WO2012128368A1 - Module de pile à combustible - Google Patents

Module de pile à combustible Download PDF

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Publication number
WO2012128368A1
WO2012128368A1 PCT/JP2012/057627 JP2012057627W WO2012128368A1 WO 2012128368 A1 WO2012128368 A1 WO 2012128368A1 JP 2012057627 W JP2012057627 W JP 2012057627W WO 2012128368 A1 WO2012128368 A1 WO 2012128368A1
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WO
WIPO (PCT)
Prior art keywords
fuel cell
temperature
cell module
air
combustion catalyst
Prior art date
Application number
PCT/JP2012/057627
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English (en)
Japanese (ja)
Inventor
暁 山本
水野　康
Original Assignee
Ｊｘ日鉱日石エネルギー株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Ｊｘ日鉱日石エネルギー株式会社 filed Critical Ｊｘ日鉱日石エネルギー株式会社
Priority to JP2013506044A priority Critical patent/JP5916707B2/ja
Publication of WO2012128368A1 publication Critical patent/WO2012128368A1/fr

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • H01M8/2475—Enclosures, casings or containers of fuel cell stacks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04228—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during shut-down
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04225—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during start-up
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H01M8/04303—Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during shut-down
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0432—Temperature; Ambient temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a fuel cell module.
  • Such a fuel cell module includes at least a reformer that generates a reformed gas using a hydrogen-containing fuel, and a cell stack that generates power using the reformed gas. It is configured as.
  • the module main body of the combustion battery module as described above, after the reformed gas is converted into carbon dioxide or water vapor, the air supplied to the cell stack and the air not consumed in the cell stack are combusted There are traces of gases such as carbon monoxide, hydrogen and methane that have reacted but have not yet reacted. Therefore, in order to prevent these gases from flowing out of the module main body, a sealing material or the like is usually provided at the piping or wiring penetration portion in the module main body, and thereby the module main body has an airtight structure. . However, since the entire module body is exposed to a high temperature, it is necessary to use an expensive gasket made of expanded graphite or the like with excellent heat resistance as a sealing material, which may increase the cost of the fuel cell module. .
  • an object of the present invention is to provide a fuel cell module that can realize cost reduction while reliably preventing the outflow of gas to the outside.
  • a fuel cell module includes a reformer that generates a reformed gas using a hydrogen-containing fuel, and a cell stack that generates power using the reformed gas.
  • a module main body including at least a module main body, a heat insulating material provided so as to surround the module main body, and a housing that has an airtight structure and accommodates the module main body and the heat insulating material.
  • the module main body is housed in a casing having an airtight structure. For this reason, even if gas leaks from the module body, the casing can reliably prevent the gas from flowing out. As a result, the module body does not need to have an airtight structure, and an expensive sealing material with excellent heat resistance provided on the module body becomes unnecessary. And since the temperature of a housing
  • FIG. 1 is a schematic block diagram showing a fuel cell module according to a first embodiment. It is a schematic block diagram which shows the fuel cell module which concerns on 2nd Embodiment. It is an enlarged view which shows the exhaust part in the fuel cell module of FIG. 3 is a flowchart showing an example of control in the fuel cell module of FIG. 2. It is an enlarged view which shows the modification of the exhaust part in the fuel cell module of FIG. It is a flowchart which shows an example of the control in a fuel cell module provided with the exhaust part of FIG. It is a schematic block diagram which shows the fuel cell module which concerns on 3rd Embodiment. It is a schematic block diagram which shows the fuel cell module which concerns on 4th Embodiment. It is a schematic block diagram which shows the fuel cell module which concerns on 5th Embodiment.
  • FIG. 1 is a schematic block diagram showing the fuel cell module according to the first embodiment.
  • the fuel cell module 1 according to the present embodiment includes a module body 10 that includes at least a reformer 2, a cell stack 3, a combustion unit 4, and a water vaporizer 5.
  • This module main body 10 is modularized by accommodating the reformer 2, the cell stack 3, the combustion section 4, and the water vaporizer 5 in a metal box 10a having a rectangular parallelepiped shape.
  • the module main body 10 generates power in the cell stack 3 using a hydrogen-containing fuel and an oxidant.
  • the type of the cell stack 3 in the module body 10 is not particularly limited.
  • the polymer electrolyte fuel cell (PEFC), the solid oxide fuel cell (SOFC), the phosphoric acid type Fuel cell (PAFC: Phosphoric Acid) Fuel Cell), Molten Carbonate Fuel Cell (MCFC), and other types can be employed.
  • hydrocarbon fuel a compound containing carbon and hydrogen in the molecule (may contain other elements such as oxygen) or a mixture thereof is used.
  • hydrocarbon fuels include hydrocarbons, alcohols, ethers, and biofuels. These hydrocarbon fuels are derived from conventional fossil fuels such as petroleum and coal, and synthetic systems such as synthesis gas. Those derived from fuel and those derived from biomass can be used as appropriate. Specific examples of hydrocarbons include methane, ethane, propane, butane, natural gas, LPG (liquefied petroleum gas), city gas, town gas, gasoline, naphtha, kerosene, and light oil.
  • methanol and ethanol are mentioned as alcohols.
  • ethers include dimethyl ether.
  • biofuels include biogas, bioethanol, biodiesel, and biojet.
  • oxygen-enriched air is used as the oxidizing agent.
  • the reformer 2 generates a reformed gas as a hydrogen rich gas (hydrogen containing gas) from the supplied hydrogen containing fuel.
  • the reformer 2 reforms the hydrogen-containing fuel and generates a reformed gas by a reforming reaction using a reforming catalyst.
  • the reforming method in the reformer 2 is not particularly limited, and for example, steam reforming, partial oxidation reforming, autothermal reforming, and other reforming methods can be employed.
  • the reformer 2 may have a configuration for adjusting the properties in addition to the reformer reformed by the reforming catalyst depending on the properties of the hydrogen-rich gas required for the cell stack 3.
  • the reformer 2 is configured to remove carbon monoxide in the hydrogen-rich gas. (For example, a shift reaction part and a selective oxidation reaction part). The reformer 2 supplies the reformed gas to the cell stack 3.
  • PEFC polymer electrolyte fuel cell
  • PAFC phosphoric acid fuel cell
  • the cell stack 3 generates power using the reformed gas and oxidant from the reformer 2.
  • the type of the cell stack 3 is a solid oxide fuel cell
  • the cell stack 3 supplies the reformed gas and the oxidant that have not been used for power generation as off-gas to the combustion unit 4.
  • the combustion unit 4 burns off gas supplied from the cell stack 3 and heats the reformer 2 and the water vaporizer 5.
  • the combustion unit 4 is located at the upper part of the cell stack 3.
  • the exhaust gas generated by the combustion of the combustion unit 4 is exhausted out of the housing 7 through the exhaust gas pipe 4a.
  • the exhaust gas pipe 4a is provided with a combustion catalyst 4b, whereby the exhaust gas exhausted is combusted by the combustion catalyst 4b.
  • the water vaporizer 5 heats and vaporizes the supplied water to generate water vapor supplied to the reformer 2.
  • the water vaporizer 5 supplies the generated steam to the reformer 2. Heating of the water in the water vaporizer 5 can use heat generated in the fuel cell module 1 such as recovering heat of the reformer 2, heat of the combustion unit 4, or exhaust gas.
  • the water vaporizer 5 is disposed on the upper side of the combustion unit 4.
  • a through pipe 11 is connected to such a module body 10, and a hydrogen-containing fuel is supplied to the reformer 2 through the through pipe 11.
  • the through pipe 12 is connected, and water is supplied to the water vaporizer 5 through the through pipe 12.
  • a through wiring 13 is connected to the module main body 10, and the module main body 10 is electrically connected to the outside through the through wiring 13.
  • the module main body 10 does not have an airtight structure.
  • the airtight structure here refers to the inflow of gas from a dedicated gas inflow path, and the discharge of gas is performed only from the dedicated gas exhaust path, from the gap of the parts connection part, the gap of the welding location, etc. It means a structure that does not allow the inflow and outflow of gas.
  • the fuel cell module 1 of the present embodiment includes a heat insulating material 6, a casing 7, and a control device (control unit) 8.
  • the heat insulating material 6 is provided so as to surround the module body 10 and thermally seals the module body 10.
  • the material and specifications of the heat insulating material 6 are not limited, and various types can be used.
  • the housing 7 is a metal box having a rectangular parallelepiped shape, and houses (encloses) the module main body 10 surrounded by the heat insulating material 6.
  • a seal material 9 is provided at least at the penetrating portions of the through pipes 11 and 12, the through wiring 13, and the exhaust gas pipe 4a, whereby the inside of the casing 7 is sealed and hermetically sealed.
  • the housing 7 has an airtight structure with respect to the outside.
  • the sealing material 9 a normal temperature specification sealing material used at normal temperature (low temperature) can be used, and here, for example, a material made of fluorine rubber or the like is used.
  • the casing 7 is provided with an exhaust part 21 and an intake part 22.
  • the exhaust unit 21 exhausts leaked gas such as carbon monoxide, hydrogen or methane (hereinafter simply referred to as “leakage gas”) leaking from the module body 10 to the outside.
  • the exhaust unit 21 includes a gas processing unit 23, a temperature detection unit 24, and a heater (heating unit) 25.
  • the gas processing unit 23 burns and removes the leaked gas using the combustion catalyst 23a.
  • the temperature detection unit 24 includes a pair of thermocouples provided in the exhaust unit 21 on the upstream side and the downstream side of the combustion catalyst 23a. The temperature detector 24 detects the temperature of the combustion catalyst 23a based on the difference between the temperatures detected by the pair of thermocouples, and grasps the state of the combustion catalyst 23a.
  • the temperature detection unit 24 is connected to the control device 8 and outputs the detected temperature of the combustion catalyst 23 a to the control device 8.
  • the heater 25 heats the combustion catalyst 23a.
  • the heater 25 is connected to the control device 8, and its operation is controlled by the control device 8.
  • the intake part 22 allows air to flow into the housing 7 from the outside.
  • a blower (air supply part) 26 is connected to the air intake part 22 so that air flows from the air intake part 22 toward the exhaust part 21 between the module body 10 and the housing 7.
  • the blower 26 is connected to the control device 8, and its operation is controlled by the control device 8.
  • the exhaust part 21 and the intake part 22 are provided so as to be most separated from each other in the casing 7.
  • the exhaust part 21 is located on one side in the left-right direction (upper left in the figure) of the upper part of the casing 7
  • the intake part 22 is the other side in the left-right direction in the bottom part of the casing 7 (lower right in the figure). Is located.
  • the control device 8 is configured by an ECU (Electronic Control Unit) including, for example, a CPU, a ROM, a RAM, and the like.
  • the control device 8 is connected to the temperature detection unit 24, the heater 25, and the blower 26.
  • the control device 8 controls the operation of the heater 25 based on the temperature of the combustion catalyst 23a detected by the temperature detection unit 24 (details will be described later). Further, the control device 8 controls the operation of the blower and monitors the soundness of the blower 26.
  • the module main body 10 is accommodated in the casing 7 having an airtight structure. Therefore, even if leaked gas leaks from the module main body 10, the casing 7 can reliably prevent the leaked gas from flowing out.
  • the module body 10 it is not necessary for the module body 10 to have an airtight structure, and an expensive sealing material or the like provided in the module body 10 is not necessary. Therefore, for example, as described above, it is sufficient to provide a gasket or the like having a high temperature resistance but a low airtightness in a through portion between the through pipes 11 and 12, the through wiring 13, and the exhaust gas pipe 4a. Further, it is not necessary to provide a module body 10 with an airtight structure by providing a stuffing box in the penetrating portion or by making the opening of the module body 10 into a flange structure. An inspection process for inspecting the above is also unnecessary.
  • the ambient temperature of the module body 10 is lowered by the heat insulating material 6, and when the cell stack 3 is a solid oxide fuel cell, the temperature of the module body 10 (for example, the outer surface temperature 700 ° C. to 800 ° C.
  • the temperature of the housing 7 is lower (for example, the outer surface temperature is 70 ° C. to 80 ° C.). Therefore, the airtight structure of the housing 7 can be easily ensured by the inexpensive room temperature specification sealing material 9 made of fluoro rubber or the like as described above. Therefore, according to the present embodiment, it is possible to realize cost reduction while reliably preventing outflow of leakage gas to the outside.
  • the exhaust part 21 is provided in the housing
  • This exhaust part 21 has the gas processing part 23 which processes leakage gas using the combustion catalyst 23a. . Therefore, the leaked gas from the module body 10 can be safely processed and exhausted outside the housing 7. Furthermore, it is possible to suppress the internal pressure of the housing 7 from being excessively increased due to the leaked gas and the heat from being trapped in the housing 7.
  • the operation of the heater 25 is controlled by the control device 8 so that the temperature of the combustion catalyst 23a detected by the temperature detection unit 24 becomes equal to or higher than a predetermined temperature (for example, 80 ° C. or higher) suitable for the leakage gas combustion process. Be controlled. Therefore, at the time of start-up, for example, the operation of the heater 25 is turned on by the control device 8 to heat the combustion catalyst 23a, and the temperature of the combustion catalyst 23a can be reliably set to a predetermined temperature or higher. Further, for example, during normal operation, when the temperature of the combustion catalyst 23a falls below a predetermined temperature, the operation of the heater 25 can be turned on by the control device 8 to assist the combustion catalyst 23a. Therefore, according to the present embodiment, the gas processing unit 23 can appropriately process the leaked gas.
  • a predetermined temperature for example, 80 ° C. or higher
  • the casing 7 is provided with the intake portion 22, and the intake portion 22 is provided with the blower 26. Therefore, the blower 26 is operated by the control device 8 and air is forced into the housing 7 from outside to form a forced air flow from the intake portion 22 toward the exhaust portion 21 in the housing 7. be able to. As a result, the leaked gas from the module body 10 can be safely processed without convection.
  • control device 8 may control the operation of the blower 26 based on the temperature of the combustion catalyst 23a.
  • the combustion catalyst 23a when the temperature on the downstream side of the combustion catalyst 23a detected by the temperature detection unit 24 is higher than the temperature on the upstream side, the combustion catalyst 23a can be determined to be normal, while the other temperatures In the state, it can be determined that an abnormality has occurred in the combustion catalyst 23a.
  • the heater 25 is stopped by the control device 8 while the blower 26 is continuously operated, and the blower 26 is stopped after a predetermined time after the combustion catalyst 23a is sufficiently cooled. Stopped.
  • FIG. 2 is a schematic block diagram showing a fuel cell module according to the second embodiment
  • FIG. 3 is an enlarged view showing an exhaust part of the fuel cell module of FIG.
  • the module main body 10 of the fuel cell module 200 in the present embodiment houses a power generation unit 201 including a cell stack and the like.
  • the power generation unit 201 has a PCS (Power A Conditioning System (power conditioner) 202 is connected.
  • PCS Power A Conditioning System
  • the module main body 10 air is supplied from the outside through a pipe 203.
  • the air supplied to the module main body 10 is circulated in the module main body 10 and at least a part thereof is used as cathode air (oxidant) of the power generation unit 201.
  • the pipe 203 is provided with a blower 205 for supplying air to the module body 10 side.
  • a heat exchanger 207 is provided on the downstream side of the combustion catalyst 4b.
  • a heat medium (not shown) circulates, and heat exchange is performed between the gas flowing through the exhaust gas pipe 4a and the heat medium.
  • the heat exchanger 207 When the exhaust gas is cooled by the heat exchanger 207, the moisture contained in the exhaust gas is condensed, and the condensed moisture is stored in the reforming water tank 209 as reforming water.
  • the reformed water stored in the reformed water tank 209 is supplied to the water vaporizer 5 through the through pipe 12.
  • the fuel cell module 200 includes an outer case 211 that accommodates each of the devices described above, and the outer case 211 constitutes an envelope of the fuel cell module 200.
  • a temperature sensor 213 is provided on the combustion catalyst 23 a of the exhaust part 21.
  • the temperature sensor 213 outputs the detected temperature T to the control device 8.
  • the arrangement position of the temperature sensor 213 is not limited.
  • the temperature sensor 213 may be a temperature sensor 213a provided on the downstream side of the combustion catalyst 23a in the exhaust pipe 215 of the exhaust part 21, A temperature sensor 213b provided on the upstream side of the combustion catalyst 23a may be used, or a temperature sensor 213c provided on the outer wall surface of the exhaust pipe 215 may be used.
  • the temperature sensor 213 may be a temperature sensor 213d provided on the outer wall surface of the housing 7 or a temperature sensor 213e provided on the inner wall surface, or may be an internal space of the housing 7 (for example, the outer surface of the heat insulating material 6).
  • the temperature sensor 213f may be provided.
  • the control device 8 stops the fuel cell module 200 when the temperature detected by the temperature sensor 213 exceeds the maximum temperature (predetermined temperature) Tmax (that is, when the temperature of the combustion catalyst 23a exceeds the maximum temperature). Further, the control device 8 increases or decreases the output of the blower 26 stepwise based on the temperature detected by the temperature sensor 213.
  • the control device 8 determines whether or not the temperature T is equal to or lower than the maximum temperature Tmax ( S1, S2).
  • the process proceeds to S1 as it is.
  • the output of the blower 26 is decreased stepwise by the controller 8. The process proceeds to S1 (S3, S4).
  • the fuel cell module 200 is stopped when the blower 26 output is maximum, while when the blower 26 output is not maximum, the control device 8 causes the output of the blower 26 to be stepwise. Increased and the process proceeds to S1 (S5, S6, S7).
  • the fuel cell module 200 is stopped when the temperature T exceeds the maximum temperature Tmax, so that the sealing material 9 is preferably damaged. Can be suppressed.
  • control device 8 of the present embodiment may control the blowers 26 and 205 according to the power generation amount of the power generation unit 201.
  • the relationship between the power generation amount and the outputs of the blowers 26 and 205 is tabulated. What is necessary is just to store in the control apparatus 8. For example, as control according to such power generation amount, when the power generation amount is large, it is assumed that the heat generation amount is large and the output of the blower 26 is increased, and when the power generation amount is large, the necessary cathode air amount is increased. For example, control for increasing the output of the blower 205 can be given.
  • FIG. 5 is an enlarged view showing a modification of the exhaust part in the fuel cell module of FIG.
  • the 1st temperature sensor 223 may be provided in the combustion catalyst 23a
  • the 2nd temperature sensor 224 may be provided in the upstream of the combustion catalyst 23a.
  • Each of the first and second temperature sensors 223 and 224 outputs the detected temperatures T1 and T2 to the control device 8, respectively.
  • the arrangement positions of the first and second temperature sensors 223 and 224 are not limited, and the first temperature sensor 223 is provided on the downstream side of the combustion catalyst 23 a in the exhaust pipe 215 of the exhaust unit 21 as illustrated.
  • the temperature sensor 223a may be used, or the temperature sensor 223b provided on the outer wall surface of the exhaust pipe 215 may be used.
  • the second temperature sensor 224 may be a temperature sensor 224 a provided on the outer wall surface of the housing 7 or a temperature sensor 224 b provided in the internal space of the housing 7.
  • the temperature T1 or the temperature T2 is detected by the control device 8. Is less than or equal to the maximum temperature Tmax (S11, S12).
  • the process proceeds to S11.
  • the temperature T1 or the temperature T2 is higher than the maximum temperature Tmax, the fuel cell module 200 is stopped (S13). Thereby, when the temperature inside or downstream of the combustion catalyst 23a exceeds the maximum temperature Tmax, it is determined that the leakage is excessive, and the system can be stopped.
  • the control device 8 subtracts the temperature T1 from the temperature T2. It is determined whether the subtracted value is equal to or lower than the maximum differential temperature Tdmax (S21, S22). When the subtraction value is equal to or lower than the maximum difference temperature Tdmax, the process proceeds to S21. On the other hand, when the subtraction value is higher than the maximum difference temperature Tdmax, the fuel cell module 200 is stopped (S23). Thereby, the system can be stopped when the temperature difference between the temperature inside or downstream of the combustion catalyst 23a and the upstream of the combustion catalyst 23a exceeds the maximum differential temperature Tdmax.
  • FIG. 7 is a schematic block diagram showing a fuel cell module according to the third embodiment.
  • the fuel cell module 300 of the present embodiment is different from the second embodiment in that the pipe 203 and the blower 205 (see FIG. 2) are not provided, and the downstream side of the exhaust pipe 215 is connected to the module body 10. It is a connected point. Even in this embodiment, the same effects as the above-described embodiment can be obtained.
  • FIG. 8 is a schematic block diagram showing a fuel cell module according to the fourth embodiment.
  • the fuel cell module 400 of the present embodiment is different from the third embodiment in that a pipe 401 for exhausting gas (including air) to the outside and an upstream side of the pipe 401 are provided. And a flow rate control valve 403.
  • the piping 401 is connected to the branching portion 405 on the upstream side of the module main body 10 in the exhaust piping 215.
  • the same effects as in the above embodiment can be obtained. Further, in the present embodiment, when the air supplied and circulated by the blower 26 is larger than the cathode air used in the module main body 10, the flow rate control valve 403 is controlled by the control device 8 to be opened, Thereby, surplus air is exhausted outside.
  • FIG. 9 is a schematic block diagram showing a fuel cell module according to the fifth embodiment.
  • the fuel cell module 500 of the present embodiment is different from the third embodiment in that it includes a pipe 501 for allowing air to flow in from the outside, and an auxiliary blower 503 provided on the pipe 501. It is a point.
  • the pipe 501 is connected to the branch portion 505 upstream of the module main body 10 in the exhaust pipe 215.
  • the same effects as in the above embodiment can be obtained. Further, in the present embodiment, when the air supplied and circulated by the blower 26 is insufficient with respect to the cathode air used in the module body 10, the auxiliary blower 503 is controlled by the control device 8, and also by the auxiliary blower 503. Air is supplied to the module main body 10 via the pipe 501, and thus the insufficient air is compensated.
  • the oxidizing agent is introduced from the upper part of the housing 7 and the exhaust gas is led out from the lower part, but the present invention is not limited thereto.
  • An oxidant introduction flow path and an exhaust gas discharge flow path may be optionally formed inside the heat insulating material 6.
  • air supplied from the blower 26 is introduced from the lower right side of the housing 7 and led out from the upper left corner.
  • the inlet and outlet of air in the housing 7 may be provided so that the air circulates around the heat insulating material 6 without significant air retention.
  • the introduction port may be provided in the center of the bottom wall portion of the housing 7 and the outlet port may be provided in the center of the upper wall portion of the housing 7.
  • the introduction port may be provided above the side wall surface of the housing, and the lead-out port may be provided at the lower part of the side wall surface facing the surface provided with the introduction port.
  • the arrangement position of the water vaporizer 5 is not limited to the above embodiment.
  • the water vaporizer 5 is arranged in the exhaust gas flow path at the bottom in the module main body 10, and the heat of the exhaust gas is converted into the water vaporizer 5. It is good also as a structure collect
  • the temperature detection part 24 is comprised by a pair of thermocouple provided in the upstream and downstream of the combustion catalyst 23a, the temperature detection part 24 directly detects the temperature of the combustion catalyst 23a. As such, it may be provided directly on the combustion catalyst 23a.
  • one exhaust part 21 and one intake part 22 are provided in the casing 7, but two or more casings 7 may be provided, and at least one of the casings 7 may be provided. What is necessary is just to be provided. In some cases, the configuration may be such that the intake section 22 is not provided in the casing 7 or the exhaust section 21 and the intake section 22 are not provided in the casing 7.
  • the blower 26 is provided in the intake section 22, but a fan may be used in place of the blower 26, and various types can be used as long as air can be supplied. Further, the arrangement position of the blower 26 is not limited, and it may be arranged at a position where air can be circulated from the outside toward the exhaust section 21 from the intake section 22.
  • a gas sensor that detects a leaked gas is provided in the casing 7 or upstream of the combustion catalyst 23a in the exhaust part 21, and when the leaked gas is detected by the gas sensor, the combustion catalyst 23a is at a predetermined temperature.
  • the heater 25 may be turned on by the control device 8 to heat the combustion catalyst 23a. Further, the combustion catalyst 23a and the heater 25 may not be provided.
  • a gas that does not require reforming such as pure hydrogen or a hydrogen-enriched gas, can also be supplied as the hydrogen-containing fuel.
  • the reformer 2 and the water vaporizer 5 can be omitted.

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  • Fuel Cell (AREA)

Abstract

L'invention porte sur un module de pile à combustible, qui comprend : un corps de module comprenant, à l'intérieur de celui-ci, au moins un empilement de cellules qui génère de l'électricité par l'utilisation d'un gaz reformé ; un matériau d'isolation thermique disposé de façon à entourer le corps de module ; et un boîtier ayant une structure étanche à l'air et qui renferme le corps de module et le matériau d'isolation thermique.
PCT/JP2012/057627 2011-03-24 2012-03-23 Module de pile à combustible WO2012128368A1 (fr)

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JP2011-065897 2011-03-24

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JP2016046160A (ja) * 2014-08-25 2016-04-04 三浦工業株式会社 燃料電池システム
JP2016072054A (ja) * 2014-09-30 2016-05-09 アイシン精機株式会社 燃料電池モジュールおよび燃料電池システム
WO2017154137A1 (fr) * 2016-03-09 2017-09-14 株式会社 東芝 Récipient pour des empilements de cellules d'électrolyse à oxyde solide, système de production d'hydrogène et système de stockage d'énergie électrique
JP2017183254A (ja) * 2016-03-31 2017-10-05 本田技研工業株式会社 燃料電池システム
EP3240082A1 (fr) * 2016-04-28 2017-11-01 Panasonic Intellectual Property Management Co., Ltd. Système de pile à combustible fonctionnant à haute température et procédé de fonctionnement d'un système de pile à combustible fonctionnant à haute température
WO2018024774A1 (fr) * 2016-08-02 2018-02-08 Avl List Gmbh Unité de générateur comportant un dispositif à pile à combustible, véhicule comportant une unité de générateur de ce type et procédé de surveillance d'unité de générateur
WO2019021481A1 (fr) 2017-07-28 2019-01-31 日産自動車株式会社 Système de piles à combustible
AT525203A1 (de) * 2021-07-06 2023-01-15 Avl List Gmbh Brennstoffzellensystem mit einer Rekombinationsvorrichtung

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WO2019004032A1 (fr) * 2017-06-30 2019-01-03 ダイニチ工業株式会社 Dispositif de pile à combustible
WO2024104596A1 (fr) * 2022-11-18 2024-05-23 Volvo Truck Corporation Dispositif d'élimination d'hydrogène pour système de pile à combustible

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JP2002093435A (ja) * 2000-09-12 2002-03-29 Nissan Motor Co Ltd 燃料電池ユニット
JP2004253260A (ja) * 2003-02-20 2004-09-09 Nissan Motor Co Ltd 燃料電池プラントの制御装置
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016046160A (ja) * 2014-08-25 2016-04-04 三浦工業株式会社 燃料電池システム
JP2016072054A (ja) * 2014-09-30 2016-05-09 アイシン精機株式会社 燃料電池モジュールおよび燃料電池システム
WO2017154137A1 (fr) * 2016-03-09 2017-09-14 株式会社 東芝 Récipient pour des empilements de cellules d'électrolyse à oxyde solide, système de production d'hydrogène et système de stockage d'énergie électrique
JPWO2017154137A1 (ja) * 2016-03-09 2019-02-14 株式会社東芝 固体酸化物形電解セルスタックの収容容器、水素製造システム、電力貯蔵システム
JP2017183254A (ja) * 2016-03-31 2017-10-05 本田技研工業株式会社 燃料電池システム
EP3240082A1 (fr) * 2016-04-28 2017-11-01 Panasonic Intellectual Property Management Co., Ltd. Système de pile à combustible fonctionnant à haute température et procédé de fonctionnement d'un système de pile à combustible fonctionnant à haute température
US11165078B2 (en) 2016-08-02 2021-11-02 Avl List Gmbh Generator unit having a fuel cell device, vehicle having a generator unit of this type and method for monitoring a generator unit
WO2018024774A1 (fr) * 2016-08-02 2018-02-08 Avl List Gmbh Unité de générateur comportant un dispositif à pile à combustible, véhicule comportant une unité de générateur de ce type et procédé de surveillance d'unité de générateur
CN109643812A (zh) * 2016-08-02 2019-04-16 Avl李斯特有限公司 具有燃料电池装置的发电机系统、具有这种发电机系统的载具和发电机系统监视方法
WO2019021481A1 (fr) 2017-07-28 2019-01-31 日産自動車株式会社 Système de piles à combustible
US10998564B2 (en) 2017-07-28 2021-05-04 Nissan Motor Co., Ltd. Fuel cell system
AT525203A1 (de) * 2021-07-06 2023-01-15 Avl List Gmbh Brennstoffzellensystem mit einer Rekombinationsvorrichtung
AT525203B1 (de) * 2021-07-06 2023-03-15 Avl List Gmbh Brennstoffzellensystem mit einer Rekombinationsvorrichtung

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