WO2014022363A3 - Revêtement dur antisalissure et précurseur pour revêtement dur antisalissure - Google Patents

Revêtement dur antisalissure et précurseur pour revêtement dur antisalissure Download PDF

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Publication number
WO2014022363A3
WO2014022363A3 PCT/US2013/052677 US2013052677W WO2014022363A3 WO 2014022363 A3 WO2014022363 A3 WO 2014022363A3 US 2013052677 W US2013052677 W US 2013052677W WO 2014022363 A3 WO2014022363 A3 WO 2014022363A3
Authority
WO
WIPO (PCT)
Prior art keywords
particle size
hard coat
nanoparticles
average particle
smudge
Prior art date
Application number
PCT/US2013/052677
Other languages
English (en)
Other versions
WO2014022363A2 (fr
Inventor
Saori Ueda
Naota SUGIYAMA
Yorinobu Takamatsu
Original Assignee
3M Innovative Properties Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Company filed Critical 3M Innovative Properties Company
Priority to KR1020157004809A priority Critical patent/KR102159140B1/ko
Priority to CN201380040679.0A priority patent/CN104540900B/zh
Priority to SG11201500748XA priority patent/SG11201500748XA/en
Publication of WO2014022363A2 publication Critical patent/WO2014022363A2/fr
Publication of WO2014022363A3 publication Critical patent/WO2014022363A3/fr
Priority to HK15110293.6A priority patent/HK1209448A1/xx

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/68—Particle size between 100-1000 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/69—Particle size larger than 1000 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)

Abstract

Cette invention concerne un revêtement dur contenant un mélange de nanoparticules et un liant, lesdites nanoparticules constituant de 40 à 95 % en masse de la masse totale du revêtement dur ; 10 à 50 % en masse des nanoparticules ont une dimension granulométrique moyenne comprise dans la plage allant de 2 à 200 nm ; 50 à 90 % en masse des nanoparticules ont une dimension granulométrique moyenne comprise dans la plage allant de 60 à 400 nm ; le rapport dimension granulométrique moyenne des nanoparticules ayant une dimension granulométrique moyenne comprise dans la plage allant de 60 à 400 nm/dimension granulométrique moyenne des nanoparticules ayant une dimension granulométrique moyenne comprise dans la plage allant de 2 à 200 nm est compris dans la plage allant de 2:1 à 200:1 ; et le liant contient un composé (méth)acrylique fluoré polyfonctionnel, son produit de réaction ou une association de ceux-ci. Le composé (méth)acrylique fluoré polyfonctionnel comprend des unités siloxanes cycliques. La répartition granulométrique des nanoparticules est bimodale ou multimodale.
PCT/US2013/052677 2012-08-01 2013-07-30 Revêtement dur antisalissure et précurseur pour revêtement dur antisalissure WO2014022363A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020157004809A KR102159140B1 (ko) 2012-08-01 2013-07-30 방오성 하드 코트 및 방오성 하드 코트 전구체
CN201380040679.0A CN104540900B (zh) 2012-08-01 2013-07-30 防污硬涂层和防污硬涂层前体
SG11201500748XA SG11201500748XA (en) 2012-08-01 2013-07-30 Anti-smudge hard coat and anti-smudge hard coat precursor
HK15110293.6A HK1209448A1 (en) 2012-08-01 2015-10-20 Anti-smudge hard coat and anti-smudge hard coat precursor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012-170999 2012-08-01
JP2012170999A JP6062680B2 (ja) 2012-08-01 2012-08-01 防汚性ハードコートおよび防汚性ハードコート前駆体

Publications (2)

Publication Number Publication Date
WO2014022363A2 WO2014022363A2 (fr) 2014-02-06
WO2014022363A3 true WO2014022363A3 (fr) 2014-06-12

Family

ID=48998699

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/052677 WO2014022363A2 (fr) 2012-08-01 2013-07-30 Revêtement dur antisalissure et précurseur pour revêtement dur antisalissure

Country Status (7)

Country Link
JP (1) JP6062680B2 (fr)
KR (1) KR102159140B1 (fr)
CN (1) CN104540900B (fr)
HK (1) HK1209448A1 (fr)
SG (2) SG11201500748XA (fr)
TW (1) TWI623595B (fr)
WO (1) WO2014022363A2 (fr)

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KR101539262B1 (ko) * 2014-08-20 2015-07-29 주식회사 콘텍 불소함유 Diol을 이용한 폴리머 조성물 및 이를 이용한 표면처리물
US20170233591A1 (en) * 2014-09-04 2017-08-17 3M Innovative Properties Company Hardcoat and method of making the same
JP6552186B2 (ja) * 2014-11-21 2019-07-31 デクセリアルズ株式会社 塗料組成物、及び超撥水フィルム
EP3261842A1 (fr) * 2015-02-24 2018-01-03 3M Innovative Properties Company Surface d'impression en 3d
CN108481856A (zh) 2015-03-18 2018-09-04 理研科技株式会社 硬涂层层合膜及其生产方法
WO2016147733A1 (fr) 2015-03-18 2016-09-22 リケンテクノス株式会社 Film stratifié à revêtement dur antireflet
US11433651B2 (en) 2015-03-18 2022-09-06 Riken Technos Corporation Hard coat laminated film
KR102479158B1 (ko) 2015-03-18 2022-12-19 리껭테크노스 가부시키가이샤 하드 코트 적층 필름
CN107405897B (zh) 2015-03-18 2020-08-07 理研科技株式会社 粘合膜
KR102551428B1 (ko) 2015-03-18 2023-07-04 리껭테크노스 가부시키가이샤 다층 하드 코팅 필름
US10596739B2 (en) 2015-03-18 2020-03-24 Riken Technos Corporation Molded body
KR102345843B1 (ko) * 2015-04-07 2021-12-31 닛산 가가쿠 가부시키가이샤 방현성 코팅용 경화성 조성물
CN108026394B (zh) 2015-07-29 2021-02-19 3M创新有限公司 包含二氧化硅纳米粒子和官能硅烷化合物的防污组合物及其涂覆制品
WO2017023120A1 (fr) * 2015-08-03 2017-02-09 주식회사 엘지화학 Composition de revêtement pour film en plastique souple
KR102094450B1 (ko) * 2015-08-03 2020-03-27 주식회사 엘지화학 플렉시블 플라스틱 필름
KR102107736B1 (ko) 2015-08-03 2020-05-07 주식회사 엘지화학 플렉시블 플라스틱 필름용 코팅 조성물
KR101862252B1 (ko) 2015-08-03 2018-05-29 주식회사 엘지화학 플렉시블 플라스틱 필름
KR101862251B1 (ko) * 2015-08-03 2018-05-29 주식회사 엘지화학 플렉시블 플라스틱 필름
KR20180063180A (ko) * 2015-09-30 2018-06-11 쓰리엠 이노베이티브 프로퍼티즈 캄파니 다층 배리어 코팅
TWI745316B (zh) 2015-11-25 2021-11-11 日商理研科技股份有限公司 門體
US11774166B2 (en) 2015-11-25 2023-10-03 Riken Technos Corporation Door body
JP6644534B2 (ja) 2015-12-08 2020-02-12 リケンテクノス株式会社 ハードコート積層フィルム
JP6862183B2 (ja) * 2016-01-18 2021-04-21 リケンテクノス株式会社 ハードコート積層フィルム
EP3416810B1 (fr) 2016-02-18 2019-09-04 3M Innovative Properties Company Surface d'impression en 3d
EP3808800B1 (fr) 2016-09-14 2022-01-05 Riken Technos Corporation Film de revêtement dur stratifié
JP7064313B2 (ja) 2016-11-25 2022-05-10 リケンテクノス株式会社 ハードコート積層フィルム
KR102429958B1 (ko) * 2017-06-21 2022-08-09 현대자동차주식회사 차량의 전파투과 커버용 자외선 경화형 프라이머
TWI667303B (zh) * 2018-08-02 2019-08-01 明基材料股份有限公司 硬塗層光學膜、具有此硬塗層光學膜的偏光板、及含此硬塗層光學膜及/或偏光板的影像顯示裝置
TWI684632B (zh) * 2018-08-02 2020-02-11 明基材料股份有限公司 抗反射膜、具此抗反射膜之偏光板、及含此抗反射膜及/或含具此抗反射膜之偏光板的影像顯示裝置
DE102019106081B4 (de) * 2019-03-11 2024-05-08 Joanneum Research Forschungsgesellschaft Mbh Oligomere Hexafluorpropylenoxidderivate
CN114231137A (zh) * 2021-12-27 2022-03-25 武汉格林鸿业新材料科技有限公司 无溶剂型自清洁uv树脂环保涂层及其制备方法
CN117177941A (zh) * 2022-01-13 2023-12-05 日产化学株式会社 具有粒度分布的硅溶胶和其制造方法
CN116656155A (zh) * 2023-05-22 2023-08-29 兰州空间技术物理研究所 一种太阳能电池表面月尘防护涂层及其制备方法和防尘效率评价方法

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WO2006016998A1 (fr) * 2004-07-09 2006-02-16 3M Innovative Properties Company Revetement de film optique
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WO2008002953A1 (fr) * 2006-06-29 2008-01-03 3M Innovative Properties Company Films de protection de transfert pour substrats graphiques
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WO2003022935A1 (fr) * 2001-09-11 2003-03-20 3M Innovative Properties Company Revetements durs nanocomposites resistant aux taches et procedes de fabrication
WO2006016998A1 (fr) * 2004-07-09 2006-02-16 3M Innovative Properties Company Revetement de film optique
WO2006102383A1 (fr) * 2005-03-23 2006-09-28 3M Innovative Properties Company Additifs de type perfluoropolyéther et uréthane incluant des groupements acryle ou méthacryle et des couches dures
WO2008002953A1 (fr) * 2006-06-29 2008-01-03 3M Innovative Properties Company Films de protection de transfert pour substrats graphiques
WO2008067262A1 (fr) * 2006-11-29 2008-06-05 3M Innovative Properties Company Composition polymérisable comprenant un matériau perfluoropolyéther ayant un segment de motifs répétitifs de type oxyde d'éthylène
WO2009070643A2 (fr) * 2007-11-28 2009-06-04 3M Innovative Properties Company Films à revêtement dur pour substrats graphiques

Also Published As

Publication number Publication date
SG11201500748XA (en) 2015-02-27
SG10201707666UA (en) 2017-10-30
CN104540900A (zh) 2015-04-22
WO2014022363A2 (fr) 2014-02-06
TWI623595B (zh) 2018-05-11
HK1209448A1 (en) 2016-04-01
KR102159140B1 (ko) 2020-09-23
JP2014031397A (ja) 2014-02-20
CN104540900B (zh) 2017-11-17
JP6062680B2 (ja) 2017-01-18
TW201406877A (zh) 2014-02-16
KR20150040310A (ko) 2015-04-14

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