JP2014005255A - Cosmetics - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide cosmetics which are completed by considering the function of an aluminate complex oxide as a cosmetic raw material, the cosmetics exhibiting excellent performance in lubricative property, adhesive property, soft focus property and the like.SOLUTION: The cosmetics contain a compound represented by CaAlO.

Description

The present invention relates to a cosmetic containing an aluminate composite oxide.

Plate powders represented by mica, sericite and talc are widely used as foundations for cosmetics mainly in foundations. The performance required for these powders is required to have smoothness as to how smoothly the foundation spreads on the skin and strong adhesion to the skin. Furthermore, in order to blur the texture of the skin surface and make the skin stains and freckles inconspicuous, particles having soft focus properties are also required.

On the other hand, compounds described in Non-Patent Document 1 and the like are known as aluminate complex oxides. These are known to be used mainly as phosphors and the like, and have not been used in the cosmetic field. Therefore, the physical properties required for use in cosmetic applications have never been studied.

Antioxidants are disclosed in Patent Document 1 to use a 12CaO · 7Al ₂ O ₃ as an active ingredient, it is described that the blending them into cosmetics. However, in this document, no consideration is given to the feeling of use, adhesion, soft focus, and the like as particles used in makeup cosmetics.

JP 2009-161728 A

2010 Mie Industrial Research Institute research report No. 35 “Synthesis and Evaluation of Manganese-doped Calcium Aluminate Red Phosphor” http://www.mpstpc.pref.mie.lg.jp/KOU/kenhou/h22/ 22a01.pdf

In view of the above, the present invention has been completed by studying the function of aluminate composite oxide as a cosmetic raw material, and a cosmetic having excellent performance in terms of lubricity, adhesion, soft focus, etc. It is to provide. Moreover, it is preferable also in the point which does not contain a heavy metal component.

The present invention is a cosmetic containing a compound represented by CaAl ₁₂ O ₁₉ .
The compound represented by the above _CaAl 12 _{O 19} is preferably 1 to 90 wt% based on the total cosmetic.
The compound represented by CaAl ₁₂ O ₁₉ preferably contains 90% or more of plate-like particles having a major axis L in the range of 6 μm to 30 μm and a minor axis S in the range of 0.1 μm to 5 μm.
The compound represented by CaAl ₁₂ O ₁₉ contains 90% or more of plate-like particles in which the ratio L / S of the major axis L to the minor axis S is in the range of 1.2 ≦ L / S ≦ 300. Is preferred.

The cosmetic of the present invention has excellent performance in terms of lubricity, adhesion, soft focus properties and the like.

2 is a drawing showing a surface SEM of aluminate composite oxide particles of Example 1. FIG.

The present invention is described in detail below.
The cosmetic of the present invention contains a compound represented by CaAl ₁₂ O ₁₉ (hereinafter referred to as “calcium aluminate”). Calcium aluminate is a compound known as a phosphor material or the like. However, the use of the compound of the present invention as a cosmetic material has not been studied and is a novel material as a cosmetic material.

In the composition of the calcium aluminate, the molar ratio represented by CaAl ₁₂ O ₁₉ is stable as a crystal.

It is particularly preferable that the compound of the present invention has a plate shape. The compound of the present invention having a plate shape has excellent performance in terms of slipperiness, adhesion, soft focus properties and the like, and therefore can be particularly suitably used as a raw material for cosmetics.

The calcium aluminate particles of the present invention preferably contain 90% or more of plate-like particles having a major axis L in the range of 6 μm to 30 μm and a minor axis S in the range of 0.1 μm to 5 μm.
By setting the major axis L to 6 μm or more, it is possible to obtain particles having good slipping, and by setting the major axis L to 30 μm or less, sufficient mechanical strength can be obtained even during processing.
Further, when the minor axis S is 0.1 μm or more, sufficient mechanical strength can be obtained even during processing, and when it is 5 μm or less, particles with good slip can be obtained.
In the present invention, 100 particles included in a photograph magnified 1000 times using a scanning electron microscope are arbitrarily selected, their major axis and minor axis are measured, and the particle diameter is within the above-mentioned range. The plate-like particles are preferably 90% or more. The plate-like particles within the above range are more preferably 95% or more.
Moreover, it is preferable that the average values of L and S measured by the method described above are each included in the numerical value range described above.

The ratio L / S of the major axis L to the minor axis S of the plate-like particles having such a particle size is preferably in the range of 1.2 ≦ L / S ≦ 300.
By setting L / S to 1.2 or more, plate-like particles having good slippage can be obtained, and by setting L / S to 300 or less, sufficient mechanical strength can be obtained even during processing.
In addition, in this specification, it is preferable that the particle | grains which L / S at the time of measuring the major axis and the minor axis measured by the method mentioned above are contained in the said range are 90% or more.
Moreover, it is preferable that L / S measured from the average value of L and S measured by the method described above is also within the numerical range described above.

The method for obtaining the calcium aluminate used in the present invention is not particularly limited, and examples thereof include a method in which a calcium precursor compound and an aluminum precursor compound are mixed and calcined at 800 ° C. to 2000 ° C. It is done.
Examples of calcium precursors include calcium carbonate and calcium hydroxide.
Examples of the aluminum precursor compound include aluminum oxide and aluminum hydroxide.
These precursor compounds described above are measured using a precision balance so as to achieve the desired composition ratio, mixed well, and then fired.

  During firing, calcium fluoride, magnesium fluoride, aluminum fluoride, ammonium fluoride, sodium chloride, potassium chloride, lithium chloride, ammonium bromide, ammonium iodide, sodium hydroxide, potassium hydroxide, ammonium sulfate, sodium sulfate, One or more compounds such as potassium sulfate, sodium nitrate, and ammonium nitrate may be used as the flux. Use of such a compound is preferable in that particles having good crystallinity can be synthesized.

When using such a flux, it is preferable to use it in a proportion of 0.01 to 10% by weight based on the weight of the calcium aluminate obtained.
By making the amount of flux 0.01% by weight or more, it is preferable in that particles with high crystallinity are obtained, and by making it 10% by weight or less, highly independent particles can be obtained without abnormal binding. This is preferable.

The mixing method of these precursor compounds may be any conventionally known method. For example, a method in which the precursor compound is made into an aqueous dispersion and mixed while being pulverized with stirring or a wet media mill, and then the whole amount is evaporated to dryness, or a method in which the mixture is mixed in a dry manner using a hammer mill or a high-pressure air jet mill. It is done.
The firing method may be any conventionally known method. For example, a method of firing using a ceramic crucible or a method of firing while rotating using a rotary kiln may be used.
The range of the firing temperature is preferably 800 ° C to 2000 ° C. More preferably, it is 1000 degreeC-1600 degreeC.
By setting the firing temperature to 800 ° C. or higher, the reaction between the precursors proceeds and a single crystal can be obtained, and by setting it to 2000 ° C. or lower, it is economically possible without causing abnormal particle growth. Is also advantageous.

The calcium aluminate of the present invention can be blended in cosmetics as it is, but it may be blended after various conventionally known surface treatments if necessary.

The type of surface treatment may be any material as long as it can be used in cosmetics, and is not particularly limited. For example, oxides such as silicon, zinc, titanium, aluminum, zirconium, tin, or water A coating layer of an inorganic compound such as an oxide, carbonate, or phosphate can also be provided. Further, for the purpose of imparting water repellency, dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, methylmethoxypolysiloxane, dimethylpolysiloxane dihydrogen or the like, or a copolymer thereof, stearic acid, lauric acid, Oleic acid and their metal salts (aluminum salt, zinc salt, magnesium salt, calcium salt, etc.), polyvinyl alcohol, ethylene glycol, propylene glycol, monoethanolamine, aminomethylpropanol, diethanolamine, triethanolamine, monopropanolamine, di Propanolamine, tripropanolamine, paraffin wax, polyethylene wax, amino silane, epoxy silane, methacryl silane, vinyl silane, mercapto Orchids, chloroalkyl silane, alkylsilane, fluoroalkylsilane, hexamethyldisilazane, hexamethylcyclotrisilazane, trimethylolpropane, trimethylolethane, pentaerythritol. These organic compounds may be used alone or in combination of two or more.

Further, these surface treatments may be performed in one kind or in combination of several kinds. Furthermore, an organic compound coating layer may be provided after treatment with an inorganic compound, but it is important that the inherent lubricity is not impaired.

  The coating amount of the inorganic compound and the organic compound is preferably in the range of 0.1 to 30% by weight and more preferably in the range of 0.1 to 20% by weight with respect to the calcium aluminate. When the content is 0.1% by weight or more, the effect of improving the functionality due to the surface treatment can be exhibited, and when the content is 30% by weight or less, the treatment can be performed without impairing the original lubricity. Is advantageous from a general point of view.

  The surface treatment method is not particularly limited, but it can be coated by adding an inorganic compound or an organic compound in an aqueous dispersion of calcium aluminate and optimizing the pH. Moreover, in order to coat | cover the organic compound which is not water-soluble, it can surface-treat by adding an organic compound by a dry type, grind | pulverizing and mixing, and heating as needed.

The cosmetic of the present invention preferably contains calcium aluminate as described above in a proportion of 1 to 90% by weight. When the content is less than 1% by weight, it is not preferable in that the above-described effects cannot be obtained sufficiently. When the content exceeds 90% by weight, the powder according to the present invention is excessive, and the degree of freedom in blending as a cosmetic becomes small, which is not preferable.

Examples of the cosmetic of the present invention include foundations, makeup bases, eye shadows, blushers, mascara, lipsticks, sunscreen agents, and the like. The cosmetics of the present invention can be in any form of oily cosmetics, aqueous cosmetics, O / W type cosmetics, and W / O type cosmetics. Especially, it can use especially suitably in makeup cosmetics and sunscreen agents, such as a foundation, a makeup base, and an eye shadow.

The cosmetic of the present invention may be used in combination with any aqueous component or oily component that can be used in the cosmetic field, in addition to the components constituting the mixture. The aqueous component and the oil component are not particularly limited, and examples thereof include oils, surfactants, moisturizers, higher alcohols, sequestering agents, natural and synthetic polymers, water-soluble and oil-soluble polymers, UV shielding agents, Various extracts, inorganic and organic pigments, various powders such as inorganic and organic clay minerals, inorganic and organic pigments treated with metal soap or silicone, organic dyes and other colorants, preservatives, antioxidants, dyes, You may contain components, such as a thickener, a pH adjuster, a fragrance | flavor, a cooling agent, an antiperspirant, a disinfectant, and a skin activator. Specifically, it is possible to produce any desired cosmetic by a conventional method by arbitrarily blending one or more of the blending ingredients listed below. The compounding amounts of these compounding components are not particularly limited as long as the effects of the present invention are not impaired.

The oil content is not particularly limited. For example, avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor Oil, flaxseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagari oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, glycerin trioctanoate, Glycerin triisopalmitate, cocoa butter, coconut oil, horse fat, hydrogenated coconut oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork tallow, beef bone oil, owl kernel oil, hydrogenated oil, cow leg Fat, Owl, Hardened castor oil, Beeswax, Candelilla wax, Cotton wax, Carnauba wax, Bayberry wax, Ibotaro, Whale wax, Montan wax, Nukarou, Norin, Kapok, lanolin acetate, liquid lanolin, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoballow, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol POE hydrogenated lanolin alcohol ether, liquid paraffin, ozokerite, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax and the like.

The lipophilic nonionic surfactant is not particularly limited. For example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate. Sorbitan fatty acid esters such as diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate, mono-cotton oil fatty acid glycerin, glyceryl monoerucate, glyceryl sesquioleate, glyceryl monostearate, α, α Glycerol polyglycerin fatty acids such as glycerin '-oleic acid pyroglutamate, glyceryl monostearate malate, propylene glycol monostearate, etc. It can be exemplified glycol fatty acid esters, hardened castor oil derivatives, glycerin alkyl ether.

The hydrophilic nonionic surfactant is not particularly limited. For example, POE sorbitan fatty acid esters such as POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan tetraoleate, POE sorbite monolaurate, and POE sorbite mono POE sorbite fatty acid esters such as oleate, POE sorbite pentaoleate, POE sorbite monostearate, POE glycerin fatty acid esters such as POE glycerin monostearate, POE glycerin monoisostearate, POE glycerin triisostearate, POE POE fatty acid esters such as monooleate, POE distearate, POE monodiolate, ethylene glycol stearate, POE lauryl ether, POE POE alkyl ethers such as yl ether, POE stearyl ether, POE behenyl ether, POE 2 -octyldodecyl ether, POE cholestanol ether, POE alkyl phenyl ethers such as POE octyl phenyl ether, POE nonyl phenyl ether, POE dinonyl phenyl ether Pluronic type such as brulonic, POE / POP cetyl ether, POE / POP2-decyltetradecyl ether, POE / POP monobutyl ether, POE / POP hydrogenated lanolin, POE / POP alkyl ethers such as POE / POP glycerin ether, Tetronic PEO / TetraPOP ethylenediamine condensates, POE castor oil, POE hydrogenated castor oil, POE hydrogenated castor oil monoisos POE castor oil triisostearate, POE cured castor oil monopyroglutamic acid monoisostearic acid diester, POE castor oil cured castor oil derivatives such as POE cured castor oil maleic acid, POE beeswax and lanolin derivatives such as POE sorbite beeswax, Alkanolamides such as coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, POE propylene glycol fatty acid ester, POE alkylamine, POE fatty acid amide, sucrose fatty acid ester, POE nonylphenyl formaldehyde condensate, alkylethoxydimethylamine Examples thereof include oxide and trioleyl phosphate.

Examples of other surfactants include anionic surfactants such as fatty acid soaps, higher alkyl sulfates, POE lauryl sulfate triethanolamine, alkyl ether sulfates, alkyltrimethylammonium salts, alkylpyridinium salts, alkyl quaternary salts. Stabilizes cationic surfactants such as ammonium salts, alkyldimethylbenzylammonium salts, POE alkylamines, alkylamine salts, polyamine fatty acid derivatives, and amphoteric surfactants such as imidazoline-based amphoteric surfactants and betaine-based surfactants. And you may mix | blend in the range with no problem in skin irritation.

The moisturizing agent is not particularly limited, and examples thereof include xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate, sodium lactate, bile salt, dl- Examples include pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Isaiyobara extract, yarrow extract, and merirot extract.

The higher alcohol is not particularly limited, and examples thereof include linear alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, monostearyl glycerin ether (batyl alcohol), 2-decyl. Examples thereof include branched chain alcohols such as tetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol, and the like.

The sequestering agent is not particularly limited. For example, 1-hydroxyethane-1,1-
Diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, etc. be able to.

The natural water-soluble polymer is not particularly limited. For example, arabia gum, tragacanth gum, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (rice, rice, Corn, potato, wheat), plant polymers such as glycyrrhizic acid, microbial polymers such as xanthan gum, dextran, succinoglucan and pullulan, and animal polymers such as collagen, casein, albumin and gelatin. .

The semi-synthetic water-soluble polymer is not particularly limited. For example, starch-based polymers such as carboxymethyl starch and methylhydroxypropyl starch, methylcellulose, nitrocellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, Examples thereof include cellulose polymers such as hydroxypropylcellulose, sodium carboxymethylcellulose (CMC), crystalline cellulose, and cellulose powder, and alginic acid polymers such as sodium alginate and propylene glycol alginate.

The synthetic water-soluble polymer is not particularly limited, and examples thereof include vinyl polymers such as polyvinyl alcohol, polyvinyl methyl ether, and polyvinyl pyrrolidone, and polyoxyethylene polymers such as polyethylene glycol 20,000, 40,000, and 60,000. Examples thereof include polymers, polyoxyethylene polyoxypropylene copolymer copolymer polymers, acrylic polymers such as sodium polyacrylate, polyethyl acrylate and polyacrylamide, polyethyleneimine, and cationic polymers.

The inorganic water-soluble polymer is not particularly limited, and examples thereof include bentonite, silicate AlMg (beegum), laponite, hectorite, and silicic anhydride.

The ultraviolet screening agent is not particularly limited. For example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl Benzoic acid UV screening agents such as PABA ethyl ester and N, N-dimethyl PABA butyl ester; Anthranilic acid UV screening agents such as homomenthyl-N-acetylanthranylate; Amyl salicylate, Menthyl salicylate, Homomentil salicylate , Salicylic acid UV screening agents such as phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate; octylcinnamate, ethyl-4-isopropylcinnamate, methyl-2,5- Isopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2- Ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexa Cinnamic acid-based ultraviolet screening agents such as noyl-diparamethoxycinnamate; 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone , 2, 2 ', 4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4 -Benzophenone-based UV shielding agents such as phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone; (4′-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor, urocanic acid, urocanic acid ethyl ester, 2-phenyl-5-methylbenzoxazole, 2,2′-hydroxy- 5-methylphenylbenzotri Sol, 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole, 2- (2′-hydroxy-5′-methylphenylbenzotriazole), dibenzalazine, dianisoylmethane, 4-methoxy-4′- Examples thereof include t-butyldibenzoylmethane and 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one.

Other drug components are not particularly limited and include, for example, vitamin A oil, retinol, retinol palmitate, inosit, pyridoxine hydrochloride, benzyl nicotinate, nicotinamide, nicotinic acid DL-α-tocopherol, magnesium ascorbate phosphate, 2 Vitamins such as -O-α-D-glucopyranosyl-L-ascorbic acid, vitamin D2 (ergocaciferol), dl-α-tocopherol, dl-α-tocopherol acetate, pantothenic acid, biotin; estradiol, ethinylestradiol, etc. Hormones; amino acids such as arginine, aspartic acid, cystine, cysteine, methionine, serine, leucine and tryptophan; anti-inflammatory agents such as allantoin and azulene; whitening agents such as arbutin; astringents such as tannic acid; L Menthol, cooling agents and sulfur camphor such as, lysozyme chloride, can be mentioned pyridoxine chloride, and the like.

There are no particular limitations on the various extracts, for example, Dokudami extract, Oat extract, Merirot extract, Odorikosou extract, Licorice extract, Peonies extract, Soap extract, Loofah extract, Kina extract, Yukinoshita extract, Clara extract, Kouhone extract, Fennel Extract, Primrose Extract, Rose Extract, Giant Extract, Lemon Extract, Shikon Extract, Aloe Extract, Shobu Root Extract, Eucalyptus Extract, Horsetail Extract, Sage Extract, Thyme Extract, Tea Extract, Seaweed Extract, Cucumber Extract, Clove Extract, Raspberry Extract, Melissa Extract , Carrot extract, horse chestnut extract, peach extract, peach leaf extract, mulberry extract, cornflower extract, hamamelis extract, placenta extract, thymus extract, silk extract, licorice Mention may be made of the kiss and the like.

Examples of the various powders include bengara, yellow iron oxide, black iron oxide, titanium mica, iron oxide-coated mica titanium, titanium oxide-coated glass flakes and other bright colored pigments, mica, talc, kaolin, sericite, titanium dioxide, Examples thereof include inorganic powders such as silica and organic powders such as polyethylene powder, nylon powder, crosslinked polystyrene, cellulose powder, and silicone powder. Preferably, a part or all of the powder component is hydrophobized by a known method with a substance such as silicones, fluorine compounds, metal soaps, oils, acyl glutamates in order to improve sensory characteristics and cosmetic durability. May be used.

EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to these examples.

Example 1 (Method for producing plate-like particles)
Calcium carbonate (CWS-20, produced by Sakai Chemical Industry Co., Ltd., 4.47 g), aluminum oxide (AKP-50, produced by Sumitomo Chemical Co., Ltd. 32.01 g), and calcium fluoride (Wako first grade reagent 0.21 g) and magnesium fluoride (Wako Special Grade) as flux components Reagent 0.16 g) was weighed, placed in water, and thoroughly mixed using a planetary ball mill. The solid obtained by evaporating and drying the mixed slurry at 130 ° C. was crushed in a mortar to obtain a calcined precursor powder. Next, 20 g of the calcined precursor was filled in an alumina crucible, heated to 1600 ° C. at 200 ° C./hour in the atmosphere, held for 3 hours, and then cooled to room temperature at 200 ° C./hour.
The fired product thus obtained was pulverized and sized in water using a planetary ball mill, filtered and dried to obtain the desired calcium aluminate.

Example 2 (Method for producing surface-treated plate-like particles)
The calcium aluminate obtained in Example 1 was pulverized in water using a planetary ball mill, sized, filtered and dried to obtain calcium aluminate.
Thereafter, 1 g of sodium stearate (special grade reagent manufactured by Kanto Chemical Co., Inc.) was weighed, added to 500 ml of pure water with stirring, and heated to 80 ° C. to completely dissolve the sodium stearate aqueous solution in advance. While maintaining the temperature, 100 g of calcium aluminate powder was added to make slurry A.
Further, 0.263 g of aluminum chloride hexahydrate (special grade reagent manufactured by Kanto Chemical Co., Ltd.) was weighed out and an aqueous solution of aluminum chloride dissolved in 10 g of pure water was prepared to obtain an aqueous solution A.
The aqueous solution A was added to the slurry A over 10 minutes, and then stirred for 30 minutes while maintaining 80 ° C.
Next, the slurry was allowed to cool to 30 ° C. or lower under stirring, followed by filtration, washing with water, and drying to obtain a surface-treated calcium aluminate having a surface treated with 1% by weight of aluminum stearate.

Evaluation example 1 (shape evaluation)
Using the JSM-840F scanning electron microscope manufactured by JEOL, 10 photographs of the powder obtained in Examples 1 and 2 were magnified 1000 times, and arbitrarily 100 particles included in the field of view. Selected, the major and minor diameters were measured.
As a result, a plate-like shape having a major axis L in the range of 6 μm to 30 μm, a minor axis S in the range of 0.1 μm to 5 μm, and a ratio satisfying the range of 1.2 ≦ L / S ≦ 300 In Example 1, the number was 98, and in Example 2, the number was 97.
Table 2 shows the average value of the measured values of the major axis L and minor axis S of the sample and the calculated value of the L / S ratio. In addition, the numerical value of Table 1 is the value which rounded off the 2nd decimal place.

Evaluation Example 2 (Slidability evaluation)
The slipperiness evaluation of the powders obtained in Examples 1 and 2 was performed by the following method. Double-sided tape was affixed to the slide glass, about half a spoonful of powder was placed on the adhesive surface, the powder was spread with a cosmetic sponge, and a friction piece was set thereon. The average friction coefficient and the variation of the average friction coefficient were measured from the load applied to the friction piece by moving the slide glass. The measurement was performed with a friction tester (KES-SE manufactured by Kato Tech).
Table 2 shows the measurement results.

In the evaluation, mica, sericite, talc, and titanium oxide for pigments that are generally used in cosmetics were compared.
The average friction coefficient MIU is an index indicating that the smaller the numerical value, the more the powder slides, and the friction coefficient variation value MMD is an index indicating that the smaller the numerical value, the smoother and free from roughness.
From Table 1, it was found that the powders obtained in Examples 1 and 2 had slipperiness comparable to that of commercially available mica, sericite, and talc.
In particular, it was found that the surface-treated powder obtained in Example 2 has an extremely high slip property and is suitable as a cosmetic material.

Evaluation Example 3 (Evaluation as Cosmetic)
Using the powders obtained in Examples 1 and 2 and commercially available talc and sericite, powder foundations were prepared with the formulations shown in Table 3 below. In addition, the materials used for the following foundations are all cosmetic grade except for the examples.

Each material was measured with such a composition, and stirred and mixed for 30 seconds using a coffee mill. 10 g of a powdery mixture obtained by repeating this mixing operation three times was measured on a metal lid with a diameter of 3 cm, and held for 1 minute at a pressure of 100 kgf / cm ² using a press machine. Got.
The sensory test was performed on the foundations F1 to F4 obtained as described above on 10 panelists.
When the evaluation was made to select one with good usability without knowing the number, the following results were obtained.

These results show that the powder of the present invention can be blended into cosmetics without any difference from commercially available plate-like materials, and further, it is possible to further improve the feeling of use by surface treatment. is there.

Evaluation example 4 (soft focus evaluation)
The soft focus properties of the powders obtained in Examples 1 and 2 were evaluated by the following method.
The powder and dimethylpolysiloxane (1000 cps) were weighed to a weight ratio of 1: 9 and mixed well, and then a paste was prepared by rotating 50 times at a rotation speed of 1 rpm using a Hoover type muller.
The paste thus prepared was uniformly formed on a glass plate using a 1 MIL applicator.
The thus obtained coating film was measured for haze and total light transmittance with a haze meter (NDH2000 type manufactured by Nippon Denshoku Industries Co., Ltd.) to evaluate the soft focus property.
Table 5 shows the results. In the evaluation, comparison was made between ultrafine titanium oxide and titanium oxide for pigment.

As a result, first of all, ultrafine titanium oxide has a large total light transmittance and a low haze, which indicates that it is a very transparent coating film. Conversely, titanium oxide for pigments has a total light transmittance of Since it was small and had a large haze, it was shown that it was a highly concealing coating film.
For the samples shown in Examples 1 and 2, since the total light transmittance is relatively large and the haze is also a relatively large numerical value, the substrate is hardly concealed as in the case of titanium oxide for pigments. It is shown that it is not transparent like fine particle titanium oxide.
That is, it was shown that the transmitted light is scattered moderately and an effect of blurring the substrate can be obtained, so that it has a soft focus property.

The cosmetic of the present invention has excellent performance in terms of lubricity, adhesion, soft focus, etc., and therefore can be suitably used for makeup cosmetics such as foundations.

Claims (4)

A cosmetic comprising a compound represented by CaAl ₁₂ O ₁₉ . The cosmetics according to claim 1, wherein the compound represented by CaAl ₁₂ O ₁₉ is 1 to 90% by weight based on the whole cosmetics. 3. The makeup according to claim 1, wherein the compound represented by CaAl ₁₂ O ₁₉ contains 90% or more of plate-like particles having a major axis L in the range of 6 μm to 30 μm and a minor axis S in the range of 0.1 μm to 5 μm. Fee. The compound represented by CaAl ₁₂ O ₁₉ contains 90% or more of plate-like particles in which the ratio L / S of the major axis L to the minor axis S is 1.2 ≦ L / S ≦ 300. Cosmetics according to 1, 2 or 3.