WO2012165511A1 - イネの病害防除方法 - Google Patents
イネの病害防除方法 Download PDFInfo
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- WO2012165511A1 WO2012165511A1 PCT/JP2012/063999 JP2012063999W WO2012165511A1 WO 2012165511 A1 WO2012165511 A1 WO 2012165511A1 JP 2012063999 W JP2012063999 W JP 2012063999W WO 2012165511 A1 WO2012165511 A1 WO 2012165511A1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/06—Coating or dressing seed
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
Definitions
- the present invention relates to a rice disease control method. More specifically, the present invention relates to a method for controlling rice diseases by causing active ingredients to act directly on rice seeds.
- rice diseases and countermeasures are important issues regardless of old and new. So far, various active ingredients exhibiting rice disease control activity have been studied, and a large number of rice disease control agents have been developed and commercialized.
- These rice disease control agents take various application forms according to the properties designed as agricultural chemical formulations.
- foliage sprayed directly on the foliage water surface application on the paddy field
- rice seedling application applied directly to the nursery box for rice seedling growth before transplanting to the rice field, after transplanting to the side of the transplanted seedling
- Examples include side strip application to be applied to the seed, and seed treatment in which the chemical is directly applied to the rice seeds before germination.
- a preparatory step for promoting the germination of rice seeds is usually performed prior to sowing. That is, the rice seed is immersed in cold water at around 15 ° C. and the water is absorbed by the rice seed continuously for about 6 days while changing the water as appropriate. Then, the rice seed is immersed in warm water at around 30 ° C. for about 24 hours. A sprouting step is carried out, which is immersed and exposed to heat. In seed treatment, chemical application is performed before or during these steps.
- the seed treatment mode is further subdivided, for one batch of water used in the preparatory step, seed soaking using a chemical solution containing the chemical, seed powder that scatters the powdered chemical on rice seeds before the preparatory step
- a chemical solution containing the chemical, seed powder that scatters the powdered chemical on rice seeds before the preparatory step examples include seed smearing and seed spraying, in which a drug dissolved in water is dripped or sprayed on the rice seeds before the pretreatment process.
- seed treatment is a method in which a high concentration of chemicals is directly brought into contact with seeds that are the most immature and delicate state of rice during the life of the rice. For this reason, there are several drugs that can theoretically be used for seed treatment, but currently, there are many drugs that are highly safe for rice in seed treatment and have been registered as agricultural chemicals for practical use in seed treatment. Very limited.
- the application form of seed treatment is characterized in that the period from treatment of the drug to the onset of rice disease is longer than other control methods. For this reason, there is a problem that the efficacy of the seed-treated active ingredient is not sustained and a sufficient control effect cannot be exerted against rice diseases that occur in a relatively late period (for example, the late stage of rice growth). Therefore, at present, rice disease control by seed treatment is performed exclusively for the purpose of controlling rice diseases until the seedling stage. For rice diseases that occur after that, it is necessary to separately carry out agricultural work to spread the chemicals on the paddy fields before and after the occurrence of the target rice diseases, and the reduction of labor load by seed treatment is still insufficient.
- powder coating treatment, smearing treatment, etc. also have problems in the physical utilization rate of active ingredients. Even if the active ingredients are attached to the surface of the rice seeds by these treatments, the rice seeds are immersed in water several times and taken out in the subsequent preparatory steps. Most of it will be washed away. This is also true in the dipping process, except when dipping at the final stage of the pretreatment process. Therefore, in these treatments, in addition to the amount of the active ingredient originally required for obtaining a sufficient control effect, an extra active ingredient amount in anticipation of the above-mentioned loss is required. This means that seed treatment (especially powder coating treatment and smear treatment) requires more chemicals than the method of spraying chemicals on paddy fields, and it can be evaluated that it contributes to labor saving in farm work. However, it cannot be denied that this is an economically disadvantageous method.
- Compound 1 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide (hereinafter sometimes referred to as Compound 1) is one of the active ingredients of rice disease control agents. ) Is known (Patent Document 2). However, the effectiveness, application rate, phytotoxicity (safety), etc. when compound 1 is allowed to act on rice seeds have not been specifically studied, and the practicality of compound 1 as a seed treatment agent is completely unknown. is there.
- the present invention provides a rice disease control method that is highly safe to rice, simple and efficient, has a low labor load, and can exhibit a sufficient effect. Objective.
- the embodiment of the present invention is as follows.
- a rice disease control method comprising performing at least one treatment selected from a soaking treatment, a powder coating treatment, a smearing treatment, and a spraying treatment on rice seeds before sowing using an agrochemical formulation.
- rice diseases can be effectively controlled with a small labor load without causing phytotoxicity of rice.
- it is effective for rice blast and can control rice blast caused by drug-resistant bacteria, which has recently become a problem.
- the disease control effect lasts from the seedling season to the harvest season, no additional disease control work is required in the late growth stage of rice.
- rice diseases can be controlled with a smaller amount of chemicals than the conventional control method, which is more effective in terms of safety and economy. is there.
- 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide which is a compound represented by the following chemical formula 1, is used as an active ingredient.
- the method for producing this compound (hereinafter also referred to as Compound 1) is disclosed in Patent Document 2 described above, and there is no particular obstacle in obtaining it.
- an agrochemical composition agrochemical formulation
- the immersion treatment include a method of using a chemical solution in which a chemical is added for one batch of water used in the pretreatment process.
- the powder coating treatment is exemplified by a method in which a powdered medicine is applied to the rice seeds before the pretreatment process. Or the method of spraying is illustrated.
- compound 1 itself may be used, and if desired, compound 1, an additive component generally used as an agrochemical adjuvant is blended, and emulsion, powder, wettable powder, granular hydration Compositions formulated in the form of agents, flowables and the like can also be used. In the latter case, a suitable dosage form may be selected and used in light of the actual treatment mode. For example, if seed dressing is performed, a powdery composition such as a powder is preferable because it is necessary to attach the compound powder to the seed.
- the drug in seed soaking, seed smearing, and seed spraying, the drug is diluted in water and used as a prescribed concentration, so that the liquid formulation composition such as emulsion or flowable, or the drug is well dispersed and suspended in water
- Solid pharmaceutical compositions such as designed wettable powders or granular wettable powders are easy to use.
- the combination with the form and the processing method is not limited to the above.
- agrochemical adjuvant examples include a carrier such as a solid carrier or a liquid carrier, a surfactant, a binder, a tackifier, a thickener, a colorant, a spreading agent, a spreading agent, an antifreeze agent, and an anti-caking agent.
- a carrier such as a solid carrier or a liquid carrier
- a surfactant such as a surfactant, a binder, a tackifier, a thickener, a colorant, a spreading agent, a spreading agent, an antifreeze agent, and an anti-caking agent.
- a carrier such as a solid carrier or a liquid carrier
- a surfactant such as a solid carrier or a liquid carrier
- a binder such as a surfactant, a binder, a tackifier, a thickener, a colorant, a spreading agent, a spreading agent, an antifreeze agent, and an anti-caking agent.
- solid carriers include natural minerals such as quartz, clay, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, attapulgite, zeolite, and diatomaceous earth; inorganic such as calcium carbonate, ammonium sulfate, sodium sulfate, and potassium chloride Salts: Organic solid carriers such as synthetic silicic acid, synthetic silicates, starches, celluloses and plant powders; Plastic carriers such as polyethylene, polypropylene and polyvinylidene chloride.
- liquid carrier examples include monohydric alcohols such as methanol, ethanol, propanol, isopropanol, and butanol; polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol, and glycerin; propylene Polyhydric alcohol compounds such as glycol ethers; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, and cyclohexanone; ethers such as ethyl ether, dioxane, ethylene glycol monoethyl ether, dipropyl ether, and tetrahydrofuran; Aliphatic hydrocarbons such as normal paraffin, naphthene, isoparaffin, kerosene, mineral oil; benzene, tolue Aromatic hydrocarbons such as xylene, solvent
- surfactant examples include sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene resin acid ester, polyoxyethylene fatty acid diester, polyoxyethylene alkyl ether, polyoxyethylene alkyl ether, Oxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, polyoxyethylene alkyl phenyl ether formalin condensate, polyoxyethylene polyoxypropylene block polymer, alkyl polyoxyethylene polypropylene block polymer ether, polyoxyethylene fatty acid amide, polyoxyethylene Fatty acid bisphenyl ether, polyalkylene benzyl phenyl ether, polyoxyal Nonionic surfactants such as lenstyryl phenyl ether, acetylene diol, polyoxyalkylene-added acetylene diol, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil
- binders and tackifiers include carboxymethyl cellulose and salts thereof, dextrin, water-soluble starch, xanthan gum, guar gum, sucrose, polyvinyl pyrrolidone, gum arabic, polyvinyl alcohol, polyvinyl acetate, sodium polyacrylate, and an average molecular weight of 6000 to Examples include 20,000 polyethylene glycol, polyethylene oxide having an average molecular weight of 100,000 to 5,000,000, cephalin, and lecithin.
- thickener examples include water-soluble polymers such as xanthan gum, guar gum, welan gum, carboxymethyl cellulose, polyvinylpyrrolidone, carboxyvinyl polymer, acrylic polymer, starch compound and water-soluble polysaccharide; high-purity bentonite, fumed Examples thereof include inorganic fine powders such as silica.
- the colorant examples include inorganic pigments such as iron oxide, titanium oxide, and Prussian blue; organic dyes such as alizarin dyes, azo dyes, and metal phthalocyanine dyes.
- the spreading agent examples include silicone surfactant, cellulose powder, dextrin, modified starch, polyaminocarboxylic acid chelate compound, crosslinked polyvinylpyrrolidone, a copolymer of maleic acid and styrene, (meth) acrylic acid copolymer
- examples thereof include half-esters of polymers, polycarboxylic alcohols and dicarboxylic anhydrides, and water-soluble salts of polystyrene sulfonic acid.
- the spreading agent examples include paraffin, terpene, polyamide resin, polyacrylate, polyoxyethylene, wax, polyvinyl alkyl ether, alkylphenol formalin condensate, and synthetic resin emulsion.
- antifreezing agent examples include polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, and glycerin; urea and the like.
- anti-caking agent examples include polysaccharides such as starch, alginic acid, mannose, and galactose, polyvinyl pyrrolidone, fumed silica, ester gum, and petroleum resin.
- disintegrants include sodium tripolyphosphate, sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, methacrylate copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene / isobutylene / anhydrous
- disintegrants include sodium tripolyphosphate, sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, methacrylate copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene / isobutylene / anhydrous
- examples thereof include maleic acid copolymers and starch / polyacrylonitrile graft copolymers.
- decomposition inhibitor examples include desiccants such as zeolite, quicklime, and magnesium oxide; UV absorbers such as salicylic acid and benzophenone; sulfuric acid, acetic acid, sodium acetate, phosphoric acid, ammonium hydrogen phosphate, potassium dihydrogen phosphate And pH adjusting agents such as sodium phosphate, boric acid, sodium borate, sodium hydrogen carbonate, sodium carbonate, sodium hydroxide or a mixture thereof.
- preservative examples include potassium sorbate, 1,2-benzthiazolin-3-one, and the like.
- plant pieces include sawdust, coconut husk, corn cob, and tobacco stem. *
- medical agent can be manufactured by a conventional method, for example, the following manufacturing methods are mentioned.
- the content ratio of Compound 1 in the drug is usually selected in the range of 30 to 95%, preferably 50 to 90% on the mass basis.
- the content ratio of each agricultural chemical adjuvant varies depending on the content ratio of Compound 1 and the selected dosage form, but is usually selected in the range of 5 to 70%, preferably 10 to 50%.
- compound 1 is concentrated (for example, 50% or more, for reasons of limited surface area of rice seeds to which the drug adheres).
- the preparation is preferably 80% or more.
- the application amount of Compound 1 in the present invention is about 0.1 to 1.3 g per 150 g of dry weight of rice seeds, preferably 0.1 to 1 g, more preferably 0.3 to 0.7 g. It is a range.
- powder coating treatment or smearing treatment it is contrary to technical common knowledge in the art, and even if 0.3 to 0.7 g per 150 g dry weight of rice seeds, which is about half the normal application rate after sowing, sufficient effect is obtained. It is a feature that is played.
- another rice pest control agent may be seed-treated at the same time as or before or after its implementation.
- Other rice pest control agents mentioned here include, for example, fungicides such as oxolinic acid, prochloraz, ipconazole, cupric hydroxide, triflumizole, thiuram, pefazoate, benomyl, basic copper chloride, fludioxonil; Useful microorganisms exhibiting rice disease control activity such as Atrobilide, Talalomyces flavus; insecticides such as MEP, cartap, imidacloprid, etc., but are not limited to them, and any rice pest control agent applicable to seed treatment Any combination may be used.
- microorganisms are fungi themselves, and often cause inactivation when mixed with another fungicide, but Compound 1 has an effect on microorganisms such as Trichoderma atrobide. Therefore, it can be used as a suitable combination.
- each active ingredient or its pharmaceutical composition is separately prepared and mixed in the form of an on-site preparation, It may be used in the form of a tank mix, or may be applied in the form of a single pharmaceutical composition, ie, a ready mix, previously packaged as a mixture containing both active ingredients.
- Rice seeds that have been subjected to seed treatment may be sown in accordance with a conventional method, that is, seeded in a seedling box laid with soil and germinated under appropriate management.
- the amount of rice seed sown per 30 cm ⁇ 60 cm seedling box is usually about 100 to 200 g, preferably about 150 g.
- rice seeds that have undergone seed treatment may be sown in rice fields as they are.
- the amount of rice seeds sown per 10 ares of paddy field is usually 2000 to 4000 g, preferably about 3000 g.
- the disease control effect by the above treatment is sustained from the seedling stage to the harvesting period, after sowing, the late growth stage of rice (for example, from 15 days before heading to 25 days after heading) It is also a feature that it is not necessary to perform disease control processing again during In addition, it is also possible not to perform a pest control process in all the growth periods after sowing, and conversely, it does not restrict performing a pest control process again after sowing.
- the rice disease control method of the present invention has the convenience of work labor, which is an advantage of the treatment mode of seed treatment, and is safe and economical to rice, which is a problem of the treatment mode. In addition, it is extremely useful and practical, overcoming long-term residual effects and the like.
- (Formulation example 2) 50 parts of Compound 1, 5 parts of polyoxyethylene alkylphenyl ether, 6 parts of lignin sulfonate, 0.24 part of xanthan gum, 0.02 part of dimethylpolysiloxane and 38.74 parts of water are mixed, and the glass beads are ground. A flowable containing 50% of Compound 1 was obtained by pulverization using a wet pulverizer.
- Control 1 Commercially available granular wettable powder: A trade name “Side-rowed oryzate granular wettable powder (product of Meiji Seika Pharma Co., Ltd.)” was used. This product contains 48% probenazole as a rice disease control agent.
- Control 2 2 parts of Compound 1, 0.35 part of alkylbenzene sulfonate, 3 parts of water-soluble starch and 91.65 parts of clay were kneaded with an appropriate amount of water, and then the opening diameter was 0.8 mm using an extrusion granulator. It was extruded and granulated from the screen. A granule containing 2% of Compound 1 was obtained by drying at a product temperature of 70 ° C. using a fluidized bed dryer and sieving.
- Control 3 Commercially available granule: The product name “First Orize Prince Granule 6 (Meiji Seika Pharma Co., Ltd. product)” was used. This product contains 20% probenazole as a rice disease control agent and 0.6% insecticide fipronil.
- Example 1 10 g of dried rice seed and 67 ⁇ L of water were mixed to wet the rice seed. To this, 0.05 g of the wettable powder of Formulation Example 1 was added (0.043 g as Compound 1, equivalent to 0.64 g per 150 g of rice seeds), and the active ingredients were dressed on rice seeds by mixing well. The rice seeds were soaked in 40 mL of water, soaked at 15 ° C. for 1 day, and then soaked for 4 days after changing the water. Next, the water was changed to warm water, and a germination treatment was performed at 30 ° C. for 1 day. 3.7 g of this rice seed was sown in a 7.5 cm diameter plastic cup filled with soil.
- Example 2 The flowable of Formulation Example 2 was diluted 7.5 times with water. To 10 g of dried rice seeds, 0.3 mL of the diluted solution was added (0.020 g as compound 1, equivalent to 0.30 g per 150 g of rice seeds), and the active ingredients were smeared on the rice seeds by mixing well. The rice seeds were soaked in 40 mL of water, soaked at 15 ° C. for 1 day, and then soaked for 4 days after changing the water. Next, the water was changed to warm water, and sprouting treatment was performed at 30 ° C. for 1 day. 3.7 g of this rice seed was sown in a 7.5 cm diameter plastic cup filled with soil.
- Example 3 The wettable powder of Formulation Example 1 was diluted 200 times with water. Immerse 10 g of dried rice seeds in 20 mL of the above diluent (0.085 g as compound 1; equivalent to 1.3 g per 150 g of rice seeds), soak for 1 day at 15 ° C., then discard the drug solution and add 40 mL of water. And soaking at 15 ° C. for 4 days. Next, the water was changed to warm water, and sprouting treatment was performed at 30 ° C. for 1 day. 3.7 g of this rice seed was sown in a 7.5 cm diameter plastic cup filled with soil.
- Example 4 10 g of dried rice seeds were soaked in 40 mL of water and soaked at 15 ° C. for 1 day, then the water was changed and soaked for another 4 days. Next, the water was discarded, and 20 mL of a drug solution obtained by diluting the wettable powder of Formulation Example 1 200 times with warm water was added (0.085 g as Compound 1 and equivalent to 1.3 g per 150 g of rice seeds), and 30 days at 30 ° C. Germination treatment was performed. 3.7 g of this rice seed was sown in a 7.5 cm diameter plastic cup filled with soil.
- Example 5 150 g of dry rice seed and 1 mL of water were mixed to wet the rice seed. To this was added 0.75 g of the wettable powder of Formulation Example 1 (0.64 g as Compound 1) and mixed well to dress the active ingredient on rice seeds. The rice seeds were soaked in 1 L of water, soaked at 15 ° C. for 1 day, and then soaked for 4 days after changing the water. Next, the water was changed to warm water, and a germination treatment was performed at 30 ° C. for 1 day. The total amount of this rice seed was sown in a 30 cm ⁇ 60 cm seedling box filled with soil.
- Example 6 The flowable of Formulation Example 2 was diluted 7.5 times with water. To 150 g of dried rice seeds, 4.5 mL of the above diluent was added (0.30 g as Compound 1), and the active ingredients were smeared on the rice seeds by mixing well. The rice seeds were soaked in 1 L of water, soaked at 15 ° C. for 1 day, and then soaked for 4 days after changing the water. Next, the water was changed to warm water, and a germination treatment was performed at 30 ° C. for 1 day. The total amount of this rice seed was sown in a 30 cm ⁇ 60 cm seedling box filled with soil.
- Example 1 Comparative Example 1
- a powdered powder of control powder 1 was used (0.024 g as probenazole, corresponding to 0.36 g per 150 g of rice seeds). For other points, the same operation as in Example 1 was performed.
- Example 2 (Comparative Example 2) Instead of the flowable of Formulation Example 2, a powder obtained by grinding granular wettable powder of Control Agent 1 with a mortar (corresponding to 0.019 g as probenazole, corresponding to 0.29 g per 150 g of rice seeds) was used. The other points followed the operation of Example 2.
- Example 3 (Comparative Example 3) Instead of the wettable powder of Formulation Example 1, granular wettable powder of Control 1 was used (0.048 g as probenazole, corresponding to 0.72 g per 150 g of rice seeds). For other points, the same operation as in Example 3 was performed.
- Example 4 (Comparative Example 4) Instead of the wettable powder of Formulation Example 1, granular wettable powder of Control 1 was used (0.048 g as probenazole, corresponding to 0.72 g per 150 g of rice seeds). For other points, the same operation as in Example 4 was performed.
- Comparative Example 7 10 g of dried rice seeds were soaked in 40 mL of water and soaked at 15 ° C. for 1 day, then the water was changed and soaked for another 4 days. Next, the water was changed to warm water, and sprouting treatment was performed at 30 ° C. for 1 day. 3.7 g of this rice seed was sown in a 7.5 cm diameter plastic cup filled with soil.
- the crop classification of the comparative example 7 may be referred to as “untreated section”.
- Comparative Example 9 150 g of dried rice seeds were soaked in 1 L of water and soaked at 15 ° C. for 1 day, then the water was changed and soaked for another 4 days. Next, the water was changed to warm water, and sprouting treatment was performed at 30 ° C. for 1 day. The total amount of this rice seed was sown in a 30 cm ⁇ 60 cm seedling box filled with soil.
- the crop classification of the comparative example 9 may be referred to as “untreated section”.
- Test Example 1 The plastic cups of Examples 1 to 4 and Comparative Examples 1 to 7 were covered with soil, placed in a warm seedling incubator set at 30 ° C. for 3 days to germinate, and the emergence status at that time was confirmed. The result is shown in FIG. The cup was then moved to the greenhouse and managed at 20 ° C. After 14 days of sowing, an objective survey was conducted on the growth status of the plant height, and the degree of growth inhibition was evaluated by an index of 11 levels from 0 (equivalent to the untreated area) to 10 (dead). The results are shown in Table 1.
- Test Example 2 The seedling boxes of Examples 5 to 6 and Comparative Examples 8 to 9 were covered with soil, and placed in a warm seedling device set at 30 ° C. for 3 days to germinate. Thereafter, the nursery box was moved into the greenhouse, and the seedlings were grown for 7 days and 11 days in the open field, and the rice grown to the 3-4 leaf stage was transplanted to 0.5 R watered paddy field. A survey was conducted 58 days after transplantation, and the degree of leaf blast disease per plant was evaluated as the lesion area according to the criteria shown in Table 2 below for 40 strains in each crop category, and the lesion area ratio was determined therefrom. The control value was calculated. The results are shown in Table 3.
- each Example exhibited a control effect equal to or higher than leaf blast disease with a smaller amount of use than Comparative Example 8 (seeding box application) treated with Compound 1 at the time of sowing.
- an object of the present invention is to provide a rice disease control method that is highly safe to rice, simple and efficient, has a low labor load, and can exert a sufficient effect.
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Abstract
Description
(1)下記化1にて示される化合物である3-(3,4-ジクロロイソチアゾール-5-イルメトキシ)-1,2-ベンゾチアゾール-1,1-ジオキシドを有効成分とする農薬組成物(農薬製剤)を用いて、播種前のイネ種子に浸漬処理、粉衣処理、塗沫処理、噴付処理から選ばれる少なくともひとつの処理を行うことを特徴とするイネ病害防除方法。
(2)播種前のイネ種子に粉衣処理又は塗沫処理を行うことを特徴とする(1)に記載の方法。
(3)3-(3,4-ジクロロイソチアゾール-5-イルメトキシ)-1,2-ベンゾチアゾール-1,1-ジオキシドを、イネ種子150g当たり0.3~0.7gの割合で用いて処理することを特徴とする(2)に記載の方法。
(4)イネいもち病の防除である(1)~(3)のいずれか1つに記載の方法。
(5)イネの生育後期(例えば、出穂前15日から出穂後25日までの間)において、病害防除処理を行わないことを特徴とする(1)~(4)のいずれか1つに記載の方法。
(1)化合物1、界面活性剤及びその他所望により添加される農薬補助剤を有機溶剤等の液体担体に溶解する乳剤の製造方法。
(2)化合物1、固体担体及びその他所望により添加される農薬補助剤を適当な粉砕機で混合粉砕する粉剤の製造方法。
(3)化合物1、界面活性剤、固体担体及びその他所望により添加される農薬補助剤を適当な粉砕機で混合粉砕する水和剤の製造方法。
(4)化合物1、界面活性剤及びその他所望により添加される農薬補助剤の混合物(予め、その一部又は全部を粉砕しておいてもよい)に適当量の水を加えて混練した後、所定の孔径の穴を開けたスクリーンから押し出し造粒し、乾燥する粒状水和剤の製造方法。
(5)化合物1、界面活性剤及びその他所望により添加される農薬補助剤を水等の液体担体に分散し、適当な粉砕機で混合粉砕するフロアブルの製造方法。
尚、以下の実施例及び比較例において「部」は「質量部」を意味する。また、イネ種子の品種については、実施例1~4及び比較例1~7では「ひとめぼれ」を、実施例5~6及び比較例8~9では「コシヒカリ」をそれぞれ供試した。
化合物1を85部、アルキルベンゼンスルホン酸塩1部、リグニンスルホン酸塩5部、ポリビニルアルコール4部及び珪藻土5部を衝撃式粉砕機を用いて混合粉砕することにより、化合物1を85%含有する水和剤を得た。
化合物1を50部、ポリオキシエチレンアルキルフェニルエーテル5部、リグニンスルホン酸塩6部、キサンタンガム0.24部、ジメチルポリシロキサン0.02部及び水38.74部を混合し、ガラスビーズを粉砕媒体とする湿式粉砕機を用いて粉砕することにより、化合物1を50%含有するフロアブルを得た。
市販の粒状水和剤:商品名「側条オリゼメート顆粒水和剤(Meiji Seika ファルマ株式会社製品)」を供試した。本品はイネ病害防除剤としてプロベナゾールを48%含有する。
化合物1を2部、アルキルベンゼンスルホン酸塩0.35部、水溶性デンプン3部及びクレー91.65部に適量の水を加えて混練した後、押し出し造粒機を用いて目開き径0.8mmのスクリーンより押し出し造粒した。流動層乾燥機を用いて品温70℃で乾燥し、篩い分けることにより、化合物1を2%含有する粒剤を得た。
市販の粒剤:商品名「ファーストオリゼプリンス粒剤6(Meiji Seika ファルマ株式会社製品)」を供試した。本品はイネ病害防除剤としてプロベナゾール20%を含有する他、殺虫剤フィプロニルを0.6%含む。
10gの乾燥イネ種子と水67μLを混和し、イネ種子を湿らせた。ここに製剤例1の水和剤0.05gを加え(化合物1として0.043g、イネ種子150g当たり0.64gに相当)、よく混和することでイネ種子に有効成分を粉衣した。このイネ種子を40mLの水に浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子3.7gを、土壌を充填した直径7.5cmのプラスチックカップに播種した。
製剤例2のフロアブルを水で7.5倍に希釈した。10gの乾燥イネ種子に前記の希釈液0.3mLを加え(化合物1として0.020g、イネ種子150g当たり0.30gに相当)、よく混和することでイネ種子に有効成分を塗沫した。このイネ種子を40mLの水に浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子3.7gを、土壌を充填した直径7.5cmのプラスチックカップに播種した。
製剤例1の水和剤を水で200倍に希釈した。10gの乾燥イネ種子を前記の希釈液20mLに浸し(化合物1として0.085g、イネ種子150g当たり1.3gに相当)、15℃で1日間浸種した後、薬液を捨て、40mLの水を加えて、15℃で4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子3.7gを、土壌を充填した直径7.5cmのプラスチックカップに播種した。
10gの乾燥イネ種子を水40mLに浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を捨て、製剤例1の水和剤を温水で200倍に希釈した薬液20mLを加えて(化合物1として0.085g、イネ種子150g当たり1.3gに相当)、30℃で1日間催芽処理を行った。このイネ種子3.7gを、土壌を充填した直径7.5cmのプラスチックカップに播種した。
150gの乾燥イネ種子と水1mLを混和し、イネ種子を湿らせた。ここに製剤例1の水和剤0.75gを加え(化合物1として0.64g)、よく混和することでイネ種子に有効成分を粉衣した。このイネ種子を1Lの水に浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子の全量を、土壌を充填した30cm×60cmの育苗箱に播種した。
製剤例2のフロアブルを水で7.5倍に希釈した。150gの乾燥イネ種子に前記の希釈液4.5mLを加え(化合物1として0.30g)、よく混和することでイネ種子に有効成分を塗沫した。このイネ種子を1Lの水に浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子の全量を、土壌を充填した30cm×60cmの育苗箱に播種した。
製剤例1の水和剤に代えて、対照剤1の粒状水和剤を磨り潰したものを用いた(プロベナゾールとして0.024g、イネ種子150g当たり0.36gに相当)。その余の点は、実施例1と同様の操作を行った。
製剤例2のフロアブルに代えて、対照剤1の粒状水和剤を乳鉢で磨り潰したものを用いた(プロベナゾールとして0.019g、イネ種子150g当たり0.29gに相当)。その余の点は、実施例2の操作を踏襲した。
製剤例1の水和剤に代えて、対照剤1の粒状水和剤を使用した(プロベナゾールとして0.048g、イネ種子150g当たり0.72gに相当)。その余の点は、実施例3と同様の操作を行った。
製剤例1の水和剤に代えて、対照剤1の粒状水和剤を使用した(プロベナゾールとして0.048g、イネ種子150g当たり0.72gに相当)。その余の点は、実施例4と同様の操作を行った。
10gの乾燥イネ種子を水40mLに浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子3.7gを、土壌を充填した直径7.5cmのプラスチックカップに播種し、更に対照剤2の粒剤1.2gを処理した(化合物1として0.025g、イネ種子150g当たり1.0gに相当)。
10gの乾燥イネ種子を水40mLに浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子3.7gを、土壌を充填した直径7.5cmのプラスチックカップに播種し、更に対照剤3の粒剤1.2gを処理した(プロベナゾールとして0.25g、イネ種子150g当たり10gに相当)。
10gの乾燥イネ種子を水40mLに浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子3.7gを、土壌を充填した直径7.5cmのプラスチックカップに播種した。
なお、この比較例7の作物区分を「無処理区」という場合もある。
150gの乾燥イネ種子を水1Lに浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子の全量を、土壌を充填した30cm×60cmの育苗箱に播種し、更に対照剤2の粒剤50gを処理した(化合物1として1.0gに相当)。
150gの乾燥イネ種子を水1Lに浸し、15℃で1日間浸種した後、水を換えて更に4日間浸種した。次いで、水を温水に換え、30℃で1日間催芽処理を行った。このイネ種子の全量を、土壌を充填した30cm×60cmの育苗箱に播種した。
なお、この比較例9の作物区分を「無処理区」という場合もある。
実施例1~4及び比較例1~7のプラスチックカップに覆土し、30℃に設定した加温育苗器に3日間入れて出芽させ、当該時点での出芽状況を確認した。その結果を図1に示す。次いで、このカップを温室に移動し、20℃で管理した。播種14日後に、草丈の生育状況について達観調査を行い、生育抑制の度合いを、0(無処理区同等)~10(枯死)までの11段階の指数で評価した。その結果を表1に示す。
実施例5~6及び比較例8~9の育苗箱に覆土し、30℃に設定した加温育苗器に3日間入れて出芽させた。その後、育苗箱をビニールハウス内に移して7日間、更に露地で11日間育苗し、3~4葉期まで生育したイネを、湛水した水田0.5アールに移植した。移植58日後に調査を行い、各作物区分の40株について、株当たりの葉いもち病の発病程度を、下記に示す表2の基準に従って病斑面積として評価し、そこから病斑面積歩合を求め、防除価を算出した。結果を表3に示す。
Claims (5)
- 播種前のイネ種子に粉衣処理又は塗沫処理を行うことを特徴とする請求項1に記載の方法。
- 3-(3,4-ジクロロイソチアゾール-5-イルメトキシ)-1,2-ベンゾチアゾール-1,1-ジオキシドを、イネ種子150g当たり0.3~0.7gの割合で用いて処理することを特徴とする請求項2に記載の方法。
- イネいもち病の防除である請求項1~3のいずれか1項に記載の方法。
- イネの生育後期において、病害防除処理を行わないことを特徴とする請求項1~4のいずれか1項に記載の方法。
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CN106900721A (zh) | 2017-06-30 |
AR086614A1 (es) | 2014-01-08 |
TW201311146A (zh) | 2013-03-16 |
JPWO2012165511A1 (ja) | 2015-02-23 |
JP6006203B2 (ja) | 2016-10-12 |
TWI583308B (zh) | 2017-05-21 |
CN103763919A (zh) | 2014-04-30 |
KR101902041B1 (ko) | 2018-09-27 |
KR20140037860A (ko) | 2014-03-27 |
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