WO2013118836A1 - Émulsion nettoyante pour la peau de type huile dans l'eau - Google Patents

Émulsion nettoyante pour la peau de type huile dans l'eau Download PDF

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Publication number
WO2013118836A1
WO2013118836A1 PCT/JP2013/052915 JP2013052915W WO2013118836A1 WO 2013118836 A1 WO2013118836 A1 WO 2013118836A1 JP 2013052915 W JP2013052915 W JP 2013052915W WO 2013118836 A1 WO2013118836 A1 WO 2013118836A1
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WIPO (PCT)
Prior art keywords
oil
mass
water
phase
emulsion
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PCT/JP2013/052915
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English (en)
Japanese (ja)
Inventor
義人 西島
桃 藪
謙太郎 安達
Original Assignee
株式会社 資生堂
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Publication of WO2013118836A1 publication Critical patent/WO2013118836A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the present invention relates to an oil-in-water emulsified skin cleansing material. More particularly, the present invention relates to a cleansing cosmetic composition for removing a make-up cream or cream.
  • makeup cosmetics contain a large amount of oil, and skin cleans intended to remove the oil contain an oil for dissolving and dispersing the oil and / or an interface for emulsifying the oil.
  • An active agent is blended. Therefore, a skin cleanser with a higher blending amount of oil and surfactant basically has a higher detergency.
  • the detergency and the speed of cleaning i.e. , Make-up familiarity
  • the L2 phase skin cleanser has an oily phase that is continuous with the make-up and can exhibit excellent cleaning power. However, it is difficult to remove by washing with water, and the skin after washing is oily. There is a problem of becoming addicted.
  • the L ⁇ -phase skin cleanser has a high viscosity and a heavy feel when applied, and the familiarity with the makeup occurs after the hard liquid crystal structure collapses, so that the familiarity with the makeup is slow. It is known that the Lc Present phase skin cleanser has no problem in terms of rinsing, but because it is slow in its make-up, it cannot be said that its cleaning power is sufficient, and it also has a squeaky feeling derived from the liquid crystal structure.
  • the L1 phase has a small blend of oil and surfactant, and a small amount of oil is stably retained as an internal phase (ie, Solubilized) is a phase in which excellent detergency and quick make-up cannot be expected.
  • the nature of the phase states included in the Multi Phase phase is very diverse.
  • the cleaning power is relatively high, but it is difficult to wash with water and the washed skin becomes oily.
  • an oil-in-water emulsified phase although it has a low detergency and a slow make-up, it has a desirable property as a skin cleanser that is well washed away and does not feel oily after washing.
  • Both phases give a smooth feel unique to an emulsified phase, but in particular, emulsions and creams are very popular with consumers because they are easy to handle and excellent in use.
  • Patent Document 1 emulsion-creamy oil-in-water emulsified skin cleansing agents.
  • these products are used to maintain the emulsion stability.
  • the blending amount of the oil and the surfactant is kept low (particularly, the surfactant is usually 5% by mass or less). Therefore, the problem was low detergency and slow make-up.
  • the present invention has been made in view of the above-mentioned problems of the prior art, and its purpose is to provide a milky-creamy form that has a high detergency, has a fast make-up, is excellent in emulsification stability, is easy to wash out, and is smooth and easy to stretch.
  • An object of the present invention is to provide an oil-in-water emulsified skin cleansing material (particularly a cleansing cosmetic for make-up removal).
  • oil content is 45 to 70% by mass
  • HLB 8 to 14 polyoxyethylene mono fatty acid glyceryl is 10 to 30% by mass
  • water is 10 to 45% by mass.
  • An oil-in-water emulsified skin cleansing agent containing 0.01 to 1% by mass of a thickener and having a milky to creamy form is provided.
  • an oil-in-water emulsified skin cleanser of the type to be washed away is provided.
  • the oil-in-water emulsified skin cleansing material of the present invention can be suitably used as a cleansing cosmetic for make-up removal.
  • an emulsion-cream oil-in-water emulsified skin cleanser with high detergency, quick make-up, excellent emulsification stability, easy to wash out, and smooth and easy to stretch is provided.
  • the oil-in-water emulsified skin cleansing material of the present invention can be suitably used as a cleansing cosmetic for make-up removal.
  • POE represents polyoxyethylene
  • PEG represents polyethylene glycol
  • the numbers in parentheses indicate the number of added moles.
  • any liquid, semi-solid, or solid oil that is commonly used in normal cosmetics, pharmaceuticals, and the like can be used.
  • oils include fats and oils, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, synthetic ester oils, silicone oils, and the like.
  • oils avocado oil, camellia oil, evening primrose oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, trioctanoic acid glycerin, triisopalmitic acid Liquid fats such as glycerin; cacao butter, palm oil, horse fat, hydrogenated palm oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, cow leg
  • solid fats and oils such as fat, mole,
  • the waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, lauryl hexyl, reduced lanolin, jojojo Examples include a wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, and the like.
  • hydrocarbon oil examples include liquid paraffin, isodecane, isododecane, isohexadecane, ozokerite, squalene, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax, and the like.
  • Higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, 12-hydroxystearic acid, undecylenic acid, tolic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) and the like are exemplified.
  • Higher alcohols include linear alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol; monostearyl glycerin ether (batyl alcohol), 2-decyltetradecinol, lanolin alcohol, Examples thereof include branched chain alcohols such as cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, and octyldodecanol.
  • Synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearylate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, N-alkylglycol monoisostearate, neopentyl glycol dicaprate, malic acid Diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexyl tri
  • silicone oil examples include linear polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane; cyclic polysiloxanes such as decamethylpolysiloxane, dodecamethylpolysiloxane, and tetramethyltetrahydrogenpolysiloxane; 3 Examples thereof include silicone resin and silicone rubber forming a three-dimensional network structure.
  • the component is a detergency component.
  • the above oil can be arbitrarily used.
  • a hydrocarbon oil having a relatively low molecular weight For example, liquid paraffin, isododecane, etc.
  • synthetic ester oil eg, cetyl octoate, octyl palmitate, etc.
  • silicone oil etc.
  • a component can use 1 type (s) or 2 or more types.
  • the blending amount of component (a) is 45 to 70% by mass, preferably 50 to 65% by mass, and most preferably 55 to 60% by mass in the skin cleanser of the present invention. If it is less than 45% by mass, sufficient detergency cannot be obtained. On the other hand, if it exceeds 70% by mass, sufficient emulsion stability cannot be obtained, which is not preferable.
  • the component (b) is polyoxyethylene monofatty acid glyceryl having an HLB of 8 to 14, preferably an HLB of 10 to 13.
  • HLB is lower than 8
  • HLB is higher than 14
  • Palm oil fatty acid glyceryl can be suitably used, and commercially available products include Emalex GWIS-108 (Nippon Emulsion Co., Ltd.), Emarex GWIS-120 (Nippon Emulsion Co., Ltd.), Cethiol HE ( Cognis Japan Co., Ltd.).
  • the amount of component (b) is 10 to 30% by mass, preferably 15 to 25% by mass, and most preferably 15 to 20% by mass in the skin cleanser of the present invention. If it is less than 10% by mass, the effect of easy washing is not obtained, whereas if it exceeds 30% by mass, it is not preferable from the viewpoint of emulsion stability.
  • a nonionic surfactant other than the polyoxyethylene monofatty acid glyceryl of HLB 8 to 14 can be blended within a range not impairing the effects of the present invention.
  • the component (c) is water.
  • the amount of component (c) is 10 to 45% by mass in the skin cleanser of the present invention.
  • the oil-in-water emulsified skin cleansing agent of the present invention containing the above components (a) to (c) as essential components has a milky lotion to a creamy shape, and is easy to wash, easy to wash off, smooth when used, Excellent emulsification stability.
  • Milky to creamy has a viscosity range of about 100 to 100,000 mPa ⁇ s (measured at 30 ° C., B-type viscometer, 12 rotations / minute) (as a general guideline, emulsion: 100 to 10,000 mPa ⁇ s, cream form: 10,000 to 100,000 mPa ⁇ s).
  • a thickener can be suitably blended in order to improve the ease of stretching during use.
  • a thickener is particularly preferably a polysaccharide thickener, and examples thereof include xanthan gum, succinoglycan, agar, carrageenan, gellan gum, guar gum, locust bean gum and the like.
  • succinoglycan and xanthan gum are preferable.
  • succinoglycan when succinoglycan is used, it is possible to obtain an improvement effect on the emulsification stability and the skin feel after washing (no stickiness or smoothness).
  • thickeners such as carboxyvinyl polymer and alkyl-modified carboxyvinyl polymer can be blended in addition to the polysaccharide thickener.
  • the component (d) When the component (d) is blended, it is preferably about 0.01 to 2.5% by mass, more preferably 0.01 to 1% by mass, and most preferably 0.1 to 2.5% by mass in the skin cleanser of the present invention. 0.5% by mass.
  • the oil-in-water type emulsified skin cleansing agent of the present invention further comprises (e) an anionic surfactant as a surfactant in addition to the above component (b) from the viewpoint of further improving the emulsion stability. You may mix
  • alkyl glycol acetates such as lauryl glycol acetate
  • POE alkyl sulfonates such as POE sulfosuccinate
  • POE alkyl ether sulfates such as POE lauryl ether sulfate
  • alkyl taurines such as cocoyl methyl taurate Salts
  • N-acyl-glutamate salts such as sodium N-lauroyl-L-glutamate
  • N-acylglycine salts such as sodium N-coconut fatty acid acylglycine
  • fatty acid salts such as sodium laurate.
  • the component (e) When the component (e) is blended, it is preferably about 0.01 to 10% by mass, more preferably 0.05 to 5% by mass, and most preferably 0.1 to 2% by mass in the skin cleanser of the present invention. It is.
  • the oil-in-water emulsified skin cleanser of the present invention usually contains additional components that can be incorporated into the cleanser, such as moisturizers, preservatives, powders, pigments, fragrances, pH adjusters, etc., It can mix
  • the oil-in-water emulsified skin cleansing material of the present invention is preferably a wash-off type.
  • the skin cleansing agent of the present invention can be easily washed away with water, and a refreshing feeling can be obtained.
  • the oil-in-water emulsified skin cleansing material of the present invention is particularly suitably used as a makeup removing cosmetic for removing makeup cosmetics such as foundation, lipstick, eye makeup (mascara, eyeline, etc.).
  • D (%) [(RW ⁇ RS) / (R0 ⁇ RS)] ⁇ 100
  • D Cleaning rate (%)
  • R0 Reflectivity (%) of artificial leather before applying makeup cosmetics
  • RS Reflectivity of artificial leather after applying makeup cosmetic (%)
  • RW Artificial leather reflectance after washing (%) (Criteria)
  • X The cleaning rate is less than 80%.
  • Emulsification stability In order to evaluate the stability (emulsification stability with time) of the skin cleanser of the present invention, the appearance after standing at 50 ° C. for 1 month is visually observed, and the stability is observed according to the following criteria. evaluated.
  • ⁇ Oil floating, separation, and other appearance changes were not observed. Although there was a slight change in the emulsified particle size, there was no practical problem.
  • X Significant changes in appearance such as remarkable oil floating, oil phase separation, and viscosity change occurred.
  • Ease of rinsing of the skin cleansing material of the present invention was evaluated by eight specialist panels, with ease of rinsing after washing with water (use of W / O liquid foundation as makeup cosmetic). Judgment was made. (Criteria) ⁇ : All 8 responded that it was easy to wash away with water after make-up removal. ⁇ : 5 to 7 out of 8 responded that it was easy to wash away with water after make-up removal. ⁇ : 0 to 4 out of 8 responded that it was easy to wash away with water after make-up removal.
  • Ease of use during use In order to evaluate the easiness of use of the skin cleansing material of the present invention, eight specialist panels evaluated the easiness of use during use according to the following criteria. (Criteria) A: All eight responded that it was easy to extend when in use. ⁇ : 5 to 7 out of 8 responded that it is easy to extend during use. ⁇ : 0 to 4 out of 8 responded that it was easy to extend during use.
  • HLB 8 to 14
  • cleaning material (a) the washing
  • cleaning material (Example 2, 3) which replaced a part of oil component ( cetyl octanoate) with isododecane, dimethylpolysiloxane, and methylphenylpolysiloxane, further improvement of the detergency was achieved. Admitted.
  • the cleaning agent containing 15% by mass (Examples 1 to 3), 20% by mass (Example 4) and 25% by mass (Example 5) of glyceryl and POE (7) coconut oil fatty acid glyceryl is a stable oil-in-water solution. Formed emulsified phase, it was revealed that it was excellent in make-up familiarity and easiness of spreading, and also excellent in detergency, washability and smoothness during use.
  • the carboxyvinyl polymer, xanthan gum, succinoglycan, or a cleaning agent containing 0.1 to 0.15% by mass of these in combination was extremely excellent in easiness of extension during use ( Examples 1 to 9).
  • succinoglycan was blended, it was shown that the emulsion stability and smoothness during use were further improved (comparison between Example 2 and Examples 8 and 9).
  • a skin cleanser with further improved emulsification stability can be obtained by further adding (e) an anionic surfactant to the oil-in-water emulsified skin cleanser of the present invention containing 10 to 45% by mass of water. It was shown that.
  • a skin cleansing material having the following formulation was prepared according to a conventional method, and the aforementioned performance evaluation was performed. All skin cleansers were emulsion-creamy oil-in-water emulsified phases with high detergency and quick make-up, and excellent emulsification stability, washability, smoothness, and ease of extension.
  • Formulation Example 1 (cleansing milk, emulsion) Formulation Amount (% by mass) (1) Liquid paraffin 30.0 (2) Cetyl octanoate 10.0 (3) Isododecane 10.0 (4) Dimethylpolysiloxane (6cs) 5.0 (5) POE (8) glyceryl monoisostearate * 2 5.0 (6) POE (7) Palm oil fatty acid glyceryl * 4 5.0 (7) Sodium lauryl glycol acetate 1.0 (8) Succinoglycan 0.1 (9) Acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer (polyquaternium-39) 1.0 (10) 1,3-butylene glycol 2.0 (11) Edetate 0.2 (12) Purified water residue
  • Formulation Example 2 (cleansing milk, emulsion) Formulation Amount (% by mass) (1) Liquid paraffin 45.0 (2) Cetyl octanoate 25.0 (3) POE (7) Palm oil fatty acid glyceryl * 4 15.0 (4) Carboxyvinyl polymer 0.2 (5) Succinoglycan 0.03 (6) Dipropylene glycol 1.0 (7) Potassium hydroxide 0.05 (8) Edetate 0.2 (9) Purified water residue
  • Formulation Example 3 (cleansing milk, cream) Formulation Amount (% by mass) (1) Liquid paraffin 50.0 (2) Cetyl octanoate 10.0 (3) POE (8) glyceryl monoisostearate * 2 10.0 (4) Carboxyvinyl polymer 0.6 (5) Dipropylene glycol 1.0 (6) Highly polymerized polyethylene glycol (PEG-90M) 0.03 (7) Potassium hydroxide 0.30 (8) Edetate 0.2 (9) Purified water residue
  • Formulation Example 4 (cleansing milk, cream) Formulation Amount (% by mass) (1) Liquid paraffin 20.0 (2) Cetyl octanoate 25.0 (3) POE (7) Palm oil fatty acid glyceryl * 4 15.0 (4) Carboxyvinyl polymer 0.8 (5) Succinoglycan 0.1 (6) Dipropylene glycol 1.0 (7) Dimethyl diallylammonium chloride / acrylamide copolymer (polyquaternium-7) 0.5 (8) Potassium hydroxide 0.4 (9) Edetate 0.2 (10) Purified water residue
  • Formulation Example 5 (cleansing milk, emulsion) Formulation Amount (% by mass) (1) Liquid paraffin 25.0 (2) Cetyl octanoate 25.0 (3) POE (7) Palm oil fatty acid glyceryl * 4 30.0 (4) Carboxyvinyl polymer 0.2 (5) Dipropylene glycol 1.0 (6) Potassium hydroxide 0.1 (7) Edetate 0.2 (8) Purified water residue
  • Formulation Example 6 (cleansing milk, emulsion) Formulation Amount (% by mass) (1) Liquid paraffin 20.0 (2) Cetyl octanoate 25.0 (3) POE (7) Palm oil fatty acid glyceryl * 4 15.0 (4) Diisostearic acid PEG-12 2.0 (5) Carboxyvinyl polymer 0.15 (6) Succinoglycan 0.1 (7) Dipropylene glycol 1.0 (8) Dimethyldiallylammonium chloride / acrylamide copolymer (polyquaternium-7) 0.5 (9) Potassium hydroxide 0.4 (10) Edetate 0.2 (11) Purified water residue
  • Formulation Example 7 (cleansing milk, emulsion) Formulation Amount (% by mass) (1) Liquid paraffin 20.0 (2) Cetyl octanoate 25.0 (3) POE (10) glyceryl monoisostearate 15.0 (4) PEG-10 monoisostearate 3.0 (5) Carboxyvinyl polymer 0.15 (6) Glycerin 2.0 (7) Dimethyl diallylammonium chloride / acrylamide copolymer (polyquaternium-7) 0.5 (8) Potassium hydroxide 0.4 (9) Edetate 0.2 (10) Purified water residue

Abstract

Cette invention concerne une émulsion nettoyante pour la peau de type huile dans l'eau douée d'une performance de nettoyage élevée, qui peut être rapidement mélangée à un produit de maquillage, a une excellente stabilité d'émulsion, s'élimine facilement par simple lavage, est lisse et par conséquent facile à étaler, et est sous la forme d'une émulsion ou d'une crème. L'émulsion nettoyante pour la peau de type huile dans l'eau selon l'invention comprend (a) 45 à 70 % en poids d'un composant huileux, (b) 10 à 30 % en poids d'un glycéryle de monoacide gras de polyoxyéthylène ayant un indice HLB de 8 à 14, (c) 10 à 45 % en poids d'eau et (d) 0,01 à 1 % en poids d'agent épaississant et est sous la forme d'une émulsion ou d'une crème.
PCT/JP2013/052915 2012-02-07 2013-02-07 Émulsion nettoyante pour la peau de type huile dans l'eau WO2013118836A1 (fr)

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JP2012-023680 2012-02-07

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JP2017197434A (ja) * 2016-04-25 2017-11-02 花王株式会社 水中油型日焼け止め化粧料
US11213463B2 (en) * 2015-07-09 2022-01-04 Shiseido Company, Ltd. Oil-in-water type cosmetic composition

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WO2015111249A1 (fr) * 2014-01-23 2015-07-30 株式会社マンダム Feuille nettoyante
JP6036874B2 (ja) * 2014-02-21 2016-11-30 学校法人神奈川大学 クレンジング組成物及びクレンジング用品
JP2016124866A (ja) * 2014-12-26 2016-07-11 日光ケミカルズ株式会社 クレンジング化粧料
JP6845649B2 (ja) * 2016-09-29 2021-03-24 川研ファインケミカル株式会社 脂肪酸アルカノールアミド誘導体混合物を含有する含有するクレンジング組成物

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Publication number Priority date Publication date Assignee Title
US11213463B2 (en) * 2015-07-09 2022-01-04 Shiseido Company, Ltd. Oil-in-water type cosmetic composition
JP2017197434A (ja) * 2016-04-25 2017-11-02 花王株式会社 水中油型日焼け止め化粧料

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