WO2014024299A1 - Produit cosmétique pulvérulent pour le bain - Google Patents

Produit cosmétique pulvérulent pour le bain Download PDF

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Publication number
WO2014024299A1
WO2014024299A1 PCT/JP2012/070468 JP2012070468W WO2014024299A1 WO 2014024299 A1 WO2014024299 A1 WO 2014024299A1 JP 2012070468 W JP2012070468 W JP 2012070468W WO 2014024299 A1 WO2014024299 A1 WO 2014024299A1
Authority
WO
WIPO (PCT)
Prior art keywords
powder
magnesium hydride
sodium
cosmetic
water
Prior art date
Application number
PCT/JP2012/070468
Other languages
English (en)
Japanese (ja)
Inventor
史暁 太田
齋藤　雅人
摩里 萩原
宇津木　彰
Original Assignee
クラシエホームプロダクツ株式会社
水素健康医学ラボ株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by クラシエホームプロダクツ株式会社, 水素健康医学ラボ株式会社 filed Critical クラシエホームプロダクツ株式会社
Priority to PCT/JP2012/070468 priority Critical patent/WO2014024299A1/fr
Priority to JP2014529217A priority patent/JPWO2014024299A1/ja
Publication of WO2014024299A1 publication Critical patent/WO2014024299A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/022—Powders; Compacted Powders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9755—Gymnosperms [Coniferophyta]
    • A61K8/9767—Pinaceae [Pine family], e.g. pine or cedar
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9794—Liliopsida [monocotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the present invention relates to a powder bath cosmetic containing magnesium hydride.
  • Magnesium hydride is a compound that holds hydrogen in the gaps between the metal atoms of magnesium and decomposes while releasing hydrogen by reacting with water according to the reaction formula of the following formula (1).
  • magnesium hydride there are various methods for producing magnesium hydride. For example, it can be efficiently produced by the methods disclosed in Patent Document 1 and Patent Document 2 below.
  • Patent Document 4 discloses a hydrogen generator in which a powder of a hydrogen compound such as an alkaline earth metal hydride is embedded in a water-soluble compound such as polyethylene glycol, xylitol, or trehalose. Is used for lotion and bathing agent.
  • Japanese Patent No. 4083786 Japanese Patent No. 4425990 JP 2000-119161 A Japanese Patent No. 4384227
  • magnesium hydride reacts with water, it is gradually decomposed by moisture and the like, and there is a problem that it is difficult to stably develop the function of magnesium hydride.
  • An object of the present invention is to provide a powder bath cosmetic that can stably exhibit the function of magnesium hydride even when stored for a long period of time.
  • the powder bath cosmetic of the present invention is characterized by containing magnesium hydride and a moisture absorbing component.
  • the moisture-absorbing component eliminates moisture that is going to contact the magnesium hydride, thus preventing the magnesium hydride from gradually decomposing due to moisture and the like, and storing for a long period of time. Even so, the function of magnesium hydride can be expressed stably.
  • the magnesium hydride is preferably finely divided into particles having an average particle size of 10 to 120 ⁇ m.
  • magnesium hydride reacts relatively slowly with water compared to other alkaline earth metal hydrides, but its surface area is increased by making fine particles, so it promotes the reaction with acids and the like. Even if it is not, suitable hydrogen generation can be realized when combined with water-containing products such as water, hot water or a water-containing cosmetic precursor. In addition, the rough feeling of magnesium hydride during use is alleviated.
  • the powder bath cosmetic of the present invention is preferably prepared so that the water content does not exceed 10%.
  • inorganic salts such as sulfates, sodium, and carbonates may be used for bathing, but depending on the combination, if there is moisture, it may solidify, generate gas, etc. Where there are drawbacks, this can be suppressed.
  • the powder bath cosmetic of the present invention preferably further contains at least one powder selected from the group consisting of chimpi (citrus peel), red pepper, ginseng, ginger, toki, and mugwort.
  • the powder bath cosmetic of the present invention may further contain at least one inorganic salt powder selected from the group consisting of sodium sulfate, sodium chloride, potassium chloride, magnesium sulfate, and alum. Furthermore, you may contain the powder of the at least 1 sort (s) of carbonate chosen from the group which consists of sodium hydrogencarbonate, sodium carbonate, and sodium sesquicarbonate.
  • the powder bath cosmetic of the present invention is selected from the group consisting of anhydrous silicic acid, aluminum silicate, aluminum oxide, potassium oxide, sodium oxide, magnesium oxide, ferric oxide, calcium oxide, and a rock composition containing these. It is preferable to contain 0.005 to 5% by weight of at least one powder.
  • the hygroscopic component is preferably contained in an amount of 1 to 99% by weight.
  • the moisture-absorbing component eliminates moisture that is going to contact the magnesium hydride, thus preventing the magnesium hydride from gradually decomposing due to moisture and the like, and storing for a long period of time. Even so, the function of magnesium hydride can be expressed stably.
  • the cosmetic for powder bath of the present invention is a cosmetic containing magnesium hydride, and is used for generating functional water (hydrogenated water) together with water-containing products such as water, hot water or a water-containing cosmetic precursor.
  • Cosmetics. Magnesium hydride decomposes while releasing hydrogen by reacting with water according to the following reaction formula (1). MgH 2 + 2H 2 O ⁇ Mg (OH) 2 + 2H 2 (1)
  • the method for obtaining the magnesium hydride used in the present invention is not particularly limited, but it can be efficiently produced by, for example, the methods disclosed in Japanese Patent No. 4083786 and Japanese Patent No. 4425990. It has become.
  • a raw material powder containing magnesium as a main component is held in a hydrogen gas atmosphere sealed in a sealed container, While maintaining the pressure of the hydrogen gas atmosphere at a predetermined pressure, the temperature of the hydrogen gas atmosphere in the enclosure is on the equilibrium curve between the reaction in which single magnesium and hydrogen molecules combine to produce magnesium hydride and the reverse reaction.
  • the coating on the surface of the raw material powder is removed by maintaining at a temperature higher than the temperature corresponding to the predetermined pressure and at a temperature difference from the temperature within a predetermined value for a predetermined first period, Next, without returning the temperature of the hydrogen gas atmosphere in the enclosure to room temperature, the temperature is lower than the temperature corresponding to the predetermined pressure on the equilibrium curve, and the temperature difference from the temperature is within a predetermined value.
  • Ah The temperature, by maintaining a predetermined second period, the production of magnesium hydride from the raw material powder. According to this method, magnesium hydride having a high hydrogenation rate can be efficiently produced. Further, as disclosed in Japanese Patent No.
  • a compressed product is prepared by compressing a plurality of flakes mainly composed of magnesium and compressing them in a hydrogen gas atmosphere. You may make it react with gas. According to this method, magnesium hydride having a high hydrogenation rate is manufactured more safely than a method of manufacturing from a powder raw material that may cause a dust explosion because it is manufactured from a flake mainly composed of magnesium. It can be manufactured efficiently.
  • the hydrogenation rate is a percentage of the amount of hydrogen that can be ideally occluded according to the MgH 2 molecular weight 26 and Mg molecular weight 24, and the mass before and after hydrogen occlusion is measured during the production of magnesium hydride. It is obtained as in 2).
  • Magnesium hydride obtained by the above method usually has a hydrogenation rate of about 70 to 100%, more preferably about 90 to 100%, which is higher than other hydrogen storage alloys and is resistant to chemical deterioration.
  • it is a very good hydrogen storage material that is stable and easy to handle in terms of workability such as transportation, supply, and storage.
  • it since it has reactivity with water, there is a problem that it gradually decomposes due to moisture or the like over a long period of time.
  • the powder bath cosmetic of the present invention contains the above-mentioned magnesium hydride and a moisture absorbing component.
  • the hygroscopic component only needs to contain a component that absorbs moisture, such as silica, sodium sulfate, magnesium sulfate, copper sulfate, calcium chloride, magnesium chloride, alumina, diphosphorus pentoxide, diatomaceous earth, zeolite, etc. It may be included.
  • silica and sodium sulfate are preferably used.
  • the average particle size of magnesium hydride is preferably 10 to 120 ⁇ m, and more preferably 20 to 80 ⁇ m. If the average particle size is large, the surface area decreases, so that the hydrogen generation rate due to the reaction with water tends to decrease, and the rough feeling of magnesium hydride tends to remain. If the average particle size is too small, it will be difficult to increase the amount of dissolved hydrogen due to floating on the surface when combined with water, hot water or a hydrated cosmetic precursor, etc. Tend to be. Specifically, when the magnesium hydride is added at a rate of 2.5 mg to 1 liter of water in a 40 ° C.
  • the dissolved hydrogen amount after 30 minutes is 0.01 mmol / L.
  • the particle size is 0.03 mmol / L or more and does not float.
  • a measuring method for obtaining the average particle size of magnesium hydride a method of estimating the particle size value from the analysis of the diffraction peak shape observed by a powder X-ray diffractometer is simple and preferably used.
  • the fine particles may be formed by a known method, and there are no particular restrictions on the apparatus and method. For example, a jet mill or a high-pressure gas ultrafine pulverizer can be used. Also, pulverization in a mortar can be used as a simple method.
  • the powder bath cosmetic of the present invention is preferably prepared so that the water content does not exceed 10%, and more preferably prepared so that the water content does not exceed 7.5%. Preferably, it is most preferably prepared so as not to exceed 5%.
  • the moisture content can be measured as follows, for example. That is, 5 g of the accurately weighed sample is put in an evaporating dish and dried for 3 hours in an air-cooled thermostat kept at 105 ° C., then the mass of the sample is measured again and calculated by the following equation (3).
  • a value obtained by correcting the weight loss due to volatilization based on the blended amount of the component is defined as the water content.
  • the powder bath cosmetic of the present invention preferably contains 0.005 to 10% by weight of the above magnesium hydride, more preferably 0.01 to 5% by weight.
  • the hygroscopic component is preferably contained in an amount of 1 to 99% by weight, more preferably 1 to 80% by weight, and most preferably 10 to 60% by weight.
  • the hygroscopic component preferably has a particle size comparable to that of magnesium hydride. Specifically, the average particle size is preferably 10 to 120 ⁇ m, more preferably 20 to 80 ⁇ m.
  • the powder bath cosmetic of the present invention for the purpose of imparting a cooperative action effect with blood circulation promotion effect by hydrogen water generated by magnesium hydride, chimpi (citrus peel), red pepper, ginseng, You may make it contain the at least 1 sort (s) of powder chosen from the group which consists of ginger, toki, and mugwort. In this case, it is preferable to use those whose water content does not exceed 10% or those prepared, and more preferably those whose water content does not exceed 7.5% or so prepared. Preferably, no more than 5% or so prepared is most preferred. Moreover, it is preferable that it is the powder finely ground to 1000 micrometers or less.
  • additives and other components can be appropriately blended in the powder bath cosmetic of the present invention.
  • suitable additives and other components include alcohols such as ethanol, nonionic surfactants, polysaccharides, low molecular sugars, natural fats and oils, emulsifiers, and fragrances.
  • the powder bath cosmetic of the present invention needs to consider stability in addition to the above composition, but considering the amount of moisture in the cosmetic, for example, inorganic salts, inorganic acids, organic acids, fats and oils Ingredients such as binders, polyhydric alcohols, moisturizers, plant powders and herbal medicines (extracts, powders) can be appropriately blended.
  • the bath cosmetic of the present invention may contain the following components:
  • Inorganic salts boric acid, borax, magnesium sulfate, sodium sulfide, potassium sulfide, sodium nitrate, calcium nitrate, ammonium sulfate, sodium thiosulfate, calcium hydrogen phosphate, potassium chloride, ammonium chloride, sodium phosphate, sodium hyposulfite, Calcium thiosulfate, sulfur, urea, sodium sesquicarbonate and alum.
  • Inorganic acids such as metasilicic acid and boric acid.
  • Organic acids Benzoic acid, citric acid, fumaric acid, tartaric acid, malic acid and salicylic acid.
  • Fats and oils Olive oil soybean oil, almond oil, castor oil, palm oil, palm oil, turtle oil, nuka oil, jojoba oil, mink oil, egg yolk oil, squalane, avocado oil, lanolin, liquid paraffin, white petrolatum, DHA And EPA etc.
  • Binders Sodium carboxymethylcellulose, methylcellulose, sodium salt, casein, pectin, starch, sodium alginate, polyvinyl alcohol, polyvinylpyrrolidone, locust bean gum, carrageenan, agar, carbopol and glucomannan.
  • Natural and synthetic fragrances such as spearmint oil, geraniol, mandarin oil, spruce and citronellol.
  • Plant powder and herbal medicine Extract, powder
  • Lemon skin seaweed, spirulina, chlorophyll, donariella, cypress, hiba, rice bran, shobu, daffodil, licorice, spruce, mint, keihi, baibai, dokudami, momonoha, chamomile, aloe, jasmine, rosehip, lavender, guava , Pulverized products such as oxon, wolfberry, litchi, elderberry, ashitaba, okogi, burdock, licorice, koko, gennoshouko, ginger, pepper, etc. and water-soluble or oil-soluble extracts thereof.
  • the powder bath cosmetic of the present invention contains, in addition to the above, bactericides, surfactants, vitamins, amino acids and pharmaceuticals, quasi drugs, and tar tar pigments for cosmetics, etc. It can be included as appropriate.
  • the powder bath cosmetic of the present invention can be used at any concentration. Usually, bath cosmetics are generally used in an amount of about 25 to 30 g per 150 to 220 liters of hot water in a bathtub. In addition, when the bath cosmetic contains ore, the ore concentration in the water during bathing is usually 1 ppb to 20,000 ppm. Therefore, the powder bath cosmetic of the present invention can be used so that the concentration of the composition containing silicon dioxide as a main component is 1 ppb to 20,000 ppm (2% by weight) at the time of bathing, for example. For example, the bath cosmetic of the present invention can be used by mixing 25 g of bath cosmetic containing 250 mg of composition with 180 L of hot water as shown in the examples.
  • the powder bath cosmetic of the present invention is prepared to be provided to the user in a state of being packaged so as to block moisture by aluminum packaging, vinyl packaging, paper packaging, inert gas sealing, etc. preferable. Moreover, it is preferable to take out from a package at the time of use, and to prepare for using together with hydrated substances, such as water, hot water, or a hydrated cosmetic precursor, as cosmetics.
  • the water-containing cosmetic precursor contains water for reacting with magnesium hydride, and was prepared to be combined with the powder bath cosmetic of the present invention to obtain a desired cosmetic. Means things.
  • Examples of cosmetics to which the powder bath cosmetic of the present invention is applied include whole body, half body, foot and arm bath cosmetics and bath agents.
  • Ingot-shaped magnesium hydride (hydrogenation rate 90-95%) is prepared by the method disclosed in Japanese Patent No. 4425990, and this is roughly crushed by a mill and pulverized to about 0.1 mm. Milled with a mill. The particle size of the obtained magnesium hydride was 60 ⁇ m according to analysis using a powder X-ray diffractometer.
  • a dissolved hydrogen meter “Micro-sensor Multi-Meter (H2 sensor)” (manufactured by UNISENSE) was used for the measurement, and the measured value was observed every hour while the electrode was kept in the hot water in the water tank. The room was not ventilated, and the temperature and humidity were controlled by the installed air conditioning. The test was performed a total of 8 times with different dates.
  • Table 1 shows the results of a total of 8 tests.
  • the amount of dissolved hydrogen increased to an average of about 0.036 mmol / L between 0 and 15 minutes after adding magnesium hydride, and the amount of dissolved hydrogen gradually increased over time.
  • Example 1 (bath agent) Using the magnesium hydride obtained in Production Example 1, a bath preparation was produced according to the formulation shown in Table 2 below, and packaged with aluminum according to a conventional method.
  • the storage stability test of the obtained powder bath cosmetic was conducted. Specifically, the quality of the expandability of the air in the packaged aluminum after storage at 60 ° C. for 4 days, the quality of the fluidity of the powder after storage at 40 ° C. for 6 months, the powder after storage at 40 ° C. for 6 months The quality of the absence of lumps was evaluated in four stages: ⁇ : very good, ⁇ : good, ⁇ : slightly bad, x: bad.
  • Example 2 in which sodium sulfate was blended at 98% by weight and Examples 3 to 6 in which 50% by weight was blended, the storage stability was very good in any evaluation. .
  • Example 7 which substituted 50 mass% of the sodium hydrogen carbonate with 50 weight% of sodium sulfate was more favorable.
  • the storage stability of Example 8 which substituted 50 mass% of the sodium carbonate with 50 weight% of sodium sulfate was more favorable.
  • Example 9 which substituted 50 mass% of the calcium carbonate with 50 weight% of sodium sulfate was more favorable.
  • Example 10 which substituted 50 mass% of the sodium sesquicarbonate with 50 weight% of sodium sulfate had better storage stability.
  • sodium sulfate can improve the storage stability of a powder bath cosmetic containing magnesium hydride.
  • the moisture content (loss on drying) of the obtained powder bath cosmetic was measured according to a conventional method. Specifically, it dried for 3 hours in the ventilation type thermostat kept at 105 degreeC, and computed by following formula (3).
  • Example 11 As a result, as shown in the lower part of Table 4, in Example 11, the water content was 3.5%, and the storage stability was extremely good. Moreover, the storage stability was also good in Example 12, which was close to the formulation of Example 11 and had a water content of 10%. On the other hand, in Comparative Examples 5 and 6, which are close to the blends of Examples 11 and 12 but have a moisture content of 11.2%, the expansion of air in the packaging aluminum is recognized, and the fluidity of the powder is also deteriorated. It was. On the other hand, in Examples 13 to 16 having different blending modes, the water content was adjusted to about 2.8 to 4.8%, and the storage stability was extremely favorable or good.
  • the storage stability of the powder bath cosmetic containing magnesium hydride can be improved by adjusting the water content to a predetermined value or less.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Botany (AREA)
  • Biotechnology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un produit cosmétique pulvérulent pour le bain qui peut présenter de façon stable la fonction d'hydrure de magnésium même lorsqu'il est conservé pendant une longue période de temps. Ce produit cosmétique pulvérulent pour le bain comprend de l'hydrure de magnésium et un composant hygroscopique. L'hydrure de magnésium est, de préférence, finement pulvérisé à une dimension moyenne de particule de 10-120 µm. En outre, le produit cosmétique pulvérulent pour le bain comprend, de préférence, au moins un type de poudre choisi dans le groupe consistant en chinpi (pelure de citrus unshiu), poivre de Cayenne, ginseng, gingembre, angelica acutiloba et armoise vulgaire.
PCT/JP2012/070468 2012-08-10 2012-08-10 Produit cosmétique pulvérulent pour le bain WO2014024299A1 (fr)

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PCT/JP2012/070468 WO2014024299A1 (fr) 2012-08-10 2012-08-10 Produit cosmétique pulvérulent pour le bain
JP2014529217A JPWO2014024299A1 (ja) 2012-08-10 2012-08-10 粉末浴用化粧料

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6000490B1 (ja) * 2015-12-02 2016-09-28 健司 木山 入浴剤
JP2017197435A (ja) * 2016-04-25 2017-11-02 株式会社バスクリン 水素発生入浴剤
JP6241768B1 (ja) * 2016-07-22 2017-12-06 株式会社ドクターズチョイス 化粧料組成物
JP2018158862A (ja) * 2017-03-22 2018-10-11 デンカ株式会社 六方晶窒化ホウ素の保管方法
KR20210152080A (ko) * 2020-06-05 2021-12-15 채수연 흡습 조성물 및 이를 포함하는 흡습제품
WO2024083800A1 (fr) * 2022-10-17 2024-04-25 Viawa Gmbh Oléogel stable

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JPH02218608A (ja) * 1989-02-17 1990-08-31 Pola Chem Ind Inc 発泡性剤及びその製造方法
JPH0517339A (ja) * 1991-07-04 1993-01-26 Tsumura & Co 浴用剤
JP2005200350A (ja) * 2004-01-15 2005-07-28 Asahi Kasei Life & Living Corp 炭酸足浴剤
WO2007055146A1 (fr) * 2005-11-10 2007-05-18 Hiromaito Co., Ltd. Agent générant de l'hydrogène et utilisation de celui-ci
JP2009046370A (ja) * 2007-08-22 2009-03-05 Aquafairy Kk 水素発生装置及び水素発生方法
JP2012171875A (ja) * 2011-02-18 2012-09-10 Dr's Choice Co Ltd 粉末浴用化粧料

Family Cites Families (1)

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Publication number Priority date Publication date Assignee Title
JP2013253036A (ja) * 2012-06-07 2013-12-19 Kracie Home Products Ltd 血行促進剤、発汗促進剤及び浴用組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02218608A (ja) * 1989-02-17 1990-08-31 Pola Chem Ind Inc 発泡性剤及びその製造方法
JPH0517339A (ja) * 1991-07-04 1993-01-26 Tsumura & Co 浴用剤
JP2005200350A (ja) * 2004-01-15 2005-07-28 Asahi Kasei Life & Living Corp 炭酸足浴剤
WO2007055146A1 (fr) * 2005-11-10 2007-05-18 Hiromaito Co., Ltd. Agent générant de l'hydrogène et utilisation de celui-ci
JP2009046370A (ja) * 2007-08-22 2009-03-05 Aquafairy Kk 水素発生装置及び水素発生方法
JP2012171875A (ja) * 2011-02-18 2012-09-10 Dr's Choice Co Ltd 粉末浴用化粧料

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6000490B1 (ja) * 2015-12-02 2016-09-28 健司 木山 入浴剤
JP2017197435A (ja) * 2016-04-25 2017-11-02 株式会社バスクリン 水素発生入浴剤
JP6241768B1 (ja) * 2016-07-22 2017-12-06 株式会社ドクターズチョイス 化粧料組成物
JP2018012680A (ja) * 2016-07-22 2018-01-25 株式会社ドクターズチョイス 化粧料組成物
JP2018158862A (ja) * 2017-03-22 2018-10-11 デンカ株式会社 六方晶窒化ホウ素の保管方法
KR20210152080A (ko) * 2020-06-05 2021-12-15 채수연 흡습 조성물 및 이를 포함하는 흡습제품
KR102456258B1 (ko) 2020-06-05 2022-10-20 채수연 흡습 조성물 및 이를 포함하는 흡습제품
WO2024083800A1 (fr) * 2022-10-17 2024-04-25 Viawa Gmbh Oléogel stable

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