JP3667503B2 - Skin cosmetics - Google Patents

Skin cosmetics Download PDF

Info

Publication number
JP3667503B2
JP3667503B2 JP22935097A JP22935097A JP3667503B2 JP 3667503 B2 JP3667503 B2 JP 3667503B2 JP 22935097 A JP22935097 A JP 22935097A JP 22935097 A JP22935097 A JP 22935097A JP 3667503 B2 JP3667503 B2 JP 3667503B2
Authority
JP
Japan
Prior art keywords
weight
skin
agent
chloride
sulfate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP22935097A
Other languages
Japanese (ja)
Other versions
JPH1160460A (en
Inventor
光利 木村
勝彦 竹内
穣 渡邊
哲朗 神谷
秀一 土屋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP22935097A priority Critical patent/JP3667503B2/en
Publication of JPH1160460A publication Critical patent/JPH1160460A/en
Application granted granted Critical
Publication of JP3667503B2 publication Critical patent/JP3667503B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【0001】
【発明の属する技術分野】
本発明は、温感性能に優れた皮膚化粧料に関する。
【0002】
【従来の技術】
冬季の化粧料使用時の冷え、寒さの防止のみでなく、血行促進作用により、血行障害によるこりや痛み等の緩和、皮膚活性(賦活)化(新陳代謝促進)、更に毛穴の拡張による表皮汚れの除去性向上等を期待して、温感を付与した化粧料が開発されている。化粧料に温感を付与する方法としては、主に血行促進剤を配合する方法、温感剤を配合する方法、発熱剤を配合して皮膚上で発熱させる方法がある。
【0003】
しかしながら、血行促進剤を配合した化粧料では、効果発現が遅く、使用時の実感が不足するという欠点があった。また、温感剤を配合した化粧料は、温感効果は得られるものの、温感の初期の立ち上がりが悪く、効果の持続性等の点でも充分満足できるものではなかった。
更に、発熱剤を配合した化粧料は、発熱反応が短時間で終了するため、温感が持続しないという問題があった。
【0004】
【発明が解決しようとする課題】
従って、本発明の目的は、温感の初期の立ち上がりが良好で、十分な温感持続効果が得られるなど、温感性能に優れた皮膚化粧料を提供することにある。
【0005】
【課題を解決するための手段】
かかる実情において、本発明者らは鋭意研究を行った結果、発熱剤及び温感剤を組合わせて用いれば、発熱剤による即効的な温まり効果と、温感剤による持続的温まり効果のみならず、温感性能、特に初期の温感の立ち上がりや、持続効果が相乗的に高められた皮膚化粧料が得られることを見出し、本発明を完成した。
【0006】
すなわち、本発明は、次の成分(a)〜(d):
(a)発熱剤20〜40重量%、
(b)温感剤0.01〜10重量%、
(c)タルク、セリサイト、マイカ、カオリン及びシリコーン樹脂から選ばれる粉体5〜25重量%、
(d)シリコーン油1〜10重量%、
を含有する、水で濡れた肌に塗布して使用する皮膚化粧料を提供するものである。
【0007】
【発明の実施の形態】
本発明で用いられる発熱剤としては、特に制限されないが、無機塩の無水物及び水和物などが挙げられ、具体的には、塩化カルシウム、塩化マグネシウム、塩化アルミニウム、塩化第二鉄、塩化亜鉛等の塩化物;硫酸マグネシウム、硫酸亜鉛、硫酸第一鉄、硫酸アルミニウム、硫酸カルシウム等の硫酸塩;その他乾燥ミョウバン、酸化カルシウム、炭酸ナトリウム、リン酸水素ナトリウム、活性化ゼオライト、炭酸カリウム等や、これらの含水塩などが挙げられる。
これらのうち、特に塩化カルシウム、硫酸マグネシウム、活性化ゼオライト、炭酸カリウムが好ましい。
【0008】
これらの発熱剤は、1種又は2種以上を組合わせて用いることができ、その配合量は、全組成中に20〜40重量%配合すると、十分な温かさが得られるので好ましい。
【0009】
本発明で用いられる温感剤としては、通常化粧料に配合されるものであれば特に制限されず、例えば唐辛子末、唐辛子チンキ、唐辛子エキス、カンタリスチンキ、ショウキョウ(生姜)エキス、ショウキョウチンキ、イチョウエキス、チンピエキス、トウヒエキス、センキュウエキス、トウキエキス等;ノニル酸バニリルアミド(合成カプサイシン);ニコチン酸ベンジル、ニコチン酸メチル、ニコチン酸アミド等のニコチン酸類;dl−α−トコフェロール類、酢酸dl−α−トコフェロール、ニコチン酸dl−α−トコフェロール等のトコフェロール類;サリチル酸メチル等のサリチル酸類;4−(ブトキシメチル)−2−エトキシフェノール、ブチル−〔(3,4−ジメトキシ)ベンジル〕エーテル、ブチル−〔(3,4−メチレンジオキシ)ベンジル〕エーテル、5−(ブトキシメチル)−2−メトキシフェノール、4−〔(2−エチルヘキシルオキシ)メチル〕−2−メトキシフェノール、2−メトキシ−4−〔(2−メトキシエトキシ)メチル〕フェノール等のイソバニリン誘導体;カプサイシン、ショウガオール、ピペリン、カンフル、メントール、下記一般式(1)で表わされるバニリルアルコールアルキルエーテル等が挙げられる。
【0010】
【化2】

Figure 0003667503
【0011】
〔式中、R1 は炭素数1〜6のアルキル基を示す〕。
【0012】
上記一般式(1)中、R1 で示される炭素数1〜6のアルキル基としては、直鎖又は分岐鎖いずれのアルキル基も挙げられ、例えばメチル基、エチル基、n−プロピル基、イソプロピル基、n−ブチル基、イソブチル基、sec−ブチル基、tert−ブチル基、n−アミル基、イソアミル基、n−ヘキシル基等が挙げられる。このうち、エチル基、n−プロピル基、n−ブチル基、n−アミル基、イソアミル基又はn−ヘキシル基が特に好ましく、n−ブチル基がことさら好ましい。
【0013】
温感剤としては、このうち、唐辛子末、唐辛子チンキ、唐辛子エキス、ショウキョウエキス、ショウキョウチンキ、ノニル酸バニリルアミド、4−(ブトキシメチル)−2−エトキシフェノール、ブチル−〔(3,4−ジメトキシ)ベンジル〕エーテル、ブチル−〔(3,4−メチレンジオキシ)ベンジル〕エーテル、5−(ブトキシメチル)−2−メトキシフェノール、4−〔(2−エチルヘキシルオキシ)メチル〕−2−メトキシフェノール、2−メトキシ−4−〔(2−メトキシエトキシ)メチル〕フェノール、カプサイシン、ショウガオール、バニリルアルコールアルキルエーテル(1)が特に好ましい。
【0014】
これらの温感剤は、1種又は2種以上を組合わせて用いることができ、その配合量は、全組成中に0.01〜10重量%、特に0.05〜5重量%が好ましい。
【0015】
本発明の皮膚化粧料には、更に粉体を配合することができる。かかる粉体としては、タルク、セリサイト、マイカ、カオリン、シリコーン樹脂が肌での感触が良好であることから、本発明の皮膚化粧料には特に好ましい。
【0016】
かかる粉体の形状は特に限定されず、平板状、塊状、鱗片状、球状等のいずれであってもよいが、平板状、鱗片状、球状等の粉体が皮膚感触を高める上で特に好ましい。
【0017】
これらの粉体は、使用感を高める上から、平均粒径が0.1〜15μmのものを用いるのが好ましく、平均粒径が1〜10μmのものが特に好ましい。平均粒径が小さすぎると皮膚のさらさら感が得られないことがあり、一方大きすぎるとざらざら感が生じることがある。
【0018】
これらの粉体の配合量は、本発明の化粧料中5〜25重量%が使用感の点から特に好ましい。
【0019】
本発明の皮膚化粧料には、更に油性物質を配合することができる。
【0020】
油性物質としては、使用感を高める上から、25℃における表面張力が30dyn/cm以下の油性物質の1種又は2種以上を配合することが好ましい。このような油性物質としては、シリコーン油が挙げられ、具体的にはメチルポリシロキサン、ジメチルポリシロキサン、メチルシクロポリシロキサン、ジエチルポリシロキサン、メチルフェニルポリシロキサン、脂肪酸変性ポリシロキサン、高級アルコール変性ポリシロキサン、アミノ変性ポリシロキサンが挙げられる。これらの中で、メチルポリシロキサン、ジメチルポリシロキサンが特に好ましく、25℃における粘度が200センチストークス(cs)以下のものが使用感をより高める点から特に好ましい。
【0021】
表面張力が30dyn/cm以下の油性物質は、全組成中に1〜10重量%配合することが特に好ましい。
【0022】
これらの油性物質と前記粉体との配合比は、粉体の皮膚上への残存率を高める点から、重量比で1:20〜20:1、特に1:1〜1:10が好ましい。
【0023】
本発明の皮膚化粧料にはアルコール類を配合することができる。アルコール類としては、エチルアルコール、プロピレングリコール、1,3−ブチレングリコール、グリセリン、ソルビトールなどが好ましい例として挙げられ、これらは1種を単独で用いても2種以上を混合して用いてもよい。これらのアルコール類の配合量は、使用感の点から0.1〜30重量%が好ましく、1〜20重量%が特に好ましい。
【0024】
更に本発明の皮膚化粧料には、生理的に有効な保湿成分、抗炎症剤、美白剤、UVケア剤、殺菌剤、制汗剤、香料等を配合することもできる。保湿成分としては、グリセリン、乳酸、セラミド、コレステリルエステルなどが挙げられる。保湿剤の配合量は本発明化粧料中0.1〜40重量%が好ましく、1〜10重量%が使用感の点から好ましい。
【0025】
抗炎症剤としては、グリチルリチン酸塩、β−グリチルレチン酸、アラントイン、インドメタシン、グアイアズレン、グアイアズレンスルホン酸塩、生薬抽出液、薬草エキスなどが挙げられる。配合量は本発明化粧料中0.01〜10重量%が好ましく、特に0.1〜2重量%が効果の点から好ましい。
【0026】
美白剤、UVケア剤としてはビタミンC誘導体(アスコルビン酸リン酸エステルマグネシウムなど)、アルブチン、コウジ酸、カミツレエキス、パーソールMCX、エスカロール507、オキシベンゾン、ユビナール、などが挙げられる。配合量は本発明化粧料中0.01〜10重量%が好ましく、特に0.1〜5重量%が効果の点から好ましい。
【0027】
殺菌剤としては、塩化ベンザルコニウム、塩化ベンゼトニウム、トリクロロカルバミド、塩化セチルピリジニウム、イソプロピルメチルフェノールなどが挙げられる。配合量は本発明化粧料中0.01〜5重量%が好ましく、特に0.1〜1重量%が効果の点から好ましい。
【0028】
制汗剤の例としては、塩化アルミニウム、クロロヒドロキシアルミニウム、乳酸アルミニウム、アラントインアルミニウム誘導体、p−フェノールスルホン酸亜鉛などが挙げられる。配合量は本発明化粧料中0.01〜10重量%が好ましく、特に0.05〜5重量%が効果の点から好ましい。
【0029】
更に、本発明の皮膚化粧料には、温感剤の刺激を緩和する目的で清涼剤を配合してもよい。清涼剤の例としては、l−メントール、薄荷油、カンフルなどが挙げられる。配合量は本発明化粧料中0.01〜5重量%が好ましく、特に0.01〜1重量%が効果の点から好ましい。
【0030】
本発明の皮膚化粧料は全身に塗布しやすくするため、製剤の粘度は、常温で100〜3000センチストークスであることが好ましい。
【0031】
本発明の皮膚化粧料は、常法に従って上記成分を混合することにより製造することができる。
なお、本発明の皮膚化粧料は、発熱剤が水和反応により発熱するため、実質的に水を含有しない非水系の剤型として、使用時に水と混合して使用することができ、また発熱剤を含有する非水系のものを使用時に水を含む系と混合して用いる2剤式の形態とすることもできる。2剤式の場合には、温感剤はいずれの系にも配合することができる。
【0032】
本発明の皮膚化粧料は、例えば化粧水、乳液、クリーム、パウダー、ハップ剤、パック剤、マッサージ剤、ペースト剤等のあらゆる化粧品形態をとることができ、使用部位や使用場面にあわせて種々の使用形態とすることができる。
【0033】
本発明の皮膚化粧料は、非水系の剤型のものを水で濡れた肌に塗布して使用すると、発熱剤が皮膚上の水と反応して発熱するため、簡便に使用することができ好ましい。
本発明の皮膚化粧料を濡れ肌用として使用する方法としては、入浴やシャワー後の濡れた肌に塗布後、そのまま乾燥させる方法、濡れた肌に塗布後、タオルドライする方法、塗布後、浴水やシャワー水で洗い流し、タオルドライする方法などが好ましい。
【0034】
【発明の効果】
本発明の皮膚化粧料は、発熱剤による即効的な温まり効果と、温感剤による持続的温まり効果のみならず、温感の初期の立ち上がりや、持続効果などの温感性能が相乗的に高められたものである。
【0035】
【実施例】
以下、本発明を詳細に説明するが、本発明はこれらの実施例に限定されるものではない。
【0036】
実施例1〜4及び比較例1〜3
表1に示す組成の皮膚化粧料を常法により製造し、その温感性能を評価した。結果を表2に示す。
【0037】
(評価方法)
各皮膚化粧料50gを浴後の濡れた肌に塗布し、塗布直後、5分後、10分後及び30分後の温感を以下の基準で官能評価した。
<評価基準>
○;十分な暖かさを感じる。
△;やや暖かさを感じる。
×;暖かさを感じない。
【0038】
【表1】
Figure 0003667503
【0039】
【表2】
Figure 0003667503
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a skin cosmetic excellent in warm feeling performance.
[0002]
[Prior art]
Not only the prevention of cold and cold when using cosmetics in winter, but also blood circulation promotion action, alleviation of stiffness and pain due to blood circulation disorder, skin activation (activation) (promoting metabolism), and further skin epidermal stains by expanding pores Cosmetics with a warm feeling have been developed with the expectation of improved removability. As a method for imparting warmth to cosmetics, there are mainly a method of blending a blood circulation promoter, a method of blending a warming agent, and a method of blending a heat-generating agent and generating heat on the skin.
[0003]
However, cosmetics formulated with a blood circulation promoter have the drawbacks that the effect is slow and the actual feeling during use is insufficient. Moreover, although the cosmetics which mix | blended the warming agent were able to obtain warmth effect, the initial rise of warmth was bad and it was not fully satisfactory also in terms of the sustainability of an effect, etc.
Furthermore, cosmetics containing exothermic agents have a problem that warmth does not last because the exothermic reaction is completed in a short time.
[0004]
[Problems to be solved by the invention]
Accordingly, an object of the present invention is to provide a skin cosmetic excellent in warm feeling performance such that the initial rise of warm feeling is good and a sufficient warm feeling sustaining effect is obtained.
[0005]
[Means for Solving the Problems]
In such a situation, the present inventors have conducted intensive research. As a result, when a combination of a heat generating agent and a warming agent is used, not only an immediate warming effect by the heat generating agent and a continuous warming effect by the warming agent. Thus, the present inventors have found that a skin cosmetic with synergistically enhanced warming performance, particularly the initial warming and sustaining effect, has been completed.
[0006]
That is, the present invention includes the following components (a) to (d):
(A) exothermic agent 20-40% by weight,
(B) 0.01-10% by weight of a warming agent,
(C) 5 to 25% by weight of a powder selected from talc, sericite, mica, kaolin and silicone resin,
(D) 1 to 10% by weight of silicone oil,
The skin cosmetics which apply | coat and use on the skin wetted with water are provided.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
The exothermic agent used in the present invention is not particularly limited, and examples thereof include inorganic salt anhydrides and hydrates, and specifically include calcium chloride, magnesium chloride, aluminum chloride, ferric chloride, and zinc chloride. Chlorides such as magnesium sulfate, zinc sulfate, ferrous sulfate, aluminum sulfate, calcium sulfate, etc .; other dried alum, calcium oxide, sodium carbonate, sodium hydrogen phosphate, activated zeolite, potassium carbonate, etc. These hydrated salts are exemplified.
Of these, calcium chloride, magnesium sulfate, activated zeolite, and potassium carbonate are particularly preferable.
[0008]
These exothermic agents can be used singly or in combination of two or more, and the blending amount thereof is preferably 20 to 40% by weight in the total composition because sufficient warmth can be obtained.
[0009]
The warming sensation agent used in the present invention is not particularly limited as long as it is usually blended into cosmetics. For example, chili powder, chili tincture, chili extract, cantalis tincture, ginger extract, gyoza Tincture, ginkgo biloba extract, tinpipe extract, spruce extract, senkyu extract, toki extract, etc .; nonylic acid vanillylamide (synthetic capsaicin); nicotinic acid such as benzyl nicotinate, methyl nicotinate, nicotinamide; dl-α-tocopherols, dl acetate -Tocopherols such as α-tocopherol and dl-α-tocopherol nicotinate; salicylic acids such as methyl salicylate; 4- (butoxymethyl) -2-ethoxyphenol, butyl-[(3,4-dimethoxy) benzyl] ether, Butyl-[(3,4-methylenedio B) benzyl] ether, 5- (butoxymethyl) -2-methoxyphenol, 4-[(2-ethylhexyloxy) methyl] -2-methoxyphenol, 2-methoxy-4-[(2-methoxyethoxy) methyl] Examples include isovanillin derivatives such as phenol; capsaicin, gingerol, piperine, camphor, menthol, and vanillyl alcohol alkyl ether represented by the following general formula (1).
[0010]
[Chemical formula 2]
Figure 0003667503
[0011]
[Wherein R 1 represents an alkyl group having 1 to 6 carbon atoms].
[0012]
In the general formula (1), examples of the alkyl group having 1 to 6 carbon atoms represented by R 1 include linear or branched alkyl groups such as a methyl group, an ethyl group, an n-propyl group, and isopropyl. Group, n-butyl group, isobutyl group, sec-butyl group, tert-butyl group, n-amyl group, isoamyl group, n-hexyl group and the like. Of these, an ethyl group, an n-propyl group, an n-butyl group, an n-amyl group, an isoamyl group, or an n-hexyl group is particularly preferable, and an n-butyl group is particularly preferable.
[0013]
Among them, among them, chili powder, chili tincture, chili extract, ginger extract, ginger tincture, nonylic acid vanillylamide, 4- (butoxymethyl) -2-ethoxyphenol, butyl-[(3,4- Dimethoxy) benzyl] ether, butyl-[(3,4-methylenedioxy) benzyl] ether, 5- (butoxymethyl) -2-methoxyphenol, 4-[(2-ethylhexyloxy) methyl] -2-methoxyphenol 2-methoxy-4-[(2-methoxyethoxy) methyl] phenol, capsaicin, gingerol, and vanillyl alcohol alkyl ether (1) are particularly preferred.
[0014]
These warming agents can be used alone or in combination of two or more, and the blending amount thereof is preferably 0.01 to 10% by weight, particularly 0.05 to 5% by weight in the total composition.
[0015]
The skin cosmetic of the present invention can further contain a powder. As such a powder, talc, sericite, mica, kaolin, and silicone resin are particularly preferable for the skin cosmetic of the present invention because they feel good on the skin.
[0016]
The shape of the powder is not particularly limited, and may be any of a flat plate shape, a lump shape, a scale shape, a spherical shape, and the like, but a flat plate shape, a scale shape, a spherical shape, and the like are particularly preferable for enhancing skin feel. .
[0017]
These powders preferably have an average particle diameter of 0.1 to 15 μm, and particularly preferably have an average particle diameter of 1 to 10 μm from the viewpoint of enhancing the feeling of use. If the average particle size is too small, it may not be possible to obtain a smooth feeling of the skin, while if it is too large, a rough feeling may occur.
[0018]
The blending amount of these powders is particularly preferably 5 to 25% by weight in the cosmetic of the present invention from the viewpoint of feeling of use.
[0019]
The skin cosmetic composition of the present invention can further contain an oily substance.
[0020]
As the oily substance, it is preferable to add one or more oily substances having a surface tension at 25 ° C. of 30 dyn / cm or less in order to enhance the feeling of use. Examples of such oily substances include silicone oils. Specifically, methylpolysiloxane, dimethylpolysiloxane, methylcyclopolysiloxane, diethylpolysiloxane, methylphenylpolysiloxane, fatty acid-modified polysiloxane, higher alcohol-modified polysiloxane. And amino-modified polysiloxane. Among these, methylpolysiloxane and dimethylpolysiloxane are particularly preferable, and those having a viscosity at 25 ° C. of 200 centistokes (cs) or less are particularly preferable from the viewpoint of further enhancing the feeling of use.
[0021]
The oily substance having a surface tension of 30 dyn / cm or less is particularly preferably blended in an amount of 1 to 10% by weight in the total composition.
[0022]
The blending ratio of these oily substances and the powder is preferably 1:20 to 20: 1, particularly 1: 1 to 1:10 in terms of weight ratio from the viewpoint of increasing the residual rate of the powder on the skin.
[0023]
Alcohols can be mix | blended with the skin cosmetics of this invention. Examples of alcohols include ethyl alcohol, propylene glycol, 1,3-butylene glycol, glycerin, sorbitol and the like, and these may be used alone or in combination of two or more. . The blending amount of these alcohols is preferably from 0.1 to 30% by weight, particularly preferably from 1 to 20% by weight from the point of use feeling.
[0024]
Furthermore, physiologically effective moisturizing ingredients, anti-inflammatory agents, whitening agents, UV care agents, bactericides, antiperspirants, perfumes and the like can also be blended in the skin cosmetics of the present invention. Examples of the moisturizing component include glycerin, lactic acid, ceramide, cholesteryl ester and the like. The blending amount of the humectant is preferably 0.1 to 40% by weight in the cosmetic composition of the present invention, and preferably 1 to 10% by weight from the point of use feeling.
[0025]
Examples of the anti-inflammatory agent include glycyrrhizinate, β-glycyrrhetinic acid, allantoin, indomethacin, guaiazulene, guaiazulene sulfonate, herbal extract and herbal extract. The blending amount is preferably 0.01 to 10% by weight in the cosmetic of the present invention, and particularly preferably 0.1 to 2% by weight from the viewpoint of the effect.
[0026]
Examples of whitening agents and UV care agents include vitamin C derivatives (such as magnesium ascorbate phosphate), arbutin, kojic acid, chamomile extract, persole MCX, escalol 507, oxybenzone, and ubinal. The blending amount is preferably 0.01 to 10% by weight in the cosmetic of the present invention, and particularly preferably 0.1 to 5% by weight from the viewpoint of the effect.
[0027]
Examples of the disinfectant include benzalkonium chloride, benzethonium chloride, trichlorocarbamide, cetylpyridinium chloride, isopropylmethylphenol, and the like. The blending amount is preferably 0.01 to 5% by weight in the cosmetic of the present invention, and particularly preferably 0.1 to 1% by weight from the viewpoint of the effect.
[0028]
Examples of antiperspirants include aluminum chloride, chlorohydroxyaluminum, aluminum lactate, allantoin aluminum derivatives, zinc p-phenol sulfonate, and the like. The blending amount is preferably 0.01 to 10% by weight in the cosmetic of the present invention, and particularly preferably 0.05 to 5% by weight from the viewpoint of the effect.
[0029]
Furthermore, you may mix | blend a cooling agent with the skin cosmetics of this invention in order to relieve the irritation | stimulation of a warming agent. Examples of the refreshing agent include l-menthol, light cargo oil, camphor and the like. The blending amount is preferably 0.01 to 5% by weight in the cosmetic of the present invention, and particularly preferably 0.01 to 1% by weight from the viewpoint of the effect.
[0030]
In order to facilitate application of the skin cosmetic of the present invention to the whole body, the viscosity of the preparation is preferably 100 to 3000 centistokes at room temperature.
[0031]
The skin cosmetic of the present invention can be produced by mixing the above components according to a conventional method.
The skin cosmetics of the present invention can be used as a non-aqueous dosage form that does not substantially contain water because it is exothermic due to a hydration reaction, and can be used by mixing with water during use. A non-aqueous type containing an agent may be used in a two-part form used by mixing with a system containing water at the time of use. In the case of the two-agent type, the warming agent can be blended in any system.
[0032]
The skin cosmetic of the present invention can take any cosmetic form such as lotion, milky lotion, cream, powder, haptic agent, pack agent, massage agent, paste agent, etc. It can be used.
[0033]
The skin cosmetic composition of the present invention can be used easily because a heat generating agent reacts with water on the skin to generate heat when a non-aqueous preparation is applied to wet skin. preferable.
The method of using the skin cosmetic of the present invention for wet skin includes: a method of applying to wet skin after bathing or showering, followed by drying; a method of applying to wet skin; towel drying; A method of rinsing with water or shower water and towel drying is preferred.
[0034]
【The invention's effect】
The skin cosmetics of the present invention synergistically enhance not only the immediate warming effect by the exothermic agent and the continuous warming effect by the warming agent, but also the warming performance such as the initial rise of warmth and the sustained effect. It is what was done.
[0035]
【Example】
Hereinafter, the present invention will be described in detail, but the present invention is not limited to these examples.
[0036]
Examples 1-4 and Comparative Examples 1-3
Skin cosmetics having the composition shown in Table 1 were produced by a conventional method, and their warm feeling performance was evaluated. The results are shown in Table 2.
[0037]
(Evaluation methods)
50 g of each skin cosmetic was applied to wet skin after bathing, and the sense of warmth immediately after application, 5 minutes, 10 minutes and 30 minutes was subjected to sensory evaluation based on the following criteria.
<Evaluation criteria>
○: I feel a sufficient warmth.
Δ: A little warm.
×: I do not feel warmth.
[0038]
[Table 1]
Figure 0003667503
[0039]
[Table 2]
Figure 0003667503

Claims (3)

次の成分(a)〜(d):
(a)発熱剤20〜40重量%、
(b)温感剤0.01〜10重量%、
(c)タルク、セリサイト、マイカ、カオリン及びシリコーン樹脂から選ばれる粉体5〜25重量%、
(d)シリコーン油1〜10重量%
を含有する、水で濡れた肌に塗布して使用する皮膚化粧料。
The following components (a) to (d):
(A) exothermic agent 20-40% by weight,
(B) 0.01-10% by weight of a warming agent ,
(C) 5 to 25% by weight of a powder selected from talc, sericite, mica, kaolin and silicone resin ,
(D) 1 to 10% by weight of silicone oil ,
Skin cosmetics that contain and apply to wet skin .
発熱剤が、塩化カルシウム、塩化マグネシウム、塩化アルミニウム、塩化第二鉄、塩化亜鉛、硫酸マグネシウム、硫酸亜鉛、硫酸第一鉄、硫酸アルミニウム、硫酸カルシウム、乾燥ミョウバン、酸化カルシウム、炭酸ナトリウム、リン酸水素ナトリウム、活性化ゼオライト及び炭酸カリウムから選ばれるものである請求項1記載の皮膚化粧料。  The exothermic agent is calcium chloride, magnesium chloride, aluminum chloride, ferric chloride, zinc chloride, magnesium sulfate, zinc sulfate, ferrous sulfate, aluminum sulfate, calcium sulfate, dry alum, calcium oxide, sodium carbonate, hydrogen phosphate The skin cosmetic according to claim 1, which is selected from sodium, activated zeolite and potassium carbonate. 温感剤が、唐辛子末、唐辛子チンキ、唐辛子エキス、ショウキョウエキス、ショウキョウチンキ、ノニル酸バニリルアミド、4−(ブトキシメチル)−2−エトキシフェノール、ブチル−〔(3,4−ジメトキシ)ベンジル〕エーテル、ブチル−〔(3,4−メチレンジオキシ)ベンジル〕エーテル、5−(ブトキシメチル)−2−メトキシフェノール、4−〔(2−エチルヘキシルオキシ)メチル〕−2−メトキシフェノール、2−メトキシ−4−〔(2−メトキシエトキシ)メチル〕フェノール、カプサイシン、ショウガオール及び次の一般式(1):
Figure 0003667503
〔式中、R1は炭素数1〜6のアルキル基を示す〕で表わされるバニリルアルコールアルキルエーテルから選ばれるものである請求項1又は2記載の皮膚化粧料。
The warming sensation agent is chili powder, chili tincture, chili extract, ginger extract, ginger tincture, nonyl acid vanillyl amide, 4- (butoxymethyl) -2-ethoxyphenol, butyl-[(3,4-dimethoxy) benzyl]. Ether, butyl-[(3,4-methylenedioxy) benzyl] ether, 5- (butoxymethyl) -2-methoxyphenol, 4-[(2-ethylhexyloxy) methyl] -2-methoxyphenol, 2-methoxy -4-[(2-methoxyethoxy) methyl] phenol, capsaicin, gingerol and the following general formula (1):
Figure 0003667503
The skin cosmetic according to claim 1 or 2, which is selected from vanillyl alcohol alkyl ether represented by the formula: wherein R 1 represents an alkyl group having 1 to 6 carbon atoms.
JP22935097A 1997-08-26 1997-08-26 Skin cosmetics Expired - Lifetime JP3667503B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22935097A JP3667503B2 (en) 1997-08-26 1997-08-26 Skin cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22935097A JP3667503B2 (en) 1997-08-26 1997-08-26 Skin cosmetics

Publications (2)

Publication Number Publication Date
JPH1160460A JPH1160460A (en) 1999-03-02
JP3667503B2 true JP3667503B2 (en) 2005-07-06

Family

ID=16890794

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22935097A Expired - Lifetime JP3667503B2 (en) 1997-08-26 1997-08-26 Skin cosmetics

Country Status (1)

Country Link
JP (1) JP3667503B2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000076463A1 (en) * 1999-06-14 2000-12-21 Kao Corporation Thermal preparations
HRP20000029C1 (en) * 2000-01-18 2005-02-28 Mustapi Marina Cosmetic preparations for the skin and hair care
DE10009424A1 (en) * 2000-02-28 2001-09-06 Henkel Kgaa Use of flavone and isoflavone compounds, especially of plant origin, for the treatment of cellulite
DE10009423A1 (en) * 2000-02-28 2001-09-06 Henkel Kgaa Cosmetic or pharmaceutical preparation especially for treatment of cellulite comprises nerve fibre stimulator or depolariser, phosphodiesterase inhibitor and antiestrogen
JP2002020246A (en) * 2000-07-03 2002-01-23 Pola Chem Ind Inc Cleaning agent for pore care
FR2811557B1 (en) * 2000-07-11 2003-04-18 Oreal EXOTHERMIC COSMETIC COMPOSITION
JP2003095841A (en) * 2001-09-21 2003-04-03 Sunstar Inc Cosmetic
EP1725246A4 (en) * 2004-01-30 2009-07-15 E L Management Corp Compositions containing internally activated antioxidant
DE102006050984A1 (en) * 2006-10-26 2008-04-30 Henkel Kgaa Cosmetic agent, useful e.g. as hair treating agent, and to increase the elasticity of keratin fibers, preferably human hairs, comprises purine and/or its derivative, coolness producing substances and/or heatness producing substance
JP5312847B2 (en) * 2008-05-30 2013-10-09 株式会社マンダム Non-aqueous warm skin cleansing composition
JP5704900B2 (en) * 2010-11-17 2015-04-22 花王株式会社 Skin circulation enhancer
CN103340760B (en) * 2013-06-04 2015-11-25 金红叶纸业集团有限公司 Comprise the napkin of skin care compositions
CN103767898A (en) * 2014-01-26 2014-05-07 新疆亲努尔生物科技有限公司 Horse-oil cold-dispelling foot cream
JP1665824S (en) 2019-08-21 2020-08-11
WO2022094553A1 (en) 2020-10-27 2022-05-05 The Procter & Gamble Company Warming conditioner
USD1006632S1 (en) 2020-12-11 2023-12-05 The Procter & Gamble Company Container for hair care products
USD1012718S1 (en) 2020-12-21 2024-01-30 The Procter & Gamble Company Container for hair care product

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58113113A (en) * 1981-12-26 1983-07-05 Johnson Kk Cosmetic
JPH0723295B2 (en) * 1986-03-03 1995-03-15 鐘紡株式会社 Warm skin cosmetics
JP3101035B2 (en) * 1991-03-11 2000-10-23 株式会社コーセー Pack cosmetics
JPH09208483A (en) * 1996-01-30 1997-08-12 Kao Corp Preparation composition for external use for skin and bath agent composition
JP3595057B2 (en) * 1996-02-09 2004-12-02 花王株式会社 Sheet-shaped cosmetic composition

Also Published As

Publication number Publication date
JPH1160460A (en) 1999-03-02

Similar Documents

Publication Publication Date Title
JP3667503B2 (en) Skin cosmetics
JP5093998B2 (en) Pigmentation preventing or improving agent
JP4664750B2 (en) Self-foaming cleansing system
JP3025453B2 (en) Stable gelled composition containing electrolyte
JPH08501553A (en) Skin conditioning composition, its application and manufacture
JPH026321B2 (en)
JP2001019606A5 (en)
JP3923226B2 (en) Topical skin preparation
PL189774B1 (en) Cosmetic composition containing antiperspirant or deodorising agent and moistening cream
JP2000044430A (en) Composition in form of water-in-oil type emulsion having variable shear rate
JP5766258B2 (en) Pigmentation preventing or improving agent
JP5495810B2 (en) Non-aqueous warm skin cleansing composition
TWI324932B (en) Sugar-uptake promoting agent
CZ351198A3 (en) Local preparation for supplying skin active agents into skin, treatment method, cleaning and lightening of skin and method of reducing size of pores
JP2010511609A (en) Dual composition with warming and analgesic effects
JP2003160465A (en) Pretreatment agent for promoting transdermal absorption and make-up method using the pretreatment agent
JP2009215256A (en) Non-aqueous thermal sensation skin cleaning composition
JP2004175750A (en) Dermopathy inhibitor and dermopathy improving agent, and skin care preparation for external use containing them
JP2003183144A (en) Body odor-inhibiting composition
JP3688848B2 (en) Skin cosmetic for wet skin
JP2007191406A (en) Emulsifying agent-formed cosmetic
JP2000247860A (en) Massage cosmetic
JP5945566B2 (en) Itching agent, itching reducing composition using the same, and method for reducing itching caused by external stimulation
JP4550201B2 (en) Fever cosmetics
JP2002053425A (en) Solid water-in-oil type emulsified cosmetic

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20040812

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20040907

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20041108

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20050105

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050304

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20050405

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20050406

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090415

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090415

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100415

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110415

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120415

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130415

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130415

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140415

Year of fee payment: 9

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

EXPY Cancellation because of completion of term