WO2012124935A3 - 그라핀 및 탄소나노튜브를 포함하는 하이브리드 고분자 복합 섬유 및 이의 제조 방법 - Google Patents

그라핀 및 탄소나노튜브를 포함하는 하이브리드 고분자 복합 섬유 및 이의 제조 방법 Download PDF

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WO2012124935A3
WO2012124935A3 PCT/KR2012/001719 KR2012001719W WO2012124935A3 WO 2012124935 A3 WO2012124935 A3 WO 2012124935A3 KR 2012001719 W KR2012001719 W KR 2012001719W WO 2012124935 A3 WO2012124935 A3 WO 2012124935A3
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composite fiber
carbon nanotube
manufacturing same
polymer composite
fiber including
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PCT/KR2012/001719
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English (en)
French (fr)
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WO2012124935A2 (ko
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김선정
신민균
김시형
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한양대학교 산학협력단
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Priority to EP12758257.5A priority Critical patent/EP2698457B1/en
Priority to US14/005,407 priority patent/US9453118B2/en
Publication of WO2012124935A2 publication Critical patent/WO2012124935A2/ko
Publication of WO2012124935A3 publication Critical patent/WO2012124935A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
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    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
    • C08J3/2053—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the additives only being premixed with a liquid phase
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K3/00—Use of inorganic substances as compounding ingredients
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
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    • C—CHEMISTRY; METALLURGY
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    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
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    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00—Treatment of filament-forming or like material
    • D01D1/02—Preparation of spinning solutions
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/06—Wet spinning methods
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    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
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    • D01F1/02—Addition of substances to the spinning solution or to the melt
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    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
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    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
    • C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/14—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals
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    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/16—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated carboxylic acids or unsaturated organic esters, e.g. polyacrylic esters, polyvinyl acetate

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  • Chemical & Material Sciences (AREA)
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  • Textile Engineering (AREA)
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  • Condensed Matter Physics & Semiconductors (AREA)
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  • Toxicology (AREA)
  • Inorganic Fibers (AREA)
  • Carbon And Carbon Compounds (AREA)
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Abstract

본 발명은 그라핀 기반의 하이브리드 고분자 복합 섬유 및 이의 제조 방법에 관한 것으로서, 보다 구체적으로 그라핀, 탄소나노튜브 및 고분자를 포함하며, 상기 그라핀과 상기 탄소나노튜브가 수소결합을 통한 자가정렬 방식으로 결합되어 연신 과정 없이도 높은 인성(toughness)과 유연성(flexible) 특성을 갖는 하이브리드 고분자 복합 섬유 및 이의 제조 방법에 관한 것이다.
PCT/KR2012/001719 2011-03-15 2012-03-09 그라핀 및 탄소나노튜브를 포함하는 하이브리드 고분자 복합 섬유 및 이의 제조 방법 WO2012124935A2 (ko)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP12758257.5A EP2698457B1 (en) 2011-03-15 2012-03-09 Hybrid polymer composite fiber including graphene and carbon nanotube, and method for manufacturing same
US14/005,407 US9453118B2 (en) 2011-03-15 2012-03-09 Hybrid polymer composite fiber including graphene and carbon nanotube, and method for manufacturing same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020110022834A KR101182380B1 (ko) 2011-03-15 2011-03-15 그라핀 및 탄소나노튜브를 포함하는 하이브리드 고분자 복합 섬유 및 이의 제조 방법
KR10-2011-0022834 2011-03-15

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WO2012124935A2 WO2012124935A2 (ko) 2012-09-20
WO2012124935A3 true WO2012124935A3 (ko) 2012-12-27

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US (1) US9453118B2 (ko)
EP (1) EP2698457B1 (ko)
KR (1) KR101182380B1 (ko)
WO (1) WO2012124935A2 (ko)

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* Cited by examiner, † Cited by third party
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KR101338033B1 (ko) 2012-02-10 2013-12-06 금오공과대학교 산학협력단 아라미드／그래핀／탄소나노튜브 복합체의 제조방법 및 그에 따라 제조된 아라미드／그래핀／탄소나노튜브 복합체
WO2014040275A1 (en) * 2012-09-14 2014-03-20 Empire Technology Development Llc Graphene and carbon nanotube compositions
KR101373049B1 (ko) 2012-11-20 2014-03-17 한국과학기술연구원 환원그래핀산화물이 코팅된 섬유사 및 그 제조방법
KR101408277B1 (ko) * 2012-12-04 2014-06-16 숭실대학교산학협력단 계면활성제를 이용한 방사성이 향상된 탄소나노튜브 섬유의 제조방법 및 이에 의해 제조된 탄소나노튜브 섬유
KR101410854B1 (ko) * 2013-04-01 2014-06-23 한국전기연구원 다중수소결합에 의해 고차구조를 지니는 탄소나노소재와 금속나노소재를 하이브리드하여 형성된 고전도성 소재 및 그 제조방법
WO2014186452A1 (en) * 2013-05-14 2014-11-20 Ilhan Aksay Graphene dispersions
US9804493B2 (en) * 2013-11-22 2017-10-31 Samsung Electronics Co., Ltd. Composition for forming topcoat layer and resist pattern formation method employing the same
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KR20150078508A (ko) * 2013-12-30 2015-07-08 엘지디스플레이 주식회사 멀티-기능 배리어층을 갖는 플렉서블 전자 디바이스
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CN104328653B (zh) * 2014-10-11 2016-06-08 江南大学 一种氧化石墨烯衍生物用于纺织品多功能整理的方法
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US10683590B2 (en) 2015-07-16 2020-06-16 Rensselaer Polytechnic Institute Graphene fiber and method of manufacturing same
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CN105131359B (zh) * 2015-09-19 2017-10-13 四川大学 石墨烯/碳纳米管杂化填料网络增强橡胶材料及其制备方法
CN105502353B (zh) * 2015-12-14 2018-08-17 湖南科技大学 一种包裹型单层氧化石墨烯/碳纳米管复合物及其制备方法
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KR101812536B1 (ko) * 2016-05-04 2017-12-29 재단법인 차세대융합기술연구원 습식 방사공정을 이용한 그래핀산화물/탄소나노튜브 복합섬유, 그래핀산화물/그래핀 복합섬유 또는 그래핀산화물/그래핀/탄소나노튜브 복합섬유의 제조 방법
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WO2012124935A2 (ko) 2012-09-20
KR101182380B1 (ko) 2012-09-12
US9453118B2 (en) 2016-09-27

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