1259773 A7 B7 五、發明說明（） 技術範圍 本發明係有關摻合於護膚、護臉、護髮、脱臭、除毛、 脱毛等之用途所用之非水化粧品，與水接觸水合發熱之發 熱劑，尤有關一種發熱量大。持續性佳，且使用中之ΡΗ^ 不會過高之溫熱劑。 背景技術 作爲藉水合而自體發熱之化粧料用溫熱劑，廣泛地已知 有無水彿石、氧化躬等。 其中，無水沸石，氣體之吸收性高，掺合此之製品，自 保存中之環境放出其吸收之氣體，有使製品之容器膨脹之 問題。又，典水沸石，由於與水蒸氣之反應性高，爲維持 穩定之發熱性，必須在摻合於化粧料之前加溫脱氣。作爲 解決這些之溫熱劑，於特公平8_5770號公報有揭示鉀沸 石，但無法完全地抑制氣體之吸收性。又，沸石水合速度 非常快，一方面與氧化鈣比較，有水合熱小、發熱之持續 性欠缺之問題。 一方面氧化鈣發熱量高，持續性亦佳，但發熱溫度過度 上升’顯示高之pH値，所以自與其他摻合成分之反應性與 對皮膚之刺激性之觀點並不佳。 本發明以提供發熱量大，持續性佳，使用中之pH値不含 變過高之溫熱劑爲目的。 發明之揭示 本發明&供以組成式xCa〇 · yAl2〇3(x/y = 〇 5〜4.0)表示之 鈣鋁化物爲主成分之溫熱劑及含此之非水化粧料。 -4 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) I裝 ----訂--------- 經濟部智慧則產局員Η消費告竹赵邱絮 1259773 A7 B7 2 五、發明說明（） 又’本發明提供以將此非水化粧料適用於潤濕之皮膚或 (請先閱讀背面之注音3事項再填寫本頁) 使該非水化粧料與水一起適用於皮膚爲特徵之皮膚溫熱方 法。 属式之簡單説明 圖1爲表示於水中投入各種粉體攪拌時之懸浮液之溫度變 化之圖。 供實施本發明之最佳形式 用於本發明#5銘化物之組成式xCaO · yAl203之X及y，自1259773 A7 B7 V. INSTRUCTION DESCRIPTION () Technical Field The present invention relates to a non-aqueous cosmetic for use in skin care, face protection, hair care, deodorization, hair removal, hair removal, etc., and a heat-generating agent which is in contact with water and hydrates. Especially related to a large amount of heat. The continuation is good, and the enthalpy in use is not too high. Background Art As a warming agent for cosmetics which is self-heating by hydration, anhydrous smectite, cerium oxide or the like is widely known. Among them, anhydrous zeolite has a high gas absorption property, and the product blended therein releases the absorbed gas from the environment in which it is stored, and has a problem of expanding the container of the product. Further, the water-containing zeolite has a high reactivity with water vapor, and in order to maintain stable heat build-up, it is necessary to heat and degas before blending with the cosmetic. As a warming agent for solving these problems, the potassium boil is disclosed in Japanese Patent Publication No. Hei 8-5770, but the absorption of gas cannot be completely suppressed. Further, the hydration speed of the zeolite is very fast, and on the one hand, compared with calcium oxide, there is a problem that the hydration heat is small and the heat is not continuously maintained. On the one hand, calcium oxide has a high calorific value and is excellent in persistence, but the exothermic temperature rises excessively, indicating a high pH 値, so the reactivity with other synthetic components and the irritation to the skin are not good. The present invention aims to provide a large amount of heat and a good durability, and the pH in use does not contain a superheating agent. Disclosure of the Invention The present invention is a warming agent containing a calcium aluminide as a main component represented by a composition formula xCa〇 · yAl2〇3 (x/y = 〇 5 to 4.0) and a non-aqueous cosmetic containing the same. -4 - This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) I------------- - The Ministry of Economic Affairs, the wisdom of the production bureau, the consumption of the staff, Zhu Zhaoqiu, 1257973 A7 B7 2 V. Invention Description () In addition, the present invention provides for applying this non-aqueous cosmetic to moisturized skin or (please read the phonetic transcription on the back) 3 items to fill out this page) This non-aqueous cosmetic is applied to the skin as a skin warming method. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing changes in temperature of a suspension when various powders are stirred in water. BEST MODE FOR CARRYING OUT THE INVENTION X and y of the composition formula xCaO · yAl203 of the invention #5, from
充分之發熱量及發熱之持續性之觀點，及不使使用中之pH 値變過高之觀點，x/y有等於〇·5〜4.0之必要，較好 1.5 〜3.5 〇 如此之鈣鋁化物之中，自發熱量之觀點，亦以具有來自 JCPDS No· 9-413鑑定之12CaO · 7Α12〇3之X射線繞射圖案及 JCPDS No. 32-148，32_149，3 2- 150，3 3 -251，3 8- 1429 經濟部智慧財產局員工消費合作社印製 等鑑足之3CaO · Al2〇3之X射線繞射圖案之任一者之結晶 性物爲佳。又，鈣鋁化物之比表面積，爲提高與水之接觸 概率’水合速度，實現高之發熱，以1平方米/克以上爲 佳。另外，鈣鋁化物之粒徑，自水中之分散性，發熱性及 作爲適用人體之商品之使用感之觀點，平均粒徑以5 〇微米 以下，尤其〇·；!〜〗〇微米之範圍爲佳。 於本發明所用之鈣鋁化物可藉由將鈣源化合物與鋁源化 合物以使成前述所希望之作爲Ca0與Al2〇3之組成之比例混 合烺燒後，粉碎而製造。作爲此鈣源與鋁源，不論水溶性 或不落性，所有皆可使用，例如作爲鈣源化合物，可舉碳 -5- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1259773 經濟部智慧財產局員工消費合作社印製 A7 --—------~~—-------- 五、發明說明（） 酸鈣，作爲鋁源化合物，可舉氫氧化鋁等。烺燒於 5〇〇〜1600X，尤其800〜1400Χ之條件進行爲佳。 作爲本發明之溫熱劑，自上述句銘化合物照原樣或於水 中之PH値調整、分散性提高等之觀點，除上述解化合物 外亦可使用添加其他金屬氧化物、黏土礦物、砍酸鹽，其 他無機鹽、有機物、高分子、界面活性劑等而造粒者。 本發明之溫熱劑，可人合U从· ^ 1 # j 口且地作爲非水化粧料之摻合成 分，其摻合量自溫熱效果觀之，作爲前述㈣化物，以化 粒料全組成中之卜⑼重量％，作爲霜劑使用之情形，尤以 2 3 0重里/。爲佳。又’作爲粉餅劑使用之情形以2 〇〜5 〇重 量％爲佳。 本發月之非水化粧料中，p佘本發明之溫熱劑外，於化粒 料中通常摻合之其他成分，例如扣値調整劑、界面活性 劑、油劑、潤滑劑、潤濕劑、防腐劑、殺菌劑、抗菌劑、 防臭劑m脱臭劑、消炎劑、收斂劑、制汗劑、除 毛劑、抑毛劑、止血劑、鎮痛劑、維生素及其衍生物、整 合劑、黏度調整劑、皮膜劑、黏著劑、發泡劑、清涼劑、 冷感劑、金屬防銹劑、動植物萃取物、色素、抗氧化劑、 香料等，只要不妨礙本發明效果，皆可適宜地接合。又， 於本發月之「非水」，意即實質上無捧合水，但只要藉由 與水之接觸，掺合之溫熱劑得以幻起發熱即可，混入多少 水皆可。 作馬本發明i非水化粧料之劑形，並無特別限制，自易 於適用於皮膚、易於延伸之點，以掺合液狀基劑之含觸變 -6- (請先閱讀背面之注意事項再填寫本頁) ---11111 訂--— — — — — — — 本紙張尺度適用中國國家標準（CNS)A4規格（21^ 297公釐） 1259773 A7 B7 五、發明說明（ 之凝膠狀之液狀劑形爲佳。 丄作爲如此之液狀基劑，以甘油、丙二醇、丁二醇、乙二 (請先閱讀背面之注意事項再填寫本頁) 醇一乙醚、山梨糖醇、聚乙二醇等， 一 > ,、 予守万；至溫液狀之1價或 夕價I醇爲佳。該液狀基劑以非水化粒料中之卜Μ重旦 %，尤其2 - 8 0重量％掺合爲佳。 里 又，本發明之非水化粧料中 ，馬賦予通當黏性，或使本 發明之溫熱劑之分散性提高，可將合 、 ^ 匕土寺I黏土礦物以全 組成中之5〜60重量％，尤並$〜舌旦0/ t. 几，、5 3 0重量％，將羥丙基纖維 素、丙烯酸、甲基丙烯酸共聚物、瓜爾膠、黃蓍膠、普魯 南（7十7 >)、聚乙烯基吡咯啶酮、聚乙烯醇等之天然、 合成、半合成水溶性高分子化合物以全組成中之〇 〇1〜5重 量％，尤其0.05〜1重量❹/❶，將矽粉、氧化鋁粉、二氧化矽 粉、石膏粉等之有機、無機系粉體以〇丨〜2 〇重量％，尤其 0.1〜10重量％捧合爲佳。 經濟部智慧財產局員工消費合作社印製 又’本發明之非水化粧料中，可適宜地掺合供調整p Η値 之ρ Η値調整劑，作爲其摻合量，化粧料全組成中之丨〜5 〇 重量％ ’尤其作爲霜劑使用之情形，以2〜3 〇重量％，作爲 粉餅劑使用之情形，以2 0〜5 0重量％爲佳。又，與鈣鋁化 物之掺合量之比可任意選擇，尤其自皮膚刺激性之觀點， 有必要降低p Η値之化粧料之情形，使（鈣鋁化物）··（ ρ η値 調整劑）二5 0 : 5 0〜2 0 : 8 0爲佳。作爲ρ Η値調整劑，可將 例如明礬、硫酸鋁等之無機物，擰檬酸、富馬酸、琥珀 酸、抗壞血酸等之有機物1種或2種以上組合使用。特別是 明礬、硫酸鋁、抗壞血酸，自不損害發熱性之觀點，作爲 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1259773 A7 B7 發明說明（） pH値調整劑爲佳。又’ pH値調整劑，自化粒料中之八 性之觀點’平均粒徑使成5 〇微米以下爲佳。 月 (請先閱讀背面之注意事項再填寫本頁) 另外，本發明之非水化粒料，爲提高清淨效果 .面活性劑及粉體等，又爲提高使用後之觸感或除去性能，1 可將油劑等其他化粧料成分適宜地摻合。例如提高觸咸使 用砍酮油等，提高除去性能可使用液體㈣、礦脂、相 油、酯油、、橄欖油、荷荷芭（示示油等。其摻合量， 自發熱性之觀點，以化粧料全組成中之〇〇丨〜3 〇重量％爲 佳。 ” 本發明您此非水化粧料，例如適用於潤濕之皮膚，則與 水接觸藉由水合發熱可得適度之溫感，發揮良好之按摩效 果及清潔效果。 實施例 於以下之實施例，結晶之平均粒徑，使用乙醇爲分散媒 以（公司）堀場製作所製「雷射繞射/散射式粒度分布測定裝 置L A - 7 0 0」測定。 實施例1 經濟部智慧財產局員工消費合作社印製 將氫氧化鋁（昭和電工社製H1 0)122克與碳酸鈣（神島化 學工業社製輕質碳酸鈣）238克混合，於1250 °C烺燒4小 時。將所得烺燒物粉碎，使通過4〇〇網目篩。所得粉末爲 白色，CaO與Al2〇3之組成比x/y爲3/1，X射線繞射圖案相 當於JCPDS No. 3 8-1429者。又，其平均粒徑爲5微米， BET比表面積爲6.6平方米/克。 實施例2 8- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1259773 A7 B7 6 - 五、發明說明（） (請先閱讀背面之注咅？事項再填寫本頁) 將氫氧化銘（昭和電工射H4 2) 170克與實施例同樣之 CaCCb 190克混合，於13〇(rc烺燒4小時。粉碎所得之煅燒 物’使通過400網目篩。所得粉末爲白色，Ca0與a12〇3之 組成比x/y爲12/7，X射線繞射圖案相當於jCPDS No. ΡΑΠ 者 。又， 其平均 粒徑爲 13 微米， bet 比表 面積爲 5.5 平 方米/克。 實施例3 將於實施例2所得之鈣鋁化物丨〇〇克懸浮於4〇〇克離子交 換水’將水合物於600。〇再煅燒2小時。粉碎所得烺燒物， 使通過400網目篩。所得粉末爲白色，X射線繞射圖案與實 施例2者比較’含許多背景部分，相當於JCpDs N〇. 9-413 者。又’其平均粒徑爲28微米，BET比表面積爲33平方米 /克。 試驗例1 實施例1〜3所得之鈣鋁化物之發熱性與ρ η値之測定依下 示方法進行。又，作爲比較例，使用無水之4Α型沸石（比 較例1 ;平均粒徑2微米，BET比表面積5.0平方米/克）及生 石灰（比較例2 ;平均粒徑1 2微米，BET比表面積0.5平方米 /克）。 經濟部智慧財產局員工消費合作社印製 (試驗方法） 將實施例所得之鈣鋁化物粉末或比較例之粉末，於室溫 下’投入離子交換水4 〇克，一面禮拌，一面藉由熱電偶測The viewpoint of sufficient heat and the persistence of heat generation, and the viewpoint that the pH in use is not excessively high, x/y has the necessity of 〇·5 to 4.0, preferably 1.5 to 3.5 〇 such calcium aluminide Among them, the viewpoint of spontaneous heat is also X-ray diffraction pattern with 12CaO · 7Α12〇3 from JCPDS No. 9-413 and JCPDS No. 32-148, 32_149, 3 2- 150, 3 3 -251 , 3 8- 1429 The Crystallization of any of the X-ray diffraction patterns of 3CaO · Al2〇3, which is printed by the Ministry of Economic Affairs, the Intellectual Property Office, and the Consumer Cooperatives. Further, the specific surface area of the calcium aluminide is a hydration speed to increase the probability of contact with water, and it is preferable to achieve a high heat generation of 1 m square / gram or more. In addition, the particle size of the calcium aluminide, the dispersibility from the water, the heat generation, and the use feeling of the product suitable for the human body, the average particle diameter is 5 〇 micrometer or less, especially 〇·; good. The calcium aluminide used in the present invention can be produced by pulverizing the calcium source compound and the aluminum source compound by mixing and calcining the above-mentioned desired ratio of the composition of Ca0 and Al2〇3. As the calcium source and aluminum source, all of them can be used regardless of water solubility or non-falling property, for example, as a calcium source compound, carbon-5- This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 public) PCT) 1259773 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 ---------~~--------- V. Description of invention () Calcium acid, as an aluminum source compound, can be cited Aluminum hydroxide and the like. It is better to carry out the conditions of 5〇〇~1600X, especially 800~1400Χ. As the warming agent of the present invention, in addition to the above-mentioned solution compound, other metal oxides, clay minerals, and chopped acid salts may be used in addition to the above-mentioned compound of the above-mentioned compound or the pH adjustment in water and the improvement of dispersibility. , other inorganic salts, organic substances, polymers, surfactants, etc. and granulators. The warming agent of the present invention can be used as a blending component of a non-aqueous cosmetic material, and the blending amount thereof is obtained from the above-mentioned (four) compound as a chemical pellet. In the whole composition, (9)% by weight, used as a cream, especially 260 cc. It is better. Further, it is preferable to use it as a powder cake in an amount of 2 〇 to 5 〇 by weight. In the non-aqueous cosmetic of the present month, in addition to the warming agent of the present invention, other components usually blended in the granulated material, such as a buckle adjuster, a surfactant, an oil agent, a lubricant, and a wetting agent. Agent, preservative, bactericide, antibacterial agent, deodorant m deodorant, anti-inflammatory agent, astringent, sweating agent, hair removal agent, hair suppressant, hemostatic agent, analgesic, vitamin and its derivatives, integrator, A viscosity adjusting agent, a filming agent, an adhesive, a foaming agent, a cooling agent, a cooling agent, a metal rust inhibitor, an animal and plant extract, a coloring matter, an antioxidant, a fragrance, and the like can be suitably joined as long as the effects of the present invention are not impaired . Moreover, the "non-water" in this month means that there is essentially no water in the water, but as long as it is in contact with water, the blended warming agent can be heated up and heated, and it is possible to mix as much water as possible. The dosage form of the present invention is not particularly limited, and is suitable for application to the skin and easy to extend, to incorporate a liquid-based base containing a thixotropic-6- (please read the back of the note first) Matters fill out this page) ---11111 Order --- — — — — — — — This paper scale applies to China National Standard (CNS) A4 specification (21^297 mm) 1259773 A7 B7 V. Invention Description (The gel The liquid form of the form is preferred. As such a liquid base, glycerin, propylene glycol, butylene glycol, and ethylene (please read the following on the back of the page) Alcohol monoethyl ether, sorbitol, Polyethylene glycol, etc., one, and 10,000; to the warm liquid 1 or valence I alcohol is preferred. The liquid base is in the non-hydrated pellets. 2 - 80% by weight is preferably blended. In addition, in the non-aqueous cosmetic of the present invention, the horse imparts a proper viscosity, or the dispersibility of the warming agent of the present invention is improved, and the Temple I clay minerals in the total composition of 5~60% by weight, especially $~ tongue density 0/t. Several, 530% by weight, hydroxypropyl cellulose, propylene , natural, synthetic, semi-synthetic water-soluble polymer compounds such as methacrylic acid copolymer, guar gum, tragacanth, pluron (7:7 >), polyvinylpyrrolidone, polyvinyl alcohol, etc. 1 to 5 wt%, especially 0.05 to 1 wt%/❶ in the total composition, and organic or inorganic powders such as tantalum powder, alumina powder, cerium oxide powder, gypsum powder, etc. 〇丨~2 〇 The weight%, especially 0.1~10% by weight, is better. The Ministry of Economic Affairs, the Intellectual Property Bureau, the employee consumption cooperative, and the 'non-aqueous cosmetic of the present invention, can be blended appropriately for adjustment p Η値 ρ Η値 adjustment As the blending amount, 丨~5 〇% by weight in the total composition of the cosmetic material', especially when used as a cream, in the case of 2~3 〇% by weight, used as a powder cake, to 2 0~5 0 The weight % is preferable. Further, the ratio of the amount of the calcium aluminide blended can be arbitrarily selected, and in particular, from the viewpoint of skin irritation, it is necessary to lower the condition of the cosmetic material of p , to make (calcium aluminide)·( ρ η値 adjuster) two 50: 5 0~2 0 : 8 0 is preferred. As a ρ Η値 adjuster For example, an inorganic substance such as alum or aluminum sulfate, or an organic substance such as citric acid, fumaric acid, succinic acid or ascorbic acid may be used in combination of two or more kinds, in particular, alum, aluminum sulfate, and ascorbic acid, which do not impair heat generation. The point of view, as the paper scale applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1259773 A7 B7 Description of the invention () pH 値 adjuster is better. Also 'pH 値 adjuster, self-chemical pellets The octagonal point of view 'average particle size is preferably less than 5 〇 micron. Month (please read the back of the note before filling this page) In addition, the non-hydrated granules of the present invention, in order to improve the cleansing effect. And powder, etc., in order to improve the touch or removal performance after use, 1 other cosmetic ingredients such as oil can be suitably blended. For example, it is possible to use liquid (4), petrolatum, phase oil, ester oil, olive oil, jojoba (showing oil, etc.) in order to improve the removal performance by using chopped ketone oil, etc. The blending amount, self-heating property, It is better to use ～3 〇% by weight of the total composition of the cosmetic material. ” The non-aqueous cosmetic material of the present invention, for example, for moisturizing skin, is in contact with water, and a moderate temperature is obtained by hydration heat. In order to achieve a good massage effect and a cleaning effect in the following examples, the average particle size of the crystals in the following examples, using the ethanol as a dispersing medium, the "laser diffraction/scattering particle size distribution measuring device LA" manufactured by the company Measured by the Ministry of Economic Affairs, the Ministry of Economic Affairs, the Intellectual Property Office, and the Consumers' Cooperatives, which produced 122 grams of aluminum hydroxide (H1 0, manufactured by Showa Denko Co., Ltd.) and 238 g of calcium carbonate (light calcium carbonate manufactured by Shendao Chemical Industry Co., Ltd.). The mixture was calcined at 1250 ° C for 4 hours. The obtained calcined material was pulverized and passed through a 4 〇〇 mesh sieve. The obtained powder was white, and the composition ratio x/y of CaO to Al 2 〇 3 was 3/1, X-ray diffraction. The pattern is equivalent to JCPDS No. 3 8-1429. It has an average particle size of 5 μm and a BET specific surface area of 6.6 m 2 /g. Example 2 8- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1259773 A7 B7 6 - V. Explanation of the invention () (Please read the note on the back first and then fill out this page). 170 mg of Hydroxide (Showa Denko H4 2) is mixed with 190 g of the same CaCCb as the example, at 13 〇 (rc烺 4 The pulverized calcined product was passed through a 400 mesh sieve. The obtained powder was white, the composition ratio of Ca0 to a12〇3 was 12/7, and the X-ray diffraction pattern was equivalent to jCPDS No. 。. The average particle size was 13 μm and the specific surface area of bet was 5.5 m 2 /g. Example 3 The calcium aluminide obtained in Example 2 was suspended in 4 g of ion-exchanged water. The crucible was calcined for 2 hours. The obtained calcined material was pulverized and passed through a 400 mesh sieve. The obtained powder was white, and the X-ray diffraction pattern was compared with that of Example 2, which contained many background portions, which corresponded to JCpDs N〇. 9-413 And 'the average particle size is 28 microns, and the BET specific surface area is 33 M./g. Test Example 1 The calcination of the calcium aluminide obtained in Examples 1 to 3 and the measurement of ρ η 依 were carried out according to the following methods. Further, as a comparative example, anhydrous 4 Α type zeolite was used (Comparative Example 1; average 2μm particle size, BET specific surface area 5.0m2/g) and quicklime (Comparative Example 2; average particle size 12 μm, BET specific surface area 0.5 m 2 /g). Printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative (test Method) The calcium aluminide powder obtained in the examples or the powder of the comparative example was put into ion-exchanged water at a temperature of 4 g at room temperature, while being mixed by a thermocouple.
足懸浮液之水溫上升。又，攪拌10分後測定懸浮液之pH 値0 -9- 本紙張尺度適用中國國家標準（CNS)A4規格（21〇 x 297公釐） 739 5 2The water temperature of the foot suspension rises. Also, after stirring for 10 minutes, determine the pH of the suspension. 値0 -9- This paper scale applies to the Chinese National Standard (CNS) A4 specification (21〇 x 297 mm) 739 5 2
t明說明（ (結果） 、圖1表示發熱曲線。實施例i〜3中任一者之鈣鋁化物與比 較例1之無水沸石比較，明白皆具高發熱性與發熱之持續 性。又，比較例2之生石灰，發熱溫度過度上升，作爲化 粒料用溫熱劑使用並不適合。 又，揽拌1 0为後之p Η値，示於表！。本發明之實施例 1〜3中任一者之鈣鋁化物，與比較例2之生石灰比較，明白 皆呈低之pH値。 (請先閱讀背面之注意事項再填寫本頁) --- --訂--------- 經濟部智慧財產局員工消費合作社印製 實施例4 按摩化粒料 (成分） (重量 鈣鋁化物（實施例1) 20.0 聚乙二醇（重量平均分子量2000) 8.0 聚乙二醇（重量平均分子量200 ) 10.0 丙二醇 餘額 微粒氧化鋁（比表面積1〇〇平方米/克， 10 攪拌10分後之pH値 實施例1 11.8 實施例2 11.3 實施例3 11.3 比較例1 11.6 比較例2 12.5 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1259773 A7 B7 8五、發明說明（） 經濟部智慧財產局員工消費合作社印製 一次粒徑1 3毫微米） 2.0 羥丙基纖維素 1.0 陶土 10.0 實施例5 清潔劑 (成分） (重量％) 鈣鋁化物（實施例2 ) 25.0 甘油 5.0 1，3_ 丁二醇 15.0 聚乙二醇400 餘額 丙晞酸·甲基丙晞酸系共聚物 (佩母廉b >)TR-1, B.F.古 得里奇（夂v卜、W v千）公司製 0.5 十二羧醯胺丙基甜菜鹼 0.5 十二後酸抑 0.5 氯化鈉 5.0 實施例6 粉餅化粧料 (成分） (重量％) 鈣鋁化物（實施例3 ) 10.0 1，3 - 丁二醇 餘額 二丙二醇 20.0 甘油 5.0 微粒氧化鋁（比表面積100平方米/克， 一次粒徑1 3毫微米） 10.0 二甲基聚矽氧烷[6平方米/秒（25。(：）] 2.0 ；—---------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1259773 A7 B7 五、發明說明（） 聚氧乙埽·甲基聚矽氧烷共聚物 3.〇 產業上之利用可能性 如上地’於本發明使用之_銘化物，與從來之無水沸石 比較，具鬲發熱性，又，與生石灰比較，使用中之pH値亦 =抑制、攸而，以此爲主成分之本發明之溫熱劑，適宜 馬摻合於護膚、護臉、護髮、護齒、脱臭、除毛、脱毛等 之用途使用之非水化粧料之溫熱劑。 (請先閱讀背面之注意事項再填寫本頁} •I I I I I I丨丨丨丨丨丨丨丨丨丨丨丨丨 經濟部智慧財產局員工消費合作社印製 2 準 標 家 國 國 中 用 適 度 張 紙 本 釐 公 97 一 2 X 10 2 /V 格 規The description shows ((Results), Fig. 1 shows the heat generation curve. The calcium aluminide of any of Examples i to 3 is compared with the anhydrous zeolite of Comparative Example 1, and it is understood that both have high heat build-up and persistence of heat generation. In the quicklime of Comparative Example 2, the heat generation temperature was excessively increased, and it was not suitable as a warming agent for the granulated pellets. Further, the mixture of 10 and 10 was shown in Table 1-3. In the examples 1 to 3 of the present invention, The calcium aluminide of either of them is lower than the quicklime of Comparative Example 2. It is understood that the pH is low. (Please read the notes on the back and fill out this page) --- ----- -- Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Example 4 Massaged pellets (ingredients) (weight calcium aluminide (Example 1) 20.0 polyethylene glycol (weight average molecular weight 2000) 8.0 polyethylene glycol (weight Average molecular weight 200) 10.0 Propylene glycol balance particulate alumina (specific surface area 1 〇〇 square meter / gram, 10 pH after stirring for 10 minutes Example 1 11.8 Example 2 11.3 Example 3 11.3 Comparative Example 1 11.6 Comparative Example 2 12.5 The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1259773 A7 B7 8 V. Invention description () Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed primary particle size 1 3 nm) 2.0 Hydroxypropyl cellulose 1.0 Clay 10.0 Example 5 Cleaner (ingredient) (% by weight) Calcium aluminide (Example 2) 25.0 Glycerin 5.0 1,3 - Butanediol 15.0 Polyethylene glycol 400 Balance Propionate/Methylpropionic acid copolymer (Peimulian b >) TR- 1, BF Goodrich (夂v Bu, W v thousand) company made 0.5 dodecyl propyl propyl propyl betaine 0.5 12 after acid suppression 0.5 sodium chloride 5.0 Example 6 powder cake cosmetics (ingredients) (weight %) Calcium aluminide (Example 3) 10.0 1,3 - Butanediol balance Dipropylene glycol 20.0 Glycerol 5.0 Particulate alumina (specific surface area 100 m 2 /g, primary particle size 1 3 nm) 10.0 Dimethyl polyfluorene Oxytomane [6 square meters / sec (25. (:)] 2.0; ----------- loaded -------- order --------- (please read first Note on the back side of this page) This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1259773 A7 B7 V. Invention Description () Ethylene-methyl polyoxyalkylene copolymer 3. The industrial use possibility As above, the intrinsic compound used in the present invention has a heat-producing property compared with the anhydrous zeolite, and, in comparison with quicklime, The pH 値 in use is also suppressed, 攸, and the main component of the warming agent of the present invention is suitable for use in skin care, face protection, hair care, tooth care, deodorization, hair removal, hair removal, etc. A non-aqueous cosmetic warming agent used. (Please read the notes on the back and fill out this page again) • IIIIII丨丨丨丨丨丨丨丨丨丨丨丨丨Intellectual Property Bureau of the Ministry of Economic Affairs, employee consumption cooperatives, printing 2 Public 97 one 2 X 10 2 /V grid