WO2013051691A1 - 熱電発電装置 - Google Patents
熱電発電装置 Download PDFInfo
- Publication number
- WO2013051691A1 WO2013051691A1 PCT/JP2012/075936 JP2012075936W WO2013051691A1 WO 2013051691 A1 WO2013051691 A1 WO 2013051691A1 JP 2012075936 W JP2012075936 W JP 2012075936W WO 2013051691 A1 WO2013051691 A1 WO 2013051691A1
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- WIPO (PCT)
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- ring
- plate
- thermoelectric
- heat receiving
- cooling plate
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/10—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects
- H10N10/17—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects characterised by the structure or configuration of the cell or thermocouple forming the device
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
- H02N11/00—Generators or motors not provided for elsewhere; Alleged perpetua mobilia obtained by electric or magnetic means
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/10—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects
- H10N10/13—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects characterised by the heat-exchanging means at the junction
Definitions
- the present invention relates to a thermoelectric generator, and more particularly to a thermoelectric generator in which a plurality of thermoelectric modules are interposed in the same plane between a heat receiving plate and a cooling plate.
- thermoelectric power generation apparatus in which a thermoelectric conversion circuit using the Seebeck effect is sandwiched between two metal heat conversion plates is known (see, for example, Patent Document 1).
- a thermoelectric generator an O-ring is disposed so as to surround the thermoelectric conversion circuit. With this O-ring, airtightness between the heat exchange plates is secured, and the portion where the thermoelectric conversion circuit is interposed is secured. Prevents ingress of moisture (humidity).
- the heat conversion plates are tightened in a direction in which a plurality of outer edge portions and a central portion approach each other by bolts, and the O-ring is appropriately crushed by this tightening force and heated. Adhering to the exchange plate, sufficient sealing performance can be obtained.
- thermoelectric generator described in Patent Document 1
- the close contact state between the heat exchange plate and the O-ring cannot be secured, and the heat exchange plate is interposed between the heat exchange plates.
- the sealing performance of the thermoelectric module to be maintained cannot be maintained.
- An object of the present invention is to provide a thermoelectric generator capable of maintaining good adhesion with an O-ring by absorbing deformation of a heat exchange plate and improving sealing performance.
- thermoelectric generator includes a heat receiving plate that receives heat, a cooling plate that is maintained at a lower temperature than the heat receiving plate, and a thermoelectric module that is interposed between the heat receiving plate and the cooling plate.
- a first O-ring that surrounds the outside of the thermoelectric module is provided between the plate and the cooling plate, and the heat receiving plate and the cooling plate are connected to each other by a first bolt at a position outside the first O-ring.
- the first bolt is connected to the first bolt, and is provided with a first biasing member having elasticity for biasing the heat receiving plate and the cooling plate toward each other.
- thermoelectric generator the heat receiving plate and the cooling plate are connected to each other by a second bolt at a position inside the first O-ring, and the heat receiving plate is connected to the second bolt.
- a second urging member having elasticity for urging the cooling plates toward each other, and the urging force of the second urging member inside the first O-ring is the first urging force. It is characterized by being larger than the urging force of the urging member.
- thermoelectric generator In the thermoelectric generator according to the third aspect of the present invention, a second O-ring that is inserted through a second bolt inside the first O-ring is interposed between the heat receiving plate and the cooling plate. It is characterized by.
- the first O-ring that surrounds the thermoelectric module and the second O-ring that is inserted through the inner second bolt are made of fluorine-based rubber. It is characterized by.
- thermoelectric power generation device the heat receiving plate, the cooling plate, a thermoelectric power generation unit having the plurality of thermoelectric modules, a metal shielding cover that covers the thermoelectric power generation unit, and the thermoelectric power generation device A fixing bracket that fixes the heat receiving plate and the cooling plate to each other at an outer position and an inner position of the first O-ring that surrounds the thermoelectric module.
- first and second bolts are connected by bolts, and are provided with the first and second biasing members that bias the heat receiving plate and the cooling plate toward each other,
- the biasing force of the second biasing member inside the first O-ring is larger than the biasing force of the first biasing member outside the first O-ring, and the heat receiving plate and the cooling
- a second O-ring penetrating a second bolt inside the first O-ring is interposed, and the first O-ring has a rectangular shape having an R shape at each corner.
- the first bolt at the outer position of the first O-ring is provided corresponding to a corner of the first O-ring, and the first biasing member and the second biasing force are provided.
- the member is a coil spring.
- the first bolt that connects the heat receiving plate and the cooling plate is provided with the first urging member that urges the heat receiving plate and the cooling plate toward each other, so that the heat receiving plate is deformed by heat. Even in this case, the deformation state is absorbed by the elastic deformation of the first urging member, and the connection state between the heat receiving plate and the cooling plate can be maintained well. Therefore, the heat receiving plate, the low temperature plate, and the first O-ring It is possible to ensure the tight contact state and improve the airtight performance.
- the heat receiving plate and the cooling plate are urged by the second urging member even inside the first O-ring, so that the water cooling plate of the thermoelectric module interposed between them is Adhesion can be maintained satisfactorily, and it is possible to improve the reliability by suppressing the generation of stress in the thermoelectric module.
- the inner second bolt and its surroundings are also sealed with the second O-ring. Therefore, even when moisture enters from the insertion hole through which the second bolt is inserted, the heat receiving plate There is no fear of spreading between the cooling plate and the cooling plate, and the airtightness can be improved.
- the first and second O-rings are made of fluorine-based rubber, good heat resistance can be imparted, and it is suitably used for a thermoelectric power generator that generates power by receiving heat from a heat source. it can.
- the fifth invention it is suitable when the corners of the four corners are sealed with a square O-ring having a rounded shape between the heat receiving plate and the cooling plate, which are formed into a quadrangle, and particularly at the four corners where thermal deformation is likely to occur. There exists an effect that a connection state and airtightness can be maintained reliably.
- thermoelectric power generation apparatus which concerns on one Embodiment of this invention to the burner combustion part of the heat treatment furnace.
- FIG. 6 is a sectional view taken along line VI-VI in FIG. 4.
- the top view which shows the support structure of a thermoelectric module. Sectional drawing of the principal part of a thermoelectric module. Sectional drawing which shows the terminal block periphery of a thermoelectric power generation unit.
- FIG. 1 shows an example in which the thermoelectric generator 1 according to the present embodiment is applied to a burner combustion portion of a heat treatment furnace 100.
- the gas is burned in the gas burner 3 as fuel, and the exhaust gas after combustion is exhausted through the exhaust duct 2.
- a combustion gas burner 3 is provided below the exhaust duct 2, and the thermoelectric generator 1 is arranged at a position where the flame of the gas burner 3 reaches.
- heat energy at the time of gas combustion is converted into electricity by the thermoelectric generator 1.
- the thermoelectric generator of the present invention is not limited to the case where the thermoelectric generator is applied to the heat treatment furnace 100 as long as it is provided at a location exposed to a high temperature.
- FIG. 2 is a perspective view showing the thermoelectric generator 1.
- the thermoelectric generator 1 includes a thermoelectric power generation unit 4 that performs thermoelectric conversion, a shielding cover 5 that covers the thermoelectric power generation unit 4, and a fixing bracket 6 for fixing the thermoelectric power generation unit 4 to the exhaust duct 2.
- a bracket 6 is fixed to the exhaust duct 2.
- thermoelectric power generation unit 4 will be described in detail later with reference to FIG. 3 and thereafter, but is interposed between the lower heat receiving plate 10, the upper cooling plate 20, and the heat receiving plate 10 and the cooling plate 20.
- Thermoelectric module While the lower surface of the heat receiving plate 10 is heated from below by the flame of the gas burner 3, the cooling plate 20 is cooled by cooling water, and the heat receiving plate 10 and the cooling plate 20 are connected by a power generation module interposed therebetween. The Seebeck effect due to the temperature difference occurs and generates electricity.
- the shielding cover 5 is used to protect the thermoelectric power generation unit 4 from the flame of the gas burner 3 that wraps around from below.
- the shielding cover 5 includes a pair of long-side lower shielding plates 7 and 7 that are bolted to the long-side side surface of the heat receiving plate 10 that has a rectangular plate shape in plan view, and the long-side lower shielding.
- Long side upper shielding plates 8 and 8 that are bolted to the upper edges of the plates 7 and 7 and a pair of short side shielding plates 9 and 9 that are bolted to the short side surface of the heat receiving plate 10.
- Each of the shielding plates 7 to 9 is made of stainless steel, for example.
- the outer diameter of the cooling plate 20 is slightly smaller than the outer diameter of the heat receiving plate 10, and when the shielding cover 5 is attached to the heat receiving plate 10, a space is formed between the shielding cover 5 and the cooling plate 20.
- the long side lower shielding plate 7 has a height dimension up to approximately the fixed bracket 6. That is, the long side of the thermoelectric generator unit 4 is covered with the shielding plates 7 and 8 that are divided into two at the height position of the fixed bracket 6. Therefore, slits 7A and 8A are provided on the upper side of the long side lower shielding plate 7 and the lower side of the long side upper shielding plate 8 at positions corresponding to the fixing bracket 6, so that even if thermal expansion occurs, the fixing bracket 6 is not interfered with.
- One long side upper shielding plate 8 is provided with an opening 8B between the slits 8A and 8A. The opening 8 ⁇ / b> B is provided in order to pass the electrical wiring from the thermoelectric power generation unit 4 and the cooling water hose.
- Each of the shielding plates 7 to 9 has vertical side portions 71, 81, 91, the side portions 71, 81 of the upper and lower shielding plates 7, 8 on the long side, and the short side shielding adjacent thereto.
- the entire peripheral side of the thermoelectric power generation unit 4 is covered by causing the vertical edges to abut each other.
- a trapezoidal upper surface portion 82 and a triangular upper surface portion 92 bent in the plane direction are formed on the upper portions of the long side upper shielding plate 8 and the short side shielding plate 9, and these upper surface portions 82, The entire upper area of the thermoelectric power generation unit 4 is covered by the end edges of 92 being abutted.
- each of the shielding plates 7 to 9 the side surface portions 71, 81, 91 and the upper surface portions 82, 92 are not joined to each other. It is absorbed when the boundary part of each edge shifts. Therefore, in the entire shielding cover 5, thermal stress is unlikely to occur, and there is no fear of affecting the heat receiving plate 10 of the thermoelectric power generation unit 4 to which the shielding plates 7 and 9 are fixed. Conversely, even if thermal expansion and contraction occurs in the heat receiving plate 10, the boundary portions of the shielding plates 7 to 9 are displaced following the thermal expansion and contraction, so that it is difficult to generate stress in the shielding cover 5. The influence by the flame generated from the gas burner 3 is suppressed.
- the fixed bracket 6 has a support frame 61 in which a metal steel having an L-shaped cross section is joined in a substantially well shape. That is, the support frame 61 includes a pair of parallel support frame members 62 projecting from the shielding cover 5 at both ends, and a pair of parallel installation frame members 63 spanned between the support frame members 62 in the shielding cover 5. Consists of.
- Bolt holes 62A are provided at both ends of the support frame member 62, and the fixing bracket 6 is fixed to the exhaust duct 2 by bolts inserted through the bolt holes 62A.
- a pair of metal fixing blocks 64 are welded to the lower surface of the erection frame member 63 at intervals in the longitudinal direction.
- the fixed block 64 is a member for arranging the support frame 61 at a predetermined height position with respect to the cooling plate 20.
- the support frame 61 is cooled by bolts that penetrate the installation frame material 63 together with the fixed block 64. It is fixed to the upper surface of the plate 20.
- a metal cooling water block 65 is installed between the installation frame members 63.
- a supply hose that supplies cooling water from the outside and a return hose that returns the cooling water to the outside are connected to the cooling water block 65 through the opening 8B of the long side upper shielding plate 8, and an inlet provided in the cooling plate 20
- a supply hose for supplying the cooling water to and a return hose for returning the cooling water from the discharge port are connected. That is, the temperature-adjusted external cooling water is supplied to the cooling water circuit of the cooling plate 20 through the cooling water block 65, flows through the cooling water circuit, and then flows from the cooling plate 20 through the cooling water block 65. Returned outside.
- thermoelectric generator unit 3 is an overall perspective view of the thermoelectric generator unit 4, FIG. 4 is a plan view thereof, FIG. 5 is a side view thereof, and FIG. 6 is a sectional view taken along line VI-VI in FIG. FIG. 7 is a rear view of the cooling plate 20 of the thermoelectric power generation unit 4.
- the thermoelectric power generation unit 4 includes a copper-made rectangular plate-shaped heat receiving plate 10 whose surface is treated by black electroless nickel plating, and a copper-made rectangular shape whose outer dimensions are slightly smaller than the heat receiving plate 10.
- a plate-shaped cooling plate 20 and a plurality of thermoelectric modules 30 interposed between the heat receiving plate 10 and the cooling plate 20 are provided.
- the heat receiving plate 10 and the cooling plate 20 are fastened to each other by four bolts 11 at four corners and twelve bolts 12 positioned in four rows parallel to the long side and three rows parallel to the short side. . Accordingly, the heat receiving plate 10 is provided with bolt holes 13 and 14 into which the bolts 11 and 12 are screwed, and the cooling plate 20 is provided with an insertion hole (described later) through which the bolts 11 and 12 are inserted.
- a disc-shaped washer 11A is inserted through the bolt 11, and a coil spring 15 (first urging member) is inserted between the washer 11A and the upper surface of the cooling plate 20 while being inserted through the bolt 11. Is intervening. Further, a washer 12A is inserted through the bolt 12, and a coil spring 16 (second urging member) is interposed between the washer 12A and the upper surface of the cooling plate 20 while being inserted into the bolt 12. It is disguised.
- the coil spring 16 has a larger wire diameter and outer diameter than the coil spring 15, and the spring force of the coil spring 16 is greater than the spring force of the coil spring 15.
- the heat receiving plate 10 and the cooling plate 20 are biased toward each other by the spring force of the coil springs 15 and 16.
- a rectangular O-ring 17 (first O ring) having R shapes at the corners of the four corners extends along the peripheral edges of the heat receiving plate 10 and the cooling plate 20. It is intervened.
- the O-ring 17 surrounds the thermoelectric module 30, prevents moisture (humidity) from entering from the outside, and protects the thermoelectric module 30 from moisture.
- the four corner bolts 11 are located outside the O-ring 17 and close to the corner portion, and the other 12 bolts 12 are located inside the O-ring 17.
- the bolt 12 Since the bolt 12 is located inside the O-ring 17 and penetrates the cooling plate 20, as shown in FIG. 6, a small circular O-ring 18 (second O-ring 18) corresponding to this penetration portion. ) Is arranged. All the O-rings 18 are arranged inside the O-ring 17, and the periphery of the bolt 12 is sealed with the O-ring 18, thereby protecting the thermoelectric module 30 from moisture entering from the penetrating portion.
- the material of the O-rings 17 and 18 fluorine rubber having excellent heat resistance is employed.
- the coil spring 15 inserted through the bolt 11 urges the four corners of the heat receiving plate 10 and the cooling plate 20 that are easily separated by thermal deformation, reliably presses the corner portions of the O ring 17, and receives heat from the O ring 17.
- the close contact state between the plate 10 and the cooling plate 20 is maintained well.
- the coil spring 16 inserted into the bolt 12 biases the heat receiving plate 10 and the cooling plate 20, thereby securely holding the thermoelectric module 30, and also the heat receiving plate 10, the cooling plate 20 and the O-ring 17. It functions to maintain a close contact state with the straight portion and a close contact state with the O-ring 18. Further, the coil springs 15 and 16 reliably suppress warpage caused by heat of the heat receiving plate 10.
- a cooling water circuit 21 for flowing cooling water is provided inside the cooling plate 20.
- the cooling plate 20 has a two-layer structure, and the plate material forming one layer has a series of grooves substantially parallel to the long side and close to the short side edge.
- the cooling water circuit 21 is provided between the two plates, that is, inside the cooling plate 20 by covering the groove with a plate forming the other layer. Both plate materials are brazed at the outer peripheral portion and fixed together.
- an inlet 22 is erected at a position corresponding to one end of the cooling water circuit 21, and an outlet 23 (shown in FIGS. 4 and 5) is erected at a position corresponding to the other end.
- a supply hose and a return hose (not shown) from the cooling water block 65 are connected to the inlet 22 and the outlet 23, respectively.
- the insertion holes 24 through which the bolts 11 are inserted are provided at the four corners of the cooling plate 20, and the bolts 12 are inserted into 12 locations inside the cooling plate 20.
- An insertion hole 25 is provided.
- positioning pins 26 are provided on the back surface of the cooling plate 20 so as to be close to the inside of the insertion holes 24 at the four corners, and four positioning pins 27 are provided on the long side edge. Positioning pins 27 project from the center positions of the edges.
- An O-ring 17 is disposed so as to pass outside these positioning pins 26 and 27.
- thermoelectric module 30 a large number of positioning pins 28 for the thermoelectric module 30 are projected from the back surface side of the cooling plate 20.
- the plate-like thermoelectric module 30 that is substantially square in plan view is positioned by abutting the center portions of the three sides thereof with the positioning pins 28.
- the positioning pins 26 to 28 described above are provided on the cooling plate 20 side because the cooling plate 20 hardly expands and contracts due to heat, and the positioning state of the O-rings 17 and 18 and the thermoelectric module 30 can be maintained well. is there.
- a strip-shaped metal plate (not shown) is provided on the outer peripheral end surface of the cooling plate 20, and the metal plate covers the gap between the heat receiving plate 10 and the cooling plate 20 to reduce the thermal effect on the O-ring 17. ing.
- thermoelectric module 30 has a structure in which a plurality of thermoelectric elements 301 are sandwiched between plate-shaped heat receiving surface portions 302 and cooling surface portions 303, respectively. That is, in the thermoelectric module 30, the heat receiving side electrode 302A is disposed on the inner side surface of the heat receiving surface portion 302, and the cooling side electrode 303A is disposed on the inner side surface of the cooling surface portion 303, so that the P-type thermoelectric element 301A and the N-type thermoelectric element are arranged.
- the end surface on the heat receiving surface portion 302 side of the element 301B is connected to the heat receiving side electrode 302A, and the end surfaces on the cooling surface portion 303 side of the P-type thermoelectric element 301A and the N-type thermoelectric element 301B are connected to the cooling side electrode 303A.
- the P-type thermoelectric element 301A and the N-type thermoelectric element 301B are electrically connected in series via the heat receiving side electrode 302A and the cooling side electrode 303A alternately to constitute the thermoelectric module 30.
- thermoelectric module 30 is arranged in the same plane with a total of 16 rows of 4 rows parallel to the long sides of the heat receiving plate 10 and the cooling plate 20 and 4 rows parallel to the short sides. Of the four thermoelectric modules 30 parallel to the short side, two adjacent thermoelectric modules 30 are arranged close to each other (see also FIG. 4). The thermoelectric module 30 is in contact with the heat receiving plate 10 and the cooling plate 20 through grease applied to the front and back sides. When the heat receiving plate 10 becomes hot, the heat receiving side electrode 37A of the thermoelectric module 30 is thermally expanded. The thermoelectric module 30 warps due to the temperature difference between the heat receiving side electrode 37A and the cooling side electrode 38A.
- thermoelectric modules 30 (311, 312, 313, 314) that are parallel to the short side and arranged along the left side edge in FIG. 4 will be described as a representative pair.
- the thermoelectric modules 311, 312 (and 313, 314) of the other thermoelectric module 311 (313) and the positive electrode connection terminal of the other thermoelectric module 312 (314) are electrically connected by the lead wire 33.
- the lead wire 34 is connected to the positive electrode of one thermoelectric module 314, and the lead wire 35 is connected to the negative electrode of the other thermoelectric module 311. That is, the thermoelectric modules 311 to 314 are electrically connected in series.
- the other four thermoelectric modules 30 arranged parallel to the short sides.
- the lead wire 34 from the positive electrode is connected to the first terminal block 36 at the left end in the figure provided on the upper surface of the cooling plate 20,
- the lead wire 34 is connected to the second terminal block 37, and in the thermoelectric module 331 in the third column and the first row, the lead wire 34 is connected to the third terminal block 38.
- the lead wire 34 is connected to the fourth terminal block 39 at the right end.
- the first to fourth terminal blocks 36 to 39, 41 will be described with reference to FIGS. 9 and 10, the first to fifth terminal blocks 36 to 39, 41 are centered around the fifth terminal block 41 on the central axis parallel to the long side of the cooling plate 20, Each includes a spacer 43, a terminal 44, and a resin cover 45.
- the cooling plate 20 is provided with through holes 42 at positions corresponding to the first to fifth terminal blocks 36 to 39, 41, and the lead wires 34, 35 from the thermoelectric module 30 are drawn to the upper surface through the through holes 42. .
- a cylindrical spacer 43 made of a fluororesin is disposed on the upper surface of the cooling plate 20 so as to surround the through hole 42.
- a cylindrical terminal 44 made of a metal such as stainless steel having conductivity is provided on the upper portion of the spacer 43.
- the spacer 43 and the terminal 44 are covered with a resin cover 45 made of, for example, polyimide resin having heat resistance.
- the first to fifth terminal blocks 36 to 39, 41 are covered with a metal cover 46 such as aluminum fixed directly to the cooling plate 20.
- a metal cover 46 such as aluminum fixed directly to the cooling plate 20.
- Each of the resin cover 45 and the metal cover 46 has a cylindrical shape, and has cutout openings 45A and 46A cut out from the upper part in a part of the outer periphery. Further, the opening portions on the upper side of the covers 45 and 46 are closed by disk-shaped lids 47 and 48.
- the resin cover 45 is fixed to the cooling plate 20 with the lid 47 being fastened together with three bolts 49
- the metal cover 46 is fixed to the cooling plate 20 with the lid 48 being fastened together with two bolts 51. Is done.
- a terminal 52 at the tip of the lead wires 34 and 35 is fixed to the lower surface of the terminal 44 by a screw 53, and a terminal 55 of an external power line 54 is connected to the upper surface of the terminal 44 by a screw 56.
- the power line 54 is wired through the cutout openings 45A and 46A of the covers 45 and 46, respectively.
- an O-ring 57 is interposed between the upper surface of the cooling plate 20 and the lower surface of the spacer 43, and an O-ring 58 is interposed between the spacer 43 and the terminal 44, so that the spacer 43 and the resin cover 45 are interposed.
- An O-ring 59 is interposed between the two. Moisture that enters from between the cooling plate 20 and each of the covers 45 and 46 and moisture that enters from the cutout openings 45A and 46A of the covers 45 and 46 are sealed by their O-rings 57 to 59 and are contained in the spacer 43. This prevents moisture from penetrating from the through hole 42 located at the side to the thermoelectric module 30 side.
- the resin cover 45 and the O-rings 57 to 59 are covered with the metal cover 46, the resin cover 45 and the O-rings 57 to 59 are not affected by the influence of heat from the outside, particularly the radiation heat from the shielding cover 5. Thus, by preventing the deformation of the O-rings 57 to 59, etc., there is an effect that the airtight performance can be maintained satisfactorily.
- the metal cover 46 is cooled by being in contact with the upper surface of the cooling plate 20, there is no concern that the metal cover 46 itself becomes excessively hot due to radiant heat. Further, since the first to fifth terminal blocks 36 to 39, 41 described above are concentrated on the central axis near the center of the cooling plate 20, the distance from the shielding cover 5 is gained and the influence of radiant heat is reduced. Less.
- thermoelectric generator 1 was applied to the heat treatment furnace 100, it is not limited to this, You may apply the thermoelectric generator of this invention to the arbitrary locations which have a heat source.
- the cooling plate 20 is provided with the cooling water circuit 21 and is actively cooled with the cooling water.
- the cooling plate may be maintained at a low temperature relative to the heat receiving plate. Even when there is no such positive cooling means, it is included in the present invention.
- the coil spring is used as the biasing member according to the present invention, but an elastic body made of any elastomer material may be used.
- the material of the O-ring according to the present invention is not limited to a fluorine-based material, and may be a general material such as nitrile rubber or butyl rubber when heat resistance is not required so much.
- the present invention relates to a thermoelectric power generation apparatus that generates power by receiving heat from a heat source, and can be used for various industrial equipment, automobiles driven by engines, construction machines, railway vehicles, and the like.
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Abstract
Description
図1は、本実施形態に係る熱電発電装置1を熱処理炉100のバーナ燃焼部分に適用した例を示すものである。熱処理炉100で使用済みのガスを排気するにあたり、このガスを燃料としてガスバーナ3にて燃焼させ、燃焼後の排気ガスを排気ダクト2を通して排気している。排気ダクト2の下方には燃焼用ガスバーナ3が設けられ、ガスバーナ3の火炎が届く位置に熱電発電装置1が配置されている。ガスバーナ3からの火炎で炙られることで、ガス燃焼時の熱エネルギを熱電発電装置1によって電気に変換している。
ただし、本発明の熱電発電装置は、高温に曝される個所に設けられればよく、熱処理炉100に適用される場合に限らない。
図2は、熱電発電装置1を示す斜視図である。
熱電発電装置1は、熱電変換を行う熱電発電ユニット4と、この熱電発電ユニット4を覆う遮蔽カバー5と、熱電発電ユニット4を排気ダクト2に固定するための固定ブラケット6とを備え、この固定ブラケット6が排気ダクト2に固定される。
熱電発電ユニット4は、詳細には図3以降に基づいて後述するが、図中下側の受熱板10と、上側の冷却板20と、これら受熱板10および冷却板20との間に介装された熱電モジュールとを備えている。受熱板10の下面がガスバーナ3の火炎で下方から加熱される一方、冷却板20が冷却水にて冷却され、これらの間に介装された発電ジュールにて受熱板10と冷却板20との温度差によるゼーベック効果が生じ、発電する。
遮蔽カバー5は、下方から回り込んで来るガスバーナ3の火炎から熱電発電ユニット4を保護するために用いられる。具体的に遮蔽カバー5は、平面視で矩形板状とされた受熱板10の長辺側の側面にボルト止めされる一対の長辺側下部遮蔽板7,7と、これら長辺側下部遮蔽板7,7の上縁にボルト止めされる長辺側上部遮蔽板8,8と、受熱板10の短辺側の側面にボルト止めされる一対の短辺側遮蔽板9,9とで構成されている。各遮蔽板7~9は、例えばステンレス製である。冷却板20の外径寸法は受熱板10の外径寸法よりも僅かに小さく、遮蔽カバー5が受熱板10に取り付けられた時、遮蔽カバー5と冷却板20との間には空間が形成される。
固定ブラケット6は、断面L字形状の金属形鋼を略井型形状に接合した支持枠61を有している。すなわち支持枠61は、両端が遮蔽カバー5から突出する一対の平行な支持枠材62と、遮蔽カバー5内において、支持枠材62間に跨って架け渡される一対の平行な架設枠材63とで構成される。
架設枠材63の下面には、長手方向に間隔を空けて一対の金属製の固定ブロック64が溶着されている。固定ブロック64は、冷却板20に対して支持枠61を所定の高さ位置に配置するための部材であり、支持枠61としては、架設枠材63を固定ブロック64ごと貫通するボルトにより、冷却板20の上面に固定されている。
図3は、熱電発電ユニット4の全体斜視図、図4はその平面図、図5はその側面図、図6は図4のVI-VI線断面図である。図7は、熱電発電ユニット4の冷却板20の裏面図である。
ボルト11には円板状の座金11Aが貫挿されており、座金11Aと冷却板20の上面との間には、ボルト11に挿通された状態でコイルばね15(第1の付勢部材)が介装されている。また、ボルト12には座金12Aが貫挿されており、座金12Aと冷却板20の上面との間には、ボルト12に挿通された状態でコイルばね16(第2の付勢部材)が介装されている。コイルばね16の線径および外径はそれぞれ、コイルばね15よりも大きく、コイルばね16のばね力はコイルばね15のばね力よりも大きい。これらのコイルばね15,16のばね力により、受熱板10および冷却板20は互いに近づく方向へ付勢されている。
図3、図7に示すように、冷却板20の内部には、冷却水を流す冷却水回路21が設けられている。詳細な図示を省略するが、冷却板20は2層構造であり、一方の層を形成する板材には、一連の溝が長辺に対して略平行で、かつ短辺側の辺縁近くで折り返されて蛇行するように設けられ、この溝を他方の層を形成する板材で覆うことで、両板材の間、すなわち冷却板20の内部に冷却水回路21が設けられる。両板材は、外周部分でろう付けされて一体に固着される。
また、冷却板20の外周端面には、図示しない帯状の金属板が設けられ、この金属板により受熱板10と冷却板20との間の隙間を覆い、Oリング17への熱影響を軽減させている。
図8Aおよび図8Bにおいて、熱電モジュール30は、複数の熱電素子301をそれぞれ板状の受熱面部302および冷却面部303で挟持した構造である。すなわち、熱電モジュール30では、受熱面部302の内側面に受熱側電極302Aが配置され、冷却面部303の内側面に冷却側電極303Aが配置されており、P型の熱電素子301AおよびN型の熱電素子301Bの受熱面部302側の端面が受熱側電極302Aに接続され、P型の熱電素子301AおよびN型の熱電素子301Bの冷却面部303側の端面が冷却側電極303Aに接続されている。P型の熱電素子301AとN型の熱電素子301Bとが交互に受熱側電極302Aおよび冷却側電極303Aを介して電気的に直列接続されることにより、熱電モジュール30が構成されている。
以下には、図9、図10に基づき第1~第4ターミナルブロック36~39,41について説明する。
図9、図10において、第1~第5ターミナルブロック36~39,41は、第5ターミナルブロック41を中心として、冷却板20の長辺に平行な中心軸線上で中央に集約されており、それぞれスペーサ43、ターミナル44、および樹脂カバー45を備えている。
例えば、前記実施形態では、熱電発電装置1が熱処理炉100に適用されていたが、これに限定されるものではなく、熱源を有する任意の箇所に本発明の熱電発電装置を適用してよい。
また、本発明に係るOリングの材質はフッ素系に限定されず、例えば、さほど耐熱性が要求されなない場合には、ニトリルゴムやブチルゴム等の一般的な材質であってもよい。
Claims (5)
- 受熱する受熱板と、
前記受熱板よりも低温に維持される冷却板と、
前記受熱板および前記冷却板の間に介装される熱電モジュールとを備え、
前記受熱板および前記冷却板の間には、前記熱電モジュールの外側を囲む第1のOリングが設けられ、
前記受熱板および前記冷却板は、前記第1のOリングの外側の位置で互いに第1のボルトにより連結され、
前記第1のボルトには、前記受熱板および前記冷却板を互いに近づける方向に付勢する弾性を有した第1の付勢部材が設けられている
ことを特徴とする熱電発電装置。 - 請求項1に記載の熱電発電装置において、
前記受熱板および前記冷却板は、前記第1のOリングの内側の位置で互いに第2のボルトにより連結され、
前記第2のボルトには、前記受熱板および前記冷却板を互いに近づける方向に付勢する弾性を有した第2の付勢部材が設けられ、
前記第1のOリングの内側の前記第2の付勢部材の付勢力は、前記第1の付勢部材の付勢力よりも大きい
ことを特徴とする熱電発電装置。 - 請求項2に記載の熱電発電装置において、
前記受熱板および前記冷却板の間には、前記第1のOリングの内側の前記第2のボルトに貫挿された第2のOリングが介装されている
ことを特徴とする熱電発電装置。 - 請求項1ないし請求項3に記載の熱電発電装置において、
前記熱電モジュールを囲う前記第1のOリング、および前記第1のOリングの内側の前記第2のボルトに貫挿された前記第2のOリングは、フッ素系のゴム製である
ことを特徴とする熱電発電装置。 - 請求項4に記載の熱電発電装置において、
前記受熱板、前記冷却板、および複数の前記熱電モジュールを有した熱電発電ユニットと、
前記熱電発電ユニットを覆う金属製の遮蔽カバーと、
当該熱電発電装置を所定の位置に固定する固定ブラケットとを備え、
前記受熱板および前記冷却板は、前記熱電モジュールを囲う前記第1のOリングの外側の位置および内側の位置で互いに前記第1および前記第2のボルトにより連結され、
これらの前記第1および前記第2のボルトには、前記受熱板および前記冷却板を互いに近づける方向に付勢する前記第1および前記第2の付勢部材が設けられ、
前記第1のOリングの内側の前記第2の付勢部材の付勢力は、前記第1のOリングの外側の前記第1の付勢部材の付勢力よりも大きく、
前記受熱板および前記冷却板の間には、前記第1のOリングの内側の前記第2のボルトに貫挿された前記第2のOリングが介装され、
前記第1のOリングは各角部にR形状を有する四角形とされ、
前記第1のOリングの外側の位置にある前記第1のボルトは、前記第1のOリングの角部に対応して設けられ、
前記第1の付勢部材および前記第2の付勢部材はコイルばねである
ことを特徴とする熱電発電装置。
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JP2018049886A (ja) * | 2016-09-20 | 2018-03-29 | 昭和電工株式会社 | 熱電変換装置 |
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JP2001165525A (ja) * | 1999-12-07 | 2001-06-22 | Seiko Seiki Co Ltd | 熱電加熱冷却装置 |
JP2002139264A (ja) * | 2000-11-02 | 2002-05-17 | Komatsu Electronics Inc | 熱交換装置 |
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US6341490B1 (en) * | 2001-03-03 | 2002-01-29 | Gilson, Inc. | Heat transfer apparatus for sample containing well plates |
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US20070095379A1 (en) * | 2005-10-31 | 2007-05-03 | Taher Mahmoud A | Thermoelectric generator |
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JP2001165525A (ja) * | 1999-12-07 | 2001-06-22 | Seiko Seiki Co Ltd | 熱電加熱冷却装置 |
JP2002139264A (ja) * | 2000-11-02 | 2002-05-17 | Komatsu Electronics Inc | 熱交換装置 |
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US20140216516A1 (en) | 2014-08-07 |
KR20140051416A (ko) | 2014-04-30 |
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