WO2013064575A1 - Verfahren zum thermischen aufbereiten eines hilfsmaterials und aufbereitungsanlage - Google Patents
Verfahren zum thermischen aufbereiten eines hilfsmaterials und aufbereitungsanlage Download PDFInfo
- Publication number
- WO2013064575A1 WO2013064575A1 PCT/EP2012/071627 EP2012071627W WO2013064575A1 WO 2013064575 A1 WO2013064575 A1 WO 2013064575A1 EP 2012071627 W EP2012071627 W EP 2012071627W WO 2013064575 A1 WO2013064575 A1 WO 2013064575A1
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- WO
- WIPO (PCT)
- Prior art keywords
- auxiliary material
- pollutant
- fluidized bed
- gas stream
- filter
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D37/00—Processes of filtration
- B01D37/02—Precoating the filter medium; Addition of filter aids to the liquid being filtered
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D41/00—Regeneration of the filtering material or filter elements outside the filter for liquid or gaseous fluids
- B01D41/02—Regeneration of the filtering material or filter elements outside the filter for liquid or gaseous fluids of loose filtering material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/66—Regeneration of the filtering material or filter elements inside the filter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
- B01D53/12—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents according to the "fluidised technique"
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/83—Solid phase processes with moving reactants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B14/00—Arrangements for collecting, re-using or eliminating excess spraying material
- B05B14/40—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths
- B05B14/43—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths by filtering the air charged with excess material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B16/00—Spray booths
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B7/00—Selective separation of solid materials carried by, or dispersed in, gas currents
- B07B7/01—Selective separation of solid materials carried by, or dispersed in, gas currents using gravity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B7/00—Selective separation of solid materials carried by, or dispersed in, gas currents
- B07B7/08—Selective separation of solid materials carried by, or dispersed in, gas currents using centrifugal force
- B07B7/10—Selective separation of solid materials carried by, or dispersed in, gas currents using centrifugal force having air recirculating within the apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
- F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
- F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
- F23C10/12—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated exclusively within the combustion zone
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/022—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
- F23J15/025—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0258—Other waste gases from painting equipments or paint drying installations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2273/00—Operation of filters specially adapted for separating dispersed particles from gases or vapours
- B01D2273/12—Influencing the filter cake during filtration using filter aids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B14/00—Arrangements for collecting, re-using or eliminating excess spraying material
- B05B14/40—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B14/00—Arrangements for collecting, re-using or eliminating excess spraying material
- B05B14/40—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths
- B05B14/43—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths by filtering the air charged with excess material
- B05B14/437—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths by filtering the air charged with excess material with means for introducing solid material into the air charged with excess material for preventing clogging of the filter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B15/00—Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/60—Sorption with dry devices, e.g. beds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Definitions
- the present invention relates to a process for the thermal treatment of an auxiliary material which can be introduced into the raw gas stream for the purification of a crude gas stream laden with an organic pollutant and together with the organic pollutant forms a stable system of pollutant and auxiliary material.
- auxiliary material loaded with pollutant can be processed in a wet-chemical process.
- the present invention has for its object to provide a method for the thermal treatment of an auxiliary material, which is simple and resource-saving feasible.
- This object is achieved by a method for the thermal treatment of an auxiliary material in which the auxiliary material for cleaning a laden with an organic pollutant crude gas stream is introduced into the crude gas stream, wherein the auxiliary material forms a stable system of pollutant and auxiliary material together with the pollutant.
- the method comprises:
- a filter auxiliary material is selected as the auxiliary material, which is used to clean a loaded with a pollutant in the form of paint overspray crude gas stream, wherein the filter aid with the paint overspray a stable under normal conditions system with paint -Overspray laden filter auxiliary material forms, which is deposited on a filter device.
- the treatment device contains or comprises a fluidized bed base material.
- the fluidized bed base material has a chemical composition that corresponds to the chemical composition of a material used as auxiliary material.
- the loaded with pollutant auxiliary material can be easily prepared in particular by the common stirring up with a fluidized bed base material.
- normal conditions is to be understood in particular a temperature between about 20 ° C and about 30 ° C.
- the carrier gas stream may for example comprise air or consist of air. Furthermore, it can be provided that the carrier gas stream comprises nitrogen or one or more other inert gases or consists of nitrogen or one or more other inert gases.
- the carrier gas stream may in particular comprise or consist of a reactive gas or gas mixture and / or an inert gas or gas mixture for supporting the thermal treatment.
- auxiliary material in particular any medium can be used which is capable of absorbing a liquid portion of the pollutant.
- Auxiliary material is preferably a particulate and / or powdery material.
- auxiliary materials for example, lime, stone powder, in particular limestone powder, aluminum silicates, aluminum oxides, silicon oxides, powder coating or the like into consideration.
- particles having a cavity structure and relative to their outer dimensions of large inner surface can be used as auxiliary material for receiving and / or binding the pollutant, for example natural and / or synthetic zeolites or other hollow, for example spherical, body of polymers, glass or aluminum silicate and / or natural or synthetically produced fibers.
- pollutant for example natural and / or synthetic zeolites or other hollow, for example spherical, body of polymers, glass or aluminum silicate and / or natural or synthetically produced fibers.
- Alumina silicates which have the general empirical formula M n + x / n [(AlO 2 ) x - (SiO 2 ) y ] .z H 2 O are in particular called zeolites
- M n + metal cation
- module aluminate anion
- calcium, magnesium, calcium magnesium, sodium and / or potassium zeolites may be used.
- mixtures of two or more of these types of zeolites are used.
- chemically reacting with the pollutant particles can be used as auxiliary material for receiving and / or binding of the pollutant, for example, chemically reactive particles with amine, epoxy, carboxyl, hydroxyl or isocyanate groups, chemically reactive particles with octylsilane aftertreated alumina or solid or liquid mono-, oligo- or polymers, silanes, silanols or siloxanes.
- the auxiliary material preferably consists of a plurality of auxiliary material particles, which in particular have a mean diameter in the range of about 10 ⁇ to about 100 ⁇ .
- the auxiliary material is, in particular, a flowable, particulate material which, for example in the form of filter aid material, is also referred to as "precoat" material.
- the filter aid serves in particular to deposit itself as a barrier layer on the surface of a filter element, in order to prevent this surface from sticking to it by adhering paint overspray particles.
- periodic cleaning of the filter element passes a system of pollutant and auxiliary material, in particular paint overspray and filter aid, from the filter element in a receptacle.
- a pollutant-laden auxiliary material may be, in particular, a mixture or a system of pollutant particles and auxiliary material particles.
- the mixture may comprise conglomerates and / or agglomerates of particles of pollutant and particles of auxiliary material.
- Particles of pollutants are especially paint droplets.
- Particles of auxiliary material are especially stone meal granules.
- Auxiliary material which can be used for purifying the pollutant-laden crude gas stream preferably has a particle size distribution which makes it possible for at least a majority of the particles of the auxiliary material to be entrained and / or absorbed by the crude gas stream.
- a fluidized bed base material chemically substantially the auxiliary material, in particular the reprocessed
- Auxiliary material corresponds.
- a material which corresponds essentially to the auxiliary material chemically is in particular a material which has essentially the same chemical composition as the auxiliary material.
- a material substantially chemically corresponding to the auxiliary material is formed from the same substance as the auxiliary material.
- the fluidized bed base material comprises a chemically different auxiliary material from the auxiliary material to be processed.
- the fluidized bed base material has a chemical composition which, optionally after performing a comminuting operation of the fluidized bed base material, allows the use of the fluidized bed base material as an auxiliary material.
- the fluidized bed base material is compatible with the auxiliary material to be reprocessed, so that a mixture of processed auxiliary material and optionally comminuted fluidized bed base material can be used to purify a pollutant-laden crude gas stream.
- any particulate material may preferably be used. This may in particular be an inorganic and / or flowable material. It can be used as a pure substance, eg. As limestone, or as a mixture of different materials, eg. B. as a mixture of limestone and zeolite present.
- a fluidized bed is preferably produced, in particular a bubble-forming and / or a circulating fluidized bed.
- the treatment device is designed in particular as a fluidized bed furnace.
- a filter device is preferably a regenerable filter device.
- a regenerable filter device Under a regenerable filter device is a separation device for separating impurities from a guided through a paint gas stream, in particular for separating pollutants, in particular paint overspray, from a pollutant-containing crude gas to understand, in which deposited impurities can be cleaned without filter elements of To replace filter device.
- a regenerable filter device is in particular also to be understood as meaning a filter device which has one or more dry filter elements and / or dry separation devices in which a gas stream is purified substantially without the addition of a liquid to the filter elements. Irrespective of this, subsequent or upstream purification stages can in turn be provided using (under normal conditions) liquid solvents or cleaning agents.
- the filter device comprises at least one filter element which, in filter operation, is provided with a barrier layer and / or a protective layer which comprises filter aid material, in particular limestone powder.
- fluid paint is here - in contrast to the term
- Powder paint a paint with a flowable consistency, from liquid to pasty (for example, in the case of a PVC plastisol) referred.
- fluid paint includes in particular the terms “liquid paint” and “wet paint”.
- the paint overspray from the painting device is thus a fluid paint overspray; when wet paint is used, a wet paint overspray.
- the median of the particle size distribution of the fluidized bed base material is greater than the median particle size distribution of the auxiliary material usable for purifying the crude gas stream and / or as the median particle size distribution of the pollutant-laden auxiliary material, in particular the system of pollutant and auxiliary material.
- the median of the particle size distribution is the particle size which is not reached by 50% of the particles present, while the other 50% of the particles present are larger than this particle size.
- the median particle size distribution of the fluidized bed base material is at least about twice, in particular three times, for example ten times, the median of the particle size distribution of the auxiliary material usable for purifying the crude gas stream and / or the median particle size distribution of the pollutant-laden auxiliary material.
- the median of the particle size distribution of the fluidized bed base material is at most approximately one hundred times, in particular at most about fifty times, in particular at most about thirty times, the median of the particle size distribution of the auxiliary material usable for purifying the crude gas stream and / or the median particle size distribution of the pollutant-laden auxiliary material.
- the pollutant-laden auxiliary material is heated in the treatment device, so that agglomerates of pollutant and auxiliary material are broken.
- the pollutant-laden auxiliary material is heated in the treatment device, so that the pollutant is at least partially converted, while leaving particles of the auxiliary material unchanged.
- particles of the auxiliary material remain chemically unchanged.
- a particle is both a solid particles, especially in the case of the filter aid material, as well as a drop, especially in the case of paint overspray to understand.
- drying and / or chemical conversion of the pollutant preferably takes place.
- the pollutant in particular the particles of paint overspray, can thereby either completely converted, for example, burned, or at least loses any previously existing adhesive property, so that the agglomerates of pollutant and auxiliary material in particles of the auxiliary material, optionally with residues of pollutant, disintegrated.
- the pollutant-laden auxiliary material is heated in the treatment device at most to about 550 ° C, for example to at most about 500 ° C, to undesirable chemical transformation of the limestone flour, especially the calcium carbonate , to prevent.
- the treatment device is preferably operated such that a bubble-forming and / or a circulating fluidized bed is formed.
- a receptacle for the fluidized bed has a cross-section which widens upward in the direction of the direction of gravity, whereby a so-called "freeboard" can be formed.
- the treatment device is operated such that a gradient in the particle size distribution of the auxiliary material, in particular a mixture of pollutant-laden auxiliary material and / or fluidized bed base material is formed, wherein the median of
- Particle size distribution of the auxiliary material, in particular of the mixture increases in the direction of gravity downwards.
- Small particles of the auxiliary material in particular those without contamination by pollutants, and preferably abrasion of the fluidized bed base material preferably accumulate in an upper region of the auxiliary material with respect to the direction of gravity, in particular of the mixture of pollutant-laden auxiliary material and fluidized bed base material.
- the auxiliary material laden with pollutant is supplied to the fluidized bed in a lower region of a gravitational direction of a fluidized bed produced in the thermal treatment device by fluidization.
- a particularly long residence time of the pollutant-laden auxiliary material in the mixture of pollutant-laden auxiliary material and / or fluidized bed base material can be made possible.
- Particles of the system of pollutant and auxiliary material, particles of the processed auxiliary material and / or particles of a fluidized bed base material, which preferably collect in a gravitational direction at the top of a swirling fluidized bed or are carried out of the fluidized bed, are preferably removed from the treatment apparatus.
- the particles are removed by means of an overflow of the treatment device from the processing device.
- the discharged particles are preferably usable for purifying the crude gas stream as an auxiliary material.
- the carrier gas stream may be guided from the bottom upwards through the auxiliary material in order to swirl auxiliary material against the direction of the gravitational force.
- the carrier gas flow is conducted to raise the auxiliary material against the direction of gravity from bottom to top by the auxiliary material, wherein the carrier gas stream is supplied before and / or after flowing through the auxiliary material of a separator and / or a combustion device. In this way, an undesirable escape of potentially harmful substances from the treatment device can be avoided.
- a separation device may in particular be a filter device, for example a hot gas filter, or a cyclone.
- the carrier gas stream which is preferably guided through the auxiliary material for the purpose of fluidizing the auxiliary material, can be heated in particular by means of a heating device. As it flows through the auxiliary material, the auxiliary material can be heated thereby.
- the combustion device comprises a thermal afterburning device.
- the combustion device comprises a thermal afterburning device.
- particles of the auxiliary material and / or particles of a fluidized bed base material are discharged by means of the carrier gas flow from a fluidized bed generated by fluidization and deposited on the separation device for removal from the treatment device.
- the separation device can in particular be spatially separated from a receptacle for the fluidized bed, for example offset laterally. This is particularly effectively reduced or completely avoided that deposited on the deposition device material back into the receptacle of the treatment device in which the fluidized bed is formed passes.
- the particles of the pollutant-laden auxiliary material and / or the particles of a fluidized bed base material, which are preferably removed from the treatment device, are particularly useful for purifying the crude gas stream.
- This auxiliary material is thus a processed auxiliary material.
- the carrier gas flow is conducted to raise the auxiliary material against the direction of gravity from bottom to top by the auxiliary material, wherein the carrier gas stream before and / or after flowing through the auxiliary material is fed to a heat exchanger and / or a drying device for drying workpieces , In this way, the heat present in the carrier gas stream can be efficiently reused.
- the carrier gas flow is used in particular for the generation and / or the
- the discharged carrier gas stream is supplied in particular to a drying device for drying vehicle bodies.
- the heat contained in the carrier gas stream is transferred by means of a heat exchanger to other gas streams or other fluid streams.
- the heat contained in the discharged carrier gas stream is transferred by means of a heat exchanger to supply air for a drying device for drying workpieces, in particular vehicle bodies.
- the carrier gas stream may further comprise a drying device for
- Dismounting of workpieces and / or heated prior to its delivery to the treatment device by means of a heat exchanger and a fluid flow from the drying device.
- a control device for controlling and / or regulating the devices and systems and the components of the devices and systems.
- a treatment plant can be controlled and / or regulated by means of at least one control device according to the inventive method.
- the present invention further relates to a treatment plant for the thermal treatment of an auxiliary material which can be introduced into the crude gas stream for purifying a crude gas stream laden with an organic pollutant and together with the organic pollutant forms a stable system of pollutant and auxiliary material.
- the invention is in this respect the task of providing a treatment plant, by means of which auxiliary material is easy and resource-friendly reprocessed.
- thermal treatment device for chemically reacting at least a portion of the organic pollutant to produce a conditioned auxiliary material
- a feeding device for supplying the system of pollutant and auxiliary material and a carrier gas stream heated to normal conditions to the thermal processing device
- a discharge device for discharging the processed auxiliary material from the processing device.
- the treatment plant according to the invention preferably has one or more of the features and / or advantages described in connection with the method according to the invention for the thermal treatment of an auxiliary material.
- the auxiliary material loaded with pollutant by means of the feed device in a direction of gravity lower portion of a fluidized bed produced by a fluidization in the thermal treatment device of the fluidized bed can be fed.
- the auxiliary material loaded with pollutant for this purpose can be fed to a lower region of a receiving device of the treatment device for receiving the auxiliary material and / or a fluidized bed base material with respect to the direction of the gravitational force.
- the treatment device is designed in particular as a fluidized bed furnace.
- the processing device comprises a receptacle which comprises a gas-permeable bottom.
- the material accommodated in the receptacle in particular a fluidized bed base material and / or auxiliary material loaded with pollutant, can be particularly easily flowed through, flowed through and thus swirled up with gas, in particular carrier gas.
- the treatment plant comprises a heating device, by means of which the receptacle, the gas-permeable bottom and / or the supplied gas, that is to say the carrier gas stream, can be heated.
- particles of the auxiliary material, in particular of the pollutant-laden auxiliary material, and / or particles of a fluidized bed base material can be discharged in an upper region of a fluidized bed produced by fluidization in a direction of gravity.
- an overflow can be provided for this purpose.
- the treatment plant comprises a separation device and / or a combustion device, to which the carrier gas stream can be fed, which in particular for swirling a
- the processing plant according to the invention is particularly suitable for use in a paint shop.
- the present invention further relates to a paint shop for painting workpieces.
- the invention is in this respect the task of providing a paint shop, which is particularly simple or resource-friendly operable.
- the painting installation for painting workpieces, in particular vehicle bodies comprises the following:
- a painting device by means of which the workpieces can be painted with paint
- a filter device for cleaning a generated in the paint, loaded with paint overspray raw gas stream by supplying filter aid to the raw gas stream and depositing the paint overspray together with the filter aid to a filter element of the filter device;
- organic pollutant is paint overspray and wherein the auxiliary material is filter aid.
- the painting plant according to the invention is particularly simple and resource-saving operable.
- the paint shop preferably further comprises a mixing device, by means of which fresh auxiliary material and processed auxiliary material can be brought together and mixed.
- the mixed auxiliary material is preferably fed to the filter device of the paint shop.
- the paint shop comprises at least one measuring device for measuring and / or determining a proportion of pollutant in the pollutant-laden auxiliary material, that is, a degree of loading of the auxiliary material with pollutant.
- the process according to the invention, the treatment plant according to the invention and / or the coating plant according to the invention can have one or more of the features and / or advantages described below:
- An attrition of particles of a fluidized bed base material is preferably used to dilute the auxiliary material to be processed, in particular residual material optionally remaining in the auxiliary material, in particular aluminum flakes of metallic lacquers.
- limestone powder as an auxiliary material
- the temperature of the fluidized bed base material and / or the auxiliary material is selected in the treatment device so that the limestone powder neither burns nor calcination takes place.
- the method is operated at a temperature plateau between combustion and calcination of the limestone meal.
- the treatment device is operated at very high temperatures at which the fluidized bed base material and / or the auxiliary material are chemically converted.
- the resulting materials can then be used in particular otherwise.
- zeolites as auxiliary material and / or
- Fluidized bed base material can be used. Zeolites change chemically preferably only slightly at higher temperatures.
- inorganic materials such as quartz (Si0 2 ) as a fluidized bed base material and / or as an auxiliary material allows the use of very high temperatures, for example up to 1000 ° C. As a result, in particular organic materials can be burned out of the auxiliary material. A thermal post-combustion is then preferably unnecessary.
- quartz Si0 2
- sands if appropriate as mixtures, also quartz sand, as fluidized bed base material and / or as auxiliary material are used.
- a thermal postcombustion device can be, for example, a separate thermal postcombustion device assigned to the treatment plant or a thermal postcombustion device already present in a paint shop.
- a thermal post-combustion device is preferably arranged after a deposition device, in particular after a hot gas filter, the processing plant.
- thermal afterburning apparatus is designed as a torch.
- incomplete burned, organic constituents of the gas stream passed through the fluidized bed base material and / or the pollutant-laden auxiliary material gas stream are completely burned to carbon dioxide.
- thermal postcombustion device for the treatment plant can simplify the integration of the treatment plant into a paint shop, since the site of the treatment plant is then substantially independent of a thermal postcombustion device of the paint shop.
- the combustion is preferably an exothermic process, so that the resulting waste heat can be used to heat other process air, in particular a gas stream, in particular preheat.
- the necessary heating power of the thermal treatment device can thereby be preferably reduced.
- an electric heater is preferably used as the heating device for heating the gas flow through the fluidized bed base material and / or the pollutant-laden auxiliary material.
- the gas stream can be heated by means of exhaust air from a drying device for drying workpieces, in particular vehicle bodies.
- a part of the exhaust air of the drying device branches off, through the processing device, in particular the fluidized bed base material and / or loaded with pollutant auxiliary material, passed and optionally then fed to a thermal afterburner.
- the total air volume flow supplied to the thermal afterburning apparatus preferably remains at least approximately unchanged, and as a result also the design and the size of the thermal afterburning apparatus. It may be favorable if the exhaust air from a drying device is loaded with solvents.
- the solvent already contained in the gas flow can be used to heat the gas stream, so that less additional energy is needed for heating.
- a partial air flow of the gas stream is overheated, for example, has a temperature of 700 ° C to compensate for endothermic processes.
- a partial air flow from another gas for example nitrogen, oxygen, carbon dioxide, or comprises another gas in an increased concentration to specifically influence the combustion and / or conversion of the pollutant by reactions of this gas in the treatment device.
- each process air stream can be introduced into the processing device via the burner, ie at the process temperature, or without the burner, ie at room temperature.
- one of the process air streams is exhaust air of a drying device, this can react very flexibly to possible changes in state (operating state changes) of the paint shop. For example, a rapid heating of the treatment device, in particular the fluidized bed base material and / or the loaded with pollutant auxiliary material, by means of exhaust air of a drying device, if the exhaust air already a predetermined
- the processing device can thereby be operated reliably even without the operation of a drying device.
- Solvents from the exhaust air can be burned in a combustion chamber of the treatment device, in particular in the area of the fluidized bed base material and / or the auxiliary material laden with pollutant. Different paint concentrations (loading levels) in the pollutant-laden auxiliary material can be compensated thereby preferably.
- the treatment device can be cooled by means of air whose temperature is room temperature.
- a partial air flow which is introduced into the treatment device, in particular through the fluidized bed base material and / or charged with pollutant auxiliary material is passed, the exhaust air of the treatment device, which in particular has a temperature of about about 400 ° C.
- This partial air flow may comprise all of the exhaust air of the treatment device or any part thereof.
- partial air streams are introduced at mutually different points of the treatment device into the treatment device, in particular fed to the fluidized bed base material and / or the pollutant-laden auxiliary material.
- a partial air flow is added directly above a bottom of a receptacle for the fluidized bed base material and / or the pollutant-laden auxiliary material, in particular over a fluidized bed, in particular to improve the formation of a fluidized bed.
- a "stoichiometric stratification" can be produced in the processing device, that is to say that different oxygen concentrations predominate at different points in the processing device.
- stoichiometrically in excess oxygen may favor the combustion of pollutants.
- those in the preferred embodiment may favor the combustion of pollutants.
- Process air for the thermal treatment device that is, in particular the guided through the fluidized bed base material and the pollutant-laden auxiliary material air (carrier gas stream) can be preheated, for example via an air heat exchanger.
- heat-emitting process air streams are in particular exhaust air streams from a thermal post-combustion device into consideration.
- the supply of pollutant-laden auxiliary material to the thermal treatment device, in particular to the fluidized bed base material can be reduced or completely stopped. If, alternatively or additionally, the amount of air supplied to the treatment device is reduced to such an extent that oxygen is present in stoichiometric amounts in deficit, pyrolysis can take place so that tars, soot and / or ash can form.
- the treatment device preferably comprises a control or regulating device, by means of which the temperature of the gas flow supplied to the treatment device, the mass flow of the gas flow supplied to the treatment device and the amount of the supplied pollutant-loaded auxiliary material can be controlled and / or regulated.
- a regulation can be carried out, for example, as a function of a determined, for example by means of a measuring device oxygen content in the treatment device.
- the supply of pollutant-laden auxiliary material can be throttled or completely stopped when the oxygen concentration in the treatment device is too low, for example equal to or less than about 5%.
- the feed device for example a screw conveyor
- the feed device can be controlled by means of a frequency converter, for example, which is throttled as a function of a signal of an oxygen sensor of the measuring device, in particular until the complete delivery stop. In this way it can be ensured that pollutants of the pollutant-laden auxiliary material can burn off substantially completely before further auxiliary material laden with pollutant is supplied.
- a flow guide such as a pipe
- the gas stream preferably flows in the direction of gravity from top to bottom and is already preheated by the prevailing temperatures.
- the pipes are at least partially, preferably for the most part, or completely within the treatment device.
- the treatment device comprises a receptacle whose bottom is formed as a nozzle bottom.
- a nozzle bottom is formed as a bubble tray.
- a small pressure loss results in the introduction of the gas stream for stirring up the pollutant-laden auxiliary material and / or the fluidized bed base material.
- a bottom of the receptacle of the processing device comprises a fluidizing device, for example a fluidizing device formed of sintered ceramics or sintered metal.
- the gas flow can be introduced particularly uniformly over the entire surface of the soil.
- the pollutant-laden auxiliary material effectively, in particular to fluidize the fluidized bed base material.
- further substances with organic content can be burned in the treatment device.
- a Kabinenfolie- tion which is contaminated after removal from a designed as a paint booth painting device of the paint shop with paint, crushed, in particular shredded, and as an additional solids flow the
- Fluidized bed base material and / or the pollutant-laden Auxiliary material to be supplied As a result, the calorific value of the material to be processed can be increased.
- the treatment plant is preferably designed so that even if several streams, material flows and / or gas streams are provided, a thermal treatment of laden with pollutant auxiliary material is always possible only with the use of a gas stream and the reprocessed loaded with pollutant auxiliary material.
- the treatment device comprises a hot gas filter through which the gas flow is guided.
- the treatment device is, preferably continuously, fed by means of the feed device, such as a screw conveyor, loaded with pollutant auxiliary material, which is supplied for this purpose, for example, just above a bottom of a recording of the treatment device. Due to the material input into the treatment device, the filling level increases in the treatment device. Particles of auxiliary material and / or abrasion of fluidized bed base material, which accumulate in the direction of gravity upper end of the fluidized bed, for example, generated by the fluidization, for example, can be removed by means of an overflow from the treatment device. The prepared auxiliary material thus removed is then preferably cooled.
- the treatment device has a receptacle (tube) in which the thermal treatment takes place and thus the auxiliary material and / or the fluidized bed base material are strongly heated.
- a further receptacle (tube) of the treatment device in which processed auxiliary material from the first receptacle, for example by means of an overflow, is passed, the treated auxiliary material for cooling the same is fluidized with a cold gas stream.
- the cold gas stream takes the heat of the processed Auxiliary material, so that the second recording can cool to a total temperature of about 350 ° C, for example.
- the heated air can then be removed via a filter device which adjoins the second receptacle or is arranged in the second receptacle.
- the temperature of the air is preferably above the condensation temperature of the organic substances contained therein. This makes it possible to effectively reduce or completely avoid condensation of organic substances, in particular on the filter device.
- a bubble-forming fluidized bed is formed.
- the solids discharge from the fluidized bed is minimized.
- an optimum ratio of atmospheric oxygen to pollutant to be burned is selected here.
- a circulating fluidized bed is formed by the fluidization of the pollutant-laden auxiliary material and / or the fluidized bed base material. It may be favorable if the processing device has a receptacle with a cross-section (widened) which increases in the upward direction towards the direction of gravity
- processed auxiliary material is discharged via a filter device from the processing device.
- the formation of a circulating fluidized bed can be provided for this purpose.
- the filter device in particular a hot gas filter, is preferably arranged outside the vertical projection of the receptacle, in particular the fluidized bed. This is a drop, if necessary, at a cleaning of on the filter device deposited particles from the filter device back into the fluidized bed effectively reduced or completely avoided. Instead, the fall can take place in a container arranged below the filter device.
- the treatment device is in this case operated so that the particles have a long residence time in the treatment device in order to ensure complete conversion of the organic constituents of the pollutant can.
- the processing device comprises two receptacles (as described above) and a filter device for discharging the processed auxiliary material (as described above).
- the treatment device is preferably integrated in a cleaning device for cleaning a pollutant-laden crude gas stream, in particular a filter device with regenerable filter modules.
- Auxiliary material is preferably automatically removed from the filter device for purifying the crude gas stream and fed to the treatment device.
- a, in particular automatic or manually operated, buffer device is provided, in which loaded with pollutant
- Auxiliary material from the filter device for cleaning the crude gas stream can be temporarily stored. From the buffer device, the pollutant-laden auxiliary material is fed to the treatment device.
- the buffer device comprises in particular a buffer container which has a storage volume of, for example, at least about one cubic meter, in particular about 100 cubic meters.
- the feeding of pollutant-laden auxiliary material to the treatment device preferably takes place via a cooling screw, which is also referred to as a screw heat exchanger.
- a cooling of the treatment device supplied, loaded with pollutant auxiliary material is preferably such that the temperature is up to the supply to the processing device at most about 120 ° C, to a
- a thick flow can be carried out, wherein for preventing the heat conduction, a conveying line is preferably cooled. If a rapid promotion, can preferably be dispensed with a cooling of the auxiliary material.
- a trickle device and / or a vibrating trough can be provided as the feed device.
- An average particle size of the fluidized bed base material is preferably between about 0.1 mm to about 10 mm, more preferably between about 0.3 mm to about 3 mm.
- the median particle size distribution of the fresh and / or processed auxiliary material is preferably between about 10 ⁇ and about 50 pm, in particular between about 15 ⁇ and about 30 ⁇ .
- Auxiliary material is, for example, about 50 pm to about 60 pm.
- FIG. 1 shows a schematic vertical cross section through a painting plant for painting workpieces.
- FIG. 2 shows a schematic vertical cross section through a first embodiment of a treatment plant for the treatment of auxiliary material.
- Fig. 3 is a corresponding to Fig. 2 schematic representation of a second
- FIG. 2 corresponding schematic representation of a third
- Embodiment of a treatment plant in which a thermal post-combustion device is provided;
- Fig. 5 is a corresponding to Fig. 2 schematic representation of a fourth
- Embodiment of a treatment plant in which a plurality of partial air streams are provided as mixed supply air for the treatment device;
- Fig. 6 is a corresponding to Fig. 2 schematic representation of a fifth
- FIG. 7 is a of FIG. 2 corresponding schematic representation of a
- FIG. 8 shows a schematic vertical cross section through a seventh embodiment of a treatment plant, in which a thermal afterburning device and a bypassed heat exchanger for heating supply air for the treatment device of the treatment plant are provided;
- FIG. 9 is a corresponding to FIG. 8 schematic representation of an eighth
- Embodiment of a treatment plant which is coupled to a drying device for drying workpieces;
- Fig. 10 is a corresponding to FIG. 8 schematic representation of a
- Ninth embodiment of a treatment plant in which an electric heater for heating supply air for the treatment device of the treatment plant is provided;
- Fig. 11 is a corresponding to FIG. 8 schematic representation of a
- Fig. 12 is a corresponding to FIG. 8 schematic representation of an eleventh
- Embodiment of a treatment plant in which an electric heater and a heat exchanger are provided;
- Fig. 13 is a corresponding to FIG. 8 schematic representation of a
- a measuring device for determining gas concentrations in the treatment device of the treatment plant
- 14 shows a schematic representation of a treatment device of a treatment plant in which a bubble-forming fluidized bed is formed
- Fig. 15 is a schematic representation of a processing device of a
- FIG. 16 is a schematic illustration, corresponding to FIG. 8, of a thirteenth embodiment of a treatment plant in which a discharge of processed auxiliary material takes place by means of a filter device; FIG. and
- 17 is a schematic illustration of a fourteenth embodiment of a treatment plant including buffering devices for buffering pollutant-laden auxiliary material and processed auxiliary material.
- Fig. 1 designated as a whole by 100, comprises a painting device 102 designed as a painting booth, in which workpieces 104, for example vehicle bodies, can be coated with paint (paintable).
- a painting device 102 designed as a painting booth, in which workpieces 104, for example vehicle bodies, can be coated with paint (paintable).
- the workpieces 104 can be fed by means of a workpiece conveying device 108 to an application region 106 of the coating device 102 and can be removed again from the application region 106.
- the painting installation 100 further comprises a plenum 110 arranged above the painting device 102, by means of which air can be fed to the application area 106.
- the painting installation 100 comprises a filter installation 112 arranged below the painting apparatus 102, by means of which the air guided through the application area 106, which has received pollutant formed by the application of paint to the workpieces 104 as paint overspray, can be cleaned.
- the filter system 112 comprises a plurality of filter devices 114.
- Each filter device 114 comprises an enclosure 116, which delimits a raw gas chamber 118 and in which at least one filter element 120 is arranged.
- the filter device 114 comprises an inlet channel 122, through which a stream of raw gas, which is formed by the polluted air guided through the application region 106, can flow into the raw gas chamber 118 of the filter device 114.
- the filter device 114 is designed as a dry filter device, that is to say that purification of the raw gas stream takes place essentially without the addition of a liquid to the filter elements 120. Rather, the raw gas stream, an auxiliary material, in particular filter aid material, are supplied, which preferably absorbs a liquid content in the pollutant and can be deposited together with the pollutant loaded with pollutant auxiliary material on the filter element 120.
- the auxiliary material forms together with the pollutant a stable system of pollutant and
- Auxiliary material By cleaning the crude gas stream, a clean gas stream is obtained, which leaves the filter device 114 through a clean gas line 123.
- a barrier layer or a protective layer is formed, which can be easily cleaned from the filter element 120.
- the filter device 114 is thus a regenerable filter device 114 which can be regenerated and reused without replacement of filter elements 120.
- Auxiliary material may be received in a receptacle 124 of the filter device 114 disposed below the filter element 120.
- the paint shop 100 For the preparation of the auxiliary material, the paint shop 100 comprises a thermal treatment plant 126 (see FIG. 2).
- the treatment plant 126 comprises a treatment device 128, which is in particular designed as a fluidized bed furnace 130.
- the treatment device 128 comprises a receptacle 132 for receiving fluidized bed base material and auxiliary material, in particular pollutant-laden auxiliary material.
- fluidized bed base material can also be dispensed with in another embodiment.
- fluidized bed base material may be advantageous when it is desired to treat an auxiliary material that, for example, can not be fluidized by itself, due to binding forces between the particles of the auxiliary material and / or due to the particle size.
- a bottom 134 of the receptacle 132 is formed, for example, as a nozzle bottom 136, in particular as a bell bottom 138, and allows the supply of supply air through the bottom 134 to the fluidized bed base material and the auxiliary material, in particular the system of pollutant and
- a fluidized bed 140 of fluidized bed base material and / or of the system of pollutant and auxiliary material in the receptacle 132 can be formed.
- the bell bottom 138 of the receptacle 132 comprises a plurality of nozzles 142, which are provided, for example bell-like with covers 144.
- Receiving 132 of the treatment device 128 supply air to be supplied.
- the treatment plant 126 comprises a heating device 148, in particular a burner, which serves for heating the supply air.
- the supply air to be heated by means of the heating device 148 and to be supplied to the receptacle 132 of the processing device 128 is ambient air from the surroundings of the processing plant 126, in particular room air, in the first embodiment of the processing plant 126 shown in FIG.
- the gas stream, in particular the carrier gas stream, which as supply air by means of Zu Kunststoff admir 146 of the receptacle 132 of the treatment device 128 can be fed and passed through the fluidized bed base material and the pollutant loaded auxiliary material, from the receptacle 132 of
- Processing device 128 are discharged.
- the treatment plant 126 comprises a separation device 152, for example a filter device 154. This can be used to prevent unwanted pollutants from the exhaust air, i. the guided through the fluidized bed 140 gas stream, are discharged to the environment of the treatment plant 126.
- a separation device 152 for example a filter device 154. This can be used to prevent unwanted pollutants from the exhaust air, i. the guided through the fluidized bed 140 gas stream, are discharged to the environment of the treatment plant 126.
- processed auxiliary material can be discharged from the receptacle 132 of the processing device 128 (see also FIG. 16).
- the separating device 152 can thus also serve as a discharge device 156 for removing processed auxiliary material from the processing device 128.
- the separation device 152 is part of a separation device 157 for separating recycled auxiliary material from the pollutant-laden auxiliary material.
- the treatment plant 126 further comprises a supply device 158, by means of which the receptacle 132 of the processing device 128 can be supplied with auxiliary material loaded with pollutant.
- auxiliary material loaded with pollutant.
- the above-described first embodiment of the treatment plant 126 functions as follows:
- Air is sucked in from the surroundings of the treatment plant 126 via the supply air line 146 and supplied to the treatment device 128 as supply air to the receptacle 132.
- the supply air is heated by means of the heater 148 over the temperature at normal conditions (about 20 ° C to 30 ° C), in particular to a temperature of about 550 ° C.
- the supply air is passed as a gas stream, in particular carrier gas stream, through the bottom 134 of the receptacle 132, swirls the fluidized bed base material arranged in the receptacle 132 and heats the fluidized bed base material.
- Conditioning device 128 is formed.
- the fluidized bed base material with pollutant-laden auxiliary material for example, from the filter devices 114 of the filter system 112 of the paint shop 100, respectively.
- the pollutant-laden auxiliary material is then heated in the treatment device 128 and thereby processed.
- the treatment device 128 is thus a thermal treatment device 128.
- the treatment plant 126 is thus a thermal treatment plant 126.
- the pollutant By heating the pollutant-laden auxiliary material, the pollutant is at least partially chemically converted, in particular burned, or at least reduces the stickiness of the pollutant, so that agglomerates of particles of pollutant and particles are broken from auxiliary material. Particles of auxiliary material preferably remain chemically unchanged.
- an organic constituent of the pollutant is vaporized, preferably burned, and removed from the system of pollutant and auxiliary material.
- the particles of auxiliary material freed of pollutant accumulate in an upper region 162 of the fluidized bed 140 with respect to the direction of gravity 160 and can be entrained there by the gas stream flowing through and finally deposited on the precipitation device 152.
- these particles are removed as treated auxiliary material from the treatment device 128 and can be reused in the filter system 112, in particular in the filter devices 114 of the filter system 112, for the purification of a raw gas stream.
- limestone powder is considered as auxiliary material.
- the fluidized bed base material is preferably limestone meal, but preferably has particles of larger particle diameter.
- the particles of the fluidized bed base material are on average at least about 10 times, for example about 50 times, as large as the particles of the auxiliary material.
- the fluidized bed base material is progressively reduced by abrasion to form particles of fluidized bed base material having a similar size to the particles of the auxiliary material.
- the fluidized bed base material preferably has a chemical composition corresponding to the chemical composition of a material usable as an auxiliary material
- the small particles of fluidized bed base material can be discharged from the treatment device 128 by means of the discharge device 156 and used as a treated auxiliary material in the filter system 112 for purifying a raw gas stream ,
- FIG. 3 illustrated second embodiment of a thermal treatment plant 126 differs from that shown in FIG. 2 substantially by the fact that the exhaust air guided through the separation device 152 is not released unused to the environment. Rather, a heat exchanger 164 is provided, by means of which the heat contained in the exhaust air from the treatment device 128 is at least partially transferable to the supply air to be supplied to the treatment device 128 supply air. As a result, a fuel requirement of the heating device 148 can preferably be reduced.
- FIG. 3 illustrated second embodiment of a treatment plant 126 in terms of structure and function with the in FIG. 2, so that reference is made to the above description thereof.
- FIG. 4 differs from the first embodiment shown in FIG. 2 essentially in that exhaust air from a drying device (to be described later) for drying workpieces 104, in particular vehicle bodies, is used as supply air for the treatment device 128 , Furthermore, in the third embodiment of the treatment plant 126 shown in FIG. 4, a combustion device 166, in particular a thermal afterburning device 168, is provided.
- the exhaust air from the dryer apparatus is thereby partially supplied to the treatment apparatus 128 and partly directly to the thermal afterburning apparatus 168.
- the exhaust air from the treatment device 128 is also supplied to the thermal afterburning apparatus 168 in the third embodiment of the treatment plant 126 shown in FIG. 4 by means of the exhaust air line 150 after flowing through the separation device 152.
- exhaust air from the drying device as supply air for the treatment device 128, the fuel requirement of the heater 148 can be reduced. On the one hand, this is due to the fact that the exhaust air of the drying device already has an elevated temperature. On the other hand, exhaust air from the drying device usually contains flammable solvents which, when burned in the treatment device 128, also contribute to increasing the temperature while avoiding heating by means of the heating device 148.
- the thermal post-combustion device 168 serves to eliminate all organic and other potentially hazardous substances from the exhaust air of the drying device and the exhaust air of the treatment device 128. In particular, by means of the thermal post-combustion device 168 a very high temperature for chemical
- a condensate separator can be used.
- the temperature of the air stream is cooled below the dew point of the organic substances to be separated by means of a heat exchanger.
- the condensed substances are taken up in a collecting container.
- FIG. 4 illustrated third embodiment of the treatment plant 126 with the in FIG. 2, so that reference is made to the above description thereof.
- Fig. 5 fourth embodiment of a thermal treatment plant 126 differs from the third embodiment shown in FIG. 4 essentially in that the treatment plant 126 comprises a valve arrangement 170, by means of which the supply air for the treatment device 128 optionally from different sources, in particular from ambient air, for example Room air, or exhaust air of a drying device, can be provided.
- the supply air for the treatment device 128 optionally from different sources, in particular from ambient air, for example Room air, or exhaust air of a drying device, can be provided.
- the air provided can optionally be supplied to the heating device 148 and heated or be conducted past the heating device 148.
- valve arrangement 170 can in particular be controlled and / or regulated such that a temperature in the receptacle 132 of the treatment device 128 is substantially constant.
- a measuring device 174 is provided.
- the supply device 158 and the discharge device 156 can also be controlled and / or regulated by means of the control device 172.
- FIG. 5 illustrated fourth embodiment of a treatment plant 126 in terms of structure and function with the in FIG. 4, so that reference is made to the above description thereof.
- a fifth embodiment of a thermal treatment plant 126 shown in FIG. 6 differs from that shown in FIG. 2 essentially in that the supply air for the treatment device 128 is introduced at different locations in the receptacle 132 of the treatment device 128.
- the supply air is introduced via the bottom 134 of the receptacle 132 in order to allow fluidization of the fluidized bed base material and of the pollutant-laden auxiliary material.
- supply air is introduced at various points above the fluidized bed 140, in order to be able to influence a swirling and / or a discharge of fluidized auxiliary material in a targeted manner.
- FIG. 6 illustrated fifth embodiment of a treatment plant 126 in terms of structure and function with the in FIG. 5, so that reference is made to the above description thereof in this regard.
- FIG. 7 illustrated sixth embodiment of a thermal treatment plant 126 differs from that shown in FIG. 2, essentially in that the treatment device 128 comprises an air line 176 which is substantially vertical is arranged centrally in the receptacle 132 of the treatment device 128 and extends substantially over the entire length of the receptacle 132 of the treatment device 128.
- the air line 176 allows the supply of air to the bottom 134 of the receptacle 132, wherein the air is guided in the direction of gravity 160 from above through the receptacle 132 of the treatment device 128 and thus automatically heated during operation of the treatment device 128.
- the heat generated and / or existing in the treatment device 128 can be used efficiently to minimize the need for an additional heating.
- FIG. 7 illustrated sixth embodiment of a treatment plant 126 with the first embodiment shown in FIG. 2, so that reference is made to the above description thereof in this regard.
- a seventh embodiment of a thermal treatment plant 126 shown in FIG. 8 essentially differs from the first embodiment shown in FIG. 2 in that the treatment plant 126 comprises a thermal afterburning device 168 (see also the third and fourth embodiments according to FIGS. 4 and 5).
- the exhaust air from the treatment device 128 is thereby fed to the thermal afterburning device 168 and heated strongly therein.
- Both the heated exhaust air from the thermal afterburning device 168 and the supply air for the treatment device 128 are supplied to a heat exchanger 164 to transfer the heat from the heated exhaust air to the supply air to be heated.
- the heated exhaust air can be partially or completely passed by means of a bypass 178 to the heat exchanger 164.
- valve assembly 170 is provided in the seventh embodiment of the treatment plant 126 shown in FIG.
- the valve arrangement 170 can be controlled, for example, by means of the control device 172 (see in particular the fourth embodiment according to FIG. 5).
- a separating device 157 designed as an overflow device 179 can be provided.
- this overflow device 179 which is preferably arranged in the upper region 162 of the fluidized bed 140, can be separated in the upper region 162 accumulating processed auxiliary material from the accumulating in particular in the lower region 161 loaded with pollutant auxiliary material.
- the seventh embodiment of the processing plant 126 shown in FIG. 8 coincides in structure and function with the first embodiment shown in FIG. 2, so that reference is made to the above description thereof.
- FIG. 9 An eighth embodiment of a thermal treatment plant 126 shown in FIG. 9 differs from that shown in FIG. 8 illustrated substantially by the fact that the air duct (supply and exhaust air) of the treatment device 128 together with the heat exchanger 164 in the air duct (supply and exhaust air) of a drying device 180 for drying workpieces 104, in particular vehicle bodies, and an associated thermal post-combustion device 168 is integrated.
- the supply air for the treatment device 128 is heated by means of a heat exchanger 164, to which the exhaust air heated in the thermal afterburning device 168 is supplied to the treatment device 128.
- FIG. 8 illustrated ninth embodiment provided that the heat from the exhaust air of the thermal afterburning device 168 is transferred by means of further heat exchanger 164 to the supply air for the drying device 180.
- FIG. 9 illustrated eighth embodiment of a treatment plant 126 in terms of structure and function with the in FIG. 8 illustrated seventh embodiment, so that reference is made to the above description thereof in this regard.
- FIG. 10 illustrated ninth embodiment of a thermal
- Processing plant 126 differs from that shown in FIG. 2 essentially in that the heating device 148 is designed as an electric heating device 148, in particular as an electric heating unit.
- the supply air for the treatment device 128 is thus heated by means of an electric heater 148.
- the exhaust air from the treatment device 128 is supplied to a thermal post-combustion device 168, thereby freed of undesirable pollutants and finally released to the environment.
- the in Fig. 10 illustrated ninth embodiment of a treatment plant 126 in structure and function with the in Fig. 1. 2, so that reference is made to the above description thereof.
- FIG. 11 illustrated tenth embodiment of a thermal
- Processing plant 126 differs from that shown in FIG. 9, essentially in that the supply air for the treatment device 128 is a part of the exhaust air from the drying device 180.
- the remaining part of the exhaust air from the drying device 180 is fed to the thermal afterburning device 168.
- the exhaust air from the treatment device 128 is supplied to the thermal afterburning apparatus 168.
- FIG. 11 illustrated tenth embodiment of a treatment plant 126 in terms of structure and function with the in FIG. 9, so that reference is made to the above description thereof.
- FIG. 12 illustrated eleventh embodiment of a thermal treatment plant 126 differs from that shown in FIG. 3, essentially in that the heating device 148 is designed as an electric heating device 148, in particular as an electric heating unit.
- the heating device 148 is in particular a backup heater.
- FIG. 12 illustrated eleventh embodiment of a treatment plant 126 in terms of structure and function with the in FIG. 3 illustrated second embodiment, so that reference is made to the above description thereof in this regard.
- Processing plant 126 differs from that shown in FIG. 5 illustrated substantially by the fact that by means of the valve assembly 170 not only different tempered air streams, but also gas streams of different composition either individually or mixed as supply air of the treatment device 128 can be fed.
- the measuring device 174 is preferably a gas concentration, in particular an oxygen concentration, in the processing device 128 can be determined.
- control device 172 can influence the valve arrangement 170 in order to optimize the process parameters in the conditioning device 128.
- Fig. 13 illustrated twelfth embodiment of a treatment plant 126 in terms of structure and function with the in FIG. 5, so that reference is made to the above description thereof in this regard.
- FIG. 14 an operating mode of a treatment device 128 is shown schematically in which a bubble-forming fluidized bed is produced in the receptacle 132 of the treatment device 128.
- a bubble-forming fluidized bed is produced in the receptacle 132 of the treatment device 128.
- the fluidized bed base material and / or the pollutant-laden auxiliary material is traversed by air.
- FIG. 15 schematically illustrates an operating mode of a treatment device 128 in which a circulating fluidized bed is produced in the receptacle 132 of the treatment device 128.
- the receptacle 132 has a section 182 that widens upwards in the direction of the force of gravity 160, which leads to a slowing down of the gas flow in the receptacle 132 of the treatment device 128 and allows the discharged particles to trickle back into the fluidized bed 140 ,
- Such an upwardly expanding portion 182 is also referred to as
- a thirteenth embodiment of a thermal treatment plant 126 shown in FIG. 16 differs from that shown in FIG. 2 illustrated first embodiment essentially in that below the
- Separator 152 a collecting container 184 is arranged by means of which can be received by the separating device 152 falling treated auxiliary material.
- both the separating device 152 and the collecting container 184 are arranged laterally offset from the receptacle 132 of the processing device 128, it is avoided that the deposited processed
- Auxiliary material passes back into the fluidized bed 140.
- the processed auxiliary material thus easily separated and finally discharged by means of the discharge device 156 from the processing device 128.
- a fourteenth embodiment of a thermal treatment plant 126 differs from that shown in FIG. 2 essentially in that the treatment plant 126 comprises buffer devices 186, by means of which pollutant-laden and / or treated auxiliary material can be intermediately stored.
- buffer containers 188 of the buffer devices 186 are provided.
- a first buffer tank 188 serves to receive pollutant-laden auxiliary material from the filter system 112.
- a conveying device 190 for example a screw conveyor, in particular a cooling screw or a screw heat exchanger
- the pollutant-laden auxiliary material from the buffer tank 188 for laden with pollutant auxiliary material of the processing device 128 can be supplied.
- the conveying device 190 is thus part of the feeding device 158.
- the pollutant-laden auxiliary material in particular in the lower region 161 of the fluidized bed 140, can be supplied to the fluidized bed base material and thus to the fluidized bed 140 itself.
- auxiliary material which has been removed from the receptacle 132 of the processing device 128 by means of an overflow 192 can be fed to a further buffer container 188 of a further buffer device 186.
- the overflow 192 and the further conveyor 190 are thus part of the discharge device 156th
- the treatment plant 126 further comprises a storage device 194 for storing fresh auxiliary material, a mixing device 196 for mixing prepared auxiliary material and fresh auxiliary material, and / or a disposal device 198 for disposing of excessively contaminated auxiliary material, especially contaminated with pollutant
- the storage device 194 comprises a further buffer container 188, in which, for example, supplied by trucks fresh auxiliary material can be cached.
- the mixing device 196 also includes a buffer tank 188 in which a mixture of fresh auxiliary material and processed auxiliary material can be temporarily stored.
- the in Fig. The fourteenth embodiment of the processing plant 126 shown in FIG. 17 functions as follows:
- a laden with pollutant raw gas stream is cleaned with the aid of auxiliary material.
- the pollutant-laden auxiliary material must be replaced or treated after a certain period of use.
- thermal treatment plant 126 By means of the thermal treatment plant 126 such a treatment can take place.
- the pollutant-laden auxiliary material is supplied from the filter system 112 to a buffer device 186, in particular temporarily stored in a buffer container 188 for pollutant-laden auxiliary material.
- the pollutant-laden auxiliary material is conveyed by means of the conveying device 190 into the receptacle 132 of the processing device 128.
- the processed auxiliary material accumulating in the upper region 162 of the fluidized bed 140 is removed from the receptacle 132 of the processing device 128 and fed via the further conveying device 190, in particular a screw heat exchanger, to the buffer container 188 for the processed auxiliary material.
- the auxiliary material is cooled to a temperature of at most about 40 ° C, so that it can be stored at ambient temperature and optionally processed.
- a bulk material heat exchanger in which a cooling through Vorbeirieseln done on heat exchanger tubes, or be provided with a pneumatic conveying or integrated heat exchanger in a delivery line.
- the mixture comprises, for example, about 70% recycled auxiliary material and about 30% fresh auxiliary material.
- the auxiliary material mixed by the mixing device 196 is finally supplied to the filter unit 112 for reuse.
- the drive of the required gas streams, in particular air streams, in the thermal treatment plant 126 is preferably carried out by means of at least one fan, which in particular overcomes all pressure losses in the treatment plant 126.
- the pressure losses can be, for example, between about 200 mbar and about 300 mbar.
- the fourteenth embodiment of the treatment plant 126 shown in FIG. 17 is identical in construction and function to the one shown in FIG. 2, so that reference is made to the above description thereof.
- thermal treatment plants 126 can be provided that single or multiple features of the described embodiments are combined in any manner with each other.
- the fourteenth embodiment shown in FIG. 17 of the thermal treatment plant 126 according to FIG the in Fig. 4 illustrated third embodiment is provided with a thermal post-combustion device 168.
- auxiliary material Since in all embodiments of thermal treatment plants 126 contaminant-laden auxiliary material is thermally treated and the processed auxiliary material is separated by gas flow from the still loaded with pollutant auxiliary material, the preparation of auxiliary material is particularly simple and resource-friendly.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Treating Waste Gases (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Combined Means For Separation Of Solids (AREA)
- Details Or Accessories Of Spraying Plant Or Apparatus (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Incineration Of Waste (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Processing Of Solid Wastes (AREA)
- Drying Of Solid Materials (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
Description
Claims
Priority Applications (12)
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EP20151818.0A EP3659691A1 (de) | 2011-11-02 | 2012-10-31 | Verfahren zum thermischen aufbereiten eines hilfsmaterials und aufbereitungsanlage |
IN3044DEN2014 IN2014DN03044A (de) | 2011-11-02 | 2012-10-31 | |
JP2014539329A JP2015504504A (ja) | 2011-11-02 | 2012-10-31 | 補助材料を熱的に処理する方法及び処理設備 |
BR112014010239-2A BR112014010239B1 (pt) | 2011-11-02 | 2012-10-31 | Processo para a preparaqao termica de um material auxiliar e unidade de laqueadura de peqas a trabalhar |
KR1020147011701A KR20140088119A (ko) | 2011-11-02 | 2012-10-31 | 보조 재료의 열 처리를 위한 방법 및 처리 유닛 |
MX2014005213A MX2014005213A (es) | 2011-11-02 | 2012-10-31 | Metodo para el acondicionamiento termico de un material auxiliar e instalacion de acondicionamiento. |
RU2014122026A RU2613410C2 (ru) | 2011-11-02 | 2012-10-31 | Способ термической переработки вспомогательного материала и перерабатывающая установка |
CA2853596A CA2853596A1 (en) | 2011-11-02 | 2012-10-31 | Method for the thermal conditioning of an auxiliary material and conditioning facility |
CN201280053820.6A CN103958070B (zh) | 2011-11-02 | 2012-10-31 | 用于热准备辅助材料的方法和准备设施 |
EP12788481.5A EP2773466B1 (de) | 2011-11-02 | 2012-10-31 | Verfahren zum thermischen aufbereiten eines hilfsmaterials und lackierungsanlage |
ZA2014/02716A ZA201402716B (en) | 2011-11-02 | 2014-04-14 | Method for the thermal preparation of an auxiliary material and preparation unit |
US14/265,872 US9381465B2 (en) | 2011-11-02 | 2014-04-30 | Method for the thermal conditioning of an auxiliary material and conditioning facility |
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DE202011107555.2 | 2011-11-02 | ||
PCT/EP2012/058167 WO2013013848A1 (de) | 2011-07-27 | 2012-05-03 | Filteranlage und verfahren zum betrieb einer filteranlage |
EPPCT/EP2012/058167 | 2012-05-03 | ||
DE102012110243.0 | 2012-10-26 | ||
DE102012219692A DE102012219692A1 (de) | 2011-11-02 | 2012-10-26 | Vorrichtung für das Aufbereiten von partikelförmigem Hilfsmaterial |
DE102012219692.7 | 2012-10-26 | ||
DE102012110243A DE102012110243A1 (de) | 2011-11-02 | 2012-10-26 | Verfahren zum thermischen Aufbereiten eines Hilfsmaterials und Aufbereitungsanlage |
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PCT/EP2012/071552 WO2013064534A1 (de) | 2011-11-02 | 2012-10-31 | Vorrichtung für das aufbereiten von partikelförmigem hilfsmaterial |
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US (1) | US9381465B2 (de) |
JP (1) | JP2015504504A (de) |
KR (1) | KR20140088119A (de) |
CN (1) | CN103958070B (de) |
BR (1) | BR112014010239B1 (de) |
CA (1) | CA2853596A1 (de) |
DE (4) | DE202011107555U1 (de) |
IN (1) | IN2014DN03044A (de) |
MX (1) | MX2014005213A (de) |
RU (1) | RU2613410C2 (de) |
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-
2011
- 2011-11-02 DE DE202011107555U patent/DE202011107555U1/de not_active Expired - Lifetime
-
2012
- 2012-10-26 DE DE102012219692A patent/DE102012219692A1/de not_active Withdrawn
- 2012-10-26 DE DE102012110243A patent/DE102012110243A1/de active Pending
- 2012-10-31 BR BR112014010239-2A patent/BR112014010239B1/pt not_active IP Right Cessation
- 2012-10-31 KR KR1020147011701A patent/KR20140088119A/ko not_active Application Discontinuation
- 2012-10-31 IN IN3044DEN2014 patent/IN2014DN03044A/en unknown
- 2012-10-31 DE DE202012013508.2U patent/DE202012013508U1/de not_active Expired - Lifetime
- 2012-10-31 RU RU2014122026A patent/RU2613410C2/ru active
- 2012-10-31 WO PCT/EP2012/071627 patent/WO2013064575A1/de active Application Filing
- 2012-10-31 CA CA2853596A patent/CA2853596A1/en not_active Abandoned
- 2012-10-31 WO PCT/EP2012/071552 patent/WO2013064534A1/de active Application Filing
- 2012-10-31 CN CN201280053820.6A patent/CN103958070B/zh active Active
- 2012-10-31 JP JP2014539329A patent/JP2015504504A/ja not_active Withdrawn
- 2012-10-31 MX MX2014005213A patent/MX2014005213A/es unknown
-
2014
- 2014-04-14 ZA ZA2014/02716A patent/ZA201402716B/en unknown
- 2014-04-30 US US14/265,872 patent/US9381465B2/en active Active
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US2571380A (en) * | 1948-06-23 | 1951-10-16 | Socony Vacuum Oil Co Inc | Method of regenerating adsorptive material |
US2650155A (en) * | 1951-07-16 | 1953-08-25 | Shell Dev | Apparatus for stripping and regenerating spent adsorptive powders |
DE2506394A1 (de) * | 1975-02-15 | 1976-08-26 | Bergwerksverband Gmbh | Wirbelschichtreaktor zur thermischen regenerierung von beladenen aktivkohlen |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104368398A (zh) * | 2013-10-22 | 2015-02-25 | 上海派特贵金属环保科技有限公司 | 一种贵金属催化网的活化方法及装置 |
JP2015112521A (ja) * | 2013-12-10 | 2015-06-22 | 株式会社大気社 | 塗料ミスト捕集装置 |
Also Published As
Publication number | Publication date |
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US9381465B2 (en) | 2016-07-05 |
BR112014010239B1 (pt) | 2020-11-24 |
MX2014005213A (es) | 2014-05-28 |
JP2015504504A (ja) | 2015-02-12 |
DE202011107555U1 (de) | 2012-10-29 |
DE202012013508U1 (de) | 2017-05-02 |
CN103958070B (zh) | 2016-12-14 |
KR20140088119A (ko) | 2014-07-09 |
WO2013064534A1 (de) | 2013-05-10 |
CA2853596A1 (en) | 2013-05-10 |
IN2014DN03044A (de) | 2015-05-08 |
DE102012110243A1 (de) | 2013-05-02 |
CN103958070A (zh) | 2014-07-30 |
BR112014010239A2 (pt) | 2017-04-18 |
DE102012219692A1 (de) | 2013-05-02 |
RU2613410C2 (ru) | 2017-03-16 |
ZA201402716B (en) | 2015-11-25 |
RU2014122026A (ru) | 2015-12-10 |
US20140230725A1 (en) | 2014-08-21 |
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