WO2013183706A1 - 光半導体装置 - Google Patents
光半導体装置 Download PDFInfo
- Publication number
- WO2013183706A1 WO2013183706A1 PCT/JP2013/065688 JP2013065688W WO2013183706A1 WO 2013183706 A1 WO2013183706 A1 WO 2013183706A1 JP 2013065688 W JP2013065688 W JP 2013065688W WO 2013183706 A1 WO2013183706 A1 WO 2013183706A1
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- WIPO (PCT)
- Prior art keywords
- plating layer
- semiconductor device
- peripheral surface
- optical semiconductor
- transparent sealing
- Prior art date
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- 230000003287 optical effect Effects 0.000 title claims abstract description 50
- 239000004065 semiconductor Substances 0.000 title claims abstract description 50
- 239000004927 clay Substances 0.000 claims abstract description 102
- 238000007747 plating Methods 0.000 claims abstract description 78
- 238000007789 sealing Methods 0.000 claims abstract description 72
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 71
- 229910052709 silver Inorganic materials 0.000 claims abstract description 71
- 239000004332 silver Substances 0.000 claims abstract description 71
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- 230000002093 peripheral effect Effects 0.000 claims description 55
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- 229910052802 copper Inorganic materials 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 5
- 229910052901 montmorillonite Inorganic materials 0.000 description 5
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
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- 239000011521 glass Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
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- 238000009413 insulation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000001579 optical reflectometry Methods 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006375 polyphtalamide Polymers 0.000 description 1
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- 239000005368 silicate glass Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/483—Containers
- H01L33/486—Containers adapted for surface mounting
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
- H01L33/56—Materials, e.g. epoxy or silicone resin
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/58—Optical field-shaping elements
- H01L33/60—Reflective elements
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/62—Arrangements for conducting electric current to or from the semiconductor body, e.g. lead-frames, wire-bonds or solder balls
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
- H01L2224/4809—Loop shape
- H01L2224/48091—Arched
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/484—Connecting portions
- H01L2224/48463—Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond
- H01L2224/48465—Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond the other connecting portion not on the bonding area being a wedge bond, i.e. ball-to-wedge, regular stitch
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73251—Location after the connecting process on different surfaces
- H01L2224/73265—Layer and wire connectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L2224/85—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a wire connector
- H01L2224/85909—Post-treatment of the connector or wire bonding area
- H01L2224/8592—Applying permanent coating, e.g. protective coating
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/44—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the coatings, e.g. passivation layer or anti-reflective coating
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
- H01L33/54—Encapsulations having a particular shape
Definitions
- the present invention relates to an optical semiconductor device in which a light emitting diode is bonded.
- Patent Document 1 As an optical semiconductor device on which an LED (Light Emitting Diode) is mounted, the one disclosed in Patent Document 1 is known.
- the optical semiconductor device described in Patent Document 1 is formed by bonding a blue LED to a molded body, raising the molded body so as to surround the blue LED, and reflecting the light emitted from the blue LED.
- the blue LED is sealed by filling a transparent sealing portion containing a body.
- thermoplastic resin has been adopted as the reflecting plate, and since the yellowing rate of the reflecting plate was faster than the sulfiding rate of the silver plating layer, the decrease in illuminance due to the sulfidation of the silver plating layer was not noticeable.
- thermosetting resin has been adopted as a reflection plate, and the yellowing rate of the reflection plate has become slower than the sulfidation rate of the silver plating layer. It has come to stand out.
- the LED illumination is made high-powered, the heat generation temperature of the blue LED is increased and the temperature of the silver plating layer is increased, so that the sulfidation of the silver plating layer is promoted.
- the present inventors have conducted intensive studies and found that the silver plating layer was effectively sulfidized by covering the silver plating layer with a clay film, rather than improving the gas permeability of the transparent sealing portion. It was found that it can be suppressed.
- the present inventors manufactured an optical semiconductor device based on such knowledge, since a clay film is interposed between the silver plating layer and the transparent sealing portion, the transparent sealing portion for the optical semiconductor device is provided. From the viewpoint of preventing the peeling of the optical semiconductor device, the inventors have found that there is room for optimizing the configuration of the optical semiconductor device.
- an object of the present invention is to provide an optical semiconductor device capable of suppressing peeling of a transparent sealing portion while suppressing sulfidation of a silver plating layer.
- An optical semiconductor device includes a substrate having a silver plating layer formed on a surface thereof, a light emitting diode bonded to the silver plating layer, a light reflecting portion surrounding the light emitting diode, and a light reflecting portion.
- the transparent sealing portion that seals the light emitting diode and the clay film that covers the silver plating layer are joined, and the transparent sealing portion and the light reflecting portion are joined.
- the sulfidation of the silver plating layer can be suppressed.
- the illumination intensity fall of the optical semiconductor device by a silver plating layer blackening can be suppressed significantly.
- the clay film is interposed between the transparent sealing portion and the silver plating layer, but since the transparent sealing portion and the light reflecting portion are joined, it is transparent. It can suppress that a sealing part peels.
- the light reflecting portion includes an inner peripheral surface that rises from the substrate so as to surround the light emitting diode and forms an inner space that accommodates the light emitting diode, and the clay film is a part of the inner peripheral surface.
- the transparent sealing portion may be joined to the non-covered portion that is not covered with the clay film on the inner peripheral surface.
- the clay film is coated on the silver plating layer by, for example, diluting clay with a solvent to produce a clay diluted solution, dropping or spraying the clay diluted solution on the inner space of the light reflecting portion, and then drying the solvent. Can be performed.
- the inner space of the light reflecting portion is small, it is difficult to drop or spread the clay diluent only on the silver plating layer by adjusting the dripping amount or spreading amount of the clay diluent. Therefore, by allowing the clay film to cover the inner peripheral surface of the light reflecting portion, it is possible to easily cover the silver plating layer with the clay film.
- the transparent sealing portion and the non-covering portion on the inner peripheral surface of the light reflecting portion are joined, it is possible to suppress the peeling of the transparent sealing portion.
- the light emitting diode may be a blue light emitting diode that generates blue light.
- the inner peripheral surface of the light reflecting part reflects the light generated from the light emitting diode and outputs it from the optical semiconductor device, but the clay film has the effect of amplifying the frequency band of blue light, so the clay film reflects light.
- the reflection efficiency of the blue light generated from the blue light emitting diode can be increased.
- the area of the non-covering portion may be 1% or more of the area of the inner peripheral surface.
- the bonding strength between the translucent resin portion and the light reflecting portion can be ensured by setting the area of the non-covering portion to 1% or more of the inner peripheral surface of the light reflecting portion.
- the area of the non-covering portion can be 99% or less of the area of the inner peripheral surface.
- the area of the non-covering portion 99% or less of the inner peripheral surface of the light reflecting portion, it is possible to more easily cover the silver plating layer with the clay film.
- the light reflecting portion rises from the substrate so as to surround the light emitting diode and forms an inner space that accommodates the light emitting diode, and an outer surface of the inner space adjacent to the inner peripheral surface.
- the clay film covers the inner peripheral surface, and the transparent sealing portion is joined to the top surface.
- the clay film is coated on the silver plating layer by, for example, diluting clay with a solvent to produce a clay diluted solution, dropping or spraying the clay diluted solution on the inner space of the light reflecting portion, and then drying the solvent. Can be performed.
- the inner space of the light reflecting portion is small, it is difficult to drop or spread the clay diluent only on the silver plating layer by adjusting the dripping amount or spreading amount of the clay diluent. Therefore, by allowing the clay film to cover the entire inner peripheral surface of the light reflecting portion, it is possible to more easily cover the silver plating layer with the clay film.
- the transparent sealing portion and the top surface of the light reflecting portion are joined, it is possible to suppress the peeling of the transparent sealing portion.
- the junction between the transparent sealing portion and the top surface of the light reflecting portion is, for example, dripping or spreading the clay diluted solution in the inner space of the light reflecting portion so that the clay diluted solution overflows from the inner space of the light reflecting portion, Then, it can carry out by drying a solvent.
- an optical semiconductor device capable of suppressing peeling of the transparent sealing portion while suppressing sulfidation of the silver plating layer.
- FIG. 2 is a plan view of the optical semiconductor device shown in FIG. 1. It is a figure for demonstrating the coating method of a clay film. It is a figure for demonstrating the coating method of a clay film. It is a figure for demonstrating the coating method of a clay film. It is a figure for demonstrating the coating method of a clay film. It is a figure for demonstrating the coating method of a clay film.
- FIG. 4 is a cross-sectional view of an optical semiconductor device filled with a transparent sealing resin in the case of FIG. 3.
- FIG. 5 is a cross-sectional view of an optical semiconductor device filled with a transparent sealing resin in the case of FIG. 4.
- FIG. 6 is a cross-sectional view of an optical semiconductor device filled with a transparent sealing resin in the case of FIG. 5.
- FIG. 7 is a cross-sectional view of an optical semiconductor device filled with a transparent sealing resin in the case of FIG. 6. It is a conceptual diagram for demonstrating the structure of the clay film using a montmorillonite
- FIG. 1 is a cross-sectional view of an optical semiconductor device according to an embodiment.
- FIG. 2 is a plan view of the optical semiconductor device shown in FIG.
- the optical semiconductor device 1 according to the embodiment is generally classified as a “surface mount type”.
- the optical semiconductor device 1 includes a substrate 10, a blue LED 30 bonded to the surface of the substrate 10, a reflector 20 provided on the surface of the substrate 10 so as to surround the blue LED 30, and the reflector 20 filled with the blue LED 30.
- a transparent sealing resin 40 for sealing for sealing.
- illustration of the transparent sealing resin 40 is abbreviate
- a copper plating plate 14 is wired on the surface of an insulating base 12, and a silver plating layer 16 is formed on the surface of the copper plating plate 14.
- the silver plating layer 16 is an electrode that is disposed on the surface of the substrate 10 and is electrically connected to the blue LED 30.
- the silver plating layer 16 may have any composition as long as it is a plating layer containing silver.
- the silver plating layer 16 may be formed by plating only silver, or the silver plating layer 16 may be formed by plating nickel and silver in this order.
- the copper plating plate 14 and the silver plating layer 16 are insulated on the anode side and the cathode side.
- the insulation between the copper plating plate 14 and the silver plating layer 16 on the anode side and the copper plating plate 14 and the silver plating layer 16 on the cathode side is, for example, the copper plating plate 14 and the silver plating layer 16 on the anode side and the cathode side.
- the copper plating plate 14 and the silver plating layer 16 can be separated from each other, and an insulating layer such as a resin and ceramic can be appropriately inserted therebetween.
- the blue LED 30 is die-bonded to one of the silver plating layer 16 on the anode side and the cathode side, and is electrically connected to the silver plating layer 16 through the die bonding material 32.
- the blue LED 30 is wire-bonded to the silver plating layer 16 on either the anode side or the cathode side, and is electrically connected to the silver plating layer 16 via the bonding wire 34.
- the reflector 20 fills the transparent sealing resin 40 for sealing the blue LED 30 and reflects the light emitted from the blue LED 30 to the surface side of the optical semiconductor device 1.
- the reflector 20 is erected from the surface of the substrate 10 so as to surround the blue LED 30. That is, the reflector 20 is formed with an inner space 22 that rises from the surface 10a of the substrate 10 so as to surround the blue LED 30 and accommodates the blue LED 30 inside, and has an inner circumference formed in a circle in plan view (see FIG. 2).
- the shapes of the inner peripheral surface 20 a and the outer peripheral surface 20 c are not particularly limited, but from the viewpoint of improving the illuminance of the optical semiconductor device 1, the inner peripheral surface 20 a has a truncated cone shape (funnel) whose diameter increases as the distance from the substrate 10 increases.
- the outer peripheral surface 20 c is preferably formed in a rectangular shape perpendicular to the substrate 10 from the viewpoint of improving the degree of integration of the optical semiconductor device 1.
- the inner peripheral surface 20a As an example of forming the inner peripheral surface 20a, the lower part located on the substrate 10 side is perpendicular to the substrate 10, and the upper part located on the opposite side of the substrate 10 is separated from the substrate 10. An enlarged diameter is shown.
- the reflector 20 is made of a cured product of a thermosetting resin composition containing a white pigment.
- the thermosetting resin composition is preferably one that can be pressure-molded at room temperature (25 ° C.) before thermosetting.
- thermosetting resin contained in the thermosetting resin composition various resins such as an epoxy resin, a silicone resin, a urethane resin, and a cyanate resin can be used.
- an epoxy resin is preferable because of its excellent adhesion to various materials.
- the white pigment alumina, magnesium oxide, antimony oxide, titanium oxide, zirconium oxide or the like can be used. Among these, titanium oxide is preferable from the viewpoint of light reflectivity.
- Inorganic hollow particles may be used as the white pigment. Specific examples of the inorganic hollow particles include sodium silicate glass, aluminum silicate glass, borosilicate soda glass, and shirasu.
- the transparent sealing resin 40 is filled in the inner space 22 formed by the inner peripheral surface 20a of the reflector 20, and seals the blue LED 30.
- the transparent sealing resin 40 is made of a transparent sealing resin having translucency.
- the transparent sealing resin includes a translucent resin as well as a completely transparent resin.
- the transparent sealing resin preferably has an elastic modulus of 1 MPa or less at room temperature (25 ° C.). In particular, it is preferable to employ a silicone resin or an acrylic resin from the viewpoint of transparency.
- the transparent sealing resin may further contain an inorganic filler that diffuses light and a phosphor 42 that emits white light using blue light emitted from the blue LED 30 as an excitation source.
- the silver plating layer 16 is covered with the clay film 50, and the transparent sealing resin 40 and the reflector 20 are joined.
- the clay film 50 suppresses sulfidation of the silver plating layer 16 by covering the silver plating layer 16.
- any of natural clay and synthetic clay can be used.
- any one or more of stevensite, hectorite, saponite, montmorillonite and beidellite can be used.
- natural clay montmorillonite as shown in FIG. 11, has a high aspect ratio such as a thickness H of 1 nm or less and a length L of 10 nm or more and 400 nm or less, and has a long gas path route.
- the film thickness of the clay film 50 is preferably 0.01 ⁇ m or more and 1000 ⁇ m or less, more preferably 0.03 ⁇ m or more and 500 ⁇ m or less, further preferably 0.05 ⁇ m or more and 100 ⁇ m or less, and 0.05 ⁇ m or more.
- the thickness is more preferably 10 ⁇ m or less, and further preferably 0.05 ⁇ m or more and 1 ⁇ m or less.
- this effect can be further improved by setting the film thickness of the clay film 50 to 0.03 ⁇ m to 500 ⁇ m, 0.05 ⁇ m to 100 ⁇ m, 0.05 ⁇ m to 10 ⁇ m, 0.05 ⁇ m to 1 ⁇ m. it can.
- FIGS. 3 to 6 are diagrams for explaining a method of coating a clay film.
- 7 to 10 are cross-sectional views of an optical semiconductor device filled with a transparent sealing resin.
- a clay diluted solution in which clay is diluted with a solvent is generated.
- the clay diluted solution L is dropped or spread on the inner space 22 of the reflector 20.
- the dripping amount or the spraying amount of the clay diluent L is adjusted so that at least the entire silver plating layer 16 is covered with the clay diluent L.
- the solvent of the clay diluent L is dried.
- a clay film 50 in which the dried clay is laminated over the entire range covered with the clay diluent L is formed.
- the clay film 50 is formed over the entire range in which the clay diluent L is dropped or sprayed in this way, in order to cover only the silver plating layer 16 with the clay film 50, the clay film 50 is formed on the silver plating layer 16. Only clay dilution L needs to be dripped or sprayed. However, since the inner space 22 is very small, it is difficult to drop or spread the clay diluent L only on the silver plating layer 16 by adjusting the dripping amount or spreading amount of the clay diluent L.
- the clay film 50 formed to have a film thickness of 0.01 ⁇ m or more and 1000 ⁇ m or less using the clay described above has sufficient translucency, even if the clay film 50 is formed on the inner peripheral surface 20 a of the reflector 20.
- the reflection characteristics of the reflector 20 are not greatly affected.
- the thin film of montmorillonite, which is natural clay has an action of amplifying the frequency band of blue light
- the clay film 50 using montmorillonite, which is natural clay is formed on the reflector 20, and is emitted from the blue LED 30. The reflection efficiency of blue light can be increased.
- the clay diluent L is dropped or spread on the inner space 22 so that a part of the inner peripheral surface 20a of the reflector 20 is covered with the clay diluent. Then, as shown in FIG. 4B, the clay diluent L is dried to form a clay film 50 on a part of the inner peripheral surface 20 a of the reflector 20.
- the clay diluent L may be dropped or dispersed in the inner space 22 so that the entire inner peripheral surface 20a of the reflector 20 is covered with the clay diluent.
- FIG. 5B when the solvent of the clay diluent L is dried, a clay film 50 is formed on the entire inner peripheral surface 20a of the reflector 20.
- the clay dilution liquid L is dripped or spread
- the clay film 50 is formed up to the top surface 20b of the reflector 20.
- the inner space 22 formed by the inner peripheral surface 20a of the reflector 20 is filled with the transparent sealing resin 40 containing the phosphor 42, and the filled transparent sealing resin 40 is filled. Then, the blue LED 30 is sealed.
- the area of the uncovered portion U is preferably 1% or more, more preferably 5% or more, and further preferably 10% or more of the area of the inner peripheral surface 20a.
- the area of the uncovered portion U is preferably 99% or less of the area of the inner peripheral surface 20a, more preferably 95% or less, and still more preferably 90% or less.
- the clay film 50 can be easily covered. Furthermore, this effect can be further improved by setting the ratio of the uncovered portion U to 95% or less, and further to 90% or less.
- the clay film 50 is formed on the entire inner peripheral surface 20a of the reflector 20, as shown in FIG.
- the inner space 22 is filled with the transparent sealing resin 40 containing the phosphor 42 from the top to the top surface 20b, and the filled transparent sealing resin 40 is brought into close contact with the top surface 20b of the reflector 20.
- the optical semiconductor device 1 in which the top surface 20b of the reflector 20 and the transparent sealing resin 40 are joined is obtained.
- the clay film 50 is formed up to the top surface 20b of the reflector 20, as shown in FIG. 10, first, the clay film formed on the top surface 20b is formed. 50 is removed. Thereafter, the transparent sealing resin 40 containing the phosphor 42 is filled into the inner space 22 until the transparent sealing resin 40 overflows from the inner space 22 to the top surface 20b, and the top surface 20b of the reflector 20 is filled. The transparent sealing resin 40 is adhered. Thereby, the optical semiconductor device 1 in which the top surface 20b of the reflector 20 and the transparent sealing resin 40 are joined is obtained.
- the silver plating layer 16 is covered with the clay film 50, the sulfidation of the silver plating layer 16 can be suppressed. Thereby, the illumination intensity fall of the optical semiconductor device 1 by the silver plating layer 16 blackening can be suppressed significantly. Moreover, since the transparent sealing resin 40 and the reflector 20 are bonded, it is possible to suppress the transparent sealing resin 40 from being peeled off from the optical semiconductor device 1.
- the clay film 50 can be easily coated on the silver plating layer 16.
- the clay film 50 has an action of amplifying the frequency band of blue light, the reflection efficiency of the blue light generated from the blue LED 30 is increased by forming the clay film 50 on the inner peripheral surface 20a of the reflector 20. Can be made.
- the reflector 20 is described as being formed only of resin, but a light reflecting layer such as silver may be formed on the inner peripheral surface 20a of the reflector 20.
- the transparent sealing resin 40 can be bonded to the inner peripheral surface 20a or the top surface 20b of the reflector 20 on which the light reflecting layer is not formed.
- the base 12 and the reflector 20 have been described as separate members, but may be formed integrally.
- a square silver plating layer having a side of 2 mm is formed on a resin plate serving as a light reflecting portion, and a circular transparent sealing portion having a diameter of 1 mm is formed across the silver plating layer and the resin. It formed in five places.
- Polyphthalamide (Amodel A4122 as a commercial product, manufactured by Solvay Advanced Polymers Co., Ltd.) is used as the material for the resin plate, and methylsilicone (manufactured by Shin-Etsu Chemical Co., Ltd. as a commercial product) is used as the material for the transparent sealing portion. -2600 A / B) was used.
- a square silver plating layer having a side of 2 mm is formed on the resin to be the light reflecting portion, and circular transparent sealing portions having a diameter of 1 mm are formed only on the silver plating layer at five locations. Formed.
- the same material as that used in the example was used for the resin plate and the transparent sealing portion.
- the adhesive tape was peeled off from the Example and the comparative example.
- the transparent sealing part of the comparative example peeled, the transparent sealing part of the Example did not peel. From this, it can be inferred that, in the optical semiconductor device, it is possible to prevent the transparent sealing portion from being peeled off by joining the transparent sealing portion and the light reflecting portion.
- SYMBOLS 1 Optical semiconductor device, 10 ... Board
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Abstract
Description
Claims (6)
- 表面に銀めっき層が形成された基板と、
前記銀めっき層にボンディングされた発光ダイオードと、
前記発光ダイオードを取り囲む光反射部と、
前記光反射部に充填されて前記発光ダイオードを封止する透明封止部と、
前記銀めっき層を被覆する粘土膜と、
を有し、
前記透明封止部と前記光反射部とが接合されている、
光半導体装置。 - 前記光反射部が、前記発光ダイオードを取り囲むように前記基板から立ち上がって前記発光ダイオードを収容する内側空間を形成する内周面を備え、
前記粘土膜が、前記内周面の一部を被覆し、
前記透明封止部が、前記内周面の粘土膜で被覆されていない非被覆部と接合されている、
請求項1に記載の光半導体装置。 - 前記発光ダイオードは、青色光を発生する青色発光ダイオードである、
請求項2に記載の光半導体装置。 - 前記非被覆部の面積が、前記内周面の面積の1%以上である、
請求項2又は3に記載の光半導体装置。 - 前記非被覆部の面積が、前記内周面の面積の99%以下である、
請求項2~4の何れか一項に記載の光半導体装置。 - 前記光反射部が、前記発光ダイオードを取り囲むように前記基板から立ち上がって前記発光ダイオードを収容する内側空間を形成する内周面と、前記内周面に隣接して前記内側空間の外側に位置する頂面と、を備え、
前記粘土膜が、前記内周面を被覆し、
前記透明封止部が、前記頂面と接合されている、
請求項1に記載の光半導体装置。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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US14/405,946 US9525114B2 (en) | 2012-06-06 | 2013-06-06 | Optical semiconductor device |
KR1020147034832A KR20150029641A (ko) | 2012-06-06 | 2013-06-06 | 광 반도체 장치 |
JP2014520043A JP6164215B2 (ja) | 2012-06-06 | 2013-06-06 | 光半導体装置 |
CN201380029857.XA CN104364922A (zh) | 2012-06-06 | 2013-06-06 | 光半导体装置 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2012129028 | 2012-06-06 | ||
JP2012-129028 | 2012-06-06 |
Publications (1)
Publication Number | Publication Date |
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WO2013183706A1 true WO2013183706A1 (ja) | 2013-12-12 |
Family
ID=49712095
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2013/065688 WO2013183706A1 (ja) | 2012-06-06 | 2013-06-06 | 光半導体装置 |
Country Status (6)
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US (1) | US9525114B2 (ja) |
JP (1) | JP6164215B2 (ja) |
KR (1) | KR20150029641A (ja) |
CN (1) | CN104364922A (ja) |
TW (1) | TWI597865B (ja) |
WO (1) | WO2013183706A1 (ja) |
Families Citing this family (4)
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JP2017163058A (ja) * | 2016-03-10 | 2017-09-14 | パナソニックIpマネジメント株式会社 | Ledモジュール |
JP6817599B2 (ja) * | 2016-03-10 | 2021-01-20 | パナソニックIpマネジメント株式会社 | Ledモジュール |
US10672960B2 (en) | 2017-10-19 | 2020-06-02 | Lumileds Llc | Light emitting device package with a coating layer |
KR20200065074A (ko) * | 2017-10-19 | 2020-06-08 | 루미레즈 엘엘씨 | 발광 디바이스 패키지 |
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JP2008010591A (ja) * | 2006-06-28 | 2008-01-17 | Nichia Chem Ind Ltd | 発光装置およびその製造方法、パッケージ、発光素子実装用の基板 |
JP2008041706A (ja) * | 2006-08-01 | 2008-02-21 | Dainippon Printing Co Ltd | 発光装置および白色変換シート |
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JP2009224538A (ja) * | 2008-03-17 | 2009-10-01 | Citizen Holdings Co Ltd | 半導体発光装置 |
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KR20120131712A (ko) * | 2011-05-26 | 2012-12-05 | 엘지이노텍 주식회사 | 발광소자 패키지 |
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- 2013-06-06 WO PCT/JP2013/065688 patent/WO2013183706A1/ja active Application Filing
- 2013-06-06 US US14/405,946 patent/US9525114B2/en not_active Expired - Fee Related
- 2013-06-06 TW TW102120140A patent/TWI597865B/zh active
- 2013-06-06 JP JP2014520043A patent/JP6164215B2/ja not_active Expired - Fee Related
- 2013-06-06 CN CN201380029857.XA patent/CN104364922A/zh active Pending
- 2013-06-06 KR KR1020147034832A patent/KR20150029641A/ko not_active Application Discontinuation
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WO2005023714A1 (ja) * | 2003-09-08 | 2005-03-17 | National Institute Of Advanced Industrial Science And Technology | 粘土膜 |
JP2008010591A (ja) * | 2006-06-28 | 2008-01-17 | Nichia Chem Ind Ltd | 発光装置およびその製造方法、パッケージ、発光素子実装用の基板 |
JP2008041706A (ja) * | 2006-08-01 | 2008-02-21 | Dainippon Printing Co Ltd | 発光装置および白色変換シート |
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Also Published As
Publication number | Publication date |
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JP6164215B2 (ja) | 2017-07-19 |
US9525114B2 (en) | 2016-12-20 |
CN104364922A (zh) | 2015-02-18 |
KR20150029641A (ko) | 2015-03-18 |
JPWO2013183706A1 (ja) | 2016-02-01 |
TWI597865B (zh) | 2017-09-01 |
TW201405883A (zh) | 2014-02-01 |
US20150171293A1 (en) | 2015-06-18 |
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