WO2012168530A1 - Munición ecológica - Google Patents
Munición ecológica Download PDFInfo
- Publication number
- WO2012168530A1 WO2012168530A1 PCT/ES2012/070428 ES2012070428W WO2012168530A1 WO 2012168530 A1 WO2012168530 A1 WO 2012168530A1 ES 2012070428 W ES2012070428 W ES 2012070428W WO 2012168530 A1 WO2012168530 A1 WO 2012168530A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- zinc
- bismuth
- tin
- composite material
- Prior art date
Links
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 37
- 239000011701 zinc Substances 0.000 claims abstract description 34
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052751 metal Inorganic materials 0.000 claims abstract description 29
- 239000002184 metal Substances 0.000 claims abstract description 27
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 22
- 229910052718 tin Inorganic materials 0.000 claims abstract description 22
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000011159 matrix material Substances 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 229910001297 Zn alloy Inorganic materials 0.000 claims abstract description 11
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 10
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001152 Bi alloy Inorganic materials 0.000 claims abstract description 7
- 239000002923 metal particle Substances 0.000 claims abstract description 7
- -1 wolframium carbides Chemical class 0.000 claims abstract description 6
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims description 43
- 239000011135 tin Substances 0.000 claims description 20
- 239000008188 pellet Substances 0.000 claims description 14
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 11
- 229910052721 tungsten Inorganic materials 0.000 claims description 11
- 239000010937 tungsten Substances 0.000 claims description 11
- 229910001128 Sn alloy Inorganic materials 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- VVRQVWSVLMGPRN-UHFFFAOYSA-N oxotungsten Chemical class [W]=O VVRQVWSVLMGPRN-UHFFFAOYSA-N 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 4
- 238000003466 welding Methods 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000009428 plumbing Methods 0.000 claims description 2
- 230000002787 reinforcement Effects 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 238000007792 addition Methods 0.000 description 16
- 230000008018 melting Effects 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 235000019589 hardness Nutrition 0.000 description 6
- 239000010953 base metal Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 description 3
- 229910001145 Ferrotungsten Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- JWVAUCBYEDDGAD-UHFFFAOYSA-N bismuth tin Chemical compound [Sn].[Bi] JWVAUCBYEDDGAD-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- GXBKELQWVXYOPN-UHFFFAOYSA-N iron tungsten Chemical compound [W][Fe][W] GXBKELQWVXYOPN-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C12/00—Alloys based on antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C28/00—Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/26—Selection of soldering or welding materials proper with the principal constituent melting at less than 400 degrees C
- B23K35/262—Sn as the principal constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/26—Selection of soldering or welding materials proper with the principal constituent melting at less than 400 degrees C
- B23K35/264—Bi as the principal constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/28—Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
- B23K35/282—Zn as the principal constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
- C22C13/02—Alloys based on tin with antimony or bismuth as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
- C22C18/04—Alloys based on zinc with aluminium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/001—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
- C22C32/0015—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
- C22C32/0042—Matrix based on low melting metals, Pb, Sn, In, Zn, Cd or alloys thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
- C22C32/0052—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/72—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material
- F42B12/74—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material of the core or solid body
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B7/00—Shotgun ammunition
- F42B7/02—Cartridges, i.e. cases with propellant charge and missile
- F42B7/04—Cartridges, i.e. cases with propellant charge and missile of pellet type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B7/00—Shotgun ammunition
- F42B7/02—Cartridges, i.e. cases with propellant charge and missile
- F42B7/04—Cartridges, i.e. cases with propellant charge and missile of pellet type
- F42B7/046—Pellets or shot therefor
Definitions
- the present invention relates to new composite materials that replace lead for, among other applications, the manufacture of ecological ammunition such as, for example, pellets, which comprise a metal matrix in which metallic reinforcing particles are distributed.
- Lead pellets are conventionally used in hunting activities. Density is the characteristic that gives lead pellet its excellent ballistic properties. This characteristic is what makes it very difficult to obtain new materials for the manufacture of pellets suitable for said hunting activities.
- US Pat. No. 6149705 describes the development of pellets composed of a tungsten carbide powder core, which may also contain elements such as tungsten or Tantalum, coated with metals such as aluminum, bismuth, copper, tin or zinc.
- said ammunition has the disadvantage of excessive hardness of the tungsten carbide core, which, when impacted with the hunting objective, produces a perforation of the animal with exit.
- Said composite material was based on a metal matrix in which reinforcing particles were distributed, the metal matrix being composed of an alloy of zinc and bismuth, of zinc and aluminum, of tin and bismuth and the tungsten reinforcing metal particles being or ferro-tungsten subjected to oxidation prior to its addition to the metal matrix.
- These materials are of type ODS (Oxyde dispersed strenght or particulate dispersion).
- the authors of the present invention have introduced a series of improvements in the composition of the ODS-type composite material of the ES 2223305 patent. Specifically, in this addition they contemplate a new base metal alloy, of tin and zinc, as well as the incorporation of a third metal, selected from aluminum and / or bismuth, to the metal matrix.
- the new composite materials with bismuth addition have higher densities, lower melting points and a combination of optimum hardness-plasticity properties.
- the object of the present invention is the same as that of Spanish patent ES 2223305, that is, to provide an alternative composite material to lead for the manufacture of ecological ammunition comprising a metal matrix and metal reinforcing particles distributed therein.
- the present invention provides an ecological composite material type ODS (Oxyde dispersed strenght or particulate dispersion) comprising a) a metal matrix composed of an alloy of zinc and bismuth, zinc and aluminum, tin and bismuth or zinc and tin and a metal selected from aluminum, bismuth and its combination and b) reinforcing metal particles distributed therein selected from tungsten, ferro-tungsten, tungsten carbides, tungsten carbides, tungsten oxides and tungsten oxides, subjected to oxidation prior to their addition to the metal matrix
- ODS ecological composite material type ODS (Oxyde dispersed strenght or particulate dispersion) comprising a) a metal matrix composed of an alloy of zinc and bismuth, zinc and aluminum, tin and bismuth or zinc and tin and a metal selected from aluminum, bismuth and its combination and b) reinforcing metal particles distributed therein selected from tungsten, ferro-tungsten, tungsten carb
- One of the advantages of the new addition of bismuth to the composite materials of the patent ES 2223305, is to reduce the melting points of said composite materials. This entails significant economic savings in terms of the energy cost of merging these new composite materials and, therefore, saving the cost of the final product produced.
- Another improvement of the addition of bismuth to the composite materials of the patent ES 2223305 is the obtaining of new composite materials with intermediate properties between the certain fragility of the bismuth and the greater hardness of the composite materials, thus maintaining the optimal properties of deformability that these composite materials possess.
- the addition of bismuth allows to obtain materials with even greater density. This fact allows the use of these new composite materials with guarantees in those applications in which lead is still present, and which have been discussed previously.
- the new addition of aluminum to the composite materials of the patent ES 2223305 makes it possible to obtain a new range of lighter and lower cost materials, which can be used for those applications that require lightness in their components, given that Aluminum is a metallic element with low density.
- the base metal alloy is zinc and bismuth, tin and bismuth or zinc and tin
- the addition of aluminum is contemplated.
- aluminum is present in a proportion of 0.1 -10% by weight with respect to the total weight of metal alloy.
- the addition of bismuth is contemplated.
- bismuth is present in a proportion of 0.1 -10% by weight with respect to the total weight of metal alloy.
- the addition of aluminum and / or bismuth is contemplated, each in a proportion of OJ I OLO by weight with respect to the total weight of metal alloy.
- the metal matrix is composed of a zinc alloy and bismuth with 2-44% by weight of bismuth and 56-98% in zinc weight; or a zinc and aluminum alloy with 75-95% by weight zinc and 5-25% by weight aluminum; or a bismuth and tin alloy with 71 -99% by weight of bismuth and 1 -29% by weight of tin, or a zinc and tin alloy with 1 -99% by weight of zinc and tin with a 99 -1% by weight, percentages by weight with respect to the total alloy weight.
- the new metal alloys contemplated in this application would therefore be defined by the following formulas:
- the melting temperatures of these new ODS-type materials would be between 300 -600 e C, in the case of bismuth and zinc, between 300-650 e C, in the case of zinc and aluminum, between 170-400 e C, in the case of bismuth and tin, or between 300-600 e C , in the case of zinc and tin.
- the reinforcing metal particles have an average diameter of 1-500 ⁇ .
- the ratio between the metal matrix and the reinforcing metal particles varies between 0 and 1.5.
- the metal matrix of the new composite material additionally comprises a metal selected from antimony, iron, tin, zinc, copper and combinations thereof.
- the composition of the new composite material contemplated in this addition to the patent ES 2223305 gives it some properties that make it suitable not only for the manufacture of ecological ammunition, but also for the manufacture of weights and plumbing hooks for fishing, inertial counterweights in cars and mobile devices, welding in electronic products, sports equipment, radiation protection materials, personal protection material, car batteries and water pipes.
- the new ODS type composite material is constituted by the tin-base alloy. bismuth and aluminum (1 -10%), has a density between 8-9 g / cc, a melting point between 350-650 e C and mechanical properties such as good ductility and malleability, which make it a material Optimum compound for the manufacture of weights and leaded hooks for fishing.
- the new composite material is constituted by the zinc-tin and bismuth base alloy (1-10%), has a density between 7.5-8 g / cc, a melting point between 350-650 e C and physical properties such as a low melting point that make it an optimal composite material for use in welding electronic products.
- Another aspect of the invention contemplates an ecological ammunition manufactured from the composite material of the present invention.
- said ecological ammunition is a pellet with a density of 7-14 g / cm3.
- said pellet has magnetic properties.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12796970.7A EP2719785A1 (en) | 2011-06-08 | 2012-06-08 | Ecological ammunition |
BR112013031687A BR112013031687A2 (pt) | 2011-06-08 | 2012-06-08 | munição ecológica |
US14/124,363 US20140130698A1 (en) | 2011-06-08 | 2012-06-08 | Ecological ammunition |
RU2014100119/02A RU2014100119A (ru) | 2011-06-08 | 2012-06-08 | Экологические боеприпасы |
KR20147000282A KR20140135143A (ko) | 2011-06-08 | 2012-06-08 | 생태적 탄약 |
AU2012266210A AU2012266210A1 (en) | 2011-06-08 | 2012-06-08 | Ecological ammunition |
MX2013014313A MX2013014313A (es) | 2011-06-08 | 2012-06-08 | Municion ecologica. |
JP2014514115A JP2014523964A (ja) | 2011-06-08 | 2012-06-08 | 低環境負荷弾体 |
CA2843682A CA2843682A1 (en) | 2011-06-08 | 2012-06-08 | Ecological ammunition |
CN201280038241.4A CN103781930A (zh) | 2011-06-08 | 2012-06-08 | 生态弹药 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES201130955A ES2398575B1 (es) | 2011-06-08 | 2011-06-08 | Adición a la patente es2223305 "munición ecológica". |
ESP201130955 | 2011-06-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012168530A1 true WO2012168530A1 (es) | 2012-12-13 |
Family
ID=47295536
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/ES2012/070428 WO2012168530A1 (es) | 2011-06-08 | 2012-06-08 | Munición ecológica |
Country Status (14)
Country | Link |
---|---|
US (1) | US20140130698A1 (es) |
EP (1) | EP2719785A1 (es) |
JP (1) | JP2014523964A (es) |
KR (1) | KR20140135143A (es) |
CN (1) | CN103781930A (es) |
AR (1) | AR086855A1 (es) |
AU (1) | AU2012266210A1 (es) |
BR (1) | BR112013031687A2 (es) |
CA (1) | CA2843682A1 (es) |
CL (1) | CL2013003509A1 (es) |
ES (1) | ES2398575B1 (es) |
MX (1) | MX2013014313A (es) |
RU (1) | RU2014100119A (es) |
WO (1) | WO2012168530A1 (es) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2878917A1 (en) * | 2013-11-29 | 2015-06-03 | Real Federacion Espanola de Caza | Chemical composition for manufacturing ammunition |
US10343219B2 (en) * | 2014-03-04 | 2019-07-09 | University Of Florida Research Foundation, Inc. | Method for producing nanoparticles and the nanoparticles produced therefrom |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9528804B2 (en) * | 2013-05-21 | 2016-12-27 | Amick Family Revocable Living Trust | Ballistic zinc alloys, firearm projectiles, and firearm ammunition containing the same |
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CN106854718B (zh) * | 2016-12-02 | 2019-05-21 | 中国人民解放军国防科学技术大学 | 含能结构材料及其制备方法和应用 |
US20220316845A1 (en) * | 2019-05-06 | 2022-10-06 | Dlm Holding Group Llc | Plated Bismuth Shot |
CN115198142A (zh) * | 2022-07-21 | 2022-10-18 | 株洲威利格钨钢制品有限公司 | 一种基于铋锡合金的渔具用材料及加工工艺 |
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- 2012-06-08 RU RU2014100119/02A patent/RU2014100119A/ru not_active Application Discontinuation
- 2012-06-08 KR KR20147000282A patent/KR20140135143A/ko not_active Application Discontinuation
- 2012-06-08 WO PCT/ES2012/070428 patent/WO2012168530A1/es active Application Filing
- 2012-06-08 US US14/124,363 patent/US20140130698A1/en not_active Abandoned
- 2012-06-08 CA CA2843682A patent/CA2843682A1/en not_active Abandoned
- 2012-06-08 CN CN201280038241.4A patent/CN103781930A/zh active Pending
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US10343219B2 (en) * | 2014-03-04 | 2019-07-09 | University Of Florida Research Foundation, Inc. | Method for producing nanoparticles and the nanoparticles produced therefrom |
US11618077B2 (en) | 2014-03-04 | 2023-04-04 | University Of Florida Research Foundation, Inc. | Method for producing nanoparticles and the nanoparticles produced therefrom |
US11781199B2 (en) | 2014-03-04 | 2023-10-10 | University Of Florida Research Foundation, Inc. | Method for producing nanoparticles and the nanoparticles produced therefrom |
Also Published As
Publication number | Publication date |
---|---|
KR20140135143A (ko) | 2014-11-25 |
ES2398575A2 (es) | 2013-03-20 |
EP2719785A1 (en) | 2014-04-16 |
CN103781930A (zh) | 2014-05-07 |
US20140130698A1 (en) | 2014-05-15 |
ES2398575R1 (es) | 2013-06-10 |
AR086855A1 (es) | 2014-01-29 |
CA2843682A1 (en) | 2012-12-13 |
ES2398575B1 (es) | 2014-04-15 |
JP2014523964A (ja) | 2014-09-18 |
CL2013003509A1 (es) | 2014-07-18 |
RU2014100119A (ru) | 2015-07-20 |
BR112013031687A2 (pt) | 2016-12-06 |
AU2012266210A1 (en) | 2014-01-30 |
MX2013014313A (es) | 2014-04-30 |
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