented by the general formula (2).
- R5 to R10 in the general formula (2) are independently a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, preferably an alkyl group having 5 to 16 carbon atoms, an alkoxy group, F, Br, Cl, I, cyano. A group, an amino group or an OH group.
- the imidazole derivative suitably used in the production method of the present embodiment is represented by the general formula (3).
- R11 and R12 in the general formula (3) are independently a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, an alkoxy group, F, Br, Cl, I, a cyano group, an amino group, or an OH group.
- the benzimidazole derivative suitably used in the production method of the present embodiment is represented by the general formula (4).
- R13 to R17 in the general formula (4) are independently a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, an alkoxy group, F, Br, Cl, I, a cyano group, an amino group, or an OH group.
- the adhesiveness increases as the number of carbon atoms of R11 to R17 increases. Therefore, the carbon number of R11 to R17 is preferably 5 to 16.
- the mercaptobenzothiazole derivative suitably used in the production method of the present embodiment is represented by the general formula (5).
- R18 to R21 in the general formula (5) are independently a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, preferably an alkyl group having 5 to 16 carbon atoms, an alkoxy group, F, Br, Cl, I, cyano. A group, an amino group or an OH group.
- the benzothiazole thio fatty acid derivative suitably used in the production method of the present embodiment is represented by the general formula (6).
- R22 to R26 in the general formula (6) are independently a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, preferably 1 or 2 carbon atoms, an alkoxy group, F, Br, Cl, I, cyano. A group, an amino group or an OH group.
- the above tackifying compound is preferably dissolved in water or acidic water, and preferably reacted in a state adjusted to slightly acidic pH of about 3-4.
- a substance used for adjusting the pH of such a tackifier compound solution if the conductive substance is a metal, for example, an inorganic acid such as hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, or formic acid, acetic acid, propionic acid, Organic acids such as malic acid, oxalic acid, malonic acid, succinic acid and tartaric acid can be mentioned.
- the concentration of the tackifying compound may be set as appropriate depending on the solubility and use conditions, and is not strictly limited. It is preferable to be within the range of 20% by mass. When the concentration is set within this range, the tackifier compound becomes easy to handle. On the other hand, if the concentration is lower than this range, the generation of the adhesive portion 28 becomes insufficient, such being undesirable.
- the printed wiring board 23 shown in FIG. 2B is dipped in the tackifier compound solution, or the tackifier compound solution is injected onto the surface 25a of the circuit pattern 25 at the joint 26.
- the tackifier compound solution is injected onto the surface 25a of the circuit pattern 25 at the joint 26.
- a suitable temperature for reacting the tackifier compound is not particularly limited because it varies depending on the concentration of the tackifier compound, the type of the conductive substance, and the like.
- the temperature at which the tackifying compound is reacted is preferably slightly higher than room temperature, and is preferably in the range of 30 ° C to 60 ° C. Thereby, the production
- the immersion time for reacting the tackifier compound is not particularly limited, but it is preferable to adjust other conditions so as to be in the range of about 5 seconds to 5 minutes from the viewpoint of work efficiency.
- copper ions having a concentration of about 100 to 1000 ppm coexist in the tackifying compound solution from the viewpoint that the production efficiency such as the production rate and production amount of the adhesive portion 28 is further increased.
- the adhesive part 28 is washed with water and dried.
- the resist 27 is finely patterned so as to correspond to the fine pitch in the resist forming process, as shown in FIG.
- a printed wiring board 29 in which the adhesive portion 28 is formed on the surface 25a of the pattern 25 is obtained.
- solder adhesion process Next, the solder powder 30 is adhered to the adhesive portion 28 by a method such as sprinkling the solder powder on the printed wiring board 29. Thereafter, when excess solder powder is removed, a printed wiring board 31 shown in FIG. 2D is obtained.
- solder powder 30 used in the manufacturing method of the present embodiment for example, Sn—Pb, Sn—Ag, Sn—Pb—Ag, Sn—Pb—Bi, Sn—Pb—Bi—Ag, Sn—P—P Examples thereof include powders made of Pb—Cd solder alloys. Further, from the viewpoint of eliminating Pb in recent industrial waste, the solder powder 30 may be Sn—In, Sn—Bi, In—Ag, In—Bi, Sn—Zn, Sn, which does not contain Pb.
- the metal composition of the solder powder 30 is 96.5 Sn / 3.5 Ag, 62 Sn / 36 Pb, mainly eutectic solder (hereinafter referred to as 63 Sn / 37 Pb) with 63 mass% Sn and 37 mass% Pb.
- the average particle size of the solder powder 30 in the manufacturing method of the present embodiment may be set as appropriate based on the standard defined by the Japanese Industrial Standard (JIS).
- JIS Japanese Industrial Standard
- standards such as 63 to 22 ⁇ m, 45 to 22 ⁇ m, and 38 to 22 ⁇ m are determined by sieving.
- the second heating step is a step for increasing the holding power of the solder powder 30 to the adhesive portion 28. Therefore, by performing the second heating step, it is difficult for the solder powder 30 to be detached from the adhesive portion 28 in each step after the second heating step.
- the temperature in the second heating step is preferably 100 ° C. to 180 ° C.
- the temperature range is preferable. By setting it as the said temperature range, the adhesive force of the adhesion part 28 can be made higher.
- copper is used as the conductive material, and naphthotriazole derivatives, benzotriazole derivatives, imidazole derivatives, benzimidazole derivatives, mercaptobenzothiazole derivatives, benzothiazole thio fatty acids, etc.
- the heating temperature of the printed wiring board 31 in this step is in the range of 100 to 180 ° C. and the heating time is in the range of 30 to 120 seconds. Under this condition, the adhesive force of the adhesive portion 28 is further increased.
- the resist 27 of the printed wiring board 31 is peeled off.
- the type of the stripping solution for the resist 27 is not particularly limited as long as it does not dissolve and alter the solder powder 30 and the adhesive portion 28.
- a stripping solution that does not alter the property-imparting compound is used. Examples of such stripping solutions include alkaline stripping solutions such as tetramethylammonium hydroxide (TMAH), aqueous sodium hydroxide, tetrabutylammonium hydroxide (TBAH), and ammonium salts.
- the resist when the resist is of an alkali developing type, it is preferable to remove the resist using an alkaline liquid in the resist removing step.
- the resist is preferably an alkali developing type. Therefore, the resist can be easily removed by using an alkaline solution. Moreover, when an alkaline liquid is used, it is possible to prevent the solder powder from falling off in the adhesive layer having alkali resistance.
- a printed wiring board 32 from which the resist 27 has been peeled is obtained.
- the fine pitched adhesive part 28 having a fine pitch is formed, so that the solder powder 30 is formed on the printed wiring board 32 at a fine pitch.
- the resist removal step may be performed after the adhesive portion forming step, and then the solder attaching step may be performed. Even with such a manufacturing method, the printed wiring board 32 is obtained. Moreover, in the manufacturing method of this embodiment, you may provide the process of apply
- solder powder 30 of the printed wiring board 32 is melted to obtain the solder circuit board 34 in which the solder layer 33 is formed on the surface 25a of the circuit pattern 25 at the joint location 26 as shown in FIG.
- the solder layer 33 constitutes a solder circuit later.
- the heating temperature and heating time for melting the solder powder 30 may be set as appropriate in consideration of the alloy composition and particle size of the solder powder 30.
- the heating temperature is 210 to 230 ° C., preferably 210 to 230 ° C.
- the heating time is 220 ° C. and the heating time is 30 to 60 seconds, preferably 30 to 40 seconds.
- the heating temperature is 200 to 350 ° C., preferably 200 to 250 ° C.
- the heating time is 30 to 60 seconds, preferably 30 to 40. Preferably it is seconds.
- the heating temperature is 250 to 350 ° C., preferably 220 to 270 ° C.
- the heating time is 30 to 60 seconds, preferably 30 to 40. Preferably it is seconds. Under such conditions, the solder powder 30 is melted satisfactorily. Further, in this step, the solder layer 33 having an appropriate solder thickness is formed without substantially spreading from the adhesive portion 28 due to the surface tension of the solder powder 30 and the adhesive force of the adhesive portion 28.
- the heating temperature when other alloy solder powder 30 is used is preferably +20 to + 50 ° C. with respect to the melting point of the solder alloy, and preferably +20 to + 30 ° C. with respect to the melting point of the alloy.
- the heating temperature may be set in the range of 200 ° C. to 350 ° C., and the heating time may be set in the same range as described above.
- surface mounting technology SMT
- SMT surface mounting technology
- a solder paste is applied to the joint portion 26 of the surface 25a of the circuit pattern 25 by a screen printing method.
- an electronic component 35 such as a chip component or QFP is placed on a solder paste (not shown) and soldered together by a reflow heat source.
- a reflow heat source in such a reflow process, a hot air furnace, an infrared furnace, a vapor condensation soldering device, a light beam soldering device, or the like can be used.
- the conditions may be set as appropriate in consideration of the metal composition.
- the preheating temperature is 130 to 180 ° C., preferably 130 to 150 ° C.
- the preheating time is 60 to 120 seconds, preferably 60 to 90 seconds.
- the reflow temperature is 210 to 230 ° C., preferably 210 to 220 ° C., and the reflow time is 30 to 60 seconds, preferably 30 to 40 seconds.
- the reflow temperature in the solder powder 30 and solder paste of other alloys is +20 to + 50 ° C. with respect to the melting point of the alloy to be used, preferably +20 to + 30 ° C. with respect to the melting point of the alloy.
- the preheat time and reflow time may be in the same range as described above.
- the above reflow process may be performed in any atmosphere of nitrogen or air.
- the oxygen concentration is 5% by volume or less, preferably 0.5% by volume or less, so that the solder paste is wetted onto the solder layer 33 more than when reflowing in the atmosphere. It is possible to improve the performance and suppress the generation of solder balls, and perform stable treatment.
- the surface mounting is completed by cooling the solder circuit board 34.
- Such joining of electronic components by SMT may be performed on both sides of the printed wiring board 24.
- the resist removal step is performed between the adhesive portion forming step and the first heating step, so that the surface 25a of the circuit pattern 25 is joined.
- the resist 27 can be removed before the solder powder 30 applied to the location 26 is melted.
- the resist 27 applicable to the photolithography technique for performing fine patterning can be used even if the resist does not have heat resistance with respect to the melting temperature of the solder.
- the resist 27 can be patterned with a fine pattern of 20 ⁇ m level.
- the portion of the surface 25a of the circuit pattern 25 of the printed wiring board 23 that is not covered with the resist, that is, the joint portion 26 of the electronic component is made fine pitch, and the adhesive portion 28 and the solder particles 30 that are sequentially formed at the joint portion 26 are formed.
- the pattern is also fine pitched.
- the amount of solder used can be minimized. In this way, when the first heating process is completed, the solder circuit board 34 on which the fine pattern solder layer 33 corresponding to the fine pitch is formed is obtained.
- solder circuit board 17 of FIG. 3A is usually formed, and as shown in FIG. 3B, solder bumps 15 formed so as to cover the circuit pattern.
- pressure is applied while heating with a flip chip bonder.
- the distance between the electrodes 16 is narrow, so that the solder may contact the adjacent electrodes 16 as shown in FIG.
- the mounting substrate 22 having the solder circuit 20 shown in FIG. 3C can be obtained, but a part of the mounting substrate 22 like the electrode 21 may be bridged.
- a resist layer (not shown) is formed on every other electrode surface of the circuit pattern 40 on the substrate 39, so that a solder layer is formed every other electrode.
- a solder circuit board 42 shown in FIG. 4A can be produced. If the electrode 41 on which the solder layer of the solder circuit board 42 is formed and the electrode portion 44 of the electronic component 43 are pressed while being heated using a flip chip bonder as shown in FIG. 4B, FIG. As shown in FIG. 3, the mounting substrate 46 in which the solder is melted and connected to the solder circuit 45 without the occurrence of a bridge is obtained.
- a printed wiring board (hereinafter simply referred to as “printed wiring board”) was prepared using copper as the conductive material.
- the line width of the circuit pattern of the printed wiring board made of a conductive material was 25 ⁇ m, and the interval between the narrowest circuit patterns was 25 ⁇ m.
- a substrate was prepared by attaching a photoresist (model number: H-7034, manufactured by Hitachi Chemical Co., Ltd.) to this printed wiring board. After the printed wiring board was exposed to ultraviolet rays using a photomask, the printed wiring board was patterned using alkaline development, for example, 1% aqueous sodium carbonate solution. The region not covered with the resist on the surface of the conductive circuit electrode was 25 ⁇ 80 ⁇ m in size every other electrode.
- a 2% by mass aqueous solution of an imidazole compound in which the alkyl group of R12 in the general formula (3) is C 11 H 23 and R11 is a hydrogen atom, the pH of which is adjusted to about 4 with acetic acid is used.
- This imidazole compound aqueous solution was heated to 40 ° C., and the printed wiring board pretreated with the hydrochloric acid aqueous solution was immersed for 3 minutes, and then an adhesive portion was formed in the opening region of the resist.
- the printed wiring board was washed with water and dried.
- the printed wiring board was sprinkled with solder powder having an average particle size of about 10 ⁇ m and an alloy composition of 63Sn / 37Pb, and lightly brushed to selectively adhere to the adhesive part.
- the printed wiring board was heated at 120 ° C. for 10 minutes, and then the photoresist formed on the surface of the printed wiring board was peeled off using an alkaline peeling liquid 3% sodium hydroxide aqueous solution.
- the printed wiring board was placed in an oven at 240 ° C. to melt the solder powder.
- a solder circuit board having an eutectic solder layer of about 10 ⁇ m formed on the solder powder adhering portion of the circuit pattern made of copper was obtained.
- the printed circuit board on which the solder bumps were formed was placed on a flip chip bonder and heated to 160 ° C.
- the bare chip was mounted while being heated to 230 ° C. so that the electrode of the chip in which the stud bump (diameter 50 ⁇ m ⁇ height 80 ⁇ m) was formed on the bare chip electrode (pitch: 100 ⁇ m) was aligned with the electrode of the printed circuit board.
- Example 2 A bare chip was mounted on the printed circuit board in the same process and conditions as in Example 1 except that the printed wiring board was not heated (second heating process) after the solder powder was adhered.
- Example 1 (Evaluation in Example 1, Example 2 and Comparative Example) In the solder circuit board on which the bare chip was mounted by the above process, as shown in Table 1, it was possible to form minute bumps having substantially the same bump height in Example 1, Example 2, and Comparative Example.
- Example 1 by performing the second heating step, the solder powder was prevented from falling off in the photoresist peeling step, so that the bump height could be secured.
- flip chip mounting the mounting substrates of Examples 1 and 2 in which the photoresist was formed on the printed wiring board were good, but the mounting of the comparative example in which the photoresist was not formed on the printed wiring board. Generation of bridges was observed on the substrate.
- Example 1 and Example 2 described above since the photoresist is removed after the solder powder is adhered to the adhesive portion, and then the solder powder is melted, there is no resist on the substrate when the solder is melted, and heat resistance There is no need to use a resist. Therefore, according to the present invention, as can be seen from the evaluation results shown in Table 1, it was confirmed that a fine solder circuit with a fine pitch can be formed and the stud bumps of the electronic component can be lowered.
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Abstract
Description
また、はんだ合金は溶融時に表面張力の影響で金属回路の幅が広い部分に移動するため、その部分のはんだ層厚が大きくなる。これにより、はんだ回路基板のはんだ層厚にばらつきが生ずると、はんだ層の形成工程後に行う電子部品の接合工程において、電子部品のリード端子と回路パターンとの接合強度にばらつきが生じる等の悪影響がある。
また、通常図1(g)に示す電子部品9とソルダーレジスト4の間に、電子部品9を固定するための樹脂を充てんするが、ファインピッチになると、電子部品9の電極部10を小さくせざるを得ず、十分な間隔が取れにくい状態であった。
特に、電子部品としてベアチップを用いる際にファインピッチになると、ベアチップに形成するスタッドバンプの影響により電極部を2列以上に形成する必要がある。しかし、電子部品の電極部はますます小さくなり、電子部品と基板との間隔はますます取れにくい状態となっていた。
(1)プリント配線板上の導電性回路電極表面をレジストにより部分的に覆うレジスト形成工程と、前記導電性回路電極表面のうちレジストに覆われていない部分に粘着性を付与して粘着部を形成する粘着部形成工程と、前記粘着部にはんだ粉末を付着させるはんだ付着工程と、前記レジストを除去するレジスト除去工程と、前記プリント配線板を加熱してはんだ粉末を溶融させる第1の加熱工程と、を順次行うことを特徴とするはんだ回路基板の製造方法。
(2)プリント配線板上の導電性回路電極表面をレジストにより部分的に覆うレジスト形成工程と、前記導電性回路電極表面のうちレジストに覆われていない部分に粘着性を付与して粘着部を形成する粘着部形成工程と、前記レジストを除去するレジスト除去工程と、前記粘着部にはんだ粉末を付着させるはんだ付着工程と、前記プリント配線板を加熱してはんだ粉末を溶融させる第1の加熱工程と、を順次行うことを特徴とするはんだ回路基板の製造方法。
(3)前記はんだ付着工程の直後に、第2の加熱工程を設けることを特徴とする前項(1)または(2)に記載のはんだ回路基板の製造方法。
(4)前記レジスト除去工程と前記第1の加熱工程との間に、前記はんだ粉末にフラックスを塗布する工程を設けることを特徴とする前項(1)~(3)の何れか1項に記載のはんだ回路基板の製造方法。
(5)前記レジストがアルカリ現像型であり、前記レジスト除去工程において、アルカリ性液を用いて前記レジストを除去することを特徴とする前項(1)~(4)の何れか1項に記載のはんだ回路基板の製造方法。
(6)前記はんだ粉末がSn-Pb系はんだ粉末であり、第1の加熱工程における加熱温度が200℃~350℃の範囲内であり、第2の加熱工程における加熱温度が100℃~180℃の範囲内であることを特徴とする前項(2)~(5)の何れか1項に記載のはんだ回路基板の製造方法。
(7)前記はんだ粉末がSn-Ag系はんだ粉末であり、第1の加熱工程における加熱温度が250℃~350℃の範囲内であり、第2の加熱工程における加熱温度が100℃~180℃の範囲内であることを特徴とする前項(2)~(5)の何れか1項に記載のはんだ回路基板の製造方法。
(8)前記導電性回路電極が銅合金からなり、前記粘着部形成工程において、前記銅合金と、ベンゾトリアゾール系誘導体、ナフトトリアゾール系誘導体、イミダゾール系誘導体、ベンゾイミダゾール系誘導体、メルカプトベンゾチアゾール系誘導体、ベンゾチアゾールチオ脂肪酸系誘導体との反応により、前記レジストに覆われていない部分に粘着性を付与することを特徴とする前項(1)~(7)の何れか1項に記載のはんだ回路基板の製造方法。
(9)前項(1)~(8)の何れか1項に記載のはんだ回路基板の製造方法を用いて作製したはんだ回路基板。
(10)前項(9)に記載のはんだ回路基板に、電子部品を載置する電子部品載置工程と、前記はんだ粉末をリフローして前記電子部品の電極部分と前記はんだ回路基板とを接合する電子部品接合工程と、を含むことを特徴とする電子部品の実装方法。
先ず、図2(b)に示すように、プリント配線板24の電子部品の接合箇所26を除く回路パターン25の表面25aをレジスト27で覆う。後述するように、はんだ粉末を溶融させる前にレジスト27を除去するため、レジスト27にははんだの溶融温度に対して耐熱性を有するソルダーレジストを用いる必要はない。本実施形態の製造方法で用いるレジスト27には、後に説明する粘着部形成工程において、回路パターン25の表面25aのうち粘着性を付与しない部分を充分に保護できる性質を持ったレジストであり、かつ、粘着性付与化合物を変質させないレジストを用いる。即ち、レジスト27には、はんだ粉末の溶融温度での耐熱性を有していなくとも、フォトリソグラフィー技術を用いた微細なパターニングに適用可能なレジストを用いることができる。これにより、基板24上にファインピッチ化された微細なパターンの接合箇所26を形成できる。
次に、図2(c)に示すように、電子部品の接合箇所(レジスト27に覆われていない部分)26の回路パターン25の表面25aに粘着性を付与することにより、粘着部28を形成する。具体的には、次に説明するように、接合箇所26の回路パターン25の表面25aにおいて粘着性付与化合物を反応させることにより、粘着部28を形成できる。
一般式(1)で表されるベンゾトリアゾール系誘導体は、一般に、R1~R4の炭素数が多くなる程、粘着性が強くなる。そのため、R1~R4の炭素数は5~16であることが好ましい。
また、粘着性付与化合物を反応させる際の浸漬時間は、特に限定されないが、作業効率の点から5秒~5分程度の範囲になるように、他の条件を調整することが好ましい。
なお、粘着部28の生成速度、生成量等の生成効率がより高まる点から、粘着性付与化合物溶液中に濃度100~1000ppm程度の銅イオンを共存させることが好ましい。
次に、プリント配線板29にはんだ粉末をふりかける等の方法により、はんだ粉末30を粘着部28に付着させる。その後、余分なはんだ粉末を除去すると、図2(d)に示すプリント配線板31が得られる。
本実施形態の製造方法では、図2(d)に示す付着工程の直後に第2の加熱工程を設けるのが好ましい。第2の加熱工程は、粘着部28へのはんだ粉末30の保持力を高めるための工程である。従って、第2の加熱工程を行うことにより、第2の加熱工程以降の各工程において、はんだ粉末30が粘着部28から脱離し難くなる。
また上述のように、導電性物質として銅を用いるとともに、粘着性付与化合物としてナフトトリアゾール系誘導体、ベンゾトリアゾール系誘導体、イミダゾール系誘導体、ベンゾイミダゾール系誘導体、メルカプトベンゾチアゾール系誘導体及びベンゾチアゾールチオ脂肪酸等を用いる場合は、本工程におけるプリント配線板31の加熱温度を100~180℃の範囲内とし、加熱時間を30~120秒の範囲内とすることが好ましい。この条件により、粘着部28の付着力がより高められる。
次に、プリント配線板31のレジスト27を剥離する。レジスト27の剥離液の種類は、はんだ粉末30と粘着部28を溶解及び変質させないものであれば、特に限定されない。また、上述のように、ナフトトリアゾール系誘導体、ベンゾトリアゾール系誘導体、イミダゾール系誘導体、ベンゾイミダゾール系誘導体、メルカプトベンゾチアゾール系誘導体及びベンゾチアゾールチオ脂肪酸等を粘着性付与化合物として用いる場合は、これらの粘着性付与化合物を変質させない剥離液を用いる。このような剥離液としては、例えば、テトラメチルアンモニウムヒドロキシド(TMAH)、水酸化ナトリウム水溶液、水酸化テトラブチルアンモニウム(TBAH)、アンモニウム塩等のアルカリ性剥離液が挙げられる。
また、本実施形態の製造方法では、レジスト除去工程と次に説明する第1の加熱工程との間に、はんだ粉末30にフラックスを塗布する工程を設けてもよい。この工程により、第1の加熱工程におけるはんだ粉末30の溶融性を高めることができる。はんだ粉末30に塗布するフラックスとしては、ロジン等を用いることができる。
次に、プリント配線板32のはんだ粉末30を溶融させて、図2(f)に示すように接合箇所26の回路パターン25の表面25aにはんだ層33を形成したはんだ回路基板34を得る。はんだ層33は、後にはんだ回路を構成するものである。
このような条件により、はんだ粉末30が良好に溶融される。また、本工程でははんだ粉末30の表面張力と粘着部28の付着力により、粘着部28からほとんど拡がることなく、適度なはんだ厚のはんだ層33が形成される。
次に、電子部品35としてファインピッチのベアチップを実装する場合はフリップチップボンダー等を用いて、図2(g)に示すように、はんだ層33とベアチップの電極上に形成されたバンプ36との位置を合わせ、加熱しながら加圧する。この工程により、図2(h)に示すように、はんだが溶融しはんだ回路37に接続された実装基板38を得る。
これに対し、本実施形態の製造方法では、基板39上の回路パターン40の電極表面に1つおきにレジスト層(図示略)を形成することで、電極の1つおきにはんだ層を形成した図4(a)に示すはんだ回路基板42を作製することができる。このはんだ回路基板42のはんだ層を形成した電極41と電子部品43の電極部44を、図4(b)に示すようにフリップチップボンダー用いて加熱しながら加圧すれば、図4(c)に示すようにはんだが溶融してはんだ回路45に接続された、ブリッジの発生がない実装基板46が得られる。
導電性物質に銅を用いてプリント配線板(以降では、単に「プリント配線板」と記載する)を作製した。導電性物質からなるプリント配線板の回路パターンの線幅は25μmで最も狭い回路パターンの間隔は25μmとした。このプリント配線板にフォトレジスト(型番:H-7034、日立化成株式会社製)を貼り付けた基板を準備した。フォトマスクを用いてプリント配線板を紫外線露光した後、アルカリ性現像たとえば1%炭酸ナトリウム水溶液を用いてプリント配線板をパターニングした。導電性回路電極表面でレジストに覆われていない領域は、1電極おきにサイズを25×80μmとした。
はんだ粉末付着後のプリント配線基板の加熱(第2加熱工程)を行わなかったこと以外は、実施例1と同様の工程および条件でプリント基板にベアチップを実装した。
プリント配線板としてフォトレジストを貼り付けていない基板を使用し、回路パターンをレジストで覆わずに粘着性を付与し、ハンダ粉末を付着させた。他は実施例1と同様の工程及び条件によってプリント基板にベアチップを実装した。
上記の工程によりベアチップを実装したはんだ回路基板において、表1に示すように、実施例1、実施例2及び比較例で同程度のバンプ高さを有する微小バンプを形成できた。実施例1は、第二加熱工程を行うことにより、フォトレジストの剥離工程ではんだ粉末の脱落を抑制したため、バンプ高さを確保できた。またフリップチップ実装においては、プリント配線板上にフォトレジストを形成した実施例1及び実施例2の実装基板は良好であったが、プリント配線板上にフォトレジストを形成しなかった比較例の実装基板にはブリッジの発生が認められた。
Claims (10)
- プリント配線板上の導電性回路電極表面をレジストにより部分的に覆うレジスト形成工程と、
前記導電性回路電極表面のうちレジストに覆われていない部分に粘着性を付与して粘着部を形成する粘着部形成工程と、
前記粘着部にはんだ粉末を付着させるはんだ付着工程と、
前記レジストを除去するレジスト除去工程と、
前記プリント配線板を加熱してはんだ粉末を溶融させる第1の加熱工程と、
を順次行うことを特徴とするはんだ回路基板の製造方法。 - プリント配線板上の導電性回路電極表面をレジストにより部分的に覆うレジスト形成工程と、
前記導電性回路電極表面のうちレジストに覆われていない部分に粘着性を付与して粘着部を形成する粘着部形成工程と、
前記レジストを除去するレジスト除去工程と、
前記粘着部にはんだ粉末を付着させるはんだ付着工程と、
前記プリント配線板を加熱してはんだ粉末を溶融させる第1の加熱工程と、
を順次行うことを特徴とするはんだ回路基板の製造方法。 - 前記はんだ付着工程の直後に、 第2の加熱工程を設けることを特徴とする請求項1または2に記載のはんだ回路基板の製造方法。
- 前記レジスト除去工程と前記第1の加熱工程との間に、
前記はんだ粉末にフラックスを塗布する工程を設けることを特徴とする請求項1または2に記載のはんだ回路基板の製造方法。 - 前記レジストがアルカリ現像型であり、
前記レジスト除去工程において、
アルカリ性液を用いて前記レジストを除去することを特徴とする請求項1または2に記載のはんだ回路基板の製造方法。 - 前記はんだ粉末がSn-Pb系はんだ粉末であり、
第1の加熱工程における加熱温度が200℃~350℃の範囲内であり、
第2の加熱工程における加熱温度が100℃~180℃の範囲内であることを特徴とする請求項3に記載のはんだ回路基板の製造方法。 - 前記はんだ粉末がSn-Ag系はんだ粉末であり、
第1の加熱工程における加熱温度が250℃~350℃の範囲内であり、
第2の加熱工程における加熱温度が100℃~180℃の範囲内であることを特徴とする請求項3に記載のはんだ回路基板の製造方法。 - 前記導電性回路電極が銅合金からなり、
前記粘着部形成工程において、
前記銅合金と、ベンゾトリアゾール系誘導体、ナフトトリアゾール系誘導体、イミダゾール系誘導体、ベンゾイミダゾール系誘導体、メルカプトベンゾチアゾール系誘導体、ベンゾチアゾールチオ脂肪酸系誘導体との反応により、前記レジストに覆われていない部分に粘着性を付与することを特徴とする請求項1または2に記載のはんだ回路基板の製造方法。 - 請求項1または2に記載のはんだ回路基板の製造方法を用いて作製したはんだ回路基板。
- 請求項9に記載のはんだ回路基板に、電子部品を載置する電子部品載置工程と、
前記はんだ粉末をリフローして前記電子部品の電極部分と前記はんだ回路基板とを接合する電子部品接合工程と、
を含むことを特徴とする電子部品の実装方法。
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US14/782,658 US20160219721A1 (en) | 2013-04-09 | 2014-04-09 | Method for manufacturing solder circuit board, solder circuit board, and method for mounting electronic component |
CN201480019731.9A CN105122957B (zh) | 2013-04-09 | 2014-04-09 | 焊料电路基板的制造方法、焊料电路基板和电子部件的安装方法 |
KR1020157029616A KR20150132477A (ko) | 2013-04-09 | 2014-04-09 | 땜납 회로 기판의 제조 방법, 땜납 회로 기판 및 전자 부품의 실장 방법 |
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JP2017208485A (ja) * | 2016-05-19 | 2017-11-24 | 昭和電工株式会社 | 電子部品の実装方法 |
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US11127706B2 (en) * | 2018-09-28 | 2021-09-21 | Intel Corporation | Electronic package with stud bump electrical connections |
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